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By Walter H. Bruckner, George B. Clark

SINCE the end of World War II interest has been increasing in the use of shaped charges in the mining industry and in other industries using explosives for blasting purposes. Shaped charges employ the principle known as the "Munroe effect," which was discovered by Charles E. Munroe more than 50 years ago (in 1888). Details of their design have been explained e1sewhere.l,2,3 Fig I shows the essential features of design of two types of shaped charges (with conical and hemispherical cavities) and a schematic sketch of their action upon detonation. The following discussion deals with the behavior of the metal in the cavity liners when they are subjected to intense pressures exerted when the explosive charge is detonated. Among the conclusions reached in research on shaped explosive charges, the following have been established concerning cavity liners: 1,2 I. The optimum wall thickness of a conical cavity liner is dependent upon the apex angle of the cone as well as on the base diameter of the charge. Acute apex angles require thinner walls for optimum performance and more obtuse angles require thicker walls for the same base diameter. 2. Cones were more effective in forming a penetrating jet when the walls were tapered; i.e., the thickness of the wall of the cone increased from the apex down. 3. The physical and mechanical proper- ties of metals have a marked effect upon their performance as cavity-liner material. Boiling point, ductility, malleability, tensile strength, and hardness are among the properties that influence the effectiveness of a metal used as a cavity liner. Lead, for example, makes a wide, flat crater in steel plates. Aluminum makes a deeper crater than lead, and an aluminum alloy having a high tensile strength makes a deeper hole, but slightly smaller in diameter. Cast iron makes a deep, narrow hole. These findings, together with the following analysis under Metallographic Survey of Slug, offer solutions to many of the problems involved in solving the mechanism of the formation of Munroe jets. It has been fairly well established that cavity liners collapse in a manner similar to that indicated in Fig 2. Conical liners are known to collapse upon themselves while hemispherical liners are believed to turn inside out in the process of jet formation. The first has been definitely proved by recovery of collapsed portions of cones, while liners from partly detonated charges show that hemispheres may turn inside out. Fig 3 shows a sketch of a recovered slug from a 6-in. shaped charge using a 45° cone made of cast iron. (This size of charge drilled holes up to 3 ft in depth in solid granodiorite.)

Jan 1, 1947

By Shiou-Chuan Sun, R. F. Wesner, J. D. Morgan

A new apparatus termed a "distribution analyzer" is introduced to ascertain the optimum conditions of electrostatic separation of minerals. It was found that with similar surface condition, testing environment and a constant feed rate of not higher than one layer of particles fed on the grounded roll of the separator, the behavior of each component mineral in a synthetic mixture or ore is roughly similar to that of the same mineral when tested alone.

Jan 3, 1950

By O&apos, M. W. Neill

Mini-piles have been found to be a practical, technically correct remedial underpinning method. They can be constructed in limited access areas with very little disruption. Experience indicated that mini-piles installed using a down-the-hole soil displacement hammer would be particularly effective in the "bottomless" Beaumont Clay formations in the Houston, Texas, U.S.A. area. The University of Houston Foundation Testing Facility was ideally suited to perform tests on mini-piles. The availability of extensive geotechnical data and previous pile test results was invaluable in evaluating the mini-pile test data. As expected, the mini-pile test results were consistant with test results from large sized driven piles in the same soil formation.

Jan 1, 1989

By Kato T, Eguchi M, Seino T, Itagaki K, Kimura T, Muto T, Shimizu T, Kobayashi T

