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By M. D. Everell

Le Centre de Recherches minérales (CRM), qui est un organisme de recherche appliquée du ministère de l'Energie et des Ressources du Québec, a été créé en 1969, dans le but de procurer un support scientifique et technique à l'industrie dans le domaine des mines et de la métallurgie. Pour atteindre ses objectifs, le CRM met à la disposition de l'industrie un personnel spécialisé et compétent dont une quarantaine d'ingénieurs et de scientifiques. Etant donné la nature même de l'industrie minérale, ce personnel est très versé dans l'étude des problèmes diversifiés des domaines de la technologie minière, du traitement des minerais, de la métallurgie extractive et de l'analyse minérale. Ce Centre de recherches met également à la disposition de l'industrie une usine-pilote permettant de reproduire les résultats du laboratoire au moyen d'un appareillage de type industriel, d'obtenir des échantillons en quantité suffisante pour une exploration du marché et de familiariser du personnel avec les opérations normales de l'industrie. Certaines de ses contributions récentes au développement de l'industrie minérale du Québec seront présentées.

Jan 1, 1985

By K. D. Peaslee

Slag splashing is an important development that has dramatically improved BOF vessel campaign life and reduced operating costs. This paper highlights research from physical modeling work using a 1/8-scale room temperature model BOF and slag characterization studies from several plants in North America and China. In the model studies, gas flow rate during blow and viscosity of the liquid were found to be two of the most important factors to changing the overall rate of liquid splashed onto the vessel sidewalls. When the flow rate was increased or viscosity decreased, the lower regions of the walls were splashed at a much greater rate. It was also shown that by changing the lance height, more liquid was deposited in the upper regions of the vessel at the expense of lower regions. Reducing the number of nozzles was found to be the most effective method of selectively coating a particular vertical section of the wall. Studies of BOF's using slag splashing in North America and China showed a difference in the melting characteristics of the final slag. Generally, slag splashing is successful when the melting point of the slag is 220-270°C below the tap temperature to maintain a balance between fluidity and refractoriness.

Jan 1, 2004

By Brian K. Ayres

Inco Limited, Ontario Division is currently in the process of decommissioning the Whistle Mine site located near Sudbury, Ontario, Canada. The most significant component of site decommissioning involved relocating approximately 6.4 million tonnes of acid-generating waste rock to the open pit from two adjacent stockpiles. An engineered cover system was designed for the backfilled pit to reduce the long-term production of acid rock drainage. Geochemical modelling was conducted to assess the effectiveness of various cover options on the longterm water quality of the backfilled pit. Results obtained from performance monitoring of cover system field trials at the site and estimated full-scale construction costs were used to select an appropriate material for the cover system barrier layer. The two-dimensional soil-atmosphere model VADOSE/W was used to develop a calibrated model of covered waste rock based on field data obtained from the cover trials, which was subsequently used to predict net percolation and oxygen ingress through various cover system alternatives for site-specific climate conditions. Erosion and landform evolution numerical modelling was completed to assist in designing the runoff management system and final landform for the pit cover system. The potential impact of various physical, chemical and biological processes on the sustainable performance of the pit cover system was also considered in the design process. This paper provides an overview of the design and construction of the backfilled pit cover system.

