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By Fadeela Saloojee, Frank K. Crundwell

"Pressure leaching is an option for copper recovery from chalcopyrite. Leaching takes place at high temperatures and pressures in the presence of an oxidising agent. This work shows how the performance of pressure leaching circuits may be improved by optimising the configuration of autoclaves and the heat-removal method. The objective was achieved by creating an autoclave model by combining mass balances, energy balances and population balances. A base-case circuit consisting of a single autoclave was chosen, and this base case was compared with options for increasing capacity by adding more autoclaves to the circuit. These capacity–increase options include circuits in which the additional autoclave is added in parallel, in series and in series with thickening between the two autoclaves. The copper extraction, productivity and cooling requirements for these options are compared. The series circuit with inter-stage thickening has the highest extraction and productivity, however, the cooling duty in the first autoclave is high. In addition to comparing circuit options, three options for heat removal were investigated: cooling coils, quench water and flash recycling. The flash-recycle option results in the highest copper extraction, and the quench-water option gives the lowest copper extraction. INTRODUCTION Background Copper sulfide ores and concentrates containing chalcopyrite are typically hard to leach under atmospheric conditions. Smelting of these ores may also be a challenge, due to the inability of smelting processes to handle low-grade ores, as well as impurities such as arsenic and antimony. Alternative hydrometallurgical routes to treating chalcopyrite are therefore required. One option is pressure leaching, which is the focus of this work. In the pressure leaching process, sulfide ores and concentrates are leached in autoclaves at temperatures of 200 to 220°C and a pressure of about 3000 kPa (Schlesinger et al., 2011). An oxidising agent, usually oxygen, is required to oxidise sulfide ions to sulfate ions. The oxidation of sulfur to sulfate is exothermic; consequently, a method of heat removal is necessary in order to maintain the temperature in the autoclave."

Jan 1, 2015

By Brian T. Burch, Paul N. Worsey

When fired, submerged Linear Shaped Charges (LSCs) lose all effectiveness in the cutting of steel. Users in underwater applications have reported having to substantially increase the charge size to the point where brute explosive force shears rather than cuts the target.

Jan 1, 2015

By S. F. Guo, Z. F. Zhan, X. L. Huang, Y. Zou, S. W. Qi

"FLAC3D is an important numerical analysis software to study dynamic response of rock slope. In application of the program, the common issues such as absorbing boundary and the method to apply wave have been well studied. However, effects of model mesh size, damping and width of slope are still unknown. In order to make the result more convictive, this article has discussed the above issues systematically. It found that when the maximum mesh size is smaller than 1/10~1/8 of the smallest wavelength, the mesh size is smaller, the computational accuracy is higher. Meanwhile, values of damping and width of slope have no effect on the result. Additional, results of FLAC3D modeling on wave transmission across rock joints agree well with analytical solutions, so it has verified the capability and accuracy of FLAC3D on dynamic response of rock slope.INTRODUCTIONChina is a mountainous country accompanied with many earthquakes. Thousands of geological disasters are triggered by the Wenchuan Earthquake in Sichuan Province, and the majority of the disasters are landslides induced (Xu et al., 2009). Meanwhile, the paper (Li et al., 2003) points out five significant issues about dynamic loading in the area of geotechnical engineering, which includes the study of rock slope stability under earthquakes, and the dynamic response of rock slopes is one of its important study issues."

