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By William E. Wallace, Michael J. Keane

This review summarizes three sets of ongoing studies which we are performing in collaboration with a number of researchers associated with the Dept. of Interior - Generic Mineral Technology Center for the Study of Respirable Dusts, concerning surfactant-particle interactions studied using this surrogate surfactant. These topics are: (A) the suppression of mineral particle cytotoxic potential by DPL adsorption and the persistence of this effect under conditions of enzymatic digestion; (B) surfactant suppression of organic particle cytotoxicity by DPL adsorption and the effect on subsequent expression of genotoxic potential; (C) potential effects of surfactant on heterogeneous structured complex respirable particles. The references list some of our reports which can provide additional information on these studies. Further, those reports provide references to the literature of the field and to the works of others on these topics. Deep lung airspaces, the pulmonary alveoli and respiratory bronchioles, are coated with a hypophase which is rich in surfactant biomolecules secreted by the alveolar type II epithelial cells. The surfactant is known to be critical to maintaining stable low surface tensions on the inner surfaces of the alveoli by forming a surfactant layer on the airliquid interface of the alveolar hypophase. Upon deposition in the acinar regions of the lung a respired particle's initial contact will be with this surfactant coating over pulmonary tissue. A primary component of this surfactant is the phospholipid diacyl glycerophosphorylcholine, commonly called lecithin. A surface layer of dipalmitoly lecithin on saline will act much as full pulmonary surfactant in decreasing surface tension and producing a hysteresis in surface tension behavior with surface area. We have used dipalmitoyl glycerophosphorylcholine, or dipalmitoyl lecithin (DPL), a major component of that surfactant, dispersed in physiologic saline as a surrogate for studying interactions of both mineral and organic respirable particles with pulmonary surfactant and consequent effects on particle toxic behavior. A. DUST CYTOTOXICITY AND LECITHIN SURFACTANT ADSORPTION Respirable quartz and kaolin clay particles are found to be comparably cytotoxic in a number of in vitro bioassays including lavaged rat pulmonary macrophage release of cytosolic and lysosomal enzymes, and red blood cell hemolysis as a measure of dust membranolytic potential. These direct and prompt cytotoxic activities do not account for the distinctly greater potential for quartz to induce pulmonary disease. When respirable quartz and kaolin are incubated with a dispersion of DPL in saline at 37C it is found that the prompt cytotoxicity of both dusts is fully suppressed as measured in vitro by pulmonary macrophage release of lactate dehydrogenase, beta-N-

Jan 1, 1991

By Abdullah Arik

An ore reserve block model is the basis for various decisions in mine development and production. The block model is initially built using the information from the drillhole data only. Once the mine is put in operation, the information from the blasthole data becomes available. Since the spacing of the blastholes are much closer than the exploration drillholes, the blasthole data gathered from the mine over the years become quite extensive containing valuable information about the deposit. In practice, the information from the blastholes is the basis of determining the ore and waste boundaries between and within mining blocks. In an ore reserve model, the valuation of blocks on and close to the pit face can obviously be improved by using blasthole data from neat by drilled and mined-out blocks in addition to using the widely spaced drillhole data. The ideal basis on which to integrate blasthole and drillhole data is to use cokriging.

Jan 1, 1996

By C. Manea

During exploration and exploitation of complex ores, waste dumps that contaminate severely the environment and in particular soils, are genetated. The most hazardous pollutants are heavy metals and metalloids (e.g As, Mo, Pb and Cu) as well as radionuclides (e.g U and Ra). Ecological remediation aims, among others, at decontamination of soils by preserving important properties as soil fertility.

Jan 1, 2008

By H. R. G. Steeghs

Recently developed organic binder systems have the advantage of eliminating bentonite contamination. This results in better chemically reactive taconite pellets. Both acid and fluxed pellets show increased R40 reducibilities, whereas mechanical and physical properties of the taconite pellets are not adversely affected. Blast furnace performance of these pellets is excellent, and substantial economic benefits are achieved.

Jan 1, 1989

By Yongping Hu, Dianchen Cai, Congya Zhang

China is a rich in stromite mineral resource. Unfortunately, the resource is very difficult to separate by using conventional flotation method because stromite and gangue minerals are very fine disseminated, the average size of them is about 10 µm or below, and the content of clay minerals such as illite is 19% or even more. In this paper, the aggregation floatation behavior of ultrafine (-10 µm) stromite, illite, ablbite and quartz using anion collector were studied. The result show that, Oxidized paraffin (O.P) is a good collector and has better selectivity for stromite particles flotation. The salted sodium silicate depressed illite gangues minerals effectively. The separation of mineral mixtures was carried on successfully at one stage flotation by the technique. The mechanism of O.P. and salted sodium silicate were studied and discussed by using IR and Zeta- potential measurements.

