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By J. W. Davis

The storage stability characteristics of a diesel type fuel were determined to evaluate the effect of the polar compounds in the fuel. These compounds, comprising most of the nitrogen and oxygen containing compounds and many sulfur containing compounds, were separated from the fuel with a chromatographic column. This fraction was further separated into three polar extracts by graded elution through the column. Each extract was characterized. A storage program using the depolarized fuel, the fuel as received, and blends of the extracts with both fuels, was conducted. Results showed that the removal of the more polar components stabilized the fuel. Blending the polar extracts with the original fuel and with the depolarized fuel in the same ratio as they existed originally and at two and three times the original ratio increased the amount of gum present before storage, but had little effect on the formation of additional gum during storage. Distillate fuels produced by commercial refining of petroleum contain traces of organic nitrogen, sulfur, and oxygen compounds that are more polar4 than the remainder of the fuel. Recent laboratory studies by the Federal Bureau of Mines (1),6 in which these compounds were removed from a fuel, have shown that they influence its storage stability. The objective of this work was to determine the amount of these compounds present in a fuel and their effect upon its stability in storage. To evaluate the role of these polar compounds, it is necessary to remove them from the distillate fuel. Many can be removed by chemical treatment (2), but such treatment precludes reblending the polar components to approximate the original fuel composition. Solvent extraction is free of some of the criticism of chemical treatment, but it is more difficult because of the complex mixture from which compounds must be removed.

Jan 1, 1961

By F. William Bloecher, William B. Plank

CURRENTLY 12,892 students are enrolled in the mineral engineering schools of the United States and Canada, marking an all-time record high for these schools. It shows a remarkably rapid recovery from the effects of World War II. Enrollment in all the other engineering branches has also increased but not so rapidly as in the mineral engineering branch. Almost all the data in this report are from the eighth questionnaire study of the mineral engineering schools made, as formerly, under the auspices of the Mineral Industry Education Division of the AIME. Every school is represented in the data, for which the authors thank the deans and professors who supplied the information. For this reason, the data of all the studies are comparable, an achievement not always possible in endeavors of this kind. For comparison with the general engineering enrollment situation, data are included from the January 1947 issue of the Journal of Engineering Education.

Jan 1, 1947

By Stéphane Bourg

The SCRREEN project gathers more than 50 European initiatives, associations, organisations or independent experts working on Critical Raw Materials (CRM) into a long-lasting network including stakeholders, public authorities, and civil society representatives. SCRREEN contributes to improve the CRM strategy in Europe by (i) mapping primary and secondary resources and substitutes of CRMs, (ii) estimating the expected demand of various CRMs in the future and identifying major trends, (iii) providing policy and technology recommendations for actions improving the production and the potential substitution of CRM, (iv) addressing specific waste electrical and electronic equipment (WEEE) and other End-of-Life (EoL) product issues related to their mapping and treatment standardization, and (vi) identifying the knowledge gathered over previous years and making the data accessible to those beyond the project. As a first step, SCRREEN worked at providing stakeholders with a comprehensive analysis of the current use of the CRM, the mapping of potential primary and secondary resources, and identification of the key technologies used in their production. Substitution profiles, analysis of European business and policy issues pertinent to CRMs, and an identification of the standards, policies, and regulatory frameworks concerning these CRM was also completed. In a second step, to be conducted between mid-2018 and mid-2019, SCRREEN will provide guidance for improving the CRM market in Europe by identifying opportunities from research, development, and innovation (R&D&I) that could reduce the supply and/or economic risks around the most relevant CRM for Europe.

