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Mr G. Maude was educated at Huish's Grammar School (Taunton) and Leeds University. He graduated in 1961 with a B.Sc. degree in Mining. Mr E.B. Crocker was educated at Florida Park High School, Witwatersrand Technical College, and the University of the Witwatersrand.

Jan 1, 1985

By J. P. Coetzee

Dr. K. Gebhard In his excellent and comprehensive survey on the future development of the Iron and Steel Industry in South Africa, Mr. Coetzee has also mentioned the direct reduction processes as a possible method of converting iron ore to iron. Mr. Coetzee has made it quite clear that at this stage one should not consider these processes as a 'magic formula' which herald a 'break through'. I agree entirely with this point of view. Once upon a time I held the opposite view, but in the meantime I have revised my views. To do so, I had 40 years at my disposal. In 1930 I had the privilege of being connected with the first commercial sponge iron plant in Germany1 - a plant which was capable of producing 40 tons of sponge iron a day. We were determined to prove that the blast furnace would become obsolete in the near future. We considered it as an unnecessary detour to convert iron ore first into an iron-carbon alloy, which contained further quite a number of undesirable elements, and to remove this carbon by an endothermic process. Direct iron-making seemed to be a logical short cut. Unfortunately, we were not able to establish this 'short cut,', but the life of our sponge iron plant was cut short. We had solved all technical but not the economic problems. Basically the positon is still the same today - mainly economic and to a lesser degree technological aspects determine the rate at which sponge iron plants are installed. More has been said and written than done about direct reduction plants. I think that there are two main reasons for this stagnation in the introduction of direct reduction processes. The first reason is that modern blast furnaces are just too good and too economic ever to be replaced by direct reduction processes on a large scale. This, of course, already limits the field of application for direct reduction plants. The second reason is that sponge iron production and utilisation is based on technical considerations, which increase not only the production cost of sponge iron but also the conversion cost to steel to such an extent that under special conditions only are direct reduction plants an economic proposition. Are these technical considerations still as forceful and valid today as they were when 'direct steelmaking' was first contemplated? The development of sponge iron production as a method of direct

Jan 3, 1971

By J. E. Dickinson, R. Campbell, M. J. Cole, K. P. Galvin, M. C. Cole

It is common practice in the beneficiation of iron ore ultrafines to apply reverse flotation, and hence float the gangue minerals, leaving behind a high-grade iron ore product. Given the difficulty in floating particles finer than 20 μm, especially those finer than 10 μm, it is necessary to subject the feed to desliming ahead of flotation. There are two problems with this approach. Firstly, given the known inefficiencies of cyclones, desliming needs to be aggressively applied to particle sizes upwards of 45 μm to ensure all the offending ultrafine gangue is removed. Secondly, desliming also removes a significant portion of the valuable iron ore. Thus, a significant portion of the ultrafines, including the iron ore, is lost to the tailings. This paper examines the direct flotation of iron ore fines using the Reflux Flotation Cell. The RFC operates using a concentrated bubbly zone, in the absence of a conventional froth zone, for delivering strong counter current washing through an inverted fluidised bed of bubbles ahead of the product discharge. A system of parallel inclined channels in the lower part of the cell provides enhanced segregation of the bubbles from the tailings, preventing the loss of air bubbles into the tailings. Experiments conducted under semi-batch conditions produced encouraging results with concentrates of ~65% Fe grade in a single flotation stage. Comparatively, up to five successive batch flotation stages were required when using a laboratory scale batch mechanical flotation cell to achieve similar Fe grades. For a given grade, lower Fe recoveries were typically achieved by the RFC. This was attributed to the effective prevention of ultrafine particles succumbing to hydraulic entrainment under a positive bias flux, as well as an increasing feed volume involved in the semi-batch operation using inverted fluidisation water for cleaning. Overall, similar grade-recovery curves were produced, however, significantly higher grades were obtained by the RFC and with fewer separation stages. Keywords: Desliming flotation, iron ore, modified release analysis, reflux flotation cell

