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By Jun Miao, Kang Liu, Jilai Xue, Jun Zhu

CO2 emissions must be reduced by at least 50 % by 2050, and hence the technical solutions to capture and convert CO2 into value–added products should be considered. A Cobalt(III) Schiff base complex (Salen–Co(III)) has been investigated as a catalyst for synthesis of cyclic carbonate from CO2 and epichlorohydrin(ECH) with tetrabutylammonium bromide (TBAB) as co–catalyst. To recover Salen–Co(III) for the next cycling operation, it was immobilized onto zeolite 13X through excessive impregnation method. The immobilized catalyst was characterized using XRD, SEM, BET and ICP–AES techniques. Catalytic tests showed that yield of cyclic carbonate reached 90 % using 0.5 mol % Salen–Co(III) at ambient conditions. The immobilized Salen–Co(III) exhibited better catalytic activity than the homogenous one when used at the first cycle, but the yield decreased by some 20 % after five cycles.

Jan 1, 2015

By Ronald S. Tanaka

In the planning stages for a dozen years, the 9.11 mile long Mount Macdonald Tunnel is the focal point of the $600 million dollar Rogers Pass Project. The paper will discuss the construction of the tunnel that is being carried out from both ends. The eastern portion contractor has used a tunnel boring machine to excavate the upper part of the tunnel and at the west end contractor selected the conventional drill and blast method. A ventilation shaft located near the mid point is the main part of a ventilation system unique in the Western Hemisphere.

Jan 1, 1987

It has been proven theoretically and experimentally that the use of 10 - 30 per cent DRI in blast furnace along with iron ore or sinter results in lower coke rate and higher productivity. However, to-date this remains unpractised on a regular basis mainly because of economic reasons. The DRI produced by several methods are expensive and difficult to store/handle in large quantities because of its reactive nature and thus DRI in blast furnace remains unacceptable.

Jan 1, 1999

By Mark M. Petersen

As part of the addition of eight new combined cycle generating units at the Florida Power & Light Sanford Plant, 2,129 piles were to be installed. The existing plant elements were supported on driven piles, and the variation in pile lengths during previous work, as well as available subsurface information, indicated a complex stratigraphy. At the request of the owner, the designer/construction manager developed a program to evaluate the use of pressure-grouted displacement piles. A pre-design load test program in areas that represented the apparent extremes in subsurface conditions indicated that the system was feasible; however, the presence of existing features that were to be demolished later precluded the clear delineation of subsurface conditions in advance of construction. A contract was negotiated with the pile installer based on the best estimate of potential pile lengths, with modifications to pile lengths to be set based on additional exploration. A total of 52 cone penetration soundings and five load tests were performed immediately prior to and during pile installation to establish correlations between the CPT data and pile performance. Pile depths were set based on these correlations. Pile installation was completed 6 weeks ahead of schedule and 15 percent under the original budget estimate. This paper documents the evaluation of pressure-grouted displacement piles as an emerging technology, and illustrates the benefits of a close working relationship between the owner, designer, and pile contractor at a site with variable subsurface conditions.

Jan 1, 2002

By Howard A. Perko, Margaret Dring, Gerald Verbeek, Scott Slaughter

Helical piles have become a widely used deep foundation system in recent years due to their many inherent advantages. The cone penetration test (CPT) is commonly used in geotechnical practice to evaluate subsurface conditions for deep foundation design as the method provides a continuous soil profile in a short amount of time, measures in-situ soil strength, and in many ways behaves similar to a “mini pile” during penetration. In the CPT test, an instrumented cone is hydraulically advanced into the soil at a constant rate. As the cone is advanced, strain gauges embedded in the cone body continuously measure the tip resistance and side friction. In addition, a piezometer element is commonly used to measure the (dynamic) pore water pressure in the soil as the cone is advanced. A study was conducted comparing the CPT tip resistance to helical pile installation torque and capacity. In this paper, the outcome of this study was compared with historical data of helical pile installation torque records, static analysis predictions using commonly used techniques, and pile load test results over a wide range of soil conditions. A literature review was also conducted where a comparison was made for CPT tip resistance and helical pile installation torque data with previously published correlations.

