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By G. P. Gladis, R. H. Atkinson

PALLADIUM has been used for jewelry for many years, particularly in conjunction with gold. This use increased in amount during the war, as palladium and gold were only moderately used for war purposes while demands for platinum and some of the other members of the platinum group were so great that their use in jewelry was prohibited. Palladium hardened with a small percentage of ruthenium has the necessary technical properties and appearance for good jewelry, and it is sufficiently rare to be desirable for luxury items-at least 100 times as rare as gold. Although both visual and spectrophotometric examination demonstrated that the color of palladium was almost the same as that of platinum, a few jewelers found the surface of palladium, even after some polishing, rather dark in areas that had been repeatedly heated during the soldering necessary to assemble certain types of handmade ornaments. This phenomenon is not to be confused with the thin, bluish oxide film that can be produced by heating in air over the range 400° to 800°C., as that film is easily reduced by dipping in warm 5 per cent formic acid or in warm methanol. It was suspected that the difficulty arose from heating in atmospheres that were alternately oxidizing and reducing, as Wise and Vines1 had found that this opened the grain boundaries of palladium and palladium-silver alloys in the same manner as in pure silver, as reported by Martin and Parker.2 This damage is caused by the reaction between oxygen in solid solution in the metal, acquired when heated under oxidizing conditions, and hydrogen diffusing in from subsequent heating under reducing conditions; the steam cannot diffuse out and therefore builds up sufficient pressure to disrupt the metal near the surface. Copper and various other metals can be damaged similarly, but platinum is nearly immune; therefore the problem was new to the platinum jeweler. Sulphur in the fuel gas also can cause trouble but did not appear to be dominant in the present instance. Metallographic examination of both pure palladium and ruthenium-palladium showed that the usual torch using oxygen and city gas as normally operated did in fact cause the surface and subsurface damage that had been observed, and also disclosed that a reducing flame caused more damage than an oxidizing flame and was very damaging even in the absence of any intentional swing in atmosphere from oxidizing to reducing (Fig. 7); besides the surface damage, there was serious loss of ductility. A full explanation of the mechanism of attack is not evident at the moment, but may be allied to the attack that occurs on heating catalytically active metals in nonequilibrium atmospheres.

Jan 1, 1946

By Mario Giavani

"IntroductionBy the 1980s, the continuous casting process had almost replaced the ingot casting of steel in Japan, Europe and North America. While economic benefits were probably initially the prime motivator, the transition rapidly proved that continuous casting in conjunction with ladle metallurgy offered a much greater degree of process control and made possible routine steel specifications not previously available.This new technology demanded improved procedures for the quantitative addition of the required metallurgical reagents, especially as regards the more volatile or toxic elements such as calcium , boron, carbon, sulphur, lead and tellurium. The injection of a thin steel tube containing the additive into the metal bath of a ladle refining station offers the best procedure for this. In the industry this has been referred to as ""Cored Wire "".Operators using this technology find that they are faced with balancing the injection speed against the small cross section of the tube to feed the required amount of reagent within the short time span available to the operation. Large-ladle shops requiring major quantities usually resort to multiple machines and high speeds. Many machines approach a maximum feed rate of 400 m/min. Higher speeds exceed the melting rate of the system, and the ferro static buoyancy of the tube will cause it to coil up the ladle wall and possibly resurface into the slag layer, and even eject itself above the surface. Under these conditions, exact control of element recovery becomes difficult, especially with the commonest addition, calcium silicon alloy.Many experts are persuaded that the final melting position of the carrier tube has major importance in establishing consistent element yield to the bath.For instance, the vapour pressure of calcium at l500 °C is close to I bar. Reaching a melting depth sufficient to accommodate this value is considered to be critical to achieving an acceptable and reproducible yield.Many studies have elaborated semi-empirical formulae to establish the melt zone depth, connecting this value essentially to the diameter of the tube , the injection rate and the superheat of the steel. The author's experience in steelmaking could not confirm such formulae in many cases, and he set about to develop a mathematical model which would be useful in addressing this problem, taking into account the several parameters which will regulate the behaviour of a filled tube immersed in molten steel."

