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By Omar A. Muhtadi, David A. Milligan

7.1 INTRODUCTION The circulating fluid (generally an aqueous cyanide solution) is the major active component of heap leaching. This solution extracts precious metal from the heap and is then processed to recover the precious metal. The solution continuously recycles through the heap to recover more precious metal. With each cycle through the heap, water and chemicals are lost. Make-up water and chemicals must be added to balance losses from evaporation, seepage, entrainment, and chemical reaction in the heap, as well as any other processing losses. Adding more water than needed can result in a build-up of water as inventory in the various ponds and can eventually require that water be discharged from the operation. This is an extremely undesirable condition, and can often be very expensive in both investment in water treating facilities and operating costs. Most heap leach facilities operate under a zero discharge permit; thus, a situation requiring water discharge can result in permit violation. Chemical solution control must be managed to maintain the optimum pH, dissolved oxygen content, and cyanide content, while preventing "scaling". Calcium-based precipitation is a common scaling problem in mill reclaim waters. A buildup of these deposits can result in severe reduction of water flow, loss of pump efficiency and eventual interruption in metal production. In addition, problems of plugged sprinkler heads, blinded leach pads and fouled carbon (in carbon recovery systems) can be and often are experienced when scale control is not maintained. The remainder of this chapter discusses chemical solution control and scaling prediction/prevention in the context of a "closed" system. Sizing of ponds to accommodate precipitation and runoff, collection systems, and other similar design considerations are not discussed here. These topics are deferred to later chapters, e.g. Chapter 10 considers design of collection systems while Chapter 12 discusses pond sizing. 7.2 CHEMICAL CONTROL Chemical composition of the circulating solution must be controlled by the operator if the heap leaching process is to be successful. The primary or essential chemical control parameters in any heap leaching operation are:

Jan 1, 1988

By J. E. Powell

Introduction The disposal of mine tailings, development rock, and other unwanted refuse material underground in mines by using pneumatic conveying techniques has been undertaken in the coal industry for many years. Similar equipment has been utilized for backfilling hard rock mines and is currently being applied in a gold mine in South Africa where development rock is being stowed in the mined-out stopes to help reduce the incidence of rock outbursts. On a limited scale, pneumatic conveying has been applied for backfilling uranium mines and one particular mine in New Mexico, U.S.A., has used this technique for 8 years. Other uranium mines in this area are now considerinq the dry backfill technique to eliminate the problems associated with hydraulic fill. The need to backfill in uranium mines is primarily of importance to improve ventilation, stabilize the pillars and roof, and possibly to extract a larger percentage of the uranium ore. If this can be achieved by utilizing the tailings from the beneficiation plant and using rock from the development headings which in itself may be slightly radioactive, then a greater benefit can be derived. Backfill can be achieved with hydraulic fill methods by running slurry into the stopes and allowing the water to decant and return through the footwall development entries to sumps for pumping to the surface. However there are several disadvantages associated with this method in that water is percolating throough the mine workings; it is necessary to build bulk heads in flat lying deposits; it is difficult to fill right to the back; and the decanted water takes with it quantities of the finer sand particles which results in maintenance problems with the mine pumps. Pneumatic conveying can overcome these problems in that the voids can be completely filled with high degree of compaction, heavy bulk heads are not necessary, the development rock can be added to the pneumatic system for disposal underground so eliminating hoisting cost to the surface, and cement can be added to the wetted material. To

Jan 1, 1980

By S. E. Phillipson

Slickensides cause potentially hazardous ground conditions in underground coal mines. Investigations by MSHA’s Roof Control Division indicate that many slickensides represent bedding plane faults and drag folds that formed during coal bed decollement, a style of faulting that occurs in shale units above coal seams. These slickensides formed in response to regional tectonic compressional stresses, rather than by differential compaction, and are parallel to folds and thrust faults. This paper relates slickensides in the Appalachian, Illinois, and Black Warrior basins to the structural grain of the Appalachian Mountains, provides descriptions of slickensides, and advocates geologic mapping as a predictive method for identifying areas with adverse ground conditions.

Jan 1, 2003

By Ian Larkins

The Ruby Hill Mine agglomerates crushed low-grade ore (nominally -1 .5'') with high-grade filtered tailings (filter cake, nominally 80% -65#). Cement is added as a binding agent. The agglomerated ore is then conveyed and stacked on the heap. In 1998 approximately $480 000 was spent on cement for agglomeration. Cement for mill pH control and agglomeration was the largest single reagent cost at Ruby Hill. In an effort to reduce agglomeration costs a test-work program was initiated to investigate alternative binders and optimum binder additions. This paper summarizes the test­work results to-date.

