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In order to fully understand why Amax Coal puts such extreme emphasis on the drilling and blasting programs at each of our mines, we must review the past. This paper will discuss the drilling and blasting techniques we used in the 1970s and their evolution to current practices. As time progressed, major changes influenced the surface mining of coal through new more restrictive governmental controls and local communities organising into groups with two goals in mind, one to shut down the mines and the second to try and get rich by making false and unjust damage suits against the mines. In virtually all of our midwest surface operations we have at one time or presently are facing litigation that has reached into the millions of dollars. Amax Coal has worked in co-operation with the United States Bureau of Mines in the areas of blast vibration, shot design, highwall safety, blast casting studies and many more. Today we are continuing to work with Dr David Siskind and his expert staff seeking answers to old and new problems addressing the blasting of overburden and parting seams.

Jan 1, 1995

The paper highlights the conceptual developments in rock mechanics applied to quantify the effect of bolts in the stabilization of joints and yielding soft rocks. NOTATION Aa = stress change after excavation Eä EE, Eä = moduli of intact rock, single joint and jointed rock Eb = elastic modulus of the bolt k, = normal stiffness of joint Ab = cross section area of the bolt A, = area of influence per bolt ab = axial bolt stress e, = axial strain of the bolt eä e,, ej, = strains of intact rock, joint and jointed rock Ai = area of the joint ,r+ = shearing resistance of the bolt (at the joint) a = normal stress at the joint plane aäa3 = major and minor principal stresses c;, 4i; = cohesion and friction angle of the joint 0 = angle between the bolt and the joint a = inclination of the joint to the vertical axis P = bolt density parameter u, = convergence of unsupported tunnel section u, = convergence of bolted tunnel

Jan 1, 1992

By G Solly, P J. Leevers

Day-to-day operating practices at existing operations need provide high quality data for decisions that will impact directly on the potential value of the available resource, in addition to meeting standards of quality expected of data used in feasibility studies that will be completed to obtain additional capital required to finance operational improvements. Drill hole location, down hole survey and assay data standards of accuracy and precision have received considerable attention in recent years. The authors propose that geological descriptions of both cored and non-cored drilling warrant at least equal attention, considering their fundamental role in establishing the framework used for geological modeling and resource estimation. The iron ore deposits of the Middleback Ranges have been a major source of iron ore for almost a century. High-grade hematite-dominant ore is currently mined by OneSteel from three open pit operations supplying ore to the companyÆs integrated steelworks at Whyalla. A review of OneSteelÆs future iron ore resources, commenced in 2002, highlighted the need for more flexible and comprehensive management of all forms of geological data used in resource evaluation. Driving this program was the information needs of feasibility studies of the Iron Magnet deposit, located beneath the existing Iron Duke and Iron Duchess mines. Prior to the beginning of 2003, resource evaluation drilling data collected by OneSteel was managed using an in-house system based on industry standard relational database software. The system was demonstrably effective in ensuring the fundamental integrity of basic drilling data, but lacked necessary capabilities for the acquisition and management of geological descriptions, geotechnical and geophysical data obtained by down-hole logging. OneSteelÆs existing system for the management and interpretation of geological descriptions was restricted to storage of a single three digit code for each lithological description interval. The original logs for a large number of older drill holes could not be located, having been either poorly archived or culled from the database in the belief that they did not contribute to the understanding of the resources currently being mined. The three digit codes represented a combination of lithological and stratigraphic descriptions, including many subtle variations in iron ore colour and texture believed to be associated with variations in geochemistry, but subsequently demonstrated to be either incorrect or inconsistently applied. This resulted in the establishment of a plethora of codes for a relatively small number of distinct lithologies. Improvements implemented by OneSteel geologists addressed these shortcomings by ensuring the new data management system: facilitated the objective description of lithological characteristics; distinguished between obsevations and interpretations (eg lithology versus stratigraphy); promoted consistency between descriptions provided by different geologists; and helped to ensure data integrity by developing an audit trail for alterations made to data subsequent to its acquisition. The data used to develop interpretations of mineralisation distribution and characteristics are fundamental to the effective utilisation of a mineral resource: any mineÆs most important asset. Resource related risk is widely recognised as the principal source of technical risks affecting resource development projects, whether they are new mines or expansions of existing operations. A key lesson from this work is that most commercial or æin-houseÆ developed geological data management systems are able to handle basic data validation tasks effectively. Geologists, however, need to ensure that the data management system is appropriately structured to help promote the acquisition of objective and consistent data for interpretation.