Jan 1, 1991

By Ben Habermann

"The object of the work described in this paper was to increase the understanding of the relation that capillary pressure of a rock, hydro-dynamics, and accumulation of oil in stratigraphie traps have to one an-other. The hydrodynamic oil-water tilt equation is derived by considering the two vector gradients involved: (1) buoyancy of oil in water and (2) hydraulic gradient.Recent theories show the necessity for oil to have a continuons phase in the reservoir rock in order to mi-grate; this fact applies to hydro-static as well as to hydrodynamic conditions. Hydrostatically, the displacement pressure of the rock deter-mines the amount of oil that can be trapped behind a permeability barrier. If the buoyancy of oil in water exceeds the displacement pressure, oil will migrate up-dip; an oil trap will be formed where displacement pressure is greater.In stratigraphie traps the pressure drop caused by moving water is positive when its direction is down-dip, helping accumulation; and it is negative when its direction is up-dip, forcing the oil into the tighter section of the reservoir. Theoretically, pro-vided we have data such as: (1) the displacement pressure of an up-dip permeability pinchout, (2) density difference between the oil and water in place, and (3) the direction and magnitude of the hydrodynamic gradient (if any), the possible extent of a stratigraphie oil accumulation down-dip can be predicted.To test the above theory sample cores from three wells in the Denver Basin were analyzed and the oil column that could be held under hydro-static conditions was calculated. After the hydrodynamic influence was considered, the results were compared with actual field data.The significant fact shown by this investigation is that the calculated oil column in one reservoir very closely approximates the actual extent of the oil column in a well. Also in accordance with the theory, the capillary pressure caused by the buoyancy of the oil column exceeded the measured displacement pressure on core samples from another productive field. For very tight shaly sand and questionable oil shows, the interpretation of data is very critical, as shown by experiments on core samples from a third field."

Jan 1, 1960

By M. Mentser

The exchange of oxygen between carbon dioxide and carbon monoxide that occurs reversibly on carbon surfaces was studied at temperatures of 750° to 850°C and a pressure of 1 atmosphere. Carbon-14 was used to detect and measure the exchange reaction. The extent of oxygen exchange was a linear function of com- position of the gas mixture, and this relationship was used to evaluate the forward and backward rate constants of the reaction. Equilibrium constants, directly determined for oxygen exchange in this study, agreed well with values in the literature that were derived only by indirect procedures. This result establishes the validity of oxygen exchange in the mechanism of carbon gasification by CO2. Rates of carbon gasification were less than an order of magnitude slower than rates of oxygen exchange. Activation energies for these two processes were 58 and 53 kcal/mole, respectively. The closeness in the activation energies argues against any change in the rate-controlling step over a wide temperature span at atmospheric pressure. The role of CO as a retardant on the CO2-C reaction, and the nature of the carbon-oxygen complex are also discussed in view of the data obtained.

Jan 1, 1973

By Y. Mori, K. Kawanaka

The permeability changes during the sintering of the feed for the Imperial Smelting Process (ISP) were investigated using an experimental sintering pot, as well as with a mathematical model. The results obtained were as follows. The blowing resistance in the sintering bed changes as the sintering reaction proceeds. It increases at the beginning of the reaction when the temperature of the bed is still low. Then it decreases as the reaction continues, accompanied by an increase of the bed temperature. The increase of the blowing resistance in the bed during the sintering process mainly occurred in the drying zone, and was comparatively small in the reaction and cooling zones. Based on Erugen's equation, the change of the permeability during sintering is explained by the decrease of the apparent fractional void volume in the drying zone of the bed.

Jan 1, 2000

By Thornber MR, Davidson LR

The cause of spontaneous combustion of pyritic black shale has been studied by calorimetry and other techniques. The conditions required for ignition to occur are: 1. A critical mass of pyritic black shale. 2. Acidity. 3. Fine shale particle size. 4. A high ambient temperature. 5. The exclusion of air during the preparation of a calorimeter charge. The reaction is characterised by an initial incubation period during which an unknown phase is produced. The build up and oxidation of this phase results in a chain reaction culminating in ignition. The mechanism is believed to involve the interaction of pyrite, sulphuric acid, ferrous sulphate, or meta-stable oxysulphates, with ammonium nitrate. The recommended strategy for prevention of premature detonation is to neutralise the acids in the shale with quick and slow release alkaline materials.

