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By Helen Shang, Jianjun He

In nickel and copper production, sulfur dioxide (SO2) is generated during mineral smelting. Emission of sulfur dioxide into the atmosphere causes serious health and environment issues. Sulfuric acid plants, which convert the harmful SO2 gas to commercially useful sulfuric acid product, ensures safe and environmentally sound smelter operations. The sulfuric acid plant is mainly composed of a SO2 to SO3 converter, a series of heat exchangers and SO3 absorption towers. The SO2 converter is crucial for minimizing SO2 emission in a smelter. In this paper, steady state and dynamic modelling are carried out for the converter using mole and energy conservations. Simulations are performed to investigate the effect of feed conditions on SO2 conversion. The developed model represents an important component for modelling the acid plant in a smelter and is expected to provide a fundamental tool for the future optimization and control development.

Jan 1, 2014

By Roy T. Bowles

This paper focusses on technological developments which occurred in the village of Deloro, Ontario between 1868 and 1919. These developments illustrate the manner in which improved metallurgical processes linked Ontario mineral resources to industrial expansion. Overview of Deloro The village of Deloro is in Hastings county, about 5 miles from the village of Marmora, the site of the old Marmora iron works and the more recent Marmoraton iron mine. In this area, the Canadian Shield meets the Great Lakes lowlands. The first settlement in the vicinity occurred in the 1820s and was associated with the Marmora iron works. Settlement grew around agriculture. Gold was discovered in Hastings county in 1868. Deloro - the name derives from gold - developed as a concentrated settlement in proximity to several gold mines and the related processing activities. By 1901, substantial smelting works were successfully producing gold and arsenic from local ores. The village was developing as a company town within the framework of benevolent paternalism. For reasons associated with markets and with local ore supplies, the Deloro mills were idle for a period beginning in 1902. Developments in later periods connected Deloro to world events. In 1903, silver was discovered at Cobalt, Ontario. By 1907, M.J. O'Brien, who owned mines at Cobalt, had purchased the Deloro works and was using them to process Cobalt-area ores*.

Jan 1, 1999

By Shila Jafari, Mari Lundström, Aleksei Kritskii, Pia Sinisalo

A typical process adopted at nickel plant is the processing of nickel-copper mattes and converter mattes using the following technology: pressure oxidative leaching (POX), solvent extraction (SX), electrowinning (EW), cobalt recovery, and solutions purification. As a result of multi-stage atmospheric and autoclave process leaching, copper-nickel separation is achieved. Cobalt and nickel are further separated by SX. Copper in the process can be removed as copper cake (Cu-cake), which is a by-product with high content of valuable metals. In the current paper, a method combining atmospheric and pressure leaching of Cu-cake in sulfuric-acid media is discussed. Suggested method allows to obtain high copper extraction (>98%), with leach residue containing precious metals and PGMs. Sulfuric acid media was chosen to make the suggested technology adaptable for the primary POX-SX-EW circuit. The initial Cu-cake was analysed and a range of process parameters (t = 25–190°C; PO2 = 0–7 bar) investigated to achieve the optimal conditions for leaching process at the ambient as well as at increased pressure. As a result, an initial process block diagram for the treatment of Cu-cake with high copper leaching efficiency and low metal losses is provided. INTRODUCTION The conventional technology for nickel sulphide ore processing includes the following main stages: froth flotation, matte smelting and converting. The subsequent processing of nickel converter matte is possible using fundamentally different approaches - hydrometallurgical (Llanos, Queneau & Rickard, 1974; Rademan, Lorenzen & Van Deventer, 1999; Kshumaneva, Kasikov, Neradovskii & Belyaevskii, 2009; Dutrizac & Chen, 2013) and pyrometallurgical (Tsymbulov, Knyazev, Tsemekman & Golov, 2007). Hydrometallurgical approach in comparison with pyro-process has several advantages, such as reduced environmental load, reduced PGM losses, increased copper and nickel extraction. Typically, hydrometallurgical technologies include leaching, solvent extraction as well as nickel and cobalt recovery in metallic form by electrowinning or hydrogen reduction or as valuable metal salts via crystallization process (Crundwell, Moats, Ramachandran, Robinson & Davenport, 2011).

