Search Documents

By C Bie, S Li, P Xiao, P Zhao, H Lin

"Based on solid simulation material research, the simulation conditions for methane and coal solid-gas coupling were obtained using solid-fluid coupling theory. Using sand as the aggregate and paraffin and oil as the cementing agents, a material suitable for solid-gas coupling simulation was developed. A permeability testing instrument was also developed, and the compressive strength, brittleness parameters and seepage velocity of material were tested with different aggregates. The results showed that as the paraffin content increased, the compressive strength of the material increased but the permeability decreased. The oil removed the drawback of intensely changing material compressive strength. By setting a different ratio of aggregate to cementing agent, it can simulate rocks with different strengths and permeability. Applying the material to a mining simulation experiment revealed a relationship between methane seepage velocity and overlying strata movement. By extracting pressure relief gas from Shanxi Tianchi coalmine drainage, the authors found that the mining fissure zone was a storage area of pressure relief gas, and a gas drainage system can be placed to achieve good results. CITATION: Li, S, Zhao, P, Lin, H, Bie, C, Pan, H and Xiao, P, 2015. Character of simulation material of coal – rock and gas solid-gas coupling and engineering application, in Proceedings The Australian Mine Ventilation Conference, pp 105–110 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 31, 2015

By George Riter

OUR mineral-land laws need revising so as to provide definite title at the outset to the mineral deposits within any definite piece of land. The laws as they now stand, especially those applicable to lodes, breed uncertainty as to rights of possession prior to patent; and to my mind this is the worst feature of all, worse even than the apex bugbear. It is now almost impossible for anybody to tell with certainty what mineral rights exist within any area that is not covered y patent, or whether any valid rights exist at all. Our system is unique in permitting individuals to appropriate and exploit mineral lands of the public domain without notice of any kind to the Federal government, and to relinquish them without any ceremony at all. The result is a clouded record that cannot be cleared' up until each claimant is put to some sort of final proof. In order to accomplish this, new Federal legislation will be required. The requirements for a mineral survey and the proceedings for patent have always been cumbersome and expensive; and perhaps out of regard for the poor claim owner, who can ill afford the outlay for that sort of thing, the law does not require him to go through it unless he chooses to do so. Consequently, every active mining district has become encumbered with tangled groups of doubtful or conflicting locations, whose rights and boundaries, when any valuable ore is found, must usually be determined by lawsuits that are as expensive and as distressing as the stakes are high. So deeply has litigation entered into our mining system that a claim whose rights have never been disputed would probably be set down offhand, y a miner of the old school, as of no value. Think of the litigation over rights of possession on the Comstock lode-12 leading companies involved in an aggregate of 245 suits within a period of less than eight years! Ambiguous local records; the chance of erroneously placed or obliterated monuments; doubt as to the sufficient performance of the statutory annual labor; uncertainty as to prior conflicting or overlapping locations; anxiety as to the changing attitude of the Department of the Interior and the Forest Service-such considerations as these make an unpatented mining claim an unclean thing in the eyes of possible investors. Is it any wonder that they keep themselves and their money at a safe distance,

Jan 7, 1914

By George H. Ashley

Character The bituminous coals of Pennsylvania range from low volatile to high volatile, but are all low moisture coals The coals are of three types caking of coking, noncaking or splint, and cannel The percentage of volatile matter in all kinds changes from low at the east to high at the west This change is thought to be due to the pies sure and folding to which the coals along with the other rocks have been subjected In the Broad Top field, and in Somerset, Cambric, Clearfield, Centre, and other counties to the northeast, most coals contain from 3 to 5 times as much fixed carbon as volatile matter, the fixed carbon ranging from 67 to 75 per cent, and the volatile mattes from 16 to 24 per cent These coals are classed as lovol coals In the line of counties just west of those listed the coals are of the medium volatile class (midvols) This includes the famous Connellsville coking coal Still farther west, covering most of Washing ton and Westmoreland counties, and the counties to the north of them are high volatile coals of gas coals (hivols) This is discussed in Part I on the geology of the coals of Pennsylvania, where is given in isocaib map Cannel coals ale found in many par is of the bituminous coal field of Pennsylvania, but in particular in Beaver Butler, Armstrong, Indiana, and Clear field counties The cannels of Beaver and Butler. counties are typical high volatile cannels, many of which have been used in times past for oil distillation The cannels of Armstrong and Indiana counties are medium volatile cannels, and while main taming the physical character of cannels, have no more volatile neat ten than the coals around them The cannels of Clearfield County tie low volatile Splint coals of noncakmg coals are not abundant in Pennsylvania. The Sharon coal, formerly mined in Mercer County, was a noncaking or splint or block coal, and was formerly used in the raw state in non smelting Uses STEAM COAL Practically all of the coals of Pennsylvania are steam coals, though many coals in the Commonwealth, because of high ash, are not good steam coals The coal of the Pittsburgh district has long been famous

