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By A. Eslami

When producing high grade mattes in smelter plants, copper losses in the slag are inevitable. Hence, the recovery of copper from slag has been the focus of many research projects, copper flotation being a widely used process. In the Khatoonabad converter, 200 t/d of slag are presently produced with a grade of 2.3% Cu. Assuming a 85% recovery by flotation, about 3.9 t/d copper could be produced, which is of prime importance economically. In the present work, a sample of this slag was crushed and ground in the laboratory to liberate the copper-bearing minerals. Following mineralogical studies, optimum laboratory flotation parameters were obtained, resulting in 90.27 % recovery and 9.42% of copper grade for the rougher stage. At pilot scale, a pulp of 28% solids was floated at ph 10.5 using 40 git of Z6, 25 git of R407 and 20 git of MIBC and A65. A recovery of 83.52% was obtained for a concentrate grade of 28.36% Cu. In the rougher cells, the feed consisted of particles 94% finer than 74 microns whereas in the cleaning stage, particles were 95% finer than 44 microns. Based on the obtained results, the Sarcheshmeh Khatoonabad converter slag is presently being fed to the Chargonbad flotation plant, where a concentrate of 32% copper at 86% recovery is being produced.

Jan 1, 2007

By J-F. Turgeon, Y. Pépin, G. Hudon

The high temperature hydrochloric acid leaching of titanium slag in the QIT upgraded slag process (UGS) creates a harsh environment for materials of construction. Because of their excellent chemical and heat resistance, furan mortars are a key component in the lining system of the UGS pressure leach reactors. Similar products coming from different manufacturers have however shown unequal performances in service. In some cases, cracking of the brick lining has occurred during curing of the mortar. This study was initiated to investigate the impact of the curing conditions on the properties of carbon filled furan mortars. Laboratory tests were conducted to assess the effects of temperature and exposure to water and HCl solutions on mortar shrinkage and mechanical properties (tensile, compressive and bond strength). Three commercial furan mortars that have been used in the UGS leach reactors were thus characterized. Mortar properties were found to vary significantly among the products tested. Moreover, the curing conditions were shown to have a significant impact on mortar shrinkage and mechanical strength. The experimental findings provide explanations for the unequal performances of the mortars in service and for the problems of brick lining cracking that occurred in the UGS leach reactors. This study demonstrates that excessive mortar shrinkage compromises the integrity of a brick lining system.

Jan 1, 2004

By R. G. Helberg, S. M. Rebelo

"Copper and cadmium are removed from the zinc sulphate solution in primary purification by cementation reaction followed by filtration. The solids are sent to the cake leach section where zinc and cadmium are recovered from the copper rich slurry. The copper solids from cake leach are filtered, bagged and sold. In order to achieve a lower cadmium copper cake, an altered process flow is suggested. It is proposed the primary purification be split into two steps for individual removal of copper and cadmium. INTRODUCTIONCopper cake is a product of primary purification, also known as copper and cadmium removal. Copper and cadmium are removed by cementation reaction in four stirred reaction tanks. The slurry is then filtered through Shriver manual plate and frame presses with the solution advancing to the next stage of purification, hot zinc purification (HZP). The solids from primary purification are further processed at the cake leach section where zinc and cadmium are separated from the copper rich slurry. Cadmium and zinc are dissolved in the cold cake leach tanks using spent electrolyte. Cadmium is recovered from this cadmium rich solution by cadmium sponging, leaching and electro-winning circuits. The residue from this cold leach step is further leached using spent electrolyte at a temperature of 85°C. The copper rich solids from hot cake leach are filtered on a drum filter and bagged in 1 ton bulk bags for shipping to buyers.Current assays of copper cake are shown in Table 1. The goal is to produce a copper cake product that is below 0.5% cadmium."

