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By Kazuteru Tozawa, Robert G. Robins

"The stability of calcium arsenate is discussed in relation to the possible misuse of lime in the treatment of gold processing waste waters. Stability diagrams have been derived and experimental results cited to show that calcium arsenate has a higher solubility in neutral to alkaline solution than has previously been recognized and this solubility is further enhanced by the presence of carbon dioxide, bicarbonate or carbonate.IntroductionThe removal of arsenic from gold mine waste waters has been of interest for more than thirty years, but with the recent emphasis on clean water standards there has been renewed activity in relation to that problem. The processing of gold-bearing sulphides which contain arsenopyrite and other complex arsenic sulphides is well established. Initial roasting to oxidize the sulphides leaves the arsenic in the form of both arsenic and arsenic, in which forms it is soluble in the subsequent leaching stage. Further oxidation of the leach liquors is required before the well-established procedure of precipitating calcium arsenate with lime, which is carried out despite an immense lack of knowledge of the calcium-arsenic-water system.The solubility product and free energy of formation for Ca3(AsO4)2, which are to be found in recent and reliable sources of data, originate from the work of Chukhlansev, whose experimental determination of the concentration of calcium from the solubility of calcium arsenate in solutions of various pH yields the results plotted in Figure 1. This is the work which has resulted in a wide acceptance of the ""insolubility"" of calcium arsenate and the use of lime to stabilize arsenic in that form.Laguitton attempted to further elucidate the chemistry of the lime addition method for treating arsenical waste waters from gold processing operations. The low solubility product for Ca3(AsO4)2 was the basis for his examination of likely chemical equilibria in the system. Laguitton and other workers have not considered atmospheric carbon dioxide as an important component in this system."

Jan 1, 1982

By R. del Villar, A. R. Laplante

"This article presents four grinding simulation programs, written in Applesoft BASIC. The firs t two calculate residence time distributions (RT Ds) for open and closed loops mills. The third program calculates the select ion functions from the RTD, breakage function and particle size distribution (PSD) o f the feed and discharge. Two linear regression programs are also included to calculate the breakage function. These results are used in the fourth program to simulate continuous or batch grinding kinetics.The modelling approach presented is the size discrete, time continuous matrix formulation presented by Reid (1965) from concepts originally proposed by Epstein (1948). It is at the present time the most widely accepted phenomenological model of grinding kinetics and is standard textbook material (Austin et 01., 1982; Kelly and Spottiswood, 1982, p. 152). The concepts of RTDs and tracer testing originated from chemical engineering theory and practice, and are well presented in Leven spiel (2n d Ed . 1972 , Ch. 9) .Applesoft* was chosen because it is compatible with many micro computers. It is also one of the simplest and least powerful BASIC versions. Thus it can easily be adapted to other more complex BASIC versions.Open Loop Residence Time Distributions (Program RTDOPEN)As mixing, channelling, stagnation and short-circuiting all affect slurry motion in tumbling mills, transport characteristics are very complex an d cannot be derived from fundamental principles. Fortunately , as grinding follows first order kinetics, transport characteristics for the purpose of grinding simulation ca n be represented by the RTD of the slurry phase . It is normally determined using liquid tracers, as it has been demonstrated and is commonly accepted that in industrial ball mill s, the RTD of the so lid phase is particle size independent and equal to that of the liquid phase."

