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By T. Feldmann, G. P. Demopoulos

The adsorption of gold complexes on inorganic metal oxides has been mainly discussed in geochemical literature, but it is also of interest to the hydrometallurgical industry. This is so because it could be responsible for valuable metal losses or because it could potentially serve as alternative adsorbent material to activated carbon in certain cases such as from hot and acidic process slurries. This paper constitutes an early investigation into this subject by focusing on the effectiveness of FeOOH, Fe3O4 and Al2O3 as sorbent materials. All tests were done in a batch stirred-tank reactor under atmospheric conditions with synthetic gold(III)-chloride solutions at 23°C and 80°C, in the pH range of 1.6 to 9.0. Detailed kinetic tests were performed at different pH values (3 and 6) on FeOOH and Fe3O4 with solutions having gold concentrations from 5 mg/L to 130 mg/L. The adsorption of gold was found to be best both in terms of kinetics and loading characteristics at 80°C and pH=6. This was explained by a change in Au(III)-Cl speciation from a gold(III)-chloride complex to a gold(III)-chloride-hydroxy complex. By far, magnetite (reagent grade chemical) yielded the best gold adsorption characteristics making it an interesting sorbent material for further development considering that it can be advantageously recovered from slurry streams via magnetic separation. On the other hand, the tendency of gold(III)-chloro complexes to adsorb on metal (hydro) oxides needs to be taken into account to minimize undesirable metal losses in chloride-containing leaching media.

Jan 1, 2015

By K. N. Han

The adsorption of gold onto activated carbon in iodide solutions was studied. The adsorption rates were determined as a function of temperature, salt concentration and pH, as well as activated carbon concentration. A kinetic model was developed for the adsorption. The adsorption rate was believed to be controlled by a combined mechanism of film diffusion and pore diffusion with the film diffusion having the most significant effect. Experimental findings were in good agreement with the model developed. The apparent activation energy was found to be 14.9 kJ/mol.

Jan 1, 1995

The adsorption of gold onto activated carbon in iodide solutions has been studied. The adsorption rates were determined as a function of temperature, salt concentration and pH as well as activated carbon concentration. A kinetic model was also developed for the adsorption. The adsorption rate was believed to be controlled by a mixed mechanism of film diffusion and pore diffusion, but the film diffusion had a major contribution to the overall rate. Experimental findings were in good agreement with the model developed. The apparent activation energy was found to be 14.9 kJ/mol.

Jan 1, 1993

By Batric Pesic

Adsorption of gold on activated carbon from gold bromide solutions was examined as a function of pH, particle size, carbon amount, initial gold bromide concentration, bromine concentration, temperature, and various cations and anions. pH did not have any effect below pH=6. Above pH=6, pH had dramatically negative effect. The adsorption results satisfied a first reaction order model. The reaction rate constant was proportional to the inverse of carbon particle radius. It was also proportional to the amount of carbon, and independent of initial gold concentration. Temperature had a very little effect at pH=l. At pH=8, the activation energy was a function of the extent of a reaction, increasing with the extent of a reaction. Cu, Fe, Ca, Mg, and Na cations and sulfate, chloride and bromide anions did not have any effect on gold adsorption. Bromine had a very negative effect on gold uptake.

Jan 1, 1991

Adsorption of guar gum was investigated on model minerals typically found in water-insoluble slimes of potash ores. The ionic strength of the adsorption mixtures was varied from distilled water to saturated NaC1 and KC1. The tests were also performed using a saturated brine. The adsorption density of guar gum on illite, dolomite, and kaolinite was found to be not only a function of total ionic strength but also of the type of electrolyte present in solution. Generally, the adsorption of the polymer on the clay minerals was higher in KC1 solutions than in NaCI, but the differences gradually disappeared when the electrolyte concentration approached saturation. The results were analyzed in terms of chaotropic (K ) or kosmotropic (Na') properties of background counter-ions and their different behaviors at the hydrated mineral-water interface. Guar gum adsorption on dolomite was related to the presence of calcium and magnesium sites on the mineral surface, and to the cis-configuration of OH groups of mannose units. Based on viscosity measurements, it was suggested that guar gum macromolecules form entanglements in NaCI solutions (and distilled water), but individual molecules exist in KC1 solutions thus creating different modes of adsorption of guar gum from concentrated NaCl and KCl solutions.