Jan 1, 1995

By R. Venugopal, T. C. Rao, M. Vanangamudi

Introduction The kinetic approach, to understand a process in detail, has been extensively used in the unit operations of many engineering systems. In green pelletization, the kinetic studies have been mainly oriented towards quantifying the growth mechanism (Kapur and Fuerstenau, 1964; Sastry and Fuerstenau, 1977; Capes and Danckwerts, 1965; Kapur and Fuerstenau, 1966; Kapur, 1972) and in a few cases, relating the rate of growth with added liquid content (Kapur and Fuerstenau, 1964; Newitt and Conway-Jones, 1958). Studies on the kinetics of green pelletization, in terms of the order of the kinetics are virtually non-existent. Sastry and Fuerstenau (1970) classified the agglomeration process into "free in-space" (dilute particle system) and "restricted-in¬space" (highly dispersed particle system) and noted that the former is a second-order process while the latter corresponds to a pseudo first-order rate process. The present paper attempts to describe the kinetics of green pelletization, in terms of order of the kinetics, using pyritiferrous shale as the material system. Experimental Pelletization experiments were carried out using -100 mesh pyritiferrous shale, in a laboratory disc pelletizer, at four intervals of pelletization time (15, 20, 25 and 30 min). The green pellets obtained were size analyzed. The size distribution of pellets has generally been represented by a single parameter such as the mean granule diameter, ratio of maximum and minimum pellet diameter, etc. In the present study, the d50 (50% passing size) of pellets has been considered to represent the size distribution of pellet. Kinetic equations The process of size enlargement is considered analogous to chemical reaction and a general kinetic equation of nth order for growth of pellets is given as

Jan 1, 1990

By S. K. Kawatra, S. T. Bagley, T. C. Eisele

The use of the bacteria Thiobacillus ferroxidans to catalyze pyrite dissolution in coal is well known, and recent investigations have shown that T. ferrooxidans are also capable of rapidly altering the pyrite surface to facilitate its removal from coal by froth flotation and oil agglomeration. However, the effect of reactor design on the bacterial leaching rate is poorly documented, and the ability of bacteria other than T. ferrooxidans to affect pyrite flotation has been unknown. In this study, the effect of a number of different microorganisms on the flotation of unoxidized pure mineral pyrite has been investigated, and it was shown that organisms other than T. ferrooxidans are also capable of depressing pyrite flotation. In addition, comparative studies of leaching in shake-flasks and pachuca tanks have shown that the pachuca tanks allow leaching to proceed to a greater degree and at a significantly accelerated rate.

Jan 1, 1989

By Y. Topkaya, R. E. Johnson, B. R. Palmer, Bruce E. Kurtz, Anatoli Omelian, John I. Choi

This paper relates to hydrometallurgical studies on the recovery of soluble aluminum values from aluminum-bearing ores, i.e., Georgia clays. At least 50% of the soluble alumina values were recovered by leaching the calcined clays from aqueous solutions, comprising simultaneously contacting a stream containing an effective amount of a reducing agent such as sulfur dioxide and a stream containing an effective amount of an oxidizing agent such as chlorine gas for a time sufficient to dissolve alumina. The recovery of alumina from this aqueous slurry of the calcined clay by leaching with sulfur dioxide and chlorine gas showed much better results than that by leaching with concentrated sulfuric acid and/or concentrated hydrochloric acid at 100O C. The leaching reactions between the aqueous slurry of the calcined clay, chlorine gas, and sulfur dioxide were strong exothermic reactions for several hours, requiring no external heating.

Jan 1, 1993

By X. Zhou

A novel flotation device, cyclonic static micro-bubble column flotation (FCSMC), was introduced in this paper. FCSMC has been widely applied for fine coal preparation in China, and its application has been further expanded to the mineral processing industry. The FCSMC system features a unique cyclonic structure which enhances the separation performance of the column. In this paper, the cyclonic separation mechanism of FCSMC process was investigated, and corresponding kinetics equations were established to probe the separation principle of this device. Some typical examples of using FCSMC to separate different materials including coal, copper, fluorite, etc., were presented. Key words: cyclonic static micro-bubble flotation column, cyclonic separation

Jan 1, 2008

By Harold L. Kike

Until recently sulphur uses were so broadly based that economists used sulphur consumption to measure industrial activity. However, sulphur use patterns are changing and the manufacture of phosphate fertilizers presently accounts for approximately 65% of the world's sulphur consumption compared with only 25% in 1960. This has encouraged the development of new agricultural and industrial uses for sulphur. Major emphasis has been placed on its use as a fertilizer and in the manufacture of paving materials, specialty concretes and coatings. Some of these uses could have a significant impact on future sulphur usage.

