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By Alan S. Lock

Large scale feasibility studies for the establishment of oil-seed and cellulose producing crops on mine tailings have been successfully conducted over 1 growing season with the purpose of these crops to be used as feedstock to the biofuels industry. An acid sulphide tailings impoundment in Copper Cliff, Ontario and a near neutral pH goldmine tailings impoundment in Timmins, Ontario were both tested by amending half hectare plots to approximately 1 m thick with residual biosolids from the pulp and paper industry and growing canola and corn on these plots. Full scale agricultural equipment was used to cultivate seed and harvest the plots to prove the full scale feasibility of farming on these biosolids. The vegetation development, growth, yield, quality and composition were assessed to identify the best species that would maximize biomass development for feedstock to the biofuels industry and carbon credits for the mining industry. Groundwater, biosolids and tailings chemistries were investigated to identify potential deleterious impacts of degrading organic matter on tailings metal mobility. Preliminary hydrologic investigations using moisture sensor profiles elucidate potential conservation of water in amended plots. Tailings amended with biosolids have the potential to provide the mining industry with carbon credits and supply feedstock to this new industry while reclaiming brownfields to a new level, utilizing industrial and municipal organic waste material.

May 1, 2009

By A. P. Annan, C. Vaughan, J. L. Davis

"The increase in the price of gold in the last decade has led to a significant increase in placer gold exploration around the world. Placer deposits occur in depressions along ancient river and stream channels. In many instances these channels have been covered with materials from subsequent erosion or glacial activity. Use of high resolution geophysical techniques to map the bedrock and soil strata can improve the probability of finding the placer deposits. The buried bedrock surface is often the factor controlling deposition. Ground probing radar (GPR) and seismic sounding are complementary high resolution techniques which can be used to map bedrock topography and soil stratigraphy. Current radar instrumentation operates best in coarse grained soils. Penetration depths of up to 30 m have been attained, and stratigraphic horizons have been mapped with spatial resolutions of better than 0.5 m. Although its spatial resolution is considerably lower than radar, seismic refraction achieves superior penetration in electrically conductive environments such as clay and silt soils. The seismic refraction method thus proves to be complementary to the radar method. The seismic reflection technique is analogous to the radar method. Current seismic instrumentation and energy sources however, provide limited spatial resolution and do not permit the use of seismic reflection for reflecting horizons lying at depths of less than 20 m to 30 m.This paper discusses the use of both radar and seismic methods for placer exploration. The radar and seismic techniques, the field methods, equipment, and data displays are presented. Field examples illustrate the high resolution mapping capabilities of the techniques. The radar data agree very well with the borehole data, and in fact they sometimes detect subtle soil strata variations associated with changes of permeability that were not initially observed in the borehole logging. The radar method can give a continuous profile of water table and bedrock in sandy soils. Seismic soundings are necessary to differentiate between the bedrock and water table reflections observed by the radar."

Jan 1, 1987

By D. Marcotte

The Rock Quality Designation (RQD) is a standard scalar measure of rock quality used in common rock mass classification systems (e.g. RMR, Q system). RQD is measured along diamond drill holes. RQD interpolation between holes is nontrivial. Despite the inherent limitations of drill hole data and the local complexities of structural geology, it is often the only information available for mining and major civil engineering projects. Therefore, maximizing the usefulness of this data is warranted. We derive a correction for directional effects that help reduce the bias and improve the accuracy of the estimations. The correction is derived with the aid of numerous simulations. It relies on simple information, the angle between the joint normals and the borehole axis (JO). A reference direction is identified as the borehole direction with smallest JO. A multiple linear regression model based on JO statistics in the various boreholes defines the correction model. The corrected RQD values are then interpolated. It is shown the method enables reducing the bias on RQD estimation by 50% and improves the accuracy of the estimates by 30%. The corrected RQD values show stronger spatial continuity than the raw values. The benefits of estimating the RQD indirectly by using joint frequency measures are also assessed.

