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By A. L. Rutledge, R. S. Nichols

"Waste dump development at the Fording River Operation s in British Columbia began in 1971. In 1981, several unique as well as unplanned situations provided an opportunity to study water flows through waste dumps.The key to the drainage is naturally segregated rock sizes .created by end dumping from the crest of a pile. The largest size material accumulates at the toe. Flow rates along the base of the studied dumps varied from 2,800 to 13,500 m3/day or 0.032 to 0. 156 m3/s (1.2-5.5 cfs}. Sediment concentrations in the water ranged from 1 to 1,800 mg/I.This paper describes water flows through dumps of varied lithology and maturity. The results suggest that neither long-term water flow nor contained sediments in small streams are jeopardized when crossed by end-dumped fills.IntroductionThe Fording River Operations are located in southeastern British Columbia approximately 115 km north of the United State s and 10 km west of Alberta, within the medial range of the Rocky Mountains. All production is carried out at elevations ranging between 1,600 and 2,200 m above sea level.The property is within a continental climatic zone, with temperature extremes of - 40°C in January to +35°C in July. The average annual precipitation of 335 mm of rainfall and 390 cm of snowfall feeds the numerous seasonal, small drainage courses along the Fording River valley.Since start-up in 1971, 149 million bank cubic met res of waste from truck-shovel and dragline mining have been placed in numerous dumps or ""spoils"". The dumps were developed to the point that several unique situations could be studied. During the peak run-off period of May-June 1981, water flow studies were performed on dumps of varied lithology and maturity. This paper describes the results of the study."

Jan 1, 1982

By M. Boher, J. Lehmann, M. C. Kaerlé

"In the production of high quality steel, the understanding of the interactions between liquid steel and refractories and of their effect on steel purity and cleanness are becoming more and more important.An experimental study has been per-formed in order to estimate the importance of the reaction between a MgO-based tundish refractory and an Al-killed steel. The results show a pollution of the liquid steel:•the silicon content of the liquid steel increases due to the reduction of the silica of the refractory by the aluminum contained in the steel; and•a reoxidation of the steel occurs and the formation of an oxide layer on the refracto-ry, mainly composed of spinel crystals and of Ca-aluminates is observed.The transfer mechanisms of the various elements are analyzed."

Jan 1, 1997

By S. J. Cook

The subject of capital and the Canadian mining industry is so broad as to be impossible of comprehensive treatment in brief form. The purpose of the present paper therefore will be only to outline in a meagre and somewhat sketchy way the nature and extent of the mineral industry in Canada and to point out those features which are likely to be of general public interest. Canada's mineral industry has a long and creditable production record. The? value of the output per capita rose from $2.23 in 1886 to a maximum of $26.40 in 1920 and the value of the products from ten million dollars in the former year to almost two hundred and twenty-eight million dollars in 1920. Compared with other primary industries and on the basis of the value of production, mining held third place in Canada in 1920, the premier position going to agriculture and the value of forestry production placing that industry second in the list. In the mineral industry, between six and seven thousand properties are operated annually giving employment to up- wards of sixty thousand employees to whom about seventy-five million dollars is paid in salaries and wages. During 1923, seventeen mineral products reached a production value of one million dollars or over in Canada and in order of the values assigned these were: coal, gold, nickel, cement, cop-per, silver, clay products, lead, asbestos, natural gas, stone, zinc, lime, cobalt, sand and gravel, gypsum and salt.

