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By K. Adham

Both the dry and the wet fluorination systems require hydrogen fluoride (HF) for the process of uranium conversion to uranium hexafluoride (UF6). The dry methods depend on the electrolysis of HF to generate the fluorine (F2) required for the high temperature pyro-fluorination. The wet methods require aqueous HF in water solutions for the low temperature hydro-fluorination (Argonne, 2019). This paper uses the available HF safety guidelines and industry information to discuss the issues of transportation, storage and utilization. Health effects and environmental considerations are reviewed. Safe practices for handling the HF (both as anhydrous and as aqueous) are considered. Proper selection of different materials of construction are discussed, for both the anhydrous and the aqueous HF.

Jan 1, 2020

By C. Holmes, T. Holmes

Engineered-in material handling problems are responsible for significant unrealized value in mineral processing plants. At the root, is a lack of awareness and understanding of bulk material handling science and how important it is, especially in early design stages. Mineral processes add value to mined raw feedstock through physical and chemical transformations in unit operations, but only if the material can flow through them. Essentially, each unit operation receives a unique feedstock and produces a unique product to be collected, transported, and fed into the next unit operation. Such material-handling systems can only be expected to achieve design throughput if the system equipment is designed to the materials’ characteristics, over their full range of conditions. This requires quantification of flow properties to support the necessary customized equipment designs. Too often, assumptions or “library values” of a material’s properties are used as the basis for flow modelling and conceptual, and sometimes even detailed, design. This is especially true for hazardous materials like uranium ore, for which the additional precautions, costs, and time necessary for safe handling are often used to rationalize postponing or even bypassing testing. The surprises that often transpire in the wake of insufficient material handling consideration can have acute and costly effects. Fortunately, there is a better way.

Jan 1, 2020

By M. Vaillé, B. Bossé, N. Durupt, A. Michaut

Imouraren is a sedimentary uranium deposit (> 150,000 tU @ 800 ppm), located approximately 100 km North-Northwest of Agadez (Niger); its depth reaches 110 to 170 meters. For low-grades ores, heap leaching is commonly considered as the appropriate technology for metal recovery. More precisely, the ore is crushed (≤ 300 mm) and agglomerated before being stacked. In this case, sulfuric acid can be added during agglomeration and/or irrigation (for three months to a year) to improve uranium recovery. It is known that mineralogical, chemical and physical properties of the uranium ore impact recovery, yet many challenges remain to increase recovery using this process. For example, ore heterogeneity and spatial variability (e.g., variation in uranium, carbonate and/or clay contents) can affect heap leaching performances (i.e., metal recovery, acid consumption or neutralization, percolation rate). However, laboratory column tests using composite ore sample that do not consider ore heterogeneity are widely used to anticipate recovery. Consequently, a new approach that consists in using Imouraren drill core ore samples was recently investigated. This latter also enabled a better assessment of the main parameters that influence uranium recovery and proposed a new predictive model to optimize mining operations.

Jan 1, 2020

By A. D. Burns, K. M. Nikolaisen

Electrolytic reduction followed by the addition of sulfuric acid and the application of heat can be used to selectively crystallize uranous sulfate from solution. This approach, when coupled with downstream thermal decomposition, forms the basis of a process for primary uranium recovery and purification where much of the sulfuric acid value can be recovered and recycled. In this process, a purified uranium (VI) leach solution is first electrolytically reduced to uranium (IV) in a membrane electrolysis cell. Sulfuric acid is then added to the solution which, in conjunction with the input of heat, causes the crystallization of uranous sulfate tetrahydrate. The precipitate is then dried and thermally decomposed to U3O8, which releases a mixture of high-purity SO2, SO3, oxygen, and water vapour. This gas can be recovered as sulfuric acid in an existing acid plant, processed through a new wet sulfuric acid process, or absorbed directly into the upstream electrolyte as a substitute for fresh acid in the crystallization step. This process has been shown to be practical, efficient, and cost-effective on the laboratory scale, and could be practiced on the industrial scale using commercially available equipment. This paper focuses on the thermal decomposition process and options for acid recovery.

