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This publication summarizes the research (in-house and contract projects) programmed by the Bureau of Mines for fiscal year 1985 (October 1, 1984-September 30, 1985) under its Health and Safety Technology Program. The objective of these projects is to provide an ordered and sequenced advance toward the Bureau's overall goal of providing the system technology required to create a more healthful and safer working environment for the Nation?s mining and minerals processing workers.

Jan 1, 1985

By David E. Morse

Burundi, a small central African republic located between Tanzania and Zaire, remained essentially a nation of small family farms in 1978-79 with approximately 95% of the population engaged in subsistance agriculture. Coffee and tea continued as the nation's major export commodities. Mineral exports, small tonnages of cassiterite, wolframite and bastnasite, accounted for an estimated 3% of total exports in 1978 and 2% in 1979, or $2 million2 in both years. Burundi's major mineral imports in 1978-79 were cement, iron and steel, and refined petroleum products. Abnormal weather conditions, a drop in world coffee prices in 1978, and the conflict in neighboring Tanzania and Uganda in late 1978 and early 1979 combined to re-strict economic growth in Burundi during 1978-79. The gross domestic product (GDP) posted a gain of 6.7% in real terms for 1978 and an estimated 2.5% for 1979 which was significantly less than the 13.7% recorded in 1977, a time of high world coffee prices. The manufacturing and construction sectors were hard hit in 1979 by the conflict between Burundi's eastern neighbors because of transport disruptions which made building materials and manufacturing inputs almost unobtainable.

Jan 1, 1981

By Leonard Obert, Wilbur Duvall

"INTRODUCTION 'The investigation reported herein is part of a comprehensive research program being conducted by the Metal Mining Research Section, Mining Division, Bureau of Mines, on pressure problems in underground mines. This program was initiated in 1937 and for the first 3 years was concerned primarily with measurement of the pressure on mine pillars and supports and their strength. 4/ 5/ During this period, investigations were conducted in both the laboratory and the field in the comparatively shallow load and zinc mines of Missouri and Oklahoma. As a result a seismic method of determining the pressure on mine pillars was developed.Before this research program was initiated, Chas. F. Jackson, chief of the Mining Division, suggested that rock under pressure might give rise to noises inaudible to the unaided ear - that is, subaudible noises. As a result of this suggestion, listening tests were made concurrently with the routine pressure measurements to see if any rock noises were present; with one exception, it was found there were no rock noises in any of these shallow mines. At the same time, pressure measurements disclosed that, with one exception, pillars were not under pressure amounting to more than 10 percent of the crushing strength of the rock. The one exception was a pillar in the Big John mine of the Eagle Picher Mining & Smelting Co. in the Tri-State district, which showed some physical evidence of failure, such as small cracks and spalling; it was reported that the pillar had been heard to crack or snap at intervals. Listening tests in this pillar disclosed that subaudible noises of comparatively small intensity were present and occurred at 1- to 2-minute intervals, on the average. Unfortunately, owing to the shortness of this pillar it was impossible to make any pressure measurements."