Jan 1, 1986

By P. K. Kaiser

A rational approach for the design of fully grouted bolts in underground excavations is presented. An analytical model involving elasto-plastic concepts and the mechanics of bolt/ground interaction was developed and tested by comparison with laboratory tests and field measurements. The theory elucidates the influence of shear stress distribution, bolt pattern and geometry on tunnel convergence. Laboratory simulation has provided convincing evidence to support the theoretical predictions. A dimensionless bolt efficiency parameter is introduced as a design tool that relates the reduction of tunnel convergence to the bolt length and density. Its application in practice is highlighted by the analysis of one case history.

Jan 1, 1987

By Shuang Shuang Huang, John Fillos

Ozonation was evaluated as an alternative treatment process for leachates of municipal landfills. The study was carried out on leachate from the Fresh Kills Landfill, New York City. The leachate has strong tea color and BOD5 ranging between 90 mg/L and 130 mg/L. The average COD, TOC and NH3-N concentrations were 1800 mg/L , 550 mg/L, and 665 mg/L, respectively. The kinetics of the process were studied in a sparged batch reactor by developing concentration- time profiles for residual color and TOC. Continuous flow experiments were then carried out at two selected contact times. The process was found to be effective in the treatment of leachates for color and TOC removal.

Jan 1, 1992

By R. Spears, J. B. Vincent, S. Donald, J. Litaker

Previous efforts to remove and concentrate heavy-metal ions from wastewater streams via metalloprotein affinity metal chromatography (MAMC) were limited to the metal transport protein transferrin. Extension of the technique to the enzymes carbonic anhydrase and carboxypeptidase A, which possess different metal affinity properties, is described. Preliminary results indicate that the technique is capable of selectively removing and separating late first-row transition metal ions from aqueous solution. The results suggest that by properly choosing the matrix, i.e., protein or enzyme, MAMC may he applicable to problems involving a wide range of heavy-metal-hearing aqueous solutions.

Jan 1, 1996

By Ing. E. h. Martin Herrenknecht

The paper will describe a number of developments and innovations now in use in microtunnelling machines. These include the use of fuzzy logic steering systems, the proven ability to successfully undertake complex curved microtunnel drives, the ability to complete ultra long drives using microtunnelling techniques, and machines with access to the face of the machine from inside the machine. The ability to tunnel in relatively hard rock utilizing a rock head with back loaded cutters changeable from inside the microtunnel machine and the ability to utilize microtunnel machines in multi modes, such as hard rock mode, “open” mode, EPB mode, and slurry mode with the same base machine again with access to the face of the machine will be described. In addition, the latest computer technology gives the operator “full visualization” of machine functions together with the ability to data log machine operating parameters. Reference will be made to a number of projects worldwide recently completed or under way where these innovations have successfully been utilized.

Jan 1, 1999

By Richard R. Klimpel

This paper reviews some of the factors involved in selecting amine flotation reagents used to remove silica from ores. A comparison is made between the chemical reagent design approaches used to identify flotation reagents that are used to recover silica- and oxygen-containing minerals and the chemical reagents used to recover sulfide minerals. This introduction gives practitioners who are involved with oxide- and carbonate-type minerals and who may not be familiar with sulfide mineral flotation some ideas of the chemical reagent design challenges that exist with froth flotation on a broader scale and why oxide type mineral flotation reagents are what they are. This is followed by several sections that discuss various classes of available amines. The closing sections emphasize that the optimal choice of an amine collector depends not only on that amine's specific chemical characteristics and costs but also on the operating conditions, especially the flotation feed particle size distribution.

