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By Elham Najafi, Sina Ghassa, Ata Akcil, Hadi Abdollahi, Sandeep Panda, Zohreh Boroumand

Bioleaching is an environmental friendly process that has gained much interest for the production of metals from metal-bearing wastes or materials. The process decreases carbon footprint by reducing consumption of fossil fuels. Iron is a key factor in acidophilic iron-oxidizing bacteria’s activity, which is used extensively in the bioleaching of sulfide minerals. In the present study, the effect of different iron sources is investigated on sphalerite (ZnS) bioleaching. For this purpose, the effects of FeSO4  .7H2O, Fe2(SO4  )3 and FeS2 (pyrite) were studied on bacterial activity, and zinc (Zn), lead (Pb), cadmium (Cd) and arsenic (As) dissolutions were monitored from a ZnS concentrate. Under optimum conditions, the dissolutions of Zn, Pb, Cd and As were found to be 39.8, 0.1. 0.03 and 10 percent, respectively, in 25 days.

By Elham Najafi, Sina Ghassa, Ata Akcil, Hadi Abdollahi, Sandeep Panda, Zohreh Boroumand

The present study investigates the influence of ferrous iron (as FeSO4) and ferric iron (as Fe2 (SO4)3), and pyrite (FeS2) on the ability of bacterial leaching of a high-grade sulfide Zn–Pb ore. In this regard, shake flask experiments were carried out at 5% (w/v) pulp density of the ore sample (having 40.7% Zn and 12.4% Pb initial metal content) using a consortium of mesophilic iron and sulfur-oxidizing acidophiles. A concentration of 0.04 mol/L of ferric iron in the leaching media was found to be optimum for zinc extraction without affecting growth of the microorganisms. Under this concentration, the dissolution of Zn, Pb, Cd, and As was found to be 57%, 0.2%, 0.03%, and 9.9% in 25 days. Using ferrous iron in the media, 0.16 mol/L of Fe2+ was found to be the optimum concentration for efficient bacterial growth and metal dissolution (54.6% Zn, 0.08% Pb, 0.03% Cd, and 10.2% As) from the sample in 25 days. On the other hand, using pyrite as the source of energy for bacterial growth, an initial 12-day lag period was observed when compared to the effect of ferrous iron in the media. Under the optimum concentration (test with 0.24 mol/L iron in the form of pyrite), the dissolution of Zn, Pb, Cd, and As was found to be 39.8%, 0.1%, 0.03%, and 10% in 25 days. The surface chemistry analysis indicated formation of a sulfur layer over the particle surface that hindered reagent diffusion and affected metal recovery through bioleaching.

By Jewel Andrew Gomes

Arsenic is considered as one of the toxic materials being controlled by Environmental Protection Agencies in several developed and developing countries. It is found in the nature as constituents of the soil, minerals and also in various organic forms. It enters the air, water, and land from wind-blown dust and gets into water from runoff, leaching, soil erosion and anthropogenically from chemicals used for wood preservation, insecticides, medicine, military purpose, pigments, and electronic circuitries. There are several techniques available for removal of Arsenic, such as coagulation/filtration, lime softening, ion exchange, reverse osmosis, nanofiltration, wet chemical, and electrochemical. Electrocoagulation has been found as one of the most efficient techniques to remove inorganic arsenic with more than 99% efficiency. In this paper, we present our work on electrochemical treatment of both the inorganic and organic arsenic from water using various sacrificial electrode materials, i.e., iron, aluminum, copper, and combination of them. The floc produced by this method has been also characterized using XRD, SEM/EDS, FTIR, and cyclic voltammetry.

Jan 1, 2010

By Robert M. Cox

The principal factor that must be determined for the effective design of a coal mine roof bolt support system is the maximum stable tension that can be developed with a given bolt assembly in a particular roof rock. There are four basic types of roof bolt anchorage techniques available: (I) the splitwedge; (2) mechanical expansion units; (3) resin point anchors or grouted expansion units; and (4) the cone shell which is placed in a reamed hole. A study of this problem has been made which includes theoretical analyses, laboratory experiments and field tests. A static free-body analysis of each of the anchorage techniques has provided formulas for predicting the anchorage capacity for a particular rock from the results of standard pull tests. The formulas also provide an insight into the anchorage mechanism of technique and allow for a comparative evaluation of the methods for design purposes. The theoretical analyses also indicate clearly the pertinent variables affecting the anchorage mechanism of each method.

