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Cokriging uses a sparsely sampled, but accurate and precise primary dataset, together with a more abundant secondary data-set, for example grades in a polymetallic orebody, containing both error and bias, to provide improved results compared to estimation with the primary data alone, as well as filtering the error and mitigating the effects of conditional bias. The method described here may also be applied in polymetallic orebodies and in other cases where the primary and secondary data could be collocated, and one of the data-sets need not be biased, unreliable, etc. An artificially created reference data-set of 512 lognormally distributed precious metal grades sampled at 25×25 m intervals constitutes the primary data-set. A secondary data-set on a 10×10 m grid comprising 3200 samples drawn from the reference data-set includes 30 per cent error and 1.5 multiplicative bias on each measurement. The primary and secondary non-collocated data-sets are statistically described and compared to the reference data-set. Variograms based on the primary data-set are modelled and used in the kriging of 10×10 m blocks using the 25×25 m and 50×50 m data grids for comparison against the results of the cokriged estimation. A linear model of coregionalization (LMC) is established using the primary and secondary data-sets and cokriging using both data-sets is shown to be a significant improvement over kriging with the primary data-set alone. The effects of the error and bias are filtered and removed during the cokriging estimation procedure. Thus cokriging using the more abundant secondary data, even though it contains error and bias, significantly improves the estimation of recoverable reserves.

Jan 1, 2014

By H. Powell

"This paper discusses how elemental analysis of conveyed bulk flows in real time using PGNAA (Prompt Gamma Neutron Activation Analysis) technology has resulted in significant improvements in advancing plant control in mineral processing operations. PGNAA through belt, full stream, continuous, multi-elemental, real time analysis technology is explained. Capabilities and limitations in plant operating environments are discussed including comparison with other real time, on-line technologies through review of published information available for on-conveyor minerals applications. Case studies include an iron ore and copper-gold company, both of which consider the technology an essential component in advanced plant control necessary in new process flow sheet designs, rather than an optimisation tool.INTRODUCTION Process operators rely on supply of a reasonable ore quality and consistency from the mine. Unfortunately neither the mining nor process operators have much control over the ore quality once it has been put into the crusher. Grade control typically stops once the material is designated as ore and the process plant operator needs to process it irrespective of quality. Plant control is most effective when technologies measure process streams directly and preferably in real time. Measuring sampling streams that are not representative of the primary flow will result in incorrect plant control decisions. Sampling coarse conveyed flows is expensive and impractical at many operations, however, this does not mean those flows cannot be measured. Investigations to find techniques suitable for real time elemental analysis have focussed on the application of known laboratory techniques to process streams. For conveyed applications, development of neutron irradiation techniques were most promising and early studies indicated potential success for bauxite measurement (Beurton et al, 1995). Tran & Evans (2001) concluded there was no equivalent technology to PGNAA in terms of material penetration power and that the technology was eminently suitable for basic industries such as cement. Nelson and Riddle (2003) evaluated PGNAA for possible use in the phosphate industry by using a unit installed in a cement plant to test performance on phosphate samples and ultimately recommended its use for further characterisation of the mine’s various ore types to improve stockpile allocation and grade control"

Jan 1, 2014

By N. L. Ayres

Tendon support systems have been successfully used to stabilize excavations. Tendon support systems are routinely designed using the axial load-bearing capacity of tendons, namely the tensile strength. To attain tensile strength the tendon must be loaded along its length, which often does not occur in practice. Tendons should optimally be installed at 90° to the surface of the excavation to achieve maximum penetration depth, yet this is often not physically or practically possible, and installations at angles less than 90° occur. Furthermore, the intersection of geological features within the rock mass frequently results in complex loading situations on tendons. The position and angle at which loading occurs results in different combinations of tensile and shear forces acting on the tendon, which can impact on the support performance of each unit and ultimately the whole system. All factors that influence the support system should be understood and taken into account to ensure a sound support design. Combination loading situations are further investigated and tested to obtain a better understanding of the mechanisms involved and the effects on tendon load-bearing capacity. Tendon support units were tested at different installation angles to establish the tendon performance, mechanical behaviour, and load capacity during these loading situations. The results and outcomes are aimed at providing rock engineers with additional data and improved understanding of how tendons could perform under certain conditions.

