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By M. J. Gula, S. S. Xue, E. P. Horwitz, J. T. Harvey

A study has been conducted to control iron in copper electrolyte streams using Eichrom Industries’s new Monophosphonic /sulphonic acid resin. The resin strongly and selectively extracts ferric ion over copper and cobalt from highly acidic copper electrolytes. The resin has a loading capacity of 27 g/L of iron and can be readily regenerated. In addition, the new resin can be easily synthesized using commercially available starting materials. This paper presents the experimental results for iron control in copper electrolyte streams using the new resin and discusses its potential applications to other hydro-metallurgical streams.

Jan 1, 2000

By S. Shairp

The first commercial application of the Dynatec two-stage zinc pressure leach process commenced operation at the metallurgical complex of Hudson Bay Mining and Smelting Co., Limited in Flin Flon, Manitoba in 1993. A key feature of the successful leaching operation is the presence of iron in solution, which facilitates oxygen transfer in the autoclaves and enables rapid oxidation of zinc sulphide minerals. At the same time, the solution from which zinc is recovered must be essentially iron free. Precipitation of iron from the solution starts in the autoclaves and is completed in subsequent atmospheric purification steps. Conveniently, these iron precipitation steps also remove nuisance elements such as arsenic and fluoride from the solution, while producing solids with good liquid-solid separation characteristics. This paper provides an overview of the current operations in Flin Flon, with particular reference to the behaviour and deportment of iron throughout the zinc plant.

Jan 1, 2006

By M. H. Pettibone

During the past decade, the size of grin- ding mills has steadily increased. Mills 11 m in diameter with 9 mW motors have been installed with even larger units on the drawing board. The rising costs of energy and labor have spurred interest in improving efficiency while reducing capital investment and operating labor. Autogenous and semiautogenous grinding have experienced renewed interest as efforts to reduce operating and capital costs have increased.

Jan 1, 1981

By Nozomu Hasegawa

The phase diagrams and microstructures of the slags in the Mitsubishi Continuous Copper Smelting and Converting Process were studied for the prevention of the magnetite troubles such as accretion build-up on furnace hearths and launders, blockages at the melt outlet, slag viscosity increases and so on. According to the results of those studies, the silica and lime contents in the silicate slag at the smelting furnace, and the lime content in the lime-ferrite slag at the converting furnace were changed, resulting in lower and more consistent copper levels in the discard slag, with much less need for operators to clean melt outlets and launders. However, these changes may decrease the desirable amount of accretion-coating inside the furnaces and thereby reduce furnace campaign lives. Therefore, a method of estimating the magnetite level in the melts was developed, and slag compositions and temperatures have been controlled within the appropriate ranges to prolong furnace lives and also prevent magnetite troubles.

Jan 1, 2003

By Pengfu Tan

Converter slag chemistry control has played an important role in optimizing converter operations. A thermodynamic model of copper P-S converter has been developed to predict the behavior of magnetite in the converter slag. Predictions of bath temperature, slag and matte compositions, and magnetite content in the slag have been validated by industrial data. The effects of fluxing strategy, returns and skim charges, oxygen enrichment, and temperature on the magnetite formation in the slag have been predicted and discussed. Some improvements of the industrial operations have been presented.

Jan 1, 2005

By Bratt G. C

When zinc is electrowon from concentrates or residues of high manganese content, the zinc sulphate electrolyte may contain high levels of manganese. The manganese level is usually controlled by removal of manganese at the anode as the dioxide during the zinc electrodeposition stage.By increasing the temperature of an electrolyte containing 8 gll manganese from 35°C to 90°C, decreasing the acidity from 100 gll to 30 gll, reducing the current density from 432.A.m-2 t6 286 A.m-2 and using new lead anodes containing over 0·75 per cent silver, the current efficiency for manganese dioxide removal was .increased from less than 1 per cent to over 20 per cent.At the same time the current efficiency for zinc deposition was maintained above 90 per cent by additions of high molecular weight cationic polyacrylamides to the cell. By utilization of these conditions in a small number of cells, the manganese level in the circuit could be economically concrolled to any desired level.With these conditions the formation of the dioxide changes from an indirect route, via Mn04-, to a direct oxidation of Mn2+ to Mn02.The incorporation of impurities such as Pb, K, NH4, Cu, Ni, or Fe makes the deposit unsatisfactory for direct use in Zn - Mn02 dry cells. The deposit structure changes from cryptomelane at low temperature to y3-Mn02 at high temperature.