Apr 1, 2005

By Richard R. Klimpel, Simon Isherwood

"The industrial processing of ores containing gold and/or platinum minerals is generally mining site specific, e.g. McQuiston and Shoemaker (1985). The variety of various mineral processing techniques employed is extensive and includes size classification, gravity concentration, amalgamation, roasting, cyanidation, chemical leaching, ion ex-change/solvent extraction and froth flotation. Because of the relatively small quantities of Au and Pt that exist in the earth’ s crust, the economical recovery of Pt and Au often requires that the Au and Pt be associated with other industrially important minerals. This association of Au and Pt with other minerals can occur in very complicated mineralogical forms. It is probably safe to say that Au and Pt mineral concentration from natural ores represents some of the most complex metallurgical challenges facing the mining industry.Froth flotation is a technique that is receiving increasing industrial attention for the treatment of finely disseminated and/or associated Au and Pt minerals. The high throughput at relatively low capital cost, the potentially high selectivity, and the existence of a well-established technology for treating more abundant associated minerals such as base metal sulfides makes froth flotation an attractive processing alternative. Broadly speaking, the industrial oriented froth flotation experience with Au and Pt minerals exists in two major categories: 1) the flotation of Au and Pt associated with pyrite (or pyrrhotite) and 2) the flotation of Au and Pt associated with primarily Cu, Zn, or Cu/Pb/Zn containing sulfide ores.In the case of the precious metal association with pyrite (or pyrrhotite), much of the published froth flotation experience comes from South Africa. Typically, such processes are done using an acid side flotation with a collector such as mercaptobenzothiazole. The approach obviously is to float pyrite and hence recover associated gold. Generally the higher the total sulfur recovery the higher the gold recovery. Similar experiences of Pt associated with pyrite are a lot less common mineralogically and hence less well documented industrially. For example, in Canada, Pt is often associated with pyrrhotite but is not really processed as a straight pyrrhotite recovery.For the situation of Au and/or Pt associated with other base metal sulfide minerals, the industrial experience base is quite varied and is well documented from both North and South American operations. The nature of most of these flotation processes is to design, operate, and optimize the installed concentrator to get the Cu, Pb, Zn, Ni, etc. that is the bulk of the valuable sulfide ore and then take whatever precious metal recovery comes. Typically, such flotations are on the basic side using standard thiol collectors such as xanthates, dithiophosphates, thionocarbamates, etc. It is very common with such ores to use mixtures of collectors in order to get ""everything"". Often in such plants, there is an inherent balancing act occuring so as to operate in such a manner to reject pyrite (and pyrrhotite) in order to maintain high base metal mineral concentrate grades and yet recover sufficient precious metals such as Au and Pt minerals which often are associated with the iron sulfides being rejected. Obviously in such an environment, the smelter operation often ends up telling the concentrator what the precious metal recovery actually was in a given production period."

Jan 1, 1994

By Thom Sedun

No sector of the mining industry is more closely tied to local communities than aggregates. Noise, dust, traffic, visuals aesthetics and environmental impacts all fall under the purview of neighbours, local governments and nongovernment organizations. It is no surprise that aggregate operations may not be welcome neighbors in many communities. In British Columbia (BC), the regulatory environment for aggregate operations includes a local component of municipal bylaws and land use-planning in addition to the usual suite of federal and provincial statutes that apply to its sister mining sectors. Additionally, under common law aggregate extraction is not considered to be a land use subject to land use zoning, and some aggregate processing activities can be regulated by zoning. Often traversing multiple local government jurisdictions, aggregate producers find themselves negotiating not only local traffic, but also a mosaic of regulatory environments. There is an opportunity in this present situation to facilitate the application of current technology and practices in the mitigation of many community and environmental concerns associated with aggregate operations. Moving a bulk commodity is a volume-based business, and operators often don?t have time for matters that don?t directly or obviously affect the bottom line. Regulatory agencies often play multiple and complex roles with respect to their industry, not the least of which is the fiduciary role. Balancing how and when to assist an industry is often a difficult decision. For the aggregate industry in BC, the Ministry of Energy and Mines saw an opportunity to assist not only aggregate operators, but also regulatory agencies, local governments, and the general public. Through investing in the Aggregate Operators Best Management Practices Handbook (handbook) project, the Ministry of Energy and Mines (MEM) believes that it will realize a return of upheld community values, enhanced environmental protection, improved regulatory compliance, reduce disputes and a stronger provincial aggregate industry. It is the intent to publish the handbook electronically through the MEM website later this year.

May 1, 2002

By D. Song

In this paper, the differential equations governing the mass transport and the electrochemical reaction in a cathode catalyst layer of polymer electrolyte membrane fuel cells are solved based on the polynomial series expansion method. Explicit expressions for the polarization curve as well as for the distributions of oxygen, current density and overpotential are obtained when a quadratic, cubic or quartic polynomial is employed to approximate the oxygen concentration distribution. These kinds of explicit solutions are desirable for MEA design and diagnosis purposes. The comparison between the conventional numerical approach and the explicit solution approach proposed here shows that satisfactory accuracy can be reached by the first four terms of the polynomial series. The effect of the catalyst layer thickness on the accuracy of the obtained explicit polynomial solutions is also discussed.