Jan 1, 1924

By J. C. Farge, G. G. Jacox

"The effect of composition and process variables on the properties of Marmet and modified Ni-Hard slugs will be discussed. The effect of shape on the over-all performance of grinding media and its relationship to the end product has been investigated and these results will be reviewed. The cost effectiveness of slugs versus balls has been well documented under various operating conditions and this will be presented in detail. IntroductionThe selection of grinding media is based on the cost-to-wear ratio combined with the consideration that it must stand repeated impacts without breaking. The specific consumption of grinding balls and slugs depend s primarily on their microstructure, which, in turn, is controlled by chemical composition and by the processing condition s to which they are subjected during manufacture.The first part of the paper deals with the optimization of alloy content to produce cast iron slugs with microstructures consisting essentially of marten site and carbide and with hardnesses of 650 B.H.N. and higher. The second part deals with the use of cast iron slugs to replace forged steel balls in milling operations. Tests indicate that the shape of the media has little if any effect on results and that the hardness and microstructure of grinding media will determine its relative performance. Where price is equal under similar milling conditions, the cost effectiveness of cast iron slugs is superior to that of forged steel balls.In order to understand the role of alloying elements in cast irons, it is judicious to consider the microstructural changes which occur during solidification and subsequent cooling, particularly from above the eutectoid temperature. Solidification starts with the formation and growth of dendrites of austenite. As temperature decreases, an eutectic nucleates and grows between the primary austenite dendrites. Immediately after solidification, the structure consists of proeutectic austenite and of the eutectic of primary carbides and austenite. On cooling to room temperature, austenite can be retained or transformed to pearlite, bainite, martensite or mixtures thereof. It is necessary to prevent decomposition of austenite into pearlite by adjusting the alloy content. For best abrasion resistance, the microstructure at room temperature should consist essentially of martensite and carbide. These types of irons are known as ""martensitic irons "". Depending on the carbon content of the austenite and cooling rate, "" as-cast"" martensitic irons will contain different proportions of martensite and retained austenite. The more carbon in solution in the austenite, the lower is the temperature at which the martensitic transfoemation takes place. By the time room temperature is reached ., the transformation is seldom complete, and the end product is generally a mixture of martensite and retained austenite."

Jan 1, 1980

By Z. Farhat

In spite of advances in cutting tool technology, the understanding of the basic wear behavior and failure mechanisms needs further study. Tool wear is the main factor contributing to geometrical error and thermal damage in machined components. Manifested as a reduction in tool life, it also affects the workpiece surface finish, increases cutting forces and induces residual stresses. Furthermore, the emergence of high and ultra-high speed machining processes necessitates the investigation of tool wear under these severe working conditions. Tungsten carbide-cobalt composite material has been used traditionally as wear resistant materials for many years. One main application of this material is in cutting tools. WC-Co tools consist of hard WC particles imbedded in a tough Co matrix, which functions as a binder phase. More recently, Cubic boron nitride (CBN) tool material have attracted special attention due to its high hardness and excellent wear resistance. Boron nitride in its cubic form is known to be the hardest material next only to diamond. In this paper microstructural and tribological properties of commercial grade WC-Co and CBN cutting tool materials are investigated under high speed cutting conditions. The CBN cutting tools were found to be superior to tungsten carbide (WC) tools. Four-fold increase in productivity and significant reduction in chipping and cratering was achieved for CBN as compared to WC. Wear mechanisms are proposed and are related to the observed wear characteristics in the cutting zone.

Jan 1, 2006

By Bordeaux Sciences Agro-INRA UMR 1065 SAVE, S. Piutti, E. Benizri, S. Lopez

Ultramafic soils display high concentrations of nickel (Ni) and a number of nutrient deficiencies (e.g. N, K, P). Ni-hyperaccumulator plants have evolved on such environments, developed specific metal homeostasis showing concentrations of Ni sometimes above 1% in their aerial biomass (Baker & Brooks 1989). Alyssum murale, a Ni-hyperaccumulator, is commonly found around the Mediterranean but can grow on non-ultramafic soils as well, with an altitudinal extension ranging from sea level to 2000 m.a.s.l. Rhizosphere bacterial communities associated with Ni-hyperaccumulator plants can differ from those of non-accumulating plants growing at the same site. Among edaphic factors that could influence the phylogenetic structure of the bacterial communities, altitude and metal-bioavailability and in particular nickel could be significant. However, most studies have focused on analyzing soils with techniques that provide little detail about the phylogenetic structure of these bacterial communities present in ultramafic soils. The objectives of this study were to understand the specific changes in the structure of A. murale rhizosphere bacterial community that occur across two gradients: 1°) elevation and 2°) Ni geochemistry, using pyrosequencing technique (454-pyrosequencing of 16S rRNA gene). It was found that the higher the soil chemically-available Ni contents, the higher the relative abundance of Proteobacteria and Actinobacteria. On the contrary, the abundance of TM7 decreased with increasing levels of available Ni. Moreover, Chloroflexi was present with 53 to 77% of relative abundance. These results demonstrate that soil chemically-available Ni drives the bacterial community diversity in the rhizosphere of Alyssum murale regardless the elevation gradient and other different soil physicochemical parameters. These results should now be confirmed in different ultramafic edaphic environments worldwide (e.g. ultramafic lateritic covers) and in the rhizosphere of different hyperaccumulator taxa.