Jan 1, 2003

By E du Plessis, M Rowley, M Fallon, F Golenya, R Swanson, I Robertson

"Check sampling programs were undertaken at Barrick Australia Pacific LimitedÆs Lawlers and Plutonic mine sites in Western Australia. The programs identified that the sampling, sample preparation and assaying protocols required modification to ensure acceptable precision (reproducibility) for each gold mineralisation type. These case studies describe the processes used to identify the: inconsistent precision different types of test work programs that were conducted to quantify the appropriateness for each mineralisation type steps used to modify the protocols.The type of test work conducted included: a duplicate series heterogeneity test for particulate gold mineralisation in the Lawlers gold deposit screen fire assay test work on duplicate subsamples for arsenopyrite associated mineralisation at the Plutonic gold deposit.Each test work program required a detailed scope specifying the sample selection criteria, sample preparation and assaying steps. The aim of the test work flow chart design was to ensure the assay precision between the different particle sizes or duplicate sample pairs could be measured and calculated. In the screen fire test work the true grade of the primary sample was calculated and compared against each subsample.A high quality assay laboratory was utilised for the test work. All samples were fire assayed and the gold grade determined using a gravimetric finish. The assay results were validated and the data was analysed using tables and graphs in spreadsheets. Following data analysis a modified sample preparation and assaying protocol for each mineralisation type was designed for use by the principal assay laboratories. Following implementation of the new protocols, routine check samples were collected during the sample preparation and assaying stages to monitor the performance of the new protocol.CITATION:Fallon, M, Rowley, M, Du Plessis, E, Golenya, F, Robertson, I and Swanson, R, 2012. Confirming the sampling, sample preparation and assaying protocols used at two Yilgarn gold deposits, in Proceedings Sampling 2012, pp 47-62 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Aug 21, 2012

The P49 Shaft, Hilton Mine, was sunk and equipped for Mount Ise Mines Limited by con- tractors Cementation - Thiess Joint Venture. The leached siltstones to a depth of 150m were known to contain large volumes of water. These siltstones were cored and tested in the laboratory. Field results confirmed that cement grouting was relatively ineffective but that chemical grouting was effective. The Sm diameter shaft was sunk to a depth of 1040m. Weak strata to the full depth re- quired continuous temporary support by rock bolts and mesh before the concrete lining was poured, and made sinking conditions difficult. After completion of the shaft sinking the headframe was redesigned and modified to allow shaft equipping as a combined service and hoisting shaft with seven compartments. The shaft steelwork was designed and fab- ricated for service with high speed conveyances operating under corrosive conditions. The steelwork, weighing approximately 1500 tonnes, was installed to a high degree of accuracy which required guides not to depart from true verticality by more than 2mm over any 5m, or 15mm over the full shaft depth.

Jan 1, 1976

By C I. Edwards

Phosphorous is typically present in iron ore either in the mineral apatite, Ca5(PO4)3OH, or associated with the goethitic fraction of the ore. In this paper, we present results that show that phosphorous associated with the goethitic fraction can be removed with a heating pretreatment around 300 176;C for 1 h, followed by a caustic leach with 1 - 5 M NaOH, or a leach with sulfuric acid at pH 0.5. The heating pretreatment is considered to dehydroxylate the goethite to form a haematite intermediate phase, ‘protohaematite’, that reacts during the leach making the phosphorous accessible to the leachant. In the acid leach, ten to 15 per cent of the sample was dissolved to obtain a leach product with 0.08 per cent P. In the caustic leach, as no weight loss occurs, it is proposed that iron species associated with the protohaematite have either not dissolved or have reprecipitated at the high pH values of the leach.For an ore containing apatite as the source of phosphorous, a leach with sulfuric acid dissolved the apatite, lowering the phosphorous levels in the sample. The sample treated contained carbonate minerals (including siderite) that also reacted with the acid, and in practice a balance between the dissolution of the apatite and the carbonate minerals may be needed to minimise acid consumption.

Jul 11, 2011

By Konishi Y, Morioka Y, Okabe K

A part of the results of dissection survey of Chiba No.1 blast furnace, Kawasaki Steel Corporat- ion, is presented. Distributions of coke size and of slag and metal holdup are shown in the region of the dropping zone. A similar relation to the irri- gated packed bed is obtained. The distribution of coke size, coke temperature and liquid holdup are measured in and around the raceway. The shape of raceway in the horizontal and vertical sections indicates that each raceway worked individually. Liquid flow in the dropping zone and around the raceway on the basis of holdup measurements is Discussed.