Jan 1, 2006

By Ping K. Di

A naturally aged and synthesized manganese oxide-coated granular media was found in our laboratory to have the capability of the removal of soluble Mn(H) from mine drainage by adsorption and oxidation. Mine drainage commonly also includes other heavy metal ions. Extending this principle, this paper presents the removal of heavy metals including lead, copper, cobalt, zinc and nickel in the aqueous solution by using the synthesized manganese oxide-coated granular media. It was found that the adsorption of lead, copper, cobalt, zinc and nickel on the manganese oxide-coated media follows both Langmuir and Dubinin-Radushkevich adsorption isotherms except in the concentration range less than 0.1 mmole/L. The adsorption mechanism involves the ion exchange between the heavy metal ions and synthesized manganese oxide coated on the media. The synthetic manganese oxide surface has a strong metal binding ability to the heavy metals in the order of Pb2+ > Cu2+ > Ni2+ > Zn2+ > C02+ based on the adsorption results using batch and continuous column operations. The breakthrough curves of these heavy metals showed that the synthesized media could be used effectively in the removal of these heavy metal ions in a cell or packed column. The process can simultaneously facilitate the immobilization of the heavy metals on the synthesized manganese oxide coated media. A subsequent pH adjustment dislodges the heavy metals and regenerates the synthetic media. Thus, the process accomplishes the adsorption, immobilization and concentration of the heavy metal from waste stream in one monolithic procedure.

Jan 1, 1995

By M. A. Barakat

"Adsorption of heavy metal ions specifically, Cu(II), Zn(II), Mn(II), and Cr(VI) from aqueous solution on synthetic 4A Zeolite was evaluated. The 4A zeolite was synthesized previously by dehydroxylation of low grade Kalabsha Kaolin at 800 °C, and reacted hydrothermally with 2-4 M NaOH solution at 100 °C for 2h. The adsorption capacity of the metal ions were found to be strongly dependent on pH and initial metal ion concentration. At the optimium conditions the adsorption capacity decreased in the order Cu(II) > Zn(II) > Mn(II) > Cr(VI) ions. Almost complete adsorption was achieved for both of Cu(II) and Zn(II) ions at pH > 6, while the adsorption capacity for both Mn(II) and Cr(VI) was 96, and 55.3 % at pH 11 and pH 3, respectively. The results also showed that the grain size of the 4A zeolite has a little effect on the adsorption capacity. The experimental data was compared with two adsorption isotherms, Langmuir and Freundlich isotheroms. The results showed a good agreement of the Langmuir plots with the experimental data.1. IntroductionSeveral industrial wastewater streams may contain heavy metals such as Cr, Cu, Pb, Zn, Co, Ni, Mn, etc. including the waste liquids generated by metal finishing or the mineral processing industries. Heavy metals are considered hazardous pollutants due to their toxicity, even at low concentration, and nonbiodegradability. Increasing level of heavy metals in natural water bodies poses a serious threat to all living species including humans. It is, therefore, essential to reduce the heavy metal concentration in effluents/wastewater before it is discharged into the water bodies [1]."

Jan 1, 2008

By R. F. Robertson

"Adsorption isotherms of hexyl mercaptan vapour on synthetic sphalerite, zinc sulphide and zinc oxide were de-termined with a gravimetric McBain-Baker micro balance incorporated in the B.E.T. apparatus. Isotherms are given for hexyl mercaptan on synthetic sphalerite at 25°C, 0.5°C and 50°C; on zinc sulphide at 25°C and 1.5°C; and on zinc oxide at 25°C. All these isotherms are sigmoidal, with a definite change in slope at or close to the mono-layer. The amount of mercaptan adsorbed below the monolayer increases almost linearly with relative pressure to P/P0 = 0.8.Above this value, the amount adsorbed increases very rapidly with relative pressure. Hysteresis loops appear in the isotherms for all adsorption-desorption cycles. These loops are completely reversible. It is not possible to desorb the mercaptan monolayer from any of the adsorbents, even at elevated temperatures."