Behaviour of minor elements in the dust collecting system connected with fluidized bed roaster for zinc concentrate was investigated by use of the bench scale experimental appara- tus. The dust collecting system was consisting of two dust chambers, hot electrostatic precip- itator, washing tower, mist electrostatic pre- cipitator, drying tower, absorption towers and potassium permanganate solution towers. Some volatile elements such as lead, cadmium and arsenic tend to concentrate in the fine calcine obtained in hot electrostatic precipitator especially in the case of the roasting with insufficient air supply. Special attention was paid to behaviour of mercury. In the roasting tests for plain zinc concentrate, it was considered that most mercury volatilizes at first as elemental vapour in the roaster, but with decrease in temperature of gas around a half of mercury forms compound, and both elemen- tal and compound forms of mercury were found in the gas stream. Elemental mercury is of course difficult to be trapped in the dust collecting system. To promote the compound formations, some additives for concentrate, such as selenium and halogens were effective, especially selenium of a few times equivalent to form HgSe repre- sented complete conversion of mercury from elemental to compound. To clarify the behaviour and removal mech- anism of mercury, various small scale laboratory tests were also carried out. It was confirmed that mercury sulfate formation is possible if temperature and flow rate are adjusted adequate- ly for gas stream consisting of 02-SO2-N2. To trap elemental mercury, various substances were tested, and excellent results were obtained with selenium. Satisfactory results were obtained with a selenium disc heated at 100 to 200¦C in a mercury containing gas stream. Also, applica- bility of scrubbing method with SeO2 solution was investigated, and the solution containing a few hundred ppm SeO2, 0.01 per cent additive and 6 per cent H2SO4 proved to be satisfactory.

Jan 1, 1980

By Henry J. Miller, Marcella Lindeman

DURING some experiments made by Henry J. Miller, partly in Germany and partly in the United States, in which it was found necessary to melt metals in quantities up to 60 kg. in a vacuum or under low pressures of hydrogen, molybdenum was tried as the resistor in the electric melting furnaces. Molybdenum ribbons 16 by 0.55 mm. and 18 by 0.45 mm. were used as resistors. The furnaces were of the type shown in Fig. 1. [ ] About the heating tube, Y, are wound parallel resistors of molybdenum ribbon from the water-cooled electrodes, E1, E2. The whole is within a copper container having outlets for the removal or introduction of gases and a window, W, for observation, the space about the heating tube and electrodes being filled with insulating material. The life of the molybdenum used as the resistor was found to depend very much on the manner of using it, its failure being due in some cases to thinning by evaporation or chemical reaction and in others to hardening, which prevented it from following the expansions and shrink¬ing of the heating tubing without cracking. As such failures are often rather expensive in commercial work, it was thought worth while to determine the causes. The factors influencing the behavior of molybdenum resistors used in this manner may be briefly stated as follows:

Jan 1, 1928

By John A. Hansuld

Molybdenum presents a series of baffling geo- chemical puzzles. It can exist in six different valence states, possessing three different coordination numbers. As a result, it combines with other elements to form a wide variety of negatively and positively charged ions and complexes whose exact chemical nature are relatively unknown. Its rather complex chemistry might be described as "ambidextrous, bi-sexual and polygamous". It is little wonder then that the geochemistry of molybdenum is relatively unknown, and compared to most common metals its geochemical behavior is somewhat unique. The behavior of a particular element or metal, such as molybdenum, in a given dispersion media is largely controlled by the stability relations among its various oxidation products. Recognition of these products and an understanding of their stability relations is therefore a prerequisite to a proper understanding of its observed behavior. Because most secondary dispersion media represent aqueous chemical systems, stability relations are best expressed as functions of Eh and pH.

Jan 12, 1966

By Lassi Klemettinen

For better understanding and maximal value utilization of the WEEE smelting process, the behavior and distribution of different trace elements must be known. In this study, the behavior of nickel as a trace element was studied in an equilibrium system with metallic copper—spinel saturated iron silicate slag (with 3 wt-% K2O)—iron aluminous spinel—gas. The experiments were conducted in alumina crucibles at 1300 °C, in oxygen pressure range of 10−10–10−5 atm. A time series of 15–60 min experiments was also conducted for investigating the formation rate of the primary spinel phase in the system. The results show that the distribution coefficient of nickel between metallic copper and liquid slag changes from approximately 70 to 0.4 along the increasing oxygen pressure range. In addition, a significant part of the nickel deports into the spinel phase. The spinel formation was investigated based on composition analysis results and visual observations from SEM-images.

