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By E. V. Koporulina, I. Zh. Bunin, M. V. Ryazantseva

"We studied the mechanism of structural and chemical transformations of columbite, tantalite, zircon and feldspar surface during the treatment by high – power electromagnetic pulses (HPEMP) using the methods of X - ray photoelectron spectroscopy (XPS), analytical electron microscopy (SEM - EDX), Kelvin probe force microscopy and flotation experiments. According to XPS and SEM - EDX data, major changes in the atoms chemical state of investigated minerals surface are related with formation and modification of functional cover and changing in concentration (% at.) of hydroxyl groups on the mineral surface, leading to increase in the contrast of technological properties of the rare metals minerals. Research has identified the optimal parameters of HPEMP - treatment of rare - earth minerals Npuls ??104, Ttreatment ??100 sec. improving the selectivity of the flotation separation of columbite and zircon. The difference in mineral recovery into the froth (? e) before and after HPEMP - treatment was about 11 % and 24.5 %, respectively. No significant increase was observed in the flotation activity of feldspar. This study's findings demonstrate the effectiveness of HPEMP - treatment in inducing a controlled change in the structural and chemical properties of rare - earth minerals and improving the process efficiency for the processing of rougher tantalum - niobium gravity concentrates.INTRODUCTIONThe importance of improving the processing methods of tantalum-niobium ores and concentrates is explained by the mineralogical properties of rare - earth ores. These are properties such as the variable mineral, chemical, and grain size composition, complex morphometric properties, and the dissemination of ore mineral grains of micro - and nanometric size. Iron oxide and hydroxide films on the mineral surfaces neutralize the surface physicochemical and absorption properties of the minerals. Both in Russia and globally, nonconventional (non - mechanical) methods are being developed based on physicochemical, electrochemical, and pulsed energy impacts to improve the efficiency of disintegration and liberation processes of disseminated mineral complexes and to enhance the contrast of the structural, chemical, and technological (floatability) properties of refractory ores. This study is devoted to the investigation of the applicability of high – power electromagnetic pulses (HPEMP – treatment) for the change in the structural and chemical properties of rare - earth minerals and improving of the flotation properties contrast."

Jan 1, 2018

By L. A. Vaisberg, E. V. Shishkin, S. V. Kazakov

"This research is targeted at finding solution to the problem of reduction of specific energy consumption during disintegration of solid materials with the help of machines, operating in a quasiresonant mode. The objective of the research is the development of an energy-saving method of disintegration of supestrong rock and by-products on the basis of vibrational units with two movable crushing elements, operating in a rigorous synchronous-antiphase mode without stringent kinematic links. In the course of investigations a mathematical analysis of the dynamics of vibrational units was performed to determine required mechanical parameters, allowing for adjustment of the machine actuating elements to high-frequency synchronous-antiphase oscillations in the quasiresonant frequency range. As a result of performed pilot tests, the reliability of desktop studies was confirmed and the dependency of process parameters on the machine regulated parameters in the quasiresonant frequency range was identified. The analysis of obtained data showed that during machine operation with cone-shaped crushing elements in the quasiresonant frequency range, the yield of the high-quality finished product (WFA grits of -3+1 mm grain size class) in one pass reaches 35%, whereas the form of the particles corresponds to the grain form with sharp edge. The quasiresonant operation mode of the vibrational unit with two freely suspended crushing elements (without stringent kinematic links) provided substantial reduction of energy intensity during crushing down to 0.16 kWh/t, which shows reduction of power consumption for crushing by more than 15% compared to conventional equipment.INTRODUCTION The most common and energy-consuming processes in the mining industry are the crushing and grinding of various solid materials. Such large energy costs are due to the fact that the capabilities of the existing crushing and grinding machines are based on traditional methods of destruction, and are limited by their kinematic features, which do not allow to reduce the energy intensity of processes, to lower the irreversible loss of useful components, to improve the quality of marketable products. In connection with the foregoing, the task of energy costs reducing for disintegration is one of the most important issues in the enrichment of both minerals and processing of man-made raw materials. The solution of this problem is possible only through the creation of a fundamentally new highly efficient technique and technology for processing raw materials [1, 2]. It seems that the greatest prospects in this respect are the vibration methods of disintegration, in particular, the vibratory cone crusher based on a two-mass system without rigid kinematic connections between the crushing bodies, with vertical vibrations of the working bodies. In this machine, the principle of rational material destruction is realized – crushing without re-grinding [3-5]."