Jan 1, 1986

By Boyd Dudley

THE material presented in this paper is an abstract of a thesis submitted by the writer to the faculty of the Massachusetts Institute of Technology, as part requirement for the degree of Master of Science. The investigation was undertaken at the suggestion of Prof. H. 0. Hofman, and it was conducted, under his direction, in the laboratories of the Mining Department of the Institute. The purpose of the work was, first, to study some of the reactions that have been considered as a part of the mechanism of the chloridizing roast, and second, to study the conditions under which nickel oxide and copper oxide may be chloridized. While the production of chlorine gas by various reactions during the chloridizing roast may not be primarily useful in the chloridation of metal oxides and compounds, it nevertheless serves a useful purpose in preventing the dissociation and decomposition of chlorides once they have been formed; for example, the dissociation of cupric chloride into cuprous chloride and chlorine. Therefore it was thought that a study of some chlorine-producing reactions would prove of interest, and the first series of experiments dealt with this phase of the subject. The object of the latter part of the work was to show the possibility of treating heavy sulphide ores, such as those of Sudbury, Ontario, containing much iron and small amounts of copper and nickel, by chloridizing and removing the copper, leaving an iron-nickel oxide product suitable for smelting in the blast furnace for nickel-bearing pig iron. The chloridizing of the copper would, of course, be preceded by a roast for the removal of sulphur, the sulphur oxides being available for the manufacture of sulphuric acid, if under the local conditions this product would be of commercial value.

Jan 12, 1914

Discussion of the paper of BOYD DUDLEY, JR., presented at the New York meeting, February, 1915, and printed in Bulletin No. 96, December, 1914, pp. 2767 to 2782. H. 0. HOFMAN, Boston, Mass.-At the close of the paper Mr. Dudley said that his experiments in the laboratory had shown that it was possible to separate nickel from copper by means of a chloridizing roasting, but that in order to demonstrate a process of this kind, work upon a large scale would have to be carried out. I think it was in 1913, that experiments of this kind were carried out at the works of the Pennsylvania Salt Manufacturing Co., Philadelphia, in a Wedge furnace, and at Sault Ste. Marie in a Sjöstedt furnace. They showed a satisfactory separation of nickel and copper. The ore was first subjected to an oxidizing roast, then mixed with pyrite and salt, and given a chloridizing roast. A. H. Carpenter published in the Engineering and Mining Journal, vol. xcvii, p. 1085 (1914) the details of this work. The conclusion arrived at is, that if you subject sulphide ore to an oxidizing roast, finishing at the temperature at which all nickel sulphate is dissociated, i.e., 764° C., then mix it with pyrite and salt, and subject the mixture to a chloridizing roast between 600° and 700° C., you can chloridize a high percentage of the copper without chloridizing any of the nickel, and obtain thereby a satisfactory means of separating the two.

Jan 5, 1915

By Gudrun A. Saevarsdotti

For decades tile aluminium industry has been practicing gas treatment of aluminium melts. This treatment is of great importance because of its influence on 'impurity" and inclusion removal from the melt. The gas-melt interaction is greatly influenced by the gas composition, melt temperature etc. This paper gives an overview of the interaction between argon-chlorine gas mixtures and the aluminium melt. It covers the thermodynamics of the reaction between the chlorine and a number of different elements commonly found in liquid aluminium, and discusses the behaviour of reaction products in the melt. The paper reports an experimental study of the behaviour of the chlorine-molten aluminium interface, using sodium contaminated aluminium melt with and without the addition of grain refiner.

Jan 1, 1996

By G. Ahuja

Tests were conducted to investigate the effects of cyclone geometry, operating conditions, and particle size on magnetite classification. The effects of these parameters on the partition curve for narrow size fractions were studied using a 25mm diameter cyclone cleaning -150 µ m coal. Additional tests were run to investigate the effects of geometry and operating conditions on the slurry, solid, and water splits. The relationship between the relative density of the underflow stream and the relative density of separation was also investigated. This paper presents the results from this study.