Jan 1, 2016

By Hajime Miki, Gde Pandhe Wisnu Suyantara, Tsuyoshi Hirajima, A. M. Elmahdy, Keiko Sasaki

"Seawater has been reported to depress molybdenite in a copper-molybdenum (Cu-Mo) flotation process at high pH due to the precipitation of Mg(OH)2. Meanwhile, to improve mineral recoveries, collectors are usually added into the flotation cells, thus adding the complexity to the mechanism of bubble-particle interactions involved in Cu-Mo flotation. Therefore, understanding the interaction mechanism in seawater flotation and in the presence of collectors is important to explain the minerals depression. The present work investigated the effect of kerosene on the bubble collision and attachment to pure chalcopyrite and molybdenite surfaces in MgCl2 solution as one of the seawater major components at pH 6 and 11. Mineral surfaces were characterized using atomic force microscopy (AFM). In addition, minerals floatability in the same system were tested in a column flotation. The study of bubble-particle interactions shows that following several collisions, bubble could displace the intervening liquid layer on the mineral surfaces, forming a three-phase contact (TPC). A TPC formed more rapidly in the presence of emulsified kerosene in a 0.01 M MgCl2 solution at pH 6 for both minerals. The reason is kerosene increased the surfaces hydrophobicity and destabilized the intervening liquid layer on the surfaces. Moreover, the average time required to form a TPC was shorter on molybdenite surface. This can be attributed to the effect of adsorbed kerosene on molybdenite surface and molybdenite surface roughness.INTRODUCTIONIn froth flotation, bubbles are used to separate hydrophobic mineral particles from hydrophilic particles. In this process, bubble-particle interactions (i.e., collisions, attachment, and detachment) are crucial with regard to mineral recoveries. The effectiveness of froth flotation depends on the formation of stable aggregates between the hydrophobic particles and the bubbles, allowing the bubble to carry the particles to the froth layer. To form such aggregates, the bubbles and particles must collide, and the intervening liquid layer must be drained below the liquid layer critical thickness, forming a stable threephase contact (TPC) (Ralston & Dukhin, 1999). Particles detachment may take place if the particles still have sufficient kinetic energy and the TPC is not formed. Previous studies of bubble-particle interaction in electrolyte solutions have been conducted using atomic force microscopy (AFM) (Assemi, Nguyen, & Miller, 2008), and by approaching the bubble using mica plate (Pushkarova & Horn, 2008), however, these studies did not focus on the bubble-particle collisions. Bubble collisions and attachment to hydrophobic (Teflon) and hydrophilic (glass) surfaces in a a-terpineol solution have been investigated by Krasowka et al. (2003)."

Jan 1, 2016

By J. E. Danoczi

ABSTRACT A diamond processing plant is being designed for the Star–Orion South diamond project in central Saskatchewan. Key to the plant is diamond liberation, which occurs in the comminution section and is the process of breaking up kimberlite rock as gently as possible to minimize diamond damage, particularly in larger, high-value diamonds. Kimberlite from the crater area of a volcanic pipe is generally softer than kimberlite from the diatreme zone. Softer kimberlite, comprising the majority of Star– Orion South deposits, can be readily broken up using abrasion and attrition by autogenous grinding mills, the preferred comminution method for minimizing diamond damage.