Jan 1, 1966

By S. Vivek

An Atomic force microscope (AFM) was used to measure the surface forces between hydrophobic silica surfaces. The measurements were conducted in the presence and absence of Cu(II)species in solution to study the effects of the cation adsorption on the hydrophobic force. The results obtained in the absence of the Cu (II)species showed that the hydrophobic force does not change with pH, while the electrostatic repulsive force changes substantially with pH. In the presence of the Cu(II) species, the hydrophobic force begins to decrease at a pH where Cu2+ions are hydrolyzed, indicating that the first hydrolysis product (i.e., CuOH+ions) are the species adsorbing on the surface of the hydrophobic silica. The results of the surface force measurements were used to develop a model for the adsorption of the hydrolysis product of Cu(II) species on the hydrophobic silica.

Jan 1, 2003

By Gjergj Dodbiba, Toyohisa Fujita, Takahiro Kikuchi, I-Chen Wu

"In order to separate molybdenum (Mo) from the high-level radioactive liquid waste (HLLW), Pb-Fe based adsorbents were synthesized. The adsorbents were precipitated by adding sodium hydroxide in mixture of 1 mol/L lead nitrate and 1 mol/L ferric nitrate aqueous solutions. Each precipitate was then filtered, dried and ground to obtain a fine powder, which has been used as an adsorbent. Two main parameters were considered when synthesizing the adsorbents, i.e. the pH value at precipitation of adsorbent precursor and the calcination temperature of Pb-Fe based adsorbent. Moreover, the structures of the synthesized adsorbents were investigated by means of an X-ray diffractometer.The experimental results indicated that the calcination temperature of the Pb-Fe based adsorbent has a great influence on adsorption capacity of the adsorbent for Mo. It was found that when the Pb-Fe based adsorbent was calcinated at 500 oC, the sorbed concentration of Mo was the highest.1. IntroductionThe high-level radioactive liquid waste (HLLW), arising from the reprocessing of nuclear fuel are generally immobilized in an alkali borosilicate glass matrix. Broadly speaking, alkali borosilicate glasses are the matrix of choice for the immobilization of the HLLW, since they permit vitrification of waste stream of variable composition, [1]. Within this frame, the incorporation of molybdenum (Mo) is of particular interest in the vitrification of HLLW. Molybdenum is know to have a low solubility in borosilicate glass compositions and its presence in excess results in the phase separation of a complex yellow molten salt during vitrification, [1]. The formation of so-called “yellow phase” material during the vitrification process is undesirable since it leads to the accelerated corrosion of the inconel crucible liners. Furthermore, the “yellow phase”, which is reported to contain also other fission products, is soluble in aqueous solution providing a potential route for the leaching of radionuclides from the vitrified waste, should it come into contact with water, [1]."

Jan 1, 2008

By H. Z. Liu, J. M. Zhao, F. C. Wang

"Novel silicate-alginate composite beads containing 2-ethylhexyl phosphonic acid mono-2- ethylhexyl ester (P507) were synthesized and applied for the adsorption of Nd3+ from aqueous solutions. The adsorption amount of Nd3+ has been increased owing to the introduction of P507. The effect of equilibrium pH (pHe), the kinetic and isotherm experiments were investigated. The adsorption reaches equilibrium at 9 h and the maximum uptake capacity is up to 195.4 mg/(g dry adsorbent). The Langmuir isotherm equations are used to describe the adsorption process. Complete desorption can be realized with 0.2 M HCl within 20 min. INTRODUCTIONRare earth elements (REEs) have found various applications in different domains, such as metallurgy industry, ceramic industry, nuclear fuel control, photo-electro-magnetic functional materials owing to their unique properties. Neodymium (Nd), as a representative of all of the most valuable REEs, is widely used as catalysts, laser crystals, capacitors, rubber additives, Nd-Fe-B magnets, hydrogen storage and so on. Thus, the separation and purification of neodymium is significant. Unfortunately, Nd always coexists with other REEs and selective separation of the individual Nd from the REEs mixtures is still extremely difficult owing to their strictly similar atomic structures and chemical properties.Liquid-liquid extraction (LLE) and solid-liquid adsorption (SLA) are the most widely adopted techniques for the separation of REEs in the hydrometallurgical fields. The LLE process is well suited for large-scale continuous operation because of its inherent high capacity and fast kinetics. Nowadays, as a commercial extractant, 2-ethylhexyl phosphonic acid mono-2-ethylhexyl ester (P507) has been extensively studied for extraction and separation of REEs since it has considerably good extractability and high separation efficiency (Xu et al., 1992). SLA is one of the effective and green separation methods with some prominent advantages, such as easy regeneration of adsorbents, small footprint size, less industrial wastes, higher enrichment factors and column efficiency,rapid solid–liquid separation without emulsion and so on. Hence, the introduction of extractants with excellent performance into adsorbents will integrate the advantages of LLE and SLA (Lee et al., 2009)."