Jan 1, 2015

By P. Tolvanen, A. Jalili

"When hard times strike in the mining cycle, sites tighten their belts and focus on lowering their unit costs. Lower unit costs can be achieved by reducing expenditure, increasing production, or by a combination of both. Faced with these requirements, site personnel must turn to areas where they can focus their effort for maximum return. For many sites, both in Canada and overseas, focusing on improving flotation cell maintenance is one of the areas where gains can be made for minimum outlay. Due to resource limitations and/or lack of equipment understanding, maintenance on many sites is only conducted on a reactive basis, once equipment fails. This paper will promote the idea that mineral processors should become more familiar with their equipment so they can ensure that the plant’s ability to produce is not compromised. By better understanding the flotation equipment and ensuring the critical components are maintained, it should be possible to unlock value in an operation. Flotation equipment inspections will be discussed in detail, including key items to look for during these inspections. Potential approaches for predicting wear and change-out time for flotation equipment components will be also demonstrated. An example of one approach used at a South African nickel site will be given.INTRODUCTIONWith metal prices decreasing and operating costs rising, concentrator operators are looking for ways to improve their bottom line. Lower unit costs can be achieved by reducing expenditure, increasing production, or by a combination of both. To meet the expectation of shareholders, mineral processors must turn to areas where they can get the best return for their efforts. One area where there is a large opportunity for improvement is in the maintenance of flotation equipment.On many mine sites, both domestically and around the world, it is quite common to see the philosophy applied of repairing equipment only once it has failed. Though some sites have advanced enterprise management systems and monitoring programs, in the authors’ experience, the decision on flotation equipment maintenance is rarely made on a proactive basis. Two common trends that are evident in the mining industry are that operations are under pressure to keep the plant producing, and maintenance managers generally have very strict budget targets to meet. In addition to these factors, few sites have a good understanding of the financial implications of running with worn or broken flotation equipment. Knights, Jullian and Jofre (2006) summarize this situation well, stating that the lack of correlation between some commonly used maintenance performance measures and key business drivers can lead to maintenance being seen only as a cost center (that needs to be reduced) rather than a tool for productivity improvement."

Jan 1, 2015

By Joe Pease

"The demand for minerals and metals is increasing. Head grades of ore bodies are dropping. Remaining ores are becoming finer grained, more complex, and more logistically challenging. Mineral processing – in particular comminution – already consumes a huge amount of energy. But in 20 years’ time, it will require about six times as much energy as today to meet the world’s mineral demand.Unless we do something different.As minerals professionals, it is our job to find that “something different”. The world is relying on us. Of course, we must look for new breakthrough technologies and techniques. We must find them, and we will find them – most likely in surprising areas.But what if we also already know how to make 30-50% improvements to efficiency? Just by using existing technologies, by applying modern analytical techniques, by custom designing our plants, by applying manufacturing principles, by breaking down our management silos between disciplines.The thing is, industry professionals already know this. Yet – in spite of a lot of intelligent people trying very hard – we just can’t seem to make it happen.This discussion considers why, despite our best efforts, we don’t get the best out of what we already have. Why we are wasting energy and money. Once we understand why, we can set about unlocking that value and improving industry productivity and energy efficiency. We will discuss the role that professionals and volunteer professional organisations like CMP and CEEC can play in catalysing the changes."

Jan 1, 2015

By D. F. Malan, Y. Jooste

"SynopsisScattered mining was practised on Kusasalethu Mine (previously Elandsrand Gold Mine) prior to 1998, but at deeper mining levels it was no longer feasible, since it would have resulted in unacceptably high stress levels and energy release rates. Longwall mining was not adopted at these depths as the mine required a more flexible mining method owing to the highly variable grade and the presence of geological structures. A mining method was developed that consisted of dip stabilizing pillars for regional support, as well as bracket pillars to clamp geological structures. A strict sequence of extraction was followed and this, together with the particular layout, was called the ‘sequential grid mining method’. This method addressed two key problems, namely negotiating adverse geology and the erratic grade of the Ventersdorp Contact Reef (VCR) orebody. However, a significant drop in production rates resulted in the need for alternatives and improvements to the original mine design. Modifications to the design were proposed in order to increase production rates, and an investigation to consider the rock engineering implications of these modifications was conducted. The study indicated that the modified method, called the ‘multi-raise mining method’, appears to be feasible and might address some of the production problems that were experienced with the original sequential grid design. An analysis of actual seismic data showed no significant differences between the original sequential grid mining and the implemented multi-raise mining. The numerical modelling of the mining layouts showed slightly higher interim energy release rates (ERRs) and average pillar stress (APS) levels during the extraction process. The final values are nevertheless identical to that of the original sequence. The study also investigated the use of a modelled moment method to analyse future seismic trends. The study illustrated that the expected seismic trends will be very similar for the multi-raise method compared to the original sequential grid mining method. This study is nevertheless considered of a preliminary nature and ongoing monitoring and analysis of seismic data at the mine is required to verify the response of the rock mass to the modified sequence and increased extraction rate. In particular, future work needs to investigate the effect of mining rate (advance rates in individual panels as well as volume of mining in particular raise lines) on the level of seismicity."