Jan 1, 2013

By S. R. Noble, F. R. Harris, E. T. C. Spooner

"The Logtung deposit discovered in 1976, is an example of large tonnage (162 million tonnes), low grade (0.13% WO3 and 0.052% MoS;) W(scheelite)-Mo mineralization related to multiple felsic intrusions. Because mineralization is predominantly fracture-controlled (> 95 %) rather than disseminated, Log tung is not a skarn deposit. Metamorphism of the Logtung country rocks (interbedded calcareous shale and graphitic quartizite) to a series of competent reaction skarns (quartz-diopside-garnet calc-silicate, biotite quartzite and wollastonite-vesuvianite calc-silicate) clearly precedes W-Mo mineralization. Hence mineralization was related to permeability created by hydraulic fracturing and not replacement processes.Logtung shows a theme of several phases of mineralization (4) related to multiple intrusions (>2) which is similar to that of the Climax and Urad-Henderson Mo systems. The earliest quartzmolybdoscheelite vein system, which consists of a typical ""porphyrystyle"" crackle-breccia of thin (0.5 mm to 4 mm) quartz-garnetdiopside- molybdoscheelite veins, is related to a high Si02 (approx. 76%), seriate-porphyritic monzogranite stock (approx. 2 km by 0.5 to 1 km) of Cretaceous age (118 ±2 Ma [2u]; Stewart, 1983). Later quartz-pyrite scheelite (fluorite-KINa-feldspars-molybdenite) veins, with prominent green, hornblende-bearing alteration selvages, and quartz-molybdenite (-pyrite-jluorite-scheelite) veins are related to a quartz-feldspar-spessartine-rich garnet porphyritic felsic dike complex approximately 500 m across. Both intrusive phases have anomalously high Wand Mo concentrations of about 100 ppm and 50 ppm respectively, which Stewart (1983) attributes to a primary enrichment. The final stage of mineralization consists of a prominent 4.5 km by 1 km zone of 1 em to 1 m wide polymetallic sheeted veins centred on the felsic dike complex. The system is zoned from quartz scheelite-molybdenite-pyrite-blue-green beryl-jluoritebismuthinite veins in the core to Pb-Zn-Ag veins with abundant arsenopyrite and minor Sn (approx. 0.1%) in the northeast. The focus of recurrent intrusive and hydrothermal activity was located above a flank or nose of the monzogranite stock.The distribution of WO3 and MoS2 grades within the approximately 750 m (across) by 300m (evaluation depth) mineralized zone is a result of the variable superimposition of the four separate vein systems each with different W:Mo ratios. Well-defined Wand Mo ore, shells such as those at Climax, Henderson and Mt. Emmons did not develop at Logtung. The upper surface of the mineralized zone, as shown by the 0.03% MoS2 contour defines an elongate dome with an apical region approximately coincident with the felsic dike complex. Hydrothermal alteration occurs as well-defined vein selvages, and not as pervasive zones.The Logtung deposit shows many similarities to porphyry Mo deposits in the western Cordillera and may be identified as a porphyry W(scheelite)-Mo deposit, with a W:·Mo ratio of 3.3:1. The principal reasons are: (1) mineralization is spatially associated with porphyritic granitic intrusions and (2) much of the scheelite and molybdenite occurs in typical ""porphyry-style"" vein stockworks"

Jan 1, 1995

By Michael Farley, Paul Dufour

"Relationships, Partnerships,Marriages (RPM)RPM has a nice musical ring to it, but it is in fact synonymous with science and technology, university-government -corporate links and the more genera l issue of university roles in technology development. Pick up any report on one of these issues, and chances are that you will find one of these key words in the title. Play it, and you will find that the revolutions per minute are increasing. It is difficult to keep track of the wide variety of institutional experiments now developing in Canadian universities in attempts to marry science and research with technology commercialization and technology transfer.Why is the role of Canadian universities in this matter important? There are at least five good reasons:1. It is important because these knowledge institutions are producer s of scientific research, a major component of technology. Today the gap between the two is rapidly shrinking.2. It ' is important because Canadian industry is turning to universities for tech no logy development and new knowledge. Figure 1 shows that universities are becoming an important source of technology available to Canadian firm s; more important in fact than government. Figure 2 illustrates this trend more graphically in showing that university collaboration is one of the preferred methods of industry participating in co-operative R&D efforts:3. The role of Canadian universities in technology development is also important because the provincial and federal governments have embarked on various programs and policies for promoting the use of technology and science for economic benefit. Universities are playing an increasing role here. For example, the submission of IDEA Corporation (a venture capital operation funded by the government) in Ontario to the Bovey Commission on the Future Development of Ontario Universities clearly spelled out its ideas for commercialization of university research in Ontario . Among other things, the brief suggested that Ontario's universities need to be better equipped to transfer technology, and the reward structure in university research must incorporate industrial interests."

