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Anodic stripping voltammetry is an analytical technique which has established some popularity for trace analysis of metals because of its sensitivity, selectivity and capability for simultaneous analysis of some elements. The technique can be readily adapted for field use because of its relative simplicity and low power requirements. This paper describes a relatively new instrument, the Portable Digital Voltammeter, developed by CSIRO, which utilises the glassy carbon electrode in a novel cell design and provides parts per billion (ug/L) sensitivity in an instrument which can be field operated. Ten elements, Zn, Cd, Tl, Pb, Cu, Sb, Bi, Hg, As and Au can be routinely analysed. Many of these elements are of interest to the mining industry, and to exploration geochemistry in particular. Case histories where the instrument has been successfully employed for stream and stream sediment analysis of Cu and Pb, for soil surveys of Cu and Au, and for Au in stream sediments and drill chips indicate there are advantages in having on-site data, during Exploration.

Jan 1, 1987

By P J. McCarthy

Globalisation and consolidation is resulting in the mining industry coming to be dominated by a small number of very large companies seeking to lever assets and knowledge to create wealth. As an important service provider to the mining industry, the minerals tertiary education sector needs to understand these global drivers and respond to them. However, it is under-resourced and its sustainability is under challenge in all Western countries. Through the establishment and funding of the Minerals Tertiary Education Council (MTEC), the Minerals Council of Australia (MCA) has provided a unique opportunity to build a national, world-class minerals tertiary education environment in Australia that can be sustained in the long-term. This paper reviews how the global changes occurring in the mining industry provide the model for what needs to occur in the minerals education sector and how MTEC is the logical vehicle to facilitate these changes. It concludes by suggesting that the time has come to integrate the minerals tertiary education providers into one business. Furthermore, the vision should be for a global mining education academy based around a virtual university capable of servicing the cultural diversity and continuing education needs of the global minerals industry.

Jan 1, 2001

By E Mielczarski

Determination of the adsorbed layer composition and structure at molecular and atomic levels and understanding adsorption mechanisms and dynamics are vitally important for the preparation of surface layers with specific functions. Direct information, at a molecular level, about mineral surface composition, its structure and surface distribution is crucial to perform an efficient separation process for mineral beneficiation. This information is equally important for modifying surface properties of industrial minerals for specific applications such as: fillers, composites, weathering resistance, etc. An understanding of the mechanisms and kinetics of the interaction of first adsorbed organic molecules with mineral surfaces is a fundamental requirement for the prediction and control of the macroscopic surface properties governing the efficiency of separation technologies or new material formulations. The developed infrared external reflection technique has a unique ability to study interface phenomena, at a molecular level, on heterogeneous substrates. The variety, precision and reliability of information about the interface phenomena delivered by this technique is superior to any other single technique. The experiments are fast and non-destructive. High sensitivity (starting from 20 per cent of the monolayer) in situ collected information in a multiphase system, even in the region of strong absorption of the substrate, makes this technique a very valuable experimental tool. The complexity of the recorded reflection spectra, their sensitivity to variations of the optical properties of all bulk and surface components and their spatial distribution in the system under investigation, are in fact the major strengths of this technique. A few examples of the application of this multi-diagnostic technique, for monitoring surface modifications of semi-soluble minerals for selective flotation, will be discussed in detail in this paper.

Jan 1, 2005

By Finch W, Dunne R

Understanding how liberated and unliberated minerals behave in comminution and classification circuits is of vital importance to ensure that maximum liberation occurs without unnecessary and costly overgrinding. This paper presents the results of a study carried out by the Julius Kruttschnitt Mineral Research Centre and Newcrest Mining of the liberation performance of Newcrest Mining's New Celebration grinding circuit. Using data from surveys of the circuit, together with QEM*SEM analyses of individual streams, a detailed picture of the liberation and classification of gold-associated pyrite is presented. In addition the relationship between the QEM*SEM analyses and results from laboratory leach tests are also discussed. Using the survey and QEM*SEM data, mathematical models were constructed of the performance of the ball mill and cyclones, and simulations carried out to investigate ways of improving the performance of the circuit. The results from the more promising scenarios are Reviewed.