Jan 1, 2005

By S. C. Ellis

THE bituminous sand of northern Alberta has already an extensive literature, and most of the reports dealing with the subject are still available (see Selected Bibliography at end of paper). A phenomenon so striking and, as regards its extent, so unique, as the deposit in the vicinity of McMurray settlement could not fail to attract the notice of the early explorers, and we find references to it as far back as the latter part of the eighteenth century. However, scarcely a thought had been bestowed upon the possible economic value of minerals in the the remote northern parts of Canada before the second decade of the present century, and practically no detailed mapping had been done north of the town of Athabaska. The late Wm. Ogilvie made a track survey of Athabaska river in 1884, and surveys of certain lines-including the 23rd base line-had been completed by 1911. Between this base line and lake Athabaska, nothing had been attempted. Actually, no definite information at all was available regarding the character and extent of the bituminous sand when, in the earl y summer of 1913, a reconnaissance party set out from Athabaska for McMurray. At that period, the journey was made in summer by scow or canoe. No telegraph line had been laid, and a casual mail service by canoe or dog team once in three months formed the only means of communication with the outside world. The investigation has begun by the Mines Branch was continued during several subsequent years. The sand deposits were studied and sampled, the bi rumen was extracted from the sand and studied chemically and physically, and the economic significance of the deposit was given exhaustive study.

Jan 1, 1937

By A. Bouajila

To stay competitive in an open market, mineral industries have to optimise their processes, lower their production costs and improve the commercial value of their products. Up to a recent past, they were impaired in this attempt by a lack of adequate devices allowing reliable on-line and real-time process monitoring (detection or measurement). Process monitoring for process control and the product characterisation for quality control are quite different tasks. Planners and researchers should be fully aware of this when evaluating or developing monitoring equipment for on-line process control. This paper will comment on some aspects of sensor specifications, during the design and the evaluation steps, related to sampling, measurement (accuracy, sensitivity, delay and correlation to the process) and suitability to the exploitation environment. Examples of R&D projects promoted by COREM for various industrial applications will be presented.

May 1, 2001

By D. F. Sangster

"Eight volcanogenic massive sulphide districts in Canada and Japan, ranging in age from Archean to Miocene, were selected for analysis. The study revealed that: {I) each district has an average diameter of 32 km; (2) the districts contain 4 to 20 deposits each, with an average of /2 deposits; (3) the average total base metal content per district is 4.6 million tonnes, with a coefficient of variation of32%; (4) ranked in order of size, the largest deposit in each district contains, on average, 67% of the total metal and the second largest about 13 %. The remaining deposits range downward in decreasing proportions. Empirical observations such as these may be used f or evaluating the undiscovered potential of new districts as well as contributing to a better understanding of the distribution and genesis of this important class of base metal deposits. Previous WorkThe characteristic geological features o f volcanogenic massive sulphide deposits have been described by numerous authors over the past fifteen years and it is now widely accepted that these deposits comprise a major ""deposit-type."" In addition to these geological parameters, however, it is now becoming apparent that volcanogenic massive sulphide deposits show several distinctive grade-tonnage relationships. For example, Singer et al. (1975) demonstrated a slight negative correlation between copper grade and ore tonnage in their sampling of 146 volcanogenic deposits. In a study of 110 Canadian Precambrian deposits of this type, Boldy (1977) showed that the size of the modal deposit is 0.39 million tons, that of the median deposit is 1.40 million tons and the arithmetic average is 6.85 million tons. Moreover, Boldy's data show that the average grade of combined base metals (Cu + Zn + Pb) for each of the se three deposit-sizes is, respectively, 6.25%, 5.35% and 6.47%. Because the lead content of Canadian Precambrian volcanogeni c deposits is most frequently less than 1%, the total metal grade is effectively Cu + Zn . From Figure 2 in Bold y (1977), it can be seen that 83% of the deposits fall in the range of 0.l to 10 million tons ."

Jan 1, 1980

By Egon Berger

"In recent years the trend in underground metal mining has been toward ever increasing blasts (often in excess of 100 000 tonnes per blast). The Canadian mining industry has been in the forefront of these developments (VRM, LBHand cable bolting to stabilize the surrounding rock /avoid dilution).In order to move these large tonnages, efficient loading systems have to be developed. This paper shows the technical and economic implications of various loading scenarios based on a predefined (however typical) stoping layout by:1 . discontinuous loading using scoop trams;2. discontinuous loading using scoop trams in combination with low profile dump trucks;3. continuous loading (based on loading performance/operating costs of the AL-60) in combination with low profile dumptrucks.The cost advantages of production concentration (loading large tonnages from one drawpoint}, made possible by continuous loading as opposed to sea tiered mining (small tonnages), using discontinuous loading in tunnelling will be presented, based on actual results obtained in a decline development project using the A L-60 continuous loader. At as pacing oj150m between turning bays, it was found that continuous loading was out performing discontinuous loading in approximately80% of the overall decline development.Fuel consumption and total cycle times are compared, and a cost assessment is presented.INTRODUCTIONThe subject of this paper deals with the introduction of continuous loading in underground metal mining and single heading tunnelingContinous mining has been widely introduced both in underground and surface coal mining. Mechanized longwall mining, utilizing moveable shield supports in combination with double drum- shearers, has resulted in a tremendous increase of coal production per working face.This has led to very concentrated mining operations. In a typical German coal mine two mechanized longwalls nowadays would produce the same amount of coal as 12 to 15 longwalls in the 1950s. One longwall in a South African coal mine has recently set a world record with 120 000 tonnes of coal in a single month.In underground metal mines-often due to the irregular nature of the ore body and the mining methods used-mining is far less concent rated. Ore is often produced from a large number of stopes and production sections. Sometimes, a substantial amount of ore may be obtained from development in the orebody (40070 at a German base metal mine)."