Jan 1, 2014

By Gabsoo Kim, Rulin Yang, Dave Kay

Blast vibration data, such as PPV are usually scattered. In many cases, plots of PPV versus the charge weight scaled distance are so scattered that useful trends from different blast designs cannot be identified. The scattering of the data may be attributed to the inaccuracy of the PPV measurement, the definition of the scaled distance from a multiple-hole production blast, and the measurement of distances and charge weights. The error from vibration measurements is one of the major contributors to the scattering of the plots. If accurate monitoring is conducted, improved design options may be identified. This paper documents two case examples that compare different vibration sensor couplings. The first case shows mounting accelerometers at spots that protrude from the ground, compared with the sensors that were mounted on a flat ground surface. The second case compares data from loose-sand buried geophone with that from sensors coupled to the ground using concrete blocks.

Jan 1, 2014

By I. M. London, G. P. Hatch

The Canadian Rare Earth Elements Network (CREEN) was formally launched at the Rare Earth Symposium at The Metallurgy and Materials Society of CIM (MetSoc) Conference of Metallurgists in October 2013. CREEN is an industry-led, multi-stakeholder network focused on providing collaborative solutions that will advance Canada’s REE sector to produce a significant proportion of the global production of separated critical rare earth products by 2018. The Network is industry driven by companies with REE projects under development and supported by universities, engineering firms, national and commercial laboratories, and government. CREEN aims to accelerate the development and delivery of timely solutions to technical and economic issues specifically facing Canada’s emerging rare earth sector. It will facilitate partnerships with other national and international organizations to leverage existing research initiatives. It will also support training and education to ensure that the needed qualified human resources are available to achieve the sector’s goals. CREEN membership spans the full rare earth supply chain and technical support organizations, from prospective producers, advanced project developers, national and commercial laboratories, engineering consultants, university researchers, and other innovators. This paper provides an update on CREEN's developing networking and project develop

Jan 1, 2014

By H. Cay, J. Zachwieja, T. Esplin, R. Ravenelle, T. Olsen-Tank

Barrick Goldstrike mine utilizes a carbon-in-leach (CIL) circuit to simultaneously leach gold into solution with cyanide and adsorb the gold-cyanide complex onto activated carbon for further refinement. If the gold bearing ore contains a significant amount of native carbonaceous material, gold cyanide can be adsorbed at these sites instead of onto the desired activated carbon and the gold is effectively lost to tailings in a detrimental process known as "preg-robbing." The preg-rob effect is considerably reduced by treating the ore with a surfactant, which is hypothesized to adsorb to and passivate the native carbon surfaces. Past laboratory and pilot studies have consistently demonstrated significant gains in gold recovery after treating carbonaceous ore with surfactant. With success in bench and pilot scale testing, a plant trial was conducted at Barrick Goldstrike to evaluate the feasibility of using an alkoxylated fatty amine surfactant (Ethomeen T/12) to aid in the leaching of high preg-robbing ores. This paper analyzes the performance of the surfactant during the plant trial in addition to the problems that occurred during the trial period. Suggestions for improvement are also discussed.

Jan 1, 2014

By Carmina Quintanar, Mario Palominos

"The mining industry is currently facing significant challenges to identify and adopt sustainable collector chemistry that effectively recover value minerals in difficult-to-process low-grade resources. These are typically characterized by complex mineralogy and the presence of significant amounts of penalty gangue sulfide minerals, especially pyrit which is a challenge to separate from value minerals at many major mine operations. Three chemical strategies for dealing with gangue sulfides and penalty elements are: a) selective flotation of value minerals while rejecting penalty minerals in the whole circuit, b) rejecting penalty minerals in an appropriate part of the circuit using selective depressants, c) using a combination of selective collectors and depressants in appropriate parts of the circuit. This paper will evaluate different strategies for dealing with those penalty elements and propose the most efficient alternative. New products and application technologies have been developed in the past 25 years by Cytec for implementing these strategies as dictated by the particular needs of a given plant. However, in recognition of the growing interest in meeting the sustainability challenges, Cytec Research and Development have been focused in the development of greener products (collectors, modifiers and frothers) and processes using FLOTATION MATRIX 100TM approach used to develop the optimal collector system for each specific ore. An overview of these new developments is given in this paper using case studies of application of selective collectors and polymeric modifiers including the newer, greener chemistries."