Jan 1, 2015

A reliable laboratory method to characterize the response of free gold particles to flash flotation conditions has been developed. The test has been performed on free milling gold ores as well as synthetic ores, using either a gravity concentrate or gold powder as the gold source, to assess the floatability of gold particles. Trends in free gold flotation kinetics, as well as size and milling effects, were identified for gold recovery based on the different feed types, reagent dosages, and residence times. It was shown that the ultimate recoveries and kinetic trends of gold particles from the gravity concentrate could be enhanced with increased dosage of collector, potassium amyl xanthate. Interestingly, in comparison to gravity-recoverable gold, recovery from pure Au powders was better in collectorless flotation, and cumulative recovery decreased with higher levels of collector addition. Improved coarse particle recovery appeared linked to increased collector additions for both the gravity concentrate and the pure gold powders. In general, coarse gold particles demonstrated slower kinetic rates thaen the fine or intermediate components incomparable tests.

Jan 1, 2015

By J. Hu, F. Lin, R. Chen, F Peng, S. Yang, W. Yu

"Microseismic monitoring technology has become one of the most effective method of mine ground pressure monitoring after decades of development. But safety assessment of mine ground pressure by using microseismic monitoring is still in the development stage, it needs to be perfected continuously in practice, and choose the optimal assessment indexes and methods. The definitions and physical meanings of wave velocity, b value, and EI-VA value are introduced in this paper. Statistical calculation of the microseismic events in Luomu Mine is finished by using these indexes, then the functions and calculation results of V, b value, and EI-VA value with the variable of time are also given in the paper. The preliminary safety assessment method is established in Luomu Mine, and it has achieved good results in practical application.1.1 Engineering background The Luomu Mine is a super large molybdenum and tungsten production base in China, ore reserves is up to 2 billion tons, first in Asia and third in the world. It begins mining since the 1960. and bases on underground mining until 2002. In order to recover resources more effectively, it began to use opencast mining method and formed a production of 30000t/d in the early 1990. After about 30 years of underground mining, a large mined out spaces was formed under open pit mine, up to area of 1.2 million m2 and volume of 18 million m3, as shown in figure 1. The large number of mined out spaces seriously affects the normal production, mining and handling of mined out spaces are in the high risk. In the past years, several rock mass collapsions happened, and it caused a serious security threat to persons and equipments. According to the distribution characteristics of mined out spaces, Luomu Mine is divided into A, B, C, D and E mining area. The stability of D mining area is studied in this article. D mining area mainly includes 1376,1350,1340,1317 mined out spaces and 1280 deep large mined out area, as shown in figure 2. The mined out spaces of D mining area is extremely complex and high-risk. Therefore, a microseismic monitoring system was built to monitor the stability of D mining area, a large number of valuable datum has been obtained, and it has a striking effect (Cheng & Peng, 2013; Peng et al., 2013)."