Jan 1, 1975

By T. C. Murray

An automatic control system was recently installed to insure the continuity of operation between the ship docking and ore handling facilities and the computerized conveyor-fed sintering plants and blast furnaces. Although the basic concept for material handling has not changed, many innovations including computer control have been implemented.

Jan 1, 1978

By Fred N. Kissell

In This Chapter [Ventilation and methane sampling guidelines for conventional shafts Dealing with restricted spaces where methane can accumulate Ventilation and methane sampling at raise bore drills and Filling shafts at closed coal mines] It is not unusual to encounter methane gas during shaft excavation or shaft-filling operations. Shafts into coalbeds usually produce the most methane, so the information in this chapter applies primarily to shafts at coal mines. Nevertheless, much of the information is relevant for noncoal mines that have methane in the mine or in the overlying strata. METHANE IN SHAFTS EXCAVATED BY CONVENTIONAL MEANS (DRILL, BLAST, MUCK) [ ] Ventilation. Shafts excavated by conventional means are ventilated with a fan on the surface connected to ductwork that extends down into the shaft (Figure 9–1). Shafts into coalbeds should have ventilation systems designed to handle the higher gas flows to be expected as the shaft excavation passes through any over-lying gas-containing strata and nears the coal-bed to be mined. Following are some simple ventilation guidelines for the minimum amount of air required and the selection of the ventilation duct: • Provide enough air to meet the mini-mum OSHA tunnel requirement of 30 ft/min air velocity in the open shaft, as specified in 29 CFR2 1926.800(k)(3). For example, a 20-ft-diam shaft having

Jan 6, 2006

By Fred N. Kissell

In This Chapter [Measuring the gas emission from the coal Methane at the top of the silo Methane at the load-out area and Actions taken after a silo explosion] Methane accumulations in coal silos have resulted in the occasional silo explosion. These can be quite violent and dangerous because coal dust adds to the strength of the blast. However, with the appropriate precautionary measures, methane accumulations in silos can be greatly reduced. Mine Safety and Health Administration (MSHA) regulations at 30 CFR2 77.201 require that the methane content in the air of any coal silo be maintained below 1.0 vol %.3 Also, MSHA requires that methane tests be conducted before any electrical equipment is energized, unless a continuous monitor capable of deenergizing the electrical equipment is used.4 Measuring the gas emission from the coal. The first necessary step in dealing with silo methane issues is to measure the gas emission from the coal going into the silo. Such measure-ments allow one to estimate the silo ventilation needs and permit a comparison with the methane controls used at other mines that have similar gas levels. The gassiness of the coal can be measured by taking conveyor belt grab samples.5 Matta et al. [1978] measured the gas emission from conveyor belt grab samples using a simple desorption test. To conduct the test, they collected several grab samples of coal, weighing a few pounds each, from the conveyor belt entering the silo.6 They then sealed the coal into an airtight sample container that was equipped with a valve and short hose along with a pressure gauge. Every few hours they opened the valve and bled the emitted gas into a water-filled graduated cylinder that had been inverted and placed in a pan of water (Figure 11–1). The results are shown in Figure 11–2.

Jan 6, 2006

By Edward Ernst, Richard Runvik

AT the U. S. Gypsum Co. mine in Oakfield, N. Y., a flat-lying vein of rock gypsum is mined by the room and pillar method. Averaging only 4 ft thick, this vein is 1200 to 6000 ft in mineable width and many miles in length. Overlying the vein throughout the mine is a 2-ft thickness of distintegrated gypseous shale and fractured limestone which parts easily, falling with little or no warning. This shale, known as ash, varies in thickness from less than an inch to more than a foot. Small veinlets of selenite cut this shaley material, which breaks around timber props. The 18-in. limestone over-lying the ash is fractured vertically into blocks of varying size and will fail if any but the shortest unsupported spans are permitted. Above these two members is a thick layer of competent limestone.