May 1, 2003

By M. Vaccarini

In this paper a possible methodology to supplement a predictive control approach is reported. The benefits deriving from the application of a predictive control on complex buildings lay on its capability of adapting in advance to the conditioning needs of indoor environments. In fact, the mere reactive control is usually affected by response delays, mainly determined by latency intrinsic in systems and by the massive nature of buildings, which slows down their response to changeable inputs. Hence, systems are too often solicited at their maximum power to recover against comfort deficiencies, and high consumptions are had. This paper reports on the application of a predictive approach to the Passeig de Gracia (PdG) metro station in Barcelona, which is a considerably high energy demanding building and where ventilation systems are used to control both comfort and air quality. Although an extensive simulation for estimating energy savings obtainable through that approach is currently ongoing, in this paper we detail the several components which make up a ?predictive control framework? and we perform a preliminary demonstrative simulation. In particular, the whole setup is formed by: a detailed model of PdG, which simulates the station?s ?real state?; a control model, which optimizes a given cost-function; probabilistic predictive models to infer the future state of the systems, given the assumptions on the control actions by the control module. The outcomes of this paper show that the procedure is applicable and preliminary results over a short simulation horizon of half a day are reported.

Aug 1, 2013

By Peter N. Calder, Louise H. Michaud

"An interactive mine planning package has been developed to aid with the tasks involved in generating dragline mine plans. This package employs recent advances in PC-based,3D computer graphics and 3D geologic modelling. A Gridded Seam Model (GSM), capable of modelling rugged topography and multiple coal seams, including folding and faulting, is used to generate the geologic database This model is then integrated with an interactive graphics mine planning system in order to develop one model and one database for the generation of the mine design, the depletion of the coal reserves and the removal of waste material.As well as offering large potential saving in the time required to carry out the planning tasks, the system offers immediate visual feedback to the planning engineer. This can greatly aid in the conceptual understanding of complex geology and mine plans and can allow for the evaluation of a number of mining options within a reasonable time frame.IntroductionThere are a large number of variables that must be taken into account during the development of a dragline mine plan. This is especially true when developing a mine in mountainous terrain, where there is a lack of continuity of the geology and topography over the mine site. Until recently, the complexity of dragline mine plans has prohibited the development of a universal mine planning package that is applicable to all geologic and topographic situations. The majority of the commercial programs that are presently available to facilitate dragline mine planning have been developed for specific mine properties or are limited in the coal geology and mining methods that they can simulate (Brown and Clifford, 1983; White 1983; White and Jones, 1984; Sadri and Lee, 1982; Dagdelen, 1979)."

Jan 1, 1993

By D. F. VanDine, H. George

"The possibility of spoil pile failure at the Kara Kara bauxite strip mine, Guyana, South America, is of major concern to the mine operators. The current mining technique requires the continuous operation of an 11 ms bucket capacity walking dragline on top of 18 metres of freshly spoiled uncompacted overburden material consisting of varying mixtures of kaolinitic clay and quartzitic sand. A field biased geotechnical study of undisturbed overburden and corresponding spoiled material has identified site-specific, non-linear correlations between vane shear strength, standard penetration resistance and spoil pile composition. Readily available geological exploration borehole logs has enabled a composite clay isopach map of the entire mining property to be drawn and critical areas to be zoned according to expected slope stability. Stability has been assessed using simple hand calculation techniques. Use of the resulting stability map provides the mine operators with a means of forecasting the need for appropriate preventative measures at varying stages of mine development, throughout the life of the mine.A similar investigation procedure could be employed at many presently operating and future strip mines.IntroductionThe Kara Kara bauxite stripe mine is located at Linden within the bauxite belt of Guyana in South America. The mining property covers a total area of 88 hectares of flat to gently sloping ground of which some forty per cent is being actively mined or being preparatorily stripped of overburden, prior to eventual mining (George and Gordon, 1979). The regional climate is tropic and humid. Temperatures vary from 16°C to 38°C and yearly rainfall averages 2600 mm, with at least 55 per cent of this precipitation occurring during the 'wet season' months of May to July and December to January."

Jan 1, 1983

By H. J. Meyer

"A hydrostatic elevation difference meter has been developed for use in measuring elevations along gravity traverses. Elevations of stations 100 feet apart can be obtained at a rate of 1/2 mile per hour and to an accuracy better than 1/3 foot. This can be done along traverses which have not been cut and chained. The instrument is durable, lightweight and constructed of materials which will withstand any temperature encountered in field work.It is believed that this device will more than double the rate at which gravity surveys over mining prospects can be carried out."

