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By Edwin Adoyi Ali, Zainab Shehu Aliyu, Adele Dzikwi Garkida, Muhammad Dauda

Feldspar from Matari, Nigeria was analyzed using SEM, XRD and XRF techniques for microstructural analysis, mineral phase analysis and chemical composition analysis respectively. Qualitative and quantitative XRD analyses revealed the presence of microcline 59.6%, albite 34.7% and quartz 5.71%. The XRF results showed that the feldspar contains 67.32% SiO2, 17.54% Al2O3, 11.33% K2O, 2.75% Na2O, 0.12% CaO, 0.01% MgO, 0.02% MnO2, 0.10% Fe2O3, 0.00% Ti2O, etc and 0.14% LOI. SEM/EDX analysis shows the presence of microcline feldspar as the dominant phase, exhibiting lamellar twinning. The XRD has also revealed that potash has the highest peak, indicating its high concentration. The 0.10% Fe2O3 present is within the permissible level (0.1-0.3%) for glass making and also within the potash feldspar specifications (0.17%). The Matari feldspar is a microcline type, rich in potash, alumina and silica, enabling it meet the standard specifications for alumino-silicate glass.

Jan 1, 2015

By W. Petruk, M. J. Matos

An aplite ore from Guarda in northern Portugal, containing albite, microcline and quartz and muscovite gangue was studied to identify conditions for extracting the feldspar minerals. The large amounts of quantitative mineralogical data needed to evaluate grinding behaviour were provided by automated image analysis. The images were acquired on polished surfaces by measuring back-scattered electron signals produced with a microprobe. Minerals were identified from X-ray spectra and discriminated by grey level and element-characteristic X-rays. The quantities and size distributions of the minerals were determined by measuring thin sections of unbroken ore to predict the grind required to liberate the feldspars. The ore was then ground to -1.7 mm, polished sections were prepared from sieved fractions and the quantities of mineral species and apparent total liberation were determined by analysis. The predicted and measured liberations were compared and the grinding behaviour of the ore interpreted. In an appended correction, the correct version of Equation 1 is represented and Tables 3 and 6 are revised to consider all size fractions, including those coarser than 300 micrometres, in calculating the total liberation from King's fractional liberation

Jun 18, 1905

By M. J. Matos, W. Patruk

The correct version of Equation 1 is represented and Tables 3 and 6 are revised to consider all size fractions, including those coarser than 300 micrometres, in calculating the total liberation from King's fractional liberation

Jun 18, 1905

By T. Wallmach

Heavy mineral deposits are a source of the economic important element titanium, which is contained in minerals such as ilmenite, pseudorutile and rutile. In the Ranobe heavy minerals deposit these minerals occur not only as primary unaltered minerals but also display various degrees of alteration resulting in an increased titanium content of the deposit. The presence of the various FeTi-oxide minerals? textural relations is a reflection of geological processes and may ultimately be used to unravel the geological history of the deposit. These minerals have different chemical and physical properties that influence metallurgical tests and the quality of products produced from various mineral beneficiation streams. It is therefore of metallurgical importance that the minerals are well characterized, defined and monitored during preliminary beneficiation tests.

Jan 1, 2007

By Tammy G. R. Portela

A comparative characterization of the dimensional and mechanical properties as well as structural aspects of two different types of fibers extracted from the leaves and petioles of the buriti palm tree was performed. A statistical analysis revealed that both types of fibers present a significant dispersion in length and equivalent diameter. However, the corresponding intervals of dimensional variation are sensibly different. The tensile properties showed that both types of fibers display a tendency of higher strength for smaller diameters. Moreover, the fibers extracted from the leaves depict a comparatively lower strength. By contrast, the fibers from the petiole present an average strength sufficiently high for the use as reinforcement of polymeric composites. The structural aspects of tensile-rupture fibers, characterized by scanning electron microscopy, showed marked distinction in the microstructure and fiber behavior of both types of investigated fibers. This could explain the differences in mechanical behavior

Jan 1, 2010

By Luiza Esteves

Corrosion testing was performed in white liquor from a Brazilian Kraft mill. Specimens of duplex stainless steel (DSS) and lean duplex (LDSS) were exposed at 170 °C for 30 days to simulate conditions of the digester. Corrosion rates were determined from weight loss measurements. After this exposure, the corrosion products formed on the steel surface was characterized by using scanning electron microscope (SEM) equipped with EDS, X-Ray Diffraction (XRD), and X-ray photoelectron spectrometer (XPS). EBSD can be used to quantify of basis balance phases in DSS and LDSS. General corrosion rates for UNS S32304 LDSS were higher than the UNS 31803 DSS in industrial white liquor at 170 °C for 30 days. XPS and XRD analyses indicated that the film formed after the immersion test may be consisted by Fe and Cr oxides and sulphides.