Jan 1, 2012

By P. K. Kaiser, S. M. Maloney, S. P. Singh

"Corrosion of underground support measures constitutes a concern to industry in both safety and economic terms. It also represents a potential market for corrosion resistant materials such as stainless steel.In order to assess the market potential for a stainless steel friction rock bolt, a review of current corrosion processes and remedial or preventative measures in the underground environment was undertaken. This was supplemented by distribution to industry of a detailed questionnaire, concerning the magnitude and extent of support corrosion and the costs of current support measures, and by visits to selected sites. Following data synthesis, support costs were established and the economic benefit of stainless steel rock bolts evaluated.Stainless steel rock bolts can be an effective cost reducing measure in unscreened areas requiring frequent reconditioning. Their benefit is rapidly diminished, however, if only partial reconditioning is required, the reconditioning interval is long or if screening is required.While most industry personnel are receptive to the application of stainless steel support measures, the localization of corrosion problems and the potential high cost of this type of support are barriers to its widespread implementation. They have potential for use in extreme environments. However, this relatively small market may not be economically viable.IntroductionFriction rock bolts are the simplest of all interior rock fixtures. The friction resistance to sliding of the rock on the bolt is generated by a radial pressure against the borehole wall over the length of the bolt. Two types of friction rock bolts are currently marketed, the Split Set and the Swellex.Unlike conventional point anchor bolts, friction rock stabilizers may move relative to the rock strata and maintain their capacity even if rock shifts, a condition that sometimes loosens or breaks conventional bolts. Ease of installation, effectiveness in jointed as well as weaker rock, and the possibility of having relatively long bolts are a few of the many advantages which generate considerable interest in the application of friction rock bolts (Wijk and Skogberg, 1982). However, due to their thin-walled construction and large surface area, frictional rock stabilizers are more susceptible than conventional bolts to damage by corrosion. For this reason, they are normally not recommended for long-term use (Jolly and Neumeier, 1987).In light of the above discussion; the Nickel Development Institute commissioned a study by the Geomechanics Research Centre with the objective of generating a credible database for the assessment of the feasibility of a stainless steel friction bolt system in corrosive ground and mine environments."

Jan 1, 1990

By M. B. McClenaghan

"The Matheson area of northeastern Ontario is of great interest for mineral exploration because of its geological similarities with the adjacent Timmins, Kirkland Lake and Larder Lake gold camps. Exploration in the area, however, is hampered by the presence of an extensive and thick cover of glacial sediments. For this reason, till geochemistry has become an important exploration method. The Ontario Geological Survey&apos;s Black River-Matheson (BRiM) reconnaissance till sampling project, carried out between 1984 and 1988, was designed to aid exploration in the Matheson area by documenting the Quaternary stratigraphy and providing a database of till geochemistry. Till samples were collected by backhoe trenching of surface pits in areas of thin drift (< 5 m) and by sonic overburden drilling in areas of thicker drift. This paper summarizes the results from the shallow till sampling component of the BRiM project.Two hundred and eighty-two surface samples were collected from Matheson Till, the youngest till sheet in the area, which was deposited during the Late Wisconsinan. For each sample, the non-magnetic heavy mineral (> 3.3 S.G.) and fine (- 250 mesh) till fractions were analyzed geochemically. In addition, visible gold grains were recovered by panning the heavy mineral fraction. Five areas that display multi-element anomalies in both till fractions warrant further investigation: (1) western Egan Township, overlying the Bradley Lake Syenite; (2) around and south of the Munro and Croesus mines, in Munro and Guibord townships; (3) central Garrison Township overlying the Garrison Stock; (4) south of Ore Car Lake in northern Thackeray Township; and (5) southeastern Harker Township. In these areas, Matheson Till has a local provenance and the bedrock sources for these anomalies are nearby in the up-ice (north northwest) direction. Due to the fine-grained nature of gold in bedrock deposits in the BRiM area, the small size of most gold grains recovered from till samples (< 50 um) and the variable distribution of gold in the heavy mineral concentrate and fine fractions, the fine fraction in addition to the more commonly used heavy mineral concentrate should be used for gold exploration.Surface till samples have been affected by weathering to a depth of = 3 m. Weathered till is characterized by a very low carbonate content in the matrix fraction, the absence of sulfide grains in the heavy mineral concentrate and higher concentrations of copper, nickel and zinc in the fine fraction than in the heavy mineral concentrate. As a result of the weathered/ oxidized nature of the surface till samples, the fine fraction is a better sampling medium for base metal exploration."

