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By A-A. Bogno, M. Rappaz, J. Valloton, H. Henein

"Rapid solidification of Al-Cu droplets of eutectic composition was carried out using Impulse Atomization in an argon atmosphere, to study the microstructures forming at different cooling rates and undercoolings. Two distinct morphologies were observed within the investigated Al-33wt%Cu droplets microstructures: (i) A regular lamellar morphology and (ii) an undulated morphology. The volume fraction of each type of morphology was measured as a function of the droplet size and the nucleation undercooling was deduced using the hypercooling limit equation. The scale of the microstructures was determined through measurements of inter-lamellar spacing across and along the growth direction. Growth velocity and undercooling were deduced using Jackson and Hunt (1966) eutectic growth theory. Finally, mechanical properties were estimated through micro-hardness analysis using a Vickers hardness tester, revealing exceptional properties for an aluminum-copper alloy. Indeed, the hardness values, increasing with growth rate and undercooling, were 3 times higher than the values obtained in hypo-eutectic Al-Cu alloys.INTRODUCTION Eutectic alloys are very attractive due to their good fluidity allowing ready shaping of parts in casting processes as well as in thermal spray deposition. In addition, they yield microstructures with high mechanical properties, by the virtue of their scale/size which is defined by the solidification parameters and the thermodynamic and thermophysical properties of the given alloy. Therefore, it is important to understand the relationship between the microstructures and the solidification parameters of eutectic alloys in order to control their solidification path and mechanical properties. The latter could be improved by either adding an appropriate strengthening component to a base eutectic material (Böyük, MaraslI, Kaya, ÇadIrlI, & Keslioglu, 2009) or by refining the microstructures for more effective dislocation pinning (Campbell & Campbell, 2003). Tailoring the microstructure can also be beneficial to chemical (Freitas, Osório, Spinelli, & Garcia, 2014; Osório, Freire, Caram, & Garcia, 2012) or electrical (Kaya, 2012) properties of the material. Eutectic-type microstructures, usually formed from liquid (eutectic transformation) or solid (eutectoid transformation), are made up of two or more different phases, generally of lamellar or fibrous (rod like) morphologies (Kurz & Fisher, 1998). In general, a binary eutectic structure can be regular (when both phases are non-faceted) or irregular (one of the two phases is faceted), the two solid phases having roughly the composition of the liquid from which they are formed."

Jan 1, 2017

By Arash Khosravifar, Amalia Giannakou

"Nonlinear foundation springs for bridge caisson foundations show significant coupling between the shear force and bending moment. Implementing foundation stiffness matrix with coupling effects (off-diagonal components) into the global bridge model presents numerical challenges. A simplified approach is developed to model foundation springs including coupling effects using a simple methodology. This simplified model include one translational spring and one rotational spring combined with a rigid link in 2D space. Results show that nonlinear springs (translational, rotational and coupling) can be reasonably captured using this simplified procedure.INTRODUCTIONThe Izmit Bay Bridge is a 3-km long suspension bridge that crosses Izmit Bay in Turkey and is being constructed in a highly seismic region. Figure 1 shows the project location. The South Approach Viaduct (SAV), located along the western margin of Hersek peninsula, is within 5 km from the North Anatolian Fault and within a zone of secondary deformation around the primary trace of the North Anatolian Fault. The proposed SAV consists of 11 Piers and an abutment at the south end of the structure."

Jan 1, 2017

By N. Waters

"Nickel saprolite ores are normally mined as feed to Fe-Ni smelters or Ni matte smelting operations. The smelting processes typically require high Ni cut-off grades of approximately 1.5 to 2.2% Ni, depending on the operation. These very high cut-off grades result in a significant portion of the saprolite profile being regarded as “waste” and hence having little to no value. The Starved Acid Leach Technology (SALT) was developed to recover nickel and cobalt from nickel saprolites and Caron plant residues. Relatively small amounts of acid are applied to ground saprolites or Caron residues in order to selectively leach nickel and cobalt. The leaching is performed atmospherically under low free acid conditions. Nickel and cobalt may be recovered from the leachate as a mixed hydroxide. The mixed hydroxide may be added directly to a saprolite smelting operation or refined separately. InCoR Technologies is advancing the application of SALT at a number of sites. Bench scale testing has provided a relationship between acid addition and nickel extraction in leaching. Conceptual engineering studies have been completed by SNC Lavalin. The simplicity of the SALT technology provides the benefits of low capital and operating cost and an expected rapid ramp up to full production.INTRODUCTION The recent history of hydrometallurgical nickel laterite treatment plants has demonstrated mixed financial and operational performance. Table 1 summarizes the next generation plants built after the financial and/or technical failure of the Bulong, Cawse and Murrin-Murrin plants in Australia. The Coral Bay plants (Line 1 and 2) stand out (and now Taganito) as relatively low capital cost, simple (no acid plant, production of mixed sulfide product), and modest in scale (10, 12 and 36 kt Ni/a). However, the other plants in the list (Ravensthorpe, Ramu, Goro and Ambatovy) are all characterized by financial and technical challenges. All plants have a very high capital cost ($67,000 to $120,000 USD/annual t of Ni production). Ravensthorpe was sold by BHP Billiton after a poor startup. Ramu has had a steady ramp up but only produces mixed hydroxide for refining by others. Goro has had an extended construction period (since 2001), is high cost and has been very slow to ramp up to design production rates. Ambatovy has had a steady ramp up."