Jan 1, 2018

By A. Rousselet, H. Gilbert-Tremblay, A. Berton

"Robex Resources interrupted production at the Nampala Mine in September 2014 following throughput and gold recovery results which were below expectations during the first months of operation. After a thorough plant audit, an important brainstorming took place in order to identify an economical path to resume production. It was clearly identified that a significant investment was necessary at the concentrator prior to restarting the plant, namely the addition of a ball mill and a new elution system.The mineral processing simulation software USIM PAC was used in order to simulate the grinding circuit in design. The simulations’ outputs allowed the ball mill characteristics and the surrounding classification devices to be designed with more accuracy. Many ball mills available from second hand retailers were therefore studied in the simulated circuit. The chosen ball mill, which was in perfect condition, had the advantage of being available for rapid delivery on site.The paper first describes the ball mill sizing method in comparison with the conventional Allis Chalmers method. It then describes the phase 2 concentrator start-up (that took place in 2016) with the commissioning of the ball mill, the classification circuit, the gravity concentration, the four (4) new carbon-in-leach (CIL) tanks, and the Zadra elution system (The phase 1 start-up took place in 2014). It finally provides production data compared to expected simulation data, as commercial production was reached in January 2017.IntroductionDesigning a new concentrator or new equipment within an existing concentrator requires significant efforts to identify possible bottlenecks and their causes (i.e. limiting equipment or sectors) and accurate sizing of major equipment can have a tremendous impact on the economy of the whole project. In the presented case study, the ball mill was the critical equipment and oversizing it could have brought the Capex to a level where the project would not have gone through. Inversely, undersizing the mill could have resulted in lower production and therefore no economic viability for the project once it is in operation.During engineering studies, equipment sizing often relies on a static mass balance and one-by-one sizing of all pieces of equipment. The sizing is then left to the equipment manufacturer or in the case of mills, evaluated with empirical models mostly relying on the Bond equations (Allis Chalmers method) [Rowland and Kjos, 1978]. This methodology shows the disadvantage of not considering interaction between equipment in a mineral processing circuit, especially when recirculation occurs. Also, it has the disadvantage of not using the more advanced grinding models that include the use of the whole particle size distribution as well as phenomenological components by only using limited parameters in the ore particle size distribution (i.e. the P80). This can be explained by the lack of data that sometimes needs to be gathered in order to tune the more advanced models but also by the conservative mindset in mineral concentration engineering which does not always favor the use of process simulation. In many aspects of process engineering, Soutex has demonstrated its affinity to using simulation in order to size equipment with more accuracy, consider process variability, simulate complex systems, and study supply chain management (Berton et al., 2015)."

Jan 1, 2018

By F. S. Hoseinian, K. Filho, D. Deglon, T. Souza, M. Safari

"This paper investigates the reverse flotation of hematite in three laboratory flotation cells with very different contacting environments. The main objectives are to investigate the recovery of coarse quartz by flotation and fine hematite by entrainment. The laboratory flotation cells used were the mechanical, oscillating grid and pneumatic cells. The effect of froth height and solid concentration were investigated in the mechanical and pneumatic cells. The effect of impeller speed and energy input were investigated in the mechanical and oscillating grid cells. Froth height results show that coarse quartz particle recovery decreases almost linearly with increasing froth height due to increased detachment of coarse quartz particles in the froth. Fine hematite particle recovery also decreases almost linearly with increasing froth height due to decreased water recovery and associated entrainment. Agitation/energy input results show that coarse quartz particle recovery increases with increasing impeller speed to an optimum, after which this decreases dramatically. The increase is due to improved gas dispersion, generation of smaller bubbles and increased bubble-particle collision and attachment. The decrease is due to significantly increased bubble-particle detachment at higher impeller speeds. The recovery of coarse quartz particles in the OGC is higher than that in the mechanical cell with an optimum at a much lower energy input. Solids concentration results show that both mass recovery and water recovery increase with increasing solid concentrations. The pneumatic cell achieves higher mass recoveries and lower water recoveries than those in the mechanical cell at equivalent solids concentrations and operating conditions. INTRODUCTIONFlotation is a selective process for separating different minerals from each other. The flotation separation efficiency depends on the recoveries of the mineral species by both true flotation and entrainment (Neethling and Cilliers 2009; Wang et al. 2015). Both chemical variables and hydrodynamic conditions within the flotation cell affect the recovery and selectivity of the flotation process. Cationic reverse flotation of hematite is a common method for selective separation of quartz from iron ores to produce pellet feed. The presence of coarse quartz particles in the tailings and fine hematite particles in the concentrate are two major challenges in the reverse flotation of hematite (Vieira and Peres 2007)."

Jan 1, 2018

By S. M. Narbekova, L. V. Semushkina, Zh. A. Aldybayeva, A. A. Mukhanova, D. K. Turysbekov, N. K. Tussupbayev