Jan 1, 1992

By M. I. Abbas, M. A. Shahin, M. S. Ahmed

"The influence of annealing of galvanized steel (galvannealing) on its corrosion kinetics in a saturated solution of Ca (OH)2 has been studied by means of the polarization resistance method.Galvannealing heat treatment was carried out at 450°C and 550°C for varying times. Annealing at 450°C for 24 hr or at 550°C for 5 hr showed the highest corrosion potential (Ecorr) ~= - 400 m V/ SCE as well as, the lowest corrosion current density (icorr ~= 3 mA.cm-2, while Ecorr and icorr of the unheated specimens were ~= - 1400m V/SCE and == 20 mA.cm-2, respectively.Polarization curves were also obtained for the as-received galvanized specimens together with the galvannealed ones.INTRODUCTIONHeat treatment of galvanized steel (i.e . galvannealing) is carried out at a temperature range of 450°C to 550°C for a time sufficient to convert the free zinc coating to an alloyed one consisting of layers of iron-zinc intermetallic compounds. Table I is a review of the properties of the Fe-Zn intermetallicphases while Figure I is a reproduction - of the Fe-Zn equilibrium phase diagram taken from Hansen.Several authors have studied the formation of intermetallic phases through the interdiffusion of Zn/Fe couples. Their results confirmed the stability of intermetallic phases that could be shown up on the outer surface as a result of galvannealing of galvanized steel.Bernick and Sievertv"" investigated the processing of galvan nealed steel. They found that the galvannealed coating with the best forming qualities consisted of a mixture of Zeta phase and Eta phase."

Jan 1, 1989

By D. Shishin

Continuous integrated experimental and thermodynamic modelling work is conducted in Pyrometallurgy Innovation Center (PYROSEARCH). The target is to develop a tool, which is capable to predict the compositions of phases, phase equilibria and enthalpy balance for pyrometallugical processes with higher accuracy. All these can be achieved by thermodynamic calculations based on Gibbs energy minimization algorithm. Recent developments made it possible to predict important factors, such as the chemical solubility of Cu in slag as a function of matte grade, temperature, P(SO2), Fe/SiO2 ratio in slag, wt% Al2O3, CaO and MgO in slag. In industrial practice, it is not only chemical solubility, but the overall amount of slag, which affects the recovery of copper and other valuable metals. It will also impact the energy balance. The presence of solids in the slag matrix influences the physical entrainment of matte in slag. Oxygen enrichment which is sometimes used to control the temperature of the furnace, may also affect the volatilization of minor elements into the gas phase. Same is true if additional fuel is used to compensate for heat balance. In other words, all key process parameters mentioned above are interrelated. Present study demonstrates the ways thermodynamic modelling can be used to link those process parameters on the example of copper smelting. INTRODUCTION Research methodology involving integrated thermodynamic modelling and experimental approach has been recently reported by the authors (Shishin, Hayes, & Jak, 2018 Shishin, Hidayat, Jak, Decterov, & Belov, 2016). Present paper reviews the updates and discusses challenges in the development of a large self- consistent thermodynamic database. The database covers the Al-Ca-Cu-Fe-Mg-O-Pb-S-Si-Zn-(Ag, As, Au, Bi, Ni, Sb, Sn) chemical system. The database works in the environment of FactSage software Bale et al., 2016 and related family of products: ChemApp (Petersen & Hack, 2007), ChemSheet and SimuSage. A list of phases, and thermodynamic models is shown in Table 1. For the copper industry, most important phases are Gas, Slag, Spinel and Liquid matte/metal/speiss. Black-colored elements represent the base system, elements in green can be considered as slag modifiers (slagging elements), and elements in red are minor. Ni is highlighted because it was included recently, in 2019, and currently under development. In addition to copper, the database covers the conditions typical for lead and zinc pyrometallurgical extraction. It is developed in consistency with the experimental results for high concentrations of Pb and Zn. Examples of applications in the present study include the thermodynamic analysis of fluxing for an agitated copper reactor to show the effect of Fe/SiO2, and calculations of copper slag cleaning using reductant.