Jan 1, 1972

By Wencheng Gao

An attractive way to beneficiate magnesium chloride and aluminum chloride is to prepare Mg-Al spinel, an excellent refractory material. Mg4Al2(OH)14?3H2O, the precursor of spinel, can be prepared using a co-precipitate method from aqueous MgCl2-AlCl3 solutions. The co-precipitation process of magnesium-aluminum from acidified chloride solutions by using NaOH or NH4OH as base neutralization agent was studied. Co-precipitation was conducted from different mixed solutions ? at initial CAl=0.0625M and Mg/Al molar ratio from 0.5 to 10, the temperature range from 30 to 90 °C. The effect of other parameters, including base type, method of base addition, base addition rate, aging time, background electrolyte and concentration were also investigated. The co-precipitation process was monitored by potentionmetric(pH) measurements. The experimental pH curves were characterized by two platforms separated by a steep jump in pH at Mg/Al molar ratio 0.5~6. The first platform was centered at about a pH of 3.8 and the pH of second platform was varied with different conditions. When the Mg/Al molar ratio was up to 6~10, the first platform in pH was almost disappeared. Furthermore, the shapes of pH curves were also affected by base type, base addition rate and method of base addition. Experimental results showed that the first platform in pH was connected with Al precipitation, and the second platform was involved with Mg. The final co-precipitates were characterized by XRD, TGA-DTA, particle size analysis, SEM and TEM. We found both Mg/Al molar ratio and temperature proved to be the key parameters controlling the formation of Mg4Al2(OH)14?3H2O phase. At solution Mg/Al ratio=0.5~4, the main precipitate phase was Bayerite (Al(OH)3) admixed with Mg4Al2(OH)14?3H2O; at Mg/Al ratio=4~6, the main phase was Mg4Al2(OH)14?3H2O admixed with some Mg(OH)2; while from Mg/Al ratio=6~10, the systems were mixtures of Mg(OH)2 and Mg4Al2(OH)14?3H2O.

Oct 1, 2011

By E. Nurminen

Thermal transport properties of copper flash smelting flue dust have been investigated. Such values of the dust are needed to correctly model the process and to optimize its heat recovery performance. Dust accretions on heat recovery boiler walls may have a significant influence on the boilers heat transfer efficiency. Measurements of the thermal transport properties have been made for industrial flue dust and for pure sulphate components. The measurements have been conducted at temperatures up to 400 °C and the effect of porosity on these properties has also been investigated. The results indicate that the flue dust and the sulphate components are effective thermal insulators and the dust build-up on the boiler walls is likely to greatly decrease the heat transfer efficiency of the boiler.

Jan 1, 2007

By Barbara Kirby

Mining Industry HR Challenges Mining industry needs to hire approx. 100,000 workers by 2020 Attraction and retention of talent in all occupations Mobility of skilled workers between mine sites 70 percent of employers expect labour shortages over the next 5 years. Largest shortages: -physical sciences and engineering occupations -trades and ?undesignated? occupations ?Undesignated? Occupations ?Undesignated? Occupations -eg. mill operators, production / development miners and heavy equipment operators More than 20,000 workers will be needed by 2020 in the undesignated occupations and another 11,500 tradespersons Turnover rate for trades and undesignated occupations at mines is high: 8.3% compared to 5.6 % for all other occupations There is no system to recognize the skills of high-demand undesignated occupations

May 1, 2010

By He Zhexiang

The settlement properties of tailings modified by flocculants were investigated at the Shizhuyuan Mine, with the aims to screen for the most effective flocculants and the optimum dosage rates for tailings sedimentation. The settlement rate was used as the indicator of effective tailings sedimentation. Calcareousness and three polyacrylamides (F1, F2 and F3) were selected for settlement property evaluation. The results proved that sole use of calcareousness or any of the polyacrylamides had no apparent effect on the tailings sedimentation, while a remarkable acceleration of sedimentation could be observed with a combined addition of calcareousness and polyacrylamides, among which the addition of polyacrylamide F2 together with calcareousness is the most effective. The optimum dosage rate of F2 and calcareousness is 50g/t and 3kg/t respectively. The density of tailings slurry has an effect on sedimentation at the early settlement stage, with lower density generating quicker initial settlement.