Jan 1, 1989

By J. G. Martin, J. C. Campbell

THE VICTORIA JUNCTION 31,4-million-ton coal preparation complex went into operation in October 1976."' It is designed to produce a metallurgical coking coal by lowering the sulphur and ash content of the raw coal using a heavy-media cycloning process to treat deslimed crushed coal, with scavenging of fine coal by flotation from the primary minus-28-mesh screen product. A secondary H-M cyclone scavenges a thermal-grade coal from the primary H-M cyclone tailing.

Jan 1, 1985

By W. Petruk

"D. Doyle How large is the beam to which you referred? Are we considering Watts, Griffis the probe of a 1 micron sized particle?& McOuatReply Yes. The beam would be about 1 micron. We could enlarge or reduce it depending on the current in-put.D. Doyle Then chemically bound material we might not see. If you are restricted to 1 micron then you would not be able to separate things smaller than this. Is this not so?Reply We won't be able to analyse it but we will see it as the scanning electron microscope has a resolution down to about 0.1 microns. We should be able to get the general composition of such a grain plus its surrounding grains. We feel we can then make a reasonable estimate if it were as small as 0.1 microns. An accurate analysis would be achieved with grains of 3 and 4 microns.D. Doyle Would this have an application in the hydrocarbon field?Reply The lowest atomic number would be sodium. We wouldn't be able to go below that atomic number. Anything with sodiumor a larger atomic number would enable us to analyse the carbon.M. Fairwether Do you have any policy relating to priorities. For instance areCominco companies going to be limited in the amout of samples permitted to give everyone a chance because quite frankly our company, and I'm sure all base metals companies can hardly wait for the installation of this equipment. I can forsee two years back-log of work in the first month.Reply Quite frankly, I haven't looked at this. At the present time the work is under the START program but I suppose we will have to look at possible changes. Anything under the START program has first line priority.B. Thorndycraft Will the briquetting of samples be automated as well? Pinson MiningReply No, not at this point. Our polish section laboratory is first-class and can turn out 18 polish sections a day which is more thar we can handle.B. Thorndycraft With the capability of this machine to operate in a hands-off manner perhaps it could start to look for the 5 micron gold particle in tailings?Reply I have such a program using a wave-length spectrometer rather than the energy dispersive. The wave-length spectometer is about 10 times as sensitive and would scan the section much faster. A one inch diameter polished section would be scanned in about 7 hours for anything 1 micron or larger."

Jan 1, 1984

By L. Telfer

Summary During Palaeozoic time, there were deposited in the Canadian Rockies four beds of phosphate rock, ranging in age from Mississippian to Jurassic. Two of these beds are of probable economic importance if some means of separating the phosphate from the gangue can be devised. All the more important beds of phosphate rock so far discovered are just behind the front ranges of the Rocky mountains, within fifty miles of the prairie lands of Alberta. Mining conditions are favourable, with an abundance of timber and ample power available. The phosphate beds are all of the sedimentary type, and they all occur, apparently, at the same stratigraphic horizons over a wide area. The conditions necessary for deposition evidently occurred at several different periods in geological time, and were widespread. The most important factor appears to have been the condition of the land surface surrounding the basin of de-position. Both oolitic and nodular phosphate were laid down under nearly similar conditions. Introduction Following the discovery of phosphate rock in Idaho and Montana, search was commenced in Canada to determine whether formations of similar age in the Canadian Rockies carried similar beds of phosphate. The most widespread search has been that undertaken by the mines department of the Consolidated Mining and Smelting Company of Canada. The following paper will discuss some of the results of this exploration.