By James Rowland, Marcia Harris, Richard Mainiero, Michael Sapko

All explosive materials produce a cloud of reaction products, the most toxic of which is nitrogen dioxide (NO2). In the study reported here, 4.5-kg (10-lb) charges of blasting agent confined in either thin-wall 10-cm (4-in) diameter galvanized pipe or 10-cm (4-in) schedule 80 seamless steel pipe were detonated in a closed chamber. The detonation gases were analyzed for NO2, nitric oxide (NO), ammonia (NH3), hydrogen (H2), carbon monoxide (CO), carbon dioxide (CO2), nitrogen (N2), oxygen (O2), and methane (CH4). Data were evaluated to determine the kinetics of the oxidation of NO to NO2. Analysis revealed that the only mechanism for NO loss for the conditions existing in the chamber was the reaction 2NO + O2 6 2 NO2. The rate constant was 2.08 ?? 10-38 cm6 molecules-2 sec-1 for the rate equation -??d [NO]/dt = K ?? [NO]2 ?? [O2] for NO concentrations up to 100 ppm. The rate constant is in agreement with that recommended by Baulch, Drysdale, and Horne (1973).

Jan 1, 2006

By Richard J. Mainiero, Michael J. Sapko, James H. Rowland III, Marcia L. Harris

All explosive materials produce a cloud of reaction products, the most toxic of which is nitrogen dioxide (NO2). In the study reported here, 4.5-kg (10-lb) charges of blasting agent confined in either thin-wall 10-cm (4-in) diameter galvanized pipe or 10-cm (4-in) schedule 80 seamless steel pipe were detonated in a closed chamber. The detonation gases were analyzed for NO2, nitric oxide (NO), ammonia (NH3), hydrogen (H2), carbon monoxide (CO), carbon dioxide (CO2), nitrogen (N2), oxygen (O2), and methane (CH4). Data were evaluated to determine the kinetics of the oxidation of NO to NO2. Analysis revealed that the only mechanism for NO loss for the conditions existing in the chamber was the reaction 2NO + O2 6 2 NO2. The rate constant was 2.08 @ 10-38 cm6 molecules-2 sec-1 for the rate equation -½d [NO]/dt = K @ [NO]2 @ [O2] for NO concentrations up to 100 ppm. The rate constant is in agreement with that recommended by Baulch, Drysdale, and Horne (1973).

By D. E. Larson

In cooperation with the National Institute of Environmental Health Science and the National Institute for Occupational Safety and Health the U.S. Bureau of Mines conducted grinding research on non-asbestiform tremolite. The goal of this effort was to prepare ground tremolite samples containing a considerable percentage of acicular grains with aspect ratios (approximately = 8um long with widths = 1 um) similar to those of asbestos particles suspected of causing cancer, Optical-and electron-microscopic examinations were used to monitor the size and shape of the grains in the ground products. Although customized milling techniques do have noticeable effects in producing acicular grains, the prismatic nature of fracturing in the non-asbestiform tremolites limited the number of acicular grains that could be purposely produced, and indicates that the likelihood of high concentrations of acicular particles occurring under normal mining and milling conditions is small.

Jan 1, 1991

By Zhitao Ma

The Cast-in-place Concrete thin-wall Pipe pile, referred to as PCC pile, is a new kind of pile for soft ground improvement. In this paper, firstly, the general introductions of the new pile technique, mainly including the technique principle, the structure of pile-driving machine, and the technological process were given, then based on the results of in-situ static lateral loading test, the pile lateral capacity, the relationship of load-deflection of pile at the ground surface, the lateral deflections versus depth and the soil reaction along the pile shaft were analyzed.