More complex and heavy-concentrating oxidized and mixed sulphidic oxidized ores are involved in production because of increasing needs for non-ferrous metals. Extraction of the oxidized minerals of non-ferrous metals general in current technologies. The problem is solved to oxidized polymetallic ores the preliminary selective sulphidization is the oxidized surface of the components by means of hydrogen sulphide, sulphide and calcium polysulphide, and also element sulphur, etc. The task was to study details of flotation of the oxidized lead-bearing ore of the Zarechnoe deposit (Kazakhstan) with calcium polysulphide as sulphidation. According to chemical analysis initial samples of the ore contain, %: lead – 4.8; zinc – 0.1; general iron – 0.81. Phase structure lead is characterized by the oxidized form of 57.76-64.5 %; by sulphidic status of 25.5-32.64 %, and by plyumboyarosite of 19.0-23.02 %. Researches on flotation beneficiation of oxidized lead-bearing ore are conducted. Sulfidizator gave to grinding, on flotations there were used the collector (butyl xanthogenate of sodium) and frother (T-80). Experiments were conducted with a new sulphidizator – calcium polysulphide. The latter is obtained by interaction of CaO calcium oxide with sulfur and water at high temperature with component mass the following ratio S:CaO:H2O =10:5:85. Extent of mill initial ore was optimised (88.42 % of - 0.071 mm grade). For the optimum mill mode the studies on matching of an optimized consumption of sulphidizators are performed. On basic technology with application of sulphide of sodium as a sulphidizator at optimum mill, the lead concentrate with the content of lead 64.4 % at extraction of 86.6 % was received. The content of cerussite in a concentrate was about 14.9 % at extraction of 82.1 %. With application of calcium polysulphide as a sulphidizator the lead concentrate with the content of lead 68.0 % at extraction of 88.0 % was received. The content of cerussite has made 16.0 % at extraction of 85.0 %. Application of a new sulphidizator allows to increase extraction of lead in a concentrate from 64.4% to 68% and cerussite extraction – from 82.1 % to 85.0 %. The possibility of application of calcium polysulphide as a sulphidizator instead of conventional sulphurous sodium was established.

Jan 1, 2018

By C. Newman

"Over the past decade, as conventional underground deposits have been depleted, mining operations have been forced to produce at greater depths and in more geologically and geometrically challenging conditions. As such, there has been a global increase in the application of cemented paste backfill (CPB) in tabular deposits utilizing open stope mining method with a delayed backfill placement. Despite the extensive use of CPB, many fundamental factors affecting the design of safe and economical fill structures are still not well understood. A critical issue in the design of backfilled stopes is the determination of stress states within the fill material itself as well as the surrounding rock mass. Analytical equations provide a means of quickly evaluating the effectiveness of a given design. However, in developing these equations large assumptions are implemented to simplify the design problem. It is important that one understands these simplifications as well as their effect on the overall design. This paper investigates common analytical equations utilized in the evaluation of single vertical backfilled stopes and their assumptions through comparisons to numerical modeling results. INTRODUCTION AND BACKGROUND As the mining industry continues to produce at greater depths and in more geometrically and geologically complex conditions, cemented paste backfill (CPB) has gained traction as a means of providing localized ground support in modern stope-and-fill mining operations. The application of CPB in stope-and-fill mining as a ground support material has led to the reduction of mine waste costs, while increasing both mine production and stability. In an attempt to achieve total extraction of the mining reserve, stope-and-fill mining operations often employ a primary-secondary excavation-support sequence (see Figure 1). In this practice, primary stopes are initially excavated and then backfilled in a two-stage pour; plug and final pours. During the first stage (plug), a CPB material with increased cementitious content is placed at the bottom of the stope providing a strong base from which to build a backfill structure as well as protect mine works from material breakthrough. Following placement, the backfill plug is allowed to cure to a given strength as designated by the mine design. Upon achieving the required cure strength, a less cementitious CPB material is used to backfill the remaining stope area. This is referred to as the final pour stage. With all primary stopes excavated and supported using backfill, the extraction of the secondary stopes commences as primary stopes are utilized as artificial pillars. While the application of CPB in a primary-secondary extraction-support mining sequence allows for a substantial increase in reserve recovery, it is imperative the mining personnel and planning engineers have a clear understanding of the material’s behavior and stress interaction with the surrounding rock mass to ensure the most efficient, cost-effective, and safe extraction of underground deposits."

Jan 1, 2018

By V. V. Morozov, I. S. Barmin, A. V. Tugolukov, V. V. Polivanskaya

"It was presents the results of research on improving reagent regime and scheme of enrichment of slime classes of Apatite-Staffelite ores and tailings stockpile of Kovdorsky enrichment plant. It was investigated the regularities of flocculation in the processes of thickening and selective flotation apatite-bearing ores. It was established character of the influence of flotation reagents on the flocculation process. It was shown that the sodium silicate and soda ash have a stabilizing effect by thickening of sludges. Neonol and oleic acid have a coagulating or flocculating effect. It was tested the new regime flotation, involving an initial conditioning with using of reagent - dispersants before feeding the pulp into the flotation and subsequent conditioning with reagents having a coagulating effect. The flowsheet and reagent regime for enrichment of fine-grained tailings stockpiled was developed, which providing production of standard apatite concentrate and increasing the recovery of valuable components. There are presented results of the research of activities of strong organic surfactant on solubility of colloidal form fatty acid collector and aggregate stability of fine minerals in the process of thickening and flotation. Surfactants such as Neonol have been investigated for increasing the activity of the collectors. When using the process of thickening sludge fraction with flocculant Praestol 2540 and stadial conditioning of sludge were obtained concentrates containing up to 38.1% P2O5 at recovery. INTRODUCTION A feature of the Apatite-Staffelite ores of the Kovdorsky deposit is the presence of a large number of fine mineral particles and a reduced hardness of phosphate minerals (Beloborodov et al., 2010, Tugolukov et al., 2012). Formed in the ore-preparation process, sludges are lost with a discharge in the thickening operation. Sludge is characterized by an increased content of phosphorus pentoxide (P2O5). Losses of P2O5 at enrichment of the stale tailings of Kovdorsky GOK reach 14.0%. The high losses of P2O5 caused a profound study of the behavior of thin apatite classes under conditions of thickening and flotation."