Jan 1, 1933

The SART (sulfidisation, acidification, recycle, and thickening) process is an effective way to separate copper and cyanide from each other in the waste stream of gold processing plants using cyanidation. Factorial experimentation has been conducted to create models of copper recovery, cyanide recovery, acid addition, and oxidation I reduction potential during SART. Economic analysis of the resultant models showed that SART is best operated with a sulfide to copper molar ratio of around 0.56, a pH of 4, and a minimised cyanide to copper molar ratio. The experiments also showed that thickening time may have drastic impacts on SART performance.

Jan 1, 2011

By James H. C. Martens

Among the many interesting problems of the pre-Cambrian of the Canadian Shield is that of the origin of certain types of gneisses which are intimately associated with the granites on the one hand and with the metamorphic rocks of known sedimentary origin on the other. The observations recorded in this paper on the structure and composition of these ancient rocks found in a small part of northern Quebec may help to lead to a clearer understanding of the way in which they were formed and also constitute a contribution to the regional geology and petrography of a district for which little detailed information is available. The area considered is located near the Ashuapmuchuan, or Chamuchuan, river about 180 miles north-northwest of the city of Quebec, and therefore well within the Canadian Shield. Although most attention was devoted to the rocks along this river from the 57th to the 70th mile above its entrance into Lake St. John, a few observations on other localities to the north and northwest of that lake will be included. The field work was done in the summer of 1924 in cooperation with L. W. MacNaughton, E. S. Roberts, and B. M. Shaub, all of Cornell University. The party ascended the Ashuapmuchuan river by canoe and spent about a month near the mouth of Stacker, or Brochet, river, the outlet of the lake of the same name, returning by way of Mikoasas river. The writer wishes to express his obligation to his associates for their co-operation in the field and for their permission to publish the results. He is especially indebted to B. M. Shaub for the photographs of rock outcrops. Professor A. C. Gill g:ive many suggestions which were helpful in the laboratory study of specimens and in the preparation of this paper.

Jan 1, 1927

By V. Nudo, R. del Villar, A. R. Laplante

"Fine iron ore recovery from the tails of Les Mines Quebec Cartier was investigated using Reichert trays and spirals. The effect of feed rate, density and splitter setting on the performance of rougher, cleaner and recleaner stages of a 2DS tray assembly was determined using 2- and 3- factorial experimental designs. The tray concentrate, assaying 27% Fe, was further upgraded by spiral to yield a concentrate assaying 55% Fe. Further laboratory scale testing showed this material to be easily upgraded to 65-66% Fe with high Fe recoveries.This paper presents the metallurgical results of the three tray stages. The model used to predict the performance of a full recovery circuit is then described. Simulation results are presented and their reliability assessed. Finally, an economic evaluation of the proposed scavenging circuit is summarized.INTRODUCTIONThe Mount Wright plant (UWP), located near Fermont, Quebec, processes daily 130,000-150,000 tonnes of iron ore assaying between 27 and 33% Fe, to upgrade it with three stages of 44.5 cm pitch GEC spirals to 66% Fe, while rejecting approximately 80,000 tonnes assaying between 6 and 11% Fe (1-3). Heavy liquid separation (at 3. 3 g/mL) of the plus 37 µm fraction (+400 mesh) of the tails reveals that a significant fraction of the iron is in the sink product, below 150 pm (100 mesh), as shown in Table 1. Also shown is the iron grade of the sink and float fractions. The high grade of the fine sink indicates that hematite ls well liberated below 105 µm (150 mesh), as previous studies have shown (4,5). The iron grade of the floats is very low in the fine size range, but increases with increasing size above 105 pm, because of incomplete liberation. Overall, two thirds of the plus 37 µm iron ls in the sink product, which constitutes less than 10% of the total tail."

Jan 1, 1987

By J. Jankovic

Numerous advantages have been recognized for solid oxide fuel cells (SOFCs) operating at temperatures of 500-700°C. However, there are several issues related to low temperature SOFCs, such as high electrolyte resistance and high electrode polarization. One of the routes to enhance the electrode performance, particularly for the cathode, is to use new materials with optimized microstructure. In this work, the plasma-spraying technique, recognized to have several advantages over presently used deposition techniques, was used to deposit cathode materials onto ceramic and stainless steel substrates to obtain highly porous structures. Cathode materials with composition of Lao 6Sr0.4Co02Fe0 8O3 (LSCF) were employed in the powder form. The LSCF was prepared from powder precursors with different pore formers and binder levels, or from already produced, single-phase LSCF. The (La0.8Sr0.2)0.98MnO3 (LSM) cathode material was also processed for comparison purposes. The deposition process was developed to obtain coatings with good bond strength, porosity, film thickness and residual stresses. The phase and microstructure of deposited materials were characterized using XRD and SEM.