Jan 1, 2020

By G. A. Wiebols, N. G. W. Cook, N. C. Joughin

Introductory remarks Dr N. G. W. Cook: This paper was published in your Journal in May of this year and you will, therefore, have had the opportunity of reading it over the past six months. I can state that experience has shown that the paper is substantially correct, but a number of questions have to be answered. The first question, Mr President, that I would be happy to answer, is how is it that one is able to cut hard, abrasive quartzite with a strength some six times greater than that of good concrete? The essence of the answer is that there is a tremendous difference between abrasion, or scratching, and cutting, or chipping. For example, it is well known that a diamond will scratch or abrade almost anything. It is also relatively easy to chip, crack or crush a diamond. As a demonstration I have here an ordinary bench grinder, and with the bench grinder I also have a piece of tool steel. The wheel on this bench grinder is a silicon carbide wheel, which is an extremely hard material, and the tool steel is much softer. In rock-cutting we use tungsten carbide for cutting the quartzite. The quartzite and the tool steel have roughly the same hardness. You can sharpen tungsten carbide with a silicon carbide wheel. In fact, this is done. It won't surprise any of you, therefore, when I show you that tool steel can be sharpened with silicon carbide. Now, what I propose to do is to change the configuration of this experiment and use the soft tool steel to cut silicon carbide, and if I can do that, I think you will agree that I have gone some way to being able to cut quartzite, which is about as hard as tool steel, with tungsten carbide, which is harder than quartzite. Let me do this. (Demonstrates.) That, I think, is a very clear demonstration of how it is possible, with a metal, to cut an extremely hard and brittle material. What, essentially, is the difference that we have here? In the first case, I held the tool with a relatively low force against the hard silicon carbide wheel. This generated a relatively low average stress, which was insufficient to fracture the carbide wheel. Nevertheless the protuberances on the silicon carbide wheel indented the tool steel and abraded it at a multiplicity of points, and quickly reduced the section of the tool steel that I held against the wheel. By changing the configuration and clamping my tool steel in a firm post, against the silicon carbide wheel, I changed these conditions very extensively. I now had a high force. I had to exert a considerable moment on that lever. The tool was anchored so that it could sustain these high forces, and they generated high stresses, which were adquate to fracture the silicon carbide. Now, what about wear? It so happens that, in these two experiments I have just done, the power I was using was about the same-a small fraction of a horse power.

May 1, 1968

By J. A. Maritz, D. F. Malan

Pillar strength is affected by pillar shape, but this has largely been ignored in past research studies. Bord-and-pillar layouts are typically designed using empirical strength equations developed for square pillars. Owing to the poor quality of pillar cutting, many hard-rock pillars have an irregular shape and it is not clear how this affects pillar strength. Furthermore, the strength of rectangular pillars in comparison with square pillars is also difficult to quantify. The ‘perimeter rule’ is widely adopted for rectangular pillars, but its applicability for pillars with irregular shapes has never been tested. We used numerical modelling in this study to investigate the effect of pillar shape on strength. An analytical limit equilibrium model of a square and a strip pillar also provided useful insights. For slender pillars, the strength of a long rib pillar is essentially similar to that of a square pillar. In contrast, for rib pillars with a large width to height ratio, there is a substantial increase in strength. The study found that the perimeter rule should not be used for irregularly shaped pillars. Displacement discontinuity modelling, using a limit equilibrium approach, is proposed as an alternative to determine the strength of these pillars.

May 3, 2023

By N. Hamlef

In this study, the effects of heat treatment on phase formation and surface morphology of the Cr-Pt coated system are investigated using X-ray diffraction and electron microscopy techniques. The CrPt andCr4Pt (Cr3Pt - A15 type) phases were formed after heat treatment of the coated samples. Heat treating at 1000°C renders a distinct island coating morphology that is non-continuous in nature. A diffusional model is proposed for this coated system with regards to the surface morphology formation after heat treatment.