Jan 1, 2014

By K. Halada

Current trend of the global flow of strategic metals are analyzed to discuss the strategy of the development of recycling technology and alternative technology. In many cases, each global flow of metal is changing from the trilateral structure of U.S., EU and Japan in the later 20th century into the convergence to China as the factory of the world. Scrap flows are also changing dynamically. A long term change of prices of metal has gotten changed since the entrance of this century. The estimation of metal consumption up to 2050, in which the author estimated that many kinds of metal will overshoot the reserve base line, is revised considering these change of current trends.

Jan 1, 2014

By Rick Ellman, Ian Chaney

"The Hampton Roads area encompassing the Norfolk, Virginia Beach and Newport News metropolitan region experiences some of the worst traffic congestion in Virginia. With continued growth of the ports and increasing demand, the Virginia Department of Transportation (VDOT) initiated the Downtown Tunnel/Midtown Tunnel/MLK Expressway Project, a complex undertaking critical to addressing the Hampton Roads area’s transportation needs. The project is a $2.1 billion Design/Build/Finance/Operate (DBFO) endeavor most notably involving the construction of a new two-lane vehicular tunnel utilizing the Immersed Tube Tunnel (ITT) method. The tunnel will pass under the Elizabeth River parallel to the existing Midtown Tunnel between Norfolk and Portsmouth, Va. It will be the largest design-build project constructed in the history of the Hampton Roads District.The New Midtown Tunnel will extend approximately 6,450 ft (1,966 m) along the north side of the existing tunnel where it ties into the existing Midtown Tunnel approaches in Norfolk and Portsmouth. It is being installed in a pre-excavated trench of which approximately 2,250 ft (686 m) required bracing on the Portsmouth side and approximately 1,000 ft (305 m) required bracing on the Norfolk side. The remaining 3,200 ft (975 m) of trench excavation was open cut dredging with laid back side slopes, optimized to reduce dredging, disposal and backfill quantities while also reducing the risk to the existing tunnel. The braced excavation portions of the tunnel alignment were divided into distinct segments which include: Portsmouth Approach Boat Section, Portsmouth Approach Cut-and-Cover Section, Portsmouth Dredge Section, Norfolk Dredge Section, Norfolk Approach Cut-and- Cover Section and the Norfolk Approach Boat Section. All “approach” excavations were performed in the dry and all “dredge” excavations were performed in the wet. Eleven ITT segments are being fabricated in the Sparrows Point Dry Dock facility in Baltimore, Md., and each 14,000 ton (12,700 tonne) segment is being towed approximately 220 mi (354 km) to the site. The ITT segments will extend under the Elizabeth River, with the deepest crossing 90 ft (27 m) at the Federal Navigation Channel. Once beyond the channel limits the ITT rises at an approximate 4.5% slope. Controlled screeding and element lowering operations will be performed primarily from floating barges."

Jan 1, 2014

By Roger Payne, John R. Goode, Feng Gao, James Brown

The Eco Ridge deposit is located in the Elliot Lake mining camp in Northern Ontario, Canada. Between 1955 and 1996, the area produced more than 138,000 t (300 million pounds) of U3O8 and very significant amounts of thorium and heavy rare earths. Based on the NI 43-101 Preliminary Economic Assessment by Roscoe Postle Associates (RPA) dated June 2012, and the economic review by RPA as announced in Pele Mountains’ Press release dated September 12, 2013, the Eco Ridge Mine Project would extract and process 46 Mt of material to produce about 19,000 t (42 million pounds) of U3O8 and about 65,000 t of rare earth oxide (REO) over a 14-year life. This paper discusses process optimization studies including beneficiation and hydrometallurgical testwork. The proposed modified flowsheet includes the flotation and processing of 1) a pyrite concentrate, 2) a dominantly light rare earth elements (LREE) concentrate, 3) a concentrate containing most of the balance of the uranium and heavy rare earths (HREE), and 4) a relatively inert tailings.

