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By A. -M. Lafront

The corrosion resistance of die-cast and freely-solidified and electromagnetically-stirred thixocast AZ91D alloy has been studied using electrochemical noise technique in a 0.05M NaCI solution at pH 6.1 and 25°C. Specimens polished at different depths were immersed for a period of 75 min in order to assess the influence of the microstructure on corrosion kinetics and morphology. At depths between 10 and 50 µm (skin), all specimens showed general non-uniform corrosion with the lowest corrosion resistance. Between 100 and 200 µmn (interior skin), the observed corrosion was accompanied by superficial undefined pits due to metastable pitting. The corrosion form for 100-200 µm gave the best corrosion resistance. Stable pitting corrosion was observed beyond 400 µm deep on the bulk specimens. The skin of all thixocast specimens prepared billets showed a more corroded surface than that of die-cast. The interior skin as well as the bulk specimens showed better performance than that of the die-cast specimens.

Jan 1, 2007

By Robert M. Hopkins, Craig C. Monahan

A corrosion survey was performed on ten selected H-piles which support a reinforced concrete wharf located at Trepassey, Newfoundland. Approximately 900 thickness measurements were taken at twelve different locations in each off our zones on the steel piles: the splash (atmospheric) zone, the intertidal zone, the low tide zone and the submerged zone. Results show that over the 2o-year life of the wharf, corrosion has been most severe in the splash, low tide and submerged zones with average corrosion rates for the flanges of 6.95, 9.45 and 6.86 mils per year (mpy}, respectively, and average corrosion rates for the webs of 5.13, 4.12 and 3.45 mpy, respectively. Minimal attack was found in the intertidal zone where the average corrosion rate was only 1.66 mpy on the flanges and 1.37 mpy on the webs. Such a pattern of attack is frequently observed f or steel piles partly submerged in seawater. The abnormally low corrosion rate associated with the intertidal zone is generally explained as being due to cathodic protection induced by the high corrosion rate in the adjacent low tide zone. Analysis of the corrosion data obtained for the Trepassey wharf would suggest that this explanation might be incorrect. An alternate hypothesis has been brought forward which better accounts for the extremely low corrosion rate observed in the intertidal zones of these piles.

Jan 1, 1990

By R. F. Lynch, F. E. Goodwin, A. F. Skenazi

"The Gal/an alloy has been developed for continuous galvanizing of steel. The choice of the eutectic zinc-aluminum alloy with addition of misch metal gives a coating with specific characteristics as far as structure, analysis, surface chemistry and surface morphology are concerned. The performance of the uncoated Galfan coating is superior when compared to conventional galvanized particularly for corrosion resistance and ductility. For coil coating applications, these two assets are of the utmost importance but in order to benefit from these two advantages, good paint adherence and high resistance to edge creep and blistering have to be obtained. Despite Galfan's unique features compared to other zinc based or aluminum zinc based coatings, existing pretreatments and painting conditions are used with only minor modifications in order to assure good adherence and edge creep resistance. With compatible processing, Galfan can outperform galvanized and Galvalume as a substrate for coil coating as is demonstrated with various test results.IntroductionThe technical and commercial development of Galfan, a 95% zinc-5% aluminum-0.1% lanthanum-cerium hot-dip coating for steel, has been rapid. From its identification as a promising coating in late 1980, it has evolved from a research product to a fully commercial product with over 100 000 metric tons of coated sheet produced to date, and another 90 000 tons, at minimum, scheduled for 1986. The great majority of tonnage produced to date has been coil coated for use in building panel , appliance, and similar applications. Much technical work has been done to determine the suitability of Galfan for these applications and the proper way of processing sheet for best results. The present state of knowledge is discussed in this paper, along with some recent applications which are given asexamples"

Jan 1, 1987

By M. D. Crites

As part of a multi-year program for assessing the viability of chrome-free refractories in copper smelting, converting and refining furnaces, dynamic corrosion tests have been conducted on a series of refractories from the magnesia-alumina system, using a ferrous silicate slag. The corrosion rates of the test refractories are compared with those of a reference mag-chrome brick, and recommendations are made for more in-depth evaluations of the more corrosion-resistant materials.

