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The primary arsenic minerals in the uranium ore processed at the McClean Lake Operation are rammelsbergite, niccolite and gersdorffite. During processing, a large fraction (80 - 95%) of these reduced minerals is oxidized and dissolves primarily as As5+ in the leachate solution. In the tailings preparation circuit the dissolved As5+ is precipitated as a poorly crystalline form of the mineral scorodite. Following subaqueous deposition in the tailings management facility, a temporal rise and fall in arsenic pore water concentrations has been observed. This is due to the oxidation of the residual quantities of reduced arsenic minerals initially present in the tailings sediment. The XANES (x-ray absorption near edge spectrometry) technique has shown that the As1- is gradually oxidized to As3+ and then finally As5+ in the tailings sediment. This oxidation process results in a temporary accumulation of As3+ in solution and is the source of the rise and fall in arsenic concentration observed.

Aug 1, 2010

By Morris Cohen

IT has been known for several years that in certain age-hardenable alloys precipitation of finely divided particles occurs simultaneously with the changes in physical properties; while, in other alloys, these changes take place prior to, or without any, precipitation. . The silver-copper alloys are generally considered to be the classical example of the first group, and the aluminum-copper alloys (duralumin) are typical of the second group. The two types of aging are explained by the precipitation theory and the knot theory respectively. ? It is well recognized now that these theories do not conflict with each other; the one used for a given aging system depends upon which way the alloy in question happens to age-harden. However, previous work on the aluminum-copper alloys1,2 has shown that if the aging temperature is raised sufficiently the hardening will be accompanied by actual precipitation. In fact, it is quite probable that all of the so-called knot-hardening alloys will harden by precipitation at elevated temperatures. Therefore, a combination of the knot and precip-itation theories is necessary to give a complete picture of the age-harden-ing of these alloys, and indicates that knot formation and precipitation are not independent processes. To test the generality of this concept, it is necessary to show that the alloys that commonly harden by precipitation will harden prior to precip¬itation if the aging temperature is sufficiently lowered. For this reason, it would be well to carefully re-examine the aging characteristics of the silver-copper alloys at aging temperatures somewhat below those used by previous investigators. If hardening can be detected prior to precipi¬tation in these alloys, it will lend great weight to the idea that knot forma-

Jan 1, 1936

By R. Elliott, H. Bayati

"Effect of time and temperature on microstructure and mechanical properties of an austempered ductile iron, ADI, of composition 3.6%C, 2.6%Si, 0.4%Cu, 0.2%Mn are reported. Xray analysis and. microstructural observations indicate that lowering the working temperature, aging temperature, increases the lifetime of ADI significantly. Results show· that lowering the aging temperature increases the strength and reduces the ductility of ADI. DSC traces for ADI austempered at 340°C are presented. Comparison of the DSC analysis and kinetic measurements demonstrates that the DSC traces can be· used to predict the life time of ADI successfully.IntroductionAustempered ductile iron, ADI, is one of the most significant developments in cast iron technology over the past two decades. Outstanding properties of high yield, ultimate strength, ductility, fatigue and wear· resistance make ADI suitable for a range of applications including gears, connecting rods, crankshafts and agriculture machine components. The austempering reaction in cast iron occurs in two stages, Fig. I, in contrast to the single stage reaction in steel. In stage I the relatively low carbon austenite produced during austenitising transforms into ferritic plates and high carbon austenite, a metastable structure called·ausferrite. The high carbon ailstenite and supersaturated ferrite produced in stage I decompose into ferrite and carbide in stage II: to form a structure similar to the bainitic structure in steel. This behaviour exposes a well-defined processing window, t1 - t2, over which the maximum amount of ausferrite is produced, Figure 1. Whereas the bainitic structure determines the properties of austempered steel, ADI properties are mainly affected by volume fraction of retained austenite (VRA), austenite carbon content (ACC), unreacted or martensite volume fraction (UA V), compositiori and amount of carbides, and morphology of ferritic plates[l,2]. Due to the detrimental .effect of martensite and carbides on properties of ADI, an ideal structure of ADI consists only of ausferrite [l,2]. Thus, it is common to determine the processing window for each austempering treatment in order to identify the optimized austempering time. Decomposition of austenite (stage II) signals the end of the life time for an ADI component, therefore, the aging behaviour of ADI at different working conditions can be studied by determining the t2."