Jan 1, 1981

By G D. Price

The Golden Blocks Goldfield is located in the Slaty Creek area,North West Nelson, about 20 km west of Collingwood. Alluvial gold was discovered in Slaty Creek in 1861. Gold was mined from quartz veins up to 1.5 m thick at nine mines from the 1890s until the closure of the Aorangi Mine in 1911. Total production from the Golden Blocks Goldfield is estimated at 46 000 ounces of gold. The Aorangi Mine was the largest mine, with a recorded production of 27 978 ounces of gold at an average grade of 36 g/t. Quartz veins containing gold and sparse sulphide mineralisation occur in a slightly metamorphosed, complexly deformed over-turned sequence of Lower Ordovician sandstones and shales. Primary gold mineralisation is associated with intensely deformed zones that occur near or at carbonaceous shale and sandstone contacts. Some eighty-five percent of all gold production (39 000 ounces) came from four mines confined to the stratigraphically lowest, most widespread shale unit. The quartz veins exhibit textures consistent with a hydraulic fracturing mode of vein formation with fissure infill vein types predominating over replacement textures. Stylolites of carbonaceous material and recrystallization features within the veins suggest multiple phases of deformation. The lack of wall rock alteration, and low primary fluid inclusion temperatures of 200¦ - 265¦ indicate that the ore fluids were associated with a low temperature epithermal system. A model consistent with similar mineralisation styles observed in Ordovician sediments from Pacific Rim occurrences is presented. The high grades (up to 100 g/t) mined from the upper levels of several mines suggests supergene enrichment processes associated with the Upper Cretaceous weathering surface. The Golden Blocks Goldfield has had no modern exploration. The most recent exploration was undertaken in the early 1980s. There are known acid intrusives in the area, with potential for the application of new models of intrusive-related gold mineralisation.

Jan 1, 2004

Although laterite ores already provide a significant proportion of the world's nickel and cobalt production it is anticipated that they will surpass sulphide ores as a source of nickel in the next century. The most recent period of greenfield nickel project construction was during the 1970s when it was notable that all of the eight new plants were based on treating laterite ores. This was because of the relatively large selection of available high grade laterite ore deposits amenable to cheap open cast mining and a paucity of high grade sulphide ore prospect alternatives. Of the three processing options for treating laterite ores: 1. smelting for the lower horizon saprolite ore, 2. ammonia; and 3. acid leach for the upper horizon limonite ore, smelting currently accounts for about 80 per cent of nickel production. In the future, as saprolite ore grades decline because of relatively high exploitation rates, the incentive to process the large untapped reserves of limonite ore will increase. The high cobalt content of limonite ore also makes it ideally suited to processing by a hydrometallurgical rather than smelting route. With only two exceptions, all saprolite smelting operations have a Class 2 nickel end product (largely ferronickel) and do not produce a cobalt by-product. As a result of technological advances, the modified ammonia leach process for limonite and transition ore as undertaken at Yabulu, now allows the production of pure nickel metal as a Class 1 product, along with significant tonnages of cobalt by-product. The mixed Ni-Co sulphide intermediate product of the pressure acid leach processing of limonite ore at Mon is converted to Class 1 nickel and cobalt metal at Fort Saskatchewan, Canada.