Jan 1, 1999

By J. E. Pollock, W. R. Hicks, E. Camp

IN the oil-refining industry, steel comprises by far the greatest proportion of the materials used in construction work, but with an enormous number of alloy steels and nonferrous alloys available, and a greater knowledge of their properties and corrosion resistance, a substitution first in the "hot spots" and then in locations of moderately severe corrosive conditions will be made as the greater expense can be justified. In new construction work, advantage is taken of the experience already gained and appropriate materials used, whether for high temperatures and pressures demanding additional strength or for corrosive conditions. The locations, however, where equipment in operation constantly requires replacement will soon become evident, as will the necessity for replacement in more resistant materials, if considerable down-time is to be avoided. In what direction and how far to go in the matter of alloys then becomes a question of the highest importance. Obviously, any replacement with more costly material must be justified economically by the promise of longer life, thereby saving both material and installation costs besides the reduction of loss of production. Where the equipment is overcapacity and a regular schedule of cleaning periods is in force, the last item frequently must be ruled out and justification made on the basis of the first two only. Installation of material that will outlast the remainder of the equipment and have no recovery value must also be avoided; this is particularly important in temporary construction or in old equipment that will soon become obsolete. TEST METHODS Either one Of two methods or a combination of both, in the absence of reliable data in similar services, may be adopted to determine to what extent replacement with other, and perhaps more expensive, materials is justified. A unit may be constructed incorporating different metals or alloys so that comparative service may be obtained under the same service conditions; this has been applied in many instances, such as condenser and tank construction, but the opportunities for inspection may be few and

Jan 1, 1935

By J. E. Pollock

IN the oil-refining industry, steel comprises by far the greatest proportion of the materials used in construction work, but with an enormous number of alloy steels and nonferrous alloys available, and a greater knowledge of their properties and corrosion resistance; a substitu-tion first in the "hot spots" and then in locations of moderately severe corrosive conditions will be made as the greater expense can be justified. In new construction work, advantage is taken of the experience already gained and appropriate materials used, whether for high temperatures and pressures demanding additional strength or for corrosive conditions. The locations, however, where equipment in operation constantly requires replacement will soon become evident, as will the necessity for replacement in more resistant materials, if considerable down-time is to be avoided. In what direction and how far to go in the matter of alloys then becomes a question of the highest importance. Obviously, any replace-ment with more costly material must be. justified economically by the promise of longer life, thereby saving both material and installation costs besides the reduction of loss of production. Where the equipment is overcapacity and a regular schedule of cleaning periods is in force, the last item frequently must be ruled out and justification made on the basis of the first two only. Installation of material that will outlast the remainder of the equipment and have no recovery value must also be avoided; this is particularly important in temporary construction or in old equipment that will soon become obsolete.

Jan 1, 1935

By John L. Hatton

The author will introduce and describe the nature of Fiberglas-Reinforced Plastics. Successful applications of corrosion-resistant structures will be shown and described, including pipe, ducts, tanks and other equipment. These structures are generally designed to handle corrosive liquids and gases and have proved both satisfactory and economical in service in various industries in Canada. The specification of structures will be discussed in relation to materials, construction and workmanship, physical properties and methods of testing.

Jan 1, 1970

By P. -Q. Wu

A modified electrochemical noise (EN) technique has been applied to monitor corrosion wear of TiN-coated ASP23 steel and TiN-coated AISI 316 stainless steel sliding against corundum in 0.5 M H2SO4. Experimental results show that the EN technique can sensitively detect potential and current variations during a corrosion-wear process. Corrosion-wear mechanisms of TiN coatings depend on their substrate properties. If the substrate is passive, such as AISI 316 stainless steel, the potential and current variations reflect the properties of the coating. Depassivation and repassivation alternately take place on the tribo-activated wear area during the steady-state phase. If the substrate is active, such as ASP23 tool steel, the electrochemical noise is dominated by dissolution of the substrate at the pinholes and the hydrogen evolution all over the exposed surface.

Jan 1, 2005

By S. H. Ash

NINE-TENTHS of the total anthracite deposits of North America are in Pennsylvania. Corrosion of pumping equipment by acid mine waters has been experienced at tremendous cost by mining companies in the anthracite region of Pennsylvania, for many years in many ways. The design and specifications of the large centrifugal pumps as provided in the proposed mine-drainage system (7-35, 45, 46, 48, 54, 64, 70, 71)° make it imperative that a metal or alloy be recommended that has the highest corrosion resistance and, at the same time, acceptable properties suitable for general workability (welding and machining). This report presents data on the corrosive and erosive effects of acid mine waters in the anthracite region on metals and alloys for pumping equipment and drainage facilities necessary to remove or control this water.