Jan 1, 2020

By B. Holaday, H. McLaughlin

Orano Canada Inc. (Orano) operates the McClean Lake mill, located in the Athabasca Basin region of northern Saskatchewan. It processes high concentration uranium ore, delivered in slurry form from the Cameco Corporation operated Cigar Lake mine. After the ore slurry is leached at the McClean Lake mill, the leach residue solids are washed in a process known as counter-current decantation (CCD). This process uses six thickeners to facilitate counter-current washing of solids with diluted acid, flocculation and settling, as well as pumping the washed leach residue to the tailings neutralization circuit (TN), and the uranium laden aqueous to the solvent extraction circuit (SX). Challenges in settling the slurry in CCD started in early 2017. This is largely due to the variation in fines content of the slurry (D80≤75μm), and clay content. There are several changes that have allowed the mill to adapt to the evolving challenges of settling leached Cigar Lake leach residue. Flocculant selection and mixing, temperature effects, bed level management philosophy, and centre-well feed density are key parameters that have been explored as part of adapting to changes in Cigar Lake ore quality.

Jan 1, 2020

By A. Kobzhanov, S. Saparova, S. Brochot, D. A. Mango

KATCO (an ORANO Mining and Kazatomprom joint venture) is the largest in-situ leach uranium mining operation in the world, exploiting the Muyunkum and Tortkuduk uranium deposits in southern Kazakhstan. After extraction from the deposits, uranium is then transported via a hydraulic network to be purified in three processing plants located near these deposits. Within KATCO, with the support of ORANO Mining and CASPEO, in 2018 and 2019, a large project that had as its main objective to improve the uranium accounting system was implemented. The objective of this paper is to describe this project and all the changes that it entailed. At KATCO plants, a black-box approach was previously used for uranium accounting. However, it is recommended to use all the available measurements and to deploy a data reconciliation model (between well-fields and plant) as the reconciliation uncertainty is overall lower and it provides a more accurate uranium balance. During the deployment of this project, the rules and algorithms to generate the uranium accounting report, the associated flow diagrams (for uranium accounting), the streams, units of operation, stocks, reporting and Key Performance Indicators calculation rules were re-defined.

Jan 1, 2020

By Lisa L. Van Loon, Neil R. Banerjee

Canada is a world leader in uranium exploration, but many deposits are located in remote regions making exploration targeting challenging. Novel approaches are needed to detect the presence of large-scale ore-forming systems and to vector toward mineralization. Boron is commonly used as a key pathfinder element associated with sandstone/unconformity-hosted and basement-hosted uranium deposits in the Athabasca Basin, but the genetic relationship remains uncertain. Alteration assemblages containing boron geochemical anomalies are commonly spatially-associated with – and possibly coeval with – uranium mineralization. Boron is commonly found in tourmaline minerals but in some portions of ore deposits the host mineral for the anomalous boron remains cryptic. Boron coordination chemistry within alteration haloes can better constrain boron host mineralogy, provide insight into the nature of the boron-uranium relationship, and thus has the potential to better constrain targets for exploration. Synchrotron-source X-ray absorption near-edge structure (XANES) spectroscopy is a direct, element-specific analysis that identifies boron coordinated in both trigonally- (BO3) and tetrahedrally-coordinated (BO4) forms. This makes XANES uniquely suited for identifying the geochemical hosts for boron that may be related to hydrothermal ore forming processes. XANES spectroscopy was conducted on whole-rock assay powders from uranium deposits across the Athabasca basin containing boron concentrations ranging from <10 ppm to >10,000 ppm. XANES directly identifies the relative amount of trigonally- (BO3) and tetrahedrally-coordinated (BO4) boron in these complex mineralogical mixtures. Our work suggests a link between boron and uranium that is likely related to the unique physiochemical characteristics of ore bearing fluids that may provide a unique vector to mineralization.