Jan 1, 2018

By T. Saastamoinen, N. Heino

"The Olserum deposit located in Sweden hosts an indicated mineral resource of 4.5 million tonnes over 0.6 % TREO, exhibiting a relatively high proportion of HREE. Beneficiation of a composite drill core sample was studied in the flowsheet of magnetic separation of magnetite followed by REE minerals flotation. Primary testwork was performed to select an effective REE mineral collector and then the parameters of grinding size, collector and depressant dosages, slurry pH and density, conditioning time and temperature, and flotation time were tested for optimization of REE flotation. The studies of process mineralogy showed that the REE-bearing minerals monazite, xenotime and apatite were successfully enriched from the concentrations of 0.6%, 0.31% and 2.6% in the feed to those of 17.0%, 8.9% and 65.0% in the concentrate with the recoveries of 79.0%, 81.3% and 71.0%, respectively. INTRODUCTION The Olserum deposit located in Sweden comprises lower grade placer material with higher grade apatite-magnetite veins and hosts an indicated mineral resource of 4.5 million tonnes at 0.6% TREO, with 34% of that being HREO (EURARE, 2017). The mineralization was studied by Andersson et al. (2018). At early stage, high-temperature REE is characterized by abundant monazite-(Ce) and xenotime-(Y) coexisting with fluorapatite and subordinate amounts of (Y,REE,U,Fe)-(Nb,Ta) oxides. During a subsequent stage, allanite-(Ce) and ferriallanite-(Ce) formed locally, partly resulting from the breakdown of primary monazite-(Ce). Alteration of allanite-(Ce) or ferriallanite-(Ce) to bastnäsite-(Ce) and minor synchysite-(Ce) at lower temperatures represents the latest stage of REE mineral formation. The mineralogy and beneficiation were firstly studied by GTK Mintec in the EURARE project for a composite drill core sample. The Olserum is considerably smaller than the Norra Kärr deposit. However, REE are hosted by xenotime and monazite, both of which have well established processing pathways, and meanwhile, the Olserum has a high contribution of the high value critical REE (dysprosium (Dy), yttrium (Y), neodymium (Nd) and terbium (Tb)), which provide a unique advantage for its exploration (Tasman Metals Ltd., 2013). In this paper, flotation of the REE minerals in the Olserum ore was studied."

Jan 1, 2018

By D. Purdie

"This paper aims to remind researchers, designers, operators, and managers about the benefits of seeding in the design of precipitation stages in their flowsheet. Including a high density solids (HDS™) process encourages the precipitating solids to form on the surface of existing precipitated particles. This paper discusses the application of the HDS technology at Kennecott Smelter, where the authors have witnessed significant improvements in settling and filtration rates. The authors have also applied this technology at various smelter bleed treatment plants worldwide with similar improvements in precipitation and filtration rates. HDS is a registered trademark of De Nora Water Technologies. RÉSUMÉ Cet article a pour objectif de rappeler aux chercheurs, aux concepteurs, aux exploitants et aux administrateurs les avantages de l’ensemencement dans la conception des étapes de précipitation de leur schéma de traitement. L’introduction d’un procédé des boues haute densité (procédé HDS™, de l’anglais high density sludge) encourage la formation de substances solides précipitantes à la surface des particules précipitées existantes. Cet article porte sur l’application de la technologie HDS à la fonderie Kennecott, où les auteurs ont observé des améliorations importantes au niveau de la vitesse de sédimentation et de filtration. Ils ont également appliqué cette technologie à diverses usines de traitement des rejets liquides des fonderies dans le monde entier, et ont constaté des améliorations similaires en termes de vitesse de précipitation et de filtration. Le procédé HDS est une marque de commerce déposée du fabricant De Nora Water Technologies.INTRODUCTION In 1966, the lead author worked as an assistant smelting metallurgist for the Tsumeb Corporation Limited copper and lead smelter in Tsumeb, Namibia. The smelter produced copper and lead, as well as cadmium and arsenic trioxide as byproducts. The cadmium was concentrated in the lead blast furnace off gas dust, and was collected by a baghouse. The baghouse dust was leached with dilute sulfuric acid (H2SO4) in a batch process. The iron and arsenic in the solution were oxidized with potassium permanganate (KMnO4) and basic ferric arsenate (BFAS; Fe(AsO4)x(SO4)y(OH)z·wH2O) was precipitated using milk of lime. The cadmium was cemented from the purified solution using zinc dust."