Jan 1, 2006

By Yuanbo Zhang, Mingjun Rao, Guanghui Li, Chongzhong Ouyang, Shuhui Zhang

Oolitic hematite ore with high-phosphorus content is currently recognized as one of the most refractory iron ore resources in the world. The high-phosphorus content and unique structure of the oolitic hematite ore make it difficult to be beneficiated. The process of direct reduction followed by magnetic separation has significance to the utilization of oolitic hematite ore, and sodium salts can improve the dephosphorization. However, the behavior of phosphorus during reduction roasting, and the intensified dephosphorization mechanism of sodium salts are not clear. In this study, by using chemical analysis, chemical phase analysis, XRD analysis, optical microscopy, and scanning electron microscopy analyses, the behavior of phosphorus during reduction roasting of high-phosphorus content oolitic hematite ore and the effect of sodium salts on behavior of phosphorus were studied.

Jan 1, 2015

By Hajialilue Bonab M.

The soil-pile interaction under lateral impact loads is not yet completely well known. Many tests on single piles under static lateral loads in centrifuge have been performed and P-y curves have been determined at different levels of the pile in soil. Following these static tests on piles, a large program is undertaken with the same piles submitted to impact loads. The pile equipped with various pile caps has been impacted under variable amplitudes of shock. The behavior of the pile under different impacts was studied and dynamic parameters of the soil-pile system have been determined. Many cases of loading constituting various load histories have been analyzed. They are resulting from parametric centrifuge tests run out, on the one hand with constant and cumulative impacts and on the other hand, variable and cumulative ones. The Influence of each type of loading was studied. Using a finite element method, a non-linear pile-soil system was conceived and a transient dynamic analysis have been performed. The results of the non-linear analysis and experimental data were compared giving a good agreement.

Jan 1, 2002

By Mohamed A. Sakr

An experimental study on the behavior of pile group's arrangement under lateral load was carried out in the level ground and at crest of sand slope 3H: 2V. Tests were conducted on single pile and pile groups with center-to-center pile spacing of 3D. The model piles were founded in sand with relative density 25%. Several configurations of pile groups were used to study the effect of piles arrangement in the group (series or parallel) with respect to slope crest. The behavior of the pile groups in the level ground was compared with the behavior of pile groups at different configurations at the slope crest. Based on the test results, the behavior of laterally loaded pile groups adjacent to a slope crest depends largely on piles arrangement in the group with respect to direction of the lateral load. Pile groups in the level ground have more resistance to lateral loads when they are arranged in a parallel configuration than in a series, whereas the reverse is true in cases of pile groups constructed near to the edge of a slope. It is advisable to use the pile group in series arrangement for groups constructed at slope crest to minimize the effect of the ground slope on lateral capacity of piles and the occurred deflection and maximum bending moment of the lead row in the group.

Jan 1, 2010

By Renato P. Cunha

The paper explores a parametric analysis of a four-pile group in contact (hence piled raft) and without contact (hence standard pile group) with the superficial soil layer, under a combined set of loadings (moment M, vertical V and horizontal H forces). The major design parameters of interest, as total and differential settlements, and raft bending moments and shear stresses are assessed under aforementioned distinct conditions. The slenderness ratio of the piles is also varied along the analyses, allowing the establishment of its influence on the derived parameters.

Jan 1, 2006

By Merete Tangstad, Fei Li

This paper studies the quartz and carbon black pellets at elevated temperature with varying temperature and gas atmosphere. High-purity quartz and commercial ultra-pure carbon black was mixed (carbon content wt.15%), and then pelletized into particles of 1-3mm in diameter. The stoichiometric analysis of the pellet during heating is studied in thermogravimetric analysis (TGA) furnace at different temperature in CO and Ar atmosphere. The microstructure, phase changes and element content of sample before/after heating is characterized by X-ray diffraction, scanning electron microscope, X-ray fluorescence and LECO analyzer. The reaction process can be divided into two stages. Higher temperature and argon atmosphere are the positive parameters for SiC formation.