Jan 1, 2000

By Wataru Inagaki, Kozo Kawano, Tetsuya Ando

Cu–Ni–P alloys are the typical precipitation-hardening material. Thus, Cu–Ni–P alloys is expected to apply alternative materials for heat-exchanger tubes. Therefore, it was investigated that the effect of the heat-treatment simulated brazing on mechanical properties of Cu–Ni–P alloy in this study. The hardness of specimen as heat-treatment simulated brazing after solution heat treated (sht) was shown approximately 105 HV. The peak hardness and tensile strength of the specimen as performed aged at 498 K for 43.2 ks following the heat-treatment simulated brazing achieved at approximately 140 HV and 260 MPa, respectively. From these results, it is expected the application to higher-strength tube for heat-exchanger after brazing in a furnace. INTRODUCTION Copper prices have increased dramatically with high in recent years. At the same time, manufacturing industries are required to reduce the environment load by reducing the wall thickness of the copper tubes used in heat exchangers. High-strength copper alloys are developed for reducing the wall thickness, while achieving high strength, of the copper tubes. Moreover, excellent workability and corrosive durability are also required by these copper tubes. Furthermore, the brazing, which are carried out at about 1050 K during the assembly process of heat exchangers, leads to grain growth and re-solving of additive elements. Nomura et al. achieved a tensile strength and Vickers hardness of approximately 260 MPa and 110 HV, respectively, after aging at 723 K for approximately 36 ks. Tamagawa et al. studied that the strength of Cu–Ni–P alloy rapidly increased at about 125 HV during the cooling process after the heat brazing due to the Ni2P precipitates sized 5–10 nm. Furthermore, Inagaki et al. achieved a Vickers hardness of approximately 130 HV by aging at 498 K for 10.8 ks. In the present study, we focused on the lowest aging temperature of 498 K in the previous study, and investigating the effect of heat-treatment simulated brazing on the mechanical properties of the Cu–0.93 mass%Ni–0.24 mass%P alloy.

Jan 1, 2019

By C. A. Holley

Agitative agglomeration is a rapidly expanding field related to many chemical processes. This paper reviews many processes and the particular type of agitative agglomeration that is utilized with each. Many new innovations to produce granular products in place of powder are explored. The operation and theory of the many types of agitative agglomeration equipment is reviewed.

