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By Dave Marsh, John Goode, Niels Verbaan, Kevin Bradley, Henrie Notzl

The mineralogy of the Avalon Nechalacho deposit is complex with significant fractions of HREEs, Zr, and Nb found in refractory minerals such as zircon and fergusonite. Sulphuric acid baking followed by water leaching can be used to extract REEs from flotation concentrates, but acid baking does not completely "crack" the zircon and fergusonite, so the extractions of Zr, Nb, and HREEs are not high. An alternative flowsheet has been developed that is able to obtain significantly improved extractions of HREEs, Zr, and Nb from flotation concentrates or acid bake residues. This is accomplished by cracking the zircon and fergusonite minerals with caustic soda at high temperatures, followed by water washing to recover excess caustic soda and soluble sodium silicates and phosphates. REEs, Zr, and Nb in the solid residue can then be solubilized with HCl or H2SO4. This paper highlights some of the findings from an extensive laboratory program and discusses several flowsheet implications.

Jan 1, 2014

By Yukihiro Ishihara, Nanase Ogawa, Ming Lei

"Abstract In the Press-in Method, a static jacking force is used to install a prefabricated pile, while a reaction force is gained from previously installed piles. This piling technique has solved problems in urban piling construction such as noise and vibration associated with the piling work, restricted construction conditions due to the existing structures, and so on, since its emergence in 1975. Its applicability to hard ground conditions has been improved, with the development of press-in machines that involve augering or rotation. Besides, information such as time, penetration depth, jacking force and rotational (or augering) torque in piling work are automatically obtained. The concept of PPT, Pile Penetration Test, has been developed by the authors, to apply the obtained information to the processes of construction planning or foundation design. This paper highlights the technique to estimate SPT N value from data acquired in standard press-in (press-in without any auxiliary methods), press-in with augering and rotary press-in. The technique will be helpful in assuring the adequate embedment depth, re-selecting the adequate press-in machine or auxiliary method, and re-pricing the project objectively, particularly when a contractor encounters unexpected ground conditions.INTRODUCTIONThe Press-in Method is one of the piling techniques that use a static jacking load to install piles. It mitigates environmental problems of noise and vibration that have been associated with other conventional piling techniques.It is also featured by its spatial efficiency; since a ‘press-in’ piling machine gains a reaction force from the previously installed piles, there is no need of bulky weights that will occupy a large space. This feature is emphasized in the piling system in Figure 1, where a press-in machine and its related devices are all positioned and ‘walk’ on top of the pile wall.Its applicability to hard grounds has significantly been improved, with some newly developed piling machines that involve augering or that install tubular piles with teeth on the base by applying axial load and rotational torque at the same time."

Jan 1, 2014

In this study, the effects of slag compositions, slag amount, temperature, and carbon content of steel on the manganese and phosphorus distribution ratios during converter steelmaking were analysed using the classical regular solution theory, and industrial tests were performed using two 80 t top-and-bottom combined blown converters (duplex melting process). The results indicate that the slag amount, temperature, and carbon content in steel are the main factors affecting the manganese yield when converter slag compositions remain constant. The FeO content of the slag has a strong impact on the manganese distribution ratio, while the slag basicity and MgO content have no obvious effect. The calculations and experimental results show that the phosphorus distribution ratio increases sharply with increasing slag basicity R, but then decreases with the increase of MgO and MnO contents in the slag. The final slag in converter steelmaking should have the following characteristics: 3.5 < R < 4.5, 15% < (FeO) < 20%, and 6% < (MgO) < 8%. The slag amount should be controlled appropriately at the same time. The results of this investigation would be useful in deciding on the application of manganese ore in alloying and identifying the slagging regime in converter steelmaking.

