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By J B. Gemmell, D R. Cooke

Recent mapping at the Kelian epithermal gold deposit in East Kalimantan, Indonesia has delineated intrusive and extrusive-phreatomagmatic breccias, their magmatic roots, and late-stage endogenous domes of a maar-diatreme complex. The Kelian epithermal system is characterised by a wide variety of mineralised and unmineralised breccias, which include tectonic, hydrothermal, phreatic and phreatomagmatic varieties. Phreatomagmatic breccias and associated igneous rocks post-date early stage alteration and mineralisation, and pre-date main stage precious and base-metal mineralisation. This study emphasises the spatial, temporal and genetic links that have been drawn between diatremes and both epithermal and porphyry systems in volcano-plutonic arcs.

Jan 1, 1999

By M. Nete

Qualitative analysis of three mineral samples from northern Mozambique was accomplished by X-ray diffraction (XRD), microscopy, scintillation, and magnetic determination. Chemical characterization was accomplished using ICP-OES and pressed powder XRF after dissolution using microwave-assisted digestion and flux fusion. The samples consisted of a mixture of minerals with tantalite as the major component, with minor amounts of microlite, quartz, mica, accessory garnet, and tourmaline. Incomplete dissolution was obtained using microwave digestion, with maximum recoveries of 90.25 ± 0.06% and 88.90 ± 0.04% for Nb2O5 and Ta2O5 respectively. Complete dissolution using Li2B4O7 resulted in recoveries of 98.5 ±0.2% Nb2O5 and 100.4 ± 0.3% Ta2O5.

Jan 1, 2012

By Tamal K. Ghosh

In this study, the QEMSCAN technology is used to acquire quantitative modal, textural, mineral association and liberation data on different products generated from with or without washing, fractionation by size and density using screens and heavy liquids/panning, which has provided significant information on the quality and beneficiability of four categories of low Grade iron ores from Jharkhand-Orissa region. The deposit of low Grade iron ore has been categorized into four categories viz. Grade-I with <45% Fe(t) a) containing shale rich type and b) BHJ rich type; Grade-II with 45-55% Fe(t) and Grade-III with >55% Fe(t) containing conventional flaky, hard, kanga, lateritic, shale and BHJ litho/ore types in varied proportions. Mineralogy is similar across all samples being hematite, martite, goethite, kaolinite and gibbsite. Banded Hematite Jasper has difficult liberation characteristics due to highly compact banded mode of silica mineral occurrence with hematite. In all categories, the grade dilution is by the presence of 1) ?Discrete gangue rich litho types? at lump size and 2) ?Within ore types?. The second type of grade dilution contains coating of gangue phases around the iron ore minerals and different degree of locking of gangue phases within iron ore minerals. Further characterization and beneficiation assessment details are discussed in this paper.

Sep 1, 2012

By A. E. Lewis

The emphasis of this paper is on the characterization and testing of the slag produced by a secondary lead refinery. This work forms part of a broader investigation aimed at reducing loss of valuable product from the process as well as minimizing the environmental impact of the process wastes. It was this work that led to a critical examination of the standard waste classification tests. Characterization of the slag was carried out using a number of complementary techniques. In the broader context, the slag characterization aided in identifying process deficiencies and thus was a critical tool in suggesting potential for process optimization. For this study, the slag characterization provided a relatively comprehensive picture of the composition and properties of the slag, which facilitated understanding the behaviour of the slag under batch test conditions. On the basis of quantity of hazardous components alone, the slag is hazardous according to South African Acceptable Risk Limits (ARL). However, when both the quantity and the leach potential of the hazardous components is taken into account, standard waste tests carried out by three independent agencies indicate that the slag should not be classified as hazardous according to local regulations. Also, according to United States Environmental Protection Agency (US EPA) limits, which are independent of the quantity of the waste, the slag would not be classified as hazardous. The standard waste tests used by the independent agencies was the Toxicity Characteristic Leach Procedure (TCLP), a test which was developed by the US EPA to classify hazardous wastes. One of the requirements of this batch test is that it should be quick, simple to carry out and that the results should be reproducible. Previously, the applicability of the TCLP test to mineral processing and metallurgical wastes has been challenged on a number of points. Additional testing of the slag was carried out using both the TCLP and the Synthetic Precipitation Leach Procedure (SPLP) recommended by the American National Mining Association as being more appropriate for mineral processing wastes. The particular physical and chemical characteristics of the secondary lead slag highlighted additional limitations of both the TCLP and SPLP tests as standard laboratory batch procedures. Keywords: environmental protection, secondary lead processing, slag, leach testing, TCLP, SPLP, ARL, hazardous waste, batch tests