Jan 1, 2014

By L. A. Heim, E. A. McCullough, N. J. Amiotte

The explosives industry is subject to the laws of multiple jurisdictions, which means that several regulatory agencies are responsible for governing different aspects of the commercial explosives industry. Among these regulators are the Mine Safety and Health Administration (MSHA) who implements codes that better ensure both occupational and public safety which is influenced by professional blasting projects and the Bureau of Alcohol, Tobacco, Firearms and Explosives (ATF), who enforces commercial explosives storage and security, among other responsibilities.

Jan 1, 2014

By Paolo Cavalcoli, Marco Ziller

"ABSTRACT: In the year 2010 the State of Denmark together with the Municipality of Copenhagen, launched a very important and complex Project : the complete construction of a new double Subway Line :the CITYRINGEN.Copenhagen is the capital with a metropolitan population of 1,9 million.This line is like a ring placed in the very town center which includes all the most historical and monumental buildings and churches, with a total length of 17 km, and the presence of 17 stations plus 4 service shafts.The buildings have been built in the last centuries in an area where the groundwater is near to the surface and there are lakes and channels: the techniques adopted were advanced for those times, but limited as far as regards settlements and resistance to horizontal movements.The soil consists in 2 main groups.1.Upper sediments of the glacial ages : thickness total = 5-20 m composed by clay- silt-sand-gravelcobbles- granite boulders and flint in blocs and in layers : frequency and size of these obstacles wherenot determined.2.Limestone layers : 2a. upper limestone : highly fractured ,highly permeable2b.Itermediate limestone : less fractured, medium permeability.2c. Lower limestone : almost not fractured, low permeability.2d Bryozoan limestone : composed by fossils with microscopic dimensionsIn all the limestone formations there are important layers of flint , having thickness variable up to 3 m and important extensions. Water : in a part of the areas of the Cityringen the water is drinkable and utilized in the public waternet.Pollution: there are polluted zones due to previous industrial activities. Benzene areas have been identified, and for those areas special protections against pollution have been implemented.METROSELSKABET ,the public owner of the Cityringen,has set as priority to operate for the construction of the Cityringen the full protection of the environment and the respect of all the stakeholders :Very strong limits for the exhausted gas emissions have been introduced, by far stronger than those applied from the State of Denmark, very strong limits for the acceptable noise emission. And last but not least very important safety measures and procedure to avoid any accident on site."

Jan 1, 2014

By Silas C. Nichols

"Abstract Piling and deep foundations are a staple for transportation projects in the United States (US). Driven or bored piles have been used for everything from support of bridge foundations and retaining structures to support of culverts and embankments on soft ground. Deep foundations have been popular in the US transportation market to better handle large axial and lateral loads, extreme event loading, and to better control structure movement. However, there are challenges in the maintenance of design and construction codes in transportation for consistent and reliable structure foundation elements. A significant amount of effort continues in the US to maintain national codes and specifications at a level consistent with the state of practice, and identify and conduct research for providing safe and cost effective highway structures.IntroductionThe transportation sector in the United States has a hierarchy of design and construction codes that are used for the specification of piling and deep foundations. Any highway or bridge project on the National Highway System (NHS) must be designed and constructed in accordance with a national set of standards approved by the State Highway Departments, and that are acceptable to the Federal Highway Administration (FHWA). However, in any jurisdiction, exceptions are permitted with approval. Therefore, design may be governed by the national standard specification, a state standard specification and design manuals, special provisions, or guideline specifications. Any of these standards, or a combination, may be used depending on the needs of the owner agency.The FHWA and the American Association of Highway and Transportation Officials (AASHTO) have worked together in the development and maintenance of geotechnical design and construction guidance and codes that support the surface transportation community. General geotechnical engineering practice in the United States lacks a singular, national design and construction code that addresses all aspects of geotechnical engineering. As a result, the AASHTO specifications provide the most complete geotechnical specifications focusing on structure foundations, retaining walls, and buried structures for surface transportation applications. This includes piling and deep foundation types commonly used for support of bridges and transportation structures.The FHWA National Geotechnical Team has published several technical guidance documents that include guideline specifications for the design and construction of driven and bored deep foundations. Reference documents published by FHWA summarize the state of practice and provide recommended design and construction guidance. These reference documents have long served as a basis for provisions included in the AASHTO specifications. Maintenance of the design code and specification, and related guidance documents for consistent use on US transportation projects requires a collaborative effort between industry, FHWA, and the member state highway departments that make up AASHTO."