Jan 1, 1955

By K. A. Natarajan

The relative significance of corrosive and erosive wear in magnetic taconite grinding is examined. The influence of different types of aeration, namely, nitrogen, air and oxygen on ball war was established for mild steel and high carbon low alloy steel balls. Ball wear data from dry and wet grinding tests are compared with those obtained in the presence of an organic solvent that does not promote electrochemical corrosion. 'Marked ball grinding, tests along with electrochemical measurements involving ball material and magnetite electrodes indicate that contribution from oxygen towards wear (corrosive wear) is relatively small and abrasive wear appears to be significant. Rheological properties of the slurry-appear to have an important bearing on the abrasive wear of grinding balls.

Jan 1, 1983

By K. A. Natarajan, S. C. Riemer, I. Iwasaki

The relative significance of corrosive and erosive wear in magnetic taconite grinding is examined. The influence of different types of aeration (nitrogen, air, and oxygen) on ball wear was established for mild steel and high carbon low alloy steel balls. Ball wear data from dry and wet grinding tests are compared with those obtained in the presence of an organic solvent that does not promote electrochemical corrosion. Marked ball grinding tests and electrochemical measurements involving ball material and magnetite electrodes indicate that contribution from oxygen toward wear (corrosive wear) is relatively small, and abrasive wear appears to be significant. Rheological properties of the slurry appear to have an important bearing on the abrasive wear of grinding balls.

Jan 1, 1985

By Dr. G. R. Hoey

"Abrasive wear and corrosive wear of carbon-steel grinding balls occurred simultaneously during the wet-grinding of hematite iron ore, and Ni-Cu sulphide ore, in laboratory ball mills. Two corrosion control methods, the use of corrosion inhibitors and pH control, were investigated and found to be effective means of reducing or preventing corrosive wear. Up to 50 % reduction of total ball wear resulted from the use of these methods.Corrosive wear is caused principally by the reaction of oxygen in air with the carbon-steel grinding balls, probably by the following reaction: 2Fe + O2 + 2H20 - 2Fe2 + 40H-.IntroductionA survey of corrosion problems in Canadian sulphide ore mines was completed and the findings were published in 197l(l). The corrosion survey was used to develop the present research program with the objective to find more economical and effective ways and means to reduce the corrosion that occurs in the mining and metallurgical industry. The purpose of this presentation is to review the projects being done by staff members of the Corrosion Section, Extraction Metallurgy Division, on corrosive wear and its control in wet-grind ball mills.Both abrasion and corrosion contribute to metal consumption during wet grinding of ores. The total wear of grinding media in this study is assumed to be equal to the sum of corrosive wear and abrasive wear. A great deal of research and development has been reported in the literature on ways to improve the abrasion resistance of grinding media but only a small number of studies has been reported on the corrosion resistance of conventional grinding media."

Jan 1, 1974

By Freeman C, Dingley W

Addition of sodium nitrite-borax, sodium hydroxide, sodIUm carbonate, lime, or sodium silicate reduced wear of forged steel balls and cast iron slugs in wet grinding a complex zinc-lead-copper sulphide ore in laboratory ball mills. Maximum wear reductions were 27 per cent (forged steel balls) and 33 per cent (cast iron slugs) with sodium hydroxide and nitrite-borax additives respectively.Potential measurements of balls and slugs during grinding, and analysis of the data in terms of corrosion theory demonstrated that corrosive wear had been reduced or prevented by these additives. Actual per cent wear reductions were not equated to the rate of corrosive wear because of the undefined interdependence between abrasion and corrosion in wear processes. The investigation verifies that in laboratory ball mills corrosion is significant in the wear of grinding media and wear can be reduced by corrosion inhibition and pH adjustment.

Jan 1, 1978

By Shane Andrews, Gustavo Vasquez, S. K. Varma

"The effect of solutionizing time on the corrosive wear behavior of 2014 aluminum alloy has been studied using the impact and continuous mode of scratching techniques. The transient currents (TC) evolved during the scratching of the alloy shows a linear dependence between the TC and the solutionizing time. Higher TC values at longer solutionizing time may be associated with the changes in the concentration of quenched-in vacancies, grain sizes and dislocations generated during scratching. These factors can either create (a) anodic sites or (b) pitting corrosion resulting in the generation of transient currents. The results have been compared with the similar study carried out for 6061 aluminum alloys. This 6061 aluminum alloy shows similar behavior but the rate of TC generation per unit solutionizing time is much lower than 2014 aluminum alloy. The morphological changes in the impact scratches and the TEM investigation in the scratch have been presented in this paper.IntroductionThe technique of studying corrosive wear of composites of 6061 aluminum in the monolithic and reinforced forms has been reported in the literature [1]. Two modes of scratching, consisting of impact and continuous, in a corrosive environment indicate that the composites, containing 0.10 and 0.20 volume fractions of alumina particles (VFAP), have higher corrosive wear rates than the monolith. A graph between the transient current (TC) generated during the impact scratching as a function of solutionizing time at 540°C indicates linear relationship between them. A similar slopes for the composites were observed and the TC values were less for the composite containing lesser VFAP."