Jan 1, 2018

By S. I. Anufrieva, N. A. Permyakova, E. G. Likhnikeevich

"Russia’s rare metal reserves are composed of compositionally and structurally complex ores and are characterized by an increased content of natural radionuclides due to their geochemical similarity with rare metals. For instance, concentrates of Zashikhinsky daeposit are characterized by an increased content of uranium (0,06%) and thorium (0,59%); Beloziminsky deposit holds pyrochlore-apatite-magnetite-carbonate ores characterized by increased radioactivity (130 mkR/h) and containing 0,0016-0,0025% of uranium; Etykinsky deposit is characterized by columbite-pyrochlore-microlith mineralization with an average ore grade of 0,013% of uranium and 0,0020% of thorium; eudialyte concentrate of Lovozero deposit (Alluaiv area) belongs to Class II of mineral reserves. Industrial development of these mineral reserves involves the need to comply with environmental standards, public health requirements applicable to finished core and by-products, to take into account the amount and class of the generated radioactive waste, the possibility of disposal or recycling of the radioactive production waste. Concentration processes of radioactive rare metal feeds most often lead to a concentration of natural radionuclides and their accumulation in concentrates. Comprehensive hydrometallurgical processes are currently under development for such concentrates, aimed at producing salable products compliant with the radiation safety standards. The choice of the hydrometallurgical processing method for radioactive rare metal concentrates is based on the mineralogical component of the concentrate, textural and structural features, the distribution of valuable components and impurities, and the content of radionuclides. A systemic approach to the selection of processing methods, in particular integrating several methods, is an effective solution. Methods may not only be combined, but also inextricably linked with each other. Hydrometallurgical processing methods include leaching by acidic and alkaline agents; sulfatization for selectively decomposing the minerals and moving the bulk of U and Th into solution; fluorine extraction process. Methods of precipitation and co-precipitation, extraction (by liquid and solid extractants), sorption, and ion exchange are used to decontaminate the solutions by removing thorium, mezathorium, uranium, and their radioactive decay products. Agents used in hydrometallurgical processing of radioactive rare metal ores include sulfuric, nitric, hydrochloric, hydrofluoric acid, alkali (NaOH, KOH), sorbents (for example, AB-17) for sorption of uranium and extractants (mono- and bidentate organophosphorus compounds, diamides, etc.) for the extraction separation of rare, rare-earth, and radioactive elements."

Jan 1, 2018

By Masaomi Kurihara, Seiya Kawano, Norihiro Yamaji, Satoshi Shiokawa, Nobuyuki Okamoto, Hironobu Sakurai

Seafloor polymetallic sulphides are distributed in the EEZ of Japan, including substantial deposits in the Okinawa Trough and Izu-Bonin back-arc basin. In this new frontier, the successful development of these resources in Japan is expected to bring about a new domestic supply of mineral resources. The initial stages of this development are authorized by the Basic Plan on Ocean Policy, approved by the Japanese Cabinet on April 26, 2013, and the Plan for the Development of Marine Energy and Mineral Resources, formulated by the Ministry of Economy, Trade and Industry (METI) on December 24, 2013. In 2008, the Japan Oil, Gas and Metals National Corporation (JOGMEC), commissioned by METI, began a survey and technological development programme for the development of the seafloor polymetallc sulphides (PMS) based on these Plans. The examination of four different fields: the evaluation of the amount of the resource, environmental assessment, mining technology, and processing & smelting technology, are concurrently promoted, aiming for commercialization as soon as possible. Based on the results of research for properties of geomorphology and marine environments of the target test sites in the Okinawa trough, which have been ongoing for several years, the preparation of the pilot lifting test included an in-situ excavation and crushing test conducted using test excavating and crushing systems.

Jan 1, 2018

By D. E. L. Zapata, O. J. R. Baena

"INTRODUCTION Mining is a fundamental part of the historical and economic development of a country. In Colombia, this is reflected from pre-Columbian jewelery, to being now one of the first exporters of coal worldwide, in 2017, the Colombian mining sector contributed approximately 6% of GDP (Ministerio de Minas y Energía, 2017). Coal, nickel, gold, platinum, emeralds, limestone, salt, phosphate rock, clays, siliceous sands and to a lesser extent copper, manganese, magnesite, barite, gypsum and various types of ornamental rocks, among others are produced (UPME, 2016). The contributions of mining activity in the economic dimension is more measurable, on the contrary in other dimensions, as the social and environmental, for this, every day there are new proposals and tools oriented to strengthen how to evaluate the contributions in terms of the sustainability and responsibility, with the aim of quantifying, concreting and non-utopian, to improve the life quality of a community and not only to comply with reporting and gaining prestige. Colombia has a generalized increase in the mining sector where the levels of informality and illegality are evident only 10% of mining activity is legal (UPME, 2014), also, the mining sector is accused of human rights violations, high levels of inequality, poverty and the affectation of ecosystems due to bad environmental management, among other situations (ACNUDH Colombia, 2015). This problem has generated rejection to the realization of the mining activity in many places of Colombia. At this point, it is important to clarify this problem is more complex, different actors are involved in this conflict, but it is an evidence that is needed a sustainability model for specific realities such as the Colombian mining. This situation in the current mining activity, is similar to the chemical industry situation three decades ago, because of an extensive problem in relation to repeated work accidents, natural disasters and indications as a highly polluting and unsustainable industry, with the aim of improving, not only this public perception, but also in the way of carrying out the business activity. Thus, in 1985, the Canadian Chemical Producers Association released the Responsible Care Program (RCP) (ICCA, 2015). Being aware that companies were responsible for the affected lives in some way by the operation and needed to improve workers safety, environmental protection and most importantly how legal persons should comply with the law, but go beyond this. RCP is most recognized sustainability initiative in the chemical sector, companies associated are recognized for having high quality standards, continuous improvement, visibility, corporate ethics, environmental and social management (ACC, 2015). In addition, to meeting the objectives is set out the creation of a model that increasing reputational sector levels. This initiative is considered to be a worldwide successful case of reporting corporate responsibility indicators and contributions to sustainability from the industry sector to local development (BASF Group, 2016)."