Jan 1, 2019

By Ernest A. Hodgson

A SERIOUS hazard which must be faced in some mines, though quite absent in others, is that of rockbursts. Bursts cannot be wholly avoided in such mines, but the hazard would largely disappear if they could be predicted. The problem of prediction resolves itself into that of measuring pressure in the mine and determining when that pressure nears a critical value. The geophysical approach to the problem lies in discovering some physical property of the rock, which varies with pressure, which can be measured for rock in place, and for which the indication of critical conditions is sufficiently definite and open scale. A physical property, suggested first in connection with earthquake pre-diction, is that of sub-audible snapping. It was argued that, as the pressure grows, the rock probably yields microscopically and that minute snapping occurs which is so faint as to be inaudible to the unaided ear. Experience has proved this to be the case. Following other earlier work begun early in 1939, experiments with this method were initiated at Lake Shore Mines in 1941, and equipment was slowly being developed in practice when, fortunately, it was found possible to by-pass this tedious development programme. Experiments with sub-audible snapping in mine rocks had been carried out by Dr. L. A. Obert of the U.S. Bureau of Mines and his associates over a period of about four years. An amplifier and a recorder were developed, each reasonably satisfactory in practice. Lake Shore Mines offers a tempting field for rockburst research. Dr. Obert was invited to test his equipment in this and other mines in Ontario and did so. As a result, he and the administrative personnel of the Bureau became interested in the Lake Shore experiments co the extent of most generously arranging for the manufacture of sets of their own designed equipment for use in this programme. The first three sets of recorders were ordered at once and were delivered in May, 1942. A second group of three sets, incorporating various improvements indicated by experience both in the United States and in Canada, reached Kirkland Lake in April, 1943. The pick-up devices, known as geophones, were made in the electronics laboratory at Lake Shore by Mr. Zack Gibbs, who has had charge of all the instrument development in this re-search.

Jan 1, 1943

By J. Schmidt

The development of set of laboratory experiments, intended to help undergraduate students meet Canadian Engineering Accreditation Board requirements for Engineering Design outcomes, is described.The laboratory, which is part of a third year level course in hydrometallurgy, is aimed at advancing the ability of students to generate and use experimental results to design an industrial copper leach/SX/EW plant. Emphasis is placed on the students demonstrating the ability to use of their engineering knowledge in weighing the pros and cons of the various process options that they test in converging to a final flowsheet. INTRODUCTION Over the past number of years the Canadian Engineering Accreditation Board, CEAB, has dramatically shifted the way that they evaluate undergraduate programs. In the past, the focus was on measuring of the quantity and quality of material the students were intended to learn as well as the methods and resources used to deliver that material. Now, rather than principally evaluating the inputs of programs, the focus is more on measuring the quality of the outputs from the programs, i.e. the quality of graduating students. In this regard, the CEAB has developed a list of twelve attributes that learners must develop in the course of their studies. Engineering programs must, not only demonstrate that their curriculums provide opportunities to develop these attributes, but must measure student proficiency in each of these attributes as they progress toward graduation. One particular graduate attribute that Laurentian University’s Bharti School of Engineering has encouraged its faculty members to develop content for is “design”. Engineering Canada (2018) defines this attribute as “an ability to design solutions for complex, open-ended engineering problems and to design systems, components or processes that meet specified needs with appropriate attention to health and safety risks, applicable standards, and economic, environmental, cultural and societal considerations”. The previous laboratory component for the hydrometallurgy course was a collection of unconnected experiments covering leaching, solvent extraction, ion exchange, and electrowinning. Like in other undergraduate courses, students would perform stand-alone experiments, make the specified measurements, do the specified analyses of the results, and report the findings, all as strictly detailed in the lab manual. The vision for the new lab was to create an experience that would more closely mimic an industrial research program whereby students would start with a given feed material and would progress through a series of connected experiments. Emphasis is placed on the student demonstrating competency in, not only, generating and analyzing experimental data, but also in using the data along with their engineering knowledge to design and evaluate the pros and cons various plant configuration options. Principally, students are asked to weigh cost, safety, and environmental concerns in converging to their final flowsheet. In designed the leach circuit, students must weigh the costs/benefits of varying leach temperature. Higher leach temperatures will yield faster and more complete copper dissolution, which will allow for the specification of relatively smaller leaching circuits, saving capital costs. However, hotter acid solutions are more dangerous to handle and require increasing amounts of energy to heat the slurry, increasing operating costs. In solid/liquid separation, students must weigh the pros and cons of the addition of a flocculent to assist settling. The flocculant will allow for the design of a thickener circuit that employs units with a relatively smaller area, but will result in a thickener underflow with a lower pulp density, which may necessitate a larger number of thickeners. In addition, the environmental concerns of producing a tailings product that contains an organic contaminant should be addressed. In solvent extraction, students must specify the number of stages of loading and stripping, as well as organic and aqueous flowrates to produce suitable raffinate and rich electrolyte streams. Finally, in electrowinning, students will compare the costs/benefits and risks of the use of precious metal coated titanium dimensionally stable anodes (DSAs) versus conventional Pb based anodes.