Jan 1, 1998

By Bryan de Barros Soares

O aço carbono é um material amplamente empregado na indústria petrolífera devido sua elevada resistência mecânica e baixo custo. Entretanto, este material não possui boa resistência à corrosão. Neste contexto a predição da taxa de corrosão é de extrema importância para estimar a durabilidade desses materiais. Atualmente isto é feito com base em dados de ensaios de perda de massa em um único tempo de imersão, estimando-se a taxa de corrosão. Contudo, para converter os dados de perda de massa em taxas de corrosão é imprescindível que os ensaios sejam conduzidos em diferentes tempos de imersão e que haja linearidade entre perda de massa e tempo. Neste trabalho a corrosão do aço carbono em meios saturados com CO2 foi investigada através de ensaios de perda de massa em três tempos de imersão diferentes, com o objetivo de avaliar essa linearidade. Dos quatro meios corrosivos estudados, um não apresentou linearidade entre PM e tempo de imersão, sendo portanto incorreto extrapolar os dados para taxa de corrosão. Os resultados comprovaram que a extrapolação de dados de PM para taxas de corrosão não pode ser aplicada sem uma prévia verificação da linearidade entre perda de massa e tempo de imersão.

Aug 16, 2017

By Lucas Coelho da Silva

Este trabalho tem a pretensão de problematizar a influência da corrosão, sobretudo nos trocadores de calor, e trazer a importância de um estudo prévio detalhado, ressaltando como o desempenho deste equipamento está relacionado ao material utilizado e como esse estudo pode nos abster de grandes dispêndios. Através de ensaios eletroquímicos vamos estudar o comportamento do aço Super Duplex UNS S32750 em diferentes meios corrosivos, com o intuito de avaliar se o nível de corrosão do material é adequado para as condições severas de operação impostas a um permutador de calor.

Aug 16, 2017

By José Helio Sobrinho

O aço inoxidável austenítico alto nitrogênio ISO 5832-9 tem sido promissor na manufatura de próteses ortopédicas com resistência mecânica e de corrosão superiores a do aço tradicional ASTM F-138. Pesquisas recentes têm mostrado que esta liga apresenta resultados peculiares, tais como alta resistência mecânica, resistência à corrosão e presença de partículas de segunda fase (Fase Z) na matriz. Entretanto, não se sabe como se dá a correlação mecânica-microestrutural e de taxa de corrosão em regiões de processabilidade industrial desta liga na conformação a quente de peças. No presente trabalho, ensaios sob torção a quente isotérmico contínuo e interrompidos foram realizados após tratamento térmico de solubilização a 1.200oC, por 300 s com intervalos de temperatura variando entre 1.000°C e 1.200oC com taxa de deformação variando entre 0,05 e 5 s-1, para investigar a trabalhabilidade e a taxa de corrosão sob tensão desta liga com aplicação da técnica de espectroscopia de impedância eletroquímica e caracterização microestrutural, conduzida por microscopia óptica e varredura. Os resultados mostram que a tensão de escoamento é sensível aos parâmetros de deformação. O pico de tensão diminui com o aumento da temperatura e redução da taxa de deformação com alta taxa de recuperação dinâmica com grãos alongados, gerando regiões de acúmulo de tensão. Essas regiões de instabilidade plástica apresentam grau de corrosão superior em relação às amostras como-recebidas. As regiões de alta temperatura e baixa taxa de deformação apresentam boa trabalhabilidade com microestrutura final refinada com grãos recristalizados dinamicamente.

Aug 8, 2018

By Raphael França Assumpção

O aço inoxidável duplex (AID) vem sendo considerado uma excelente alternativa para aplicações que requerem alta resistência à corrosão e alta resistência mecânica. Portanto, a microestrutura e as propriedades dos aços dúplex permanecem como temas de grande interesse. Para este proposito, estudou-se o efeito da laminação a morno em um aço inoxidável duplex. O foco deste trabalho foi o AID 2205 que é um dos tipos mais comuns de AID. O objetivo deste estudo é avaliar o comportamento eletroquímico do AID 2205 laminado a morno no ambiente de íons de cloretos utilizando medidas de polarização potenciodinâmica. O aço inoxidável dúplex foi laminado a morno à 600°C para 60 e 80% de redução na espessura e submetido a testes eletroquímicos. As amostras apresentaram uma excelente resistência à corrosão em solução de NaCl 3,5%. Apesar da existência de certa similaridade entre os valores de potencial de circuito aberto e potenciais de pites obtidos para todas as amostras, o número de pites observado foi maior na amostra CF, seguida pelas amostras com 60 e 80% de redução.