Jan 1, 1986

By R. F. Neider, W. R. Bain

"Expanding upon one aspect of a recent paper on ""Fluid Column Roasting at Sherbrooke Metallurgical Co. Ltd.,"" the present paper deals with the operation of the fluid column process to achieve substantial elimination of cadmium and lead during the roasting of pelletized zinc concentrates. Designed to meet the need for additional feed for Matthiessen and Regeler Zinc Company's vertical retort zinc smelter in West Virginia, without recourse to a sintering operation, the plant is capable of simultaneously attaining very low lead and cadmium levels on demand, through operation in the manner described. Fluidizing air admitted via the wind box is supplemented by natural gas admitted via a tuyere bank 15 ins. above the hearth, in quantities adjusted to maintain a reducing atmosphere within the interstices of the bed. In addition, careful attention is paid to bed temperatures, which run from 1,080° to 1,100°C. Under these reducing conditions, 90 per cent of the cadmium and 92 per cent of the lead in the feed are eliminated, the sulphate sulphur content is decreased by 0.5 per cent, sulphide sulphur is held at 0.6 to 0.08 per cent, and the zinc content correspondingly in-creases. The fuel value of the natural gas is recovered as extra steam, which carries a credit. There are some added difficulties with fume accretions, gas conditioning and gas -cleaning, some of which have yet to be overcome."

Jan 1, 1967

By B. Kruger

The Dundee Precious Metals Tsumeb Smelter has evolved over the last decade to meet the challenges and opportunities brought about by a changing copper concentrate market, technological advances, environmental legislation as well as social and political changes. The paper discusses some of the challenges, successes and lessons learnt through the expansion and modernization of its smelter complex. It considers the details and impact of the transition from slag granulation to that of slag slow cooling as well as the improvement program that was implemented to more than double the refractory campaign life of the Ausmelt furnace from around 6–9 months to 15–18 months. In addition, given the evolving world we live in, it considers the challenges that the smelter faces today, not the least of it being how to remain relevant in an age of digital and other 4th Industrial Revolution disruptions. INTRODUCTION Dundee Precious Metals Tsumeb (DPMT) Smelter is located just outside the town of Tsumeb, in the Oshikoto region of Namibia. It is the largest town in the region with a population of approximately 45,000. The smelter was built in the early 1960s to treat concentrate from the nearby Tsumeb copper mines. Construction of the site was completed in 1962 and the smelter was officially commissioned in 1963 by Tsumeb Corporation Limited (TCL). At the time the smelter consisted of a lead section (including a refinery), a copper section and plants that produced cadmium, sodium antimonite and arsenic trioxide. Production commenced in early 1964, with 3,500 tonnes of copper and 6,000 tonnes of lead being produced per month. TCL was acquired by Gold Fields South Africa in 1988, and a few years later the lead section was shut down due to reduced lead content of the mined ore. In mid-1996, all mining and smelting operations were halted due to labour strikes. Ongopolo Mining and Processing Limited (OMPL) re-opened the mines and the smelter in 2000, only operating the copper section of the smelter. At the end of 2008, all mining operations were halted by the new owner of OMPL, Weatherly Mining International, while the smelter continued to operate. The closure of the Weatherly owned mines in Namibia, the primary feed source to the Tsumeb Smelter, meant that the smelter had to transition its business model from operating as a ‘captive smelter’ to that of a ‘toll smelter’. Its Ausmelt Top Submerged Lance (TSL) smelting technology and various ancillary plants made it especially suitable for accepting and treating complex concentrates that were available on the global market.

Jan 1, 2019

By S. Lun Sin

In this study, the effect of silicon on the microstructure, mechanical properties and hot tearing susceptibility of permanent mould cast AZ91E magnesium alloy was investigated. Varying amounts of silicon (0.5, 1.0 and 1.5 wt.%) were added to AZ91E in the form of an Al-53 wt.% Si master alloy. The phase formation, grain size and solidification behavior of each alloy were characterized and related to their tensile properties and hot tearing susceptibility. The results showed that the addition of silicon resulted in the formation of Mg2Si particles. The presence of these particles led to an increase of the hardness, but was detrimental to the tensile strength and elongation of AZ91E. However, silicon significantly reduced the hot tearing susceptibility of AZ91E. This was attributed to the reduction of the grain size and the decreased freezing range of AZ91E, which contributed to improve the interdendritic feeding during the last stage of solidification.