Jan 1, 2019

Outline ?Red Lake Gold Mines ?Red Lake Seismic System ?Applications of Seismic System at Red Lake Mine ?Seismic System Analysis and Customization ?Seismic Software ?Array Design ?Calibration and Source Mechanism ?Auto Picking Optimization ?Acquisition Groups ?Conclusions Goldcorp?s Red Lake Gold Mines ?One of the largest gold producers in Canada ?The operations comprise the former Campbell and Red Lake underground mines, now integrated as the Red Lake Gold Mines (RLGM) ?There are a total of 4 shafts with one internal winze and two main declines beginning at the 21st level ?Daily production approximately 2,600 tons

Aug 1, 2013

By K. R. Nichol

The author points out that corrosion works 24 hours a day, every day. It is an economic reality that the cost of corrosion is inevitable and that its cost should be incurred in the least expensive way. An economic evaluation technique to properly assess its relative impact is the Discounted Cash Flow Method. Various remedial and corrosion control measures are available and these, when coupled with a planned corrosion control program, help reduce the cost of corrosion.

Jan 1, 1973

By S. M. Grillo, M. Fiori, R. Bornioli, C. Marini, S. Fadda

The Na-feldspar orebodies in Sardinia occur along structures belonging to a regional ENE-WSW system that developed during the late stages of the Hercynian orogeny, and that was reactived during the Alpine orogeny. The main petrographic facies include granitoids, albitized granitoids, albitites (more or less rich in quartz), and albitites containing Mg minerals. Field observations and petrological and geochemical data point toward a metasomatic origin for the albitite orebodies. Albitization involved depletion of K from K-feldspar and biotite, dissolution of free quartz, and a lowering of Sr/Na2O and CaO/Na2O ratios in the protolith, under conditions of a positive thermal gradient. The absence of later K-metasomatism implies that, during a subsequent decline in temperature, the composition of the albitizing fuids was modified by an influx of meteoric or other waters. Copyright © 1996 Canadian Institute of Mining, Metallurgy and Petroleum.

Jan 1, 1997

By G. M. Dunn

Pressure leach autoclave circuits are employed in the leaching of ores, concentrates, mattes, alloys and intermediates for the recovery of metals into solution. Once the metals are extracted into solution the value metals can be recovered by hydrometallurgical means such as by purification followed by electrowinning, hydrogen reduction, pyrohydrolysis, crystallisation and other unit operations. In many of these integrated flowsheets the pressure leach step is pivotal to the recovery of the value metals from the host material. In an expansion or a new project, a large component of the capital cost can be associated with the pressure leach step and process engineers frequently look for opportunities to mitigate costs. This paper examines a new route for increasing the capacity of an exothermic pressure oxidation leach for sulphide concentrates, sulphide and phosphide mattes and alloys.