Jan 1, 1996

By P G. Gaylard

P754 has been an unusual project in that its main aim was to develop a code of practice for metal accounting with the following key objectives:Development leading to an agreed industry standard at corporate governance level Significant improvement of the credibility of metal accounting from deposit to saleable product Development of guidelines for data collection, data analysis, reporting and audit A data analysis toolbox which provides go/no go testing for metal balance data Promotion of industry adoption of these guidelines to improve transparency and financial credibility. Over time, these guidelines may evolve into a code and eventually into a standard Develop and train engineers to become expert in metal balancing and reporting. Papers like this one and the workshop which follows this conference are part of promoting the code for adoption by industry. Developing a code of practice has traditionally been the provenance of professional bodies associated with particular industries û often on a voluntary basis. Given todayÆs industry pressures, it was felt that funding key input might accelerate the development process as well as offer opportunities to research some of the problems and to train some post graduate students in a difficult discipline. In fact, the project has brought together six industry sponsors from a wide range of process types, three research providers, and funded students in South Africa and Australia. The project has also attracted input from the financial community. A textbook to support the application of the code has also been written. The industry sponsors have made the Code and Guidelines available on request to help to facilitate its use by the mineral industry beyond the sponsor group. The Code and Guidelines have already been translated into Spanish and Portuguese which suggests that industry acceptance may happen quite quickly. The main thrust of the code is to integrate commercial and technical performance to a much higher degree. The Check in-Check out (CI-CO) method has been chosen as the vehicle for this combined approach. The mass and metal values used for CI-CO are 'absolute' and provide the basis of financial transfers. The CI-CO process occurs at each transfer of custody - whether between divisions within a company, or between companies. This approach means that measurement of mass and metal flows becomes the critical element of the process and that a quantitative knowledge of measurement accuracy and precision is also essential. This knowledge allows technical differentiation between differences which are within the expected margin of variation and those which must be formally identified as discrepancies and subject to a process of investigation and sign off. Hence, the application of the code for most companies should be more evolutionary than revolutionary, but with substantially more emphasis on measurement and definition of measurement error. Where this can be achieved, it should bring the mineral industry more into line with other industries competing for investment funds, community acceptance and future employees.

Jan 1, 2008

By U Rehm

The biggest hard rock double-shield tunnel boring machine (TBM) in the world, with a diameter of 12.4 m, is currently excavating the North-South Bypass, which includes a crossing under the Brisbane River, Brisbane, Australia, to relieve the often congested road traffic in the city centre. Ten years ago a 10.7 m Mixshield giant helped to handle the Olympic Games in Sydney linking the airport with the city centre for an improved transportation of fascinated visitors. In Shanghai, currently the biggest TBM in the world with 15.43 m diameter presents excellent performance rates; and in Paris a convertible Mixshield could be quickly changed from earth pressure balanced (EPB) to slurry type in order to handle the very heterogeneous ground conditions. In Madrid a 15.2 m EPB giant finished its tunnel job four months ahead of schedule. Large-scale TBMs have proved their economic and innovative potential to create the current and future underground architecture of mega-cities. TBM technology has made further large innovative steps in the last decade. State-of-the-art is a TBM for very heterogeneous ground conditions comprising hard and soft rock with additional high groundwater pressure. The machine concept is adapted to the various ground conditions and allows for a quick and flexible application. Ground treatment by means of additives developed to a helpful tool in this connection. To meet the special challenges of urban tunnel projects of nowadays it is of very high importance, beside applying highest developed technology of TBM, to have a comprehensive technical support during the project phase and to develop positive relationships between all participants of the project which last longer than only for one project.

Jan 1, 2008

I have been asked to speak today on the topic of Project Finance in the Mining Industry. Through this presentation, I hope to give you a broad outline of the concept of project finance. The first half of the presentation covers the principles involved in project finance and the second half moves to aspects more specific to the mining industry. I have worked for 3 years at Rothschild Australia. Rothschild provide finance for projects in the mining industry, world wide. We finance both large and small projects, with facilities varying from $2m to $100m.

Jan 1, 1990

It was Harold McMillan, Prime Minister of England 30 years ago, who used the phrase "The Wind of Change" to describe political events in Africa in his day. So well did this phrase capture the spirit of the time that it echoed around the world, and the echo has never stopped. Change is the constant factor in the society in which we live and everyone of us has had experience of the effect which it has had on our professional and personal lives.Change will not stop, it will continue at an increasing rate and the questions we must answer are how do we prepare ourselves to meet the challenge of future change and how do we take advantage of the opportunities which it will bring?It is these questions which I wish to discuss in this address.There is nothing new about change in the mineral industry, it has been happening for thousands of years and it will continue as long as civilisation exists on earth. One type of change is economic and we are all aware of the rises and falls which occur in the prices of metals and minerals (Figure 1). When these have happened in an orderly manner, and could be predicted and planned for, it has been possible to take advantage of the benefits and minimise ill-effects, but when they were sudden and precipitate, and could not be predicted, the consequences were serious. The extreme example, of course, was the oil price shock of the 1970s which had such disastrous effects on industry and society.Other types of change are social, cultural and political. They have all been important in recent years and will continue to be so in the future.But it is technological change which may well be the most important because its effects are profound and irreversible, and alter irrevocably the way in which we live. So in discussing the mineral industry in a changing world I will talk specifically about technological change.