Jan 1, 2014

The visit which took place on the 18th February, 1972 was a departure in that the places visited had no direct connection with the work in which members of the Institute are normally engaged. It was refreshing and stimulating to see important and involved operations normally outside ones own trend of life and to have experts to speak about technical, financial and matters of general interest concerning their work, not forgetting their troubles and problems and how they overcame them. Carlton Centre The members of the Institute were received by Mr D. Appleton, Public Relations Officer of the Carlton Centre Limited, who introduced Mr L. R. M. Fee of W. Rhodes Harrison, Architect in charge of the project; Mr W. C. E. Skilton of Murray and Roberts, the Engineer in charge of the construction of the complex and Mr A. Home the Senior Operating Engineer of Carlton Centre Limited. Each of these gentlemen addressed the members giving short rundowns on the project with special reference to their particular sphere of the undertaking. A variety of particularly interesting statistics relating to the planning construction and the ultimate operation and maintenance of the complex was given. Mining engineers present had an opportunity to compare the problems encountered by them associated with depth to problems encountered by the civil engineer in the construction of a building rising to such an enormous height. To some of the members a sense of similarity of the labour problems encountered must have been recognised. After tea the visitors were divided into groups, each under the guidance of an official, and then visited the highest floor accessible and thereafter the 19th floor where the internal arrangements for airconditioning, lighting, plumbing, power supply and communication arrangements were explained. Thereafter a visit to one of the seven basements which houses all machinery required to serve this enormous complex enabled the visitors to see the standby power arrangements as well as the refrigeration plant. The visit finished in time to proceed to the Crest Hotel in Hillbrow for lunch. To our hosts for the visit to the Carlton Complex a special vote of thanks is recorded. Strydom Tower In the afternoon the party proceeded to the Strydom Tower where Mr Knight from the Public Works Department who was the Engineer in charge of the construction of the tower gave details on the construction and the extraordinary methods which had to be adopted to achieve the desired objectives and to overcome known as well as unforeseen difficulties. The comparatively short time taken to complete the project and the good safety record appeared to impress the visitors. The final phase of the visit was taken care of by Mr Bothma of Telecommunications Department of the Post Office, who gave an extremely interesting explanation of the telecommunication organization of the Post Office with particular reference to the part the Hillbrow Tower plays in the South African telecommunication system. Both gentlemen answered many questions willingly and interestingly. Following the explanatory talks the visitors were shown the technical equipment housed in the two top levels of the tower. Short explanatory talks gave members an insight into the workings of one of the most important aspects of modern life. Even to the amateur photographer opportunities existed to view and photograph the city from the highest available observation point. We are indebted to Mr Gouws, the Regional Director of the Post Office for granting permission to visit sections of the tower normally not accessible to the general public and to our hosts for the manner in which we were received and entertained on the explanation of the many interesting features of this important installation. In conclusion, the programme for the day can be classified as interesting, of exceptional educational value, and an opportunity to see something of the engineering skills put into two vast and ambitious undertakings and the results achieved.

By I. O. Flores, A. Anani, H. Li

Current technological advancement has increased the exploitation of deeper ore bodies using underground methods. In certain cases, the mineral deposit starts near the surface and continues deep within the earth's crust. Such deposits are best mined with both underground and surface methods. Two main techniques are used to determine the optimal transition depth from surface to underground - a disintegrated approach and an integrated approach. Both methods have limitations in their use to determine the optimal transition depth. The objective of this research is to investigate the conditions in which an integrated approach to the transition depth problem is superior to a disintegrated approach. Three binary integer linear programming models are developed for this purpose: a surface and underground model for the disintegrated instance and an integrated model. A case study is performed to validate the models, with a comparative sensitivity analysis to obtain operational insights.