Jan 1, 2004

By S. M. Grillo, Fiori. M., R. Bornioli, C. Marini, S. Fadda

Abstract - The Na-feldspar orebodies in Sardinia occur along structures belonging to a regional ENE-WSW system that developed during the late stages of the Hercynian orogeny, and that was reactived during the Alpine orogeny. The main petrographic facies include granitoids, albitized granitoids, albitites (more or less rich in quartz), and albitites containing Mg minerals. Field observations and petrological and geochemical data point toward a metasomatic origin for the albitite orebodies. Albitization involved depletion of K from K-feldspar and biotite, dissolution of free quartz, and a lowering of Sr/Na2O and CaO/Na2O ratios in the protolith, under conditions of a positive thermal gradient. The absence of later K-metasomatism implies that, during a subsequent decline in temper- ature, the composition of the albitizing fluids was modified by an influx of meteoric or other waters.

Jan 1, 1996

By S. Shairp

"After cooling and thickening, slurry from the second stage of the Hudbay zinc pressure leach circuit is filtered and washed on a belt filter prior to disposal. At times, the belt filter can be a bottleneck to the process. Preliminary studies show that filterability of the second-stage (HAL) autoclave leach residue can be indicated by particle size distribution of the filter feed and filtered residue cake. In particular, the Volume Weighted Mean Diameter, D[4,3], generated by a laser diffraction particle size analyzer from samples of HAL Filter feed, shows residues that filter more poorly have a lower Volume Weighted Mean Diameter than those that filter better. INTRODUCTIONHudbay produces cast zinc metal from blends of zinc concentrates at its metallurgical complex in Flin Flon, Manitoba, Canada, using Sherritt’s two-stage pressure leach process (Collins et al., 1994; Collins et al., 1995; Barth et al., 1998; Shairp et al., 2006). Pressure leaching replaced the original roastleach- electrowinning process in 1993.Filtration for the second-stage (HAL) leach residue originally consisted of two stages of vacuum drum filtration with intermediate cake repulping stirred tanks. As part of Hudbay’s 777 Project, with a designed increase in cast zinc production, a pre-feasibility study by SNC-Lavalin Inc. showed that losses of soluble zinc in the zinc pressure leach residue could be reduced by installing more efficient filtering and washing equipment. Based on laboratory performance, capital cost, installation ability, and potential operating cost savings, a 70 m2 Filtres Phillipe belt filter was chosen for the HAL residue, and commissioned in 2000/2001.When the HAL belt filter is performing well, there is no pooling of water on the surface, moisture content is relatively low, and subsequent analysis shows that water soluble zinc content is relatively low. There have been occasions where the filter has performed poorly with respect to the aforementioned parameters. Aside from the filter experiencing mechanical difficulties, there are several variables affecting leach residue filtration:"

Jan 1, 2012

By D. F. Zhang, X. Q. Jiang, N. Tahreen, D. L. Chen, F. S. Pan, D. Y. Li

Alloying with rare-earth elements has been proven to be an important tool for magnesium to achieve superior properties via texture randomization. The role of yttrium in texture weakening and the link between texture and formability are fairly well known. Since annealing is a vital part of metal processing which could significantly contribute to ductility, it is important to ascertain the impact of annealing in terms of texture change. Also, an understanding about texture development during pre- and post-deformation annealing is essential to improve the industrial deformation processing as texture is closely related to formability. While there is independent information in the literature regarding the effect of rare-earth addition and heat treatment on the texture formation, no systematic studies have been reported on the collective impact of yttrium addition, annealing and deformation on texture evolution. The present study was, therefore, aimed to identify the inter-relationship among texture evolution, yttrium content, heat treatment and deformation behavior in an extruded Mg-Zn-Mn-Y alloy. Annealing at 450°C for 1 hour and uniaxial compression tests at a certain amount of deformation were performed. The deformed and annealed samples were then subjected to annealing and compression test, respectively, followed by texture measurements. It was observed that yttrium addition effectively weakened the crystallographic texture in all conditions, which was evident from the changes in the microstructures and textures.