Jan 1, 1928

By C Yeung, N Swa, D Gribble, R Reupana

BlastLiteÖ is a low density explosive developed by Dyno Nobel and has been in use at BHP Billiton Iron OreÆs Mt Whaleback Operation since March 2004. The Mt Whaleback Operation utilises BlastLite because it offers an attractive alternative to ANFO in soft to medium strength rock types. Its use also reduces the amount of liquid fuel oil consumed and is well aligned with BHP BillitonÆs corporate Energy Excellence initiatives to reduce greenhouse gas emissions. This paper presents the:results of characterisation work completed on-site as a fourth year mining engineering thesis, and application and benefits of the product at Mt Whaleback. One of the key features of low density products is that the detonation is non-ideal. That is, the explosive does not react fully in the detonation driving zone. This manifests itself in that the product is highly dependent on charge diameter and confinement conditions. Dyno Nobel has access to the Vixen suite of detonation codes for characterising the ideal and non-ideal behaviour of explosives. The objectives of this work were to use the Vixen_i code to characterise the detonation performance of BlastLite, in order to understand the role of the bulking agent and to allow modelling of the explosive. The detonation performance was established by detonating a series of unconfined charges at various diameters and measuring the velocity of detonation (VoD). The work program consisted of sourcing and preparing cardboard tubes of various diameters (80 mm to 305 mm). The tubes were loaded with explosive at the BHP Billiton Iron Ore Mt Whaleback test range and detonated one at a time. Over the past three years BlastLite has been used in various applications across the site. Initial findings illustrate that shovel productivity from BlastLite shots was comparable to the baseline ANFO blasts. The study results were also backed with visual inspection and feedback from shovel operators. A work program is currently in place to develop different blends of BlastLite and TITAN« BlastLite to tailor the explosives to various blasting applications. The trials at Mt Whaleback are leading to future opportunities of BHP BillitonÆs satellite orebodies.

Jan 1, 2007

By S Kakara, A Kamaraj, S S. Varanasi, B V. R Mandalika, M B. Shaik

The properties of top slags play a very important role in secondary steelmaking. Fluxes should be chosen based on the ladle furnace (LF) slag requirements like viscosity, melting temperature, sulfide capacity, etc. CaF2 and CaO-Al2O3-based synthetic slags are the most used fluxes in secondary steelmaking to improve slag fluidity and interfacial chemical reactions. CaF2 is obsolete due to fluorine pollution and CaO-Al2O3 based slags have 40–50 wt per cent Al2O3 and 30–40 per cent CaO which is not beneficial for desulfurisation. Yet another drawback is that LF slag disintegrates into fine powder during cooling due to phase transformation C2S (2CaO.SiO2). Hence, there is a need for the development of low melting fluxes with high CaO content and the capability to prevent slag disintegration. The current work studied the effect of 0–9 wt per cent B2O3 on physico-chemical properties and characterisation of LF slags. X-ray diffraction (XRD) analyses were carried out to identify mineralogical phases present in slag and Fourier-transform infrared spectroscopy (FT-IR) analysis was done to understand the changes in bonds of B2O3 added LF slag. The characteristic temperature of slag was determined by a hemispherical method using high-temperature microscopy. Empirical models were used to calculate viscosity, break temperature, and sulfide capacity. FactSage™, ver 8.2 (by GTT-Technologies) simulations were carried out to find the equilibrium phase fractions and percentage of liquid slag at different temperatures. New phases such as Ca11B2Si4O22 and Ca2B3O5 were formed in LF slag with B2O3 addition. Based on the results, 0.5–1.0 wt per cent B2O3 was found to be sufficient to prevent C2S-driven disintegration of LF slag. Also, the melting temperature and viscosity of LF slag were reduced by adding 3–8 wt per cent B2O3 due to the formation of BO3 planar triangular structure and low melting eutectics in slag. Liquid slag started forming at a temperature as low as 800°C when B2O3 is >6 wt per cent. It was found that the sulfide capacity, viscosity, and break temperature of the slag decreased with increasing wt per cent B2O3. Based on the analysis carried out, B2O3 can be a promising fluxing material in secondary steelmaking, for improving the desulfurisation kinetics and valourisation potential of LF slag.