Jan 1, 2014

By S. Q. Zhu

A newly developed coal flotation collector ZFC and its flotation characteristics for five different coals were introduced in this paper. ZFC is an emulsion composed of 27% diesel oil, 70% water and 3% surfactants. The main surfactant is synthesized with oil which is environmental favorable and reproducible. Compared flotation experiments show that, at the same dosage, ZFC give 2%~5% recovery promotion than typical collector with only a slightly ash content increment, but saving 70% diesel oil. Zeta-potential and Wetting heat measurement indicate that the surfactant helps the interactions between oil and coal particles, the industrial application tests in several coal preparation plants demonstrate that ZFC is suitable both in technical and economical aspects.

Jan 1, 2014

By Adnan A. Malik, Tadashi Maejima, Jiro Kuwano

"ABSTRACTTheoretical approach to estimate the ultimate pile capacity gives a rough idea at the initial stage of design that later on strengthen by the execution of static pile load test at site. The static pile load test is the only best option for the estimation of ultimate capacity of various types of piles. There are various methods based on strength, serviceability, net deflection for end bearing, shaft adhesion, graphical and extrapolation approaches for the interpretation of pile load test data to calculate the ultimate capacity. In this paper an attempt is made to evaluate the best-fit method for the estimation of ultimate capacity of single helix screw pile. The pile load tests on model scale were performed on screw piles of different helix diameter. The purpose of adopting model scale of testing was to achieve a state at which settlement increases without further increase in vertical load. The ground was compacted with dry sand at denser state. It was observed from the test results that extrapolation methods such as Chin- Kondner and Decourt predict the load settlement curve of screw piles very well, however ultimate pile capacity was on higher side which may not be suitable for the strength of helix plate. Decourt approach to plot the pile load data showed clear indication of the deformation of helix due to strong subsurface condition. A modified approach in Decourt method is proposed for estimating the ultimate capacity of screw pile having deformed helix whereas reduction factor is suggested for Chin-Kondner method for the estimation of ultimate capacity of intact screw pile.INTRODUCTIONDeep foundations are used to avoid the soft ground at shallow depth that is not suitable for carrying the structural load. Different types of piles have been used to transfer the load to deeper stratum. The screw pile is one of the new piling method and its use is considerably increasing. It consists of a cylindrical steel shaft with one or more helices at various length of the shaft. The diameter of helices (Dw) is usually 2 – 2.5 times the shaft diameter (Ds). The pile is installed to the required depth through torque and pressure. The advantage of screw pile over other piling system is its quick installation mechanism, high end-bearing and uplift resistance, noise reduction and minimum use of man power."

Jan 1, 2014

By Phillip J. Mackey, Gerardo R. F. Alvear F.