Jan 1, 1993

By F Shi, W Valery

WMC Fertilizers (WMCF) operates a Beneficiation Plant at Phosphate Hill in Queensland, Australia. The plant consists of two-stages of crushing, followed by a wet scrubbing and desliming circuit. Ore is then fed to a tertiary crusher and a milling/classification circuit, with the final product going to a swing-lift thickener and storage tanks. From the slurry storage tanks, the phosphate rock is fed to a horizontal belt filters which dewater the phosphate rock ahead of a hemi-hydrate phosphoric acid plant. The water soluble recovery of phosphate in the phosphoric acid plant is dependent on the moisture content in the filter cake, as this governs the wash water addition to the hemi-hydrate filters. Since commencement of operation, the moisture content of the filter cake fed to the phosphoric acid plant has been higher than design reducing the phosphoric acid plant recovery and at times reducing the throughput through the phosphoric acid plant. The moisture content in the filter cake can be decreased by reducing the generation of fines in the milling and classification circuit (classified as û38 micron material). This paper identifies the causes of fines generation in the Phosphate Hill beneficiation plant. It discusses the options that were assessed to minimise fines generation, and outlines the results to date of circuit changes undertaken at Phosphate Hill.

Jan 1, 2003

Comalco Limited has recently completed construction of a $50 million kaolin plant at the site of its bauxite mining and industrial minerals operation at Weipa. The plant will produce 100,000 tonnes per annum of coating grade kaolin for the paper industry. Comalco produced the first coating kaolin from the deposit in 1979 on a trial basis. Since then a variety of quality coating grades with specific particle size distributions and brightness values have been prepared. Extensive drilling and bulk sampling of the deposit over eight years has shown that the ore body is large and of a high grade suitable for the production of premium quality coating kaolins. The processing plant technology was developed by Comalco in association with the European kaolin and equipment producer Amberger Kaolinwerke GmbH (AKW). The Weipa kaolin plant is the first of this size to be built in the Pacific Basin region and it will offer the region's paper-coating mills a stable and reliable source of high-quality kaolin, shipped from an established bulk loading port. The paper provides an overview of the development of the kaolin investment the nature of the production process and details the

Jan 1, 1986

By Wauchope AMH

Arsenic residues from BHAS Refinery operations are currently treated to form a calcium arsenic compound and stored in lined dams on site. Laboratory and large scale work on these residues has resulted in the development of a hydrometallurgical process for production of arsenic trioxide. The process also recovers the material from the storage dams. The residues are hot water leached to produce an alkaline arsenic liquor. This liquor is mixed with material from the storage dams and lime to form a calcium arsenic precipitate. The precipitate is then reacted with sulphuric acid to form gypsum for return to the main plant, and an acidic arsenical solution. Metallurgical gas containing 3-6% sulphur dioxide is bubbled through the solution and on cooling arsenic trioxide is precipitated. The product contains in excess of 95% arsenic trioxide. Installation of a plant at Port Pirie based on this process is being evaluated by BRAS.

Jan 1, 1984

During the intial two years (1972 - 1974) of exploration at Telfer, water require- ments were limited to supporting a 50 man camp and diamond drilling to verify thickness and grade of the stratabound ore deposit. Water bores were drilled to intersect the Middle Vale Reef down dip from its outcrop about 70 metres below surface. The MVR reef is an oxidized pyritic horizon which contains 30% - 65% sulphide below the zone of oxidation and forms a highly porous leached gossanous zone to a depth of 100 metres. Surface run-off water from the low hills associated with the Main Dome structure have led to annual re- charge of this extensive aquifer which MAP AREA Lake Waukarlyearly Permian rocks Precambrian basement - - ~;; rocks Sand d.n.s pò. _ « Drainage sg 1 qo~ (`-~.~ ? ò;+ Palaeochannel and 1 d {- subsurface drainage % GLENN BOREFIELD PASSMORE FAULT ;òTsI1. G-OId MIns BOUNDARY oChr~st as t .` Pool 4, 1 j`` Lake Dora òt ~daN 22' 0, 50 Niter KILOMETRES Fig 1. Telfer district map, Great Sandy Desert, Western Australia.