Jan 1, 1977

By Richard C. Corson

The objective of blending materials in a bedding pile is to reduce the variation in successive samples taken from the materials to be blended. In designing a bedding and reclaiming operation, several mechanisms are available to effect the reduction of variability, or increase in homogeneity, of the materials. These mechanisms can act before stacking, in the stacking process, in reclaiming and after reclaiming. In evaluating alternative methods of stacking and reclaiming, the potential user must judge each method on the basis of certain criteria; the capital cost of the equipment, the allowable absolute variability of the reclaimed product and the effectiveness of blending. Several stacking and reclaiming methods have been tested using a computer simulation. Based on the results of this program, factors were developed to describe the effectiveness of blending for chevron stacking of discrete materials and preblended materials, bucket wheel reclaiming and drum reclaiming. From these factors, the total effectiveness of a combined stacking and reclaiming system can be determined.

Jan 1, 1985

By R. V. Ramani, J. M. Mutmansky, P. C. Luna, V. A. Marple, Honglin He, B. A. Olson

The development of a sampling instrument for the assessment of an underground coal miner’s exposure to airborne respirable coal mine dust on a continuous and real-time basis has been long identified as essential for timely initiation of control actions. A respirable dust dosimeter (RDD) which operates on the principle of increasing pressure across a filter media with increasing dust mass on the filter has been developed by the National Institute for Occupational Safety and Health. Comparisons of the performance of the RDD with an U.S. approved gravimetric respirable dust sampler (GRD) have shown that the RDD may meet the requirements for measuring miners’ exposures on a cumulative, near real-time basis such as mid-shift and end of shift exposures. Recently, the performances of the RDD and GRD were compared by conducting side-by-side area sampling experiments in a controlled experimental environment in the laboratory and in underground coal mines under normal operating conditions. In this paper, the results from the in-mine study are presented and discussed. The experimental design for the in-mine study included two mines in different coal seams in different geographic coal regions. To ensure a wide range of concentrations, the experiments were conducted in a continuous miner section in Mine 1, and a longwall face in Mine 2. Airborne dust sampling was conducted for four different shifts at each mine. In each shift, two samples of different exposure durations were collected from two different locations. Each sample consisted of the readings of three dosimeters and the exposed filters from the three paired GRD samplers. As a result, a total of 96 comparative samples were obtained, 48 for each mine. The data were analyzed for the precision of the RDD and GRD measurements and for the relationships between the differential pressure of the RDD and the mass of dust on the paired GRD filter. The analyses indicate that, on the average, the RDD and the GRD track the airborne respirable dust concentrations well, exhibiting both a high correlation between the two measurements and a reliable predictive relationship of one from the other. Details of the experimental design, data analyses procedures, results, conclusions and recommendations of the underground experiments are presented in this paper.

By P. N. Anyalebechi

A comparative study of the mechanical properties of automotive steering knuckles produced by three different shape-casting related processes has been conducted. It involved the characterization of the tensile and fatigue properties of aluminum alloy A356 knuckles produced by the vacuum/pressure riserless casting (VRC/PRC), pressure counter pressure casting (PCPC), and the hybrid Cobapress (a casting-forging) processes, in accordance with the appropriate ASTM standards. Surprisingly, the knuckles produced by the hybrid Cobapress process exhibited the lowest strength. For example, the average 0.2% yield strength of the Cobapress knuckles was 31 MPa and 40 MPa less than that of the VRC/PRC and PCPC knuckles, respectively. However, between stresses of 150-200 MPa, the fatigue lives of the VRC/PRC, PCPC, and Cobapress knuckles were comparable. But above 200 MPa, the Cobapress knuckles exhibited the lowest fatigue life. The observed differences in the mechanical properties are attributed to the inherently different microstructures of the different knuckles.