Jan 1, 2014

By Michael Moats, Adirek Janwong

The use of cylinder electrowinning cells, such as emew® technology, for the recovery of silver from primary and secondary sources has been growing. In this study, common operating parameters used in silver electrowinning were evaluated for recycling applications. Silver powders were produced from an industrial solution in a laboratory scale emew® cell. A design of experiments was employed to evaluate the effects of HNO3 concentration, iron concentration, current density and solution flow rate on current efficiency, particle size, bulk density, and crystallographic orientation. Current efficiency was affected by each parameter with increasing HNO3 concentration having a strong negative effect, increasing iron concentration and current density having moderate negative effects and increasing flow rate having a positive effect over the ranges examined. Finer particles were produced with increasing current density and decreasing flow rate. Bulk density increased when HNO3 concentration increased. The crystallographic orientation of all powders was dominated by the (111) plane. Increasing flow rate decreased the relative intensity of (200) direction. Based on these observations, silver electrowinning in cylindrical cells can operate at high current efficiency and produce larger powders at low HNO3 concentration, low iron concentration, low current density and high flow rate.

Jan 1, 2014

By Nicholas Enraght – Moony, Alvin Johns, Zhonghan Zhang, Zhang Xianhua, T. Choo

"The tungsten (WO3)-rich ores from King Island Scheelite (KIS) Mine, Australia, containing scheelite(CaWO4) were previously recovered by gravity separation and flotation of fine scheelite (1978-92) with an overall recovery of 76% when both circuits were operating. Recently extensive test work has been conducted both in China and in Australia on KIS ores, assaying from 0.50%-1.34%WO3, and tailings assaying 0.2%WO3(GZRINM 2009; 2011a; 2011b). A new approach, which aimed at improving both recovery and grade of concentrate by means of an innovative all flotation route WOF (Whole Ore Flotation), achieved excellent results: 90%-92% recovery to concentrate grade of 66%-70%WO3for the ores. The process is characterized by the use of selective reagents in flotation, including a newly developed collector for scheelite, GYWA. The WOF process also embraces the "Improved Petrov Method" in the cleaning of scheelite rougher concentrate. Earlier investigations found that the removal of sulfides by flotation prior to scheelite flotation was not necessary. It was also found that recycling of process water did not influenceresults. Two main ore types were tested as well as tailings from 2009to 2001(0.20%WO3). In addition a flow sheet using wet high gradient magnetic separation (WHGMS) in tandem with flotation was also investigated for the tailings."

Jan 1, 2014

By Shahriar Vandani, Andy Herlache, Andrew Bro, Wei-Yu Chen

"The Presidio Parkway Project will reconstruct approximately 1.6 miles (2.6 km) of highway, including seven new bridges, three new cut-and-cover tunnels, and a new undercrossing connecting the Golden Gate Bridge to the City of San Francisco, California. The project site is approximately 5.6 miles (9 km) from the San Andreas Fault, capable of producing magnitude 8 earthquakes. Seismic hazards include strong ground shaking, soil liquefaction, ground settlement, and lateral spreading. The Main Post Tunnels (MPT) are two parallel cut-and-cover concrete tunnels approximately 1100 feet (335 m) long. The MPT site underlain by loose sandy soils susceptible to liquefaction and lateral spreading. Excessive racking and permanent displacement due to lateral spreading are identified as the main seismic vulnerabilities. Analyses showed that without ground improvement, tunnel racking of over 5 inches (13 cm) and permanent lateral tunnel displacement of up to 15 feet (4.6 m) could be anticipated. Cement Deep Soil Mixing (CDSM) is proposed to mitigate slope displacements and increase lateral stiffness of the foundation materials to reduce tunnel racking. A series of 2-D fully dynamic time domain analyses were performed to evaluate the performance of CDSM, confirm that performance criteria are met, and optimize the CDSM geometry and replacement ratio. The use of CDSM reduced the permanent tunnel displacement from over 15 feet (4.6 m) to less than 1 inch (2.5 cm). Tunnel racking was also reduced significantly. The adopted analytical approach presented herein can be considered for future tunnel design projects in seismically active areas.Introduction The Main Post Tunnels (MPT) are an integral component of the Presidio Parkway project which will replace the existing facility with a new multi-lane roadway between the Golden Gate Bridge and the City of San Francisco. The MPT are two parallel cut-and-cover concrete tunnels approximately 1100 feet (335 m) in length. As shown on Figure 1, the project site is located in a seismically active area, about 5.6 miles (9 km) east of the San Andreas Fault and 12.5 miles (20 km) west of the Hayward Fault. The San Andreas Fault can generate magnitude 8 earthquakes while the Hayward Fault is capable of producing magnitude 7.3 earthquakes. The design Peak Bedrock Acceleration (PBA) is 0.46g for the upper level design earthquake. The project alignment is shown on Figure 2."