Jan 1, 1999

By R. L. Grayson

Conventional mine safety wisdom states that "the most efficient mines are also the safest." Since the 1980s, small mines (and contractors) have been targeted as the most dangerous because of their fatality records. However, statistical analysis of West Virginia safety and production data from 1993 indicated that, when considering the correlation between accident severity and tons mined per employee-hour worked, the most efficient mines were, with the exception of very small mines, not the safest operations. This paper presents the results of an extended analysis of West Virginia mine safety using 1993 and 1996 data and concludes with the method used to suggest current priorities for focusing interventions.

Jan 1, 2000

By B. Karatzoglou

The penetration of sustainability principles in business practices has introduced the necessity for a simultaneous integrated assessment of the corporate economic, environmental and social performances. Continuous technological, political and legal evolutions indicate that Sustainable Development (SD) principles will soon have to be implemented in all sectors of the Greek corporate reality, among them in the Mineral and Mining Industry. However, the ultimate criteria for the evaluation of a company?s performance remain its profitability and its market value. Managers, shareholders, financial intermediaries, all alike, emphasize and base their decisions on the various accounting produced ratios of return (ROA, ROE, ROCE, Residual Value) included, or produced by data found, in the financial statements of the companies. This paper offers evidence that the traditional accounting ratios discourage the implementation of investment plans that aim at improving the environmental performance of companies and therefore can be inadequate and misguiding for SD applications. International studies have consistently traced a positive relationship between the environmental performances of firms and their financial positions. Yet, the fact that investors tend to reward proactive companies by increasing their corporate values is disregarded by the return ratios, which usually set up the basis for management rewards and bonuses. The book value of the firm assets and owners? equity from which such ratios are produced diverges strongly from the real corporate value, defined as the traded amount for the stock of a firm. There is an urgent need for an adjustment of the return ratios so that they can record the positive economic impact of a more sustainable attitude and encourage decision makers towards this direction.

Jan 1, 2003

By Éder Domingos Oliveira, Carlos Antonio Morais, Ruberlan Gomes Silva

The objective of this work was to assess the influence of parameters such as residence time, solid content, and temperature in a process route towards purified rare earth liquor which could be adequate to produce marketable rare earth products. The steps of the process route proposed in this study comprised water leaching of a sulfated rare earth ore and removal of impurities through the purification of the rare earth sulfuric liquor, which is the product of the water leaching step. The sample used in the water leaching experiments was a sulfated rare earth ore produced by the reaction of a beneficiated rare earth ore with sulfuric acid followed by roasting at 700 °C for 2 h in a muffle furnace and cooling at 20 °C. The water leaching experiments showed that the best condition comprised a residence time of 30 min, temperature of 20 °C, and solid content of 10% w/w, resulting in a recovery of 71.3% of the rare earth elements (REE) and a lower impurity extraction, e.g., only 15.0% of Fe, representing the main impurity in the rare earth ore. Even when presenting low amounts of impurities, the rare earth sulfuric liquor still needed to be purified before it can be used in the production of marketable rare earth products. In the study, the rare earth sulfuric liquors were purified in two consecutive neutralization steps, first by dosing the limestone pulp to pH up to 3.5 and secondly by adding the lime pulp to raise the pH from 3.5 to 5.0. The application of two consecutive purification steps at 20 °C resulted in the highest overall REE recoveries (65.4%) throughout all the steps of the process, being 71.3% in the water leaching, 99.6% in the partial purification with limestone pulp, and 92.1% in the purification with lime pulp at 20 °C. Under this condition, there was a total elimination of Fe, P, and Th and a significant reduction in the Al, U, and sulfate concentrations in the purified rare earth liquor. The purified rare earth liquor attained through the experiment is expected to be amenable to be used in the production of marketable products due to the lower impurities/REO mass ratios.

By Eric Forssberg, Ming-wei Gao

Four parameters of the Drais stirred ball mitt, i.e., bead load, bead size, flow rate and top feed size have been studied regarding their influence on the specific surface area. A factorially designed scheme was employed for conducting 27 mitting tests. The results show that the bead toad is the most important parameter in terms of increasing the specific surface area with less energy consumption. The bead size is also important. The optimum ratio of bead size to top feed size is found to be 14 to 80, which is much wider than in bat2 milling. The variations in flow rate and top feed size appear to influence the process insignificantly.

Jan 1, 1992

By D. S. Kostick

Soda ash production in the United States during 1994 increased 4%, reaching 9.3 Mt (10.2 million st). That was the second highest production year. Domestic nameplate soda ash capacity is about 11 Mt (12 million st). Overall, the industry operated at about 85% of capacity. Some companies produced at 100% of capacity while others produced at below their design ratings. Although domestic soda ash consumption was slow during the first half of the year, third- and fourth-quarter sales increased, especially in the flat¬glass and fiberglass sectors. These two sectors increased because of greater demand for glass products in the automotive and construction industries. Soda ash sold for pulp caustic soda increased during 1994. This was due to higher prices for and reduced availability of electrolytic caustic soda. It is often preferred for pulp digestion because of its stronger alkalinity.