It is now 38 years since the publication of the first edition of "Extractive Metallurgy of Copper" by Professor W.G. Davenport and the late Professor A.K. Biswas. The text book would be issued in a total of five editions, soon became the standard for students and those in industry. Interestingly it was published at the onset of great change in the industry. This was a time when sulphur dioxide controls in the USA were introduced, and almost simultaneously, world oil shocks caused significant increases in the cost of fuel - all leading to efforts to adopt new technology and move away from the reverberatory furnace, which had no potential for sulfur capture and required large amounts of fuel. At the time of publication of the book, new processes such as the Noranda Process and the Mitsubishi Process were in their infancy, while flash smelting (which was first commercialized in 1949 at Harjavalta, Finland) had made significant in-roads in boosting copper output, with some 22 new flash smelters licensed by 1976. Computer technology and associated process control techniques were rudimentary compared to systems today, available physico-chemical data remained largely in tabulated format and needed to be manually entered into the main frame computers of the era, while modeling techniques common today had not yet been developed. The copper industry has therefore seen immense changes since the time of this textbook: world tonnage of smelted copper has risen from 7.34 million tonnes/year in 1976 to 16.7 million tonnes/year in 2012, over a two times increase. Technologies such as the El Teniente Process, or Top Submerged Lance technologies, typified by the ISASMELTTM, not commercialized at the time, now treat large tonnages of copper concentrate in a single furnace. Advanced heat and mass balance software and thermochemical modeling are now used extensively to examine chemical and physical characteristics for process design and to support process optimization. These changes in the industry have been chronicled in subsequent editions of the book. This paper looks at the issues and problems seen in 1976 and over the intervening years, and compares this with the challenges facing the industry with the available tools and technologies today. Some ideas looking into the future are also discussed in the paper.

Jan 1, 2014

By Masaki Kitazume

"Abstract The wet type and dry type of deep mixing methods have been developed and widely applied for on-land and marine constructions in Japan. The quality assurance (QA) of the methods has been usually carried out by unconfined compression test on field stabilized soil sampled by core boring in Japan. In some other countries, stabilized soil excavated by the wet grab sampling instead of core sampling is often subjected to unconfined compression test for quality assurance. There are several merits and demerits in each method, but few studies have been carried out to compare the stabilized soil strength of these two types of specimens to discuss their applicability to practical construction. The author has conducted a series of field and laboratory tests to compare the stabilized soil strength and discuss the applicability of wet grab sampling to QA for wet and dry types of deep mixing method.In this study, the wet grab sampling was carried out at two road embankment construction sites where the wet type and dry type of deep mixing were applied. The cement stabilized soil was excavated at the three depths by a wet grab sampler soon after the DM column construction. The test result is compared with the other test data in the previous study to discuss the applicability of the web grab sampling method for QA of cement stabilized soil.IntroductionThe Deep Mixing Method (DMM), an in-situ soil stabilization technique using cement and/or lime as a binder, is often employed to improve soft soils (Kitazume and Terashi, 2013). A variety of factors and their interactions affect the eventual strength of a deep-mixed column, while some of which are controllable (e.g. binder type and dose) by engineers while the others are not (e.g. soil types, ground temperature, etc.; Babasaki et al., 1997). In addition to laboratory mix tests, which in essence are a parametric study to estimate the influence of these factors on a particular soil’s strength, the quality assurance (QA) practice in Japan usually involves unconfined compression test on sampling cores from the stabilized columns after a given curing period. It has been recognized, however, that the ‘field strength’, or the strength of the retrieved core, quf is on average lower than the ‘laboratory strength’, qul, evaluated by laboratory mix test. Also allowing for the inevitable variability, existing guidelines (for example, PWRC, 2004 and CDIT, 2008) recommend the design quf /qul values of, for example, 0.5-1.0 for the CDM (Cement Deep Mixing; a wet-type technique, in which binder is added as slurry) and 0.2-0.33 for the DJM (Dry Jet Mixing; a dry-type technique, in which binder is added as powder)."

Jan 1, 2014

By Claude Bazin, François Robichaud

The control of the operation of a semi autogenous grinding mill is mainly based on power and bearing pressure measurements. Image based sensors can provide on-line measurements of the size distribution of the ore feeding a SAG mill allowing the control of this variable that impacts the operation of this equipment. This paper investigates the potential of using the information from such type of sensor to maintain a SAG mill feed target size distribution by manipulating the speed of the ore extractors below an ore stockpile. A PID and adaptive predictive controller for the size distribution are studied using a simulator for a stockpile and the equipments used for ore withdrawing from the pile. The proposed controller is found to give a good performance while remaining easy to tune.