Jan 1, 1985

By Mario Gerards, Axel Wellendorf, Arulnesan Rajesh

"In times of increasing energy cost and global demand for improved machine technology, the optimization of industrial mineral processes in terms of efficiency and production cost is an important factor when choosing industrial equipment suppliers. Of course this applies for screening machines, feeders and distributers as well!Besides of the ability of a screening machine for being adjustable to changing requirements during the production process itself, it becomes more and more important to choose the correct screening machine type, peripheral equipment for arising screening tasks and to optimize the overall design of the screening machine starting at a very early stage.The different types of screening machines bring many advantages and disadvantages with them. The selection of the correct type of screening machine can improve the flow rate, energy, efficiency, yield, quality, output, availability and decrease the maintenance costs and structural steel work.The machine optimization has to be a consecutive process in which at any time results of simulation and “real-life measurement” are compared and the findings are implemented in machine development and design. As an example, it is possible to reduce machine weight and reinforce the steel structure of a screening machine at the same time, which enables the manufacturer to use smaller drives for the screen.This paper will present the methods ANSYS and 3D Solid Works used at RHEWUM GmbH for this way of optimizing machine design and construction and examples for results gained from this continuous improvement process."

Jan 1, 2016

By Michael K. O’Leary, William D. Coplin

"Risks from political instability and government policies restricting equity ownership, local operations and transfers of payments affect the profitability of foreign mining ventures. More than seat-of-the-pants judgments and old-boy networks are required to anticipate these risks and to take actions appropriate to offsetting them. A system for making political forecasts, called the Prince System, and a series of charts relaying risk s to a production of key minerals will be presented.IntroductionFirm s with extractive operations outside their home country do not have to be told that political stability and government decisions play a big role in the success o f their operations. The takeover of copper firm s in Chile during the Allende administration in 1971 and the recent decision by Venezuela to reduce Reynolds Metals equity share in a smelting operation from 50% to 28% are two examples of hundreds of events that have determined the profitability of extractive operations over the past decade. Both risks and opportunities for international firms seeking to produce and market raw materials are heavily affected by political conditions. While news of political events travel much faster than in the past and host governments are more clever in shaping the risks as well as the opportunities, politics has always been part of the mining business.What has changed is the need to be more systematic in approaching the assessment of political conditions and how it affects business. The increasing costs of extractive operations, the need for long-range planning, the importance of financial arrangements and the world-wide scope of man y firm s' activities require that the assessment be updated continuously and be comparable across different countries and different types of investments. Political risk analysis, the assessment o f macro-political changes and specific governmental decision s on the operations of extractive industries needs to become as systematic and integrated into corporate decision -making as economic analysis has become over the past two decade s."

Jan 1, 1983

By N. Shi, T. G. Joseph

ABSTRACT One-twentieth-scale field trials for conventional and concept dipper designs were compared to mid- and ultra-class-sized conventional dipper performance. Digging effort was used as the performance indicator for comparison. It was shown that linear relationships exist between dipper capacity, suspended hoist load, and peak hoist load. A ratio of conventional and concept dipper performance at the 1/20th scale was then evaluated to allow prediction of the performance of an ultra-class concept design using an independent ultra-class conventional dipper dataset. The outcome indicated a peak hoist requirement of 15.5% less to achieve the same production as the conventional design.

Jan 1, 2011

By J. Moyes

The Intec Copper Process is an internationally patented hydrometallurgical process for the extraction of pure copper and precious metals from sulfide concentrates. Developed and proven in Sydney, Australia at a cost of US$15m over the last ten years, the Intec Copper Process is now ready for commercial application. The Intec Copper Process has several notable advantages over both smelting and other hydrometallurgical processes. Starting from a base of substantially lower capital and operating costs than any other conventional or developing process, the Intec Copper Process is economically viable at capacity levels as low as 15,000tpa-Cu, and capable of accepting low grade and metallurgically complex concentrates. Precious metals are recovered within the Intec Copper Process circuit, without the need to re-treatment of the environmentally stable solid residues. The Intec Copper Process offers the lowest energy consumption of the available technologies, with no liquid emissions or production of noxious gases. Unlike smelting, sulfur is recovered in the solid residues in elemental form.