Sep 8, 2021

By Jesus Gomez, Mary Nodine

Rigid inclusions are widely used in the U.S. as a ground improvement tech- nique, particularly for industrial, low- rise and highway applications with poor subsurface conditions, where control of settlement is necessary. Rigid inclu- sions consist of grouted or concrete elements typically 12-24 in (305-610 mm) in diameter that may or may not be reinforced with a center bar. Typical soil conditions where rigid inclusions are feasible might consist of a surface layer of fill and natural, granular soil, followed by a stratum of soft silt or clay overlying a dense or stiff formation. Rigid inclusions are installed from the existing ground surface or suitable work platform, through the surface soils and through the soft, compressible layer, and into the deeper layer, which is less susceptible to compression- induced settlement. Typically, when used to support an extended area surcharge, the inclusions are installed in a rectangular or triangular pattern at regular spacings ranging from 5-12 ft (1.54 m), depending on a variety of factors. The rigid inclusion system is often capped with a load transfer platform (LTP), whose function is to direct a significant portion of the applied load toward the rigid inclu- sions. Additional load is transferred to the rigid inclusions through the upper fill soils above the compressible layer. The rigid inclusions transfer the applied load axially to their tips and into the deeper layer. In the U.S., rigid inclusions are mostly installed using displacement auger systems. The use of a dis- placement auger has significant advantages. It produces zero to near- zero spoils, which is an important environmental consideration. The

May 1, 2023

By Glen Toepfer

The paper point out geosynthetic installations as assets, Construction Quality Assurance (CQA) and how both items relate to ensuring a sound installation that should provide a significant return on investment for the owner. Also this elements that are required in obtaining a sound installation and the tangible benefits of a zero-leak geomembrane installation.

Oct 21, 2015

By R K. W Merkle, S Madoom Hussain, T Yellappa

Cr-Ni-Cu¦PGE deposits are known to occur in early Archaean mafic-ultramafic rocks. Early Archaean mafic-ultramafic (MUMF) rocks occur in the western Dharwar craton and range in size from small pods to schist belts. These MUMF pods consist mainly of meta-peridotites, tremolite-actinolite schists, serpentinites, amphibolites and metabasalts. Spinifex, nodular and ocelli textures are also present. The rocks have been subjected to greenschist and amphibolite facies metamorphism. Geochemical studies were undertaken to evaluate the possible occurrence of economically important elements in the mafic-ultramafic enclaves around the major Arsikere-Tavarkere lineament and surrounding gneissic terrain adjoining local shear zones that occur as discontinuous pods between Arsikere and Chennagiri. Talc-serpentine and tremolite- actinolite schists contain chromite which is rimmed by ferrit-chromite. A notable feature of these MUMF rocks is that they exhibit high MgO (22 - 40 per cent), total iron (8.34 - 10.01 per cent), Ni and Cr (~3000, 2800 ppm) contents, with some samples showing komatiitic affinity. The rare earth elements (REE) data show slightly fractionated patterns with enriched LREE (LREE/HREE ~5.0) and negative europium anomalies. The Pt and Pd values reach 6500 and 191 ppb. The MUMF rocks, especially those exhibiting high chromium contents and occurring near shear zones, are potential hosts for economic platinum group element (PGE) deposits.

Jan 1, 2008

By E. Ettles

This paper features some of the spectacular new advances in the fields of fluorescent penetrant inspection and magnetic particle concentration. Casting fractures in the various stages -before the repair, during the repair and in the completed repair -using the cold process method will be discussed. This cold method of repair eliminates problems of pre-heating and cooling and the stress factors that are involved in any heat repair.

Jan 1, 1971

By Douglas Rudenko PG, Jay Elkin, Siavash Mahvelati Ph. D.