Jan 1, 2011

By William Petruk, J. R. Schnarr

The behaviour of minerals during flotation of a fine-grained pyrite-rich base metal ore was investigated by studying the feeds. concentrate and tailings from every flotation cell in the mill of Brunswick Mining and Smelting Corp. Ltd. Bathurst. New Brunswick. The samples were analyzed for Zn, Pb, Cu. Fe, Ag. Sb, Sn, Bi, In. Hg, Mo and As. Mass balances were computed and recoveries of all metals from each cell. from each circuit and from the mill were calculated. The percentages of sphalerite. galena and chalcopyrite occurring as free grains in each product were determined with an image analyser, as were size analyses for free mineral grains and middling particles, and compared with screen analyses. The results show that the behaviour of minerals is defined much better by the recovery of free mineral grains than by the recovery of elements. The recovery of free sphalerite in the zinc circuit is 96 wt %, whereas Zn recovery from the same circuit is 88 wt %. the difference being due to unliberated sphalerite. The recovery of free sphalerite from the mill feed is 88 wt % and Zn 78 wt %. The recovery of free galenafrom the mill feed is 88 wt % and Pb 64 wt %. The recovery of free chalcopyrite is 75 wt % and Cu 45 wt %. Size analyses show that more sphalerite and chalcopyrite can be liberated by regrinding. but the galena is so fine grained that regrinding would not necessarily improve liberation. Silver occurs mainly in tetrahedrite and galena; the main loss in the tailings is due to large (+ 26 um) and small (-1 um} free and unliberated tetrahedrite grains.

Jan 1, 1981

RISKGATE is an interactive online risk management system developed by the Minerals Industry Safety and Health Centre (MISHC; University of Queensland) to assist the mining industry in implementing continual improvement in management of major unwanted events so maximising health and safety performance. A comprehensive body of knowledge has been compiled from diverse mining industry experts for risk management of tyres, collisions, fires, isolation, strata underground, ground control open cut, explosions, explosives, manual tasks and slips/trips/falls. This paper presents an overview of the RISKGATE body of knowledge captured specifically for the management of unwanted events that stem from the handling and use of explosives (drill and blast) within surface coal mining operations. The knowledge presented is divided into a series of initiating events (listed below) within which there are further degrees of classification based on design, operation, and management concerns. Initiating events: ? Loss of control of explosives and associated chemicals in storage on site ? Loss of control of explosives and associated chemicals during transport ? Loss of control of explosives and associated chemicals during manufacture ? Loss of control of explosives and associated chemicals during handling and blast operations ? Loss of control of explosives and associated chemicals during disposal The system guides the user in generating substantive and leading-edge controls to assist in the design, management and reporting of drill and blast operations to meet stringent internal and external requirements. From a broader industry perspective, RISKGATE provides an environment for knowledge capture and knowledge exchange to drive innovation and best practice in the identification, assessment and management of risk. By capturing operational knowledge from industry experts, RISKGATE provides a cumulative corporate memory at a time of high personnel turnover in the coal industry.

Aug 1, 2013

By Norman R. Ball

"Many people in the mining and metallurgical industries were brought up to embrace Henry Ford's pronouncement that ""History is bunk"" but it is not generally known that the same Henry Ford created and paid for one of the finest technological museums in the Western World. I am aware that many people feel that industry history is something you ask aging executives to do or that history is a clip-andpaste compendium of pictures re-discovered every 25 years or on the occasion of issuing a press release on plant expansion. Moreover, there are many who fear historians as somewhat deranged individuals interested only in corruption, injustice and sensational labour strife. Good history lies somewhere between the controlled P.R. handout and the hysterical attack. Writing good history is a difficult creative act based on the application of experience, insight, wide knowledge and careful reasoning to available evidence. To date, the Canadian mining and metallurgical industries have achieved a great deal but left too little evidence and it is this lack of evidence which must be corrected before it is too late. It is the purpose of this article to stimulate thoughts with regard to archives, one of the more important vehicles for the preservation of such evidence."