Jan 1, 2020

By Patty Simpson, Sarah Benson

In an effort to improve consistency across the nuclear industry, over the past 10 years the Canadian Standards Association has developed a series of standards related to environmental management at Class 1 nuclear facilities and uranium mines and mills. Canadian uranium mines have been required by the Canadian Nuclear Safety Commission to align their existing monitoring programs with these standards. Orano’s McClean Lake Operation’s monitoring program, which was originally presented in the Environmental Impact Statement in 1991, has evolved through regulatory change, new scientific understanding, additional projects, and experience into a comprehensive set of monitoring requirements for effluent, groundwater, air emissions, and the receiving environment. The exercise of aligning the existing practices with the standards provided an opportunity to review and rationalize the entire program. To document the process the original “Environmental Monitoring Program Design Document” was restructured and developed as both a repository for historical information and monitoring rationalization, and also to be a living document describing on-going studies and supplementary work that are outside of the regular environmental monitoring program and may justify future changes to the program.

Jan 1, 2020

By M. A. Perras, H. A. Kasani, G. Walton

The development of an underground repository for the storage of spent nuclear fuel relies on a multi-barrier system to isolate the used fuel from the environment – ultimately, the biosphere. These barriers include engineered copper and steal canisters, dense bentonite, and the natural rock as well. In order to reduce the potential flow pathway along the excavation induced damage zone, various slots perpendicular to the excavation axis have been proposed. These slots are called cut-off seals and generally are filled with bentonite as it has high swelling potential and very low permeability. Many different geometries have been proposed, but clear guidelines on the selection of the optimum geometry have yet to be developed. In order to assess the optimum geometry, three shapes have been selected for this numerical study, including a trapezoid, a triangle, and a thin rectangular slot. The cut-offs were modelled for a conceptual shaft constructed in the Queenston Formation from Ontario over a stress to strength ratio that has been found at many underground research laboratories. It was found that the excavation of a triangular and thin slot cut-off had the smallest increase in the damage as quantified based on the extensile volumetric strain within the plastic yield zone. Both shapes showed an increase in the damaged zone by 13 cm at a stress to strength ratio of 2.75. The trapezoidal cut-off damage zone increased by 20 cm at the same stress to strength ratio. Further study is required to better define the optimum cut-off shape for wider variety of conditions and other geological formations.

Jan 1, 2020

By R. Jacobs, R. E. L. Pobe

The Moab Khotsong Metallurgical Complex comprises a gold recovery circuit (Noligwa Gold Plant) and a uranium recovery circuit (South Uranium Plant). The metallurgical complex employs the reverse leach technology for the recovery of uranium; specifically, uranium extraction prior to gold using acid leaching processing. The inherent uranium species in the ore are uraninite, coffinite and brannerite. The slurry that has been subjected to the uranium leach is further subjected to solid-liquid separation to separate the uranium in a solution through counter-current decantation and the solids (solids carrying all the gold), which are repulped and returned to the gold plant for gold processing. The uranium leaching process is critical to the uranium playing a pivotal role as a value adding by-product to the gold operation. The benefit of adopting this reverse leach process, for improved gold recovery, is that it exposes gold particles occluded within the uranium matrices and avails them for cyanidation. However, the drive for operational efficiency in uranium extraction must be weighed against the incremental operating cost against the backdrop of depressed spot uranium market prices. Over the years, efforts were directed at maintaining the benefit of extracting uranium to enhance gold recovery and simultaneously, optimising the operating cost model for the uranium operation to remain relevant to the gold operation. The aim of this paper and the corresponding presentation is to give an account of the uranium processing optimisation journey embarked on over the years; namely, the operational tradeoffs made in the process of ensuring that uranium continues to add value to the gold operation. These challenges were faced while striking a fine balance between processing cost and operational efficiencies against the prevailing depressed uranium spot market prices. Mineralogical- and laboratory tests conducted form the support basis for the results and observations articulated in the paper. Keywords: By-products, gold extraction, reverse leach benefit, uranium extraction