May 1, 2002

By D. P. Fenton

The Phelps Dodge El Paso Rod Mill produces approximately 2.4 million pounds per day of copper rod from a casting and rolling operation. The newly formed rod is treated to remove mill scale and oxides using a sulfuric acid and hydrogen peroxide solution which is bled periodically when the copper concentration reaches 30-35 g/L. The bleed solution is heated to 75° C to destroy the residual peroxide. Copper is then recovered in a 270 cell EMEW electrowinning plant. Clean acid is also regenerated in the EMEW plant and is returned to the rod cleaning circuit. The EMEW plant commissioned in January 2006, has two operators and replaces a copper sulfate plant with fourteen operators. The EMEW plant has a capacity of 1700 kg/day of cathode copper at 2.1 kWh/kg copper deposited. The electrowinning plant operates in closed circuit with the rod mill returning up to 2600 kg/day of sulfuric acid resulting in zero discharge. Use of dimensionally stable anodes (DSA®) ensures that the acid quality is maintained in the closed loop operation. The operating conditions, performance and plant experience of the EMEW copper and acid recovery plant are discussed.

Jan 1, 2007

By G. Molloy

The purpose of this paper is to demonstrate the value of applying continuous improvement, in particular 5S and standard work, in an underground environment. 5S and standard work are two aspects of Lean manufacturing that have been applied in many industries. At Vale Canada Limited, the focus is to first stabilize the process, commonly through the use of 5S, standard work and other continuous improvement techniques. In parallel with building an engaged workforce, these approaches aim to incrementally stabilize and improve a process. 5S is an employee-driven, systematic methodology to reduce waste in all its forms through attaining, maintaining, and improving workplace organization. Identified as a foundational part of any improvement process, 5S aims to remove wastes that impact on the overall efficiency of the area. Standard work is used to formulate a common approach to how tasks are carried out to ensure consistency. Standardization involves identifying, establishing, and following the best method. The aim is to eliminate the variation that can occur when there is not a pre-defined established standard. Demonstrating the value of 5S and standard work in an underground environment will be achieved by first understanding the overall concept of Operational Excellence and continuous improvement as practiced within our operations. The paper will then cover a real application of 5S and standard work within the underground environment at Thompson, Manitoba.

Aug 1, 2013

By James D. Bittner

Separation Technologies, LLC (ST) has developed a processing system based on triboelectric charging and electrostatic separation that provides the mineral processing industry a means to beneficiate fine materials with an entirely dry technology. The environmentally friendly process can eliminate wet processing and required drying of the final material. The process requires little if any pre-treatment of the material other than grinding and operates at high capacity ? up to 40 tonnes per hour by a compact machine. Energy consumption is low, approximately 1 kWh/tonne of material processed. Since the only potential emission of the process is dust, permitting is typically relatively easy. In contrast to the other available electrostatic separation processes that are typically limited to particles greater than 75 µm in size, the ST belt separator is ideally suited for separation of very fine (<1 µm) to moderately coarse (300 µm) materials with very high throughputs. The triboelectric particle charging is effective for a wide range of materials and only requires particle ? particle contact. The small gap, high electric field, counter current flow, vigorous particle-particle agitation and self-cleaning action of the belt on the electrodes are the critical features of the ST separator. The high efficiency multi-stage separation through charging / recharging and internal recycle results in far superior separations and is effective on fine materials that cannot be separated at all by the conventional electrostatic techniques. Since 1995, this triboelectric process has been extensively used for the beneficiation of coal fly ash with eighteen separators in place and over 130 machine-years of operation at locations in North America and Europe. ST has also installed separators for the beneficiation of industrial minerals in North America and Europe. The technology has been successfully applied to the beneficiation of a variety of minerals including calcium carbonates, talc, barite, and potash.