Jan 1, 2012

By P. Somasundaran

Adsorption of a nonionic polyacrylamide (PAM), an anionic polyacrylamide with sulfonate functional groups (PAMS), and a cationic polyacrylamide with amine functional groups (PAMD), on hematite was investigated as a function of different solution conditions. Adsorption results indicate that the major mechanisms of adsorption of polyacrylamides on hematite is through hydrogen bonding, with electrostatic forces playing a secondary role. All the polymers exhibited irreversibility of adsorption upon dilution. Also, entropic effects were determined to be important in adsorption. Surface chemical properties of hematite and solution chemistry of the polyacrylamides are considered to explain the polymer adsorption behavior on hematite.

Jan 1, 1985

By Q. Xu, P. Somasundaran

Adsorption of nonionic/anionic surfactant mixtures on kaolinite has been studied, with •Sodium dodecylsulfate as the anionic surfactant, and •Octaethyleneglycol mono-n-dodecylether as the nonionic surfactant. Synergistic interaction between these surfactants was found to cause adsorption of the nonionic surfactant with its hydrophilic chains protruding into the bulk, leading to substantial changes in wettability and dispersion characteristics of kaolinite. Similarly, hydrophobicity changes are observed also for silica particles upon adsorption of nonionic ethoxylated alcohols owing to possible changes in the orientation of the adsorbed surfactant molecules at the interface.

Jan 1, 1993

By Q. Xu

Adsorption of nonionic/anionic surfactant mixtures on kaolinite has been studied with sodium dodecylsulfate as the anionic surfactant and octaethyleneglycol mono-n-dodecylether as the nonionic surfactant. Synergistic interaction between these surfactant was found to cause adsorption of the nonionic surfactant with its hydrophilic chains protruding into the bulk, leading to substantial changes in wettability and dispersion characteristics of kaolinite. Similarly, hydrophobicity changes are observed also for silica particles upon adsorption of nonionic ethoxylated alcohols owing to possible changes in the orientation of the adsorbed surfactant molecules at the interface.

Jan 1, 1991

By J. Drelich

The adsorption of oleate at the surface of titanium dioxide from aqueous solutions was examined by Fourier transform infrared (FT -IR.) spectroscopy using a germanium internal reflection element coated with a thin film of TiO2. This thin film, with a thickness of 100-200 A, was deposited on the surface of a germanium single crystal by RFIDC magnetron reactive sputtering. It was found that significant adsorption of oleate from a 0.02-0.03 mM aqueous solution on the surface of TiO2 thin film occurs at neutral pH, from about pH=5.5 to pH=7.7. Adsorption of oleate at the surface of the amorphous TiO2 thin film appeared to be reversible, involving soap-acid dimers.

Jan 1, 1997

By T. V. Vasudevan, J. Blaakmeer

Adsorption experiments were conducted at two different solid loadings to investigate the mechanism of oleate adsorption on apatite. Adsorption density at pH 10 was found to be dependent on solids loading in an oleate concentration region where surface precipitation could occur. Analysis of adsorption isotherms indicated three distinct regions of adsorption. In region I (below the region of calcium oleate precipitation), molecular adsorption was observed. Simultaneous molecular adsorption and surface precipitation occurred in region 11, while surface precipitation was predominant in region I11 along with some bulk precipitation. Correlation between flotation of apatite with sodium oleate and the mode of oleate interaction with the surface is established.

Jan 1, 1988

Adsorption experiments were conducted at two different solids loadings, to investigate the mechanism of oleate adsorption on apatite. Adsorption density at pH 10 was found to be dependent on solids loading in an oleate concentration region where surface precipitation could occur. Analysis of adsorption isotherms indicated three distinct regions of adsorption. In the region I (below the region of calcium oleate precipitation), molecular adsorption was observed. Simultaneous molecular adsorption and surface precipitation occurred in region II, while surface precipitation was predominant in region III along with some bulk precipitation. Correlation between flotation of apatite with sodium oleate and the mode of oleate interaction with the surface is established.