Jan 1, 2020

By L Dyer, G. J. Wilkie, P. Walters, B Tadesse, L. Keeney

Grade Engineering® is a term trademarked by the Cooperative Research Centre for Optimising Resource Extraction (CRC ORE) and includes five key levers for upgrading ores and rejecting waste prior to expensive downstream comminution and mineral processing. These five levers include natural deportment, induced deportment, bulk sorting, particle sorting and gravity separation. Over the past ten years, CRC ORE has progressed a range of technologies that exploit these levers from laboratory proof of concept through to large scale demonstration and validation. This paper details the work carried out by CRC ORE and Curtin University for assessing the amenability of an ore for its natural deportment and particle sorting attributes in an Integrated Screening and Particle Sorting (ISPS) Grade Engineering® process. ISPS is seen as a preferred method for Grade Engineering® as compared to individually operated unit operations as the benefits of each can be complementary. Furthermore, it is suggested that integrating the two levers has two important impacts: 1. Firstly, there is a risk that isolated particle sorting test results will be misinterpreted as being representative of the full sample without considering the mass balance impact of high-grade material that might have been lost in the fines fraction. This fine fraction will not be detected through the particle sorter. 2. Secondly, and potentially of more valuable impact, is that the opportunity may exist to upgrade the feed first through determining if there is a concentration of high grade to the fine (or coarse) fraction which can be separated through screening. Undertaking screening in the preparation stage of the particle sorting process will enable analysis and separation of the fine or coarse fractions of a rock mass. The result of this study provides the mining industry with an independent framework for undertaking an Order of Magnitude (ISPS) Grade Engineering® assessment on a range of constituent ore types. Keywords: Grade engineering, particle sorting, grade by size fractionation

Jan 1, 2020

By D. N. Esfahani, K. Khazen, M. Mohammadi

Electrowinning is one of the nickel recovery processes from solutions obtained from the leaching of nickel sources. Every year significant amounts of nickel products are used in various industrial processes and daily life, such as catalysts or batteries, which are a valuable source of nickel for recovery. Nickel purity is also very important in the electrowinning process, because the amount of impurities in nickel such as sulphur, if greater than 100 ppm, make it unsuitable for use in catalysts and plating. Because sulfur is intrinsic to the sulphate electrowinning system, we needed to investigate parameters that can affect the quality and purity of nickel. In this regard, experiments were performed in static and circulating electrowinning processes. A monitoring and circulation system was designed and built to measure voltage, current and temperature as well as to circulate the solution in the system at a specified rate. It was then observed that nickel ion concentration, pH, using the circulation system and additives, were factors affecting the purity and quality of nickel, and in the best case the amount of sulphur in nickel was below 100 ppm. Keywords: Nickel, electrowinning, sulphur impurity

Jan 1, 2020

By E. Tabosa, S. Vianna, K. Duffy, W. Valery, B. Andrade, L. Pyle, P. Holtham

Pneumatic flotation cells are high-intensity flotation machines with rapid kinetics, resulting in short residence times. Examples include the Jameson, PneuFlot and ImhoFlot cells. These cells do not use impeller-like mechanical cells. Rather, the air and pulp are mixed in a continuous stream of high fluid velocity through a downcomer or venturi to disperse the air into fine (approximately 0.5 mm) bubbles and maintain particle suspension. Froth wash water is often used to enhance concentrate grade, minimising recovery by entrainment. With the growing application of these types of cells, not only in cleaner stages (their traditional use) but also in pre-flotation and scalping duties, there is a need to predict their performance more accurately for circuit design and optimisation. No widely accepted model for pneumatic flotation cells is available and their metallurgical performance is often scaled up from laboratory and/or pilot plant testing by assuming fixed values for metal recovery, concentrate grade and concentrate percent solids. This paper describes a new approach to simulate pneumatic flotation cell performance and presents case studies demonstrating its applicability. Keywords: Pneumatic flotation, flotation modelling, flotation circuit design, flotation circuit optimisation, Jameson cell