Aug 1, 2013

By A. Alfantazi, E. Asselin

"The corrosion of commercially pure titanium (CP-Ti) was studied from room temperature up to medium temperature (~160°C) under conditions relevant to medium temperature chalcopyrite leaching processes. The corrosion rates were measured by immersion and electrochemical tests in sulfuric acid. The influences of chloride, cupric and ferric ions on the corrosion rate and behavior were also investigated. Corrosion of the CP-Ti did not account for the total current density measured by linear polarization tests. The corrosion rates of CP-Ti under medium temperature leaching conditions were surprisingly high. The corrosion rate measured in ferric containing solution at 160°C was approximately 20 mm/yr.INTRODUCTIONTitanium exhibits excellent corrosion resistance in many aggressive environments because of the formation of a very chemically stable, highly adherent, and protective oxide film on its surface (Mitsuo et al., 2002). Because titanium is the only metal available at a reasonable cost that resists the high temperature corrosive slurries in many leaching processes, it is often chosen as autoclave liner material where it is subjected to severe conditions of acidity, temperature and pressure (Grauman and Say, 2000).A number of distinctly different hydrometallurgical processes for the pressure leaching of chalcopyrite have been developed and patented by various companies and they can be classified into low, medium and high temperature regimes (McDonald and Muir, 2007). For example, chalcopyrite concentrate may be processed at medium temperatures (115-175°C) and pressures of 800-2200 kPa (Dreisinger, D., 2006; Sahu and Asselin, 2011). The lixiviant may contain 20 to 55 g/L sulfuric acid, 8 to 12 g/L chloride ions, 10-25 g/L Cu2+ (Jones, 1995, 1997, 1999), and less than 1 g/L Fe3+ (Defreyne et al., 2005). The amount of these additions is determined by the grade of the ores and details are shown in Table 1."

Jan 1, 2012

By J. Borlee, F. Sorrentino, A. Fleischanderl, M. Gimenez, W. Gebert, U. Gennari

Large quantities of solid by-products are generated by the steel industry and other important activity sectors in Europe (power plants, car dismantling companies, urban incinerators) with no or very limited potential for direct recovery. In the frame of a multi¬national project supported by the European Union, a consortium has been created to develop a treatment process able to turn these by-products into valuable metallic and mineral products. VAI has been responsible for the design, erection and start-up of the pilot plant for the new metallurgical process and for the execution of the test campaigns, with the targets defined together with the partners. Up to now, 9 campaigns comprising 60 heats have been performed successfully. By-products from C-Steel and stainless steel plants, as well as fly ash and auto shredder residues, have been used and defined products such as hydraulic binders for cement, metallurgical powders for De-S practice and recycled metal phase have been produced. The mineral products were positively assessed under industrial conditions. Results from cement tests and secondary metallurgy are reported, as well as a detailed characterization. The economic value of the products, credits from avoiding dumping and significant savings on CO2 emissions make the new process economically very attractive.

Jan 1, 2004

By N. Morrison, E. J. Rogans, A. J. Macintosh, N. Schoeman

"The design of carbon-in-pulp (CIP), and carbon-in-leach (CIL) adsorption circuits has essentially remained unchanged since the early days of the carbon process for gold recovery. For CIP circuit the pulp residence time is traditionally fixed at one hour per contactor with a carbon concentration of between 15 and 20 grams per litre, and the counter current carbon transfer rates are in the region of 15% pulp recycle. For CIL, the pulp residence time is usually three hours per contact or, with lower carbon concentrations ( 5 to 10 grams per litre).The drawbacks of using the counter current CIP/CIL adsorption circuits are discussed using modeling developed for CIP/CIL plant design. Counter current CIP/CIL, circuits are then compared with the carousel method of adsorption circuit design.The use of equipment suitable for the carousel approach is discussed which is, the AAC cylindrical and pumping (MPS) screens, the AAC pump-cell plant and launder designs.Finally, two plants at the Vaal Reefs Gold Mining and Exploration Company that use carousel adsorption circuits, namely the Vaal Reefs No. 1 Gold Plant, a CIL plant with stepped contactors, and the Vaal Reefs No. 2 Gold Plant, a CIP using a very short residence time (AAC pump-cell) are discussed."