Jan 1, 1988

By J Missen, P Currie, J Bohan, D Clark

AGL is one of Australia’s leading integrated energy companies and the largest ASX listed owner, operator and developer of renewable energy and thermal generation in the country. AGL owns and operates the 2210 MW Loy Yang A power station and adjacent 30 Mt/a brown coalmine in the Latrobe Valley, Victoria. It also supplies coal to the nearby 1050 MW Loy Yang B power station owned by the GDF Suez (Engie)/Mitsui partnership. The mine is currently nearly 5 km long, more than 2 km wide at the operating face and up to 200 m deep. AGL employs a large workforce at Loy Yang and a substantial amount of services are performed on-site by contractors and consultants.GHD provides mine planning, earth sciences, civil/geotechnical engineering, dam surveillance, plant engineering and environmental services to AGL Loy Yang through an alliance framework. GHD is one of the world’s leading professional services companies operating in the global markets of water; energy and resources; environment; property and buildings; and transportation. In addition to GHD’s global footprint, the company also has a significant Victorian presence, including a permanent, well-resourced regional office in Traralgon, approximately 10 km from Loy Yang, as well as a permanent site office.A joint paper on the Loy Yang mine professional services alliance model was written for the AusIMM International Mine Management Conference in 2006 by Woods and Wood. Now ten years on, this paper provides an overview of the present relationship and arrangements, including the continued transformation of the alliance model and maturing of the relationship contract.These are challenging times, with increasing cost and regulatory pressure driving change in the broader energy and resources industry, and locally including both the mining and power sectors at Loy Yang. Flexible models to achieve a balance between internal personnel and access to key external skills, whilst achieving value for money and transparency, is increasingly critical. The right drivers and performance measures are essential, particularly when confronted with potential major technical and environmental risks (considering significant ground failure and fire events that have occurred elsewhere within the Latrobe Valley over the last decade) within a sector that is reducing costs and optimising production.This case study discusses the alliance status and changes, reasons behind adjustments and what the future is likely to hold. The paper also explores the validity of the original objectives and the extent to which they have been achieved. The philosophy of the alliance is to continue closely aligning the objectives of the two companies in the best interests of the Loy Yang site and immediate surrounds/stakeholders. Quality of service, costs, timeliness, health and safety (H&S) and some operational activities (aquifer depressurisation) remain important aspects and are reflected in key indicators for which performance is measured.CITATION:Clark, D, Bohan, J, Currie, P and Missen, J, 2016. AGL energy, Loy Yang and GHD – a further case study in alliancing: ten years on, in Proceedings International Mine Management Conference, pp 321-330 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jun 22, 2016

By Williams Morales Céspedes

Uno de los problemas que surgen durante el proceso de chancado reside en el porcentaje de humedad en los minerales. La presencia de arcillas en forma de bolones causa menor productividad puesto que atora las chancadoras y, por consiguiente, se debe reducir el tonelaje de tratamiento. En ese sentido, el presente trabajo señala el proceso de aglomeración como alternativa de mejora química y física del mineral, de forma que se utilice fajas de mayor resistencia a la abrasión. Para ello, se realizan pruebas con adición al cemento en menor cantidad, para en un futuro dosificar con menor cantidad de cemento sin afectar los actuales parámetros de lixiviación. Así, el cemento, aparte de servir como aglomerante, es un regulador del pH, que actualmentese envía al Pad con promedio de 11 pH.

Jul 31, 2003

By Edelink Efrain Tinoco Falero

Na indústria siderúrgica integrada, geram-se vários tipos de coprodutos, dentre estes escoria granulada de alto forno, os pós de aciaria extraídos nos sistemas de despoeiramento a úmido e a seco do conversor LD e o pó de coletor de alto forno. Em relação aos pós, são principalmente portadores de unidades de ferro e carbono, podendo conter também zinco, o que os tornam alvos de estudos e inovações que buscam recuperar ou reciclar estes elementos. No presente estudo foram concebidos briquetes autorredutores usando os pós finos-F e grossos -G, oriundos de um sistema de despoeiramento a seco de aciaria LD, nas proporções percentuais, F – G, de 50-50 e 70-30, misturados com pó de coletor de alto forno. Utilizando como aglomerante o cimento ARI, foram avaliadas as resistências à compressão dos briquetes em diferentes tempos de cura e determinadas suas metalizações nas temperaturas de 1100°C e 1150°C, em tempos que se estenderam até 45 minutos. Adicionalmente, as capacidades dos briquetes de alterarem a temperatura do aço liquido quando adicionados ao banho, foram avaliadas utilizando-se o balanço térmico do sistema briquete-aço liquido, bem como considerados os potenciais de oxidação do processo e o estabelecimento de um sequenciamento termodinâmico para as reações. Os resultados mostraram que os aglomerados autorredutores possuem alta capacidade refrigerante quando adicionados ao aço liquido, o que os enquadra como possíveis materiais alternativos à sucata e pelotas no controle da temperatura do aço nos convertedores LD. Além disso, a alta cinética de metalização do Fe mostrou ser também viável o uso dos briquetes autorredutores na recuperação do metal contido nos resíduos.

