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By S. D. Maksirnovic, Fred N. Kissell

The use of vertical surface degasification boreholes with bleeder systems and the use of a timbered bleeder system to degasify gob areas were studied by (the Bureau of Mines. This report describes three gob degasification studies ,conducted in the Pittsburgh coalbed. One study was conducted to determine the number of panels degasified with one large borehole . The study showed that the borehole provided degasification for three panels. Another study was conducted during the retreat of a 35-acre panel with a single-entry and a two-entry bleeder system and a large surface borehole. A major portion of methane emitted from the panel was carried away by the bore- hole, leaving the bleeder entries relatively free of methane. The last study was made to determine the effectiveness of a timbered bleeder system. The bleeder entries successfully degasified the gob area when enough entries were available and adequate pressure was available to force the air through roof falls.

Jan 1, 1980

By Francis R. Redfern

Newton's method of solving a nonlinear equation is employed to develop a least-squares acoustic emission source location method in which the spatial residuals of the location equations are minimized. These residuals, related to the distances from the least-squares source location perpendicular to the surfaces described by the location equations, permit location error to be estimated to first order along the spatial axes. The solutions obtained by this method are the best spatial solutions to the location equations in the least-squares sense. Also presented is a procedure by which the geometrical control of a transducer array can be evaluated using the rate of change of source location with fractional velocity change.

Jan 1, 1982

By Benjamin W. Haynes

The Bureau of Mines conducted research to devise technology for increasing the Nation's mineral supply by recovering valuable constituents from currently discarded waste materials. Municipal solid waste (MSW), presently a major disposal problem, represents a significant source of metals, glass, and a combustible fraction that can be used to supplement coal in generating heat and electricity. As part of the total metallurgical system to treat MSW, this study evaluates the combustible fraction of MSW to characterize the various combustible components and to identify the principal sources of elements that eventually may be objectionable from corrosive or environmental considerations. Several possible sources for cadmium, chromium, cobalt, copper, lead, nickel, and zinc have been tentatively identified. These sources are pigments, inks, paper stock, and additives to plastics. A correlation between industry consumption values and measured concentrations in MSW was found for several elements.

Jan 1, 1978

By S. E. Khalafalla

The ability of potentiometric, gas-sensing electrodes to reliably monitor free gaseous molecules in solution has been recently demonstrated. A gas such as sulfur dioxide from a dilute sample solution diffuses through a hydrophobic, gas-permeable membrane to an internal filling solution. The latter solution contains a sufficiently large excess of sodium bisulfite, the concentration of which can be considered constant regardless of the quantity of sulfur dioxide entering by diffusion. The electrode response is essentially due to the liberated hydrogen ions from the bisulfite-sulfur dioxide equilibrium. This Bureau of Mines report describes a new technique used to detect the formation, and to estimate the stability constant, of gas-molecule and gas-ion complexes in solution, as part of an effort to minimize the undesirable environmental impacts associated with mining and mineral processing. Although the unknown activity coefficients of the neutral and ionic species in the external solution complicate the quantitation of results, methods to circumvent these difficulties are presented. The technique is based on the isometric shift of the Nernst diagram of ion-selective electrodes to higher concentrations relative to the standard aqueous calibration curve. The method is applied to detect and estimate the formation constant of a sulfitocitrate complex, and agrees well with an independently determined stability constant of the disulfitomercu-rate complex.

Jan 1, 1978

By Lewis V. Wade

This Bureau of Mines work was performed to theoretically determine the effects of specimen radius and specimen boundary conditions on the stress state in the rock near the anchor for rock specimens used to investigate expansion anchor behavior. Finite element analyses were performed on mathematical models of varying radius and boundary conditions. A review of the results of these analyses revealed a definite convergence of all stress measures considered as the specimen radius increased. There was, however, a significant variation in all stress measures as the specimen diameter increased from 8 to 12 inches.

Jan 1, 1973

By M. M. Tilman

The Bureau of Mines conducted research to determine whether it is possible to substantially improve the fatigue resistance of lead sheet by means of surface coatings. Five types of coatings were applied to unalloyed chemical lead sheet. Flexural tests revealed that the best fatigue resistance was obtained with coatings of vacuum grease. Vacuum-grease coatings on unalloyed lead sheet resulted in fatigue resistance at least as good as that of the fatigue-resistant alloy Pb-0.04 Ca. Coated lead sheet was also tested in short-time tensile tests and in tensile creep tests. Tensile and yield strengths were increased by several of the coatings with only moderate loss of ductility. Creep resistance was also improved in varying degrees by most of the coatings. The Bureau also conducted research on the effectiveness of noise barriers by using sheet lead in combination with other materials. Noise barriers consisting of continuous-cast sheet lead with gypsum board were found to be effective and relatively inexpensive barriers.