Very little studies have investigated the behavior of cracks in unlined tunnels over long periods of time, especially when such flaws are subjected to blast-induced vibrations. Using a pool of 30+ blast events, a positive correlation was found between the peak particle velocity and peak crack movement.

Feb 1, 2020

By D. Cronin, A. Plumtree, A. Hosseini

"Crack in corrosion (CIC) linepipe defects are hybrid defects not directly addressed by existing assessment methods. To investigate the collapse pressure of these defects, CIC defects were formed in 508 mm (20 in) diameter, 5.7 mm thick API X52 linepipe. These defects were 200mm long and varied in depth from 3.0 to 3.8 mm. The respective failure pressures decreased from 14.3 MPa for the plain pipe to 7.9 and 6.2 MPa respectively. A standard FAD method was applied to evaluate these defects as equivalent length and depth cracks, predicting the rupture pressure conservatively by 18% on average. However, when assessed as equivalent cracks with a reduced wall thickness corresponding to the corrosion depth, the predicted collapse pressures were more accurate, approximately 14% conservative on average.INTRODUCTIONPipelines are a safe and efficient method for transporting high volumes of oil and gas. However, aging pipelines may experience defects, such as cracks or corrosion. Present approaches include detection, assessment and repair of defects before they may become critical to the integrity of the line. There are different codes and standards for assessing pipeline defects, depending on the type of defect, with API 579 (API, 2000) being the most common code for the assessment of cracks in oil and gas pipelines . Corrosion is commonly assessed using RSTRENG (Kiefner & Vieth, 1989). Other methods such as the Finite Element method and the CPS method (Cronin & Pick, 2002) may be used for crack and corrosion, respectively.At present, there is no specific method or procedure for assessing crack in corrosion (CIC) defects, and as a consequence there is a need to provide an assessment and evaluation of the integrity of these defects in order to determine the requirements for defect repair or hydro line testing. Hence, the goal of this study was to provide guidance for the assessment of CIC defects for linepipe.CRACK IN CORROSION DEFECTS (CIC)Significant amounts of corrosion and cracking are not generally found together (Hosseini, 2010). However, a new hybrid defect including cracking within corrosion (CIC) has been identified in operating pipelines. In this case, cracking coincident with corrosion (schematic shown in Figure 1) provides the motivation for the current study."

Jan 1, 2012

By Kai Koosmen, Mehdi Serati, Tengzhou Wang

Spalling and rockburst are unwanted brittle failures at the boundaries of underground excavations that are commonly observed in hard rock and high-stress environments at significant depths, although, spalling has also been observed in comparatively shallow soft rocks. The crack initiation (CI) stress threshold (representing the stress level at which new micro cracks begin to form in an intact rock) is widely used to establish the in-situ spalling strength, and is generally regarded as the lower limit of the long-term rock strength. This study analyses the evolution of CI and other mechanical properties for a high-porosity sandstone with an average UCS of 38 MPa under unconfined cyclic compressive loading. The results indicate that rock properties are variably affected by cyclic loading with; no significant effect on Youngs Modulus; a moderate increase in Poisson’s ratio and fracture angle; a moderate decrease in UCS; and a major reduction in the CI stress threshold. All of these changes were generally amplified by cyclic loading at higher stresses. From the results, it is concluded that rockburst and spalling limit in underground structures may reduce over time if the rock is subject to repetitive cyclic loading, and that the reductions will be greater for higher cyclic stresses. This may be a significant factor in the design and operation of some deep underground structures.

Apr 26, 2022

By S. Rash Ahmadi

Thin brittle coatings are deposited or developed on component surfaces for different reasons. In many practical applications the coatings are stressed by externally applied loads. Under such conditions, coating failure can occur. In this paper the probability of the extension of surface crack in coated materials due to cylindrical sliding indentation is analyzed. Contact loading problems typically result in multi-axle and strongly inhomogeneous stress fields near the contact surface. This property which strongly affects the stress intensity factors is taken into account in the failure analysis. Edge cracks were selected to model the actually accruing surface flaws. A suitable method is described for calculating the contact stress fields in coating and substrate. The coating is idealized as a brittle-elastic layer of uniform thickness, which is bonded to the surface of a half space. Method of linear elastic fracture mechanics are then used to calculate the load required to cause fracture in the coating.