Jan 1, 1998

By H. C. Cooke

Geological examination of the underground workings of the Horne and Aldermac mines during the summer of 1927 has brought out the following facts: (1) That the ores tend to replace bodies of breccia or tuff rather than massive lava or dyke material; (2) That the faulting and folding at the Horne has had a pronounced effect in localizing the ore-bodies; (3) That there is a tendency in cert?-in cases for ore-bodies to be localized beneath gently dipping dykes, which acted as impervious roofs; (4) That there is a great difference in age between the chalcopyrite part of the ore-bodies and the pyrite-pyrrhotite portion. A statement of the development to date at the Aldermac mine is also included in the paper. ALDERMAC MINE The Aldermac property is made up of eight claims in the western half of Boischatel township, Quebec, including 747 acres in all. The mine itself is approximately three miles, 25 chains from the west boundary, and four miles, 55 chains from the north boundary, of the township.

Jan 1, 1928

By W. F. McDermott

This paper covers the development, construction and operation of a 53-mile slurry pipeline operating in Tasmania, Australia. Special development techniques are discussed, as well as the operation of this line and its impact on transportation from remote areas.

Jan 1, 1970

By P. E. Weidmark

"PART 1-Published PapersAllcott, G.A., and Archibald, D.E.; ""Description of pillar behaviour at Heath Steele Mines""; Can Min Metall Bull; 74:834:80-87; 1981.Baar, C.A.; Discussion of Theme 1: ""Physical properties of intact rock and rock masses""; Proceedings 3rd Congress Intnl Soc of rock Mechanics; 3:32-33; 1979.Baar, C.A.; Discussion of Theme 1: ""Physical properties of intact rock and rock masses""; Proceedings 3rd Congress Intnl Soc of Rock Mechanics; 3:37-38; 1979.Baar, C.A.; Discussion of Theme 1: ""Physical properties of intact rock and rock masses""; Proceedings 3rd Congress Intnl Soc of Rock Mechanics; 3:38; 1979.Baar, C.A.; Discussion of Theme 1: ""Physical properties of intact rock and rock masses"" ; Proceedings 3rd Congress Intnl Soc of Rock Mechanics; 3:41; 1979.Baar, C.A.; Discussion of Theme 1: ""Physical properties of intact rock and rock masses""; Proceedings 3rd Congress Intnl Soc of Rock Mechanics; 3:42; 1979.Baar, C.A.; Discussion of Theme 1: ""Physical properties of intact rock and rock masses""; Proceedings 3rd Congress Intnl Soc of Rock Mechanics; 3:46; 1979.Baar, C.A.; Discussion of Theme 2: ""Tectonophysics""; Proceedings 3rd Congress Intnl Soc of Rock Mechanics; 3:60; 1979.Baar, C.A.; Discussion of Theme 4: ""Underground openings""; Proceedings 3rd Congress Intnl Soc of Rock Mechanics; 3: 116; 1979.Baar, C.A.; Discussion of Theme 4: ""Underground openings""; Proceedings 3rd Congress Intnl Soc of Rock Mechanics; 3:116-117; 1979.Baar, C.A.; Discussion of Theme 4: ""Underground openings""; Proceedings 3rd Congress Intnl Soc of Rock Mechanics; 3:117; 1979.Baar, C.A. &apos;; Discussion of Theme 4: ""Underground openings""; Proceedings 3rd Congress Intnl Soc of Rock Mechanics; 3:118-119; 1979.Baar, C.A.; Discussions (2) of Theme 4: ""Underground openings""; Proceedings 3rd Congress lntnl Soc of Rock Mechanics; 3:119; 1979.Baar, C.A.; Discussion of Theme 4: ""Underground openings""; Proceedings 3rd Congress Intnl Soc of Rock Mechanics; 3:120-121; 1979."