Sep 1, 2021

By G. Coetzer

"Prior to operating a non-recovery coke pilot plant oven, it was essential to ascertain coal cake stability during the loading of a 1 m3 (1 m × 1 m × 1 m) coal cake into the cold pilot-plant oven by a pusher mechanism. Previously established laboratory-scale compaction parameters, to obtain coal cakes with sufficient stability, were employed during the loading tests of the coal cakes. Two different coals were evaluated, namely Waterberg semi-soft coking coal (sscc) and Oaky North hard coking coal.It was demonstrated that lower applied compaction forces (14%) can be utilized during 1 m3 compaction, in comparison to laboratory-scale tests, to obtain similar wet cake densities, owing to differences in the effect of frictional forces. Wet cake densities for Waterberg sscc improved slightly (3%) to 1.13 t/m3 when utilizing 79 t/m2 applied force for a 1 m3 coal cake, in comparison to laboratory-scale tests. Similar results were obtained for Oaky North hard coking coal, with a 6% density increase to 1.27 t/m3 at a similar applied force. Porosities decreased by 13% and 32% for Waterberg sscc and Oaky North coal, respectively, when 1 m3 compaction was compared to laboratory-scale tests. An opportunity exists to further decrease the porosities of Waterberg sscc during compaction, whereas acceptable compaction parameters were achieved for Oaky North hard coking coal. Most major vertical cracks and the partial collapse of coal cakes were mitigated, and high-stability coal cakes were obtained that could be successfully loaded into the pilot-plant coke oven by a pusher mechanism.Factors contributing to the instability of the coal cake during loading into the oven, such as vertical cracks, are (i) the cubic geometry (1 m3) of the coal cake, (ii) friction exerted by the oven floor, and (iii) mechanical problems, such as a misalignment between the pusher machine feeder plate and the oven floor. IntroductionOperation of the stamp-charging horizontal 1 t electrically heated coke pilot-plant oven at Exxaro Resources requires coal cake stability during the loading of a 1 m3 compacted coal cake into the oven. In this case, a pusher plate is utilized to push the coal cake into the oven over the oven floor. This is in contrast to a ‘spoon’ or bottom plate feeding mechanism as found in industrial horizontal coke ovens. The pusher plate loading mechanism dictates that the coal cake should possess high stability and inherent strength owing to frictional forces exerted by the oven floor. In order to obtain a coal cake of acceptable stability for the 1 t coke oven, various compaction parameters need to be verified and established."

Apr 1, 2019

By F. P. A. Robinson, C. R. Thomas

Stress-corrosion studies on materials used for surgical implants * by C. R. THOMAS and F. P. A. ROBINSON Samples of Vitallium (a cobalt-chromium alloy), 316L stainless steel, and titanium T318 were subjected to the boiling magnesium chloride test so thattheir susceptibility to stress-corrosion cracking could be determined, and their behaviour under service conditions was then assessed. Stress-corrosion cracking was confined to the stainless-steel samples, while gross pitting was detected in the samples of forged Vitallium. It was concluded that the use of stainless steel should be avoided for long-term surgical implants. Surface imperfections on the stainless steel are generally the cause of pitting, from which stress-corrosion cracks are sometimes propagated.

Jan 11, 1976

By D. F. Malan, J. C. Esterhuyse

In this study we explore the use of a novel numerical modelling approach to study the effect of pillar reinforcement on pillar stability. Case studies in the literature indicate that tendons, strapping of the pillars, and shotcrete or thin spray-on liners are commonly used to reinforce pillars. No clear methodology exists to select the type of support or to design the capacity of the support required, however. This has led to ongoing collapses in some mines in spite of heavy support being used to reinforce unstable pillars. A limit equilibrium model with confinement on the edge of the pillar was used to simulate the interaction of the support with the failing pillar. The model correctly predicts that an increase in confinement will lead to a decrease in the extent of pillar failure. As the displacement discontinuity boundary element method allows for the efficient solution of largescale bord-and-pillar layouts, the effect of pillar confinement can now be studied on a mine-wide scale. Accurate calibration of the limit equilibrium model is, however, required before this method can be used for the design of effective pillar support.