Jan 1, 2000

By A. Bhatanagar, D. Makhija, A. K. Mukherjee, R. K. Rath, P. Dixit

Characterization and beneficiation of dry iron ore processing plant reject fines of Khondbond region, India, was investigated. Different characterization techniques viz. size analysis, size-wise chemical and density analysis, X-ray diffraction analysis, sinkfloat analysis, thermo gravimetric analysis, scanning electron microscopy, and QEMSCAN were carried out. Based on characterization results, two process flow sheets comprising wet screening followed by conventional gravity concentration and two stage classification with different beneficiation routes were used to recover the iron values from reject fines containing 58.73% Fe, 5.54% Al2O3, and 6.6% SiO2. Finally, suggested flow sheet comprising of two stage classification and advance gravity concentration followed by the combination of grinding, classification, and froth flotation produced iron concentrate of 2.36% Al2O3 with 75.8% yield which can be used in sinter/pellet making.

Since 2008 rapid advances have been made in technologies for the sensing and sorting of ores, particularly copper, and copper-related ores. Advances include significant increases in the sensitivity and throughput, specifically in the area of bulk sorting. Such advances were not possible without contemporaneous advances in the understanding of copper orebodies, in particular the understanding and quantification of the heterogeneity required within an orebody to support an effective sort, regardless of the technology deployed to do this. This paper covers fundamental knowledge in the characterization of orebodies and their ores for sorting; relationships between measures of heterogeneity and sorting response; the design of bulk sorting systems that can exploit this heterogeneity to add value to copper operations; and, a quantification of the value that can be generated from bulk sorting at a case study mine. INTRODUCTION Society currently puts increasing pressure on industries to move towards cleaner and more efficient means of production, and the mining industry is no exception. Mining additionally faces other factors increasing the pressure to be more efficient: high-grade and easily accessible reserves have become largely depleted, therefore the mined grade at operations across most commodities, including and in particular copper, is decreasing. Additionally, the grade of new discoveries in the sector continues to decrease (Schodde, 2011). Factor in the high capital cost of processing facilities and the low levels of efficiency of current grinding circuits, and the situation for such mines becomes dire. Sorting, by maximizing the amount of ore extracted while simultaneously reducing the waste content in ore delivered to downstream processes (whether simply transport and crushing, or more sophisticated circuits such as grinding and flotation or leaching) has long been of interest to mining operations and projects struggling with low margins (Bamber, 2012). However, until recently sorting technologies that are both cost effective and effective at such high throughputs have not been commercially available.

Jan 1, 2019

By S. I. Angadi, C. Eswaraiah, Sunil Kumar Tripathy, T. Santosh, Nilima Dash

Banded hematite quartzite (BHQ) and banded hematite jasper (BHJ) ores represent a promising potential iron ore resource in the near future. The hematite and quartz in BHQ and the hematite and jasper in BHJ are closely related and require fine grinding for the liberation of hematite phases. The present study investigates the mineralogical features and comminution properties of BHQ and BHJ ores. In the BHQ ore, it is observed that thick bands of hematite have fine inclusions of silicate minerals, whereas silica bands have few grains of iron-bearing minerals. The hematite and quartz minerals in the iron and silicate bands of the BHJ ore appear to be more intricately associated and complex in nature, presenting difficulties for liberation. Bond work index studies were carried out for the BHQ and BHJ ores with different product fineness in order to evaluate the energy requirements in fine grinding. A higher Bond work index value was found for the BHJ ore (15.4 kWh/ton) than for the BHQ ore (12.4 kWh/ton). A decrease in the product particle size was associated with an increase in the work index value. Single-particle breakage experiments were designed by varying feed particle size and input energy. The specific energy consumption for the BHJ ore was higher than that for the BHQ ore. The comminution parameters showed that the BHJ ore is harder to grind than the BHQ ore, which may be due to the mineral composition and association of hematite phases with the silicates.