Jul 1, 1942

By MINE SAFETY BOARD

RECOMMENDATIONS OF THE UNITED STATES BUREAU OF MINES ON CERTAIN QUESTIONS OF SAFETY AS OF FEBRUARY 3 , 1933

Jul 1, 1933

By M. S. Seehra, R. S. Pandurangi

"The interaction of amorphous silica particles with several hydrogen bonding agents (H2O,, C2H,OH, C,H,NO) was investigated by monitoring the changes in the bulk and surface IR vibrational modes of silica using photoacoustic spectroscopy, It is argued that the intensity of the silanol band at 3747 cm-1 provides (an inverse) quantitative measure of the interaction of surface groups, along with the shift in the broad hydroxyl band, the interaction following the order C,H,NO > C2H2OH > H2O.The use of IR spectroscopy to study the adsorption on solid surfaces is well documented in the literature,"" For example, hydroxylation of a clean silica surface results in the formation of the free silanol group Si-OH, with a sharp IR band near 3747 cm-1. Further hydroxylation produces a broad band near 3500 cm-1, which is believed to result from various hydrogen-bonded silanol bands leading to a multilayered surface structure of few nm.3-6 Earlier studies had indicated a relationship between the surface silanol band and various chemical activities of silica such as cytotoxicity,7-9 catalysis,10-12 and others.13 Recent studies from our group14-in which the intensity of the silanol band and cytotoxicity of silica, heat-treated at various temperatures up to 1095°C, were investigated-have provided a strong correlation between cytotoxicity and intensity of the silanol band.Coating of silica by PVPNO (polyvinyl-2-pyridine N-oxide with the empirical formula C7H8N0), a strong hydrogen bonding agent, is known to reduce the cytotoxicity of silica, presumably by chemically blocking the silanol groups from phospholipids.15 This interaction of the hydrogen bonding agents with the silica can be studied by IR spectroscopy, and Knozinger16 and Rouxlet and Semples17 have used transmission IR spectroscopy to study the effect of various chemicals on the surface IR modes of silica. However, one of the major disadvantages of transmission IR spectroscopy is that the sample preparation (grinding and mixing with KBr and pelletizing) usually distorts the surface modes (see, e.g., Ref. 14) and there is always a doubt about the effect of the sample preparation on the measured properties, In recent years, photoacoustic (PA) spectroscopy has become the technique of choice for studying the IR spectra of samples in their natural state, since no sample preparation is necessary.18,19 Moreover, according to a recent paper,20 the relative intensity of the surface modes in PA spectroscopy of silica particles is much higher than that in transmission FT-IR spectroscopy. Consequently PA spectroscopy is ideal for studying the surface chemistry, In this work, we have used PA spectroscopy to investigate the interaction of three hydrogen bonding agents (C7H8NO, C2H5OH, and H20) with the silica surface by monitoring changes in the surface IR modes, Our results show that the surface IR modes get perturbed to a larger extent than the bulk IR modes in interaction with the hydrogen bonding agents, Moreover, whereas in the earlier studies, the shift of the broad silanol band near 3500 cm-1 was used as a measure of the interaction with hydrogen bonding agents,16,17 here we show that the relative decrease in the intensity of the sharp silanol band near 3747 cm-1 also serves as a quantitative parameter for the relative surface coverage and surface modification, Details of this work are given below,The Cab-O-Sil samples of silica used here were obtained from the Cabot Corporation of Tuscola, IL, In our earlier studies,14,20 we have shown these particles to be amorphous and about 0.05 am in size, For coverage of these particles with H20 and C2H50H, the following procedure was employed. About 5 mg of silica was mixed with 50 mL of the liquid (H2O or C2H5OH) and refluxed for one hour, The remaining liquid was allowed to evap¬orate to dryness and 1 mg of the treated sample was used to collect the PA spectra. In the case of PVPNO, the amount that binds to Cab-O-Sil is taken from the data on quar"

Mar 1, 1992

By H. F. MILLE, Charles A. Kumke

This paper describes mining operations at the Iron King mine of the Shattuck -Denn Mining Corp. in Yavapai County , Ariz . It is one of a series being prepared by the Mining Division of the Bureau of Mines on mining practices and methods in various mining districts of the United States . The mine and surface plant of the Iron King mine are situated in secs . 15 and 21 , T. 13 N. , R. 1 E. , about 20 miles by State highway 69 east by southeast from the city of Prescott and 1 mile southwest of the mining town of Humboldt on the Prescott -Mayer branch of the Atchison , Topeka & Santa Fe Railroad (fig . 1 ) . A l-mile truck haul brings the mill concentrates (lead and zinc ) to bins on a siding of this line at Humboldt ; the silver -gold bullion is handled separately . Some of the oldest residents in the vicinity of Prescott claim that the original location for the Iron King mine was made in 1880. The earliest recorded production was in 1906-1907 . During the first World War the mine produced fluxing ore for the Humboldt smelter . In 1936 the property was purchased under tax sale , and a mill (140-ton capacity ) was erected in 1938. The capacity of this mill was increased to 225 tons the following year , and a cyanide plant was added in 1940 to treat mill tailings . In 1942 the Shattuck -Denn Mining Corp. purchased the property . A new working shaft was sunk , mine development was speeded , and mill capacity was again increased . The predominating locally formation of this district is a pre -Cambrian schist known as Yavapai schist . The Iron King deposit , which carries gold, silver , lead , zinc , and copper , occurs as a series of lenses in a sheared zone of the pre -Cambrian schist . Down to the 600 -foot level the ore was mined and drawn by the shrinkage method . The cut -and -fill method was adopted for the lower levels . Waste rock for stope fill was provided by block-caving an area on the 600 level . Main haulage drifts were driven in the firm footwall , and crosscuts were driven across the mineralized zone at 100 -foot intervals . Grab samples taken from each car of every working place and channel samples cut every 5 feet in development work are considered sufficient for estimating ore reserves .

Jan 1, 1950

By E. J. Lintner

This paper is one of a series being prepared by the United States Bureau of Mines describing cloy reining, crushing, and grinding methods and costs at various operations throughout the United States. These Toners are designed to disseminate technical information regarding methods used. The cost tabulations represent local operating expenditures only and not total production casts. Although the publication of total production cants might not be advisable in sore instances, yet a knowledge of operating costs is essential to the technical discussion end study of the methods employed. The attention of the reader is specifically coiled to this differentiation in order that no misunderstanding of the scope of the cost tabulations shall ensue. The following report deals specifically with the methods employed by the Clay City Fire Co., Uhrichsville, Tuscarawas County, Ohio.