Aug 21, 2024

By P K. Banerjee, S Kumar

Indian iron ores with less than 62 per cent Fe are currently unexploited, except for a few sectors which export them to foreign countries. It is anticipated that by 2012 the countryÆs domestic steel production is likely to rise to the tune of 60 million tonnes per annum. To meet this requirement, it is necessary to utilise not only the existing high-grade deposits but it is also necessary to look into exploiting the leftover iron ores of lower grades. Hence, reserves with Fe content 62 per cent and below (particularly the ores with In the present paper, an attempt has been made to beneficiate three different types of low-grade iron ores selected from three different parts (states) of the country. In the paper, alternative routes for beneficiation and effective utilisation have been tested using different techniques in the laboratory in an attempt to match their (Al2O3/SiO2) ratio after thorough characterisation and liberation studies. The paper also encompasses the geological formations, occurrences and distribution of Indian iron ores as well as highlighting the problems associated with the fines, possible metallurgical routes, and their market segregation from the perspective of end users.

Jan 1, 2007

The investigation of Noapara glass sand deposit in Sylhet district of Bangladesh is performed to beneficiate the sand for the manufacture of colourless glass. For the ease and efficient removal of the colour bearing impurities, the physical and mineralogical investigations of the sand deposits is carried out first. The sand is then treated with the standard beneficiation procedures to reduce the impurity level to an acceptable level. It is found that the Noapara glass sands are of medium grained and moderately sorted. They contain 0.15 - 0.30 per cent Fe2O3 and 0.001 -0.008 per cent Cr2O3 as major colour bearing impurities. The heavy mineral fractions containing most of the impurities can be grouped into five types of associations:stable or ubiquitous minerals (tourmaline, zircon, rutile); metamorphic species (staurolite, kyanite); amphibole minerals (hornblende, tremolite); the micas (muscovite, biotite); and discrete minerals (magnetite, ilmenite, etc). It is also seen that, the use of mechanical separation process in combination with water washing, attrition, and magnetic separation can remove a maximum of only 70 per cent of total Fe2O3 present in the deposits. This is insufficient to produce the specified grade of sand to manufacture colourless glass. Among the various chemical treatment processes used, sodium dithionite method is found to be the most effective, although the discrete minerals are not removed. Using the specific reagent group during froth flotation, the iron and chromium contents are reduced to 0.03 and 0.001 per cent respectively which are very near to the specified colourless glass composition.

Jan 1, 2000

By B Wu, C Zhao, B Lei

At present, the friction factor is calculated by measuring pressure drop and airway configurations. However, the workload of on-site measurement is heavy, and the measurement results are easily disturbed by the external environment. In order to meet the need of intelligent ventilation to quickly and accurately obtain the friction resistance of roadway. Based on the important of roughness in Atkinson friction resistance formula, in this paper, fractal theory is used to characterise the 3D rough surface, and a method based on fractal dimension to describe the roughness of roadway surface and calculate the friction resistance was proposed. A computational model of friction resistance for fractal characterisation of roadway 3D rough surface was established. The parameters of the model were deduced and verified by using Nikuradse experimental data. The fractal dimension of roadway surface was calculated by 3D laser scanning data of Kailuan roadway, the established friction resistance calculation method was compared with the field resistance measurement results. It is considered that the calculation method of friction resistance based on fractal theory is reliable and can well represent the influence of 3D rough surface characteristics of roadway. The result show that the new established friction resistance formula compared with the traditional Atkinson formula in Nikuradse experimental, the average relative error is 6.874 per cent, and compared with the measured results of ventilation resistance in Kailuan experimental roadway, the relative error is 6.667 per cent. Comprehensive evaluation and analysis suggest that the new formula can well reflect the influence of 3D rough surface on friction resistance, combined with 3D laser scanning technology, the friction resistance of roadway can be calculated quickly and accurately. This research provided a reference for the key technology and theoretical development of intelligent ventilation parameter measurement.