May 3, 2023

By A. A. Rogozhin, S. I. Anufrieva, A. V. Kurkov

The results of development of technologies for flotation concentration of two types of complex beryllium ores are presented: beryllium-fluorite in apocarbonate metasomatites (Type I) and rare-earthberyllium in feldspar metasomatites (Type II). The researched samples of Type I ores contain a mineral complex that is difficult to separate by fatty acid flotation, including phenakite, bertrandite, fluorite, and carbonate minerals. The ores are characterised by an increased content of fluorite and carbonates. The sample of Type II ore contains such rare-earth minerals as bastnesite and orthite, and a beryllium mineral - cleiophane. The size of individualised grains of cleiophane does not exceed 0.04 mm, which significantly limits the possibility of extracting the mineral into the enrichment concentrates. For the Type I ores, a technological process for the extraction of fluorite using a phosphorus-containing reagent from the class of dialkylphenyl polyethylene glycol esters of phosphoric acid (DAPEGEPhA) has been developed. The use of DAPEGEPhA enables the production of a high-grade fluorite concentrate (95% CaF2). The production of commodity phenakite-bertrandite high-grade (10% BeO) flotation concentrate from the fluorite flotation tailings with using a fatty acid collector is based on binding calcium in the flotation pulp using soda, sodium hydroxide and sodium tripolyphosphate. The use of a combined collector based on fatty acids and DAPEGEPhA made it possible to produce a collective rare-earthberyllium- lithium concentrate with high REE extraction (88%) from the Type II ores. The concentrates obtained are suitable for production of commercial-grade hydrometallurgy products. Keywords: Beryllium ores, flotation, reagents, concentrates, hydrometallurgy products

Jan 1, 2020

By A. N. Brown

The Eighteenth International Symposium on the Appli¬cation of Computers and Mathematics in the Mineral Industries was held in London from 26th to 30th March, 1984. The Symposium was organized by the Institution of Mining and Metallurgy under the leadership of Mr M.J. Cahalan, Chairman of the Organizing Committee. The venue chosen was the Royal School of Mines, Imperial College of Science and Technology, in South Kensington. Some 300 delegates from all parts of the world attended, which included a delegation from South Africa that numbered about 20 persons. This extremely successful series of international meet¬ings was begun in 1961 in Tucson, Arizona, and has grown in strength and importance over the years. The arrange¬ment of the symposia is regulated by the International Council for APCOM under the Chairmanship of Professor R.V. Ramani (U.S.A.), the other current members being Professor J. Elbrond (Canada), Dr Thys B. Johnson (U.S.A.), Professor Young C. Kim (U.S.A.), Professor D.G. Krige (R.S.A.), Professor A.J. Lynch (Australia), Professor C.T. Shaw (U.K.), Dr A. Weiss (U.S.A.), and Professor F.L. Wilke (F.R.G.). There is no doubt that the enthusiasm and dedication of this small group of people and the excellent working relationship that exists between them are responsible for the continued success of APCOM meetings.