Jan 1, 2009

Obvious differences in mineral deposit types occurring in Outer Melanesia and Northern Chile can be related to the sub- marine-dominated nature of volcanism in the' former area and the subaerial-dominated nature in the latter area. Subtle variations in subvolcanic epithermal-porphyry ore systems between the two areas probably result from differing ore fluid compositions. Hydrother- mal convection cells in Outer Melanesia will be seawater-dominated, consequently rela- tively high salinities and chlorine contents will characterise the ore solutions. Trans- portation of metals as chloride complexes is likely and the ease of seawater sulphate reduction to sulphide in the ore systems will lead to widespread, sparse dissemination of sulphide minerals. Relatively low grade por- phyry copper deposits will typify these ore systems. In Northern Chile hydrothermal convection cells will usually be dominated by meteoric waters. Consequently ore fluid salinities are likely to be lower and chlorine will be less abundant. Under these circum- stances transport of ore metals as bisulphide complexes could be important. Boiling and loss of H2S gas from these fluids would lead to rapid precipitation of metals and higher grade deposits. Erosion rate is a very important factor in the preservation of ore deposits and this may be the major control on the richness of a metallogenic province. The abundance of mineral deposits in the El Salvador region of Northern Chile compared to Fiji is probably a function of the much lower rates of erosion in the former area.

Jan 1, 1987

By Gordon C. Gutrath

Queenstake Resources Ltd. has been exploring and mining alluvial gold deposits in the Yukon Territory and British Columbia since 1980. The five mines in production produced, in 1987, a total of 13,222 ounces. This paper will briefly review Queenstake's exploration program, property descriptions and mining methods, environmental concerns and a comparison of costs. (Sueenstake has been successful in developing a cash flow base from these operations that provide the capital for the acquisition and exploration of new, and hopefully, larger scale gold producers. NOTE: The historic alluvial mining unit of ounces per cubic yard and English units of measurement have been used throughout this paper. Dollars are Canadian unless otherwise noted.

Jan 1, 1988

By A. Mazhary

"Although sensor-based ore sorting has gained significant attention recently, sorting gold deposits still face a high level of skepticism by gold mining companies. In order to shed some light on the matter, this article looks at two different gold deposits that were examined using X-ray Fluorescence, Electromagnetic and X-ray Transmission sensors. The heterogeneity of each sample is measured based on the assay results of each particle and is related to its sortability. Multivariate linear regression analysis was also performed on the XRF results to find potential proxy elements for detecting gold. The results from these deposits were varied and each sample showed different levels of sortability. While both X-ray sensors proved efficient for different deposits, the electromagnetic sensor failed to produce any promising results. Despite unsatisfactory result for one sample, this technology can have significant advantages in terms of lowering the operational costs and improving head grades and recoveries providing that the deposit is amenable to such separation methods. Therefore, it is important to mention that sensor-based ore sorting is ore and sensor dependent, and as a result, it cannot be applied and be beneficial to all deposits. Therefore, amenability tests are required in order to examine the potential for sensor-based ore sorting before one can reject the idea.INTRODUCTION Although sensor-based ore sorting has gained significant attention recently, sorting gold deposits still face a high level of skepticism by gold mining companies. Except for a few cases presented previously, no new case studies have been published. Previously, mines such as Kloof Gold Mine in South Africa used an optical sorter to sort their waste stockpile in 2003–2004 (Von Ketelhodt, 2009) and then again in 2009 (Von Ketelhodt, Falcon, & Falcon, 2011). More recently, Coeur Operations utilized an XRT sorter for their Kensington Mine in Alaska (Lasley, 2014) and also Anglo-American Platinum used an XRF sorter to pre-concentrate Platinum Group Metals through an algorithm that used chrome, copper and nickel as proxies (Rule, Fouchee, & Swart, 2015)."