Jan 1, 2015

By A. Mazhary

"Although ore sorting in mining is not a new concept, sensor-based sorting has failed to gain broad acceptance due to perceived challenges with the technology. In order to gain wider applications, this research focuses on treating waste rock and low-grade ore to identify and test appropriate sensors and to evaluate the response. Results showed that amenability of rocks to sensor-based ore sorting is both sensor and ore specific. It was also observed that the efficiency (recovery) of sorting is directly influenced by the degree of heterogeneity of the rocks. The overall outcome showed that with the right sensor, several of the materials tested are amenable to sensor-based ore sorting. Mining companies could benefit from multiple economic and design impacts, such as lower energy cost, lower transportation costs, higher metal recoveries and smaller footprints that lead to more sustainable mining. This paper will focus on the effects of heterogeneity of rocks on sorting potential and efficiency.IntroductionSensor-based ore sorting has been attracting more attention since the pressure for effective resource extraction and management has increased. An urge to make most of the current deposits, and to make the low-grade deposits economic to mine has ushered the technology to find new ways to overcome the new challenges. No matter the terminology used, such as coarse beneificiation, waste rejection, particle or bulk sorting, the purpose of sensor-based ore sorting is to remove low-grade rocks before the comminution circuit, increasing the feed head grade and quality while reducing the energy costs related to comminution.Despite nominal advantages, there have always been some concerns that have impeded the intorduction and acceptance of the technology. One of the most important shortcomings of ore sorting is their capability, or capacity, to keep up with the high-tonnage mining. Some other issues that have been mentioned as drawbacks to sorting include installation cost of such devices, feed preparation for effiecient sorting along with accuracy of sorting and probability of false negatives (Manouchehri, 2003)."

Jan 1, 2015

By E. C. de Beer

"SynopsisA number of important areas in nuclear fuel cycle, at both the front end and back end, offer ideal opportunities for the application of non-destructive evaluation techniques. These techniques do not only provide opportunities for non-invasive testing of e.g. irradiated materials, but also play an important role in the development of new materials in the nuclear sector. The advantage of penetrating radiation used as probe in the investigation and testing of nuclear materials makes X-ray and neutron radiography (2D) and tomography (3D) suitable for various applications in the total nuclear fuel cycle. The unique and different interaction modes of the two radiation probes with materials provide several opportunities. Their complementary nature and non-destructive character makes them most suitable for nuclear material analyses, analytical method development, and the evaluation of the performance of existing nuclear material compositions. This article gives an overview of the X-ray and neutron radiography/tomography applications in the field of nuclear material testing, and highlights a few of the success stories. Several selected areas of application in the nuclear fuel cycle are discussed to illustrate the complementary nature of these techniques as applied to nuclear materials.IntroductionDuring the development of new materials for the nuclear industry, materials testing and characterization are of the outmost importance to maintain safety standards and reliability. No compromise on safety in the workplace in any area within the total nuclear fuel cycle can be tolerated, and therefore most in-situ material characterization and testing is conducted by certified and qualified personnel schooled in destructive and non-destructive testing (DT and NDT) methods. Certification and qualification in NDT can be obtained through many training centres in South Africa in accordance with European, American, and other international standards (SGS, n.d.; SAIW, n.d.; African NTD Centre, n.d.)."

Jan 1, 2015

By Shi Hongchao, Zou Zou Xinkuan, Zhang Jichun

As drilling and blasting is carried out in an urban tunnel, which is adjacent to an existing building or structure, the balance between blasting-induced vibration reduction and drivage efficiency is a most important issue that must be resolved properly. Therefore, a new cut blast method named Stepped V-cut millisecond blasting (SV-cut) was developed by optimizing the most common used Vertical V-cut blasting method (V-cut). The most significant features of SV-cut lie in the utilization of sublevel interval charging structure and millisecond delay blasting technology in cut hole and the cut-cavity formed from outside to inside sequentially. SV-cut provides advantages of high borehole using ratio, low vibration level, and satisfied advance per attack. Based on the principal of millisecond blasting, the rock fragmentation process and the vibration reduction mechanism of SV-cut are analyzed. Determining methods of blasting parameters, which do have significant effect on vibration intensity and cut-cavity formed quality, are proposed according to the forming requirement of both outer and inner cut-cavity and vibration reduction. In order to compare the performance between SV-cut and V-cut, field blasting experiments were performed in the blasting engineering of Yamalike twin-arc tunnel, which closely passes over aged parallel tunnels. Blasting results show that SV-cut blasting is proven as an effective tunnel blasting method for both increasing blasting effects and decreasing blasting vibration. Comparing SV-cut with V-cut, the SV-cut can increase blasting drivage about 8.5% and reduce the vibration intensity induced by cut hole blasting 30% at least.