By N. A. D. Parlee, I. D. Shah, W. C. Phelps

THIS note reports on a continuation of a program on the thermodynamics of Fe-S-X systems in the "steel-burning" temperature range begun by Bock, Barloga, and parlee.' Small coils of 0.039-in.-diameter pure iron (Ferrovac-E) wire were equilibrated with Fe-S-0 melts in ingot iron crucibles under argon at 1324°C in the assembly shown in Fig. 1, the lower part of which was heated in a large Globar furnace. Fig. 1 shows (R) the coiled iron wire sample, (M) the Fe-S-0 melt prepared from desired proportions of ferrous sulfide and ferric oxide, (K) the iron crucible, (I) a mullite guide tube, (J) an alumina crucible, (L) alundum sand, (N) crushed mullite, (Q) hollow cylinders of K30 brick, (C) a steel rod, (B), (El, (F), (G), (P), and (O), details of brass water-cooled head, and (H) a mullite tube 2-3/4 in. ID and 26 in. long. The rod (C) bearing the sample could be removed at will and be replaced by a tube for sampling the melt, or by a thermocouple for comparing the melt temperature with a control thermocouple not far from the 2-3/4-in. mullite tube. After equilibration the iron coils were treated with acid to remove the outer layer of metal and then they were analyzed for sulfur by a standard combustion method. The melt samples were analyzed for oxygen by a variation of Lander's2 hydrogen-reduction method for mattes, and for sulfur by the ASTM combustion-iodometric method NO. E 30-47. When the results of some forty-two runs were examined it was found that the sulfur and oxygen contents of the equilibrated melts showed good consistency, in that the plotted compositions fell along the smooth curve shown in Fig. 2. The points on this curve represent the experimental compositions of melts in equilibrium with ?-iron (Fe-S-0) solid solutions. These solid solutions are saturated with sulfur and oxygen with respect to the melt and therefore have the same sulfur and oxygen activities as the melt. The curve drawn through the points therefore delineates the ? liquidus. It falls in such a position as to roughly confirm the liquidus curves of Hilty and crafts3 at 1200" and 1300°C which are

Jan 1, 1965

By D. A. Lindsey

Gravel lithology affects the quality of aggregate because different rock types in gravel have different physical and chemical properties. The lithologic composition of alluvial gravel reflects the composition of its source terrane and the variable effects of weathering and transport on each rock type. This report discusses lithologic controls on aggregate quality in the mountain-front environment of the Colorado Front Range. Lithologic controls on aggregate quality of gravels were evaluated using pebble count data. Gravel lithology along the Front Range shows both temporal and regional variation. The principal variable in gravel lithology is quartz plus quartzite, of which quartzite is commonly more abundant. Large quantities of metaquartzite derived from the mountain front southwest of Boulder, Colo., were dispersed northeastward during deposition of the oldest Front Range gravels. Average quartz plus quartzite is greatest in the oldest gravels. Aggregate quality is probably enhanced by large quantities of quartzite. Abundant volcanic rocks in gravel may enhance aggregate quantity, but such occurrences are local in extent. Abundant sedimentary rocks in gravel, mainly sandstone near the mountain front, may decrease aggregate quality.

Jan 1, 2002

By A. R. Barnes, N. O. Lotter

Recoverable economic copper sulphide minerals such as chalcopyrite, bornite, chalcocite and covellite often occur together in varying proportions in the major copper-bearing ores, and have individual flotation requirements and characteristics. Pyrite also occurs in these ores to varying extents as the sulphide gangue, and is problematic because of its natural tendency to float quickly and easily. In a bulk sulphide float, selectivity against pyrite is desirable, particularly if it does not host other paymetals such as gold or silver. At the same time it is a requirement to float all of the copper sulphides despite their electrochemical differences. The electrochemistry and semiconductor properties of these minerals are reviewed, together with implications for flotation with and without collector addition. Mixed collector systems for the improved flotation of these sulphides are proposed as a solution. The use of xanthate and dithiophosphate in the collector suite allows the co-existence of dixanthogen and free dithiophosphate radical because the latter has a higher redox potential requirement than xanthate to oxidise to the dithiolate. Because some of these minerals require dixanthogen, and others, free thiolate, to generate surface hydrophobicity, a bulk flotation of all the species becomes possible in the overlapping area of Eh and pH between the two dithiolate equilibrium lines on the Pourbaix diagram. The arsenic-signature copper minerals are added to the study, since many copper operations encounter arsenic as a penalty element in the saleable concentrate. It is shown that the addition of arsenic to the copper and iron sulphides alters the semiconductor and electrochemistry properties, and in turn, its flotation characteristics. The degree of mineral association and liberation between these minerals can be a complicating factor due to textural associations, and should also be considered in the process as a next step.