Jan 1, 1986

Organic dyes such as nigrosine and sun yellow act as depressants for carbonaceous particles in the, flotation of sulphide ores. Depression is achieved when initially hydrophobic organic surfaces are made hydrophilic by preferential adsorption of dye molecules. Experimental studies, mainly on Mount Isa ores, indicate that dyes are adsorbed as planar anionic micelles attached to carbonaceous surfaces by van der Waals and ion exchange attractive interactions. Relationships appear to exist between the amount of organic matter on the surface of ground particles, the surface area of the particles, the "saturation" adsorptions of dyes, and the degree of difficulty experienced during froth flotation.

Jan 1, 1975

By Bo Liang, Hongmin Zhu, Kai Huang, Shafiq Alam

A new approach of recovering platinum and palladium from electronic wastes by hydrochloric acid leaching followed by selective adsorption on low-cost and environmentally benign biomass sorbent prepared from easily available agriculture waste is suggested. The obtained adsorbents were prepared by a combination of chemical modification and hydrothermal carbonization process with (NH4)2C2O4. It was found that the maximum adsorption capacity of hydrothermal carbonized garlic peel for Pt( ) and Pd( ) was 1.64 and 0.42 mol/kg respectively. The Langmuir adsorption isotherm was applied to describe the adsorption process. Kinetics of the Pt( ) and Pd( ) ions adsorption was found to follow pseudo-second-order rate equation. The adsorbents were examined by scanning electron microscope (SEM), and Fourier transform infrared spectroscopy (FT-IR). Based on the characterization results, a possible mechanism of Pt( ) and Pd( ) ions adsorption with the hydrothermal carbonized garlic peel was proposed. This study provides a promising adsorbent with efficient adsorption property for platinum and palladium recovery from the leach solution of electronic wastes.

Jan 1, 2016

By Alexander Knoll, Dwight L. Baker

THIS paper is a report on work undertaken to investigate the results and conclusions of Ravitz and Porter1,2. that galena freed of surface oxidation products and lead carbonate ("clean" galena) is water-repellent, and that the action of xanthates in flotation is the action of a cleansing agent, enabling oxidized galena particles to expose a pure lead sulphide, water-repellent surface. The apparatus, in construction and use, was essentially that of Ravitz and Porter. The only significant modification introduced by the present authors was the substitution of a three-necked flask for the flotation cell as the "reaction vessel." Our procedure was to place 50 grams of freshly ground, minus 200-mesh galena in the reaction vessel, sweep out all molecular oxygen from the system with oxygen-free nitrogen, and proceed to wash the galena surface free of its oxidation products with repeated small portions of (I) ammonium acetate (500 c.c. of water, 200 grams of ammonium acetate) or (2) ammonium chloride, hydrochloric acid (2 liters containing 200 grams of ammonium chloride and 25 c.c. of 1.18 sp. gr. hydro chloric acid). The galena was next washed with many 100-c.c. portions of oxygen-free, distilled water. The galena was finally considered free of soluble salts when wash water that had been in contact with the mineral for at least 48 hr.* gave negative tests for: (I) lead ion with sulphide; (2) chloride with silver ion; (3) acetate with cuprous chloride, sodium chloride; and (4) ammonium ion with Nessler's reagent. Next 500 c.c. of potassium ethyl xanthate solution, free of dissolved oxygen, was run onto the "clean" galena particles. For this system there were determined: I. The wetting properties of the clean galena particles by shaking the reaction flask and noting the degree of mineral collection at the liquid-air interface. This was, of course, simply a qualitative test, but it proved adequate for our purpose. 2. The removal of xanthate ion from the potassium xanthate solution on being shaken with the "cleansed" mineral. Xanthate concentrations were determined by iodine titration according to the methods of Taylor and Knoll.3 3. The pH of the xanthate solution after having been shaken with the "cleansed" galena. The pH was determined colorimetrically.4 The results of five experiments of the type mentioned above are given in Table I.

Jan 1, 1941