Jan 1, 2015

By Harold L. Gibson, Don H. Rousell, Ian R. Jonasson

"The Sudbury Structure consists of three major components: 1) the Sudbury Basin; 2) the Sudbury Igneous Complex which surrounds the basin as an elliptical collar; and 3) an outer zone of shatter-coned and intensely brecciated footwall rocks. Although the Sudbury Event which formed the structure may be unique, the area has, in fact, been shaped by a series of tectonic, magmatic and mineralization events which can be considered in terms of two Wilson cycles of continental extension and closure. The first cycle, from 2500 to 1700 Ma, included the following events: doming (uplift of Levack Gneiss Complex); NE-SW extension (Matachewan dikes); N-S to NW-SE rifting (faults, mafic intrusions, sedimentation, and Ni-Cu-PGE and U mineralization); NW-SE extension (Nipissing diabase, and Ni-Cu-PGE, Ag, Co mineralization); and NW-SE and NE-SW closure (Penokean Orogeny, 1900 to 1700 Ma) with superimposed meteorite impact (1850 Ma, Ni-Cu- PGE, Zn-Cu-Pb deposits). The second cycle, from 1700 to 1000 Ma, included: N-S extension (alkali metasomatism, Au); N-S extension (hornblende diabase dikes along the Murray fault set); NNESSW extension (olivine diabase dikes); NE-SW extension (Fecunis Lake fault set); and NW-SE closure (Grenvillian Orogeny).The rich and diverse Ni-Cu-PGE and subordinate Zn-Pb-Cu and Au mineralization of the Sudbury region is related to endogenic and impact-triggered crustal extension and magmatism. The Sudbury Structure apparently was the site of a triple junction or hot-spot. The Sudbury ores, although located within an impact structure, are analogous in terms of age and tectonic setting to Ni-Cu-PGE and Zn-Pb-Cu ores elsewhere in the world. Meteorite impact accentuated on-going ore forming processes and magmatism at Sudbury."

Jan 1, 1997

By Harold L. Gibson, Don H. Rousell, Ian R. Jonasson

"Abstract - The Sudbury Structure consists of three major components: 1) the Sudbury Basin; 2) the Sudbury Igneous Complex which surrounds the basin as an elliptical collar; and 3) an outer zone of shatter-coned and intensely brecciated footwall rocks. Although the Sudbury Event which formed the structure may be unique, the area has, in fact, been shaped by a series of tectonic, magmatic and mineralization events which can be considered in terms of two Wilson cycles of continental extension and closure. The first cycle, from 2500 to 1700 Ma, included the following events: doming (uplift of Levack Gneiss Complex); NE-SW extension (Matachewan dikes); N-S to NW-SE rifting (faults, mafic intrusions, sedimentation, and Ni-Cu-PGE and U mineralization); NW-SE extension (Nipissing diabase, and Ni-Cu-PGE, Ag, Co mineralization); and NW-SE and NE-SW closure (Penokean Orogeny, 1900 to 1700 Ma) with superimposed meteorite impact (1850 Ma, Ni-Cu- PGE, Zn-Cu-Pb deposits). The second cycle, from 1700 to 1000 Ma, included: N-S extension (alkali metasomatism, Au); N-S extension (hornblende diabase dikes along the Murray fault set); NNESSW extension (olivine diabase dikes); NE-SW extension (Fecunis Lake fault set); and NW-SE closure (Grenvillian Orogeny).The rich and diverse Ni-Cu-PGE and subordinate Zn-Pb-Cu and Au mineralization of the Sudbury region is related to endogenic and impact-triggered crustal extension and magmatism. The Sudbury Structure apparently was the site of a triple junction or hot-spot. The Sudbury ores, although located within an impact structure, are analogous in terms of age and tectonic setting to Ni-Cu-PGE and Zn-Pb-Cu ores elsewhere in the world. Meteorite impact accentuated on-going ore forming processes and magmatism at Sudbury."