Oct 12, 2022

By Y Li

An ilmenite ore from the Murray Basin was initially characterised using combined X-ray Fluorescence Spectroscopy (XRF), X-Ray Diffraction (XRD), Scanning Electron Microscope (SEM) and Electron Probe Microanalysis (EPMA) techniques. XRF analysis showed the ilmenite sample contained 58.7 wt per cent TiO2 and 26.2 wt per cent Fe2O3. Major impurities included: Cr2O3 (4.5 wt per cent), Al2O3 (2.7 wt per cent), SiO2 (1.9 wt per cent), Mn3O4 (1.5 wt per cent) and MgO (1.1 wt per cent). Manganese and magnesium were present as solid solution components within the ilmenite lattice while the elevated Al2O3 and SiO2 levels were due to separate aluminosilicate gangue minerals. Chromium was associated with discrete chrome spinel gangue phases of variable composition, (Fe,Mg)(Cr,Al)2O4. Quantitative XRD analysis of the sample identified rutile (12 per cent), ilmenite (11 per cent), and pseudorutile (67 per cent) as the main titanium-containing phases and chrome-rich spinels (seven per cent) as the major impurity phase. Minor quartz, aluminosilicates, zircon and monazite were also present. The ilmenite was mixed with synthetic graphite, pressed into pellets and reduced carbothermally in nitrogen at 1200 and 1400°C with C/O molar ratio of 1.2. Titanium oxide in the ilmenite was converted to titanium oxycarbonitride. Iron oxides were reduced to metallic iron. The Changes of impurities as a result of reduction was examined by SEM and EPMA analyses. Iron and chromium oxides within Fe-rich chromite were reduced to form a Fe-Cr-C alloy. Mg-rich chrome spinels were partly reduced at 1200°C. Zircon particles were not reduced at 1200°C, but were significantly reduced at 1400°C, with the particles becoming porous and the silicon being removed.

Oct 5, 2011

By R P. Bewick

Many future and current block and panel caves extract ore from veined rock masses. These rock masses are composed of open joints forming blocks or rock with healed networks of veinlets. These two types of discontinuities pose a challenge for rock mass characterisation and classification due to difficulties in distinguishing actually open joints from healed but weak veins when diamond core drilling and excavation blasting practices disturb the rock mass. The inability of separating characteristics of open joints and healed veins has often resulted in an underestimation of the rock mass quality and as a consequence led to inappropriate assessments of rock mass response to mining (ie rock mass behaviour) and consequently deficient excavation stability assessments and ground support designs. In this paper, guidelines are provided to improve the characterisation and classification of veined rock masses. It is shown how veined rock masses can be mischaracterised resulting in often incorrect forecasting of rock mass behaviour. Following this, the classification of veined rock masses is examined. It is shown how the primary classification systems (ie Q – Barton, Lien and Lunde, 1974; rock mass rating (RMR) – Bieniawski, 1976) may not lead to reliable ratings in veined rock masses if care is not taken to differentiate between open joints and veins of varying strength. Examples are provided to illustrate how the Q and RMR systems are insensitive to veining. Finally, an example of characterising a veined rock mass for design purposes is presented.CITATION:Bewick, R P and Kaiser, P K, 2016. Characterisation and classification of veined rocks for rock mass behaviour assessment, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 825–834 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

By D J Rawlings

The Palaeo- to Mesoproterozoic McArthur Basin contains a thick (-10 km) intracratonic platform cover sequence of unmetamorphosed and relatively undeformed sedimentary and volcanic rocks (Pietsch et al, 1991). It covers an area exceeding 180 000 km2 of the North Australian Craton (Figure 1), overlying segments of the older deformed basement and transitional igneous units. Volcanism in the basin (including transitional domain) followed a four-phase pattern. These phases are geologically distinct and widely distributed, and are also recognised beyond the McArthur Basin in many similar-aged tectonic provinces in northern Australia. The four phases are described briefly below. Regional and structural nomenclature used refers to Figure 1. A stratigraphic correlation diagram is presented in Figure 2.