Jan 1, 2017

By S. Aguayo-Salinas, J. L. Valenzuela-García, A. L. Leal-Cruz, M. I. Pech-Canul, M. T. Certucha-Barragán

"The aim of this research was to carry out a comparative and systematic study of the degradation of cyanide by hybrid natural/biodegradation and biodegradation methods using a mixture of Pseudomonas sp and Bacillus megaterium native bacteria. Bioreactors consist of filled columns with contaminated ore containing 100 ppm of total cyanide. In the biodegradation tests a mixture of bacteria was inoculated into the biodegrading solution. Results of cyanide degradation show a similar asymptotic behavior in both the hybrid (opened system) and biodegradation (closed system) methods; however, for the same period of time (72 h) the permissible maximum levels (1-2 ppm of cyanide) are only attained in the closed system. While in the closed system the cyanide levels are reduced from 100 to 1.5 ppm, in the open system, cyanide decreases from 100 to 2.4 ppm.IntroductionOne of the most important tasks of mining industry is the treatment of the wastes generated in mining operations. Accordingly, industrial waste waters and ores represent a complex problem and a great challenge. In addition to ethic and communitarian considerations, there are laws that prohibit or regulate the contamination of water and air. Moreover, they establish that the restoration of wastes must be considered as a necessary operation cost [1]. Currently this important problem is being addressed by the mining and metallurgical industries using different approaches; mainly they are focusing on the treatment of waste waters and ores generated by the leaching process in which cyanide is used as a leaching agent for the recovery of precious metals as gold and silver. Cyanides have toxic characteristics and thus negatively impact the environment when they are discharged to the ground without previous treatment. While there are some processes in current use there are others that have only been proposed and that allow cyanide degradation, transformation to less toxic compounds and/or the complete elimination of cyanide. The second group includes a variety of techniques that use natural, chemical and biological treatments. Natural treatments consist of the passive abandoning of the heap and of its washing with water. Since these processes are slow and generate great volumes of water partially contaminated, then other alternatives should be considered."

Jan 1, 2008

By W. H. Holtzhausen

The purpose of this project was to compare two underground, batch coal haulers ? battery haulers and shuttle cars ? in order to determine the more viable machine to implement. The specific standards for battery haulers were investigated and compared to the requirements of shuttle cars in order to identify the unnecessary expenses related to the legal requirements that are attached to the machines. Costs such as running costs, capital costs, and maintenance costs were researched and compared over a typical life of machine. Average production rates and breakdown times were obtained and used to determine which machine would be more reliable in achieving the required annual production.

Jan 1, 2014

By Akira Miura, Katsuyuki Sato, Yuken Fukano

JX Nippon Mining and Metals Corporation has developed the JX Iodine Process, which is an innovative and patented copper-leaching process for low-grade primary sulfide ores. This process consists of the irrigation of ferric iron and a low concentration of iodide solutions. One-meter column leaching tests were conducted on ore samples from two different mines. At the end of experiments, the total copper recovery exceeded 70% for Sample A and 50% for Sample B with the iodine method, which was significantly higher than that with conventional ferric leaching of 14% for Sample A and 20% for Sample B. To elucidate the reason for the JX Iodine Process effectiveness, cross sections of leached residues were studied. Reaction products were confirmed around chalcopyrite even in the central area of particles in Sample A, however, reaction products were recognized at a depth of only 1 mm from the ore rim in Sample The resistance of Sample A to the leachate appeared to be lower than that of Sample B because Sample A had a high permeability and porosity, whereas Sample B had been affected strongly by a potassium alteration. No reaction products were visible on conventional leaching samples, even at the ore surfaces. INTRODUCTION Hydrometallurgical copper leaching (heap leaching or dump leaching) has been used extensively for copper recovery from oxide and secondary-sulfide ores, but not for primary copper sulfides, which contain mainly chalcopyrite as copper minerals. Although they are major resources of copper, primary copper sulfides are difficult to process because of their refractory nature. Extensive leaching studies have been carried out to leach primary copper sulfides (chalcopyrite), including biological and chemical, using a variety of oxidants and additives to enhance copper recovery. Watling (2013) reviewed acid-chloride-oxidizing agents with chalcopyrite. Abdollahi et al. (2015) tested silver as a catalyst for bioleaching with a chalcopyrite-bearing molybdenite concentrate. Hiroyoshi, Miki, Hirajima and Tsunekawa (2000) found a specific redox-potential zone for high-speed chalcopyrite leaching by controlling the ratio of ferric and ferrous iron. However, no ambient-temperature economic process has been developed for leaching primary copper sulfide, which usually has a low copper grade.