Jan 1, 1995

By J. E. Chilton

Methanometers with catalytic heat- of-combustion sensors used in coal mines today will read low for flammable gases when oxygen (0,) concentrations are low or when methane (CH,) concentrations are greater than 10%. Thus, these methanometers may not be reliable during operations such as fire fighting or recovery of sealed mines. The U.S. Bureau of Mines developed a total flammable gas detector (TFGD) to measure CH, at concentrations up to 100% and to measure flammable gases in low 0, concentrations. This paper describes the operation and construction of the TFGD and discusses measurements of flammable mine gases obtained from a mine in western Pennsylvania.

Jan 1, 1992

By E. M. Cukrowska

The evaporative pan complex consists of two adjacent seasonal pans. These pans carry an exceptionally high salt (TDS) load due to over 50 years of effluent discharge via the pipeline from mines. The nutrient, heavy metal, radionuclide load in the water and sediments of the pans are very high affecting groundwater around the pans. The groundwater in the region contains TDS > 40 000 mgl-1 and sulphates > 7000 mgl-1, whereas groundwater in areas assumed to be unpolluted by mining activities have TDS < 500 mgl-1 and sulphates < 200 mgl-1. The extent of continuity between the pans and the groundwater is unknown, although there appears to be seepage of contaminated groundwater into the river system.

Jan 1, 2006

By J. C. Judd, D. D. Harbuck, M. D. Odekirk

The US Bureau of Mines investigated germanium and gallium extraction from an ore containing 0.089% Ge and 0.036% Ga. While previous researchers concluded that a reducing agent, such as SO2 is needed to extract germanium and gallium from such ore, this research showed that high extractions (87% Ge, 97% Ga) were possible using sulfuric acid alone, if the acid concentration were properly controlled. This control was achieved using a two-stage countercurrent leach circuit. Microprobe analyses revealed that the non-extracted germanium is in solid solution with quartz, and therefore cannot be leached with SO2 or sulfuric acid.

Jan 1, 1992

By R. P. Benson, D. H. MacDonald, D. R. McCreath

1 - INTRODUCTION The Canadian Shield is well known as being among the older exposed areas of the earth&apos;s surface. Except for local zones, its extent from the Arctic to central North America is characterized by strong and durable crystalline rocks. It is generally regarded as highly competent for tunnelling and underground excavation and, as a result, many openings are excavated in it with minimal temporary support. If hydraulic efficiency is not a factor, tunnels do not usually require continuous concrete linings. A high percentage of the crystalline rocks of the Shield are of metamorphic origin and as such one of the dominant characteristics is their foliation. Zones of sheared or faulted rock are common in the Canadian Shield, particularly in association with foliation. These zones may be created during the late stages of the metamorphic process, leaving shear zones as an integral feature of foliated rock. As foliation is a preferred direction of weakness, deformation and rupture during subsequent tectonism may also create parallel shear zones. These "foliation shear zones", as described by Deere (1973), are an adverse feature of the otherwise durable rocks of the Canadian Shield. The zones may range from faults of major proportions to seams only a fraction of an inch thick. If fault gouge or alteration products exist in the zone the strength of the rock mass may be great1y reduced. As foliation is usually continuous, large unstable wedges of rock may be created if the opening is subparallel to the foliation. The effect on the construction of underground openings in terms of excavations, support and scheduling can be significant.

Jan 1, 1974

By Eung Ha Cho, Olufemi Olajide

A laboratory study of dense-medium cycloning with Redstone seam coal has been conducted. The investigation was performed using a 203 mm (8 inch) Heyl-Patterson dense-medium cyclone. Two underflow orifices of 31.8 mm (1.25 inch) and 44.5 mm (1.75 inch) in diam were used. The effects of feed pressure and particle size were determined on the cycloning performance. In addition, the cyclone performances with coal-rich and refuse-rich samples were also investigated. The results of the experiments were analyzed using basic hydrodynamic principles. The increase in the feed pressure increases the specific gravity of separation (defined as the specific gravity of a particle which has an equal chance of reporting to either the overflow or underfow) for both underfow orifices. The specific gravity of separation increases as the particle size decreases with the smaller underflow orifice. However, an opposite relationship has been observed with the larger under flow orifice. The separation becomes sharper with the smaller under flow orifice than with the larger underflow orifice especially for fine material. Also, the separation becomes sharper with an increased feed pressure for a coal-rich sample. However, this effect is less significant for a refuse-rich sample. This means that a high feed pressure is required for a coal-rich sample to maintain a good separation. It also means that applying a high feed pressure provides a good separation regardless of the type of feed coal in terms of ash content in the solid.