Oct 1, 2011

By J. Meissner

In this paper vibratory crack response is compared to that produced by volumetric changes in foundation soils induced by natural events. These natural phenomena include changes in the water table, changes in soil moisture, and formation of ice lenses to name a few. Previous papers have compared vibratory responses of cracks to atmospheric effects such as those produced by the passage of weather fronts and daily changes in temperature and humidity. Periodicity of these atmospheric effects is on the order of a day to half a dozen days. Thus it is possible to observe atmospheric effects with measurement over a period of weeks to several months. On the other hand, crack response produced by volumetric changes in foundation soils occurs over a period of many months and/or may be seasonal in nature if not longer in the case of drought. Thus its measurement requires long periods of observation (many months to significant fractions of a year) or observation during critical seasons. Since it occurs over long periods of time, its observation may be obscured by climatologically induced crack response. These soil volume changes are compared with climatic data to describe the correlative nature of crack response in time with the soil volume change phenomena and likely climatic causes.

Jan 1, 2009

By Karl Peterson, Bibhu Mohanty, Chanakya Nariseti

The mechanism of crack formation in two target rocks (Kuru granite and Flamboro Limestone) is studied experimentally by simulating the impact action of a percussive drilling bit. Rock samples are dynamically loaded using a custom made impacting bit (8 mm, 12 mm and 15 mm diameter bits). The target rocks are impacted at velocities 8, 10, and 12 m/s. The resulting crack patterns are visualized by three techniques, Dye penetration, CAT scans and Optical scans. Mapping of the crack patterns is manually done with Photoshop. For 3D damage visualization, the crack patterns are mapped in two planes (impact surface and longitudinal sections). The three techniques are compared to determine an optimum technique for better damage visualization. The evolution of crack pattern with impact velocity and bit diameter is discussed.

Jan 1, 2015

By Erik S. Bernard

"INTRODUCTION Conventional steel bar reinforcement is used in many tunnel linings to provide high flexural and tensile load resistance. These Reinforced Concrete (RC) tunnel linings may suffer flexural cracking during service or, in the case of precast concrete segments, during production, handling, or installation. Cracks can lead to corrosion of steel reinforcement, so limits are placed on maximum acceptable crack widths to reduce the likelihood of corrosion during the intended design life (AFTES, 2013; MC2010, 2012). However, the relatively light level of reinforcement used in many applications can result in quite wide in-service crack widths, so either additional steel bar reinforcement is required to limit maximum crack widths, or fibers can be included to control crack widths. Numerous investigations have been undertaken into the efficacy of including steel fibers to reduce crack widths in conventionally reinforced members (Stang and Aarre, 1992; Abrishami and Mitchell, 1997; Bischoff, 2003; Dupont and Vandevalle, 2003; and Jansson et al, 2010), but steel fibers suffer the problem that they are at least as sensitive to corrosion at cracks as steel bars and therefore have similarly tight limits placed on acceptable crack widths (AFTES, 2013). An alternative means of maintaining narrow crack limits in RC members has therefore been sought. The current investigation was instigated following an observation that theories promoted as an explanation for the ability of steel fibers to reduce crack widths in reinforced concrete flexural members (Deluce et al, 2014) do not depend on the material composition of the fibers used but instead depend primarily on the tensile stress generated by the fibers across cracks. Since it is known that macro-synthetic fibers are capable of equaling the post-crack tensile capacity of steel fibers, it has been hypothesized that macro-synthetic fibers are also capable of reducing crack widths in reinforced concrete flexural members but with the added advantage that macro-synthetic fibers are completely immune to the effects of corrosion. Use of macro-synthetic fibers to reduce maximum crack widths in reinforced concrete flexural members subject to aggressive environmental exposure is more rational than use of steel fibers because steel fibers are very sensitive to the corrosive effects of environmental exposure at cracks. The current investigation was therefore undertaken to explore the potential use of macro-synthetic fibers to reduce maximum crack widths in reinforced concrete members subject to flexure. Barchip BC54 fibers were selected as they are one of the most widely used and competitive high performance macro-synthetic fibers currently available."