Jan 1, 1994

By F. A. Charalambous

Brannerite is commonly referred to as a refractory uranium mineral as it is usually highly resistant to acid leaching. There is however widely varying literature data on brannerite leaching, with some studies reporting that brannerite leaching can be achieved under relatively mild conditions. The differences observed for brannerite leaching are most likely due to the high degree of variation in the composition and structure observed in natural brannerites. These aspects of brannerite chemistry however are not very well understood due to a lack of fundamental research. The aims of this study were to investigate and develop methods for synthesising brannerites of varying composition and to investigate the effects of composition on brannerite leaching in acidic conditions.

Aug 1, 2010

By K. Barbetti, J. Avraamides

"The processing of gold ores with high silver contents can provide operational challenges, such as high cyanide consumption, retardation of gold leaching and competition during adsorption stages of carbon-in-pulp/leach/column (CIP/CIL/CIC) circuits. In particular, the silver, which is about 1.5% of the value of gold, competes with gold during carbon adsorption due to its higher concentration in many Ag-Au ores, potentially leading to gold solution losses. Fresh and partially fouled (barren and regenerated) activated carbons were evaluated at various Ag:Au ratios and total metal concentrations with regard to the adsorption kinetics and equilibrium loadings. Conventional Freundlich isotherms were found to be highly inaccurate for predicting equilibrium loadings in the competitive adsorption environment. An integrated model, which incorporates competitive adsorption kinetics with a modified competitive adsorption isotherm model has been developed and validated using plant and laboratory data. The model performance and some of its salient features will be discussed.INTRODUCTIONThe processing of gold ores with high silver contents can present a range of operational challenges, such as high cyanide consumption, retardation of gold leaching and competition in carbon adsorption circuits. Silver is often present at significantly higher concentrations than gold in many gold-silver ores and competes with gold in carbon adsorption circuits, limiting the gold loading rate and capacity, resulting in gold solution losses and reduced gold recovery.Curtin University’s Gold Technology Group has evaluated fresh and partially fouled (barren and regenerated) activated carbons at various Ag:Au ratios and total metal concentrations to determine the adsorption kinetics and equilibrium loadings for gold and silver. Conventional Freundlich isotherms were found to be highly inaccurate for predicting equilibrium loadings in the presence of both gold and silver.An integrated model, which incorporates competitive adsorption kinetics with a modified competitive adsorption isotherm model has been developed and validated using plant and laboratory data. This paper describes the model performance and some of its salient features."

Jan 1, 2016

By R Munoz, R González, J Vallejos, A Delonca

In panel caving in underground mines, it is essential to characterise and monitor the stress and stability state of production level pillars to ensure the extraction of the mineralised ore column and the safety of workers. Pilar Norte is a sector in the El Teniente mine that forms a pillar between the undercut fronts of the adjacent Esmeralda and Reservas Norte sectors. It exists in a high-stress environment, which may induce damage to the rock mass production pillars. Generally, numerical models are calibrated using observed damage in galleries. This procedure does not discriminate between the structural condition and/or the blasting damage effects. This paper proposes a technique that uses borehole cameras to measure stress-induced damage. This has the advantage of being at the intact rock scale, meaning that the effect of geological structures is negligible and the blasting damage factor is eliminated. Comprehensive geotechnical characterisation and tomography monitoring has been undertaken at Pilar Norte to describe and determine the rock mass behaviour of the production pillars. By combining analytical, empirical and numerical models, a correlation between the measured overbreak recorded by the borehole cameras and the stress level of the pillar was developed. The methodology can be routinely applied to estimate the stress state in the production pillars.CITATION:González, R, Munoz, R, Vallejos, J and Delonca, A, 2016. Characterisation and monitoring of the stress state of production pillars at El Teniente Mine, in Proceedings Seventh International Conference and Exhibition on Mass Mining (MassMin 2016), pp 197–202 (The Australasian Institute of Mining and Metallurgy: Melbourne).