Oct 30, 2017

By Kevin Telmer, Daniel Merino, Scott Smith

El Aglomerado de Carbón y Aceite (COA) es un método práctico, eficiente y fácil de utilizar para la recuperación de oro libre; el método destaca por el bajo costo y fácil acceso a los insumos utilizados, por eso es considerado una alternativa limpia para el beneficio del oro sin uso de mercurio. El método se basa en la formación de aglomerados o pellets compuestos por carbón, agua y aceite, los cuales capturan partículas de oro libre. Esto ocurre gracias a las propiedades hidrófobas/oleófilas que tiene el oro, que permite adherirse a los aglomerados; el aceite actúa como líquido puente entre el carbón y las partículas de oro, facilitando su unión.

Sep 29, 2023

By Pedro Antunes Amaral

Currently there is a constant and essential concern of preserving nature. Over the years the concern with the environment is increasing, new environmental laws are emerging and being applied more rigorously and consequently emerge economic needs and mineral processing practices and other materials. In this sense briquetting becomes an alternative to fine particles agglomeration by means of pressure and or temperature, with the aid or not of a binder, which allows to get a product not only compressed, which presents shape, size, and adequate mechanical properties. The reduction in volume of the material in some cases (beyond the technological benefits) also allows fine materials can be transported and stored more economically, safely and effectively. The production of coke is greater as the content of better coking coal is, thus he low capacity coking coal is not much used in coke ovens. This research aims to demonstrate that briquetting of mineral coals with low coking coal capacity is possible, additionally allows increased coke production, obtaining then a better yield of coke. Basically they take advantage of low price of no coking coals without changing the quality of the coke produced. Anyway, briquetting became a smart alternative to aggregate values, economy and care for the environment.

Oct 30, 2017

Agnico-Eagle Mines Ltd. comprises a Gold Division at Joutel, Quebec, and a Silver Division at Cobalt, Ontario. In 1979 the Silver Division milled 41,700 mt (46,000 st) of ore at a recovered grade of 139 g per mt (4.06 oz per st) for a production of 5,816 kg (187,000 oz) of silver. The 100 -year -old mining, camp of Cobalt has long been noted for its high-grade silver ores, and now seems to be on the threshold of being revived with several companies operating in the area. In 1979, the Gold Division milled at the rate of 27,200 mt per month (30,000 st) and processed 333,000 mt (367,000 st) at a grade of 6.58 g per mt (0.192 oz per st) with a mill recovery of 91.670 to produce 2,013 kg (64,700 oz) of gold. The average total cost per ton milled was $22.10 per mt ($20.05 per st) which was $3.66 per g ($1 13.90 per 0s). These figures make Agnico-Eagle one of the lowest cost producers in North America. Gold occurrence in the Joutel ore is fine-grained and contained within sulfide facies composed mainly of pyrite with minor pyrrhotite. Two underground mining methods are employed with long hole stoping accounting for about 75% of the ore mined and shrinkage stoping the remainder. Ore from underground is hoisted into a 545 mt (600 st) coarse ore bin from where it is conveyed to a 45 mt (50 st) surge bin ahead of the 10-51 Hydrocone crusher. Crushed ore is then screened to make a 13 mm (112 in.) product with the oversize being recrushed in a 7-60 Hydrocone. Mill feed is conveyed to two 900 mt (1,000 st) fine ore bins. The Hydrocones were installed as part of a new crushing plant in March of 1980 and have contributed substantially to an increase in mill capacity. Space has been left to install a third crusher in the future. The fine ore bins discharge to a 2.75 m by 3.66 m (9 ft by 12 ft) rod mill, followed by a 3. 7 m by 5.5 m (12 ft by 18 ft) ball mill in closed circuit with a Krebs 380 mm (15 in.) cyclone to produce a 7070 minus 37 micron (400 mesh) .flotation feed. This pulp is first treated in a 34 cu m (1, 200 cu ft) Maxwell flotation cell and then in an additional twelve 2.8 cu m (100 cu ft) cells. Combined flotation concentrates are reground to 9070 minus 37 microns (400 mesh) in a 1.8 m by 4.9 m (6 ft by 16 ft) ball mill in closed circuit with a single Krebs 254 mrn (10 in.) cyclone. Flotation tailings are sent to the tailings dam. Reground concentrates are then aerated with lime to a single Pachuca and thickened in a 16.75 m (55 ft) diameter thickener with the addition of diesel fuel to render any activated graphite inert to adsorption of