Jan 1, 1990

By D. D. Harbuck

The US Bureau of Mines investigated germanium and gallium extraction from an ore containing 0.089% Ge and 0.036% Ga. While previous researchers concluded that a reducing agent, such as SO2 is needed to extract germanium and gallium from such ore, this research showed that high extractions (87% Ge, 97% Ga) were possible using sulfuric acid alone, if the acid concentration were properly controlled. This control was achieved using a two-stage countercurrent leach circuit. Microprobe analyses revealed that the non-extracted germanium is in solid solution with quartz, and therefore cannot be leached with SO2 or sulfuric acid.

Jan 1, 1991

By Peter J. Suardini

Over the last few years, researcher have been working on improving procedures for fine-coal (minus 150 microns) washability analyses. The effort was stimulated by past difficulties in obtaining accurate and reproducible results from the various commercial laboratories providing fined washability services. This paper contains the results from fine-coal washability testing, performed by Process Technology, Inc. (PTI), as part of a U.S. Department of Energy (DOE)-sponsored project. The testing focused on comparing the performance of a number of media options (i.e., aqueous solutions and organic solvents), as well as evaluating the impact of a number of procedural steps on separation performance. The paper summarizes PTI&apos;s recommended washability procedures for various size fractions and ranks of coal, and makes recommendations for future studies of certain phenomenon, such as void penetration and particle density changes, which are not well understood.

Jan 1, 1995

By Sibley C. Burnett

Early attempts to apply superconductivity to the beneficiation of kaolin required very large refrigerators to remove the heat generated during rapid charging and discharging of the magnet. In the early 1990&apos;s, Advanced Cryo Magnetics, Inc. developed and patented methods to reduce this pulsed heating by a factor of fifteen. Small, helium refrigerators and cryo-coolers are now used. Along with savings in electric power, superconductivity allows operation at higher magnetic fields and greatly improves separation process efficiency. New designs offer enormous reductions in weight, size and capital cost as compared to older copper magnets. Application of this technology to minerals other than kaolin is emerging.

Jan 1, 1999

By H. Lyn Bourne

The is the 14th consecutive year for this column and the 13th in which the royalty data have been tabulated. Some holes still exist in the list of royalties that readers hopefully will fill. Construction aggregates - either sand and gravel or crushed stone - are the most common mineral commodity. In spite of their pervasive use nationwide, royalty information for these commodities has been difficult to acquire from some states. Readers can help. Share information about these missing states and next year there will be fewer states without information. Dennis Bryan sent a copy of a report, "Regional Appraisal of Mineral Materials: Carson City District, BLM." The report was authored by real-estate appraisers. It contains more than 50 references to leases of various construction materials in Nevada and nearby states. It gives a thumbnail sketch of each lease and is a good reference. However, the authors erroneously imply that the royalty rate and the in-place value are the same. Several of this year&apos;s new entries come from the report. However, the royalties for landscaping materials vary from state to state and by rock type. Some boulders used for landscaping in Nevada have a royalty reported at $1.10/t ($1/st). At the other extreme is lava from Idaho. Used for the same purpose, it has a royalty range of $11 to $18.70/t ($10 to $17/st). Chuanming Tian of Beijing, China has shared some information about the changing mineral royalty policies in China. China first implemented an oil and gas royalty in 1984. In 1992, the government expanded that to include iron ore. In 1994, the royalty policy was extended to all mineral commodities. At the same time, the royalty rate for iron ore increased tenfold.

Jan 1, 1995

By George L. Baloo, Dave Kwiatkowski, Jose G. Cañlzales

Capital project funding for a medium to large materials handling project often includes a budget for procurement of supplier-recommended spare parts, and it is the Project Team&apos;s responsibility to select these parts. With today&apos;s economic climate, limited budget, and other factors, the spare parts selection process is a difficult and arduous effort. This decision carries with it a risk to plant operations and in some cases the commodities producers. Too often the decision-making process is not documented, and the reasons for eliminating and reducing quantities are based on "best guess " Recently on the Solids Handling Phase 2 Project in Jose, Venezuela, the Project Team took a unique approach to this problem. This paper discusses the analytical approach taken by the Project Team, the database system that was developed to manage this problem, lessons learned, and their applicability to pre- project planning and preliminary design.

Jan 1, 2004

By Tim O’Neil

Big and getting bigger. Barrick Gold Corp., the third-largest gold producer in the world, began production in September — ahead of schedule — at its Meikle Mine. At a scheduled full production rate of 12.4 t/a (400,000oz/year), it will be the largest producing underground gold mine in the United States. The $180-million Meikle Mine is located on Barrick’s Goldstrike property in Nevada and has 205 t(6.6 million oz) of gold reserves. The compact Meikle deposit has an average ore grade of 23 g/t (0.68 oz/st), making it one of the highest-grade mines in the country.

Jan 1, 1996