Oct 30, 2017

By Gustav Hawlitschek, Henrique Kahn, Carina Ulsen, Renato Contessotto

"The problems related to waste dumping increased with the growth and development of large cities. In the U.K., more than 50% of landfill waste comes from construction use and the U.S. alone produces around 200 to 300 million tons of CDW annually. The exhaustion of natural sand deposits close to large urban centres stimulates the recycling of construction and demolition waste for the production of recycled aggregates as a construction material. This paper presents a flowchart for the production of recycled sand with low porosity and regular shape by the selective removal of the cement paste attached to recycled aggregates. The products characterization was carried out by the determination of the particle size and shape distribution, chemical and mineralogical composition, heavy liquid mineral separation and quantification of all present phases using a scanning electron microscopy with automated image analysis (SEM-MLA). The comminution of CDW by vertical shaft impact crusher made possible the production of a lower porosity recycled sand. The heavy liquid mineral separation showed that the proportion of low porous phases (d>2.5 g/cm3) is very high, exceeding 70% of the weight, encouraging further mineral processing separation to obtain a fine recycled aggregate with less cement paste content. The mineralogical characterization by XRD and SEM indicates that the main phases are tectosilicates, phyllosilicates and calcite which one can be attributed to both calcareous aggregate and cement paste. The precise quantification of cement paste and calcite/dolomite alone is just possible by automated image analysis. The characterization results demonstrated that proportion of phases with no cement paste attached increases progressively in denser products. The results of heavy liquid separations and image analysis are comparable and automated image analysis can be used for the characterization of phase content and their main associations."

Jan 1, 2014

By A. Djebara

Today, indoor air quality, especially in manufacturing industries, is of great interest due to the use of new processes and advanced materials such as those containing nanoparticles. Manufacturing processes generate aerosols (dry or wet) which can be detrimental to occupational health and safety and to the environment. Controlling metallic particle emissions during machining processes should limit their formation at the source, and thus minimize the risk of exposure; this at-source reduction requires the characterization of the particle emitted (size, nature, concentration, etc). The metrics normally used in characterizing fine and ultrafine particles include the mass concentration, the specific surface and the number concentration. Most of these metrics are affected by the size, the geometry and the density of the measured particles. Information about the form and the real size of the particles is thus very important. A procedure for collecting and characterizing fine and ultrafine metallic particles was developed and applied to the study of particles emission during the machining of aluminum alloys. It was found that metallic particles emitted during the machining of aluminum alloys are of various shapes and sizes, and this information must be taken into account when characterizing these particles.

Jan 1, 2011

By S. Chander, V. N. Sharma

Nickeliferous laterite ore from Sukinda, Orissa (India), consists of very fine particles agglomerated into larger aggregates. The ore is chemically and mineralogically complex and presents many characterization and beneficiation problems. In this study the results of a detailed investigation to characterize the ore by several techniques are discussed. Various techniques used for characterisation include elemental analysis, electron microscopy, electronspectroscopy for chemical analysis, x-ray and electron diffraction, differential thermal and thermogravimetric analyses, EDAX analysis, Mössbauer and infrared spectroscopy. Generally one method compliments the other and it is shown that a combination of several techniques is necessary to fully characterize the ore. The scope and limitations of the techniques are also discussed.

Jan 1, 1980

By J. Guerrero, O. Pavez, N. Toro, A. Nazer

In the 19th century, mining in northern Chile was of great economic importance. Today, the ruinsof the copper smelters and abundant fragments of refractory bricks from their furnaces remain. Therefractory materials have not been previously studied. the origin, physical and chemical properties, and compressive strength of 10 different samples of historical refractory bricks collected on-site were investigated. The characterization results showed that the bricks are silico-aluminous, unlike the magnesium-chromium bricks used by current foundries. It was determined that 90% of them were produced in the UK and 10% were manufactured in Chile. The phases present are mullite, quartz, cristobalite, and tridymite, and the chemical composition corresponds mainly to SiO2. The compressive strength of the historical bricks is similart to those currently used,. These results may contribute to the knowledge of the 19th century mining and metallurgical historical heritage of Chile and the UK.