Jan 1, 1988

By G Neely

COPING WITH COMPLEXITY In every industry, and mining is no exception, plant and processes increase in complexity over time and managers and operators need correspondingly more knowledge. The mine manager has to delegate details to operators, engineers, metallurgists, accountants, safety specialists, personnel officers and the rest. Is it reasonable then, to expect the Mines Inspector to be competent to judge the conduct of all these operations against the criterion of the regulations? Obviously not, but what are the alternatives? One is a superficial inspection where the inspector goes on a hazard hunt for broken steps and missing handrails. Another is one in which an army of specialist inspectors marches on a mine, sometimes outnumbering the staff. Each is competent to assess some part of the operation and if he or she can find an opposite number among the mine staff, they can discuss details. But what good does it achieve? The system acts to remedy present defects and to make recommendations which, if only they were followed, would prevent the same things happening again. Given that this process has been going on since the first Factory Act of about 1840, how is it that there are any more defects left to put right? The answer of course is that defects keep appearing, and new defects arise as fast as the old ones are found and corrected. Further progress can only be made by preventing defects at their source.

Jan 1, 1994

By Q Xin, X Shengming, C RuÆan, Z Zhigeng a

The optimum defluorinating conditions for Sichuan bastnasite crude ore were determined by orthogonal experiments. Over 95 per cent fluorine in the crude ore was stripped by roasting 30 minutes of the crude ore with Na2CO3/ore =0.25 at 650oC. The stripped fluorine crude ore was further treated by NH4 Cl to recover rare earth. Above 95 per cent rare earth can be leached by water after the stripped fluorine crude ore mixed NH4Cl(NH4Cl/ore =1:1) roasted 1 h at 325oC. At the same time, the rare earth leaching solution contains little Fe, Si and Al. Therefore it is propitious to further purify the solution and recover rare earth.

Jan 1, 2000

By J Champa

The mining industry internationally seems on the verge of a major underground support revolution as suppliers, mines, consultants and researchers develop, test and use thin support (structural) membranes (or superskins as they are commonly called) mainly as a replacement for screen/wire mesh. Thick membrane support in the form of shotcrete (sprayed concrete) has been used since the 1950s in underground mines. Shotcrete, in mines, is generally applied at a thickness between 25 and 100 mm depending on the need. Thin membranes are however applied at a typical thickness between 2 and 6 mm. Certain thin membranes have been available for several years (Tannant et al, 1999), but the intense interest in such supports has only grown in the last few years. The interest lies mainly in the potential to safely reduce the mining cycle time and hence improve productivity. There is however considerable confusion concerning such supports, and this paper attempts to clarify certain aspects and dispel certain misconceptions and myths about thin support membranes.

Jan 1, 2000

By B D. Sowerby, N G. Cutmore

Improved process control can be achieved through the accurate and reliable on-line measurement of critical process parameters in real time. Over the past few decades on-line analysis techniques have been developed and applied in the mineral and energy industries for the measurement of process stream composition, mineralogy, particle size and flow rates. This has led to increased throughput and product quality while reducing processing costs and minimising emissions. The support of a sustainable mineral processing industry will require the further development of on-line analysis and control technologies. The application of developments in instrumentation combined with improved control strategies will lead to improvements in process efficiency resulting in large economic benefits to the industry, reduced energy usage and lower process emissions. There is a clear convergence of interests in being able to better measure and control minerals processing in terms of the triple bottom line of economic, social and environmental impacts. Technology is increasingly becoming available enabling measurement across the entire spectrum of minerals processing from mining to hydrometallurgy and pyrometallurgy. CSIRO is developing a range of these new technologies. A number of these developments are discussed in the present paper, namely: on-line particle size analysis and acoustic emission methods to enhance the control and optimisation of grinding circuits; on-line mineralogy of dry powders and slurries; on-line bulk elemental analysers for application on conveyor belts and in smelters; and the development of new sensing technologies for sorting base metal ores.