Jan 1, 2019

By Chu Bo-Yi

"This paper contains a comparison of creep-feed and shallow-cut grinding on ceramics with both neat oil and water-based grinding fluids. When a water-based grinding fluid was used in creep-feed grinding on ceramics the vertical forces and specific energies increased markedly fast with result that the wheel surface was damaged seriously. Creep-feed grinding on ceramics with neat oil not only produced much lower grinding forces and specific energies but also resulted in the wheel remaining in good condition and minimizing damage to the ground surface. This finding may lead to a deeper understanding of the behaviors of grinding fluids in grinding processes both on ceramics and metal as well.1. IntroductionAs advanced ceramics are obtaining more and more applications in the technical area, some machining processes are needed after the sintering to reach the accuracy and finish required by components. Because of higher hardness and brittle behaviors of modem ceramic many researches have been done in order to improve grinding efficiency and surface quality.In the grinding metals the concept of creep-feed grinding has been developed in industry as a real alternative to the normal method of shallow-cut grinding. In addition to the general economic advantages, dimensional accuracy and surface integrity are invariable improved using the creep-feed grinding technique.In grinding ceramics former studies have done many works on both creep-feed and shallow-cut grinding on ceramics with water-based grinding fluids since the water-based were thought to be better coolants than neat oil in most tests of grinding metals[l]. It was suggested that the specific grinding energies of ceramics are markedly higher in creep-feed grinding. The grinding force increases vary rapidly with time in the creep-feed case. In other words, so-called speed stroke grinding with high workpiece speed is considered more suitable for improving the grinding efficiency [2][3]."

Jan 1, 1998

By Felipe P. D. Lopes, Ailton Silva Ferreira, Sergio N. Monteiro

"Environmental issues such as global warming and water pollution are motivating fast changes in scientific and technological paradigms. Special importance is now being given to the so called environmentally friendly materials, which are renewable, recyclable and biodegradable. An example is the natural fibers with increasing industrial applications beyond the conventional uses as baskets, fabrics, ropes and carpets. In addition to traditional natural fibers, others like curaua (Ananas erectifolius) are being investigated for possible use as reinforcement of industrial composites. Since epoxy matrix is not yet incorporated with curaua fibers, the objective of this paper was to study the basic properties of epoxy composites reinforced with different amounts of curaua waste fibers. A comparative analysis aiming at the use of these composites as substitute for conventional building materials was carried out.IntroductionThis new millennium, which initiates with the 21th century, is experiencing a fast degradation of the environment by pollution and climate changes. Most of the problems are related to our methods of development associated with the use of fossil fuels and the energy intensive processing and production of synthetic materials. As a consequence, environmental issues such as global warming and ocean pollution are motivating rapid changes in technological paradigms. One relevant example is the current importance given to natural materials like the lignocellulosic fibers extracted from cultivated plants or found as industrial wastes [1]. These fibers are considered environmentally correct alternatives to substitute energy intensive conventional synthetic fibers such as carbon, glass, nylon and aramid. In addition to the renewable recyclable and biodegradable nature of the lignocellulosic fibers, the low cost and abundance in developing regions are major advantages that justify their increasing application as reinforcement of composites [2,3].In fact, nowadays, the use of natural fibers is no longer restricted to baskets, ropes, clothes and carpets. Industrial composites are introducing these fibers in large technological segments associated with car making, building construction and furniture [4,5]."

Jan 1, 2008

By Brenchley R

Partitioning behaviour studies for -particles in the 250 to 1,000 micron size range at. the Curragh coal preparation plant are presented. Plant surveys were conducted to compare the partitioning efficiencies of dense medium cyclones and froth flotation. The aim was to assess the potential for improving yield of coal by directing more of the top size of flotation feed material to dense medium cyclones. ovel mass balancing and model fitting NI procedures were used. While flotation offers high yield of low ash particles smaller than 500 microns, dense medium cyclone rejection .of high ash particles larger than 250 microns is superior. These strengths of the two processes are turned to good advantage by the use or desliming sieve bends which tend to perform some density separation on the'size fractions of interest, directing lower ash material to froth flotation than to the dense medium cyclones.