Jan 1, 2018

By A. Lewis

"Thiol collectors including the xanthates and dithiophosphates have dominated the sulfide mineral processing industry for over a century. Tecflote represents completely different chemistry, without sulfur or phosphorus, and will float all sulfides and associated precious metals. As these collectors are surfactant in nature, they comprise a head group which binds to mineral surfaces, a spacer and a long hydrophobic tail. The modification of the spacer behind the head group allows for collector optimisation for different sulfide ore types and process conditions.The Tecflote surfactants have been designed to be either very selective against pyrite at the natural pH of the ore (pH 7-9) or to float all sulfides including pyrite. Depending on the ore type and the process flow sheet, the use of lime can be maintained, reduced or completely eliminated.Tecflote can be used either as a rougher collector giving good recovery and grade for the sulfide minerals or it can be used to target valuable minerals after regrind and through cleaner flotation. It has repeatedly shown to be very effective at holding onto gold through the cleaner steps. The low solubility has a significant impact on the mechanism and surface activity of the collector, resulting in a very different flotation response compared to conventional thiol collectors.INTRODUCTIONXanthate was first made in 1882 by Zeise and first used in flotation in 1924 (Keller, 2018). In 1946 Keller patented thionocarbamate as a collector, which was produced by Dow Chemicals (Keller, 2018). Later it was replaced by Dow product Z-200, while dialkylthionocarbamate was discovered by Harris et al. (Harris, 1954. No significant chemistry change to collectors has occurred since they were introduced in the mid-20th century and now that the feed grades have been declining over the last decades creating a need to find more selective collectors to extract difficult and complex ores and pushing the industry to look at other reagents."

Jan 1, 2018

By L. J. Li, Q. Zhang, Z. H. Liu, Q. L. Chen

Phosphogypsum (PG) is an industrial waste from the production of phosphate fertilizer. The utilization of PG is restricted by its containing impurities, and the pretreatment is crucial to eliminating these impurities. The purpose of the research is to recycle pretreatment PG as raw material for preparation of a-calcium sulfate hemihydrate (a-HH) by salt solution method. The effect of pretreatment technologies of lime neutralization and washing on dehydration rate, phase composition and morphology evolution of a-HH were investigated by crystal water content analysis, XRD and SEM. Furthermore, the change of pH in the reaction process was also discussed in detail. The results show that the dehydration rate of conversion PG to a-HH increases and the corresponding induction period, crystal growth period and total time decrease with an increase in CaO dosage from 0.2% to 0.6%. In the presence of 0.4% CaO or 0.6% CaO, the a-HH presents a long hexagon-prism-shaped crystal with a purity of 94%, and the end face of a-HH presents polyhedron. The system pH sharply decreases with the reaction time under different CaO dosage, and the pH variation from the initial alkalinity to acidity. The main reason is that as the co-crystallized phosphorus dissolved and released HPO42-, and with the pH decreasing to 4-5, HPO42- transformed into H2PO4-. The dehydration rate of washing PG is lower than that of original PG. Compared with the original PG, a-HH with the larger width and smaller aspect ratio can be achieved from the pretreatment PG subjected to lime neutralization and washing, meanwhile the crystal surface is more smooth.

Jan 1, 2018

By Mingfei He, Yude Gao

"The leaching kinetics was studied during leaching of indium-bearing zinc oxide to recover indium. The effects of temperature, sulfuric acidity, particle size, stirring rate on dissolution rate of indium were investigated. Results showed that the leaching process was controlled by chemical reaction at the condition of low sulfuric acid concentration. While the acidity increased to 1.8 mol/L, the leaching process was transformed into an internal diffusion controlling model . The corresponding value of reaction orders under low acidity and high acidity were 1.194, 0.156, respectively. Further calculation results indicated that the leaching reaction activation energy was only 10.97kJ/mol under the condition of high acid. The leaching rate constant was inversely proportional to the square of particle size, while the effect of stirring rate on leaching process was insignificant. The leaching process can be enhanced by increasing the temperature and acid concentration, as well as the decrease of particle size. And a final kinetics eqution was proposed. KEYWORDS Indium, extration, leaching kinetics, zinc oxide INTRODUCTION Indium[1,2] plays an important role in many aspects of living and industrial production owning to its special physical and chemical properties. The reserve of indium is rare on the earth, and most of indium is distributed in some other minerals[3]. Some researchers [4,5] have proposed that indium mainly substitutes for the lattice of other minerals by isomorphous. Therefore, the extraction of indium should take into account of the production technologies of those minerals to comprehensively recover the valuable metals."