Jan 1, 2017

"SART technology is a useful tool for improving the economics of gold recovery from certain types of complex gold ores. SART liberates cyanide consumed by base metals such as copper, zinc and nickel, and enables the newly freed cyanide to be recycled to precious metals leaching while producing high-grade base metal sulphide concentrates for sale. The benefits of SART include the reduction in cyanide consumption, avoidance of cyanide destruction costs, minimization of risks of environmental non-compliance due to residues of cyanide destruction reporting to mine effluents, and generation of extra revenue from the sale of base metal concentrates. Concerns with SART typically include uncertainties around capital and operating costs and proper integration of SART into the overall metallurgical flowsheet. This paper presents two case studies addressing these concerns. The first involves actual costs of the full scale SART integrated into a gold heap leach operation and treating up to 500 m3/hr of leach solution at a mine in Mexico. The second involves field pilot testing and a preliminary cost estimate for integrating SART into a silver mine in Peru using Merrill Crowe.INTRODUCTION One of the current trends in the gold industry globally is the increasing importance of complex polymetallic gold deposits as discoveries of large Carlin type gold deposits become increasingly rare (Sceresini, 2005). The presence of cyanide soluble copper and zinc in complex gold deposits necessitates changes in traditional gold extraction metallurgical flowsheets. One of the tools available to the industry to help deal with interferences of cyanide-soluble base metals in gold extraction is the SART (sulphidization-acidification-recycling-thickening) process. SART breaks the weak acid dissociable (WAD) base metal-cyanide complexes, precipitates the metals as high-grade sulphide concentrates and makes the freed cyanide available for recycle. Although SART is a commercially available technology, it is still relatively new to the industry. Fewer than ten (10) full scale plants have been constructed in the past couple of decades. Some of these SART plants are small, most are located at remote sites, and the majority have not operated on a continuous basis. This has resulted in a general lack of information in the industry about the true costs, operability and metallurgical performance of SART. BQE Water has been involved in the design, construction, commissioning and operation of large scale SART plants in Mexico, Turkey and Chile and has conducted field testing programs as part of the technical assessment of SART integration into various metallurgical circuits. Having built and operated numerous plants utilizing selective sulphide precipitation of heavy metals, BQE Water has gained unique insight into the design and control of the sulphidization stage of SART to minimize costs and ensure high efficiency in cyanide recovery."

Jan 1, 2017

By D. Limpitlaw, A. Alsum, D. Neale

"Ecological footprint analysis (EFA) was first described in 1996 as a measure of carrying capacity appropriated by human activities. EFA is a resource and emissions accounting tool designed to track the demand on the biosphere’s regenerative capacity. Ecological footprints are increasingly used as indicators of organizational and corporate environmental performance and product sustainability. There is a compelling argument to develop an EFA tool for mining companies.To determine the size of a mine’s ecological footprint, land requirements for all categories of consumption and waste discharge must be summed. This land is only made up of the ecologically productive land and water in various classes (cropland, pasture, forests etc.) required on an ongoing basis to provide all energy and material resources consumed and absorb wastes.A challenge in conducting an EFA for a mine is the shortage of accessible data. Undertaking an EFA for a corporation or individual site entails compiling consumption and emissions data (which can be used for other reporting applications). The footprint results themselves highlight the most critical aspects of an organization’s impact on the environment and provide a platform for focusing actions and for educating the workforce to improve their contribution to best-practice operations. This paper discusses the benefits and challenges of undertaking an EFA for a mining company, and provides examples of the various components of ecological footprints associated with mines, as well as showing how an EFA can be used to understand and communicate some of the impacts associated with mining activities.IntroductionFundamental biophysical and economic limits are now being experienced in many countries around the world. Herman Daly, a former World Bank economist, described this scenario as ‘uneconomic growth’, where the costs of growth exceed the benefits (Daly, 2005). This occurs when the economy’s expansion encroaches excessively on the surrounding ecosystem, sacrificing natural capital. Under such conditions the sacrificed natural capital is more valuable that the resulting economic growth. Consequently, the world faces largescale threats to sustainability and especially to the viability and continued existence of the ecosystems that support human settlements (El Zein et al., 2014). In recognition of this sustainability imperative, mining companies are increasingly concerned with their ecological footprint (EF)."