Jan 1, 1982

By A. Gillis

"In order to obtain the equipment necessary to automate the equipment it was decided that the Department of Mines and Milltronics would jointly survey the circuit. This survey involved a metallurgical study by the Department of Mines and Milltronics took sound recordings during manual operation, checking in circuit bottle necks and determining the number of sensors that could be applied.The conveyer is driven by 2 PIV drives, each has a variable speed of 3/ 1. The cross conveyer that feeds directly into the rod mill feed chute will contain an automatic sampler and will eliminate the necessity of stopping the belt feeders to take samples. At present, hourly samples are taken from this point and the circuit is upset and cycling results.The Adequate scale is very close to the rod mill to totalize and thereby give a continuous indication and the second purpose is to take a signal from it and control the solution addition to the rod mill.A pneumatic positioner was obtained and put on the scale which produces a 3 tp 15 psi signal which is proportional to the actual tonnage going across the scale. This signal was fed to a bias loader which was mounted on the control panel. From there the operator can set the amount of solution that is wanted by the rod mill. No matter what the feed rate is, the signal coming from the bias loader will follow it automatically. This in turn goes to the pneumatic solution valve (1 ½” ) and the solution goes in with the feed to the rod mill. This is only part of the solution required for dilution since the rest of it is used as a force jet for the feed to the rod mill."

Jan 1, 1965

By Michael McClintock, Bern Klein

"The high pressure grinding roll (HPGR) is a relatively new comminution technology that is gaining popularity for providing energy efficient solution to hard rock mining operations. A significant barrier to increased adoption of HPGRs is the present requirement for large amounts (excess of 2 tonnes) of sample for pilot testing, which may not be possible for most early stage projects. Three methodologies have been developed at NBK Institute of Mining Engineering at the University of British Columbia that may be used for sizing design optimization of HPGR circuits. All three methodologies use a MTS pistonpress to simulate HPGR comminution. These tests are capable of providing information regarding energy consumption, energy breakage relationship, reduction ratio, and product size distributions. In a period of slow economic development, these methodologies are critical to allow the industry to cost effectively understand the operational benefits of HPGR implementation. This paper examines previous test work done at UBC, as well as the development of an HPGR and piston press database for use in sizing and budgeting of HPGR circuits.INTRODUCTIONCurrently, the mining industry faces several challenges due to falling commodity prices and escalating costs. This has applied pressure for operations and projects to reduce costs and improve project economics. In addition engineering and metallurgical budgets have shrunk as companies try to conserve cash. Improvements and optimization of milling and comminution circuits is one area project economics may be significantly improved. By considering alternative comminution technologies such as the high pressure grinding roll (HPGR), energy operating costs may be greatly lowered. Many have begun to implement HPGR crushing as an alternative to semi-autogenous grinding (SAG) mills, including KGHM and, Sierra Gorda, and Freeport Mc-MoRan’s Cerro Verde operation. However, implementing new technology for companies with little or no HPGR experience may not be practical. An operator must consider both feasibility and economics of a circuit. Currently, consideration of the HPGR requires expensive pilot scale testing for which large sample sizes are needed. In addition, few laboratories are equipped for running pilot scale HPGR test programs. Furthermore, the results of pilot HPGR testing are dependent on the quality of the sample, which cannot represent variations across a deposit. In contrast, ball mills and SAG mills can be sized using the Bond Mill Work Indexes that require a small amount of sample which enable a number of different geological blocks to be tested to allow engineers to have a complete understanding of how the comminution circuit will perform for the life of mine."

Jan 1, 2016

By R. von Bonsdorff

Electrochemical and quartz crystal microbalance (QCM) methods were used to investigate the dissolution rate of gold in a solution similar to those utilized by the Outokumpu HydroCopper® process. The measurements were conducted in an electrolyte solution where [NaCl] = 2.8-280 g/L, pH = 1-2.5, [Cu2+] = 0-30 g/L and T = 70-95°C. According to these measurements, the solution flow has the greatest impact on the dissolution rate of gold in the HydroCopper® process. Under adequately acidic conditions (pH < 3), the dissolution rate of gold increases with increasing cupric concentration, increasing chloride concentration and increasing temperature. The results and trends observed compared well with the literature.