Oct 30, 2017

By Jorgen Elbrond, Noel Billette

"La connaissance du niveau de variation de I' alimentation d' une usine minéralurgique est essentielle pour estimer le taux de récupération dans un concentrateur. De plus, il est important de connaître la période moyen ne de correlation afin d’améliorer la qualité des contrôles et de l' au tornatisation.Le modèle proposé permet de prédire ces paramètres à partir du minerai en place et des activités d'exploitation dans une opération à ciel ouvert. II est basé sur la combinaison des variogrammes directionnels dans diverses zones d'un gisement, ce qui permet de définir la correlation à la sortie de chaquc zone en fonction des decisions opérationnelles, puis sur une loi binômiale modifiée, afin de séparer minerai et stériles dans Ie but de décrire variance et corrélation dans Ie minerai même, Les statistiques classiques sont alors utilisées pour décrire la combinaison de plusieurs zones et obtenir la variance et la correlation au concentrateur.IntroductionUn concentrateur est habituellement rodé de facon à recevoir une alimentation à teneur fixe en métal ; Ie minerai qui s'y presente a, par contre, tendance à osciller auteur de cette valeur cible, tantôt plus riche , tantôt plus pauvre . Ces variations entraînent des pertes de deux types: tout d'abord, la teneur du concentré oscille de facon similaire à celle de l' alimentation , ce qui peut même impliquer des pénalties a I'usine de smeltage lorsqu'elle est trop riche ou trop pauvre; la récupération peut pour sa part être diminuée de plusieurs points par un engorgement du circuit lorsque la teneur est trop forte."

Jan 1, 1984

By Benjamin A. Allou

La seule production de columbo-tantalite réalisée en Côte d?Ivoire est effectuée dans les éluvions et alluvions du gisement d?Issia, localisé au Centre- Ouest de la Côte d?Ivoire. Même si un lien direct avec les roches granitiques est suspecté, aucune attention particulière n?a été accordée à l?étude de la minéralisation primaire en relation avec l?évolution des granites et des pegmatites associées. Ces granites, qui sont en intrusion dans les roches sédimentaires du Protérozoïque inférieur, comprennent : le granite orienté à deux micas (Lobo), le granite orienté à muscovite dominante (Bitapia) et le granite porphyroïde non orienté à muscovite dominante (Issia). Les résultats de cette étude indiquent que les pegmatites à Nb-Ta-Be-Li sont liées au granite de type Issia. Les observations de terrain et les analyses sur roche totale des granites montrent que: (1) les trois principaux granites de la région sont de type- S et peralumineux dans leur composition, (2) ils ont été formés pendant la période tardi- à post-Éburnéenne, (3) le granite d?Issia fut le dernier à se mettre en place. Les pegmatites liées au granite d?Issia ont été classées en quatre types : Apegmatites stériles; B- pegmatites à Be; C- pegmatites zonées à Nb-Ta-Be; et Dpegmatites zonées à Be-Nb-Ta-Li. Les pegmatites zonées comprennent les zones suivantes: I- zone à aplite; II- zone graphique; III- zone à albite, microcline, béryl et columbo-tantalite; IV - zone à microcline massive; V- zone à quartz. Ces pegmatites présentent une zone d?altération métasomatique externe. La minéralisation de Ta, Nb et Be est liées à la zone III des pegmatites de types C et D, et celle de Li est associée aux greisens qui peuvent être observés n?importe où dans les pegmatites de type D. Les données de terrain et de laboratoire indiquent que le granite d?Issia est la roche parentale des pegmatites à éléments rares de la région. Les pegmatites minéralisées sont distribuées seulement autour du granite d?Issia et les patrons des terres rares des granites et ceux des pegmatites à éléments rares sont très similaires. Les analyses de la composition totale montrent un lien génétique entre le granite d?Issia et les pegmatites à éléments rares. Il est suggéré que les pegmatites ont été formées durant le transport et la cristallisation fractionnée du magma.

May 1, 2003