Jan 1, 1978

Impermeable geologic faults in the coal seam can cause intermittent production problems or can cause unexpected amounts of water or gas to issue from degasification boreholes. These faults also can impact methane emissions into the mine workings, especially if they hinder proper and effective degasification of the coal bed. They may also act as barriers for methane flow in the coal seam. Although this might seem beneficial for advancing mine workings, faulting may also cause gas pressure buildups and result in compartmentalization of the gassy regions from which large quantities of water and methane may rush into mine workings. This study uses reservoir simulations to illustrate the effects of impermeable faults, with and without throws, on the production performance of vertical and horizontal degasification boreholes. These boreholes were drilled from the surface to intercept the coal layer and fault and were assumed to produce methane two years prior to mining of the coal seam. Longwall advances and face position related emissions and reservoir properties were characterized using sector definitions along the path of the panel grids. This work numerically evaluates water and gas productions of each borehole and presents the effects and the impacts of impermeable faults on methane emissions due to an advancing coal face. The results can be used to understand the effects of impermeable faults on borehole productions and face emissions due to these coal seam anomalies.

Jan 1, 2008

"It is evident that the incidence of coal worker's pneumoconiosis (CWP) or black lung disease varies in different coal producing regions of the United States. Many people have hypothesized about the reasons for the differing occurrences. Because underground coal mining involves many mining methods under changing geological conditions, several factors may be involved in contracting CWP such as: the amount of quartz in the respirable dust, the trace elements in the respirable dust, the rank of the coal that produced the respirable dust (bituminous, anthracite), the amount and size of respirable dust, etc.Recognizing the uniqueness of underground coal mining and CWP, research investigations involving seam characteristics, mining system and worker position are being conducted in the center to establish standard procedures for characterizing some coal properties that may be involved in workers contracting CWP. This has been accomplished by the in-mine sampling of airborne dust at various worker locations and mining system configuration and by performing laboratory analyses of mined material (coal and rock) taken from the mines. (FIGURE 49 and 50)The investigations includes a method of classifying coal seams according to their potential to generate respirable dust. It includes statistical analyses of the size and locational variations of the elemental compositions of respirable coal mine dust in operating underground mines from seams located in the eastern, midwestern, and western United States, and is currently completing research which is investigating the relationship between the elemental compositions of respirable dust sampled near a continuous-mining machine and a laboratory-produced respirable dust."

Nov 1, 1988

By L. E. Schultze

The Bureau of Mines operated a mineral recovery unit to recover metal values from post-flash geothermal brines from the Salton Sea known geothermal resource area as part of its research into the use of plentiful resources. The brine was available for metals recovery after its heat content had been used to generate electricity. The brine source was treated with lime to precipitate the contained iron, manganese, lead, and zinc before injection of the heat-depleted brine into the underground reservoir. Data are presented on the effects of process variables, such as rate and method of lime addition and air oxidation versus air exclusion. Variations in precipitation of metal values, composition of precipitates, effectiveness of slurry thickeners, and methods of treating the precipitates to recover metal values are discussed.

Jan 1, 1982

By C. W. Dwiggins

The Bureau of Mines characterized the chemical and physical properties of metallo-organic materials in petroleum to determine their effect on petroleum production and refining. The structures and physical properties of porphyrins and materials that normally contain metalloporphyrins such as crude oils and asphaltenes were investigated using elemental analysis, NMR analysis, absorption spectrometry, and small-angle X-ray scattering. Petroleum fractions greatly enriched in metalloporphyrins were obtained using asphaltene precipitation, liquid extraction, and large-scale liquid-solid chromatography. Selected fractions containing porphyrins were further purified by chromatographic methods, crystallization, and demetalation followed by chromatography. Nonporphyrin metals could not be appreciably concentrated from the bulk of the asphaltene.

Jan 1, 1969

By Wilbur I. Duvall, Thomas C. Atchison, David E. Fogelson

The breakage of rock by explosives depends largely on the ability of an explosive to transfer its stored potential energy to the rock as strain en- ergy. Therefore, the relative rock-breaking abilities of explosives can be determined indirectly by determining the relative amounts of strain energy transferred to the rock at the time of detonation. This report presents experimental data on the strain energy contained in explosion-generated strain pulses in a granite gneiss. Six explosives were tested. The scaled total radial strain energy E/W flowing outward through a spherical shell of scaled radius R/W1/3 surrounding the point of detonation was found to follow an exponential decay propagation law of the form Analysis of the data showed that the intercept parameter H depended upon the type of explosive used but that the absorption coefficient B was practi- cally independent of the type of explosive. Comparison of the intercept pa- rameter H and the calculated energy of the explosive showed that the percent- age of explosive energy transferred to the rock increased linearly as the ratio of the characteristic impedance (product of density and propagation velocity) of the explosive to that of the rock increased toward unity. From 5 to 9 percent of the calculated total energy released by the explosive was transferred to the rock as radial strain energy.