Jan 6, 1957

By D. W. Evans

Mine subsidence problems due to coal extraction have occurred in a number of areas throughout the United States. Depending on the local geology, the depth of the mined seam, the type of mining method employed for extraction, and other related factors, subsidence can result in anywhere from slight displacements to a total loss of ground. These conditions can have serious consequences on the health and safety of the people living above the mined areas. A number of methods exist to provide support for the ground overlying mines. All of these methods employ some mechanism for providing additional support to either the roof of the mine or the sides of the pillars. Since failure usually occurs due to overburden stresses which are transmitted to the roof and pillars, these methods employ techniques to counteract stresses induced due to the coal extraction. The applicability of any particular method will depend on the availability of backfill material, the areal extent of the affected area, and of course, the cost. The primary use of coal ash for subsidence control has been as a backfill material for the stabilization of large areas. Large scale backfilling projects for subsidence control have been performed in Rock Springs, Wyoming, Wilkes-Barre and Scranton, Pennsylvania, and in Fairmont, West Virginia. Some of these projects have utilized sand, as well as, coal ash as backfill material. Much of the backfilling work performed in the United States has been done in an effort to control mine subsidence in abandoned mines. South Africa, on the other hand, has used backfilling extensively both for ash disposal and to increase extraction in active mines. The utilization of repetitive fill and mine techniques has resulted in extraction increases of as much as eight percent in shallow mines and as much as twelve percent in deep mines.(1) The coal ash injection system which can be used for backfilling depends largely upon whether the mine voids are dry or submerged. For dry mines, hydraulic or pneumatic conveyance systems can be used, while submerged mines are limited to backfilling by hydraulic methods. The use of coal ash as a backfill material has a number of advantages, such as: 1. Coal ash is available in areas throughout the United States and in many instances is conveniently located near areas requiring backfilling. 2. Coal ash is available in significant quantities since many coals when burned will result in about 15 to 30 percent ash by weight. 3. Coal ash as backfill is, in many instances, the most economical alternative fill material. Due to the costs associated with above ground disposal, power companies will often times give the material away to lower their overall operating expenses. 4. Coal ash is usually pozzolanic in nature, that is, this material results in cementitious bonding within the backfilled matrix of material.

Jan 1, 1982

By Brian Flintoff

Basic process control is an integral part of most mineral processing plants. It is widely acknowledged to have helped many operations reduce costs and increase productivity and performance. The research community is very active in the development and evaluation of both model based and Al techniques for advanced control applications. Vendors and specialist consulting or engineering firms are in business to help deliver these solutions to the plant floor. It would seem that there is a good balance between business needs and technology, and that the industry should be moving steadily forward in an aggressive pursuit of plant-wide automation. However on closer examination one sees some systemic problems which are sewing to inhibit progress. One of the mist obvious manifestations is the gap which exists between the available technology and current This paper explores the control of mineral processing systems, with a particular emphasis on some of these problem areas.

Jan 1, 1995

By D Gelling

Mineral sands dry plants consist of a large number of repetitive unit operations with significant transport delays, in the form of stream pipes, conveyors and elevators. As part of the P255 mineral sands sponsorship and using the JKMRC developed conductor/non-conductor (CNC) gauges, control loops have been implemented at the multi-duty dry plant of Cable Sands Limited at Bunbury. This paper describes the loops for kV control on a rougher high tension roll machines (HTR). The options available are product grade control and ratio control using the JKMRC CNC gauges, which measure the percent conductors in a stream. The purpose of control is to stabilise the circuit operation against disturbances such as atmospheric and feed disturbances.

Jan 1, 2001

By Ira B. Jorafemon

In the interesting Institute symposium of the preservation of peace by force, through mineral control, one important aspect of the question was not presented. This is the responsibility the United Nations, and particularly the United States, will incur the through limitation of the economic activities of nations that are now friendly to us, as well as of nations that are enemies or are under the control of enemies. After the war all nations, friends as well as enemies will be poor. Hunger and bankruptcy will, will like the sword of Damocles, hang over the heads of all of us on this blundering planet. When the actual fighting is over, there will be a universal attempt to squirm out from under the sword by resuming production of peacetime goods, for trade as well as immediate consumption.