Jan 1, 1994

By Shoobridge PH

Operating difficulties during 1977 with the Imperial Smelting Furnace operated by Sulphide Corporation Pty. Limited at their Cockle Creek zinc-lead smelter were found to be caused by premature softening of sinter in the upper shaft of the furnace. This soft- ening was shown to be a consequence of raw materials and operating policies which led to unusually high levels of both lead and silica in a sinter of low basicity. A programme of softening tests and micro-examination of a range of sinters established that premature softening occurred when lead and silica increased to the point where a lead-calcium silicate with a low lime content became the major continuous phase in the sinter. This information was used to define a range of compositions which kept the softening temperature acceptably high for furnace operations.

Jan 1, 1978

By Walker G. S

A study of the crystalline materials on or near the surface of freshly made or "green" superphosphate granules and mature, "set" superphosphate granules was undertaken using X-ray diffraction, X-ray mapping, scanning electron microscopy and electron probe micro analysis techniques. Calcium sulphate (CaSO4), calcium sulphate hemihydrate (CaSO4 1/2H20), and mono calcium phosphate monohydrate (Ca(H2PO4)2H2O), were the only crystalline species present in the "green" superphosphate.In the set superphosphate however, additional compounds were present, namely complex iron and aluminium phosphates Ca(Fe,AI) H(HPO4hF2)2H2O, (Fe)3(H3O)H8 (PO4)6H2O and calcium sulphate dihydrate (CaSO4.2H2O).The complex phosphates tied up the major part of the Fe and Al in the system and were concentrated on or near the surface of the granule. An intimate mixture of CaSO4.2H2O, and CaSO4, along with the above mentioned complex Fe-AI compounds, crystallize close to the surface of the granule and cause the setting of superphosphate that takes place during storage.

Jan 1, 1980

By Larry D. Lawrence, Gerald W. Greenway

Corrugated boxes have been the dominant shipping container for packaged commercial explosives for the past 3 decades. Recent changes in shipping regulations have dictated to the industry the adoption of enhanced standards dealing with the construction of fiberboard shipping containers for explosives. Effective October 1944, all shipping containers used for explosives will require individual certification verifying that the containers conform to the United Nations performance oriented packaging standards. The U.S. Department of Transportation will continue to enforce compliance to the new UN standards. A renewed emphasis on the design of corrugated shipping containers to insure industry compliance to the UN standards has been a joint development program between the explosive manufacturers, fiberboard container suppliers and the academic community. Along with drop strength, leakproofness, and vibration resistance, the individual stacking strength of corrugated shipping containers has come under tight scrutiny based on the new UN standards.

Jan 1, 1994

By A. M. Rahm

PROBABLY the majority of red brass sand castings are judged merely on the basis of outside appearance and the quality of machined surfaces. Many castings, however, must individually withstand a hydraulic or air-pressure test before being accepted as parts of more complicated machin-ery. Finally, there remains a comparatively small group of castings intended for uses of considerable responsibility where only the highest possible characteristics of the metal are acceptable, and for these specially cast test bars are required. The shape of the cast piece from which the test bar must be detached varies greatly from one country to another. The test bar as specified in the American Society for Testing Materials Specification B62-36 is widely used by the American foundry industry. The actual test piece is at the bottom of the cast block and has a riser about six times its mass. It is obvious that this test bar has an advantage over the actual casting. The latter rarely possesses a riser of as much as 30 per cent of its own weight and that riser cannot generally be located in so convenient a manner. Therefore, the characteristics of the test bar cannot possibly correspond to those of the casting itself. It must be taken into consideration that red brass if melted and cast in the best possible manner may show a tensile strength of 40,000 lb. per sq. in. with 35 per cent elongation in 2 in. Such a test bar would indicate that the metal was nearly perfect from the viewpoint of its gas and inclusion content. Barring some accidental defect, a casting cor-responding to such a test bar could be accepted as being quite sound. However, actual specifications do not demand such high characteristics; indeed, few specifications require over 30,000 lb. per sq. in. and 20 per cent elongation, while one Federal specification demands merely 27,000 lb. per sq. in. strength and 15 per cent elongation. It is obvious that

Jan 1, 1939

By Page-Shipp. R. J., Elizabeth Harris

A study of the response of South African white gold miners to exposure to dust in their working environment yielded large quantities of dust data. Analysis of this data (presented in summarized form) reveals a variety of interesting relationships, including the shift-long exposure of different occupational groups, the dust levels due to various mining operations, relationships between different dust-measuring procedures and time trends in dust levels during the shift. The statistical probability of contracting silicosis at various levels of exposure to this dust is reported briefly. A new method of using microscope counts to estimate the respirable mass of dust samples is given in an appendix.