Jan 1, 2007

By G. Gagnon

"HistoryMining of the Schefferville iron deposits began in 1954 on completion of the 357 mile railway linking the mines and the St-Lawrence river port of Sept-Iles. Apart from crushing, no treatment of these ores was required before smelting. In the late 1950's, testwork began at schefferville to develop a process for upgrading the extensive lower grade deposits containing 51% iron with 15% silica (natural analysis). Engineering for a six million ton per year beneficiation plant using cationic silica flotation and the A-C grate kiln Began in 1970 and the first pellets were produced in mid-1973.Production requirements and operating difficulties have restricted capacity to approximately 85% of design but on going improvements are being made continuously to attain design capacity.GeologyThe sedimentary ore bodies of the labrador trough occur in a belt 5 to 10 miles wide and 60 miles long and contain 51 individual deposits varying in size from 1 and 60 million tons. The ores are classified into three main color groups."

Jan 1, 1981

By Y. Mudryk, D. Paudyal, K. A. Gschneidner, V. K. Pecharsky, M. Khan

"Rare earth intermetallic compounds are utilized commercially as magnetic and battery materials, electron gun electrodes, etc. Several of these intermetallics will be briefly discussed. There are many other rare earth intermetallic compounds which are not utilized industrially but have unusual properties which are of fundamental interest and may have future technological applications. Several of these materials are discussed as well.INTRODUCTIONTens of thousands of rare earth intermetallic compounds exist, but physical properties (primarily their magnetic behaviors), other than their crystal structures have been measured for only a small percentage of these materials. Among these are the commercially important compounds: Nd2Fe14B, and the SmCo5 – Sm2Co17 family – well known high strength permanent magnets; (Tb0.3Dy0.7)Fe2, Terfenol-D, a giant magnetostrictive material; LaNi5Hx a critical component of the rechargeable Ni metal hydride batteries; and LaB6 an electron emitter. There are, however, many other intermetallic compounds which are not utilized industrially, but none-the-less, exhibit interesting, and sometimes, exotic physical properties which are of fundamental interest and may have some future technological significance. These include: the giant magnetocaloric effect compounds Gd5Si2Ge2 and La(Fe13-xSix)Hy; the RCu and RAg families of ductile intermetallics; the mixed intra-lanthanide (R,R')Al2 compounds in which magnetic transitions disappear and reappear as one R is substituted for by R'; and GdNi which exhibits large dilations along two crystallographic directions and a larger contraction in the third direction at the Curie temperature resulting in zero volume change as GdNi orders magnetically via a second order phase transition.COMMERCIALLY IMPORTANT INTERMETALLICSNdFeB Permanent MagnetsThe Nd2Fe14B permanent magnets were discovered in 1984 independently in the USA and Japan. It is a ferromagnet and with proper heat treatment and processing Nd2Fe14B is the strongest near room temperature permanent magnetic material known today. This intermetallic compound is utilized as a permanent magnet in many applications, such as electric motors (e.g. the modern automobile contains up to 35 electric motors), spindles for computer hard disc drives, microphones and speaker magnets for cell phones and other audio equipment, direct drive wind turbines, actuators, and Magnetic Resonance Imaging (MRI) units. There are two kinds of NdFeB permanent magnets – bonded and sintered. The bonded magnets have a lower magnetic strength than the sintered magnet. The highest strength magnets are obtained by small substitutions of Dy (up to a maximum of 10%) for Nd, because Dy can significantly increase the coercivity and thus the energy product (a measure of the magnetic strength or hardness). The bonded magnets account for about 12% of the NdFeB market (~82 metric kt per year, containing ~20 kt/a of Nd). The NdFeB permanent magnet market is growing at a rate of about 15% per year. (Burzo & Kirchmayr, 1989; Kobayashi & Hirosawa, 2001; Coey, 2011)."

Jan 1, 2012