Jan 1, 2014

By X. -G. Chen, A. M. Nabawy

A novel manufacturing technique for Al-TiB2 nanocomposites has been developed, in which TiB2 nanoparticles were incorporated into liquid aluminum under mechanical stirring and in the presence of a K2ZrF6 flux-wetting agent. The microstructure of the Al-TiB2 nanocomposites was studied using scanning electron microscopy (SEM) and transmission electron microscopy (TEM). The microhardness test was conducted to investigate the strengthening effect of TiB2 on the aluminum matrix. The TiB2 nanoparticles were successfully incorporated and dispersed into the aluminum melt in the presence of the K2ZrF6 flux during mechanical stirring. In the as-cast microstructure, most nanoparticles segregated in the interdendritic regions as a result of particle redistribution during solidification. The addition of 2, 5 and 10 wt% TiB2 nanoparticles increased the composite hardness by 60, 90 and 150% respectively when compared to commercial purity aluminum, indicating that the TiB2 nanoparticles imposed a significant strengthening effect on the aluminum matrix. The role of K2ZrF6 flux agent on the incorporation of nanoparticles into aluminum melt was discussed.

Jan 1, 2014

By H. Zhu, Y. Sato, O. Takeda, K. Nakano

Recycling of rare earth magnet wastes is essential to insure the stable supply of rare earth resources. For the development of a novel recycling process, the removal of rare earth oxide from an off-spec alloy magnet was investigated by melting the alloy magnet at 1503 K together with fluoride flux, LiF-50 mol% NdF3 and LiF-?25 mol% NdF3-25 mol% DyF3. After melting, the separation of magnet alloy from the fluoride flux was achieved, and neither suspension of alloy in the flux nor suspension of flux in the alloy was observed. Oxygen concentration in the alloy decreased from 5000 mass-ppm to 160 mass-ppm by utilizing 1.5 times of equivalent amount of flux needed to completely dissolve the oxide. The investigated process is suitable for mildly contaminated waste such as a used (end-of-life) magnet because of its simplicity, low energy consumption and small limitation on location for operation.

Jan 1, 2014

By M. McWha

Laboratory bias is a universal problem in all branches of analytical science. It results from differences in methods, techniques, equipment, and calibrations between laboratories. Notwithstanding that it is a property that can be measured by the use of standards or by inter-laboratory testing, laboratory bias remains a material issue for the mining industry. There is extensive literature and clear guidelines on measurement from the International Organization for Standardization (ISO) and its worldwide federation of national standards bodies (ISO member bodies) and from the science of metrology. ISO guides cover the manufacture and use of standards. An accessible source of literature covering laboratory quality control comes from the public health sector, particularly pathology. There is little doubt in financial reporting rules about the meaning of materiality. Public reporting guidelines are clear that material matters need to be disclosed for investors. Unfortunately there is currently no clear guidance what to do about biased assay results in mineral industry public reporting guidelines. This paper reviews the requirements for the manufacture and use of reference materials, public reporting requirements in the mining industry, and presents proposals to improve management and reporting of laboratory biases. Keywords laboratory bias, reference materials, ISO Guides, financial reporting, materiality.