May 9, 2016

Characterisation and Processing of Electronic Waste for the Recovery of Metal Values Electronic waste (e-waste), which is a hazardous waste, can indeed be a good source of metal values especially for Cu, Pb, Sn including the precious metals such as Au, Ag, etc. In the present work a protocol for sorting and disassembly of e-waste consisting of computers, TV sets and mobile phones, as well as the characterisation and processing are investigated. E-waste consists of assorted materials consisting of metals, plastics and polymers, ceramics and glass. These components are classified into nine categories. The components, in which metal is embedded into non-metallic base, require complete pulverisation for liberation of the metal. The liberation size is observed to be around 1 mm. Several stages of crushing, shearing and shredding and grinding are required to achieve the required feed size. It is evident from detailed chemical analysis that the pulverised particulate is quite rich in metal values. Computer waste has 23 per cent metal by weight with over six per cent Cu while TV waste has 20 per cent metal with about 4.5 per cent Cu. Mobile phones are much richer in metal content with about 56 per cent metal including 32 per cent Cu in it. Metal content is observed to be more significant in the larger size classes and Pb and Cd are found to be the major contaminants. Morphological studies show that a substantial fraction of the particles is flat or elongated. Based on detailed characterisation, a flowsheet is developed involving dry and wet methods to separate the metallic materials from the plastics physically. It is established that according to this flowsheet a metal rich fraction with over 90 per cent recovery of the metal values can be achieved. Considering the relatively inexpensive unit operations involved in the flowsheet it is envisaged that it would provide a commercially viable scheme for processing large tonnage of e-waste.

Sep 13, 2010

By P. N. Mohan Das, K. Harikrishna Bhat

"The major ilmenite reserves are located in India at Chavara (CH), Manavalakurichi ( MK) and Chatrapur, Orissa (OR). India stands first in terms of ilmenite reserves, which are estimated to be 278 million tonnes out of which, 142 million tonnes are processable. Mineralo-chemical analysis shows that Chavara ilmenite is the most weathered one with about 60% TiO2 while Chatrapur is the least weathered with about 50% TiO2. Co-existence of ilmenite with pseudorutile, rutile and haematite is observed in substantially varying amounts in the three deposits. It is observed that the tropical weathering rather than the source rock difference has apparently played an important role in imparting major compositional and structural dissimilarities among ilmenites in different places.In processing of ilmenite through the Becher process, aeration rusting of pre-reduced ilmenite is found to be the rate limiting step thus, affecting the productivity of the process. Investigations have proved that the addition of some organic compounds such as glyoxal, sucrose etc., to the system accelerates the reaction to such an extent that the rusting time has been reduced to less than half.A new route of processing ilmenite for synthetic rutile has also been developed in which, ilmenite is carbothermally reduced and then processed through plasma route. The slag thus obtained is processed further to get high-grade synthetic rutile, metallic iron and high purity iron oxide. The process has been scaled up in a continuous moving bed plasma reactor. It is technologically and economically more viable where, all the iron values are recovered as salable byproducts. This paper describes the salient features of the technologies developed for the beneficiation of ilmenite to synthetic rutile."

Jan 1, 2003

By P. N. Mohan Das, K. Harikrishna Bhat

"The major ilmenite reserves are located in India at Chavara (CH), Manavalakurichi ( MK) and Chatrapur, Orissa (OR). India stands first in terms of ilmenite reserves, which are estimated to be 278 million tonnes out of which, 142 million tonnes are processable. Mineralo-chemical analysis showed that Chavara ilmenite is the most weathered one with about 60% TiO2 while Chatrapur is the least weathered with about 50% TiO2. XRD and SEM studies of different magnetic fractions of these three mineral deposits established the co-existence of ilmenite with pseudorutile, rutile and haematite phases in substantially varying amounts. It is observed that the tropical weathering rather than the source rock difference has apparently played an important role in imparting major compositional and structural dissimilarities among the ilmenites in different places. Further, the chemical analysis, XRD and SEM characterisation of differently weathered samples of MK ilmenite separated by the magnetic fractionation showed that the degree of alteration was invariably associated with the decrease in magnetism, increase in the rutile phase and the change in Fe2+/Fe3+ ratio of ilmenite grains. Magnetically separated fractions when subjected to metallisation with carbonaceous reductant such as coke showed that the degree of reduction increases with the degree of alteration and with the decrease in the Fe2+/Fe3+ ratio.In the processing of ilmenite through the Becher process, aeration rusting of pre - reduced ilmenite is found to be the rate-limiting step thus, affecting the productivity and economy of the process. Investigations have proved that the addition of some organic compounds such as glyoxal, sucrose etc., to the system accelerates the reaction to such an extent that the rusting time has been reduced to less than half. The formation of acids by the these organic compounds during the rusting reaction was proved responsible for maintaining the pH of the solution in the range 3-4 at which iron hydroxide do not precipitate and block the pores in the reacting surface of the grain."