Jan 1, 2018

By S. J. Prout, J. M. Lang, D. Lascelles, K. Sarinas

"There is a growing demand for ore characterization methods to support metallurgical development programs from a true geometallurgical perspective. Today, there are multiple automated mineral analysis systems on the market, many of which are based on conventional mineral liberation data. However, liberation data can be limited when assessing the floatability of a mineral to predict its recovery as it doesn’t consider the surface area available for collector absorption and bubble attachment; whereas mineral exposure measurements can. Using the First-Order Rate equation to predict the recovery versus time of variously exposed particles, a model has been developed to predict the recovery of copper sulphides at a particular grind size. This model provides the opportunity for the prediction of copper recovery and grade from multiple, small-scale samples. These predicted values can be imported into resource modeling software, and guide the domaining of geometallurgical units within the ore body. Data has been analyzed from various global copper porphyry systems and compared with actual flotation testwork.IntroductionAs part of the development of a mining project, resource estimation primarily focuses on the definition of the quantity and grade of the ore in the deposit; as the project evolves from preliminary economic assessment through to feasibility, the geological model is usually further populated with hardness and recovery data.The CIM Definition Standards (2011) identifies measured mineral resource as the part of a mineral resource for which quantity, grade or quality, densities, shape, and physical characteristics are estimated with confidence sufficient to allow the application of “modifying factors” to support detailed mine planning and final evaluation of the economic viability of the deposit as an asset. The modifying factors include, but are not restricted to, mining, processing, metallurgical, infrastructure, economic, marketing, legal, environmental, social and governmental factors.With market fluctuations, many investors in the mining industry have become more and more risk averse which has increased the demand for more reliable data to support these modifying factors. This has led to the widespread use of geometallurgy and statistical analysis to better inform the resource estimation. Geometallurgy is used to characterize ore variability and is especially useful for highly variable or strongly zoned deposits, several close deposits that will be milled together, projects requiring complex or new metallurgical approaches, brownfields or sight-of-mine exploration, expansion projects that exploit new, deeper or adjacent reserves, and projects with significant legacy drill core that are being re-evaluated due to new economic circumstances."

Jan 1, 2018

By Mostafa Mossaad, Ali Helwa, Manal Salem

Support of excavation (SOE) design practice tends to model SOE elements using two-dimensional (2D) analyses to avoid the complexity associated with three-dimensional (3D) analyses. Such practice overlooks soil arching in the horizontal plane and prevents designers from accounting for elements such as capping beams as part of the statical system. This study simulates square excavations supported by cantilever slurry walls in dry cohesionless soil using 2D and 3D finite element (FE) models. First, side support wall behavior is compared from 2D and 3D FE models for variable excavation length to depth (L/H) ratios. Second, the effect of slurry wall lateral bending stiffness on wall behavior is studied by modeling the wall using plate element with isotropic and anisotropic wall stiffness. Finally, the sensitivity of cantilever wall behavior to the presence of capping beam is illustrated. The study concludes that unbraced excavations with L/H ratios greater than 5 almost resemble plane-strain conditions. Slurry walls are better simulated in 3D FE models by dividing the plate element into discrete panels or by assigning anisotropic bending stiffness to the plate element. Finally, the presence of capping beam affects the behavior of cantilever walls resulting in reduction of deflections and redistribution of bending moments. INTRODCUTION Support of excavation (SOE) design practice ranges in complexity from conducting simple hand calculations to performing three dimensional numerical modeling depending on several factors among which is the geometry of the design problem. This paper addresses walls that are designed using numerical modeling, and discusses the factors governing the choice of the most suitable modeling approach. It has been believed for a while that modeling excavations using 2D numerical models would lead to a more conservative solution, which turned out to be incorrect in specific cases. This paper attempts to describe cases where 2D finite element modeling could be on the conservative side and other cases where it could be less conservative than the more complex 3D modeling.