Jan 1, 2020

By B. Nemutudi, X. Zhang, B. McFadzean, P. E. Ngoepe, P. P. Mkhonto, S. Pikinini

The comparison study on adsorption of potassium normal butyl xanthate (PNBX) and sodium (nbutyl) dithiocarbamate (SNBDTC) on sperrylite mineral forms a basis in understanding the floatability improvement and paves a way for the design of collectors that may impact on a wide range of arsenide minerals. This study used a computational density functional theory (DFT) and experimental microcalorimetry approach to determine the adsorption energies of PNBX and SNBDTC collectors onto a sperrylite mineral surface. From a computational aspect, we considered the most stable surface plane of (100) surface, which had been found to give the lowest surface energy, compared to the other surface planes. It was observed that the PNBX and SNBDTC preferred to bridge on the As and Pt atoms through the S atoms. These findings showed that the collector adsorbed on the surface through both Pt and As atoms and indicated that the As atoms were significantly active in the adsorptions. We found that the adsorption energies were in the order: SNBDTC (–278.38 kJ/mol) > PNBX (–270.92 kJ/mol), indicating that the dithiocarbamate had stronger exothermic adsorption than the xanthate. From the microcalorimetry test it was also found that the SNBDTC was more exothermic than the PNBX and the adsorption energies were: SNBDTC (–473.50 kJ/mol) > PNBX (–331.13 kJ/mol). These results showed that the nitrogen atom in the SNBDTC collector had a great influence on the adsorption strength of the collector on the mineral surface. This is due to the electron deposition behaviour of nitrogen atoms compared to the electron withdrawing character of oxygen and as such the SNBDTC showed better collecting ability than the PNBX. These results paved the way for the design of collectors for sperrylite and other arsenide minerals and suggested that nitrogen in a collector may significantly improve the ability of the collector for improved recovery. Keywords: Computational modelling, microcalorimetry, SNBDTC and PNBX collectors, adsorption energies

Jan 1, 2020

By T. Bhambhani, J. Jankolovits

Sphalerite flotation using copper sulfate has been performed in the industry for decades and the mechanism of Cu activation is well established. Despite its ubiquity, many practical questions surrounding copper sulfate persist. It is not clear how iron selectivity is achieved in zinc circuits given the propensity of iron sulfides to be activated by copper. Also, the large variation in copper sulfate dosages across different plants and ore types cannot be explained. Lastly, Zn flotation with greatly reduced copper sulfate dosages attracts significant interest and has been demonstrated in certain laboratory settings, but no information is available on why those laboratory solutions have not been adopted in plant practice. Flotation studies are presented that demonstrate that Zn flotation with very low copper sulfate dosages is possible when using certain novel collectors that are not practised in the industry. However, these reagent schemes are impractical because of a heretofore unappreciated and critical role that copper sulfate plays in Fe rejection. With both very low and standard copper sulfate dosages, copper sulfate influences both Zn flotation and Fe rejection. The results highlight the multifaceted role of copper sulfate in zinc flotation and the need to holistically consider complex systems’ behaviour to understand flotation reagent mechanisms and optimise plant performance. Keywords: Sphalerite flotation, metal activation, copper sulfate, iron rejection

Jan 1, 2020

By J. A. Sweet, T. BACHMANN, G. E. Sandoval, T. M. Hauyon, F. A. Contreras

In many respects a porphyry copper ore concentrator plant can be considered as a simple system. Chalcopyrite typically liberates well at relatively coarse sizes, and even low grade ores are amenable to upgrading 20 to 30 times to produce concentrate grades in excess of 25 % in very simple Rougher- Regrind-Cleaner+Scavenger flotation circuits. The flotation response of chalcopyrite has been well characterised in many fundamental and applied research studies and the conditions necessary to depress pyrite and other floating gangue species are well understood. But what happens to the particle surfaces when you have a 50 km pipeline between the grinding circuit and the flotation plant? How does the seasonal variation in water quality affect your ability to control pulp chemistry? What impact does the relative concentration of the different sulphide species have on their separability? Why do two plants that receive nominally the same ore produce consistently different results? And most importantly, what do you need to do to improve the performance of both plants? To answer these and other questions, a focussed sampling and analysis programme was carried out at the Las Tórtolas flotation plants in 2018 and 2019. The work included full down-the-bank sampling, hot floats, the use of radioactive tracers for determining residence time distribution profiles, gas dispersion measurements, detailed mineralogy by size across the circuits and multiple regrind surveys. This comprehensive study was augmented by analysis of historical mineralogy, geometallurgy and operating data using modern data science techniques, and has provided the foundation for current and future optimisation initiatives. Some of the findings and their implementation will be presented in this paper. Keywords: Circuit optimization, Residence time, Gas dispersion, Pulp chemistry