Jan 1, 1989

By R-H Yoon

The thin film pressure balance (TFPB) technique was used to measure the kinetics of thinning of single foam films and disjoining pressures in the presence of sodium dodecyl sulfate (SDS) and electrolyte (NaCl). The results were analysed in view of the Reynolds equation to determine the role of surface forces in film thinning. It was found that film thinning is controlled by surface forces at thicknesses below approximately 200 nm. It was also found that hydrophobic force plays an important role particularly at low SDS and NaCl concentrations. The values of the hydrophobic force constant (K232) estimated from the film thinning experiments were used to predict the disjoining pressure isotherm using the extended DLVO theory, which were found to be in excellent agreement with experiment. The TFPB technique was also used to measure the equilibrium thicknesses (He) of the foam films stabilised by a non-ionic surfactant, n-octanol, in the presence of NaCl. At a given ionic strength, He increased noticeably with increasing octanol concentration at very low concentrations. This observation suggests that hydrophobic force is at its maximum level in the absence of surfactant and decreases with increasing surfactant concentration. The results obtained with the single foam films were used to explain the stability of the three-dimensional foams.

Jan 1, 2005

By K Baker, J Purtill

One of the key challenges for the mining industry globally is the rehabilitation of mine waste, and Queensland is no exception. Out of pit waste structures including waste rock dumps and tailings storage facilities, create novel landforms which require ongoing maintenance and pose risks to the environment and sometimes to communities. Where multiple mines co-exist, such as parts of Queensland’s Bowen Basin, individual mines can often be constrained by adjoining operations. This presents opportunities for broader rehabilitation strategies to be considered, more than the current single mine focus, that may provide better environmental outcomes for a region. Given recent global disasters involving tailings storage facilities, and our team’s endeavours to drive Queensland to achieve leading practice in mined land rehabilitation, we are exploring the potential to maximise in-pit tailings disposal opportunities for coalmines through shared waste management strategies. A shared waste management strategy is where two (or more) mines, owned by different companies and operated under different environmental permits, transport tailings from one mine to the other in close proximity, for disposal in a disused pit. This would reduce the number of waste structures to be built, operated, rehabilitated, and managed in perpetuity. Our objectives are to identify and remove barriers to tailings transfers between sites to:  minimise environmental risk  minimise long-term liability of managing mining waste and associated structures  support improved outcomes for the local community. To determine the scale of coal waste disposal practices in Queensland, internal data and publicly available imagery was analysed by the Department of Environment and Science in 2022. Approximately 6500 ha of land in Queensland is utilised for coalmine tailings storage facilities or codisposal areas, with ≈ 3700 ha of this being out of pit.

Aug 2, 2023

By N G. Corner

A sea bed sampling programme by CRA Exploration Pty Limited over an area of 12 000 km offshore from Westland, Southland and Otago, New Zealand, led to the discovery of the Harvester Prospect, an area of some 67 km2 which averaged 189 mg/m3 gold in surface samples. This area was in water depths of 70 to 106 m and contained a high grade core of 33 km2 which averaged 283 mg/m3 gold. The gold recovered was fine grained, averaging 124 microns, and indicated a potential resource of approximately 10 t of gold per metre of thickness. Interpretation of existing seismic and geological data suggested that the gold anomaly may be associated with a unit of sediments 10 - 40 m thick, probably deposited during a lower sea level stand. Two initial attempts at vibrocoring the anomaly produced inconclusive results. In 1989 a much more powerful vibrocorer with scaled up support facilities and a dedicated 24 h turnaround laboratory were employed. The final results clearly showed that the gold was from an uneconomic surface enrichment.