Jan 1, 2016

Keywords: Pyrometallurgy, furnace, Lonmin, platinum, PGM, UG2 Lonmin, earlier than any other primary platinum producer, had to deal with the concentrating and smelting of UG2-rich ores and concentrates respectively. Smelting was performed at a fairly modest scale compared to its industry peers in the Platinum Group Metals (PGMs) industry, and was focused on smelting concentrates obtained through low mass pulls while still maintaining high recoveries at its concentrators. Lonmin gradually smelted larger quantities of UG2 concentrates. Initially two 2.3 MW Infurnco furnaces were commissioned in 1982, followed by three 5 MW circular 3-electrode Pyromet furnaces in 1991. Deep electrode immersions and moderately high hearth power densities were used in all the designs. Lonmin decided to continue with circular furnace technology when it planned its new high-intensity No. 1 Furnace. Neither Lonmin nor the technology supplier and EPCM company foresaw the challenges that scale-up would bring when applied to the smelting of UG2-rich concentrate blends. Superimposed on the high chromite content, was the low base-metal loading, mineralogical difficulties, and fine particle size that came with milling of all concentrates (especially UG2 and recycle materials within the smelter). Through a process of fundamental diagnoses of furnace run-outs and wear patterns observed during repairs, the main challenges operating this high-intensity furnace were identified as sulphur vapour corrosion of the copper coolers, uneven and unpredicted movements of refractory bricks with associated copper cooler lift and matte tap-block movement, the formation of three-phase ?mushy? zones, high refractory and tap-hole wear rates, uncertainty in matte level and associated insufficient matte buffer height, and high furnace operating temperatures. These factors seldom worked in isolation and will be explored in more detail in the paper. The variability in furnace feed characteristics led Lonmin to re-design Furnace No. 1, to invest in back-up furnace capacity, and to invest in improved monitoring and control. These improvements consisted of online and high-frequency off-line feed chemistry and mineralogy monitoring, online pressure monitoring of water-cooled circuits, an alternative matte liquid level measurement in the furnace, and electrode immersion estimation. Improvements were also made at the converters by installing and utilising optical spectral analysis of the converter flame to characterise converter behaviour and achieve the desired iron end-point for white matte. This paper also briefly discusses the current and future expansion plans, as well as ancillary operations at the smelter such as flue-gas handling and materials handling.

Jan 1, 2011

Lonmin, earlier than any other primary platinum producer, had to deal with the concentrating and smelting of UG2-rich ores and concentrates respectively. Smelting was performed at a fairly modest scale compared to the company's industry peers in the platinum group metals (PGMs) industry, and was focused on smelting concentrates obtained through low mass pulls while still maintaining high recoveries at its concentrators. Lonmin gradually smelted larger quantities of UG2 concentrates. Initially two 2.3 MW Infurnco furnaces were commissioned in 1982, followed by three 5 MW circular 3-electrode Pyromet furnaces in 1991. Deep electrode immersions and moderately high hearth power densities were used in all the designs. Lonmin decided to continue with circular furnace technology when it planned its new high-intensity No. 1 Furnace. Neither Lonmin nor the technology supplier and EPCM company foresaw the challenges that scale-up would bring when applied to the smelting of UG2-rich concentrate blends. Superimposed on the high chromite content, was the low base-metal loading, mineralogical difficulties, and fine particle size that resulted from milling of all concentrates (especially UG2 and recycle materials within the smelter). Through a process of fundamental diagnoses of furnace run-outs and wear patterns observed during repairs, the main challenges operating this high-intensity furnace were identified as sulphur vapour corrosion of the copper coolers, uneven and unpredicted movements of refractory bricks with associated copper cooler lift and matte tapblock movement, the formation of three-phase 'mushy' zones, high refractory and taphole wear rates, uncertainty in matte level and associated insufficient matte buffer height, and high furnace operating temperatures. These factors seldom worked in isolation and will be explored in more detail in the paper. The variability in furnace feed characteristics led Lonmin to redesign Furnace No. 1, to invest in backup furnace capacity, and to invest in improved monitoring and control. These improvements consisted of online and high-frequency off-line monitoring of feed chemistry and mineralogy, online pressure monitoring of water-cooled circuits, an alternative matte liquid level measurement in the furnace, and electrode immersion estimation. Improvements were also made at the converters by installing and utilizing optical spectral analysis of the converter flame to characterize converter behaviour and achieve the desired iron end-point for white matte. This paper also briefly discusses the current and future expansion plans, as well as ancillary operations at the smelter such as flue-gas handling and materials handling.