Jan 1, 2015

By M. Rafie, M. Rinne, F. Samimi Namin

"SynopsisRock mass classification systems constitute an integral part of empirical underground excavation design. One system that is commonly used to classify rock mass is the Rock Mass Rating, or RMR, system. The RMR system has evolved over time to better reflect the perceived influence of various rock mass factors on excavation stability. While the introduced modifications have enhanced the applicability of this classification system, there are still areas that cause potential ambiguity. The RMR system cannot deal with input data ambiguities, uncertainties, and vagueness. To deal with the uncertainty, a Fuzzy Rock Mass Rating (FRMR) has been developed. This study aims to describe the main concept of the fuzzy approach, which is implemented in the FRMR to classify rock mass. The FRMR considers the uncertainty associated with the input data (uncertain variables) used in rock mass classification. The Gol-e-Gohar (GEG) area 3 iron ore deposits in the south of Iran were chosen as the case study for investigating the applicability of FRMR. The results of this study show that the FRMR software tool can easily be used for rock mass classification, even if uncertain input parameters have been used. FRMR consists of three parts, each of which is suitable for certain conditions.IntroductionNowadays, rock engineering classification systems, which constitute the backbone of the empirical design approach, are widely employed in both civil engineering and mining engineering. Rock mass classifications have recently been quite popular and are being used mostly for the preliminary design and planning purposes of projects. According to Bieniawski (1989), a rock mass classification scheme is intended to classify the rock masses, provide a basis for estimating deformation and strength properties, supply quantitative data for support estimation, and present a platform for communication between the exploration, design, and construction groups."

Jan 1, 2015

By M. Gimpel, R. Galler, T. Antretter, H. Kargl, R. Tichy, W. Ecker, M. J. Mikl-Resch, G. Pittino

"A computational method based on a continuum-mechanical approach to simulate rock cutting is developed and evaluated. The aim is to obtain the local loading acting at the cutting pick during operation. The explicit FEM is chosen to model the pick-rock interaction. The presented method takes advantage of (i) an advanced material model (ii) a robust contact algorithm and (iii) fast calculations due to parallelization. A damage-plasticity law is chosen and modified with user-subroutines. A user integrated element deletion routine evades critical mesh distortions. Infinite elements at the model boundaries avoid unrealistic deformation wave reflection.INTRODUCTIONExcavation in mining and tunneling is a costly and complex process. Special equipment such as the roadheader (Figure 1) is employed to cut the rock in the excavation process but high material strengths limit their usability (Tockner 1999). Nowadays a challenge is to extend their field of application to harder and more abrasive rock materials. The forces on the pick (Figure 2) are of great importance and determine wear and especially the efficiency of the machine. Figure 2 shows the principle of cutting and the predominant forces. The variation of pick geometry, cutting depth or attack angle will result in an alteration of these forces and determine the efficiency of the process (Tockner 1999). The mechanisms of rock cutting follow the principle of indentation (Kou et al. 1999). Directly under the indenter a hydrostatic stress state evolves causing the material to fail only due to crushing and fragmentation mechanisms. In the close surroundings large strains emerge and tensile cracks are formed but in a further distance the material behaves elastically."