By Klaydison Silva, Maurício Curi Segato, Elves Matiolo, Neymayer Pereira Lima

Flotation is the main concentration process, has been applied with sucess for the removal of quartz on the iron ore industry aiming high quality concentrates. limiting the top size close to 0,300mm and the removal of slimes are fundamental for the efficiency of reverse flotation of quartz. The high consumption of reagents, leading to insufficient particle coverage, and increased foam stability, leading to the difficulty of removal of quartz particles, are the main deleterious effects of the presence of slimes. Recent characterization studies, together with the development of new collector of linear chain, allowed the obtaining of concentrate with SiO2 contents close to 3% with 94% of metallurgical recovery, based on pilot tests carried out on a sample flotation column of the Quadrilátero Ferrífero.

Oct 3, 2019

By R. Abel, T. Wildeman, N. Heflin

A study was conducted to assess environmental effects of waste rock piles on water in the Russell Gulch area. Each pile was rated on physical characteristics of proximity to an ephemeral gulch, extensiveness of erosion features, size, presence of vegetation, and presence of a kill zone. Chemical assessments focused on three leachate tests performed on waste rock samples. Ratings were based on pH, conductivity, acidity, and analysis for 31 metals using inductively coupled plasma emission spectroscopy. The chemical and physical assessment of each site is used to make a rating of each pile on its overall potential to deliver contaminants.

Jan 1, 2004

By D. Moffat

Rio Algom Limited has mined uranium at Elliot Lake, Ontario for 20 years. The production of this energy-generating element results in the need to dispose of low-level radioactive solid wastes and liquid effluents. Because of the wet-temperate climate at Elliot Lake, the liquid effluents are of particular importance. Radium-226 is the isotope which requires most attention, and the current practice for its control is by addition of barium chloride and retention of the resultant precipitates in large settling ponds. Analyses of typical effluents and waste streams are discussed and typical levels of radium-226, thorium-230, thorium-232, thorium-228, lead-2iO, polonium-2iO, and uranium isotopes are presented.

Jan 1, 1979

By B. K. Mishra, B. Das, L. Panda, D. S. Rao

"The dissolution behavior of lateritic nickel ore containing 1.2% Ni, 40.6% Fe, 9.5% SiO2 and 9.59% MgO by sulfuric acid was investigated. The ore was characterized adequately by different techniques such as chemical analysis, scanning electron microscope (SEM), X-ray diffraction (XRD), field emission scanning electron microscope (FESEM), thermal analysis and Fourier transform infrared (FTIR) spectroscopic measurements. The characterization results did not reveal any distinct mineral phase for nickel; it was associated with mineral phases like goethite, hematite, chromite and serpentine in various proportions. The beneficiation studies by hydrocyclone, magnetic separation and flotation did not enrich the nickel value. Reduction roasting followed by magnetic separation indicated only 2%Ni with 28.9% yield. Consequently, the recovery of nickel values from the lateritic ore by acid leaching under different conditions was studied. The kinetics of leaching obey the first order rate equations. The recovery of nickel was found to be influenced by temperature. It was observed that at an acid concentration of 2M, leaching temperature 363 K, time 240 min and solid-to-liquid ratio of 1:10, it is possible to leach out more than 95% Ni.IntroductionThe demand for nickel is ever increasing. Nickel is used to impart specific properties to steel, titanium and aluminium, and also is used in petrochemicals, catalysts, batteries, etc. It has been estimated that nickel oxide ores account for about 70% of the world nickel reserves. However, most nickel is sourced from sulfide ores. Nickel is extracted from sulfide ore by size reduction, followed by flotation to obtain a nickel-rich concentrate. The concentrate is then pyrometallurgically processed by smelting to produce a nickel-rich matte after discarding an iron-rich slag. Due to the increasing demand for nickel in stainless steel and other alloys, nickel is also extracted from many secondary sources. The recovery of nickel from oxide ores is now gaining momentum, and more exploitation of this ore is being attempted by advanced as well as environmentally feasible, cost-effective techniques. Dalvi et al. (2004) has reported that, due to the increase in demand, the world nickel production from laterites is expected to increase every year from the current level of production. In recent years, investigations of the use of low-grade ores, spent catalysts, clays, etc., have intensified to meet the market demand and also due to a shortage of high-grade nickel bearing ores (Al-Mansi and Abdel, 2002; Baba et al., 2009; Ismail et al., 2011)."