Jan 1, 1997

By K. L. Ford, D. R. Lentz, J. H. Rickard, R. P. Taylor

Abstract - Coupled gamma-ray spectrometric and lithogeochemical studies throughout the Heath Steele Mines area, Bathurst Camp, New Brunswick, indicate that primary and secondary geochemical differences exist between the stratigraphic footwall and hangingwall crystal tuff units which host the massive sulfide deposits. Of particular interest is Th, and to a lesser extent, Zr and Y, which are more concentrated in the hangingwall than the footwall crystal tuffs, whereas the opposite is true for TiO2. This expands on earlier lithogeochemical-chemostratigraphic results concentrated in the eastern part of the Heath Steele belt that led to revision of the local stratigraphy, and necessitated a structural re-interpretation of the area with implications for exploration. Although K depletion (decreased K and K/Th) is typical of chloritized footwall zones of chloritization, these features were not fully apparent here due to the recessive nature of these altered zones. In situ radiometric analysis using a portable gamma-ray spectrometer is a rapid, inexpensive analytical technique for chemostratigraphic characterization of rock units within volcanogenic massive sulfide deposit settings, provided there is a contrast in the distribution of natural radioelements, particularly Th and K.

Jan 1, 1998

"Industry Guide 7 contains the Securities and Exchange Commission’s basic mining disclosure policy. It provides guidance for Registrants on various matters including the definition and disclosure of proven and probable reserves and the definitions of exploration, development and production stages. The definitions and disclosure instructions contained in this Guide apply to all public mining entities and their public disclosures. As NI 43-101 is law in Canada, the SEC allows mineral resources and mineral reserves prepared under CIM Definition Standards for issuers that are reporting in Canada but are also registered with the SEC. The SEC places conditions on the disclosure of these estimates. US shareholders are cautioned that the requirements under NI 43-101 and the CIM Definition Standards differ significantly from those of Industry Guide 7.Note: this Guide contains the Commission's basic mining disclosure policy. The definitions and disclosure instructions contained in this Guide apply to all public mining entities and their public disclosures pursuant to the rules of Regulation S-K. Questions regarding the application of these definitions and rules to specific situations should be asked of the Commission's mining engineers or geologists at either the Office of Engineering, Division of Corporation Finance, 202-272-3252, or the Branch of Geology, Central Regional Office, 303-844-1000.(a) Definitions. The following definitions apply to registrants engaged or to be engaged in significant mining operations:(1) Reserve. That part of a mineral deposit which could be economically and legally extracted or produced at the time of the reserve determination.Note: Reserves are customarily stated in terms of DoreD when dealing with metalliferous minerals; when other materials such as coal, oil shale, tar, sands, limestone, etc. are involved, an appropriate term such as Drecoverable coalD may be substituted.(2) Proven (Measured) Reserves. Reserves for which (a) quantity is computed from dimensions revealed in outcrops, trenches, workings or drill holes, grade and/or quality are computed from the results of detailed sampling and (b) the sites for inspection, sampling and measurement are spaced so closely and the geologic character is so well defined that size, shape, depth and mineral content of reserves are well- established.(3) Probable (Indicated) Reserves. Reserves for which quantity and grade and/or quality are computed from information similar to that used for proven (measured) reserves, but the sites for inspection, sampling, and measurement are farther apart or are otherwise less adequately spaced. The degree of assurance, although lower than that for proven (measured) reserves, is high enough to assume continuity between points of observation.(4)(i) Exploration StageDincludes all issuers engaged in the search for mineral deposit (reserves) which are not in either the development or production stage."