Jan 1, 2015

By Y. Guglielmi, C. Gout, P. Henry, P. Dick

The key questions about fault reactivation in shales concern the potential enhanced fluid displacement through a previously low-permeability aseismic shale formation. Here we selected a critically-stressed fault cross-cutting the underground research facility of Tournemire (France) which is located in Toarcian shales. Several inclined boreholes were drilled across the 8.5 m thick fault zone characterized by a fractured damage zone (FDZ) and a central 2.4 m thick complex core (FC) made of multiple shear bands with gouge intercalated with highly fractured lenses. The fault was pressurized using a straddle packer system defining a 2.4m long injection chamber normal to the fault surface. Three fault zone intervals were tested, two in the fault damage zone and one in the fault core. A three-dimensional displacement sensor set in the chamber allowed continuous synchronous coupled monitoring of fault movements, injection pressure and flow rate. An anticlockwise 0.22-to-0.05 mm fault slip was captured associated with a 10-to-100 hydraulic aperture increase of the fault. Preliminary analyses of the experiments show that leakage in the fault zone is controlled by strength and stress magnitude contrasts between the fault core and the fault damage zone. Fault damage zone discontinuities display a much higher peak static friction angle than the fault core shear zones, respectively of 34 and 22° that could be related to complex interactions between healing and sealing processes. Fault core leakage is much more dependent on strain than on effective stress variations. Discontinuous, pulse-like leakage, develops following complex failure processes that may simultaneously take place in the gouge zones and along the large pre-existing discontinuities. Such results may be of importance in evaluating fault seal integrity in oil and gas exploration, production or CO2 storage or underground excavations monitoring.

Jan 1, 2015

By Piet Halliday, Ellina Kharatyan

Conventionally, emulsion matrices (unsensitized) need to be sensitized to become detonable explosives. This is done either chemically or mechanically. Both methods have their advantages and disadvantages. Mechanical sensitization involves the addition of microballoons (plastic or glass) to the emulsion matrix, in order to create hot spots during detonation. This is usually done at the manufacturing site and poses a safety risk in terms of the storage, transportation and handling of a 1.1 type explosive. Many countries throughout the world make use of chemical sensitization as opposed to mechanical sensitization as this allows for the storage, handling and transportation of two 5.1 type products rather than the 1.1 type explosive. Chemical sensitization involves the addition of a small amount of a chemical that reacts with a component of the emulsion matrix causing the formation of gas bubbles that act as hot spots during detonation. The disadvantage of this is the lack of accurate density control (due to various factors affecting the reaction) and the lack of comprehensive understanding of the operators of the reaction. This can easily result in poor blast performance. Due to these disadvantages a pumpable, non-detonable (5.1 type) mechanical sensitizer was researched and developed. This product allows for pumping at a 50:50 volume ratio with the emulsion matrix, when loading into blast holes. The significance of this is that a 1.1 type explosive is formed in the blast hole. As such, the security and logistical issues of the transportation and storage of the 1.1 type explosive are eliminated. Another advantage is accurate density control of the final product, specifically in small diameter long hole applications. A cost effective, unique mini pumping system has been developed for the loading of this product. Moreover, this system can easily be used for secondary blasting applications and the on-site packaging of cartridged explosive products.

Jan 1, 2015

By Chandrasegaran, Tamilmani

"This paper describes a case study of a retaining wall structure using a diaphragm wall to construct a stilling basin at Tanjung Bin T4 power plant in Johor Bahru, Malaysia. The stilling basin is part of the Phase IV (T4) 1x1000MW power plant’s offshore cooling water discharge culverts. The site is located close to the sea with 5m of fill on top of very soft sediments of marine origin up to 20m thick underlain by fluvial clay and metasedimentary rock. Stringent wall deflection criteria and construction program dictated adopting an efficient solution with 800mm thick diaphragm wall supported by permanent top support as the temporary prop and improved horizontal restraint provided by deep mix piles acting as a slab (ground improvement layer) below the final excavation level. The depth of excavation is about 10.12m from the existing ground level. The proposed solution kept the wall deflection below the limit of 0.7% of the depth of bulk excavation and avoided additional props leading to faster completion of the structure. With unsymmetrical loading behind the retaining walls, 2D finite element analysis was carried out to assess the wall deflection and stresses in the wall and the grout layer below. The diaphragm wall is instrumented to monitor the behavior and the findings are discussed in the paper.INTRODUCTIONConstruction in soft marine clay has always been a challenge to the engineer because of its very low shear strength and its sensitivity to disturbance. In the case of excavation projects the problem becomes even more complicated with development of excess pore pressure during excavation. Marine clay with its low shear strength and lesser passive resistance, generally leads to large wall movements and settlement behind the wall. Increased passive resistance coming from increased number of props is useful but has its limits and it is no longer the most effective way in containing or reducing the wall movements or forces in the wall. One of the solutions to these problems is to improve the soil shear strength by means of ground improvement infront of the wall at an elevation most appropriate to maximize wall performance. There are several methods adopted in improving a soil layer including mixing additives to the ground to improve the shear strength to partially replacing the weak soil while others are fully replacing the weak soil. This paper discusses the case study of approximately 10m of excavation in soft marine clay using 800mm thick diaphragm wall supported by Deep Mix Piles (DMP) being used to improve soft marine deposit to form a slab just below the formation level and thus improving passive resistance significantly. The ground improvement layer helped to reduce the wall forces and deflections making it possible to remove the need for additional temporary props leading to significant savings is time and productivity. The paper presents the various options explored before this method is adopted, the design approach, instrumentation data and the monitored results."