Jan 1, 2015

The distribution of chrome spinels in a magnetically fractionated ilmenite concentrate sourced from the Murray Basin was characterized by XRF assaying, quantitative electron microprobeanalysis, grain mapping, automated mineral phase clustering, and modal analysis. At least 14 distinct chrome spinel types were present in the concentrate. There is considerable variation in the amount of each chrome spinel type present, although a high-Mg, high-Al phase makes up close to 45 per cent of the total spinel population. Magnetic fractionation results showed significant variation in the composition and relative abundance of spinels reporting to each fraction. Low magnetic field strength fractions (ie. high susceptibility grains) were dominated by chrome spinels that are mid-range in Al and Cr. These spinels have the highest magnetite, ulvospinel and Fe(Al,Cr)2O4components. In comparison, the high field strength fractions (i.e. low susceptibility grains) have the majority of the grains with high-Al contents indicating a higher proportion of Mg(Al,Cr)2O4component. Spinels high in a (Al,Cr)2.67O4non-stoichiometriccomponent are absent at low field strengths but tend to be concentrated in the high field strength, non-magnetic fractions. Intermediate field strength fractions tend to exhibit a broad spread in spinel compositional types. A mild roast treatment of the sample had no clear effect on the distribution of chrome spinels between different magnetic fractions, but it did cause a change in the magnetic properties of the accompanying ilmenite grains. The effect of more extreme roasting conditions on the magnetic properties of the chrome spinels is to be determined.

Jan 1, 2003

By M. M. Sadawy

"The increased rate of exploitation of iron ores has resulted in a rapid depletion of high-grade iron ore deposits in Egypt. New iron reserves have to be discovered to secure the iron ore for steel production. This paper aims to study the characterization and magnetic separation of low grade Aswan iron ore. The results showed that Aswan iron ore is composed of oolitic hematite, goethite, quartz and kaolinite. The screen analysis indicated that Aswan iron ore had a uniform distribution of iron and silica in the different particle size fractions and there is no any particle size has high amount of iron or low content of silica. On the other hand the results of dry high intensity magnetic separation illustrated that this technique is not suitable for upgrading this ore.IntroductionIron is one of the common metals used in industry, as well as being the fundamental raw material used in iron-steel industry; products are wide spread even in daily uses. The total iron ore reserves of the world have been estimated as 3 70 billion tones; 160 billion tones is classified as economical, while 210 billion tones as potentially economical [1]. An estimated 98% of the iron ore exploited in the world is used in the manufacture of pig iron and steel, which are non-substitutable backbones of modem society. The rapid increase of world steel production over the last few years have required an equal increase in iron ore production, from 876.8 Mt in 2006 to 948.1 Mt in 2007 [2]. The increased rate of exploitation of iron ores has resulted in a rapid depletion of known high-grade iron ore deposits. This, in turn, has led to a dramatic increase of prices. In the absence of any major new discoveries of high-grade iron ore deposits, mining companies have turned to lower-grade materials to assess their beneficiation potential to expand their production base and beneficiation capacity, in order to satisfy future demand. Egypt is going to face shortage in iron production, consequently new iron reserves have to be discovered to secure the iron needed for the country [3]. Exploitation of low grade ores requires special equipments and techniques for recovery of minerals values. High gradient magnetic separators offer promise and great potential of application both technologically and economically in the processing of fine particles containing weakly or feebly paramagnetic components [4-6]. Within this existing framework, this research was initiated to assess the beneficiation potential of low-grade Aswan iron ore by high intensity magnetic separation."