Jan 1, 1936

By Michael G. Zabetakis

The autoignition temperatures (A.I.T.'s) of natural and synthetic lubricants in air were generally found to decrease with increasing pressure. Of the two types of fluids, synthetic and natural, studied in some detail, the phosphate esters had higher A.I.T.'s at any pressure between 1 and 200 atmospheres than the mineral oils. Most of the A.I.T. data obtained in this study obeyed the relationship predicted by Semenov's theory of ignition.

Jan 1, 1962

By H. H. Yancey

In this information circular is presented a summary of the more important articles that nave appeared in the literature pertaining to the experimental work and to the commercial operation of the froth-flotation and Trent processes as applied to the cleaning of fine coal.

Jan 1, 1933

By Wallace E. Anable

This investigation by the Bureau of Mines was conducted chiefly on Cuban serpentine nickeliferous ores to determine whether these materials would be amenable to direct carbothermic reduction in an electric furnace to produce a low-carbon ferro-nickel. The project was carried out as one of several under a Memorandum of Agreement between the Bureau of Mines and the General Services Administration (Contract GS-OO-B (D)-152l). Two ore samples were received for this investigation. One was a mixture of nickeliferous serpentine from the North Ocujal, South Ocujal, and San Juan claims of the Nicaro Nickel Co. The other sample was a mixture of material from the Ramona and the Lorna Mulo claims of the Cuban Nickel Co. Most of the ore from the Ocujal-San Juan deposits and about 40 percent of the sample from the Ramona-Lorna Mulo deposits were calcined before smelting. The remainder of the sample from the Ramona-Loma Mulo deposits was smelted after drying to about 8 percent moisture. An arc-resistance, selective-reduction smelting technique was employed in these tests. Either bagasse alone or a mixture of bagasse and coke was used for reductants. No flux was used in the furnace charges.

Jan 1, 1957

By R. A. Guereco

Accurate measurements of physical dimensions of a section of stainless steel capillary tubing are presented and used to develop two final working equations for an absolute gas viscosimeter. The effects of pressure and temperature on these dimensions are considered. The internal surface finish and nonuniformity of the capillary bore are discussed, as well as entrance, kinetic energy, gas slippage, and gas compressibility correction factors.

Jan 1, 1967

By D. A. Reynolds, C. R. Holmes

The Bureau of Mines - American Gas Association ( EM - AGA) carbonization test has been used to determine the carbonizing properties of 66 American coals and a larger number of coal blends . A summary of the results obtained for the first 30 coals , including 6 blends , has been published ,4/ and results for individual coals have been reported as the investigations were completed . A bibliography of all publications pertaining to this work has been issued recently . Many of the coals were carbonized at 800 ° and 900° C. in two sizes of retorts ( 13- and 18 - inch diameters ) ; and , because the quality of coke is affected by changing the size of the retort , this report has been prepared to show the average physical properties of coke from the two sizes . This report also purposes to extend the correlation of the physical properties of coke with the rank of coal made by Fieldner and Davis in their summary of the EM-AGA tests on the first 30 coals .

Jun 1, 1942

By Benjamin W. Haynes

The Bureau of Mines, in cooperation with the National Oceanic and Atmospheric Administration (NOAA), has updated a 1977 NOAA report prepared by Dames & Moore entitled, "Description of Manganese Nodule Processing Activities for Environmental Studies." This updated report contains detailed flowsheets and descriptions of the five potential first-generation nodule recovery schemes now considered most likely to be used by industry; they are high-temperature gas reduction and ammoniacal leach, Cuprion ammoniacal leach, high-temperature and high-pressure H2S04 leach, reduction and HCI leach, and smelting and H2S04 leach. The first three processes are three-metal recovery schemes (Cu, Ni, and Co) with the option of Mn recovery from the tailings. The remaining two processes are four-metal (Cu, Ni, Co, and Mn) recovery schemes. All except the HCI process are assumed to use a nodule feed rate of 3 million tons per year (dry basis). Final metal products are Co powder and cathode Cu and Ni. A minor amount of Ni is also recovered as powder, and some Cu and Zn are recovered as mixed sulfides. Manganese in the four-metal processes is recovered as either manganese metal or ferromanganese.

Jan 1, 1983

By Carroll W. DeKock

Thermodynamic data for selected metal sulfates were critically evaluated and compiled as part of the Bureau of Mines program to provide a scientific base for use in developing new technology and predicting the feasibility of new processes. Values for Cp°, S°, H° - H°298, -(G° - H°298)/T, ?Hf°, ?Gf°, and log Kf as a function of temperature are given in tabular form. Thermodynamic data were compiled for VOSO4, Cr2(SO4)3, MnSO4, FeSO4, Fe2(SO4)3, CoSO4, NiSO4, Cu2SO4, CuSO4, CuO-CuSO4, ZnSO4, and ZnO-2ZnSO4, together with their stable hydrates.