Dec 1, 1959

By R. D. Leitch

The pollution of streams by acid mine drainage has become of great importance in the past few years in certain regions of the United States. Large quantities of acids are used in a discharged from other industries than mining, notably in tube, sheet, tin-plate and era hell inn works. These are usually less important then coal mines as a source of acid drainage, because of their more limited distribution throughout the States most affected by acid waters and their relatively smaller numbers. Streams are naturally alkaline and are, therefore, able to take care of rather large quantities of acid wastes, but when such enormous quantities as are often found in mining districts enter the streams, the natural alkalinity is quickly overcome. When a neutral or almost neutral condition has been reached, the further addition of a relatively slight quantity of acids will cause a great difference in the quality of the water.

Jan 1, 1926

By D. S. Kingery

The practice of using doors to control main ventilating currents in bituminous-coal mines is common throughout the industry. When doors are erected in pairs to form air locks, they are usually accepted as satisfactory by both State and Federal coal-mine-inspection agencies. A review of the contributing factors in recent methane ignitions showed that interrupted ventilation (often caused by doors latched open, destroyed, or damaged) was the principal cause of methane accumulations that subsequently were ignited.

Jan 1, 1958

By Oscar Lee

"Flotation is generally regarded as a process that is only applicable to metallic minerals. However, its scope is now known to be greater than this, because some of the nonmetallic minerals are floatable, such as graphite, sulphur, and fluorite. Recent observations show that limestone may be added to the list of floatable nonmetallic minerals. Such work is being done on a laboratory scale at the Southern Experiment Station (Tuscaloosa, Ala.) of the Bureau of Mines, Department of Commerce, where experimental magnetic concentration of the low-grade iron ores of the Birmingham district is in progress. Certain experiments have demonstrated that the limestone may be floated from the magnetic log-washer tailing, and then incorporated in the iron concentrate.If the loss of lime could be prevented, some ores though low in iron and high in insoluble contain enough lime to make their concentrates self-fluxing. Since this loss in the magnetic log-washer can not be avoided, the Time must be recovered from the tailing by some method and added to the magnetic iron concentrate before sintering. Then the resulting concentrate will be self-fluxing.While seeking a suitable means of treating the tailing for recovery of lime, flotation was tried. It was at once evident that this method had possibilities, during the early part of the investigation, soap solution made from a common soap was used as a flotation reagent. The froth obtained was a fairly good lime concentrate. This result was an important clue, and led to tests with the use of such reagents as oleic acid and sodium oleate. Later, cresol, creosote, coal tar and other similar flotation reagents were tested in combination with the oleic acid and soap solutions. As a result, oleic acid and cresol used together were found to be satisfactory.The tailing from the magnetic log-washer is in excellent physical condition fur flotation. The iron ore had been ground in a ball mill to 100 mesh for magnetic concentration. Hence the bond between the lime carbonate and the other constituents of the tailing was well broken."

Apr 1, 1926

By Charles L. Kimbell

This study is intended to serve three roles. First, it is an extension of the previous works under the same title that have been the overview and summary chapter of the international volume of Minerals Yearbook since the inception of that volume. Following the traditional format of past chapters, the basic statistical presentations herein deal chiefly with 1989, and in some instances with 1988, the latter only because more recent, comprehensive global statistics for 1989 are simply not yet available owing to delayed data collection and processing in some countries and continued governmental suppression of data in others. The second role of this study is to provide an update to the coverage of events impacting on the world's mineral industry that have occurred between the end of 1989 and the preparation of this study. Inclusion of this update is almost essential because of the potential effect of some of these events on global mineral industry activities.