Jan 1, 2020

By N. Naude, R. Foisy, F. Bornman

Spiral separators have been widely accepted as one of the most flexible gravity separation devices for several decades. The International Journal of Mineral Processing, 84, pp. 118 – 132 mentioned that spirals are for treating material too coarse for flotation and too fine for dense-media separation. Powder Technology V 102, pp 244 – 252, 1999 stated that there exists a genuine need for extending the performance envelope of spirals – whether to treat finer or coarser material than the traditional size ranges. In recent times there has been an upsurge in interest, particularly in the development of newer fine gravity separators. Spiral separators for the recovery of ultra-fine particles have a unique profile, pitch and features to ensure efficient performance. The flow on the spiral trough must be controlled to minimise turbulence that will entrain fine particles in the outer section of the trough. The experimental test work showed a movement of mass from the outer region towards the centre column of the spiral, i.e., from the fine tailings band towards the concentrate. As recovery on the spiral trough is a function of mass yield and grade, the ultra-fine 7 spiral had a better recovery than the HX5. This makes the UF7 an ideal rougher spiral. Keywords: Ultra-fine particles, spiral, design, recovery

Jan 1, 2020

By Y. Tanaka, H. Miki, Y. Aoki, H. Okamoto, G. P. W. Suyantar, T. Hirajima

Due to environmental limitations and the scarcity of freshwater, flotation using seawater or desalinated seawater as process water becomes more common for mining operations. On the other hand, seawater has been reported to affect the flotation behavior of sulfide minerals. Few reports are available on influence of pyrite depression, recycled seawater and lime consumption on flotation by using seawater. In this study, the flotation tests were performed using ore sample to investigate the effect of pH with seawater and process water used in plant on the flotation behavior in a laboratory-scale flotation cell and a pilot plant-scale. The results of laboratory scale flotation indicated that copper and molybdenum flotation kinetics decreased with increasing pH. Furthermore, the iron (mainly pyrite) recovery decreased with increasing pH. The pilot plant-scale flotation test showed that water with a higher concentration of magnesium and calcium (plant processes water) consumed a higher amount of lime. Because of low lime consumption and high copper and molybdenum recovery and grade, pH 8 is suitable compared with pH 8.5 for flotation. Keywords: seawater, process water, copper-molybdenum rougher flotation, pH, pilot test

Jan 1, 2020

By J. E. Gebhardt, B. Temel Mckenna, W. Lee, C. S. Macomber

X-ray diffraction (XRD) data was extracted from various sources to develop qualitative ternary and tetrahedral plots differentiating mineralogy, bond work index (BWi) and hardness of ore bodies at different mine sites. A large number of historic reports and compiled characterization laboratory data were used to create a searchable "data lake." The data lake provides a means to locate, consolidate, and visually represent XRD from disparate sources. Visualizations with large amounts of mineral ore XRD characterization data provide a qualitative assessment of ore properties, including comminution qualities such as material hardness. The visual map can be employed to quickly estimate expected ore character and behavior, given XRD analysis of samples from newly characterized and unfamiliar ore. Keywords: Mineralogy, Characterization, Comminution, Database, Ternary, Tetrahedral

Jan 1, 2020

By F. S. Hoseinian, B. Rezai, E. Kowsari, M. Safari

In order to remove heavy metal ions from a large volume of wastewater with a low ion concentration, ion flotation appears to be promisingly effective. In the ion flotation process, because of the high ion removal percentage, the amount of water recovery percentage is a very important factor which determines the process efficiency. However, ion flotation suffers from relatively high collector concentration to achieve the high removal percentage to the desired limit, which subsequently increases the water recovery. In this study, functionalised graphene oxide (FGO) was synthesised, using a chemical method in the ion flotation process, applied as a collector for increasing process efficiency by reducing the collector consumption and water recovery. The high ion removal was achieved with both collectors of sodium dodecyl sulfate (SDS) and FGO, while the water recovery with a collector of SDS was 3.4% higher than that with a collector of FGO. The results indicated that the FGO could be effectively used for high ion removal and low water recovery in the ion flotation process. Keywords: Ion flotation, synthesised collector, ion removal, wastewater, water recovery

Jan 1, 2020