Jan 1, 1944

By J. E. Spencer

Mesozoic and Tertiary mineral deposits in west-central Arizona are commonly associated with Mesozoic thrust faults and Tertiary detachment faults, respectively. Quartz-kyanite rocks and pyritic quartz-sericite schists with local anomalous gold are the product of probable Jurassic argillic alteration of Jurassic volcanic, sedimentary, and plutonic rocks followed by Cretaceous thrust burial and associated metamorphism. Slivers and sheets of Paleozoic carbonates along Mesozoic thrust faults were locally sites of syn-and post-thrust mineralization. Widespread brecciation along Tertiary detachment faults resulted in increased permeability along fault zones. Elevated thermal gradients also resulted from detachment faulting and apparently caused convective aqueous-fluid circulation along detachment faults and associated Fe+Cu±Au mineralization.

Jan 1, 1988

By AIME AIME

AN outstanding session of the Annual February Meeting was one held under the joint auspices of several groups on Tuesday afternoon, Feb. 22, as a symposium on the question of preserving peace in the postwar era through the control of the supply of sundry minerals vital to the Axis nations. D. H. McLaughlin and R. C. Allen were associate chairmen. And C.K. Leith led the discussion.

Jan 1, 1944

By Hamid Maleki

Mine seismicity is influenced by the mechanical properties of both near-seam rocks and overburden and the prudent selection of mining methods and mine layout designs. Using finite-difference modeling, experience in many U.S. mines and measurements of the pressure arch width, the author has reviewed the engineering design factors that control seismicity in room-and-pillar retreat operations for stiff stratigraphic conditions in deep western U.S. mines. By back analyzing the overburden response in now understood to have been inadequately designed historic room-and-pillar mine, the overburden collapse mechanism is addressed as well as the need for improvements in designs including panel and barrier pillar widths, and sequence of retreat.

Jan 1, 2009

By Masayasu Kawahara, Toshiyuki Kozuka

"Lorentz force, which has the functions of wave suppression and mixing control, is very useful for many metallurgical processes. In this paper, it is found that vertical Lorentz force which can change 'the gravitational force is able to modify the dispersion relation of the surface wave generated by gravity and also modify the instability phenomena on the interface so that the lower layer can be scattered into upper layers to realize the strongly mixed region.IntroductionIn metallurgical industries, recently, a new direction of process developments is required backed not only by severer operating conditions, e.g. small amount production, rapid refining, etc. but also by environment and energy problem. Because almost technologies in conventional processes have saturated, an innovative process, which can break the limits in the conventional processes, is now strongly required. Especially, controlling of mixing phenomena between two liquid phases is considered to be one of the most important technologies for the promotion of slagrnetal reaction, wave suppression, etc. On the other hand, electromagnetic forces which have various functions have been applied to many processes. And Lorentz force is able not only to suppress the wave motion of molten _metal surface but also to promote the mixing or separation of two liquids. In this paper, new controlling methods of mixing phenomena between two liquids are proposed, where a direct electric current and a stationary magnetic field are utilized. Vertical Lorentz force due to the interaction between the electric current and the magnetic field can modify the gravity force so that the dispersion relation of surface wave and the instability on the interface can be change to improve or develop the innovative processes(l,2).In case that a direct electric current is imposed on two liquid layers with a stationary magnetic field, Lorentz force of each layer becomes different due to the difference of electrical conductivity. If Lorentz force acting on the lower layer is stronger than that on the upper layer, resonance frequency of the wave motion on the interface due to the gravity can be shifted from the frequency of a outer disturbance to suppress the wave motion. And also, the lower layer can be scattered into the upper layer as liquid particles by an instability phenomenon."

Jan 1, 2000

By Arol, A. I., I. Iwasaki

The presence of calcium ion in iron ore pulps causes heterocoagulation of rnontmorillonite on hematite leading to indiscriminate dispersion. Two methods were investigated to control the adverse effect of montmorillonite: a chemical method using such complexing agents as EDTA and sodium tripoly- phosphate, and a mechanical method involving ultra- sonic treatment. Their roles in controlling the adverse effect were investigated by zeta potential measurements, starch adsorption tests, and flocculation and selective flocculation tests.

Jan 1, 1988

By I. Iwasaki

The presence of calcium ion in iron ore pulps causes heterocoagulation of montmrillonite on hematite leading to indiscriminate dispersion. Two methods were investigated to control the adverse effect of montmorillonite: chemical method using such complexing agents as EDTA and sodium tripolyphosphate, and mechanical method involving ultrasonic treatment. Their roles in controlling the adverse effect were investigated by zeta potential measurements, starch adsorption tests, and flocculation and selective flocculation tests.

Jan 1, 1986