Jan 1, 2002

By G McLeay, T Moran

Long Shaft has traditionally been seen as one of the most challenging mines in the Kambalda area with operations having been suspended by the previous owners in 1999. When mining recommenced in October 2002, the current owners (Lightning Nickel) decided that a different approach was required for mining operations in such an aggressive geotechnical environment. This paper describes how Lightning Nickel has successfully and safely operated the Long Shaft complex on a traditional mining approach, which encompasses the key learnings of the previous owners.

Jan 1, 2005

Instantaneous outbursts of coal and gas have occurred in Australia in the Sydney Coal Basin since 1895 and in the Bowen Coal Basin since 1954. The largest has been about 500 tonnes of coal and so their magnitude and character have not approached those experienced in some other countries. The occurrence of CO2 with some Australian cases provides some similarity with the worst affected areas in France and Poland.The proneness of seams depends on coal rank and seam gas composition, among other factors. The proneness of places depends on depth, structure, intrusion, tectonism and other factors affecting the geometric, physical and chemical uniformity as well as details of mining. As a phenomenon due to gas and stress, prevention can be achieved by relief of high gas and/or stress condition. Alternatively, controls can be applied to render mining safe for personnel. Unfortunately day-to-day prediction is not widely and reliably achieved to allow selective use of prevention or control. The initial rate of desorption is the most promising day-to-day indicator.Various researches include gas conditions and parameters, stress and failure conditions and parameters, coal variables and geological variables in relation to prediction, prevention and control. Some assistance in research may derive from study of analogous phenomena of instantaneous outbursts of salt and other rocks and gas. It is concluded that in the Sydney and Bowen Basins, any coals with less than 30 per cent Volatile Matter (VM) ash free dry (afd) at depths over 200 m could be prone. Proneness increases with depth, with lower volatile content, with geological disturbance including faulting, intrusion and recent tectonics, with increased CO2 in seam gas, with narrow work and with other factors. Much more research is needed.Unfortunately outbursts are needed too, to provide the research with realistic data. With the problems of mechanism and prediction still being unsolved much research remains to be done. No present aspect of research is satisfactorily resolved.

Jan 1, 1983

By D Stow, M Edmondson

Lemington coal mine is operating in an environmentally sensitive area in the Hunter Valley, NSW, Australia. Late in 1999 the southern pit was developed using a series of box cut blasts. After the initial development the area would have been free dug due to the soft, well-jointed nature of the deposit. However, it was decided to trial drill and blast to determine if shovel productivity could be improved to enable an overall mining cost reduction. The initial trial blast results were less than satisfactory with both environmental issues occurring and the desired shovel productivity not being achieved. An audit of the blasts indicated that wet ground and the presence of soft clay inter-bedded with harder rock caused the poor blast results. Also, water-affected explosive product combined with explosive energy loss into soft ground led to flat spots and tight digging in the hard band areas, resulting in the lower dig rates. Lemington Mine and Orica Explosives developed a plan to match the rock with the appropriate explosive type and energy. This resulted in a number of blasts over a six-month period using a new non fuming explosive product, æNovaliteÆ. The results have been excellent with the environmental issues being totally resolved and dig rates improved, enabling reductions in mining costs. This has allowed the mine to continue with their exemplary record of environmental management whilst achieving operational efficiencies.

Jan 1, 2001

By Nagai K, Moriyama K

Toyo smelter has been making s veral efforts to reduce and diversify energy for dealing successfully with such :n:;rgy problems as the first and second oil crises. ::,specially it is one of th:; most important subjects to substitute oil by alternative: energy source, because oil is expensive and unstable with respect to its supply. t _'hercfore i was decided to propel tnC ezhstitution of coal *jr oil. in the first place, the supple- mental fuel oil in the reaction shaft was replaced by oil to coal in 1981, and then th, fuel substitution of pulverized coal was achieved in the steam superheater in 1984. 3y these fuel substitutions about 7u,' of the total fuel energy at 2oyo smelter has been replaced by coal. in this paper the fuel substitu- tions at loyo smelter are described in detail.