Jan 1, 2013

By M. S. Moats, C. M. Campbell

Samples of a high impurity (90.05 wt. % Cu, 4076 ppm Pb, 1939 ppm As and 635 ppm Bi) commercial copper anode were characterized and then electrorefined in a laboratory scale cell. Anode inclusions were examined using backscatter mode scanning electron microscopy and energy dispersive spectroscopy. Hundreds of inclusions were measured for size, morphology and composition. Commonly found inclusions were copper oxide (Cu2O), complex oxides (Cu-Pb-Bi-As-O) and copper selenides/tellurides. The weight percent of lead and arsenic increased with increasing inclusion size up to 4- 5 microns. During electrorefining, starter sheet ductility was negatively impacted by thiourea addition. The importance of arsenic (V) concentration on the electrolyte concentration of bismuth was observed. INTRODUCTION Copper electrorefining is a commercial process used to produce the majority of the world’s refined copper. During this process, impure copper anodes are dissolved electrolytically, and high purity copper is deposited on cathodes. As the anodes dissolve, the impurities either accumulate in the electrolyte or report to solids that form on anodes surfaces or at the bottom of the refining cell. These solids are called slimes. Slimes contain precious metals and are collected for further processing. Slimes are also an important outlet for problem impurities such as lead, antimony and bismuth. The electrorefining process is operated in such a way to encourage the deportment of these elements to the slimes. Impurities in copper anodes have been studied extensively by Chen and Dutrizac (1990, 1993 and 2005). The most common impurities found in modern copper anodes include: Ag, As, Au, Bi, Fe, Ni, O, Pb, Sb, Se, Sn and Te. Impure copper anodes are produced by pyrometallurgical methods and have purities ranging from 97.7–99.7% Cu (Moats et al., 2019). The composition ranges of commercial copper anodes from the 2019 worldwide tankhouse survey are given in Table 1. The concentrations of anode impurities vary widely dependent on the source material and prior processing steps. Based on the work of Chen and Dutrizac, both gold and silver are predominantly found in solid solution within the copper grains while a minor amount of Ag can be found in Cu2(Se/Te) inclusions. Nickel is entirely soluble within the copper grains up to anode compositions of 2500–3000 ppm Ni; above which NiO and kupferglimmer phases are formed (Chen & Dutrizac, 1990). As, Bi, Pb and Sb are found in solid solution within copper and within oxide inclusions typically found along grain boundaries. Oxides are formed due to the presence of 0.13-0.18 wt. % O (Chen & Dutrizac, 1990). This is because during solidification of the cast anodes, impurities are enriched in the liquid phase as the copper grains nucleate and grow. The inclusions form from the last liquid to freeze, which is typically along grain boundaries (Wenzl & Filzwieser, 2007; Wenzl, Filzwieser, Mori & Pesl, 2008).

Jan 1, 2019

By K. Woo

The increasing move to block cave mining methods (including sublevel and panel caving) to access deeper and lower grade ore deposits as near surface sources become exhausted raises questions as to the extent and magnitudes of caving-induced subsidence as it may affect strain-sensitive infrastructure on surface. Predicting these surface deformations is difficult as they tend to be discontinuous and asymmetric due to large movements around the cave controlled by geologic structures, rock mass heterogeneity and topographic effects. Of further impediment is the sparse number of case histories available, in which actual subsidence measurements are reported to provide guidance and empirical constraints for subsidence calculations. This study reports the development of an exhaustive and comprehensive database of available (i.e. public domain) subsidence data from block cave mining operations from around the world.

