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By W. M. Silva, PAP. Miotto, M. A. P. Silva, V. P. Ramos, L. R. M. Bittencourt

The major cause of breakdown of anode baking furnace fluewalls is chemical corrosion, which leads to deterioration of the properties of the bricks. Subsequent deformation of the fluewalls occurs, and also extensive cracking of the lining is observed. The present work studies the major changes of the brick during the operation of the furnace, after 22, 60 and 90 cycles of baking; in two different regions: upper and lower. Due to excellent cleaning conditions of the butts, negligible amounts of fluorine were found in the bricks. The major contaminants found were carbon, sulfur and alkali compounds, all of them present in the anode baked during the process.

Jan 1, 2004

By Blandine Arseneault

The Raglan Mill had been in production for less than a year when the initial toxicity tests on the effluent revealed that it was defined as ?toxic? under regulations. Testwork was begun to address the fundamental reasons for the toxicity and a systematic approach was initiated to identify causes. Elimination of the problem presented a challenge once the main conclusion identified high dissolved solids as the principal culprit. In particular, normally benign soda ash (sodium bicarbonate) reagent additions used in milling, was identified as the main contributor to the problem. Following analysis of all requirements and safety considerations, a concept to recycle 100% of the mill process water was pursued. In addition to meeting regulatory requirements, this project would have numerous positive benefits to the operation, including reducing fresh water consumption and lowering costs.

Nov 1, 2002

By B. T. Lu, J. L. Luo, H. X. Guo

This paper investigated the synergistic effect in the slurry-erosion process of carbon steel. In line with the mechanisms of material loss, the synergism due to interaction of erosion and corrosion was divided into the corrosion enhanced by erosion and erosion enhanced by corrosion. The erosion-corrosion tests were conducted with A1045 steel in slurries containing silica sand. Experimental results showed that the rotating of the sample in corrosive media raised both OCP and corrosion rate, but the impingement of solid particles did not affect the corrosion current significantly. In the quiescent solutions, the Faraday's law gave a good prediction for the weight loss caused by corrosion but for rotating samples, the weight loss experimentally measured was virtually greater than that predicted by the Faraday's law, indicating that the corrosion-enhanced erosion could occur in corrosive fluids in absence of solid particles. A half-logarithm relationship was observed between the weight loss due to corrosion-enhanced erosion and the anodic current density.

Jan 1, 2004

By Y. C. Kim

This paper discusses Air Liquide's patented SPALTM (Surface Protection Air Liquide) technology and process for the inerting of coreless induction furnaces using cryogenic liquid gas. Air Liquide Canada Inc., in collaboration with Riverside Brass and Aluminum Foundry Limited (Riverside Brass), conducted plant trials to demonstrate the applicability of the SPALTM technology for copper-based alloys. Results showed that with SPALTM, Riverside Brass benefited from a significant increase in metal yield as the level of dross formation was drastically reduced. Together with the many other benefits of this technology, SPALTM demonstrated to be a non-negligible cost-effective solution to reduce metal production costs. In an effort to optimize the argon flow, different flow rates were used and the oxygen level above the metal bath was measured to pinpoint optimal flow. The results of metal yield, charge mix, dross formation, and melt temperature are compared with and without argon. The metal yield improvements are dramatic and calculated net savings are presented hereunder.

Jan 1, 2007

By J. Scalise

The paper covers a wide range of topics relative to filtration for continuous cast copper and aluminum. Subjects include system concepts, filtration concepts, system components, filter types, filter media selection, caster water filtration, coolant disposal, and recommended materials of construction.

Jan 1, 2007

Introduction Gold Mining is an Important Economic Activity in Canada n Total value added during 1990-99 was $15.5 bn n The gold price is an important factor in the value added process n The gold price affects gold mining output, profits, exploration expenditures, employment, etc. Some Factors that Affect the Gold Price n The value of the US Dollar affects the US Dollar price of gold: a weaker US$ correlates with a higher gold price n Supply affects the gold price: the higher the supply on the market each year, the lower the average gold price that year Central Bank Gold Sales n Yearly central bank gold sales add to supply, and affect the price of gold negatively n The negative impact on the price of gold reverberates through the Canadian gold mining industry n Despite the modest amounts, even Bank of Canada gold sales affect the Canadian gold mining industry

May 1, 2003

By Ch. Wenzl

Anodes must have a certain physical and chemical quality in order to provide uniform anodic corrosion and meet the requirements of electrorefining, i.e. to achieve a high current efficiency, low energy consumption, low amount of anode scrap and low effort together with high cathode quality. Various properties of the anodes can be influenced directly by the casting process, which is the interface of pyro- and hydrometallurgy of copper. The aims of anode casting ? high output and long mould lifetimes ? are not consistent with good physical anode quality. The physical requirements of an anode are smooth surfaces, uniform weight and thickness, minimal edge effects, minimal distortion of the body and the lugs, as well as a homogeneous microstructure, in order to achieve uniform dissolution behaviour. The chemical quality of the anode copper is a task of electrorefining operations, but the elemental distribution within the anodes, which should be as homogeneous as possible in order to provide uniform anodic corrosion, can be influenced by the casting process.