Jan 1, 2011

By Terry W. Mellors, Robert J. F. Goodfellow

The underground industry has been forced to reconsider risk management sincethe introduction and implementation of the “Joint Code of Practice for Risk Management of Underground Works in the UK” published in 2003 and the subsequent international version published by the ‘International Tunneling Insurance Group’ (ITIG) in January 2006.What does this mean for major tunnel projects in the US and elsewhere? The discussion will highlight the implementation of the Codes to date, risk management principles embodied in the Codes and the use of risk registers as a projectmanagement tool and the management of risk.

Jan 1, 2007

By S Lal, S Rost, Q Williams, K Collerson

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. Shoshonite suite (absarokite-shoshonite-banakite) and adakite-hosted epithermal Au deposits are a feature of circum-Pacific magmatism. Fijian examples include Tavua (Emperor) and Tuvatu on Viti Levu. New discoveries of shoshonite suite and adakite-hosted epithermal Au mineralisation have been made in the southern Yasawa Islands and in central-northern and central-western Viti Levu. The Fijian shoshonites define four NE–SW trending suites. The oldest is the northern 7.9–5.0 Ma Yasawa suite, followed by the 4.7–3.5 Ma Sabeto–Tavua–Rakiraki suite in northern Viti Levu, the 4.7–4.2 Ma Yanuca–Vatulele suite approximately 20 km south of Viti Levu and the 3.4 Ma Astrolabe suite approximately 75 km further south. Shoshonite suite lithologies with 3.8–3.0 Ma ages also occur in the Lomaiviti islands between Vatu-Cake and Moala, to the east of Viti Levu, defining a trend oblique to the NE–SW shoshonite belts. Seatura, a 3.3–2.8 Ma ocean island basalt (OIB) volcano, sits at the northern end of the Lomaiviti trend shoshonites. Trace element/isotopic chemistries indicate that shoshonite arc magma genesis involved the melting of a hydrated supra-subduction zone mantle wedge and also a lower mantle-derived plume (OIB) component. The upwelling plume provided heat for melting and possibly Au enrichment. Accessing the melt generation zone associated with the plume required a slab conduit or window. Such slab windows form by tearing during subduction or occur at slab edges. Adakites form by plume-induced slab melting. The four NE–SW Fijian shoshonite suites are interpreted to occur in back-arc extensional zones above a slab window (tear) that migrated southward during rollback of the New Hebrides–Vanuatu subduction zone. The plume (Seatura OIB) that is interpreted to have caused mantle wedge melting and formation of the Lomaviti trend shoshonites was focused along the interface between the north-dipping Vanuatu–New Hebrides subduction zone and the west-dipping Tonga subduction zone, which we have seismically imaged at approximately 400 km depth. Our model ‘cracks the metallogenetic code’ for shoshonites and adakites and has regional and global implications for Au exploration.CITATION:Collerson, K, Lal, S, Williams, Q and Rost, S, 2015. Cracking the metallogenetic code for Fijian epithermal gold mineralisation , in Proceedings PACRIM 2015 Congress, pp 219–226 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015