Jan 1, 2015

By Marko Lampi, Marc Nicolle, Janne Karonen, Kari Valkama

"In the ten years from 2003 to 2013 global mine production of copper has increased by over 23% to meet demand while the weighted average head grade has dropped from 0.9 to 0.7% Cu. These divergent trends of increasing demand and declining economic grades will extend the life of many existing mines and improve the viability of marginal and/or complex copper deposits. Against that context this paper outlines hydrometallurgical copper sulphide leaching options as alternatives to the more conventional pyrometallurgical processing route of copper sulphides. Three copper sulphide leaching and refining processes are discussed: total pressure oxidation, ferric sulphate leaching and copper chloride leaching. The effect of mineralogy on the choice of processing technology is discussed as well as some of the unit processes used. Additionally, possible benefits that a hydrometallurgical process may offer over an existing pyrometallurgical route are discussed. Subsequently, two very important aspects to the development of projects involving the leaching of copper sulphides are discussed. Finally, a number of conclusions are presented that will be useful to keep in mind when considering projects involving the leaching of copper sulphides. INTRODUCTION In the ten years from 2003 to 2013 global mine production of copper has increased by over 23% to meet demand while the weighted average head grade has dropped from 0.9 to 0.73% Cu (Murphy, 2014). If these divergent trends of increasing demand and declining economic grades continue, they will contribute to the extension in life of many existing mines and improve the viability of marginal and/or complex copper deposits. Against that context, this paper outlines hydrometallurgical copper sulphide leaching options as alternatives to the more conventional pyrometallurgical processing route for copper sulphides. Three copper sulphide leaching and refining processes are discussed: total pressure oxidation, ferric sulphate leaching and copper chloride leaching. Ferric sulphate leaching and copper chloride leaching are carried out at atmospheric pressure while total pressure oxidation takes place at elevated pressures."

Jan 1, 2015

By Jerry Gagnon, Matt Burr, Dave Evans, Timothy Ellis, Davies Kakengela, Abbas Mirza, Larry Webb, François Leclercq, Andrew Johnston

Lead-based alloys are the primary anodes used in electrowinning from sulphate-based aqueous systems. Lead anode technology has evolved over the years, migrating from pure lead and lead-antimonial alloys to the present day lead-calcium-tin alloys for copper electrowinning and lead-silver alloys for zinc electrowinning. It has also migrated from cast to rolled microstructures in search of improved mechanical properties and higher corrosion resistance. Although great strides have been made in the development of new alloys and production processes, the industry still has unresolved issues related to untimely corrosion which limits anode life and may lead to higher contaminant levels in the metal being produced. Lead anodes corrode because of the difference in the chemical/electrochemical potential across the microstructural features of an anode. Given a very high purity material, we find that the grain boundary areas corrode significantly faster than the rest of the grain. The desire to minimize grain boundary corrosion by a balance of alloying element selection and microstructural design allows the grain boundary area to be engineered. However, operational issues can lead to unexpected corrosion behaviours which we will discuss moving forward. The comments in this work, though directed toward copper electrowinning, can be extended to similar phenomena in other metals electrowon from sulphate media (i.e., zinc, nickel, cobalt, manganese). The lifecycle of electrowinning anodes is dependent upon electrowinning tankhouse operating conditions and maintenance of the anodes, including cleaning and straightening. This paper will focus on the operational aspects of maximizing the utilization of lead electrowinning anodes.