Jan 1, 2017

By Peter Zhang

"Room-and-pillar mining with pillar recovery has historically been associated with more than 25% of all ground-fall fatalities in the underground coal mines of the United States. The risk of ground falls during pillar recovery increases in multiple-seam mining conditions. The hazards associated with pillar recovery in multiple-seam mining include roof cutters, roof falls, rib rolls, coal outbursts, and floor heave. When pillar recovery is planned in multiple seams, it is critical to properly design the mining sequence and panel layout to minimize potential seam interaction. This paper addresses geotechnical considerations for concurrent pillar recovery in two coal seams with 70 ft of interburden under about 1,000 ft of depth of cover.The study finds that, for interburden thickness of 70 ft, the multiple seam mining influence zone in the lower seam is directly under the barrier pillar within about 100 ft from the gob edge of the upper seam. The peak stress in the interburden transfers down at an angle of approximately 20° away from the gob, and the entries and crosscuts in the influence zone are subjected to elevated stress during development and retreat. The study also suggests that, for full pillar recovery in close distance multiple seam scenarios, it is optimal to superimpose the gobs in both seams, but it is not necessary to superimpose the pillars. If the entries and / or crosscuts in the lower seam are developed outside the gob line of the upper seam, additional roof and rib support needs to be considered to account for the elevated stress in the multiple seam influence zone. INTRODUCTION Room-and-pillar mining accounted for about 40% of underground coal production in the United States in 2016. Pillar recovery, practiced in about one-third of the room-and-pillar mines, represents about 10% of the coal mined underground, yet it has historically been associated with more than 25% of all ground fall fatalities (Mark, Chase, and Pappas, 2003). In some U.S. coal fields, particularly central Appalachia, many coal mines are operating under geological conditions with multiple coal seams. The risk of ground falls during pillar recovery increases under multiple-seam mining conditions. The hazards of pillar recovery associated with multiple-seam mining include roof cutters, roof falls, rib rolls, coal outbursts, and floor heave (Mark and Tuchman, 2007; NIOSH, 2010b). Pillar retreating creates abutment pressure, not only in the currently mined seam, but also in the overlying or underlying seams. Multiple-seam interactions become more pronounced as overburden depth increases and interburden thickness decreases. To safely recover the pillars in multiple seams, it is critical to properly plan the mining sequence and panel layout to minimize potential multiple-seam interaction."

Jan 1, 2017

By Stephen Stone, Kerby Dobbs, G. Richard Whittecar, W. Lee Daniels, Zach Agioutantis, Tess Thompson

A common result of Environmental Impact Assessments associated with mining projects is the construction of new wetlands in areas disturbed by mining operations. Where appropriate, this mitigation may be considered an integral part of the mine reclamation process under the principles of sustainable development in the minerals industry. Wetbud is a new tool for estimating wetland water budgets using available weather data and site-specific topographic, soil and geohydrologic data, coupled with mass balance mathematics. Wetbud is primarily intended as a planning tool for use in the design of created wetlands, but it can also be applied to native wetlands or wetland restoration sites where the required input parameters can be specified. Wetbud can be run in its basic form where wetland topography, soil parameters and groundwater flux are simplified, or in the advanced form, where these parameters are included in a more complex approach via integration of the MODFLOW package, a free 3D program that was developed by the United States Geological Survey. Both versions can also include overbank flow hydrology sources and the advanced form can also model sloping and irregular topography. The program downloads weather data from the nearest applicable station and selects appropriate wet-normal-dry (W-N-D) years following a modest user data clean-up step. Wetbud also has the ability to utilize existing short-term (e.g. 6 to 9 months) groundwater data from an up-gradient well to simulate longer-term groundwater level inputs for the selected W-N-D years. In addition, Wetbud features a “Wizard” version that comes pre-loaded with 14 pre-selected weather data sets for all areas of Virginia that can develop a simple monthly water budget in less than 15 minutes – a feature that could be expanded anywhere geographically with historic weather data.