Jan 1, 1982

By H. C. Fuller

Submerged combustion and inverse solubility methods were investigated as promising alternative means for crystallizing manganese sulfate from solutions produced by leaching manganese ores with either sulfuric acid or sulfur dioxide. Evaporation of water from typical manganese sulfate solutions by sub-merged combustion techniques enabled production of a slurry containing 32 to 39 pct MnSO4.H2O crystals suspended in a saturated solution of manganese sulfate. Such a slurry required further processing by thickening or filtration and drying to produce crystals of MnSO4.H2O. In a second approach, semicontinuous processing of manganese sulfate solu¬tions by thermal crystallization under pressure effected a recovery of 94.5 pct of the MnSO4.H2O as dry free-flowing crystals. Treatment of a solution containing about 100 grams manganese per liter at 189° C, produced a "barren" solution containing only 1.9 grams manganese per liter. Calculations made on comparable manganese sulfate solutions show that the heat requirement of the thermal crystallization method was about one-third to one-fourth that of the submerged combustion method.

Jan 1, 1966

These inspection standard have been prepared for use in the Federal inspection of strip mines producing, bituminous coal, anthracite, and lignite. This circular is a revision of the Safety Code for Strip Mining, which was prepared by the Bureau of Mines and employed as a guide for Federal inspectors. Numerous changes have been made in the original code to keep the in step with improvements in the industry. With continuing changes in mining methods and facilities some of these standards may become inapplicable and further revision may be advisable. Therefore, questions regarding these standards, and suggestions regarding new standards should be brought to the attention of the Bureau of Mines. Few States haves laws pertaining to strip mines, but where such laws do exist it is possible that some of the standards may conflict with them. In cases of conflict, the intent is not to advocate noncompliance with State laws, but to suggest reconsideration of such laws or safety orders.

Jan 1, 1946

By Margaret R. Egan

This Bureau of Mines report presents results from experimental studies on wood crib fires in an intermediate-scale fire tunnel. Gas concentrations, smoke particle characteristics, heat release rates, and ventilation rates were determined. These measurements form a data base for wood, which can be used with previous analyses for coal and future studies of other mine combustibles, to comprehend the potential hazards of these materials in underground mine fires. A knowledge of the combustion products emitted from these materials will benefit fire detection and control. Results show the changes in burning rate and heat release rate produced by different crib configurations and ventilation rates. Also included are the effects that the burning rate has on smoke characteristics and gas production.

Jan 1, 1986

By R. N. Love, L. Goldman

"INTRODUCTION When tannin is present in a boiler water, it causes certain difficulties in many analytical testing procedures because of its colloidal action in interfering with the removal of suspended matter by filtration and also because of the color it imparts to the boiler water.For example, in any test for phosphate in boiler water the first step is to filter out of the sample all sludge and suspended solids. Calcium phosphate in the sludge would give high results if not completely removed. If tannin is present in the sample, the sludge and suspended matter tend to pass through the filter paper so that it is difficult to remove it all. It may even be that tannin makes some of the suspended material in the sample completely nonfilterable. If this is true, it would be necessary to destroy or remove the tannin from the sample before filtering to get complete removal of calcium phosphate from the sample. In addition, if the test used is a colorimetric one, the tannin causes interference by its own color.As the calorimetric phosphate test is so convenient for control purposes and the use of tannin for boiler water treatment has become common, it has become necessary to develop suitable methods for employing the colorimetric phosphate test for boiler waters containing tannin. In this paper three different methods for doing this arc described and studied."

Oct 1, 1946

By B. W. Gandrud

In 1927 Coghill5 showed that there is considerable liberation of the iron oxide mineral from gangue when the Alabama red iron ores are ground to a size suitable for classification and tabling, but that there is not sufficient to make possible a high extraction and a high grade of concentrate. Coghill states: High extraction and high grade of concentrate cannot be obtained without grinding to a size comparable with flotation or cyanide practice. If grade of concentrate be sacrificed the grinding need not be so severe.

Jan 1, 1934

By Jack E. Fraley

Because of their noncombustibility, silicate and magnesium oxycements are desirable for sealing shale in underground coal mines. In this Bureau of Mines investigation, cement samples were cured and tested (nonstandard tests) for submersion to note resistance to dissolution (breaking into parts), which is an important property for a coating. Nonappreciable dissolution during 1 week of submersion was set for passing the test. Over half of the coatings passed the test.

Jan 1, 1977