Jan 1, 2016

By S Adamson

Morphological analysis of alluvial gold recovered from the same segment of a placer by four common commercial methods indicates that gold shape and the presence of quartz intergrowths or sulphide overgrowths substantially influence the recovery efficiency of each method. The amount and types of gold saved by each method varies according to the different hydrodynamic conditions under which each of the methods operates. Reverse circulation drilling has the lowest efficiency and preferentially loses moderate-high flatness gold and intergrown or overgrown gold particles with relatively low density. Gravity riffle, hydraulic riffle, and jigcentrifugal concentrator systems respectively save progressively more of these problematic gold morphotypes, but still lose significant and sometimes substantial amounts (of profit) to the tailings. Because of the differences in recovery efficiency, reverse circulation drilling probably underestimates the grade of most placers and may have resulted in bypassing several economic deposits. Losses to tailings by commercial recovery plants arise from inadequacies in fundamental plant design features. These inadequacies compromise plant efficiency by limiting the ability of plants to simulate the wide range of hydrodynamic conditions necessary to operate effectively throughout placer systems. Incorporation of sand pumps and multiple recovery methods into the more sophisticated plants only partly overcomes these inadequacies. At best, efficiency will be maximised in a few segments of the placer determined by individual plant design, and will decrease progressively upstream and downstream of those segments. Without prior knowledge of the morphological characteristics of the gold to be mined, it is difficult to choose the most appropriate plant design, or to estimate what proportion of the gold will be recoverable by any given plant. If the relevant relationships are not considered beforehand, the recovery plant is likely to lose a significant proportion of the gold, and sacrifice maximum profit.

Jan 1, 2001

By Edward L. McHugh

In 1984, at the request of the Bureau of Land Management, the U.S. Bureau of Mines studied an 84,165-acre portion of the 84,935-acre Clover Mountains Wilderness Study Area (NV-050-139) in order to evaluates its identified mineral resources. The area studied is in Lincoln County, NV, about 90 miles north of Las Vegas, NV. No mineral resources were identified in the study area. Volcanic rocks are the most common in the study area, consisting mainly of a thick sequence of ignimbrites in a cauldron complex. Cambrian to Triassic marine sedimentary rocks and Cretaceous to Oligocene clastic rocks are along and partly inside the west and south sides of the study area. No mineral production ha s come from the study area, but gold, silver, copper, and fluorspar have been mined nearby. Eleven mines and prospects in or adjacent to the study area were examined. Workings inside the study area include two shafts, 10 and 60 ft deep, and eleven shallow prospect pits at four sites along the west edge.