Jan 1, 1999

By K. M. Wild, C. D. Martin, F. Amann

"Argillaceous rock formations, in particular clay shales, are notorious for creating challenges in rock engineering. Due to their generally low hydraulic conductivity and their complete saturation in their natural state at depth, the behavior of clay shales is usually characterized by a strong hydro-mechanical coupling.This paper presents typical pore pressure responses monitored in different underground rock laboratories and explores alternative ways for their interpretation. The underpinning processes and their relevance are identified based on analytical and conceptual numerical models. Pore pressure monitoring data from Opalinus clay at the Mont Terri Underground laboratory, the Boom Clay at the Mol facility and the Callovo-Oxfordian clay in the Meuse/Haute–Marne URL show a similar pore-pressure response associated with stress changes accompanying tunnel construction although the tunnels were built in different rock types, at different locations, and under different in-situ conditions.The numerical analyses in this study shows that the pore pressure response around an excavation in low permeable clay shales may have different explanations. Pore pressure drops observed in the tunnel near field can theoretically be explained by both, a pure elastic response in an isotropic or anisotropic rock mass with an anisotropic stress state, or a inelastic response and related dilatancy. However, a comparison between the numerical models and the in-situ measurements revealed that the latter is more likely. This conclusion is justified by the observation that pore pressure drops occur significantly ahead of the tunnel face which is not the case in elastic numerical simulations. Pore pressure measurements in the far field, where failure processes are unlikely to occur, can only partly be explained by a linear poroelastic models. The introduction of an anisotropic material plays a key role in reproducing the responses, conceptually."

Jan 1, 2015

By S. Hussien, P. Somasundaran, P. Patra

"Rare earth elements (REEs) are essential for many applications in electronics, energy harvesting, and defense. The common resources for economic extraction of REEs are oxides such as bastnaesite and monazite, which are scarcely available in the earth’s crust. On the other hand, REEs are available in many clay and phosphate ores where REEs substitute Ca or Si in the mineral lattices or as physically adsorbed cations at negatively charged sites on the clay surface. While REE oxides readily dissolve in acid, making the chemical leaching of REEs an economically viable option, adopting a similar approach for leaching of silicates and phosphate ores is unfeasible because of significantly low REEs content in these ore deposits. Bio-leaching approaches are environmentally benign and economically viable. We investigated the bio-leaching (Acidothiobacillus ferrooxidans (Af) and the fungal Aspergillus niger (An)) of REEs from a phosphate ore, and examined the factors governing the leaching processes. Based on the shake flask leaching studies, an increase in surface area combined with an increase in pulp density (1-15 wt. %) was found to lead to an increase in the amount of REEs leached. In contrast, an increase in the surface area by reducing the particle size from 75 to 35 led to a decrease in the amount of REEs leached. These differing attributes are proposed to be due to the poor bacterial growth/activity with high F- ions in the leaching media, F- released from the edge-sites of the smaller particles. On the other hand, several advantages that associate with the Af bacterial bio-leaching processes relate to the media composition (Mg2+ and (NH4)+) and phenomena occurring at the electrical double layers of the mineral and bacterial- water interfaces. These studies suggested that leaching of particles occur in a layer-by-layer manner.INTRODUCTIONRare Earth Elements (REEs) are essential for many important applications, such as in electronics, energy generation, and defense. The common resources for economic extraction of REEs are typically carbonates such as bastnaesite and monazite, which are scarcely available in the earth’s crust (Y. Kanazawa and M. Kamitani, 2006). REEs are abundantly available in many clay and phosphate ores where REEs substitute Ca or Si of the mineral lattices. Conventional acid leaching of REEs from oxides is not economically feasible for clay and phosphate ores because of significantly low REE content (parts per billion) in these ores (Tian, J., Chi, R., Yin, J., 2010a; Moldoveanu G. A. and Papangelakis V. G., 2013; WK Goyne, LS Brantley and J Chorover, 2010). In some cases, REEs could be extracted from these ores via chemical leaching routes as they constitute reasonable amounts of REEs (0.1 - 1% REEs). A major challenge faced in general in chemical leaching processes (Chi, R., 1988) is the loss of REEs in the phosphate/gypsum precipitates/crystals, which are overcome in a step-by-step manner by sequentially removing impurities such as fluorine and calcium, including steps carried out at elevated temperatures. On the other hand, bio-leaching approaches provide environmentally benign and economical alternatives. Acidophilic bacteria are currently being used for industrial scale bio-leaching of Au/Cu/Ni from low grade ores. Studies on bioleaching of REEs from red mud (Al2O3) using Penicillium tricolor and Aspergilus niger (An), and, of bio-leaching (lab-scale) of phosphate rocks using Acidithiobacillus ferrooxidans (Af) have been reported (Boon, M., Heijnen, J.J., 1993; Qu, Y. and Lian, B., 2013). We conducted bacterial (Af) bio-leaching of REEs from a phosphate ore in shake flasks and columns, while examining the key factors that govern leaching kinetics."