Jan 1, 1981

By J. Cayouette, C. Bolduc, P. Blatter

"The LaRonde mill was commissioned in 1988 and began treating ore from the Penna shaft in 2000. The mill has been expanded to accommodate 7,500 t/day, but ramped down to 6,000 t/day since the deep extension began. The process recovers gold, silver, and base metals. In 2008, the Goldex plant began trucking gold-pyrite concentrate to a treatment plant feeding pulp to the LaRonde mill, increasing gold output by 40,000 oz. In 2009, the high-grade Lapa ore processing facilities were annexed to the LaRonde plant, increasing gold output by 120,000 oz. This paper outlines the metallurgical considerations related to the treatment of different ore types.RÉSUMÉ Le concentrateur de la mine LaRonde a été mis en service en 1988 et a commencé à traiter le minerai du puits Penna en 2000. La capacité du concentrateur a augmenté afin de permettre le traitement de 7 500 tonnes de minerai par jour, capacité qui est retombée à 6 000 tonnes par jour (tpj) depuis le début de l’extension en profondeur de la mine. Ce procédé permet de récupérer de l’or, de l’argent et des métaux communs. En 2008, l’usine de traitement Goldex a commencé à transporter par camion du concentré de pyrite et d’or vers une usine de traitement alimentant en pulpe le concentrateur de LaRonde, augmentant ainsi la production d’or de 40 000 onces. En 2009, les installations de traitement du minerai à haute teneur de Lapa ont été annexées à l’usine de traitement de LaRonde, augmentant la production d’or de 120 000 onces. Cet article passe en revue les considérations métallurgiques liées au traitement de différents types de minerai."

Jan 1, 2017

By J. Cayouette, C. Bolduc, P. Blatter

"The LaRonde mill was commissioned in 1988 and began treating ore from the Penna shaft in 2000. The mill has been expanded to accommodate 7,500 t/day, but ramped down to 6,000 t/day since the deep extension began. The process recovers gold, silver, and base metals. In 2008, the Goldex plant began trucking gold-pyrite concentrate to a treatment plant feeding pulp to the LaRonde mill, increasing gold output by 40,000 oz. In 2009, the high-grade Lapa ore processing facilities were annexed to the LaRonde plant, increasing gold output by 120,000 oz. This paper outlines the metallurgical considerations related to the treatment of different ore types.RÉSUMÉ Le concentrateur de la mine LaRonde a été mis en service en 1988 et a commencé à traiter le minerai du puits Penna en 2000. La capacité du concentrateur a augmenté afin de permettre le traitement de 7 500 tonnes de minerai par jour, capacité qui est retombée à 6 000 tonnes par jour (tpj) depuis le début de l’extension en profondeur de la mine. Ce procédé permet de récupérer de l’or, de l’argent et des métaux communs. En 2008, l’usine de traitement Goldex a commencé à transporter par camion du concentré de pyrite et d’or vers une usine de traitement alimentant en pulpe le concentrateur de LaRonde, augmentant ainsi la production d’or de 40 000 onces. En 2009, les installations de traitement du minerai à haute teneur de Lapa ont été annexées à l’usine de traitement de LaRonde, augmentant la production d’or de 120 000 onces. Cet article passe en revue les considérations métallurgiques liées au traitement de différents types de minerai.INTRODUCTIONThe LaRonde metallurgical plant in the Abitibi region of Quebec, Canada, evolved into a mature milling site following expansions in 2000–2003, thanks to improved processes, manpower, and water treatment capabilities that better accommodate the complex constituents of the LaRonde ore. The ore requires a sequence of grinding, copper- lead and zinc flotation, and precious metals leaching, ending with a carbon-in-pulp (CIP) gold recovery. A portion (35%) of the tailings is sent back underground as paste backfill after being treated with the SO2-air cyanide destruction process. The tailings area has a dedicated cyanide destruction and metal precipitation area through which the used water passes before returning as recycled water. A biological water treatment plant was built in 2004 to address water toxicity in the final effluent. The water toxicity was the result of the high sulfide content of the LaRonde ore (from thiocyanate or stable cyanide species buildup) and the use of 90% recirculated water in the mill. The water treatment plant uses bacteria to transform thiocyanate into nitrates and precipitate phosphorus from the water before it is discharged into the environment."