Jan 1, 1987

By Robert Stefanko

With passage of the Clean Streams Act of the Commonwealth of Pennsylvania and its impact on the coal industry, considerable research has been conducted to explore various approaches to the problem, including deep-well disposal. Available drillhole data from gas and oil wells were used to develop cross -sectional maps for various portions of the state and potential disposal zones were evaluated. Bethlehem Mines Corp., faced with a severe water problem at its Marianna operation in Washington County, cooperated with the Dept. of Mining at The Pennsylvania State University in establishing a 1500-ft well into the Salt Sands for the purpose of determining the feasibility of mine water disposal. The thickness, porosity, and permeability of the formation at the well site proved to be below what had been anticipated from drillhole data. Further, subsequent hydraulic fracturing did not improve the flow characteristics of the well; pumping pressures remained in the range of 1800-2000 psig for disposing of water at the rate of 150 gpm. The legal problems of disposal at the site were very formidable. When the Salt Sands proved to be less than satisfactory, permission could not be obtained to dispose in other promising formations. The paper details many of the problems associated with the experimental well and makes an assessment of the potential for deep-well disposal of mine water. The concept of disposing of liquid industrial wastes by deep-well injection is not a new one. Brines associated with crude oil long have been disposed of in this manner, with the additional benefit of aiding secondary oil recovery. More recently, with the expansion of nuclear energy, the lethal, highly radioactive wastes which are by-products of the fission process have created severe disposal problems. During the past ten years, a variety of industries have resorted to subsurface disposal, some of the details of which are given e1sewhere.l,2 The list reveals wide variations in injection rate, pumping pressure, cost, and waste disposition. Included are successful installations in Western Pennsylvania. Enactment of more restrictive clean-water legislation in Pennsylvania recently had a great impact on the coal industry. Among its provisions was the reclassifica-tion of most mine water as industrial waste whose dis-posal is prohibited in any stream of the Commonwealth. This had the effect of accelerating research in a variety of areas, although treatment methods still retained primary interest. When a feasibility study of deep-well disposal was proposed to the Pennsylvania Dept. of Mines and Mineral Industries, the Coal Research Board (CRB) approved it. This paper summarizes the efforts on this project. Acid mine water is a chemically complex liquid. having no definite quantitative relationship among its constituents. However, it is the iron disulfide (FeS2) associated with practically all coal seams that produces the objectionable products present in acid mine water when combined with air and water. The principal contaminants are sulfuric acid (H2SO,) and ferric hydroxide (Fe(OH)2. Ferric hydroxide is a rust-colored gelatinous precipitate that coats stream bottoms and destroys aquatic life. However, other ions and bacteria are present in acid mine water in varying amounts.

Jan 1, 1971

By M. Mohan Rao

A Sievert ' technique was used. The few determinations made on 10 per cent and 20 per cent V alloys did not show any deviations from Sieverts' law up to I>N2 = 1 atmosphere. The same held true for alloys of 0.2 per cent Ti. Nitrogen absorptions in Fe-Ti alloys, containing from 0.50 to 0.77 per cent Ti at 1,600°C, follow Sieverts' law at low PN2 values, but, due to the formation of a delta titanium nitride phase, deviate from this law beyond critical values of PN2? There is evidence that this phase is Ti1.1N. The behavior observed can be described by the followmg equations: Ti,.,N(o) = 1.7Ti + N K = (fT; ? % Ti)1?7 (f;;.? %~_) = 0.0020 K = fN. %~ = 0.042 '\)-:>N 2 I NTRODUCTJON Nitrogen's solubility in liquid iron-vanadium alloys was investi-gated briefly by Brick and Creevy ( 1), and more extensively by Kash-yap and Parlee (2) and by Pahlke and Elliott (7). Nitrogen's solubility in liquid iron-titanium alloys

Jan 1, 1963

By Stephan A. Jefferis

I presume that the questioner is not asking about the reduction of sulfate in groundwater to hydrogen sulfide as a result of biological activity promoted by organics in the grout hardener and that the question relates to sulfate attack on cementitious grout systems. For the project in Spain presented in my paper, we used a very high pulverized fuel ash (PFA) content in the cementitious material. This gives good sulfate resistance and indeed the chemical interaction will actually cause the permeability to drop for about 50 years without any question of sulfate attack and damage to the whole thickness of the grout - of course there will be attack at the exposed face of the grout where it is in contact with the contaminated groundwater. The mix had over 75% PFA, and also a very high overall cementitious content. The mix was the contractor's design and showed excellent behavior in laboratory proving trials. In grouts as distinct from concrete, PFA gives significantly better sulfate resistance than ground granulated blast furnace slag which is often used in Europe as a component of bentonite-cement mixes for slurry trench cut-off walls.