Jan 1, 1984

By V. C. Robinson

INTRODUCTION Most presidential addresses are in the nature of a review of some specific topic and this will be no different. In thinking about the subjects which might be suitable for this address I decided that as next month will see my retirement from the gold mining industry I might review the four decades since I started in the industry in 1929. These four decades have been more than usually in',~resting and exciting. They have covered a period when the price of gold increased from the old figure of 84/- an ounce to the price of $35 an ounce today, taking in on the way at least two periods of premium sales from which the producer benefitted. The industry in these four decades has survived the most totally destructive war in history and has seen fundamental changes in the political, economic and governmental life of South Africa. There have been great technological changes and improvements, some of which I shall refer to later, and in addition there have been profound changes in the relations between employer and employee in the industry which have affected not only the economy of the industry but the traditional thinking of both management and labour. I believe that the address presented to this Institute on the occasion of its 75th Anniversary by Mr Goode covered more than adequately the history of the Institute and the part it has played in the mining industry of South Africa. It would be merely repetitive, therefore, to discuss the affairs of the Institute of Mining and Metallurgy. Having said this, however, it is also necessary to point out that the history of the Institute is, and always will be, an important record of the history of mining in South Africa. There are many facets, however, on which we ought to look back and to re-examine. One of the most rewarding, but at the same time one of the dullest, places to look for historical facts is in the annual reports of the Chamber of Mines. I suppose that some of the dullest of these have been the reports for which paragraphs have been prepared by me personally. The notes which follow do not claim to be anything like a full record of this exciting period. RISE AND FALL OF THE GOLD MINING INDUSTRY In talking about the mining industry of South Africa it is inevitable that one talks, particularly in the historical sense, about the gold mining industry - an industry of fundamental importance which has made South Africa what it is and which has been dying since the early part of this century. In Table I is shown the progress of the gold mining industry measured by its output of ounces of fine gold from the beginning of operations until the end of 1969, and if you are interested in the productivity of the men who work this industry the table, composed entirely from figures set out in the Chamber's annual reports, also shows the production of gold expressed as fine ounces per European and fine ounces per Bantu worker over a long period. If you are still minded to think of this industry as dying then the last column in the table shows how uranium has played such a vital part in the prosperity of the country.

By M. Mpofu, G. Stenzel, F. Magweregwede, B. Maphalala, T. Kgarume

Surface coal operations in which mining activities are conducted above old underground workings experience hot holes after drilling. In a coal mine, hot holes are defined as shot holes, which after being drilled have an in-hole ambient temperature of 40°C or above or show a temperature increase of 3°C or more during monitoring. Hot holes and other cavities, such as cracks, pose health and safety risks to workers, such as exposure to hot air and high concentrations of noxious gases released from these holes. In addition, workers may be exposed to premature detonation of explosives caused by in-hole temperature increases and chemical reactions. To this end, Coaltech Research Association commissioned a project to develop a Best Practice Guideline for the management of hot holes. This paper is a compilation of the activities conducted in the development of the Best Practice Guideline between 2021 and 2022. The activities included a review of standard operating procedures and hot-hole temperature-measuring and -monitoring devices, and the assessment of current hot-hole procedures at selected mines. The results indicated that management of hot holes requires a focus on pre-emptive risk assessment of mining blocks, identification of hot holes using the correct temperature-measuring devices, and continuous monitoring of hot holes from the time of drilling until just before blasting. Hot-hole management accessories, such as polyvinyl chloride sleeves, were found to be effective in insulating the hot-hole emulsion from the rock mass temperature, thus preventing the potential for premature detonation.

Sep 9, 2024

By L. Cortez, Á. Magalhães, F. Durão

Methods based on regionalized variables theory, commonly known as geostatistics, have been widely used since more than three decades to predict/estimate spatial distributed data, namely mineral resources, with quite good results. However, some restrictive theoretical assumptions, such as the need of some kind of stationarity of data and the linearity of the predictor/estimator, are often wrong options in many applications. An alternative approach based on a finite mixture modelling, or cluster weighted modelling (CWM) technique, is presented and compared, in its theoretical and practical aspects, with the geostatistical methodology. CWM is a general non-linear framework based on the estimation of joint density functions allowing the calculation of the conditional probability function of the target values given their locations. Validation tests are performed in a 2D case study, where testing data proceeds from a soil contaminated by a heavy metal. The results of ordinary kriging and CWM estimations show a very good agreement with actual data. Keywords: Non-linear regression, Geostatistics, Ordinary kriging, Finite mixture modelling, Cluster weighted modelling.