Jan 1, 2017

By Jean Robitaille

La découverte du gisement du puits Penna a nécessité une révision complète de tous les circuits du concentrateur Laronde pour permettre, premièrement, l?adaptation du procédé à la nouvelle minéralogie et deuxièmement, l'accroissement du tonnage de 1800* à 4500 t/j. Aux circuits existants de broyage, de flottation du cuivre, de cyanuration et du charbon en pulpe, les circuits suivants furent greffés : broyage semi-autogène, flottation du zinc, manutention des concentrés (épaississage, filtration, entreposage et chargement automatisé), décantation à contrecourant et précipitation au zinc, destruction des cyanures et remblai en pâte. Cet article se veut une revue des différentes étapes du projet d'agrandissement du concentrateur qui se sont effectuées par phases progressives de 1997 à 2000. De plus, une description des nouvelles technologies sélectionnées et implantées est présentée.

May 1, 2001

By J. Cayouette, . Blatter, P. Cousin

The Laronde mill was commissioned in 1988 and has been treating the Laronde Perim ore since 2000. The Laronde plant, situated in the Abitibi region of Quebec, has experienced mill expansions to accommodate 7500 mtpd and to recover gold and silver as well as important amounts of base metals (Cu, Zn, Pb). Ten sequential metallurgical and environmental processes are responsible for metals recovery and process viability. Over 200,000 ounces of gold, 4,5 million ounces of silver, 7000 tonnes of copper, and 78,000 tonnes of zinc are produced annually. In 2008, the Goldex plant began trucking high wade (35-45 Wt Au) pyrite sulphide concentrate (TCGO) for gold extraction at a newly constructed treatment plant, increasing gold output at Laronde by 40,000 ounces. In 2009, the high gold wade Lapa ore processing facilities were annexed to the Laronde plant increasing output by 120,000 ounces of gold. TCGO and Lapa productions are forecasted until 2018 and 2015 respectively, with known reserves of each mine. Today, up to 140 permanent employees run and optimise the Laronde plant operation. As a result, Laronde has intricacies intrinsic to a large and varied operation. The paper will outline the metallurgical highlights, challenges, and future outlook related to the treatment of each ore type (Laronde, TCGO, and Lapa)