Jan 1, 1987

By J-P Franzidis, E V. Manl, K Runge

Over recent years a number of techniques have been developed as part of the Australian Minerals Industries Research Association (AMIRA) P9 project to represent mathematically or measure directly subprocesses occurring in flotation cells. These include the determination of a:machine parameter (bubble surface area flux, Sb); froth parameter (froth recovery, Rf); entrainment and drainage parameters; and ore floatability parameter (Pi). A cost-effective methodology was developed for using these techniques to derive models of flotation circuits. This methodology was applied to derive a model of the flotation circuit at the Western Mining Corporation (WMC) Ltd Mt Keith Nickel Concentrator. The model was used to simulate a number of minor circuit flowsheet changes, the results of which are discussed in this paper. One year later, a second study of this plant was conducted. In this second study, data were collected while operating the plant in the flowsheet configurations that were simulated from the model developed from the first study. The results obtained from the second study showed reasonable agreement with the trends predicted from the first study model; discrepancies can be explained in terms of the model assumptions. This suggests that this simple circuit modelling methodology can be useful in assisting plant engineers to optimise flotation circuits.

Jan 1, 2000

By Hegedus M

The Hydrogeological Survay of the bauxite mines in Hungary was establisned 30 years ago. The goal of the HS has been to collect the all available date needed to solve the hydrogeological problems of bauxite mines. The results of activity of the HS have been summarized in the annual reports-. This report is going to present a few methods to evaluate the hydrogeological properties of fissured, karstic rock ie. the evaluation of drilling mud losses, the statistics of core samples evaluated by a special computer program for calculation the porosity and permeability of the rocks. An experimental injection test is presented together with the development of a new portable instrument to get signes of the water table change during the injection test in every two second. It can be proved that the flow around the well may be a transient one if the yield of the injection exceeds a definite one (Figure 2.). It was observed that the permeability calculated from the pumping test date may be 1.2-1.6 time higher than it coming from the injection test. A practical example is presented also how to use the results of the HS for designing the dewatering of a new mine together with an analogous computer model to forecast the yield expectable for making the drift tunnel. A suggestion based on the hydrogeological feature has been done for the dewatering without using electric energy (see Figure 3.-6.).

Jan 1, 1988

By Kokubu H, Moro-Oka A

Gaseous desulphurization from hot metal- lurgical slags containing sulphur mainly as sulphide and(or) sulphate was measured under `low at four different oxygen pressures. The total gas rate was from 1.7 to 2,8 litre/min. Crushed slag samples weighing 2 to 12 g were used for the experiments. The amount of SO2 gas evolved from samples kept at 15500 was rieasured over tires ranging from 20 to 300 min. The gaseous desulphurization rate of sul- phide sulphur becomes high as the oxygen part- ial pressure is increased, while that of sul- phate sulphur is high under low oxygen pressure. The effect of basicity on the desulphurization rate of sulphide sulphur in oxygen atmospheres is not obvious in the range of basicity from one to three. Changes in the ratio of sulphide to sulphate sulphur during the run in oxygen axe analysed. Desulphurization reactions and the rate controlling steps are discussed. De- sulphurization phenomena can be explained by inte.-¦ucia.l chemical reaction rate control.

Jan 1, 1980

The Yabulu refinery of Queensland Nickel Pty Ltd located near Townsville now imports more than three million wet tonnes per year of nickel laterite ore from New Caledonia and Indonesia, making it the largest importer of any commodity in Australia. The project has illustrated that importing untreated bulk ore and re-exporting high value products makes good economic sense for the company and the nation. The economics of this exercise have been considerably enhanced in the past year by changing the project's principal product from nickel oxide sinter to refined high purity nickel metal. It is one of the few operations in the world where nickel ore is transformed to nickel metal at a single site. Several novel technological processes were developed at Yabulu and incorporated into the refinery to allow this product transition to occur. By utilising internally developed technology the new processes were installed at a capital cost of less than $10 million. It is unique for a large nickel producer to completely change the quality of its entire product range many years after the plant was constructed and considerable attention to marketing the new products has been required.

Jan 1, 1995