Jan 1, 2005

By K. Hanumantha Rao, A. Javadi

Our recent studies revealed that the sulfide minerals in contact with water during grinding produced hydrogen peroxide (H2O2) where the amount of H2O2 production by the minerals found to be in the order of pyrite > chalcopyrite > sphalerite > galena. The H2O2 effect on the oxidation of pulp components and its influence on the concentrate grade and recovery in flotation have been studied and the results have been presented and discussed in this paper. Studies have also been carried out to build correlation between percentage of pyrite in the concentrate, grinding conditions and concentration of OH•/H2O2 in the pulp and as well of controlling the formation of these species through known chemical means for depressing the generation of the oxidant. Flotation tests using a complex sulfide ore with the same reagent scheme that is being used at Boliden concentrator in Sweden but with the addition of i) collector and depressant, ii) Na2S reductant and iii) inorganic (EDTA) and organic (TETA) surface modifiers, during grinding stage have been performed to judge the beneficial or detrimental role of H2O2 on the selective flotation of sulfides. The results demonstrate that the selectivity of metal sulfides against pyrite increases with increasing generation of H2O2 in the pulp liquid. H2O2 is also found to be a better oxidant in chalcopyrite-galena flotation separation than the commonly used K2Cr2O7.

Jan 1, 2016

By H. J. McQueen

Aluminum was hot worked at 400 - 500°C and strain rates (e ) of 0.004 -0.1s-1, under reversing strains (c) of 0.5 to 0.2 or 0.5 to 0 and also advancing from 0.5 to 1 or 0.5 to 5. Under similar test conditions for different parts of the strain paths, the average measured flow stresses are found to agree with each other. In the forward and backward strain path tests, the almost identical steady state plateaus affirm the occurrence of dynamic recovery (DRV). On reversal of strain direction at constant e , there was generally negligible Bauschinger effect. In specimens annealed at 400°C, static recrystallisation (SRX) was followed microstructurally. mainly by disappearance of elongated grains with serrated boundaries because the new grains were only little a finer than the old due to low strain energy. The only influence of reversing strain path observed was the effect of change of grain boundary area as grains elongated or returned towards equiaxed. In optical microscopy, elongated grains with serrations and deformation bands confirmed DRV in forward path specimens. In reverse path specimens, equiaxed grains were gradually restored with retention of serrations and bands. In low magnification polarized optical microscopy, grain alignment increased with strain for forward path specimens; whereas it decreased in reverse path ones, supporting DRV. Orientation imaging microscopy (OIM/SEM) revealed that elongated grains are broken up as deformation bands rotate during the forward path and that grains return to equiaxed appearance on backward straining. Comparative studies using optical microscopy in polarized light (POM), OIM/SEM and transmission electron microscopy (TEM) revealed that while subgrains remain equiaxed and constant in size and character during the forward and backward paths, the fraction of low angle facets decreased while that of high angle grain facets increased with increasing strain; these are coupled with a fairly low fraction of medium angle boundaries. The results contribute to the understanding that dynamic recovery in aluminum maintains sub-boundaries with low misorientation but as grains elongate and more subgrain become adjacent to grain boundaries the fraction of high angle boundaries rises (with backward straining it was vice versa).

Jan 1, 2007

By J. Bednar, R. R. Rogers, W. Dingley

"Zinc is by far the most important metal used for protecting steel from the ravages of corrosion, and cadmium is also used extensively for this purpose. These metals are applied by electrodeposition in cyanide baths when a particularly good appearance and high throwing power are required. One great disadvantage in using these baths has been the decrease in cyanide concentration and the increase in carbonate concentration that takes place during the plating. Another disadvantage has been the development of serious embrittlement in high-strength steels. The present authors have developed new cyanide baths for electroplating both zinc and cadmium on steel. These baths are stable in composition during plating, they have not produced appreciable embrittlement in the high-strength steels that have been investigated up to the present time, and they permit the use of considerably higher plating current densities. In addition, they produce extremely fine grained coatings that are attractive and have excellent adherence and covering properties. Brighteners can be used in the plating baths if bright finishes are required."

Jan 1, 1967