Jan 1, 2003

By M. Aatach, St. Gaydardzhiev, M. Kadiyski, E. Visariev, V. Stoilov

Detailed process oriented characterisation on representative samples from plant survey of the slag flotation plant belonging to Aurubis, Bulgaria has been realised in order to evaluate the mineralogical occurrences of Cu, Ni, Mo and Co bearing phases. The slag subjected to flotation consisted in majority of fayalite, magnetite-iron oxides and a glass-like phase. Ni and Mo have been found to be closely associated to magnetite and fayalite. The tailing from the slag flotation has been subjected to sulphation roasting followed by water leaching as a hydrometallurgical means to recover the remaining Cu, Mo, Ni and Co. Based on the various sulphation roasting conditions (acid dosage, duration, temperature) copper, nickel and cobalt were brought to solution to a different extent. Molybdenum was the most difficult to be rendered soluble due to its close association with iron, suspected to form an insoluble compound with it. Sulphation roasting performed at 350ºC has secured the best extraction degree for Cu, Mo and Co, while maximum recovery of Ni has been documented when roasting was done at 150°C. Keywords: Copper slag; characterisation; SEM; roasting; metals leaching, hydrometallurgy 16(2), 153–65.

Jan 1, 2020

By Guozhu Ye

"One of the most essential problems associated with the treatment of EAF dust is its high content of halogens. For most thermal processes for zinc recovery, such as the plasma processes with a zinc condenser, the halides in the gas stream will form a dross phase that results in a low zinc yield. For those with zinc oxide as main product, such as Waelz oxides, the high halogen content in the product implies a great degradation of the product quality and the product can only be sold at a low price. Further processing of zinc oxide with high halogen content either by pyrometallurgical or hydrometallurgical processes will also result in process problems.This paper will review the pre- and post-treatment alternatives for halogen removal based on the comprehensive characterization work that has been carried out at MEFOS and the preliminary experimental results.The experimental results show that chlorine and fluorine content could be reduced to 450 ppm and 50 ppm respectively by selective sulfation, and to about 200 ppm by soda leaching. Selective sulfation of zinc oxide in the EAF dust will also be discussed."

Jan 1, 2000

By Mozley R

Contaminated sediments are a multinational problem. A crucial factor in solving an environmental problem is knowledge of, not only the amounts of polluted soil, the contaminants involved and their concentration, but also the historical background of the problem. Processing polluted soil is a tailor made activity based on rational decisions resulting from a detailed treatability study. Lack of information about characteristic properties of a specific sludge/pollution combination is the main obstacle in the route from first ascertaining that a particular harbour subsoil is polluted, to final identification of the full scale treatment plant. In the first instance, information must be generated regarding the distribution of pollutants in relation to the distribution of the original geophysical components. Based on this information rational decisions can be made on separation at a particular cutpoint and what sequential techniques should be involved for a certain fraction. For this purpose a `fingerprint method' is presented especially developed for investigation of polluted soil and sediments. The heart of the fingerprint method is a series of sequential hydrocyclone separations, by which a series of products is generated. The objective of the fingerprint method is to select an optimised treatment procedure in which the pollutants are concentrated in as small a volume of material as possible, leaving the bulk of the material clean. The pollutants can then readily be destroyed or isolated from the environment. The philosophy and advantages of the fingerprint method are demonstrated for a harbour sludge containing heavy metals as main pollutants. Hydrocyclone separation combined with flotation of both the coarse and fine fraction resulted in reusable and dischargeable products. Flotation of the fraction of fines was carried out by means of an experimental flotation cyclone enabling the selective recovery of mineral particles with diameters less than 10 microns. The overall conclusion is that design and engineering of treatment flow schemes for polluted dredged materials is a tailor made activity based on rational decisions resulting from the fingerprint information.

Jan 1, 1993