Jan 1, 1992

By Scott Turner

We are here today to witness the graduation of 63 young men as Engineers in the mineral industries . It is an important occasion and one in which the public takes a keen interest , since this school has long been famous for the educational facilities it affords young men, and for the high professional standing of its graduates . : : : It is fitting that once each year we should pause to review the path the student has traveled , and to reflect upon the perspective opening before him as an engineer . I was invited to come from Washington to take part in this ceremony and to say something to these young graduates . In searching for a theme ," it occurred to me. that perhaps my best contribution would be to duscuss certain beliefs as to college training , deal with the situation in which the young engineer finds himself on graduation , touch on the new ideas of the social and political responsibilities of the engineer , and point out what he may expect to find in practice , and , above all , what he must do to orient himself properly in the mining profession and maintain the best traditions of our brotherhood . Let us first review your college days and see what they have done for you . I am told there are still many temptations in college . I know there used to be . Rest assured the same holds true in the professional life ahead of you. The main difference is , perhaps , that your greatest temptations in college were those offered by your teachers , who tried to entice you into realms of harder work, closer application , increased concentration , clearer thinking and better understanding , by animating your curiosity and increasing your powers of reasoning and of observation . In other words , here you have carefully and systematically been decoyed toward finer and loftier things . Do not expect that similar helpful influences will greet you on every side in your professional life . Often quite the contrary is the case .

Oct 1, 1930

CESIUM metal production increased sharply in 1963. Domestic Production.--Cesium metal was produced by The Dow Chemical Co., Midland, Mich., MSA. Research Corp., Callery, Pa., and by Penn Rare Metals, Inc., Revere, Pa. American Potash & Chemical Corp., Trona, Calif., produced some combined cesium and rubidium. This company, Penn Rare Metals, Inc., and Rocky Mountain Research, Inc., Denver, Colo., produced various cesium compounds. Complete production data on cesium and rubidium and their compounds were not available for publication. Consumption and Uses.-Substantially more pollucite was consumed to produce cesium metal and compounds in 1963 than in 1962 but the overall consumption of pollucite continued to be small.

Jan 1, 1964

By David R. Forshey

This Bureau of Mines report presents a quantitative theoretical analysis of a coupled gasdynamics-heat release system involving the kinetics of water condensation in and behind the rarefaction wave in a shock tube using the method of characteristics. The merger of characteristics to form a shock wave is included.

Jan 1, 1977

By Carlton E. Brown

The purpose of this report is to present results of tests on the effectiveness of a spray of water mist, commonly called compressed-air water blast or water blast, in reducing the concentration of dust present in the air shortly after blasting and during mucking of the blasted material. Many observations have been male on the effectiveness of such ,sprays, but published quantitative information on comparative dust concentrations with and without their use, obtained by dust-sampling methods in use in this country, is rare if not absent. Tests conducted in South Africa about 19164/ and more recently in England5/, 6/ have shown that such sprays reduce the dust concentration to very low values within a fen minutes after blasting,

Jan 1, 1938

"The dust/lung research of the Center has several long-range objectives:* better methods for the early diagnosis of coal workers' pneumoconiosis (CWP);* methods to modify the disease process;* tests to identify toxic products; and* tests to identify individuals with heightened susceptibility to pneumoconiosis.A major immediate objective is to define the mechanism of dust-induced lung disease. This means determining:* dust characteristics that are important in causing lung diseases;* important interactions between dust and lungs; and* earliest detectable stages of the disease.Several of the Center's projects involve exposing lung cells in culture (in vitro) or animal lungs (in vivo) to samples of the suite of characterized mineral dusts described earlier. The responses of the lung cells or tissues to the dusts are being studied in order to better understand how inhaled dusts cause lung disease.One project is studying the effect of dust exposure on the production of mucus by rat tracheal explants in vitro. Mucus is a major factor in clearing inorganic dusts from the lung. Results thus far have shown that exposure of tracheal cultures to coal dust caused a decrease in micin production in comparison to parallel cultures without dust. To examine the effect of in vivo coal dust exposure, rats were maintained in an inhalation chamber for two weeks, and control rats were in an identical, but dust-free chamber. Tracheal explants results indicate that the effect of in vivo dust exposure is similar to that noted in the in vitro experiments.Pulmonary alveolar macrophages (PAMs) are a key component of the lung's response to inhaled particulates, and they play several important roles in pulmonary inflammatory and repair processes. PAMs are the cells that actually ingest dust particles. Other studies have shown that they play a critical role in the development of silicosis and asbestosis. The Center is studying the effect of dust exposure on the release of oxygen free radicals (superoxide) by PAMs. Intercellular production of superoxide occurs when PAMs phagocytize particles, such as inhaled bacteria, and is an essential mechanism by which PAMs kill ingested, bacteria. A number of complex physiological events occur during this process which are not clearly understood. It is thought that PAMs containing indigestible materials, such as mineral dusts, overproduce superoxide, or inappropriately release it into the surrounding tissues. If true, this would cause toxicity to surrounding lung cells by peroxidation of the lipids in the cell membranes. In vitro exposure of PAMs to low or high doses of kaolin is inert. Preliminary studies indicate that coating the quartz particles with a surfactant reduces toxicity."

Nov 1, 1988