Jan 1, 2014

By G. K. Nimal Subasinghe

The performance of Knelson Concentrators (KC) used in gravity gold circuits often rely on manufacturers recommendations for selecting operating parameters such as, fluidising water flow rate and cycle time. These parameters are not only dependent on the machine parameters but also on the feed characteristics such as, size distribution of the gold and gangue particles and the composition of its constituent minerals. Particles entering a KC experience a centrifugal acceleration due to the high bowl rotational speeds. The required centripetal force to maintain a circular orbit is provided by the fluid drag force created by inwardly moving fluidising water and the Bagnold?s force arising from the particle/particle collisions. When the fluidising water flow rate is low particles move towards the outer rim of the bowl forming a packed bed within the grooves. On the other hand, if the fluidizing water flowrate is high the bed expands and some particles would move towards the centre of the bowl and gets carried to the tailings stream, thereby reducing the amount of material retained within the grooves of the bowl. Based on a force balance on a particle captured within the KC, a criterion which can be used to predict the amount of material recovered in the bowl has been derived and validated by experimental data. It has been shown that this criterion may be used to demarcate the transition of the bed from a packed-bed state to a fluidised state depending on the fluidizing water flowrate. By identifying the conditions for the optimal expansion of the bed comprising different constituent mineral particles, it is possible to estimate the optimal fluidising water flow rate that would maximise gold recovery while minimising gangue recovery. It was also observed that the accumulation of valuable mineral in the bowl takes place by the displacement of the gangue particles in the bed by the incoming heavy mineral particles. The kinetics of this segregation process was also studied using synthetic mineral mixtures. The experimental data suggests that this process follows first order kinetics and that the build up of heavy mineral reaches a maximum which could be used to identify the optimal cycle time. In this work, the suitability of the above model in optimizing the performance of a KC have been reviewed. Also the necessity and merits of testing an unaltered

Jan 1, 2014

By K. Lundholm, A. E. Mäkinen

"Ore grades are declining and getting more complex around the world which not only complicate the ore processing but also produce new type of requirements to manage the produce waste streams. One specifically problematic and increasingly identified element in waste streams produced in mining and metallurgy is arsenic.Arsenic is a compound that has no significant market value, but that needs to be removed from ores, concentrates and other process streams because of environmental or process technical reasons. One example of a removal process is partial roasting of high-As sulfide concentrates, originally developed by Outotec. In this process the arsenic is volatilized in the gas phase and thus separated from the solid material, i.e. the calcine. If the arsenic is recovered by wet methods the process gas is quenched and all arsenic needs to be stabilized in the effluent treatment plant.Outotec has developed ferric arsenate precipitation as a method to produce stabile arsenic residues from wet gas cleaning effluents. Iron based precipitates, when correctly produced, can meet typical landfill criteria measured with different types of leaching methods meant for characterizing the arsenic dissolution behavior from the precipitates.In this paper partial roasting of sulfide concentrates with arsenic volatilization in combination with ferric arsenate precipitation is discussed from the perspective of producing wastes that can meet the stability requirements set by common leaching tests methods, TCLP and CEN. These leaching test methods set the normative landfill requirements for most operations generating arsenic containing wastes. A typical flow sheet of Outotec® Ferric arsenate process is discussed with results showing the importance of correct process control and sequence on producing arsenic containing waste that can meet the landfill disposal requirements."

Jan 1, 2014

By M. -C. Noël, G. P. Demopoulos

In this work the formation and environmental stabilization potential of arsenate-containing fluoroapatites is considered. In particular in this research various compounds were precipitated from synthetic solutions containing fluoride, arsenate/phosphate and calcium by varying different parameters-temperature, Ca:As ratio, pH, and P:As ratio, and aging time. The results obtained helped determine the operating window that should be used for the formation of highly crystalline fluoroapatites, in particular svabite (Ca5(AsO4)3F). It was found that svabite has a specific pH range of precipitation, with lower pH yielding CaF2 and calcium arsenate compounds such as CaHAsO4•H2O. At higher pH, a mixture of svabite and johnbaumite (Ca5(AsO4)3OH) precipitated, yielding a less stable material. This range of precipitation varied with the concentration of arsenic in the starting solution, and widened with higher initial concentrations of Ca2+, AsO4 3- and F-. Furthermore, svabite/fluoroapatite solid solutions were formed by using the same procedure as svabite but replacing some of the arsenate in solution by phosphate. The increase in phosphate content yielded a gradual change in morphology and crystallinity. Work on stability evaluation is currently under way.