May 1, 2007

By P. R. A. Andrews

"A sample of flotation feed from Bakertalc Inc., High water, Quebec was subjected to flotation evaluation to improve the recovery of talc. A number of alternative frother/collectors and depressants as well as flotation parameters including pH, conditioning time, frother/collector concentration and pulp density were assessed. In addition, the possibility of using a size coarser than that currently employed for flotation (95% minus 50 um) was investigated.As far as possible, a laboratory duplication of the present circuit arrangement was folio wed so as to minimize the cost of any changes. The best results obtained were a concentrate analyzing 95.96% acid insol for a recovery of 65.98% after four stages of cleaning. With recirculation of cleaner tailings, the recovery would be higher.The possibility of using an alternative method, based on the natural ability of talc to float unaided by a frother/collector, was briefly explored with encouraging results.IntroductionBakertalc lnc ., located in the eastern townships at Highwater, Quebec, Is approximately 140 km east of Montreal near the Vermont, U.S. border. Originally called Baker Mining and Milling Co. Ltd., it has produced pulverized talc products since 1938(1 ), although records show that talc was mined in the area as early as 1871(2). Feed to the mill originally was obtained from local deposits, but since 1952 the van Reet mine near south Bolton, approximately 25 km from Highwater, has been the source of ore .In 1957 a Raymond high -side roller mill was installed which enabled production of a greater range of talc products and, in 1960, new crushing equipment and a dryer were added. Other additions to the mill were the introduction of wet magnetic separation, although this was later discontinued, and flotation to produce high-grade talc concentrates."

Jan 1, 1985

By G. Q. Zhou, H. C. Liang, X. D. Zhao

"This study describes the strain behavior in vertical shaft lining (VSL) embedded in thick soil deposits and its application in assessment of concrete deterioration. The observed strain in VSL continuously decreased companied by a sinusoidal fluctuation due to the influences derived from negative skin friction (NSF) and temperature. The increase in strain increment between peak and trough at each year and compressive strain level as the servicing time continued and VSL depth increased implies that the concrete strength was attenuated, and this attenuation was significantly dependent on the existing compressive strain level in VSL. The reliability of the proposed approach was validated by Schmidt Hammer Technique (SHT) – based concrete strength, and is applicable in concrete assessment and then fracturing prediction of VLSs in thick soil deposits.Concrete strength, Field monitoring, Strain behavior, Vertical shaft liningINTRODUCTIONOver 100 VSLs in Southeastern China subjected to an unpredictable fracturing as shown in Figure1, and there are over 1,000 VSLs embedded in thick alluvium su?ering from challenges of damaging and potential fracturing (Cheng, Yang, Zhou, Li, & Hu, 1993; Zhou, Cui, Lv, Huang, & Chen, 1999; Li & Li,2005). Therefore, a reliable assessment of these VSLs is significant to the normal servicing of mine shafts and the recycle of underground space when these mine shafts were closed.The continuous increasing of NSF induced by the drainage of water–saturated deposits well interpreted such extensive fracturing phenomenon, and it is universally regarded as the governing indicator to determine the VSL stabilization (Cheng et al., 1993; Zhou et al., 1999). Based on this recognition, the fracturing prediction and VSL strengthening according to the field monitoring on hydrogeological characteristics, servicing environments, and mechanical behaviors of VSL were carried out (Zhao, Zhou, Zhong, Zhu, & Liang, 2009; Liang et al., 2009; Xie, Lv, & Wu, 2014). As known, the compressive strain level in VSL and the in–situ strength of VSL concrete were the main factors to perform such fracturing prediction. However, the existing studies in literatures were limited to the strain accumulating or releasing behaviors (Zhao, Zhou, Zhao, Kuang, & Hu, 2017), and lack of considering the VSL concrete strength and its attenuation. In this reported study, the in–situ monitoring data on the strain in typical VSLs and the VSL elevations between 2004 and 2014 were initially analyzed. Then, an observed strain behaviors–based approach was developed to quantitatively evaluate the VSL concrete deterioration."