Jan 1, 2015

By L. G. Stolarczyk, J. Duncan

"SynopsisLong before the environmental movement, coal miners were suffering from occupational diseases that became apparent in the later years of service, and especially during the retirement years. Chronic exposure to micro-fine dust in the respirable range (‘float’ dust) causes various lung diseases, referred to as coal mine dust lung disease. In the USA alone, 76 000 miners have died of coal mine dust lung disease since early legislation recognized the issue in 1969. Researchers believe that reducing float dust exposure limits alone will not reverse the increasing incidence of coal mine dust lung disease seen in the current generation of miners. Trace and radioactive metals are concentrated in the thin boundary layers of the coal seam (Roberts, 2013), and hence float dust includes silica and toxic trace metals. The production and quality of coal is also significantly impacted by the presence of these contaminants in the coal. In the combustion process, the trace metals are oxidized and become incorporated in the fly ash and flue gas. Since they are extremely water-soluble, they represent a significant danger to health and the environment. Coal preparation plants and power stations need to mitigate these contaminants as far as is practical, but the simple fact is that most contaminants should have been left un-mined.This paper describes an innovative coal-cutting solution to the longstanding technology gap in mining – the ability to measure uncut coal layer thickness to the boundary rock layer. Because of constant changes in geology, seam thickness, and seam undulation, the horizon sensor must be located in the bit-block of the rotating cutter drum of the mining machine. Contaminants in ROM coal must be minimized at the source – that is, at the rock/coal crushing cone directly under the bit-tips of the cutting drum. Bittip distances to the rock boundary layer must be automatically controlled in real time when mining in a complex and undulating coal bed. Horizon sensing (HS) technology enables the mining machine’s cutting picks to stop at a specified distance from undulating horizons of the boundary rock. The thin contaminated coal layer can be left in situ, significantly reducing the toxicity of the float dust. Preventing the metal picks from striking quartz-containing boundary rock also reduces the occurrence of methane ignitions. HS technology equipped with pick force vector sensing can allow optimization of the cutting pick lacing pattern for minimum coal and rock crushing, thereby reducing float dust. This technology may enable the mining industry to convert from automated machine control to autonomous during coal cutting and loading."

Jan 1, 2015

By Y. I. Yang, Y. -B. Tang, D. -J. Ma

Chlorine-containing minerals are commonly present in coal. Associated minerals such as pyrite can undergo exothermic reactions. Consequently, it is of great significance to study the effect of inorganic chloride on the spontaneous combustion of coal. In this study, the effects of five inorganic chlorides (sodium chloride, magnesium chloride, potassium chloride, calcium chloride, and zinc chloride) on the spontaneous oxidation of coal were investigated. Analysis of the gaseous products of coal oxidization at low temperatures (323K to 453K) showed that the presence of inorganic chlorine in coal markedly decreases O2 consumption and the generation of CO and CO2. Samples of raw coal and chlorine-loaded coal were oxidized for 36 hours under the same experimental conditions. Infrared diffuse reflectance spectroscopy results showed that inorganic chloride can inhibit the oxidative decomposition of some functional structure components (methyl, methylene, methine, and hydroxy) in the coal. The influence of inorganic chloride on the oxidation characteristics of the functional groups in coal during spontaneous combustion was investigated using benzyl alcohol and 1-phenylpropanol as model compounds, which were tested under the same experimental conditions as the coal samples. The oxygen consumption of model compounds with and without the addition of inorganic chloride further suggested that inorganic chloride may hinder the oxygenolysis of these structures during low-temperature oxidation. This phenomenon can be attributed to the radical reaction from the perspective of radical chemistry. It can therefore be concluded that inorganic chlorides play an inhibitory role in the spontaneous combustion of coal.

Jan 1, 2015