By T. Airaksinen, R. T. Hukki

A new static pneumatic classifier for the primary separation of the feed material for microclassification is discussed. Pilot plant test results and a novel flowsheet for microclassification at the industrial scale are presented.

Jan 1, 1980

By A. A. Kornyshev, M. Burstein, S. T. Hall

The surface "roughness" of mineral particles has long been known to influence the fundamental process of particle-bubble attachment and other subprocesses in froth flotation. The physical nature of the surface of fine mineral particles can be analysed by determining their fractal geometry. A number of techniques are available to measure the fractal properties of mineral particles, these include gas adsorption, mercury porosimetry, neutron or X- ray scattering and image analysis. From the resultant Richardson plots or their Fourier-space analogs, the fractal dimension of flotation feed and product samples can be determined. Textural characteristics of particles have an influence on the stability of 3-phase flotation froths and the selectivity of recovery in the froth. Decrease of the equilibrium froth height for particles of higher fractal dimensions was experimentally established. The induction time of quartz particles of different fractal geometry has also been studied.

Jan 1, 1995

By J. A. Maritz, D. F. Malan

Pillar strength is affected by pillar shape, but this has largely been ignored in past research studies. Bord-and-pillar layouts are typically designed using empirical strength equations developed for square pillars. Owing to the poor quality of pillar cutting, many hard-rock pillars have an irregular shape and it is not clear how this affects pillar strength. Furthermore, the strength of rectangular pillars in comparison with square pillars is also difficult to quantify. The ‘perimeter rule’ is widely adopted for rectangular pillars, but its applicability for pillars with irregular shapes has never been tested. We used numerical modelling in this study to investigate the effect of pillar shape on strength. An analytical limit equilibrium model of a square and a strip pillar also provided useful insights. For slender pillars, the strength of a long rib pillar is essentially similar to that of a square pillar. In contrast, for rib pillars with a large width to height ratio, there is a substantial increase in strength. The study found that the perimeter rule should not be used for irregularly shaped pillars. Displacement discontinuity modelling, using a limit equilibrium approach, is proposed as an alternative to determine the strength of these pillars.

May 3, 2023

Attempt has been made to determine the nature of charge on activated carbon surface by studying the electro-kinetic properties of the carbon in the presence of cations, anions and aurocyanide solutions. The zeta-potential measurements were made in the presence of individual ions and also in combinations. The cations and anions chosen were those commonly associated with gold bearing ores in Kalgoorlie area. It was found that the iso-electric point of Norit Carbon was at pH 4.45; below this pH the charge was positive, while above, it was negative. In the absence of gold cyanide solutions and in the presence of individual cations the i.e.p. shifted to the alkaline range (pH 7.2-8.5) while in the presence of anions the i.e.p. was shifted to less than pH 3.5. In the presence of aurocyanide solutions, the iso-electric point was still in the acid region irrespective of whether anions or cations were present. The probable mechanism for such a behaviour has been attempted after measuring the specific conductivities of solutions before and after gold adsorption, by studies using the electron- probe-mirco-analyser, and S.E.M. on the carbon surface.

Jan 1, 1982

By A. L. Painting

A study of the end effects in specimen cores under compression tests, with a view to the elimination of these effects by A. L. PAINTING (Student) It is well known that a cylindrical rock specimen tested under uniaxial compression in conventional fashion is subject to end effects; that is, towards the end of the core, the stress and strain distribution becomes non-uniform. The experiment described illustrates such end effects with an aluminium core between steel platens. An attempt was then made to nullifythese effects by compressing the core between pads of mercury. The resulting stress and strain distribution was significantly more uniform, but a slight over-correction was introduced.

Jan 4, 1974