Jan 1, 2019

By J. A. Russell

MR. M. W. Boom: I would like to congratulate Mr. Russell on his fine paper. One very good point which has always appealed to me is the smooth working of a steam hoist as compared with electrical. He does not mention the steam hoist at Springhill which has been working there for a good many years. MR. S. R. NEWTON: I have read with a great deal of interest the paper presented by Mr. Russell on the development of haulage engines in the mines of the Dominion Steel & Coal Corporation. He is to be congratulated on having produced a comprehensive article showing, step by step, the various improvements that have been made over the years in the design of such engines. I am quite in accord with Mr. Russell's statement that the positive tooth clutch can have too many teeth, and also that the method of driving a sliding clutch hub of any design should be by means of a hexagon or octagon on the shaft. Where the clutch hub does not of necessity slide on the shaft it can be pressed on and keyed to the shaft in the normal manner. With regard to the 'Cramp' internal-expanding jaw-type clutch, while it is true there are more moving parts than with the clutch consisting of a ring with internal cut teeth and a driver having a fewer number of teeth as .described by Mr. Russell; there are compensating advantages to the internal expanding jaw-type of clutch. The V shaped profile of the teeth permits of engagement of the clutch with very much less 'jockeying' of the drum. This is particularly the case in vertical-lift mine hoists, where it may be necessary to engage and disengage the clutching mechanism at frequent intervals.

Jan 1, 1944

By Sang-Kyun Woo

The electric power conduit (EPC) in Korea has been constructed since 1978. Facing the challenge of safety and sustainability of the EPC, it is urgent to develop an inspection strategy and maintenance system for the structure based on the concept of life-cycle management. This paper introduces the newly developed mobile inspection and diagnostic system of the EPC. The novel aspect of this particular system is the integration of non-destructive mobile inspection techniques with BIM (Building Information Modeling) and LBS (Location-Based Service). BIM is an ideal tool and platform for developing an inspection and diagnostic system, and RFID (Radio Frequency Identification) is a useful tool to construct USN (Ubiquitous Sensor Network) for LBS. The goal of this research is to establish an EPC inspection and diagnostic system concept based on BIM and LBS using RFID. In this research, a BIM model of OPENTBM tunnel for EPC will be established to show the integration of 3D CAD with the inspection data. An EPC?s maintenance database, which includes the deterioration types of the structure, inspection records, and repair methods, was designed to interact with the BIM. The system will be implemented by the BIM with the related database, in which the construction geometry and all related information are stored. The proposed system was designed to utilize the inspection and diagnostic system under the USN environment using RFID in EPC directly.

Aug 1, 2013

By Jas. E. Thomson

"The Omega mine is in McVittie township in the Larder Lake area, Ontario. Production at the mine commenced in 1936, and, until the end of 1946, ore milled amounted to 1,558,604 tons, from which 207,074 oz. gold and 28,205 oz. silver, valued at $7,585,470, were recovered. The mine workings extend to a depth of 1,975 feet.GEOLOGYThe geology of the mine has been described in detail by C. P. Jenney (l) and the writer (2). The general geology and structure in the vicinity of the mine is discussed on an earlier page in this volume. The rock formations found in the mine workings are indicated on the accompanying plan and section (Figs. 1and2). They consist of an intermingled, south dipping complex of volcanics, sediments, and secondary talc-chlorite schists and carbonates. The carbonatized rocks, which are often referred to as 'dolomite' in the Larder Lake camp, are siliceous-carbonate replacements in the talc-chlorite schist zones. In places they contain green mica, probably fuchsite, and are cut by a stockwork of quartz veinlets and stringers. A stock of syenitic intrusives lies south of the mine workings.STRUCTUREThe main structural features are indicated in Figs. 1 and 2. The formations and orebodies have a pronounced southerly dip, which flattens with depth. The talc-chlorite schist and 'dolomite' zones are part of the Larder Lake fault or 'break' on which there appears to be very large displacement. Evidence throughout the district would indicate that the south side moved up and, in the case of the Omega mine, the thrust may have been distributed throughout the several intensely sheared zones. This slice faulting could account for the repetition of sediments and volcanics. An alternative possibility would be original interbedding of volcanics and sediments."