Jan 1, 1999

By Richard H. De Voto

The Pb-Zn-Ag deposits within the Lower and Middle Paleozoic strata of central Colorado (Leadville, Gilman, Aspen, and others) occur principally in Late Mississippian karst-solution features within dolomites and, to a lesser extent, limestones. Several un- conformities within the Devonian and Mississippian carbonate rocks and the subregional dolomitization of the Leadville (Mississippian) Formation that occurred during the Late Mississippian resulted from recurrent uplift of elements of the Ancestral Sawatch, Gore, and Front Range areas within central Colorado. Uplift of these areas also strongly influenced the details of the extensive karst topography that developed during the Late Mississippian. In particular, uplift of the Sawatch Range area caused paleovalleys from 300-600 ft deep to form on the karst landscape. The pattern of karst-solution caverns, sinkholes, cutters, channelways, and breccia-rubble zones was strongly controlled by incision of surface drainages and the strong northeast-trending Mississippian joint system. These subterranean karst-solution features and breccia-rubble soil [ ] zones are the primary controls of the location of the Pb-Zn-Ag ore deposits in these rocks. In the Leadville and Aspen districts, the deeply incised paleovalleys occur immediately adjacent to the principal areas of mineralization. Pennsylvanian deposition of a thick terrigenous and evaporite sequence occurred within central Colorado in response to actively subsiding extensional basins and adjacent high-relief uplift areas. Hot brines developed within the Pennsylvanian strata, migrated laterally to, and moved upward vertically along, basin- margin faults during continued Pennsylvanian subsidence and deposition. These metal-rich brines migrated into karst-solution features within the Lower and Middle Paleozoic dolomites and limestones, principally within the Leadville Formation, in basin- edge uplifted locales where the Pb-Zn-Ag minerals were precipitated. Field relationships, mineral assemblages and paragenesis, fluid-inclusion data, and isotope studies suggest that the metals and brines were derived within the Pennsylvanian sedimentary sequence and that the ore minerals were deposited under different temperatures and at different depths from deposit to deposit. Chemical reaction with the carbonate cave sediment and wallrock, cooling of fluid temperatures, and mixing with meteoric ground waters were the probable combined causes of mineral deposition in the karst-solution features. Late Cretaceous-Tertiary intrusive activity has subsequently modified some of the primary Pb-Zn-Ag deposits in local areas.

Jan 1, 2013

By P. Malozemoff

I have no objection to using mathematics in the value appraisal of properties. The factor that is not emphasized in the paper is that very few important properties have a lifetime that reflects the initial ore reserves of the property divided by the rate of production adopted. In the majority of cases, major properties mine out several times the initial reserves. How much more will be mined out is not known, and only exceptionally gifted geologists can predict that additional reserves will be found. There is the further factor of metals price, which, over the long term, is not predictable. Another factor vitiating making calculations on initially established ore reserves is the speculative nature of exploration success. In my judgment, the life of a property, in addition to an established ore reserve, should include ample time for exploration to find additional reserves. The likelihood of additional reserves is based on the geological promise of the general area where the mine is established. This is especially important because of various risk factors associated with small orebodies, the economic life of which is about five to seven years.

Jan 1, 1993

By Barry R. Doyle, James P. Rose, Marius P. Gronbeck

This paper presents a strategy for addressing the hazards of construction of tunnels in ground containing methane. A discussion of the nature of methane includes occurrence underground, and manner of entry into excavations. Means of methane control for underground operations are discussed, including ventilation, monitoring, equipment selection, and personnel training. Principles of ventilation for gas dispersion and removal are addressed. The use of continuous gas monitors, automatic power shutdown systems, and hand-held detectors is discussed. The paper addresses integration of permissible equipment to provide a safe system. Aspects of personnel training are discussed, including maintaining hazard awareness, and evacuation and re-entry procedures.

Jan 1, 1991

By Y. Nakahiro, T. Wakamatsu, M. S. Elsalmawy

The flotation of quartz, feldspar and alumina was studied as a function of pH when using N-alkyldiamines as collectors. The lengths of alkyl chains of diamines were 8, 9, 10, and 12 carbon atoms. It was found that shorter hydrocarbon chain length of alkyldiamines has stronger tendency to float quartz while the feldspar responded poorly to flotation with these collectors at high pH values. The effect of addition of nonionic surfactant of Brij type, when using dodecadiamine as collector, was investigated. Flotation studies in the absence and in the presence of sodium dodecylsulfonate were carried out. These studies have indicated that sodium dodecylsulfonate, in the concentration studied, functions as strong depressant for feldspar.

Jan 1, 1995

By M. Rossi

The use of service variables in geostatistics (grade-thickness) is common in industry when developing block grade models and geologic resource estimates. This is particularly true in the case of sedimentary and stratabound-type deposits. The approach has proven merits when assessing ore reserves. However, there are cases where its application for preliminary data analysis produces biased estimates. One such case is encountered in uranium disequilibrium studies. This paper demonstrates the inadequacy of service variables when performing uranium disequilibrium studies. Disequilibrium analysis is a necessary preprocessing step when radiation counts are used as raw data to calculate uranium reserves. Typically, a probe is used to obtain the gamma counts from open drill holes. These counts are then regressed (and corrected) against chemical assays obtained from core samples. During this process the grade-thickness variable produces an optimistic image of the relationship between probe grades and chemical (true) grades, causing overestimation of the final geologic resource. The problem is analyzed through a case study.

Jan 1, 1993