Jan 1, 2007

By Paul D. Young, Michael J. Allan

"The Con Mine has been producing gold continuously since 1938. In 1990 laboratory and pilot plant investigations began into the use of pressure oxidation for treatment of an arsenic trioxide waste product from two previous roaster operations on the property. This led to the construction in 1992 of a 96 ton/day plant to treat a mixture of arsenic waste and flotation concentrate from the existing mill. The plant was commissioned in the fall of 1992.This paper describes experience gained in the commissioning and initial operation of the plant. The unique aspects of treating a hazardous waste product are described including special operating procedures to satisfy environmental and employee safety concerns. The paper further describes modifications made to the process flowsheet, to operating procedures and to materials of construction in the early months of operation."

Jan 1, 1994

Polymer electrolyte membrane (PEM) fuel cell has increasingly become the potential choice of zero-emission power source for portable, mobile and stationary co¬generation applications. However, technical barriers need to be overcome before its widespread commercialization; cost reduction and performance improvement including reliability are the two key areas, that can be realized through better cell/stack design and improved understanding of the transport processes occurring inside the individual cells and stacks. In this presentation, we will provide an overview of various cell/stack models that are available in the literature, their strength and weakness, and then present a comprehensive multi-species, multi-phase and multi-dimensional formulation of a single PEM fuel cell, with consistent and systematic formulation for all the regions involved, including the solid bipolar plates, gas flow channels, the electrode backing layers, the catalyst layers and the electrolyte membrane. Such a detailed approach allows us to extract sufficient information to the analysis of a stack of PEM fuel cells. Stack model will be presented that investigates the various stack designs and flow configurations, and the optimal stack design based on the present study will be described. Also some innovative cell/stack designs will be featured.

Jan 1, 2005

By G. Roy

Interest in metal-hydrogen systems can be manifold. Small amounts of hydrogen adsorbed by elemental metals and alloys usually result in strong changes in the physical and mechanical properties of engineering materials. Overwhelmingly, these changes, viz. hydrogen embrittlement, are considered deleterious with respect to structural performance of engineering materials. However, the changes, often studied by metallurgists and metal physicists, can present new possibilities and applications. A prominent example is the recent interest in safe, solid-state hydrogen storage in metallic lattices. In a new laboratory in MTL, Ottawa, a study has been initiated to investigate the effect of "micro- and macro- alloying" of Al and Mg powders with hydrogen (in high-energy mechanical alloying mills) on plastic deformation in metal and metal hydride structures. It is anticipated that high-rate impacting and subsequent grain refinement in the mill will have an effect on hydrogen storage capacity in lightweight magnesium and aluminum alloys. First examination of the state-of-stress by X-ray diffraction in high-rate milled, nanostructured pure aluminum, aluminum milled with a solid surfactant, and aluminum or magnesium alloy milled with hydride and/or gas hydrogen will be presented.

Jan 1, 2005

By M. Askari, M. H. Parsa, S. Kashani-Nejad

Sarcheshmeh refractory consumption rate is about 7.5 - 8 kg/ton of the produced copper, which is almost three times higher than the other smelters practice. High destruction rate of tuyere zone refractory controls vessel productivity and operational lifetime. In this research with the aid of cold model and computational fluid dynamic (CFD), melt recirculation pattern and gas - liquid plume properties in the wide range of gas blowing conditions were studied. Results revealed that in addition to the well-known mechanical refractory destruction mechanism, fast tuyere zone refractory destruction could also be related to the cold bubble cluster formation near tuyere tips and introducing severe thermal shock to the refractory surface. Removing accretion and its strong bonds to the refractories around tuyere tip, causes refractory mechanical destruction and increases tuyere diameter. Increased tuyere diameter, in turn assists gas discharge in the bubbling regime. Air blowing in the bubbling regime result in the formation of big bubble clusters, bubble breakup and back attack occurrence which all found to have major impact on the refractory lifetime. Outcomes of this research, contributed to the plant converting management, blowing hardware and instrumentation improvement.

Jan 1, 2004

By W. Baranek

The paper describes activities undertaken for intensification of copper cathodes production in electro-refining plants of the Polish copper smelters: 'Legnica', `Glogów I' and `Glogów II'. In the 'Legnica' smelter, Outokumpu?Wenmec machine was used for preparation of copper anodes. Intensive studies were conducted in order to optimise copper electro-refining conditions. As the result of them, spacing between the electrodes was reduced to 99 mm, which enabled placing forty-one cathodes in each tank and increasing amperage from 10.8 to 13.0 kA. This modification resulted in the increase of electro-refining capacity to 103,000 tons/y. Intensification of the copper production at `Glogów II' by 18,000 tons/y became possible after development of new electro-refining procedures, including application of a regime of changes in electrolyte level during the cathode cycle, implementation of the changes in location of starting sheets relative to anodes, and in dimensions of the sheets, and modification in the shape of the anodes. Similar works have been performed at `Glogów I', which were concentrated mainly on defining of a new method of anodes preparation, modification of their geometry, determination of optimum current density, composition of a set of inhibitors and of a method of their introducing. The implemented solutions resulted in the increase in electro-refining capacity at `Glogów I' from 207,000 to 240,000 tons/y.