Jan 1, 2011

By Jean Cayouette, Paul Blatter, Paul Cousin

"The Laronde mill was commissioned in 1988 and has been treating the Laronde Penna ore since 2000. The Laronde plant, situated in the Abitibi region of Quebec, has experienced mill expansions to accommodate 7500 mtpd and to recover gold and silver as well as important amounts of base metals (Cu, Zn, Pb). Ten sequential metallurgical and environmental processes are responsible for metals recovery and process viability. Over 200,000 ounces of gold, 4,5 million ounces of silver, 7000 tonnes of copper, and 78,000 tonnes of zinc are produced annually.In 2008, the Goldex plant began trucking high grade (35-45 g/t Au) pyrite sulphide concentrate (TCGO) for gold extraction at a newly constructed treatment plant, increasing gold output at Laronde by 40,000 ounces. In 2009, the high gold grade Lapa ore processing facilities were annexed to the Laronde plant increasing output by 120,000 ounces of gold. TCGO and Lapa productions are forecasted until 2018 and 2015 respectively, with known reserves of each mine.Today, up to 140 permanent employees run and optimise the Laronde plant operation. As a result, Laronde has intricacies intrinsic to a large and varied operation. The paper will outline the metallurgical highlights, challenges, and future outlook related to the treatment of each ore type (Laronde, TCGO, and Lapa).INTRODUCTIONFollowing the 2000 to 2003 expansions, the Laronde plant evolved into a mature milling complex with developed processing, man power, and water treatment capabilities able to accommodate the complex Laronde ore. The ore requires a series of grinding, copper/lead flotation and separation, zinc flotation, zinc tails precious metals leaching, followed by a counter-current decantation circuit and Merrill Crowe precipitation. A paste backfill and SO2-air cyanide destruction operate intermittently. The tailings area has a dedicated cyanide destruction and metals precipitation plant prior to water recycling to the mill. A biological water treatment plant was put into service in 2004 to address the build-up of thiocyanate in the tailings ponds at Laronde. This was the result of the high sulphide content of the Laronde ore and 90% recirculation of the process water. The plant uses bacteria to oxidize and destroy thiocyanate, and removes phosphate from the water before it is released to the environment."

Jan 1, 2011

By John Mair

The Ilimaussaq Intrusive Complex in south Greenland is a layered alkaline igneous body that is predominantly comprised of agpaitic nepheline syenites. The Complex is now recognized as containing vast resources of uranium in polymetallic ores that are also strongly enriched in rare earth elements (REEs) and zinc. Uranium and REEs are dominantly hosted in phosphate minerals with a minor proportion hosted in zirconium silicate minerals. Equivalent ores are yet to be mined for uranium anywhere in the world; however, studies are well advanced in confirming a process route to economically extract uranium. The Ilimaussaq Complex is considered the world?s type-locality for agpaitic rocks. Formation of the complex is attributed to four successive pulses of magma. The first produced an augite syenite, which now forms a marginal shell. This was followed by intrusion of a sheet of peralkaline granite. The third and fourth stages make up the bulk of the intrusion and are peralkaline to hyper-agpaitic in composition. The third batch of magma differentiated to produce pulaskite, foyaite and naujaite. Stage four produced the kakortokites and lujavrites, which are the units of particular economic significance. Kakortokites are strongly enriched in zirconium, niobium and tantalum, whereas the lujavrites are strongly enriched in uranium, rare earth elements, fluorine and zinc. Lujavrites are vertically zoned with arfvedonsite (black) lujavrites grading downward into aegerine (green) lujavrites. The upper most portions of the black lujavrites contain uranium concentrations of greater than 450 ppm, which decreases toward green lujavrites where uranium concentrations rarely exceeds 200 ppm. Resources defined to date in accordance with the Australian JORC code include 282 M lbs of uranium oxide at a grade of 280 ppm. With scope for several other similar sized resources within complex, the overall potential resource is of immense global significance. Metallurgical studies to date indicate that uranium can be successfully extracted from black lujavrites via an alkaline pressure leach method. This involves selectively leaching uranium with solutions containing carbonate and bicarbonate at elevated temperature and pressure. Uranium can then be recovered by hydrogen reduction to create a uranium oxide product. There is also scope to beneficiate ores as uranium and REE?s are hosted in specific mineral groups. Phosphate minerals can be effectively concentrated by froth floatation and uranium-bearing silicate minerals can be concentrated by gravitational methods. Studies indicate that REEs can be extracted from the residue following the alkaline leach process by a dilute hydrochloric acid wash, with REEs then precipitated in the form of a REE concentrate.