Feb 10, 2003

By J. Koster

[In 1178 thn S-00n of thr !~Viluralcal Divicion, pur--'11 cf Mines, bcran an o. 't iv in': n-t!Y_Vnn of vothod; for recoverin'-1, Achol, copp~r, nK precioun notnin Zycn o;. -z of tic Bunkcrvillo KOH& in Clark County, Tcv. Tho Bunkcrvillo ran arc of t,-j)(,e of -iincrilization similar to that of 02 SWbury, Ontario, CannO, nichvl dc-?o?-:.t,. At prcoont, only n anall tonnes? p of ore has loan cxDr)scd in t*ic' :hui:er7ilIp rc: inn, ann. there is decided nce! for orjn: izod OrospectiAg ina drvclo-nnnt "crk there. It wann believod, howevar, t4it the dc,cuits varo 3ilficUntly siSnIficant to warrant an investigation iito their]

Jan 1, 1939

By D. Lusinga

Hydrocyclones are a common feature in almost all mining operations in the world, serving mainly as classifiers. Some of their advantages include low capital costs, low space requirements and their ability to reduce residence time in closed circuit grinding processes. Although an extensive body of literature exists for hydrocyclones, these devices are still inherently inefficient, and more research is currently being undertaken, particularly in the field of modelling. In the vast body of hydrocyclone literature published so far, there has been little or no effort devoted to analysing the effect of the cone force ratio on the performance of hydrocyclones. The cone force ratio is defined as the ratio of the spigot to the vortex finder diameter (Shah, 2005). In this study a total of 44 tests was carried out in a custom-built rig at the University of Cape Town. These tests were aimed at evaluating the effect of the cone force ratio on the performance of as mall diameter hydrocyclone. The cut size and water split were used as the criterion for evaluating the performance of the hydrocyclone. Results from the tests showed that the cut size decreased with an increase in the cone force ratio. The cut size also appeared to decrease as the calculated locus of zero vertical velocity (LZVV) shifted inwards. The water recovery to the underflow appeared to increase with an increase in the cone force ratio. The effect on the cut size of adjusting the cone force ratio was found to be higher for a coarser feed than it was for a finer feed.

Jan 1, 2009

By A. W. Lovett

"THE last two years have been years of recession or, perhaps, years of marking time, depending upon whether the observer is a pessimist or an optimist. There has been a slackening in the industrial tempo that has been reflected in many ways in the national economy. As one of the chief barometers of economic health, the consumption and supply of energy reflect this slowing up.These same two years have also seen significant changes in the relation between the sources of energy. In periods of declining demand, it has happened in the past that coal, as the basic or residual source of energy, has shown the effects to a greater extent than the other energies. In these two years, however, in addition to this usual effect, there has been the acceleration in the Joss of market to diesels in the railway consumption category and the continuing decline in domestic consumption. The story of these years is presented in the statistical tables that form the foundation of this paper. Statistics, particularly in the form of tables, are rather dry and are sometimes difficult to follow but the overall developments are illustrated by graphs which present a more striking picture."

Jan 1, 1959

An extensive series of tests was carried out on a ball mill-rake classifier circuit in the New Broken Hill Consolidated Ltd. concentrator. The data were used to develop a mathematical model of the operation of a rake classifier and this model has been used in the simulation of the performance of a ball mill-rake classifier circuit on a digital computer. As a result of this simulation it has been possible to develop a technique for the optimization and control of a circuit which includes these units.

Jan 1, 1967

A sinter plant baghouse dust has been treated as a hazardous solid waste, and disposed at a very high price. A series of leaching tests were conducted to examine the possibility to produce high grade potassium chloride from the solid waste. It is found that around 40% of the solid wastes can dissolve into water, and a deposit with more than 90% KCl can be produced after simply drying the solution.

Jan 1, 2009

By Lianyang Zhang

For optimal design of rock socketed shafts used to support axial loading, it is important to predict the end bearing capacity. The existing empirical methods for determining the end bearing capacity of rock socketed shafts use the empirical relations between the end bearing capacity, qmax, and the unconfined compressive strength of intact rock, sc. Since rock socketed shafts are supported by the rock mass (both intact rock blocks and discontinuities separating them) not just the intact rock, one should consider not only the intact rock properties but also the influence of discontinuities when determining the end bearing capacity. Although the effect of discontinuities may have been implicitly (partially) included in the empirical relations derived from the results of load tests, it is not clear how big the effect is and how much of it has been included. In this paper, a database consisting of 50 test shafts, 25 of which contain the RQD (rock quality designation) value, is developed. Using the database, the applicability of the existing empirical relations is evaluated and two new empirical relations between the end bearing capacity, qmax, and the unconfined compressive strength of rock mass, scm, are derived. The new empirical relations explicitly consider the effect of discontinuities by using scm which is directly related to RQD. Finally, an example is presented to demonstrate the application of the newly derived relations.