Jan 1, 1990

By K Osman, P Bennett

The mining of an underground orebody requires development both in waste and ore before stoping commences. Regardless of what metal is being extracted, the waste development is minimised to reduce the cost per unit of metal mined. At the Western Metals Zinc Kapok mine site, reducing the cost per tonne of lead and zinc mined is paramount. Decline waste development costs can be minimised by methods such as increased gradient or reduced drive size. Ore development will also involve some mining of waste. The degree to which waste mining can be minimised will depend on the thickness and dip of the orebody. The drive geometry will also determine the percentage of waste within the face. It is by mining methods such as resue mining that selective mining may be used to maximise the amount of metal mined and reduce waste dilution. Resue mining can be used around a set of selection criteria established by the mine site. These selection criteria will determine how resue mining can be applied to the mine site. Selection criteria include firing times, number of headings available, acceptance criteria for percentage lost metal, dilution and most importantly operator acceptance. The single pass or two pass resue mining method should be chosen depending on the site acceptance criteria and selection criteria. The Western Metals Zinc Kapok mine site has established a set of parameters which accept the two pass resue mining method for the mining of the ore drives. The blasting results from a single pass resue method were reviewed during more recent trials in a single heading. Through a comparison of results, the parameters allowed the decision to determine the applicability of resue mining and its current form to Kapok. This paper outlines the parameters set by the Kapok mine site, reviews these in relation to the two forms of resue mining and examines the criteria which make this mining method applicable for Western Metals Zinc.

Jan 1, 2002

By R Fletcher

Pacific Hydro, a leading renewable energy company from Australia, is developing a series of cascading run-of-river hydro electricity projects in the Cachapoal Valley at the base of the Andes Mountains some 100 km south of Santiago in Chile.These projects involve extensive tunnelling and underground works. The first of these projects is called Chacayes (110 MW installed capacity) and is now under construction with Astaldi SpA of Italy and Fe Grande of Chile as the EPC contractor. Astaldi SpA also has an equity stake in the project. It involves 6 km of tunnels between 5 m and 7 m diameter, of which 2.3 km is by tunnel boring machine (TBM) (5 m diameter).This paper outlines the local and regional geology, the scope of the Chacayes project, actual tunnel excavation rates and support, and compares the decision making on Chacayes between a choice of traditional drill and blast excavation versus TBM.The paper also outlines the next project planned to be developed by Pacifi c Hydro in the valley – the 140+MW Nido de Aguila project involving a main tunnel drive of 11 km with two intermediate adits, plus a 388 m shaft and underground powerhouse. The main tunnel drives are likely to be excavated by two hard rock TBMs (5 m diameter) but will need to be able to withstand high overburden pressures of up to 1300 m.Subsequent projects in the planning stages include the downstream Coya II project with two tunnels totalling approximately 10 km, one of which may be by TBM.

Mar 8, 2011

By M Chen, Q D. Gao, Y G. Hu, P Yan, W B. Lu

The safety and stability of construction structures are often affected by blast-induced waves. Investigating the generation mechanism of shear wave (S-wave) during blasting is important, because it has a strong effect in blasting damage. In this paper the generation mechanism and verification of S-wave was studied analytically and numerically. Under the finite velocity of detonation (VOD) of cylindrical charge or the compression wave (P-wave) communicating with the interface of different media during the propagation, the generation mechanism of S-wave was analysed. Propagation of blasting wave in cylindrical charge was simulated with the elastic model, and the generation of S-wave induced by finite VOD was proved. To compare with different numerical methods in simulating the generation of S-wave, the blasting process of instantaneous detonation was simulated by using the elastic model, elastic-plastic model and smoothed particle hydrodynamics and finite element method (SPH-FEM) coupled model. Results demonstrate that the S-wave could not be found in middle section of the charge if the elastic model is employed. But when using elastic-plastic model and SPH-FEM coupled model, the generation of S-wave could be verified. Under the SPH-FEM condition, the amplitude of S-wave is larger and the arrival time difference between P-wave and S-wave is closer to theoretical results.CITATION:Gao, Q D, Lu, W B, Hu, Y G, Chen, M and Yan, P, 2015. Comparison of the generation of shear wave with different simulation approaches, in Proceedings 11th International Symposium on Rock Fragmentation by Blasting, pp 79–88 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Aug 24, 2015

By Walker G. S, Sparrow G. J

Dissolution of S02 into water-acetone mixtures results in the formation of 2-hydroxy-2-propane sulphonic acid. The pH, or acid strength, of water-carbonyl-S02 mix- tures can be controlled by varying the concen- tration of the carbonyl compound or the rate at which S02 is added to the water-carbonyl mixture during a reaction. The ease with which the acid strength of these mixtures can be controlled means that they have significant potential for use as a selective lixiviant. We have used water-acetone-S02 mixtures to selectively dissolve phosphate minerals in Christmas Island and Duchess phosphate ores and also uranium minerals in Yeelirrie uranium ore and Olympic Dam copper concentrate.

Jan 1, 1987