Jan 1, 2003

By T. Nghipulile, M. Moys, M. Bwalya, H. Simonsen

The quest for efficiency in comminution is an ongoing concern as comminution usually constitutes a major cost component in the metal production industry. Such improvements can be made by circuit optimization or development of more efficient equipment. A novel crusher, known as the rotary offset crusher (ROC), promises to deliver in this space. The ROC was invented in 2002 by Michael Hunt, Henry Simonsen, and Ian Sinclair, but failed to garner enough support to progress to production. The original design concept was recently rekindled, and a laboratory version of the crusher has been built and commissioned at the University of the Witwatersrand. The crusher is simple in design, with two cylindrical discs that are parallel to each other, and, as the name implies, there is an offset between the vertical axes of the discs. The top disc has a conical section on its lower face, and this creates a crushing zone between the opposite faces of the two spinning discs. Centrifugal motion transports particles through the crushing zone. Batch experiments have been conducted with quartz at various crusher settings (discs offset, rotational speed, and vertical exit gap) for various feed size distributions. The indications so far suggest that the disc speed is a key factor affecting the performance. Size reduction ratios as high as 11 were recorded from experiments with quartz at a speed of 830 r/min.

Jan 1, 2021

By S. W. Jacobsz, Y. Narainsamy

Several high-impact tailings dam failures around the world in recent years have placed a renewed focus on the stability of tailings dams and pointed to potential shortcomings in traditional drained design and safety evaluation procedures. A need to consider undrained shear strength in the design of tailings facilities has become apparent. However, there are specific requirements that need to be met before undrained shearing occurs. In South Africa, the last major failure was likely the Merriespruit disaster in 1994, which leads to the question of whether the conditions required for undrained shearing are readily applicable to South African tailings dams. This paper describes research at the University of Pretoria that has recently commenced to further investigate the conditions required for undrained failure to occur. The research includes laboratory and field testing to replicate these conditions in the laboratory and relate them to those found in an active tailings dam.

Jun 2, 2022

By M. J. U. T. Van Wijngaarden, R. J. Dippenaar

An electrochemical technique based on the solid oxide galvanic cel Mo / Mo + MoO2/ ZrO2-MgO / Fe + (FexO)slag + Ag / Fe was used in a determination of FexO activities in liquid slag systems. The emf measurements, scanning electron microscopy, and microprobe analysis of the cross-sections of the electrolyte tubes used in direct contact with the slag melts indicated that slag attack did not affect the open-circuit emf values during normal cell operation, The reliability of the cell was confirmed by the good agreement between the standard free energy of formation of liquid Fep obtained in the present study and those reported in the literature, The FexO activities were determined in FexO -CaO and FexO-SiO2 slags at 1673 K, and are in good agreement with those measured by the conventional gas-equilibrium technique. The experimental technique was successfully extended to the measurement of Fe2O activities in the complex slags that are used for the external desilliconization of the hot metal product of the blast furnace.

Jan 1, 1986

By Lene Hansen

Sulphuric acid plants now and then see unexpected increases in SO2 emissions. Our experience is that it is not always easy for the acid plants to pin point the exact reason for the SO2 increase. Sometimes a catalyst bed is sacrificed even though reliable emperature readings and gas analyses could have verified satisfactory activity, hence the leaking heat exchanger is never discovered and after the shutdown the SO2 emissions are still too high. This paper will look into some basic catalyst management tools: Good record keeping is a necessity for collection of representative catalyst samples, reliable operating data is an inevitable starting point for all analysis and trending of operating data is a must for plant optimisation and troubleshooting. In addition these catalyst management tools will give a continuous updated knowledge of the catalyst status in each bed providing the basis for a more effective replacement strategy. The most typical reasons for increasing SO2 emissions will be presented together with easy guidelines for cross-checking of operating data, temperature optimisation and good record keeping.

Jan 1, 2009