Jan 1, 2016

By J. A. Finch, G. Labonté

The behavior of four different redox sensing electrodes (gold spiral, black platinum, chalcopyrite, and galena) during roughing and cleaning flotation is examined and related to the flotation response. The results indicate that the solution potential (as sensed by the black platinum electrode) is different from that of the pulp potential (gold spiral) and is only weakly related to the flotation response. On the other hand, the potentials exhibited by the gold spiral and the two mineral electrodes are related to the flotation response. The transient responses of the gold and mineral electrodes during the addition of flotation modifiers could indicate the conditioning time required to achieve flotation or depression of selected minerals.

Jan 1, 1991

By G. Labonte

The behavior of four different redox sensing electrodes (gold spiral, black platinum, chalcopyrite, and galena) during roughing and cleaning flotation is examined and related to the flotation response. Although it is difficult to provide unequivocal interpretations of the different potentials measured, the results indicate that the solution potential (as sensed by the black platinum electrode) is different from that of the pulp potential (gold spiral) and is only weakly related to the flotation response. On the other hand, the potentials exhibited by the gold spiral and the two mineral electrodes are related to the floatation response. The gold and mineral electrodes exhibit different transcient responses during the addition of flotation modifiers (e.g. NaCN, SO2). These responses appear to be related to the reactivity of the minerals and could indicate the conditioning time required to achieve flotation or depression of selected minerals.

Jan 1, 1989

By Kent A. Pease

Design methods for foundation anchors and sockets constructed in rock are based largely on empirical correlations which yield a reasonable estimate for initial capacity, but do not address the general concerns of failure mode and load-displacement behavior. This paper focuses on the behavior of foundation-rock interfaces and shows that interface behavior under increasing load results in a progression from an elastic response to secondary behavior, in which interface failure occurs, and finally to a residual stage at large deformations. Procedures to follow this progression are outlined to provide a more fundamental understanding of the problem.

Jan 1, 1984

By Marwa Nabil, Alaa A. Ata

"Recent developments in the analysis of piled rafts has incorporated the load sharing of the raft and the piles to support the superstructure. In the piled-raft system, piles are cast monolithically with the raft and the load is partly transmitted by the raft to the soil directly below it, and partly by the piles to more competent deep soil. While these piles are effective in increasing the bearing capacity and reducing the settlements, they often lead to significant straining actions at the pile head-raft connection which may constitute the weakest link. An attempt to provide a more economical solution, that at the same time overcomes this weak link, is to disconnect the pile heads from the raft and introduce an intermediate cushion of compacted fill. In this case, the piles are considered as reinforcement to the subsoil and will also act as settlement reducers. This paper investigates the load transfers mechanism of the unconnected piled raft with cushion using ABAQUS finite elements Program. The main objective is to provide an in depth analysis of the raft–soil–pile interactions in multi-layered soil under static and seismic loads. The investigated system provides an economical alternative for traditional connected piled raft foundation, where there is no need to reinforce the piles, no need for pile head demolition or expensive waterproofing of the pile head connection. Cost analyses of unconnected versus connected piled raft systems confirmed a cost savings in the construction that may reach from 50 to 70 percent.INTRODUCTIONDesigners around the world have gained more confidence to use the piled-raft as a more realistic system where the raft and the piles share transferring the superstructure loads to shallow and deep soil layers. A further advancement is to use unconnected piled rafts as another practical and economical alternative to the traditional piled rafts. Unconnected piled raft is also synonymous to settlement reducing piles; or simply, soil improvement piles. Liang et al. (2003) has extended the concept of pile-raft-foundation to a new type of foundation called composite piled raft foundation or unconnected piled raft foundation. The foundation is composed of a sand/gravel cushion sandwiched between the raft and piles. The piles group may contain short and long piles. The short piles are constructed of flexible materials such as soil-cement columns or sand-gravel columns, and are used mainly to improve the bearing capacity of shallow soft soil; the long piles, which are made of relatively rigid materials such as concrete, and their main function is to reduce settlements. The cushion plays an important role in mobilizing the bearing capacity of the subsoil and in modifying the load transfer mechanism of the piles. In Shanghai, China, this system of unconnected piled raft has proved to be quite suitable and effective in coastal areas, where deep soft soil deposits exist."

Jan 1, 2016