Jan 1, 2014

Scenario reduction is designed for selecting a representative subset of geostatistical simulations out of a much larger set. Three steps are involved: measuring the dissimilarity between two simulations; finding a metric to measure the distance between any subset of k simulations and the full set of N simulations; and finding an efficient algorithm for selecting the subset that minimizes the metric. This paper focuses on the third question. We show that genetic algorithms are an efficient way of approaching the minimum when the population of subsets to be sampled is large. Two case studies based on the Walker Lake data-set are presented: firstly choosing k=4 simulations out of a total of 100, and secondly choosing 20 out of the same 100 simulations. In the first case it was possible to compute all possible combinations exhaustively and hence to demonstrate that the algorithm converges to the true minimum. This was not possible in the second case. Instead we demonstrate that it outperforms the random draw algorithm used in earlier work. A procedure for tracking individual selections during the iterative procedure was developed. This allows us to measure the evolution in the percentage of progeny resulting from crossing-over and from mutation that survived in the next generation. It gives valuable insight into how to choose the parameter values in the algorithm. Another key finding is that there is a trade-off between the number of individuals per generation and the number of generations required for the algorithm to converge.

Jan 1, 2014

By Derek Ettie

"In the Hydrometallurgical processes, the presence of the so-called "crud" is a constant challenge in solvent extraction. Crud is a stable emulsion which forms along the interface between the aqueous and organic phase. The spread is influenced by the following parameters: first, wind blows the dust and impurities into the open sedimentation tanks. Second, the undissolved solids such as sand transported in the PLS causing problems in conjunction with incorrect agitator design.The crud fraction can decisively impact the efficiency of the hydrometallurgical extraction because the phase interface can constitute a large fraction and the sedimentation tanks cannot react flexibly to it. In the downstream process of the series-connected sedimentation tanks, they are thus all contaminated with crud. At the same time, the necessary mass transport is significantly impeded at the phase boundary between organic phase and aqueous phase due to the crud formation.The transfer of the organic phase into the electrolysis cell can result in a "burnout" of the cathode. The carryover of this electrolyte into the extraction can cause problems with the pH regulation. The carry-over of the organic components into the raffinate also leads to contamination of the leaching circuit. The continuous treatment of the crud with a 3-phase decanter centrifuge is extremely effective in combating this problem. This technology splits all three phases from each other and they are consequently continuously separated. All subsequent process steps exhibit a stable, uniform effectiveness. The main advantage for the customer is that fluctuations in the process are eliminated and the organic phase can be recirculated back to the extraction. The recycling of the solvent alone justifies the investment in less than 6 months as examples from South Africa and Chile show.To operate solvent recovery in daily operation fully automated online at the optimum limit, the decanter centrifuge is equipped with a concentration-dependent pond adjustment called DControl® by this means, we can guarantee our customers the maximum possible solvent recovery and minimize the solvent costs in this process step. This system is presented in detail in this paper."

Jan 1, 2014

1. A statistical approach to some mine valuation and allied problems on the Witwatersrand. Unpublished Master?s Thesis, University of the Witwatersrand ? 1951. (Separate) 2. A statistical approach to some basic mine valuation problems on the Witwatersrand - J. of the Chem. Metall. and Min. Soc. of S.A., December, 1951 - discussions and replies March, May, July and August 1952. (Vol. 1?.1). Also: J. of the Institute of Mine Surveyors of S.A. December 1952, March 1953. (Vol. 1?2) 3. A statistical analysis of some of the borehole values of the Orange Free State goldfield - J. of the Chem. Metall. and Min. Soc. of S.A., September, 1952 - discussions and reply November 1952, and February 1953. (Vol. 1?3). 4. A study of the relationship between development values and recovery grades on the South African goldfields - J.S.A.I.M.M, January 1959, - discussion and reply April and October 1959. (Vol. 1?6) 5. On the departure of ore value distributions from the lognormal model in South African gold mines. J.S.A.I.M.M., November 1960, January and August 1961. (Vol. 1?8) 6. Developments in the valuation of gold mining properties from borehole results - Seventh Commonwealth Mining and Metallurgical Congress, 1961. (Vol. 1?9) 7. Effective pay limits for selective mining. J.S.A.I.M.M., January and August 1962. (Vol. 1?10)

Jan 1, 2014

By Jason Baird, Philip Mulligan, Caleb Baumgart

This report details the pressure variances, measured at four pressure sensors placed equidistant from the center of an airburst explosion, as the blast pressure from a single charge expands radially. Many of the empirically derived equations used for predicting the blast pressures of an explosion, assume a point source detonation and that the radial pressure expansion is equal. The authors understand that the equations used to approximate the blast pressure may not have 100 percent agreement with the observed pressure. However, during previous research at Missouri University of Science and Technology (Missouri S&T) the pressure variances had a range of 1,200 psi, between the four pressure sensors placed two feet from the center of a 1/2-pound (226.8 gram) of hand packed C4. The variances indicated that at the close distance from a suspended explosive charge the pressure does not behave as that observed from a point source.