Jan 1, 2007

UBC Mining Department As an example ?35 Graduating ?14 with Jobs ?6 with Strong leads ?149 Undergraduate ?Projecting 43 second year students ?10-30 % Dual Degree

May 1, 2010

By Jian Li, V. Y. Gertsman, David C. Katz, M. Elboujdaini

Analysis of stress corrosion cracking (SCC) usually involves high-end analytical tools including scanning electron microscope (SEM) and analytical transmission electron microscope (TEM). In recent years, focused ion beam microscope (FIB) has found many applications in materials science fields. In this study, high-resolution FIB images have shown details of crack morphology and a plan-view TEM specimen containing the selected crack-tip was successfully prepared. The preparation of cross-sectioned samples containing crack tips was of paramount importance for subsequent TEM analyses.

Jan 1, 2004

By M. Rigaud, N. Zhou, K. Sankaranarayanane, X. Zhou

The effect of amount and type of dispersants on the rheological behaviour of bauxite-based low-cement castables has been studied in detail. The rheological properties: flow resistance and torque viscosity, as measured by a rheometer, are found to be strongly influenced by the amount and type of dispersants. In the present investigation, a mix containing sodium hexametaphosphate, at an optimal level, is observed to be theologically superior at the given experimental conditions.

Jan 1, 2004

By D. Kim

Kennecott operates one of the largest and most modern copper refineries in the world at Magna, Utah, USA. The inputs to the refinery are anodes produced at Kennecott Smelter, which has extremely high contents of lead and bismuth. In order to minimize undesired effects in the electrolytic refining process, unwanted impurities, especially bismuth, must be controlled. This paper describes the process development of practicing state-of-the-art quality control and presents the pilot test results of using the MRT Technology for Bi production.

Jan 1, 2007

By M. Olper

Commercial copper plants utilising current best technology are tending towards ever increasing scale, the concentrate requirements of which cannot be serviced by a single mine. In such cases, raw materials are often sourced from different mines, which are often far away from the production plant and usually with very different ore compositions. These plants tend to use the traditional thermal processing steps of smelting, converting to blister, anode refining and casting to produce copper anodes that are then refined in a sulphate electrorefining operation. These thermal steps are in some cases troublesome and require the recycling of considerable quantities of material. A new process was developed taking advantage of the latest developments of the first thermal step of the classic loop, the smelting of copper concentrate to high grade matte or white metal using the well known AUSMELT Top Submerged Lancing Technology. The white metal and/or high grade matte product is converted directly to copper cathode and elemental sulphur using the ECUPREX technology. This approach provides an alternative to the traditional thermal steps of conversion to blister, thermal refining and anode casting, which, especially at small scale, can be expensive and problematic in terms of technical and environmental concerns. At first evaluation, this new process can be operated at low capacities, thereby, changing the traditional approach to copper production. Instead of taking the concentrate to the copper production plant, the copper production plant is taken close to the mine with some significant economic and technical advantages.

Jan 1, 2007

By Alireza Entesari

Removal of metal ions from effluents represents a significant technical challenge. As a consequence several industries, including mining, are faced with issues relating to removal of contaminant cations and anions from solution. This study evaluates three natural mineral materials referred to as basalt, scoria, and calcined shale for treatment of metal contaminated effluents by adsorption. Adsorption tests were conducted to asses the possibility of removing cationic and anionic metal ions from prepared solutions and mine water effluents. Sustainable production of industrial minerals requires that a diverse range of added value products be introduced.

May 1, 2006

By I. Cifuentes

Chemical and physical characterization of copper electrodeposits obtained on mesh and plate cathodes in conventional and reactive electrodialysis lab-scale cells have been carried out. The effect of Fe, Mn, Cl and guar on electrodeposit composition and morphology were determined by means of metallographies, scanning electron microscopy (SEM), atomic force microscopy (AFM), inductively coupled plasma mass spectrometry (ICP-MS) and Auger electron spectroscopy (AES). Each impurity influenced the deposit morphology in a different way (e. g. grain size, surface roughness). AFM proved to be a very effective tool for quantifiying and classifiying surface quality.

Jan 1, 2007

By L. W. F. Mackenzie

The influence of rolling temperature and annealing on the recrystallization and texture of magnesium AZ31 has been investigated. 100x125x6 mm AZ31 plate was cast in a permanent steel mould and then homogenized at 380°C. As-cast and homogenized microstructures were then characterized, and 35x30x6 mm specimens were machined from the homogenized material. Specimens were rolled up to 40% at temperatures between 25 and 350°C; selected specimens were subsequently annealed at 400°C. Following rolling, the microstructures were compared. The influence of rolling temperature on as-rolled texture has been demonstrated, and texture evolution has been evaluated following annealing. The recrystallization behavior has also been characterized. Optical microscopy, scanning electron microscopy and electron backscattered diffraction (EBSD) were used to characterize the microstructures of the alloys. X-ray texture analysis was used to investigate the texture in as-rolled and annealed specimens.

Jan 1, 2006