Jan 1, 1987

By M. J. Nicol

This paper ,examines the kinetics of the extraction of uranium from acid sulphate solutions by strongbase anionexchange resins. Parameters such as the concentration of uranium in solution. the agitation of the resin beads in solution. the size of the resin beads. and the degree of cross-linking within the resin matrix were varied. and the effec ts on the kinetics are reported. The applicability, of various empirical kinetic models to the description of the data is assessed, and an attempt is made at the modelling of the rate data in terms of established theories about the diffusion of ions through films of stagnant liquid and through spherical beads of resin.

Jan 1, 1980

By K M. P Singh, K M. K Sinha, G S. Jha, T Gouricharan, K K. Sharma

The majority of the powerplants in India are fed with non-coking coals, with the coals dispatched from their respective mines via wagons loaded by a rapid loading system or pay loader. The usual top size of coal is 200 mm and sampling is carried out manually from wagons. The manual method of wagon top sampling of large size raw coal is not only difficult, but also violates some of the fundamental principles of sampling. As per sampling requirements, samples are to be drawn from the full depth of the wagons, which is impossible to be done manually. Since the ash distribution in the different size fractions is not homogeneous, the results from the samples, which do not reflect the true size distribution of the lot, are likely to be biased. More importantly, sample collection by shovel from the top is a function of human discretion and not governed by the equiprobability rule. In another case, the sample has been collected by a cross belt-type auto mechanical sampler for 200 mm size coal at one of the super thermal power stations. Test analysis shows that coal collected using a cross belt-type mechanical sampler also has significant deviations from stopped belt coal samples of 200 mm size due to size segregation. Studies carried out on wagon top sampling through specially designed experiments reveal some interesting features. The presence of bias in wagon top sampling is apparent when compared with the ‘stopped belt’ sample. In this paper, a comparative study between manual wagon top sampling/auto mechanical sampling with respect to stopped belt sampling has been conducted for coal of size 200 mm. In addition, precision studies have been performed for wagon top sampling/mechanical sampling for Indian thermal powerplants.CITATION:Sinha, K M K, Sharma, K K, Jha, G S, Singh, K M P and Gouricharan, T, 2014. A comparative study of manual wagon top sampling and auto mechanical sampling of 200 mm size coal with respect to stopped belt sampling of thermal coal at Indian super thermal powerplants, in Proceedings Sampling 2014 , pp 43–48 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 29, 2014

By J. C. Huyhua

The effect or various oxidants on gold and silver dissolution in thiourea solutions (0.05 M in H2SO4) was studied using the rotating disc technique, a.t 2s c and 600 rpm. These studies were carried out at constant (4:1) initial molar ratio or thiourea to oxidant concentrations, to produce 50 % thiourea. oxidation. The initial dissolution rate of gold was approximately four times higher in the presence. of ferric sulfate (5.37 x 10-3mg cm-2 s-1) than in the presence of hydrogen peroxide (H2O2), potassium persultate (K2S2O3), or monopersulfa.te (KHS06). The dissolution rates for silver were considerably lower than gold for the same oxidants. Oxidation of thiourea in the presence of peroxygen and persulta.te compounds is a. fast reaction and it is completed in less than ten minutes. On the other hand, the oxidation or thiourea with? ferric.sulfate is slow, yielding a second-order reaction rate constant k = 6.09 I mol-1 h-1. Sulfur formation in the ferric thiourea system begins when ferric ion reduction approaches to completion. With hydrogen peroxide, sulfur is observed at lower thiourea concentration than ferric. Suifate. The presence of a large excess or free thiourea i.e., s to 20 % thiourea oxidation) retards sulfur formation and maintains favorable dissolution rates. Finally, carbon-in-leach experiments indicate that thiourea solutions a.re stable for several days, with ferric sulfate or hydrogen peroxide. The dissolution rates of gold and silver doubles in the presence or activated carbon when hydrogen peroxide is used as oxidant.

Jan 1, 1989

By Andrew Wetherelt

Blast vibrations are of paramount importance in a society where ever increasing development is putting more stringent requirements on their control. Increasing civil development and more complex extraction scenarios make the trade off between proficient vibration control and productivity difficult to ascertain. Historically, reduction of induced vibrations levels was achieved through a reduction of MIC’s leading to smaller but more frequent blasts in order to meet extraction targets.

Jan 1, 2007