Jan 1, 2008

By J. West

For many years line-of-sight (LOS) issues for underground mobile equipment is a growing focus of research. This research is a result of the numerous fatalities and injuries which occur in the mining industry and which are related to poor operator LOS. Three assessment methods are currently used to assess operator LOS of underground mobile equipment. The light filament (LF) method is a hands-on assessment method that is performed in the field. This method is not evaluated in this paper. The laser scan (LS) method of assessing equipment is a quick and reliable method that comes from the need to evaluate vehicles already located in the field. The computer simulation (CS) method can assess LOS issues using a computer aided drawing (CAD) model, which is useful for assessing current or prototype models. The purpose of the current research is to compare and validate different operator LOS assessment methods. Comparison of the results of the LS and CS visibility plots yielded similar quantifiable results. A visual comparison of the results further illustrate that the LS and CS methods are acceptable assessment tools for mobile equipment operator LOS evaluation. The visibility assessment methods are now being prepared as guidelines for the mining industry to assess current and potential designs.

Jan 1, 2007

By J. West

For many years line-of-sight (LOS) issues for underground mobile equipment is a growing focus of research. This research is a result of the numerous fatalities and injuries which occur in the mining industry and which are related to poor operator LOS. Three assessment methods are currently used to assess operator LOS of underground mobile equipment. The light filament (LF) method is a hands-on assessment method that is performed in the field. This method is not evaluated in this paper. The laser scan (LS) method of assessing equipment is a quick and reliable method that comes from the need to evaluate vehicles already located in the field. The computer simulation (CS) method can assess LOS issues using a computer aided drawing (CAD) model, which is useful for assessing current or prototype models. The purpose of the current research is to compare and validate different operator LOS assessment methods. Comparison of the results of the LS and CS visibility plots yielded similar quantifiable results. A visual comparison of the results further illustrate that the LS and CS methods are acceptable assessment tools for mobile equipment operator LOS evaluation. The visibility assessment methods are now being prepared as guidelines for the mining industry to assess current and potential designs.

Jan 1, 2007

By David C. Kraft

Helical piles and ground anchors were used to meet critical design and constructability requirements for an urban forest Canopy Walk at the Atlanta Botanical Garden, Atlanta, GA. The 12-foot wide pedestrian walkway path was to be nestled among the treetops of a forest, extending to 600 ft. in length, and soaring 40 ft. high above the forest floor. Of particular concern during construction was that the foundation system for the temporary steel shoring system had to be non-invasive to the subsoil, could not damage the forest floor, trees, root systems, or foliage, and upon completion of the concrete walkway pour, could be removed, again without disturbing the subsoil. Accubrace, Inc. designed and installed all the helical foundation types, as well as provided steel braces, typically used in Tilt-Up building construction, for the walkway project. The braces, some extending to 43 ft. in length, were used to provide lateral support against wind loads for the walkway form. In addition, the braces acted as secondary support for lateral loads during the placement of wet concrete along the 600 ft. length of the walkway. Helical foundation products installed included vertical compression piles, ground anchors for tension rods, and ground anchors for the braces. The installation of the piles and anchors was particularly challenging since the forest floor elevation varied as much as 50 ft. due to the presence of a ravine. Information is provided on the subsoil conditions, required loads, design, installation, and acceptance criteria for each helical product type installed for the project. The results of vertical and lateral load tests on the helical piles in the pre-construction phase, conducted in conformance to project specifications are presented. Photographs to illustrate the nature and complexity of the project are included. The concrete pour for the walkway was successfully completed on December 12, 2009, and the walkway was opened for visitors in May, 2010.

Jan 1, 2011