May 1, 2009

By S. B. Mishra

Ni-20Cr metallic coating was deposited on a Ni-based Superalloy (3Fe-19.5Cr¬0.3Ti-Balance Ni) by a shrouded plasma spray process; NiCrA1Y was used as a bond coat. Erosion studies were conducted on uncoated and plasma-spray coated superalloy specimens using an air-jet erosion test rig at a velocity of 40 m/s and impingement angles of 30° and 90°. The coating has been characterized for porosity, microhardness and microstructure and X-Ray Diffraction (XRD). An electron probe micro analyzer (EPMA) was used to obtain X-ray elemental mappings of the coating along the cross-section. Scanning electron microscope (SEM) with EDAX attachment was used to analyze the eroded surfaces.

Jan 1, 2005

By E. B. Zanelato

The process of casting metals and alloys occurs through the fusion of this metal and its subsequent casting into a mold with the dimensions and geometry close to the final piece. Most foundries use sand casting molds for making you. This work aims to characterize and evaluate the foundry sand to allow its use in segments of Civil Engineering, creating a viable destination for a residue is that discarded. The following characterization tests were performer: particle size, chemical analysis, X-ray Diffraction and Density Real grain. For the execution of the test specimens was used to 1:3 cement and sand, and the incorporation of 10% and 20% of the total mass replacing the sand, and the trace reference. The results show that best results in compression and bending tests were obtained by replacing 10 % of common sand for sand casting.

Jan 1, 2015

By Nikhil Dhawan, SHAILA MIR

The emerging problem of electronic waste has promoted the interest in exploring metal recovery from secondary sources under the umbrella of urban mining. This study presents the physical and chemical characterization of various components present in end-of-life laptops to help ascertain the sites of metallic values and develop sustainable and environment-friendly recycling. The recycling potential of a laptop is evaluated by sequential disassembly, separation, and characterization of components such as body (49.8 wt.%), printed circuit board (9.7 wt.%), hard disk drive (4.9 wt.%), and battery (12.4 wt.%). The printed circuit boards comprise metallic values, majorly copper (25 wt.%), tin (5.8 wt.%), and lead (3.1 wt.%). The precious metals (Au, Ag) with an economic advantage are abundantly present in electronic components such as integrated circuits, capacitors, resistors, and processors. Critical elements such as lithium, cobalt, and rare earth elements are detected in the discarded laptops' batteries and hard disk drives. The recycling potential representing the amount of material that can be recycled in various components, depending on the type, concentration, and purity, is determined in the range of 36–100%. On average, a unit laptop contains~ 386 g of Cu (14.45 wt. %), 49.73 g Co (1.86 wt. %), ~346 mg Ag, ~141.2 mg Au, ~650 mg of rare earth elements (Nd, Dy). This study presents a database for investigating integrated and economical recycling techniques from different components of a laptop, and an overall process flow is also proposed.

Jul 24, 2021

By Nikhil Dhawan, SHAILA MIR

Consumer preference for ever-higher laptop performance coupled with laptops’ declining lifespans make them a significant contributor to electronic waste. An in-depth evaluation of elemental composition and distribution is important for determining metal recovery potential and sustainable recovery processes. In this work, the characterization of individual components of laptops is studied for the systematic identification of important elements and for streamlined and structured recycling, to reduce processing steps and improve economics. A process flowsheet highlighting various recycling routes by targeting metals and various components is also proposed.

By A. P. Herring, M. Hoover, D. W. Fuerstenau

The dissolution of nickel, copper, and cobalt from five different samples of well-characterized deep sea manganese nodules was measured as a function of temperature, pH, leaching time, and particle size. Nickel, copper, and cobalt extraction each respond to these variables in a different manner. The results of this investigation indicate that copper and nickel can be selectively dissolved from iron and manganese at moderately low pH, provided the reaction is given sufficient time. A high dissolution of cobalt with dilute sulfuric acid can only be achieved from nodules that have a low iron content (<5%). The most probable rate-controlling step for copper and cobalt dissolution is diffusion through the pores of the nodules, and for nickel dissolution chemical reaction appears to be rate-controlling.

Jan 1, 1974