Jan 1, 1954

By L. A. Melis, J. W. Rowson

"Cluff Mining has successfully operated a gold recovery plant at its Cluff Lake operation in northern Saskatchewan to recover gold f rom Phase 1 uranium leach tailings. The operating circuit consists of tailings repulping, grinding, cyanidation, carbon-inpulp, gold recov ery, and cyanide destruction by acidification, volatilization and re-neutralization. The process is described and operating data and metallurgical results from the operation are provided.INTRODUCTIONCluff Mining, a Saskatchewan partnership, is owned 20 per cent by Cameco and 80 per cent by Amok Ltd. /Ltée. (Amok), manager and operator of the partnership.The current operation includes the Phase II uranium mining and milling facilities, located at Cluff Lake, 700 km north of Saskatoon, capable of processing 300 000 tonnes o f ore to produce about 4 000 000 lb UPs (1500 tonnes of uranium) per year.The Phase I operation was initially established to process the very high grade ""0"" uranium orebody from 1980 to 1983. The leach tailings from the Phase I mill operation were found to contain elevated level s of gold . These high gold values were partially due to the gravity pre-concentration step included in the uranium recovery circuit, and to the naturally high levels of gold associated with the uranium mineralization in the""0"" orebody .During the Phase I operation some 6475 tonnes of leach tails were produced and stored in a total o f 2916 large concrete containers (vaults). This method of storage was, at the time, deemed to be the preferred method of temporary storage for the tailings.This temporary storage of high-grade gold tailings facilitated the reclamation and reprocessing of the leach tail s for gold recovery. The primary reason for reprocessing the Phase 1 leach tails was to provide for long-term permanent disposal of the material as an admixture with Phase II tailings in the Cluff Lake tailings disposal area. Although there was limited tonnage, the high gold content in the material made the in stallation of a gold recovery circuit economically justifiable."

Jan 1, 1989

By E. Larsen

Marine tailings disposal may in some cases be the best solution to one of mining’s major environmental problems. The public standing of this solution is poor, partly because of past bad practices. Among the tailings problems spreading of super-fines and toxic substances stand out. The two are often interrelated as heavy metals, insoluble to sea water, tend to adsorb on fines and spread piggyback on them. Only one paper seen, has addressed the mineralogy of fine particles in suspension. The topic was a secondary tailings deposit. Studies on the sedimentation of fines in large river estuaries show that different minerals sediment sequentially as the salinity of the river increase. Mineralogy in the particle size range where particle separation takes place, has so far, naturally been in focus for the mineral processors. Next to nothing is known about the fines which may cause environmental problems. Tailings disposal has, due to its complexity, to a large extent been taken over by specialists in other fields, biologists, engineering geologists, chemists. The basics of the subject ought also to be given more input by the mineral processing community. A drawn out battle about tailings discharge into some fjords has taken place in Norway. The detractors focus at fine particles (could be dangerous nanoparticles) spreading and emphasize the effects. Calculation is simple: 5 million tonnes tailings annually discharged, containing 1 wt. % < 1µm determined by laser diffraction, results in 50 000 tonnes of nanoparticles let loose in the environment. The industry`s difficulty to answer, is lack of basic research on this topic. Test work to develop a methodology to address the problem is described. One thing the mineral processors know is that final tailings may be comprised of tailings from separate separation processes, with different properties, some of which may require special treatment. One tailings stream from a Norwegian mine is investigated in such a context.