Jul 5, 2023

By R. Hogg

The various sub-processes which, together, make up the unit operation of froth flotation all depend on the characteristics of the feed solids, the solution phase, the air bubbles and the mechanical/hydrodynamic action of the machine. Characterization is obviously necessary for evaluation and process control, but the relationships between characteristics and process response are often unclear. A model-based characterization scheme is proposed in which material and system characteristics are evaluated in the context of simplified models for the individual subprocesses. The general basis for such an approach is discussed using the process of particle attachment and the influence of mineral liberation as examples.

Jan 1, 1989

By A. Morales

Flue dusts from a copper smelting furnace (continuous furnace), have been extensively characterized. The main phases detected have been cuprospinel, anhydrous copper sulfate (chalcocyanite), lead sulfate (anglesite) and arsenic oxides (claudetite and arsenolite). As minor phases, zinc sulfate (zincosite) and several copper or copper/iron sulfides were detected (digenite, anilite, bornite, cubanite), and also a copper oxide (tenorite). The suspension of this material in water leads to the partial dissolution of copper and zinc (chalcocyanite and zincosite) and arsenic oxides. The hydrocyclone classification of the residue makes it possible to obtain two fractions: a copper-rich coarse fraction and an arsenic-rich fine fraction. The coarse fraction can be recycled to the smelting furnace and the fine fraction can be mixed with wastewater sludge from a paper factory, to make both residues inert before disposing them to landfill.

Jan 1, 2007

By B. Jena, M. Rigaud, S. C. Panigrahy

"The influence of flux addition on the structure and properties of pellets produced from low silica specularite with peat moss and bentonite as binders was investigated. Specific pellets basicities in the range of 0.4 to 3.2 were obtained by the addition of limestone or a combination of dolomite and limestone as flux. A t basicities < 1.6, the bonding in the pellets was provided by a glassy silicate phase. At basicities =1.6, calcium ferrites were the predominant bonding phase. When dolomite was added as a flux, presence of magnesia-ferrite was noted. The reduction behaviour of pellets at different basicities was found to be influenced by the type of flux and binder. The pellet compression strength and swelling characteristics were improved with increased basicity.IntroductionThe properties of iron ore pellets are influenced by the type and nature of the ore or concentrate, additives and their subsequent treatment to produce pellets. The interaction between various constituents of the concentrate and additives, i.e. iron oxides, gangue and fluxes etc. result in the formation of various mineralogical phases which affect the degree and nature of bonding achieved in the pellet and the structure and distribution of pores. The pellet properties such as pellet strength and reducibility are influenced by the extent and type of bonding achieved between the ore particles. In view of the present emphasis on the production of high quality pellets to meet progressively stringent quality control requirements, it is essential to investigate the effect of additives on the bonding mechanism and properties of the pellets.In the past, the effects of additives on the bonding mechanism of pellets have been investigated. It is important to note that the conditions and parameters to be controlled are typical of a given concentrate/ore. In this paper, the results of the investigation on characterization of fluxed pellets produced from a low silica specularite concentrate are reported.This investigation was also aimed at assessing the suitability of peat moss for use as a binder for the production of low silica fluxed pellets. Peat moss is abundantly available in the vicinity of iron ore mines in Quebec and encouraging results have been obtained du ring the production of high silica acid and fluxed pellets."

Jan 1, 1992

By John W. Graydon

Incineration is an attractive alternative to the disposal of MSW in landfill sites. However, the process of incineration generates fly ash which contains significant levels of leachable heavy metals - particularly cadmium, lead, and zinc - and it is essential to manage this fly ash in an environmentally sound manner. The compositions, phases, textures, morphologies and size of fly ash particles have been studied by light microscopy, scanning electron microscopy, X-ray microanalysis, and X-ray diffraction. The detailed spatial relationships and speciation of the environmentally significant constituents have received particular emphasis. The information obtained is useful in understanding how fly ash is formed during incineration, in understanding the leaching behavior of untreated fly ash if it is disposed of in a landfill and, most importantly, in guiding the development of the best treatment strategies for fly asti to mitigate its environmental impact.

Jan 1, 1992

By Carlos Mauricio Fontes Vieira, Sergio Neves Monteiro, Thiago Samarão Motta

This work has as its objective to characterize ceramic bodies formulated with ornamental rock waste and two different clays to produce ceramic paver. Specimens were made by uniaxial press-molding at 20 MPa and then fired at 950 and 1050oC respectively. The determined technological properties were: plasticity, dry bulk density, linear shrinkage, water absorption and flexural rupture strength. The results showed that the type of the clay has strong influence on the properties of interest for heavy clay ceramics. The investigated waste must be incorporated in small amounts to avoid increasing in the porosity of the ceramics.