Jan 1, 2019

By Graham Sim

Agenda ?The Water Challenge ?Examples from Three Case Studies ?Mine Drainage, 99% recovery ?Mine Drainage, 80% recovery ?Road Dust Control ?Technology Development ? Conclusion Global water challenges Assuring sustainable quantity Improving water quality Reducing energy consumption

May 1, 2011

By E. A. Sobering

Hydraulic filling or sand filling is a system used to fill underground excavations with a dense pulp. Milltailings are commonly used. The resultant fill, after being placed and de-watered, is known as hydraulic fill. These fills have been effectively used to (a) provide immediate support of the workings place during stoping; (b) .facilitate the recovery of pillars; (c) limit surface damage by subsidence; (d) permit the mining of parallel hanging-wall orebodies; (e) stabilize the ground in mines, thereby reducing the rock burst hazard; (f) control and prevent mine fires; and (g) solve tailings disposal .problems. The various uses of hydraulic filling have been developed during the last ninety years. In 1864 it was employed only to control surface subsidence. Since then, this system has been successfully applied to meet specific ground support problems. Methods of handling mine-fill derived from a source outside the stope include transportation ?Of the material by hand, mechanical, pneumatic, and hydraulic means, or a combination of these methods. The hydraulic method has many advantages not found in the others; a significant advantage is the low compressibility of the material when compared to other mine-fill material. The hydraulic filling operation includes the .preparation and transportation of the pulp. The underground practices in .placing the fill vary from mine to mine. The chief reason, formerly, for using hydraulic fill was the exceptional support it provided, but recently it has proven an important means of reducing mining costs. This is especially true where labour is a large part of an alternative method, or where timber consumption is greatly reduced. The indirect benefits of hydraulic filling are probably as important as the direct benefits, and few important disadvantages exist.

Jan 1, 1956

The New Zealand opportunity NZ?s only significant phosphate deposit 1 million tonnes imported annually - mostly from Morocco US $180/t + $75/t freight

May 1, 2013

By S. Y. Ezz, K. El•Guindi

A vertical tube, 8 m long and 2.5 cm in diameter, electrically heated to 650°C throughout the majority of its height, was used to study the-effect of ore feed rate and hydrogen flow rate on the reduction of fine iron ore particles. A correlation could be obtained between the combined effect of the amount of reducing gas and reduction time and the per-cent reduction. The results suggest that a method based on the reduction of fine iron ores while falling through up-streaming hydrogen cannot be recommended for industrial application.

Jan 1, 1969

By Denis Blackburn

La Direction générale du développement de l?Industrie minérale (DGDIM) du ministère des Ressources naturelles et de la Faune (MRNF) du Québec tient un inventaire de toute l?activité minière sur le territoire. Cet inventaire s?est enrichi, au cours des dernières années, d?un grand nombre de projets dédiés au fer ou à des substances qui y sont associées (titane, vanadium, phosphate). Actuellement, cinq régions du Québec sont principalement touchées par la recrudescence de projets dédiés au fer : Fermont, Schefferville, Baie d?Ungava, Baie-James et Chibougamau. Fermont et Schefferville sont les régions les plus actives. Les infrastructures en place, telles que les routes, les chemins de fer, les ports, les lignes électriques et les municipalités, ont atteint, dans certains cas, leur capacité et de nouvelles infrastructures devront être construites pour satisfaire les besoins. À la Baie-James et sur le flanc ouest de la Baie d?Ungava, des projets d?exploration sont aussi en cours. Le manque d?infrastructure pourrait peser lourd sur le développement de projets miniers dans ces régions. Enfin, dans le secteur Chibougamau/Matagami et à quelques sites ailleurs au Québec, des projets d?exploration qui visent le vanadium, le titane ou le phosphate pourraient aussi fournir comme produit secondaire des concentrés de fer. Tous les projets, décrits dans cet article, sont situés sur le territoire du Plan Nord du gouvernement du Québec.

May 1, 2011

By Andrew Dobson

The assessment and control of environmental noise from mines has become increasingly important in recent years, due to urbanization and population growth, increased regulation of environmental factors, and overall awareness and sensitivities to noise exposure.&nbsp;Minimizing adverse effects on communities and achieving compliance with local ordinances is now commonplace, and consideration of noise during the design and/or operation of a mine cannot be ignored. Ventilation equipment can represent the loudest and most bothersome equpiment at mines, however there are complexities when attempting to control the assocaited noise, due to the acoustical nature of&nbsp;mine vent fans. In fact, the utilization of traditional and/or&nbsp;industry standard methods can intensify&nbsp;the noise impact, or simply not work as intended. This paper provides recommendations on specific noise control methods that are suitable for mine ventilation equipment, based on recent assessment work and field experience.