Jan 1, 2018

By D. Jamróz, A. Surowiak, T. Niedoba, P. Pieta

"The separation of coal material of three types of coals originating from three various Polish hard coal mines (types 31, 34.2 and 35, according to Polish nomenclature, which were steam coal, semi-coking coal and coking coal) into particle size fractions and then into particle density fractions was done and then the following parameters were measured for each particle size-density fraction: combustion heat, ash contents, sulfur contents, volatile parts contents, analytic moisture. In this way a 7-dimensional vector of data was created. Using methods of factor analysis the important features of coal were selected, which decide about their membership to individual types. To evaluate the appropriateness of the applied method the Bartlett’s sphericity test as well coefficient of Kaiser-Mayer-Olkin (KMO) were used. To select important factors the Kaiser criterion and Cattell’s scree test were used. The obtained results were compared with the results obtained in previous works by means of observation tunnels method. The results showed which particular features are crucial to define the type of coal what is also important to select appropriate method of its enrichment.INTRODUCTION Coal extracted from the mine is often a mixture of coals of various quality originating, for example, from various coal layers. One of the most important issues is to determine its quality, what means to verify if it fulfills certain requirements. Usually, such parameters as combustion heat, ash contents, sulfur contents, volatile parts contents and analytic moisture decide what the coal quality is (Drzymala, 2009). Such investigations are expensive and time consuming. That is why it seems to be important to determine the mutual connections and interactions between them what would make possible to reduce the amount of the necessary parameters. This issue was already investigated with successes in several works [Jamróz and Niedoba, 2013; 2014; Niedoba, 2015]. This work is another approach to this problem. Here, the investigation of possible reduction of researched parameters was done on the basis of the factor analysis. The obtained results confirm the earlier observations."

Jan 1, 2018

By M. Rudolph, E. Schach, M. Buchmann, T. Leißner, N. Krupko, U. Peuker, M. Kern

"In mineral processing, density and magnetic susceptibility are two very fundamental properties. For the beneficiation of valuables to produce a saleable concentrate a detailed understanding of these properties is essential. Especially when it comes to the processing of cassiterite, which is the main mineral for tin production, they become highly prominent. Due to the chemically inert character of cassiterite towards most industrial applied leaching agents, density and magnetic separation processes are mainly applied for its beneficiation. To guarantee an optimized utilization of the different operations not only cassiterite but also the different gangue minerals have to be considered. In this study, a skarn ore is characterized by density and magnetic susceptibility. Therefore, the material was first split into different density classes by heavy liquid separation. The obtained classes were further separated by their susceptibility to finally obtain a density-susceptibility matrix. For this purpose, an isodynamic separator was used. A more detailed characterization of the materials is done via gas pycnometer, magnetic susceptibility balance and vibrating sample magnetometer to estimate the characteristics of density and susceptibility for the various classes. Further, the determination of the chemical assay and the mineral intergrowth by mineral liberation analysis is used to generate a three dimensional database for detailed characterization of the present ore. The objective of this study is to estimate potential material streams for a modular processing plant via characterization of the material for the entire deposit by the two afore mentioned characteristic properties. The established multidimensional data matrix, enables predictions for the separation properties of the material and contributes to the characterization of the deposit within the context of geometallurgy."

Jan 1, 2018

By M. K. Jain, Z. T. Xu, M. Bruhis, V. Hegedekatte

"Strain rate and temperature dependent deformation conditions are present during elevated temperature forming of aluminum and other metallic materials. While many constitutive laws have been proposed to represent such deformation conditions, a closer investigation often reveals their limited applicability in terms of fit to the experimental data, and interpolation within and extrapolation outside of the range of experimental stress-strain curves. This is often because material-specific primary deformation mechanisms of temperature-dependent strain and strain rate hardening are poorly captured. In the present work, the Voce-Kocks constitutive model based on mechanics of dislocations storage and annihilation has been found to be suitable for many metallic materials. The model was modified to include the effect of temperature dependent shear modulus. The modified model is then employed to represent the experimental data obtained from uniaxial tensile tests on AA7075-O sheet at elevated temperatures and strain rates. Also, hot gas bulging tests were conducted to verify the applicability of this model. Further, finite element simulation of the hot gas bulge test was performed by incorporating the model as a user material subroutine. Good general agreement was observed between the experimental and FE model predicted results. Some sources of discrepancy in the prediction are also discussed.INTRODUCTION There has been much interest in light-weighting of automobiles from automotive related industries to reduce overall carbon footprint and increase energy efficiency of the vehicles. Aluminum alloys, and especially the medium-strength 5xxx and 6xxx series alloys, have been the primary focus in the last 3 decades to reach the above environmental goals (Huo, Hou, Zhang, & Zhang, 2016) whereas aerospace industry has traditionally focused on high strength 7xxx series aluminum (Al-Zn-Mg-Cu) alloys for structural components (Deng, Yin, & Huang, 2011). Recently, there has been much interest in high strength 7xxx series aluminum as a replacement for heavier steel automotive structural parts such as A-pillar, B-pillar, side impact beams etc. (Harrison & Luckey, 2014). This is both interesting and challenging since the above aluminum structural parts will need to not only meet impact safety standards but also possess sufficient formability for manufacturing such complex parts. Since the formability of high strength 7xxx series materials is quite poor at room temperature, much interest has focused on improving both formability and final part strength via high rate hot stamping, in-die quenching, and subsequent artificial ageing process steps (Kumar & Ross, 2016)."

Jan 1, 2018