Jan 1, 2015

By R. Hogg, M. Polat, S. Chander

A fresh dust generator was designed and built in order to study the agglomeration behavior and other characteristics of freshly generated airborne dust. The size distribution of the freshly generated quartz airborne dust produced by the generator was measured both directly in air and after dispersion in water. It was observed that same dust particles had an apparently coarser size distribution in air than in water, suggesting possible agglomeration of the dust particles. It was also observed that the size distribution obtained by a cascade impactor was very similar to the liquid dispersed size distribution, implying deagglomeration by the impactor. The agglomeration was confirmed by microscopic observations of particles in air and those collected on a microscope slide. The extent of agglomeration played a decisive role on the fraction of the dust actually becoming airborne. It was also found that contamination of the airborne dust by the rolls of the crusher was almost twice as much as that of the product.

Jan 1, 1991

By Michael Young, Rodrigo Araya, Cesar Gomez, Le Huynh, James Finch

The performance of flotation machines is closely related to the gas dispersion characteristics achieved in their operation. It is known that frothers play a major role not only in the size distribution of the generated bubble population, but also on the swarm rise velocity. A program to characterize frother effects on two-phase hydrodynamics (air-water) of Jameson cells was undertaken in a fully instrumented pilot unit installed at McGill University. Gas dispersion parameters (gas velocity, gas holdup and bubble size distributions) of the gas-liquid mixture generated in the downcomer were measured after its release into the separation chamber. The unit was operated under different conditions including gas velocity, liquid jet velocity and frother concentration (MIBC). Bubble size distributions for concentrations above the critical coalescence concentration (CCC) were narrow with Sauter mean diameter between 0.6 to 1.3 mm. The bubble size followed the general trend as encountered in other types of flotation machines, i.e., rapid decrease with increasing frother concentrations below 10 µL/L, and almost no change in size for concentrations above 30 µL/L. The CCC was between 10 and 15 µL/L. Strong correlations were found between bubble size and air-to-liquid flow ratio (APR), and between the bulk density of the aerated solution in the separation tank and the vacuum inside the downcomer. An equation is proposed to estimate gas holdup in the separation tank from vacuum and bulk density readings.

Jan 1, 2014

After several years of laboratory and field evaluations, it has been established that each frother has its own unique relationship among bubble size reduction, gas hold-up increase, froth stabilization and frother concentration. It has been shown that a frother?s hydrodynamic properties can be characterized using the relationship between the froth zone property froth height and the pulp zone property gas hold-up. The relationship is established in a bubble column run at a given air rate over a range of frother concentration. The use of relationships in frother selection and plant diagnostics is illustrated in a series of plant case studies.

Jan 1, 2009

The recovery of fine hydrophilic gangue in flotation is related to the recovery of water. Water is carried by bubbles as a film and wake into the froth. The amount carried (entrained) depends on bubble size, gas rate and the subject of this paper, frother type. To isolate the effect of frother type from that of bubble size and gas rate, gas holdup is used as the correlating variable. Measurements were made using a bubble column (no solids) operated continuously with the overflow recycled. Continuous operation meant some foam depth was required to ensure only entrained water is recovered. Using an automatically controlled 7cm foam depth the overflow rate of water is used as a measure of &apos;water carrying rate&apos;. It is shown that the common frothers can be grouped into four families based on the water carrying rate-gas holdup relationship.

Jan 1, 2006

By S. J. Schatzel, P. W. Jeran, W. P. Diamond, F. E. McCall, F. Garcia, J. C. LaScola, T. P. Mucho

The National Institute for Occupational Safety and Health, Office for Mine Safety and Health Research, is investigating the geologic and mining factors influencing the migration of longwall gob gas. One goal of these studies is to optimize methane drainage strategies to reduce the volume of gob gas that reaches the underground workplace. As part of this research effort, longwall gob gas flow paths in a mine operating in the Pittsburgh Coalbed, PA, were investigated using SF6 tracer gas. Tracer gas released into the ventilation airflow underground generally stayed in the bleeder system and was vented at the associated bleeder fan shafts. Tracer gas injected into an inactive (intaking) gob gas venthole migrated to the two inby producing ventholes on the study panel, indicating that all three ventholes were in communication. The tracer gas that was injected into the gob generally stayed in the gob and only migrated to the ventilation system in response to the venthole on the study panel closest to the injection hole going off production. Tracer gas flow velocities in the longwall gob reservoir and factors influencing the production performance of gob gas ventholes in the study area are also discussed.