Oct 1, 2024

By M. B. Dusseault, A. Pirayehgar

"There is concern that hydraulic fracturing (HF) near an existing critically stressed fault could trigger slip and generate a seismic event of significance. To this end, a mathematical discontinuum model representing a naturally fractured rock (NFR) mass containing a fault is created, and fault slip response to fluid injection is studied. UDECTM is used as a Discrete Element Method (DEM) approach to define the seismic moment, and also to assess the influence of injection and slip on further shear slip propagation. In most of the simulations, slip and dilation take place along a number of oriented fracture surfaces, so it is reasonable to assume that in a real case, microseimic emissions would accompany each slip “event”. The moment magnitude scale (Mw) is used to measure the size of the microseismic event in terms of the energy released. Seismic moment is a measure of the total energy (work) released during a seismic event and is used to measure its size. From another aspect, the injection energy is calculated as the total energy required for achieving the hydraulic fracturing; this is viewed as energy to open fractures against the ambient stress field and much of it is potential stored energy that can be released and create discontinuities (work of fracture), deformations (W=F·d), heat and radiated seismic energy. A small amount of the total released energy is transformed to radiated seismic energy and another small amount results in tensile fractures. Fracture energy is used to calculate the work required to create fracture surfaces. Comparing the energy release by fracturing or seismic events indicates their contribution to the total amount of released energy or total work. The amount of energy associated with the stick-slip event is small compared with the overall work done to generate the distortions (i.e. increases in aperture by forcing them open) in the rock mass, and much of the energy in slip is lost as heat from the plastic deformation, rather than as radiated seismic energy.Microseismic monitoring shows the spatial distribution and magnitude of seismicity associated with slip of bedding planes and natural and incipient fractures. Work calculations have been undertaken to look at the various sources of energy storage (elastic strain energy) or dissipation (slip), and likely the energy losses from viscous dissipation could be addressed as well, helping to clarify HF processes in NFRs."

Jan 1, 2015

By Karen Munro

Importance of Aquatic Studies for Mining ?Aquatic habitat is usually the first area where a mine interacts with the ?real world? outside the mine footprint ?Water management is a key consideration for a mine?Effects on the aquatic environment often extend to wildlife and human uses ?There is a lot of regulatory focus on issues of water quality, fish and fish habitat

May 1, 2011

By Kenta Kusunose, Dadang Sundana, Ahmad Munib Fikry, Yosuke Unno

PT Smelting has operated the Mitsubishi Process in which feed materials are charged into the S- furnace through top lances using a pneumatic conveying system comprising 6 feeding tanks (S-Feeding Tanks). Each S-Feeding Tank was designed as a batch machine and had been operated in a batch mode so that feed materials are conveyed 70% of the operating time (conveying time). An S-Feeding Tank was revamped in August 2016 in order to attempt to achieve 100% conveying time during operation, aiming to reduce the furnace draft fluctuations and melt temperature fluctuations leading to reduced copper losses to slag and refractory wear on the sidewall in the melt zone. After two-year operation with some adjustments and modifications, it was concluded that the new system works as expected. During scheduled major shutdown in November 2018, the same modification was applied to all other 5 feeding tanks as the first one, while several modifications other than the S-Feeding system were also conducted for the purpose of expanding the capacity of the smelter. INTRODUCTION PT. Smelting (PTS) Gresik Copper Smelter and Refinery is located 30 kilometers north of the city of Surabaya, East Java major port. PT Smelting equity partners are Mitsubishi Materials with 60.5%, PT. Freeport Indonesia with 25%, Mitsubishi Corporation RtM Japan Ltd. with 9.5% and JX Nippon Mining and Metals corporation with 5.0%. PTS was established in February 1996 and started commercial operation of the Mitsubishi Process in 1999. The Mitsubishi Process is a unique technology which connects 3 stationary furnaces, namely the Smelting furnace (S-furnace), Slag-Cleaning furnace (CL-furnace) and Converting furnace (C-furnace) by covered launders. These features result in savings in manpower and energy, and make the process more environmentally friendly since there is no ladle transfer of melt. Figure 1 illustrates the outline of the Mitsubishi Process.