Jan 1, 2014

By Jing-she Li, Hai-yan Tang, Cheng-song Liu, Wei Liu

"In order to effectively utilize cheap and low quality iron ores, a hematite ore in a certain steel plant in Xinjiang was researched on to obtain ""iron increase and silicon reduction"" by ore dressing operation experiment and the performance indexes of the hematite ore were optimized. Based on the fundamental characteristics and high-temperature properties of the concentrate after ore dressing and other five kinds of iron ores which were co=only used in this steel plant, ore matching principles were proposed and a sintering ore blending optimization model was established. Finally, sinter pot test was carried out to verify the validity and practicability of the sintering ore blending optimization model which was aimed at giving consideration to the sintering indexes and the cost.IntroductionIn recent years, the price of imported iron ore with high quality is always at a high level, while iron ore self-sufficient rate in China is less than 50%. Enormous market demand and high dependence of domestic enterprises on imported iron ore makes the price of it hardly return to rational. In order to get rid of the situation of long-term meager profit and even deficit, more and more iron and steel enterprises in China transit their focus of reducing production cost to the utilization and development of relatively cheap but low-grade iron ore resources at home[l-4l_ However, besides the disadvantages of low iron grade, high content of impurities and complex embedded properties, the high-temperature properties of iron ore often go beyond the suitable ranges for producing sinter with high quality. Thus directly utilization of this kind of iron ore without ore dressing process would probably affect the metallurgical performance and indexes of sinter ore.Previous research and production practice have shown that traditional iron ore matching in sintering mainly focus on the reasonable collocation of properties of iron ores with low quality and high quality, but pay less attention to ore dressing process of low quality iron ores and matching them with high quality iron ores. Actually, compare with directly utilization, iron ores with low quality after ore dressing have higher suitability for matching with high quality ones which is beneficial to reduce the consumption of iron ores with high quality and control the production cost of sintering [5-s1."

Jan 1, 2014

By Young-Dae Kim, Dong-Sic Kim, Jong-Jin Pak, Kyung-Hyo Do

"Sulfur is one of the most harmful elements in stainless steel (SIS) products and the specification of sulfur content is getting more severe for high grade SIS. In order to accurately control the desulfurization reaction in high chromium containing SIS melts, it is important to know the thermodynamic interaction between chromium and sulfur in Fe-Cr melts over a wide range of chromium content. In this study, the equilibrium sulfur distribution, Ls, between a Ca0-Alz03 slag and Fe-Cr-C,.,-S melts were measured under CO atmosphere in the temperature range of 1823-1923 K. The specific effect of chromium on the activity coefficient of sulfur in the melts was determined with the consideration of carbon effect on sulfur. A separate experiment was carried to determine. Ls between a slag and FeCr- S melts (Cr: 0-30 mass%) at 1873K to check the validity of the thermodynamic parameter determined in the present study.IntroductionFerritic stainless steels containing chromium (Cr) up to 30 mass% have been developed for a good corrosion resistance and a high formability to replace austenitic SIS. Especially, Sulfur (S) causes a reduction of high-temperature strength and the hydrogen induced cracking (HlC) in stainless steel for line pipes. [l]Many studies on the desulfurization of hot metal and liquid steel have been carried out for several decades and they used HzS-H2 gas equilibrium technique for measuring the effects of many alloying elements on the activity coefficient of S in liquid iron. However, the study on desulfurization of Fe-Cr melts was very scarce.[2] In order to accurately control the desulfurization reaction of high Cr stainless steel, it is essential to know the thermodynamic relation between Cr and S in Fe-Cr melt over a wide range of Cr content and temperature.In the present study, the thermodynamic interaction between Cr and S in liquid iron was determined by measuring the equilibrium distribution ratios of S between Fe-Cr-C,.1-S melts containing a wide range of Cr up to 30 mass% and a 55 mass%Ca0-45 mass%Alz03 slag of which the sulfide capacity was pre-determined using Fe-C,a1-S melts in the temperature range of 1823-1923 K. The validity of thermodynamic parameter determined in the present study was checked by measuring the S distribution between a Ca0-Alz03-Mg0 slag of known sulfide capacity and liquid Fe-Cr-S alloy at 1873 K. Using Wagner's formalism, the results of experiment were thermodynamically considered to determine the effect of a specific concentration of Cr on the activity coefficient of S in liquid iron."

Jan 1, 2014