Aug 1, 2010

Introduction Agrico Mining Co.'s Florida mining division has three surface mines and employs nearly 700 workers. The division produces some 6.3 Mt (7 million st) of phosphate rock annually. It is a good business. And Agrico has made it better by making it safer through a new approach to mine safety. In one year, Agrico - the second largest phosphate mining company in the US - recorded a stretch of one million manhours without an accident. That same year, the direct cost of accidents dropped to $9137 from a previous five-year average of about $50,000. Together with Don Roe, division manager of safety and security, Division General Manager Don Morrow made 1981 a watershed year for safety at Agrico. Morrow called on consultants from Safety Management Services of Du Pont's Specialty Services division to strengthen a safety program that was already better than average. From the late 1970s and into 1981, lost-workday cases (LWCs) were costing Agrico an estimated average of $22,000 each. And they were occurring with alarming frequency. In 1977, the company recorded six LWCs at an incidence rate of 0.64. This was followed by a jump to nine cases in 1978. In 1979, both occurrences and the rate increased - 10 LWCs at a 1.19 rate. The number of LWCs decreased to seven in 1980, with a rate of 0.71. Agrico instituted a far-reaching safety program in 1981, which began to take full effect in 1982. LWCs dropped from five in 1981, to three in 1982. And the direct cost plummeted from $110,346 to $28,828. In 1983, the mines recorded only one LWC. Its $9137 cost represented a reduction of $101,209 since the Safety Management Services of Du Pont had been called in. Through early 1984, the LWC incidence rate at the facility's three mines, phosphate drying plant, and transportation department was down to 0.26. This is 84% lower than the 1982 mining industry average, making it the safety leader among all Agrico companies, including its chemical plants. New Approach Agrico had the basics of a safety program in place when the Du Pont consultants arrived. But Du Pont suggested changes in responsibilities and company philosophy that formed the foundation of

Jan 1, 1985

By Steven A. Savage

Agrico Chemical Company, as we presently know it, is the result of the coming together of several different fertilizer operations. The Williams Companies, our parent organization, first entered the fertilizer business in 1971, when it acquired the fertilizer operations of the Gulf Oil Company. This gave us, among other things, the manufacturing facility at Donaldsonville, Louisiana. In 1972, The Williams Companies acquired Agrico Chemical Company from Continental Oil Company, bringing in a manufacturing facility and phosphate mines at Pierce Florida. Our Florida Mines are in the region commonly known as the Bone Valley Region of Florida. The majority of the phosphate fertilizer produced in the United States utilizes rock mined in this region. The Donaldsonville Plant was originally built in 1967-68 on the site of the old Faustina Plantation at an approximate cost of $80,000,000. (This plant is commonly referred to as our Faustina Plant.) Until such time as Agrico was acquired from Continental Oil, the Donaldsonville Facility was solely used to upgrade phosphoric acid into finished granular products.

Jan 1, 1986

By B. C. Darst

Developments in the agricultural use of potassium (K) have been based solely on the essential role K plays in crop production. Crop plants cannot complete their normal life cycle if K is deficient or absent. In fact, no essential plant nutrient other than nitrogen is required in greater quantities. Table 1 shows the amounts of K some crops take up from the soil. Although the exact functions of K in the plant are not well known, its primary role seems to be tied to plant metabolism. Potassium is vital to the process of photosynthesis. When K is deficient, photosynthesis declines, but respiration increases. These two K-deficient conditions. . . reduced photosynthesis and increased respiration ... lower the plant's carbohydrate supply, the end result being poor agronomic crop production. Potassium is also essential to several other plant functions, including the following: 1) Protein synthesis. 2) Water use efficiency, through the influence of K on stomata opening and closing, to maintain the turgidity in plant leaf cells. 3) Translocation of heavy metals such as iron and zinc. 4) Ionic balance. 5) Control of enzyme reactions within plants.

Jan 1, 1985