Jan 1, 2003

By J. Chao, C. Tan, N. Stubina

"Since J978, Falconbridge Limited has operated two electric furnaces at its nickel-copper smelter in Sudbury. As part of its S02 Abatement Program, the smelter has undergone many changes over the last seven years.This paper describes the impact of these changes on the operation of the furnaces. Some of the topics to be covered include: the installation of sidewall copper coolers; current operating conditions; and furnace heat and mass balances. HistoricalFalconbridge began smelting ores in the Sudbury area in 1930. The original smelter consisted of a 1.3 m by 3 m blast furnace and two 4 m by 6 m converters. The blast furnace was supplied with untreated mine are and molten slag/matte was discharged into a round settler.In 1933 the smelter began treating flotation concentrates. The concentrates were mixed with fine magnetic ore and flue dust, then sintered on down-draught Dwight Lloyd machines. This provided an agglomerate suitable for furnace burden which was charged to the blast furnace while still hot.Between 1930 and 1954 nickel production was increased by lengthening the 3 m furnace to 4.6 m, then to 6 m, and later by constructing additional furnaces. By 1958, the plant consisted of one 7.5 m blast furnace, a settler, and three 4 m by 9 m converters."

Jan 1, 1994

By J B. McConnell

The Thompson smelter has three unique features which form the basis ~f its design: fluid bed roasters which treat nickel concentrate filter cake from the mill, as well as the flux, in order to achieve partial desulphurization; the use of electric furnaces for the smelting of the partially desulphurized, preheated roaster product; and the disposal of slag by water granulation and slag slurry pumping. The installation consists of three fluid bed roasters, each feeding an electric furnace. Nickel concentrate is received at the smelter via pipe line. It is thickened and filtered, and the filter cake, together with siliceous flux, is fed through rotary bin feeders and reciprocating double-gate seals into the fluid bed roasters. Air injected into the roasters through club-head tuyeres oxidizes part of the sulphur and associated iron in the concentrate. The heat of reaction dries and heats the charge. Roaster product is recovered from the gas stream in cyclones and from the roaster bed through automatic valves.

Jan 1, 1963

By D. D. Bell

This paper presents the history of uranium procurement and demand, and takes a look at future requirements. The three basic conclusions drawn are: (1) the productive capacity of former and existing producers whose operations may be profitably reactivated is insufficient to meet demand projected beyond 1975; (2) reserves in the $5 -$10 price range do not provide the flexibility to sustain production at the high rates required in the late 1970's; and (3) only higher prices can overcome these deficiencies, as this would provide sufficient inducement for the industry to explore for and develop new reserves and productive capacity.

Jan 1, 1967

By R. Holmestad, M. Gazizov, S. Wenner, R. Kaibyshev, J. K. Sunde

"Mechanical properties and microstructure of an Al-4.7Cu-0.74Mg-0.51Si-0.48Mn-0.10Cr-0.09Ti-0.02Fe (wt. %) alloy subjected to various thermomechanical processing (TMP) have been investigated and compared to conventional ageing at 170°C (designated T6). Three TMP routes involving cold deformation of solution treated samples were tested. These were (i) 3%-stretching (T8-3%), (ii) equal-channel angular pressing (ECAP) to true strain (e) of ~1 (T8-1) and (iii) ECAP to e~2 (T8-2), all with subsequent ageing at 170°C for 0-96 h. At peak age conditions, both yield stress, ultimate tensile strength and elongation-to-fracture decreased for the T8-3% state as compared to the T6 condition. Intermediate ECAP (T8-1 and T8-2) lead to significant increase in maximum yield stress, ultimate tensile strength and elongation-to-fracture. The changes in mechanical properties were related to microstructure evolution, encompassing changes in grain sizes, dislocation densities, precipitate morphology and phase fractions, which were characterised using transmission electron microscopy. Relations between TMP, precipitation behavior and contributions to different strengthening mechanisms are evaluated.INTRODUCTION Al-Cu-Mg-Si alloys are widely used as structural materials in aerospace industry due to their attractive combination of high specific strength, good fracture toughness and enhanced creep resistance. These properties are largely due to the formation of a large number of nano-sized metastable precipitates during artificial ageing (Polmear, 2006; Eskin, 2003; Gazizov, Dubina, Zhemchuzhnikova, & Kaibyshev, 2015). The precipitation behaviour in these alloys is complicated and depends among other things on Cu concentration and the Mg:Si ratio (Wolverton, 2001; Chakrabarti, & Laughlin, 2004). In general, the precipitation sequence has been presented in a prior study (Eskin, 2003) as follows:"

Jan 1, 2018