Jan 1, 2014

By D. Schleiss

Reduced access to knowledgeable workers is creating challenges for operations. We are doing more 4D Operations - dirty, dull, dangerous, and distant. Personnel costs in these environments are high, and it is not always possible to get the people where you need them. Integrated Operations is a strategy to integrate people, process, and technology for faster and better decision making. Adopting an integrated operations approach can help to relocate personnel, improve collaboration, and align objectives to deliver reduced costs and improved performance. In this paper, the authors will highlight the required infrastructure to enable an Integrated Operations platform. Key decision points for enabling this technology for both Greenfield projects and existing mines will be discussed. Furthermore, the benefits and improved return on investment that result from deployment of an Integrated Operations strategy will be presented.

Jan 1, 2014

By J. Locat, G. Parker, D. Turmel

ABSTRACT Since 1964, the Iron Ore Company of Canada has deposited iron ore tailings into Wabush Lake in western Labrador, Canada. From 1999 to 2008, the authors completed multibeam bathymetric and sampling surveys and an airborne LiDAR survey. These data were integrated to study the evolution of the tailings delta shoreline and lakebed elevation. Subaqueous channels evolved between surveys, influencing the tailings depositional pattern. With this analysis it is possible to evaluate the effect of disposal strategies on the delta topset and tailings accumulation. This project uniquely couples marine and terrestrial techniques to follow the fate of tailings in a dispersal system.

Jan 1, 2014

By Robert Bachus, Jamey B. Rosen

"Abstract Large scale In Situ Barrier Wall Construction projects, specifically those related to earth dams, dikes, and levees, frequently require stringent quality control measures to ensure the success of the wall. This presentation discusses the applications of Geographic Information Systems (GIS) technology to capture information from multiple data streams and provide geotechnical feedback, quality control, and project control feedback. Techniques used to geospatially analyze verticality data from secant piles and panels will be demonstrated. Examples will be presented from barrier wall installations at two sites owned by the U.S. Army Corps of Engineers (USACE): the Wolf Creek Dam in Kentucky, and Center Hill Dam in Tennessee.IntroductionDeep foundation installations require contractors to collect a substantial amount of information over the course of a project, both for internal quality control of construction progress and for demonstrating compliance with customer or owner specifications. Methods of collecting information are constantly improving, bringing with it the need for a systemic approach to managing the increasing amounts and types of data. Handling these diverse types of data presents challenges with both budget and schedule demands. This paper discusses some techniques for adding or increasing quality control in barrier wall constructions by consolidating, visualizing and analyzing data using relational database and Geographic Information Systems (GIS) technology, collectively referred to as Information Management System (IMS) development. The IMS concept is designed to facilitate the collection, transfer and processing of data and provide an easy way to remotely access and visualize construction progress.The remainder of this paper presents the needs and objectives of an IMS applied to quality control in barrier wall construction, the components and data flows involved, the capabilities and user interfaces of the systems and the benefits for the end users. Examples are presented throughout from case study projects including: a pile barrier wall applied in the rehabilitation at the Wolf Creek Dam in Kentucky (under contract to the Treviicos-Soletanche Joint Venture), and a secant pile barrier wall currently under construction in the rehabilitation of the Center Hill Dam in Tennessee (under contract to Bauer Foundations Corporation) (both owned by the Nashville District of the USACE)."

Jan 1, 2014

By R. J. Forzatti

The production of sulphuric acid from sulphur generates heat. The majority of this heat is recovered as steam and is often used to generate electricity. Heat not recovered as steam is rejected to cooling water systems. The design of the turbine, condenser, and cooling water systems impacts the overall water, energy, and environmental footprint of the plant. This review considers a conceptual 2000 t/d sulphuric acid plant with several alternative cooling water systems. The review utilizes Hatch?s 4 Quadrant sustainable design tool to compare the alternatives on both an economic and a weighted sustainability scale.

Jan 1, 2014