Jan 1, 2016

By C. E. White

History The Con-Rycon mine is situated in the Yellowknife mining district, North West Territories, 608 air miles north of Edmonton, Alberta. The earliest reported discovery of gold in the area was made in 1898 but no extensive exploration occurred until 1928. The birth of Yellowknife as a mining community took place in 1934 with the staking of the Rich group and subsequent shipping of 16 tons of high grade ore. The Giant group was also among the claims staked in 1934, and later staking showed a tendency to close the gap between these two properties. In the fall of 1935, the A.Y.E. claims, situated south of the Giant group, were staked to cover a discovery of the Geological Survey of Canada and, after general release of the Survey's information, the adjoining ground was staked. These claims included the Con, Negus, Meg, and Kam groups. In 1936 four lapsed claims were re-staked as the P and G group and later acquired by Rycon Mines, Limited, controlled by the Consolidated Mining and Smelting Company of Canada, Limited. The Con and various adjacent groups owned by Cominco are now operated with the Rycon under one management. Surface trenching on the Con property started in 1936 and, during the fall and winter of 1936-37, a 60- foot 5 ft. by 9 ft. inclined prospect shaft was sunk. The encouragement provided by the shaft and diamond drilling in 1937 led to the decision to establish a mining plant, and in August, 1938, the 100-ton cyanide mill produced its first brick- the first gold brick poured in the history of the North West Territories. In November, 1938, the mill was enlarged to a 175-ton capacity and operated at this rate until 1941, when refractory ore was encountered. This situation was met by the installation of flotation and roasting units and, at the same time, the milling capacity was increased to 300 tons daily. Labour shortages and Government restrictions forced a reduction of output and in 1943 milling was suspended while mine development continued on a reduced scale throughout the war years. The present full-scale of operations was resumed in 1946 and the total production to the end of 1948 amounted to 288,853 oz. gold and 72,347 oz. silver.

Jan 1, 1949

By Golaleh Riahi

An original method is used to obtain stable nanoparticles of gold-based mono- and bimetallic systems supported on an acidic zeolite. This approach has been applied to PtHY (1wt% Pt) and to bimetallic Pt-AuHY containing 1% of platinum to which is added the amount of gold required to give Au/Pt molar ratios of 20,40,60 and 80%. Metal clusters of Au or Pt-AuHY are formed inside the supercages of the zeolite framework by the thermal reduction of cations by the ligands (en = H2N-CH2-CH2-NH2) under inert gas flow at a temperature depending on the metal. The use of acidic zeolites favours the dispersion of the metal and the thermal stability of the particles. This stability is explained by chemical anchoring of metal clusters by the Brønsted sites of the support. Several techniques have proved that for a molar ratio of 20% metal particles of Pt-AuHY are bimetallic. The segregation of Pt and Au starts for molar ratio =?40%. The catalysts tested on the methylcyclopentane hydroconversion reaction reveal that the addition of gold to platinum leads to an increase in the activity and an improvement in the selectivity for isomerization of the skeleton (cyclohexane and benzene) to the detriment of hydrogenolysis. Similar results were obtained for the dodecane isomerisation to isododecane. These catalysts were also tested in CO, propene and propane oxidation. The activity of fresh catalysts is rather low. It increases after their pretreatment in oxygen or hydrogen atmosphere. In propene oxidation in the reaction mixture O2 ? H2, beside total oxidation of propene to CO2, also propene hydrogenation was observed, particularly at low temperatures. The presence of Au enhances the hydrogenation properties: high selectivities (> 90%) to propane and high propane yields on PtAu HY are observed up to ~150oC, whereas for Pt HY catalyst the selectivity and yield to C3H8 decreases rapidly with the temperature beginning from ~100oC.

Oct 1, 2003