Jan 1, 2016

By M. Maeda, H. Sasaki

"Precious metals such as platinum, palladium, and rhodium are commonly used for automotive catalyst converters. To recover these metals with lower environmental load and cost, exposure to zinc vapor was proposed as a pretreatment prior to acid leaching. Alloying with zinc is expected to enhance dissolution of precious metals and reduce the amount of toxic chemical agents required for the leaching. This study examined the effect of the alloying pretreatment using model catalysts. Catalysts were immersed in leaching solutions for a predefined time with or without zinc vapor pretreatment, and the amount of dissolved metals was then evaluated. INTRODUCTIONAutomotive catalysts account for large portions of the world consumption of platinum (Pt), palladium (Pd), and rhodium (Rh) (Butler, J., 2011). Because of their limited production and high prices, recovery of the precious metals from spent catalysts is obviously an important issue. A representative structure of an automotive catalytic converter can be described as a monolithic ceramic support with a honeycomb structure which is coated with porous oxides such as those of aluminum (Al2O3), cerium (CeO2), and zirconium (ZrO2) (Heck & Farrauto, 2001; Matsumoto & Shinjoh, 2007). Small particles of precious metals, originally several nanometers or less, adhere to the oxides.Typical recovery processes for precious metals from scraps are shown in Figure 1 (a)-(c) (Habashi, 1997; Yoo, 1998; Shibata & Okuda, 2002). Precious metals can be recovered by using non-ferrous smelters as Figure 1 (a) shows. Smelted along with metals such as copper (Cu), precious metals and ceramics in the scraps are absorbed into the metal phase and slag phase, respectively. Because the metals separate from Cu as anode slime in successive electro-refining, such a process can recover precious metals as co-products of Cu. However, in order to prevent negative effects on the principal process, a specialized procedure is needed. Figure 1 (b) is a specialized approach in which scraps are melted at elevated temperature with Cu called the Rose process. Here Cu works as a collector metal, and the absorbed precious metals are then concentrated by oxidation of Cu. Such a process can separate precious metals from ceramics constituting catalyst converters. Smelting at high temperature, however, requires extensive equipment as well as a high amount of energy. On the other hand, hydrometallurgical processes may be effective to separate precious metals from ceramics into an aqueous solution, because chemical agents can act on these metals selectively (Figure 1 (c)). Leaching of precious metals, however, requires strong acid and oxidizing agents because of their corrosion resistance; this makes liquid waste disposal and the large environmental load controversial. To solve the problem, a metal vapor pretreatment was proposed (Okabe, Yamamoto, Kayanuma, & Maeda, 2003a, 2003b; Kayanuma, Okabe, Mitsuda, & Maeda., 2004; Kayanuma, Okabe, & Maeda, 2004; Itoh, Kayanuma, Miyake, Kimura, & Maeda, 2005). A flow diagram of the process using zinc (Zn) vapor is shown by Fig. 1(d). Exposed to Zn vapor, precious metals are expected to form alloys which dissolve more easily than pure precious metals, thus reducing the use of chemical agents and environmental load involved with successive leaching. In previous research (Sasaki, Miyaki, & Maeda, 2010; Sasaki & Maeda, 2010, 2012), dissolutions of precious metal alloys formed by Zn vapor treatment were examined in hydrochloric acid (HCl) using an electrochemical method, and it was confirmed that these metals dissolved at higher rates from the alloys than from their pure states (Figure 2). In this study, the availability of the alloying pretreatment was demonstrated by testing on model catalysts in leaching solutions."

Jan 1, 2012

By Yusuke Yamamoto, Mineo Asano

"The present study investigated the texture transition during secondary recrystallization in the AA5182 sheet. During the initial stage of annealing, the texture showed a weak Cube orientation as the primary recrystallization texture. During the secondary recrystallization with abnormal grain growth, the area ratio of the {hkl} <011> orientations increased by consuming the other orientations. The texture transition was calculated by the 2-D Monte Carlo simulation with the misorientation dependency. When the higher grain boundary mobility was set in the specific range of the high angle misorientation, the orientation preferential growth of the RW {100} <011> orientation was reproduced. However, other {hkl} <110> orientations could not be well reproduced by the misorientation dependency.INTRODUCTION Crystal orientation and texture are important factors for aluminum sheet products from the standpoint of mechanical property, formability and isotropy. The recrystallization texture results from the orientation preferential growth from the rolling deformation microstructure and the texture (Alvi, Cheong, Suni, Weiland, & Rollett, 2008). Texture development has been a topic of intense research for decades with advances in analysis methods, e.g., orientation mapping (OIM) and computer simulations (Fjeldberg & Marthinsen, 2010; Ivasishin, Shevchenko, Vasiliev, & Semiatin, 2006). The grain boundary characteristic is considered to be a key for the orientation preferential growth. In the case of the recrystallization from the deformed microstructure, not only the grain boundary characteristic, but also the dislocation density and the subgrain size affect the nucleation and the grain growth (Engler, Löchte, & Hirsch, 2007). On the other hand, in the case of secondary recrystallization, the dislocation density and the subgrain size can be ignored and the effect of the grain boundary characteristic can play a significant role in the grain growth. There is intense research about the texture development during secondary recrystallization in aluminum alloys and it was reported that coarse {hkl} <011> grains were formed during the secondary recrystallization (Suk, Shin, & Huh, 2006; Rios, & Gottstein, 2001). However, the mechanism of forming the {hkl} <011> grains has not been fully clarified. In the present study, the effect of the grain boundary characteristic on the orientation preferential growth was investigated by EBSD analysis and Monte-Carlo (MC) simulation."

Jan 1, 2018