Jan 1, 2019

By L. C. So, S. Faucher, S. Mostaghel, A. Triwahyuono, D. Sauter, S. -Y. Oh, S. K. Lee, K. Aswin

"Molten hauling and water granulation are the commonly used slag treatment methods in the production of nickel. Water is present in these processes either to accelerate cooling of the dumped slag or in the granulation itself which creates an inherent safety risk of explosions. Even good design and operation are not sufficient to prevent explosions or injuries from occurring. Several dry methods to treat slags have been intensely studied. However, most of these technologies have never been commercialized due to numerous challenges including scalability, cost, low heat recovery efficiencies, and difficulties in heat utilization. Ecomaister-Hatch has recently developed and commercialized a reliable and simple Dry Atomization process, which eliminates water and allows for heat recovery. As part of the development towards other sectors, laboratory-scale and pilot-scale trials have been completed in a number of base metals and PGM facilities. Recently, Dry Atomization of a nickel laterite slag was successfully demonstrated at the laboratory-scale. The current paper introduces the technology and reports the test results obtained from atomization of the nickel slag.INTRODUCTION The processing of nickel laterites produces vast amounts of slag with over 90% of the feed to the furnace reporting as slag. Slag handing is therefore of critical importance to a laterite smelter. Traditionally there are two ways in which the slag is handled (1) Molten hauling, dumping, cooling and quarrying (2) Water granulation, dewatering, stockpiling. There are inherent disadvantages of both methods that will be outlined in this paper. An alternate route of Dry Atomization provides distinct advantages over the two conventional routes that are of particular interest to the nickel producer such as elimination of molten hauling, dumping and quarrying, elimination of water and improved safety. There is also the potential to convert the slag, which is typically regarded as a waste product, into a value added product and the continuous nature of slag tapping makes it amenable to heat recovery. Hatch has recently conducted laboratory-scale test work on laterite slag to demonstrate its viability for Dry Atomization. Results of this work are presented."

Jan 1, 2017

By B. Voyzelle

The deterioration of highway and bridge infrastructure has received considerable attention in recent years because of the billions of dollars needed for repair and rehabilitation. A major factor contributing to this problem is the corrosion of steel reinforcement. Reinforcing steels with good corrosion resistance and relatively low price are therefore essential for maintenance, cost reduction and service-life extension of the steel-reinforced structures. This article describes the development of low-alloying steels that offers good corrosion resistance with reasonably low cost. Topics include steel microstructures, mechanical properties, corrosion performance, industrial applications and economic aspects.

Jan 1, 2005

By G. Swan

"The selection of material comprising a backfill is, of economic necessity, site dependent. Nevertheless, given the existing range of typical components-coarse waste, alluvial sand, tailings a balanced or optimal choice is no straightforward matter. A new design approach toward deciding what constitutes an optimum combination of backfill material promises to be useful. In particular a &apos;binder &apos; number, based on the mean distance between aggregate particles, specific surface and cement content, is proposed. Using this number, related empirically to compressive strength, the expected mechanical performance of any cemented fill can be predicted.IntroductionOver the years a considerable volume of information has accumulated on mine backfill material design. The principal aggregate component has been deslimed mill tailings, though more recently admixtures of rock waste, sand and tailings are quite common. For these materials uniaxial compressive strength and percolation rate properties are known to be controlled by, among other things, aggregate grading. While empirical formulae exist for relating grading to percolation rates, considerable uncertainty exists concerning strength development."

Jan 1, 1985

By F. T. Rabbitts

Introduction When the investigation of radioactive ores began at the Mines Branch about five years ago it was at once evident that improved chemical methods for the determination of uranium were essential. The published methods available were time-consuming and insensitive and were lacking in accuracy and precision. It was desirable to obtain methods which would be rapid, sensitive, and accurate. They should also allow for the possible presence of any interfering elements and should be adaptable to routine analysis by technicians. Chemical methods are necessary to provide standard analysed samples for counting and to check analyses by counter methods. Moreover, counter methods cannot be used, and only chemical methods are suitable, when the sample is not in equilibrium, as with weathered minerals and leach residues. As leaching processes are improved, more sensitive chemical methods are required for the increasingly lower content of uranium in the leached residues. When the leaching process reaches the plant stage, speed of analysis becomes more important, without sacrificing accuracy. The purpose of this paper is to describe briefly .the methods used at the Mines Branch for the chemical analysis of uranium in ores. These methods represent the results of investigations by a number of groups in the United Kingdom, the United States, and Canada.

Jan 1, 1952