Jan 1, 2017

By R. Barbaroux, J. -M. Lalancette, D. Lemieux, K. Nasrallah, G. Garcia Curiel

"Arsenic released from the lithosphere by mining and metallurgical activities is a growing global environmental concern. Dundee sustainable technologies (“DST”) has developed a processing technology to sequester arsenic by means of vitrification. This method can effectively sequester arsenic trioxide without the need to oxidize from As (III) to As (V). Arsenic oxide is incorporated within a silica glass matrix that is stable as per the Toxicity Leaching Characteristic Procedure (“TCLP”) or EPA Method 1311. In this paper, the conventional treatment of arsenopyrite, commonly referred to as “two-stage roasting”, is discussed along with the options traditionally available for the remediation of the arsenic trioxide by-product. The drawbacks limiting the adoption of this processing flowsheet are discussed and a new processing route is presented for the treatment of arsenopyrite. This new flowsheet outputs an auriferous aluminosilicate highly amenable to gold extraction (> 96%) while eliminating the sulfur dioxide production associated with the second-stage roasting of pyrrhotite and ultimately uses vitrification as a definitive sequestration solution to arsenic trioxide.INTRODUCTION Faced with the depletion of conventional gold ores, the gold industry has witnessed a trend towards the exploitation of arsenical deposits. Arsenic is a naturally occurring metalloid often found in mineralogical association with gold. Many northern Canadian regions, from the Northwest Territories to Northern Manitoba, Northern Ontario and the Abitibi region are facing significant arsenic challenges. Projects are deemed uneconomic or prevented from going into operations due to the costs associated with handling arsenic material and there are penalties imposed to complex concentrates by smelters. In addition, Canadian mining operations have left an environmental legacy of gold tailings with grades typically of up to 9 grams per tonne with no processing solution as they also contain significant arsenic contamination at grades of up to 20%. Table 1 presents a list of Canadian deposits known to contain arsenic."

Jan 1, 2017

By B. Hilscher, P. Nayak, N. Yoon

"The mining industry is currently facing challenges with declining feed grades and is struggling to find solutions to improve the project’s economic value. By means of pre-concentration, ore sorting aims to separate the barren material from the valuable ore to reduce energy consumption and tailings generation, while increasing the feed grade, concentrate grade, mill recovery, and revenue. In addition, ore sorting allows the modification of deposit geometallurgy in order to allow the creation of an optimal mill feed.This paper evaluates the applicability and challenges of ore sorting by utilizing the results from four different mines, and reviews them in detail. The mines include two underground and two open pit mines that are base metal and precioius metal operations. In order to understand the applicability of ore sorting in these operations, initial rock-by-rock test results and different types of assays (atomic adsorption [AA], inductively coupled plasma [ICP], and fire assay) are utilized. Using the assay results, the grade recovery curves for ore sorting are generated and they are further improved by using and developing an ore sorting algorithm, which is discussed in this paper. The application and evaluation of ore sorting in greenfield and brownfield properties will also be discussed.The state of the art ore sorting technologies for both rock-by-rock and bulk sorting are reviewed in this paper. The future technologies on the horizon, including different combinations of sensors, are explained. The sorting technologies include, X-ray transmission (XRT), X-ray fluorescence (XRF), colour, infrared, electromagnetic, and laser induced breakdown spectroscopy (LIBS).IntroductionOre sorting is a sensor-based sorting technique introduced between the excavation stage and processing stage, where the unwanted waste is diverted to the waste dump and only the ore is sent to the mill for further processing. As a result, the quality of the material entering the mill is improved and the dilution of the ore is reduced. In greenfield projects, sensor-based ore sorting provides an opportunity to reduce the capital cost of the project and increase the return on investment (ROI). With most operations currently facing the challenge of finding a high grade deposit, having a sorting unit provides several advantages while keeping the cost at minimum."

Jan 1, 2017

By K. Madhusudan Reddy

"Pile response under combined uplift and lateral load is very important and it is imperative to evaluate the effect of combined loading and only few studies were reported on pile behavior under combined uplift and lateral loads. Model pile made-up of aluminum having an outer and inner diameter of 25.4 mm and 19.4 mm respectively is used. Dimensions of the model steel tank are fixed as 1.0 m x1.0 m x 1.2 m (depth) to avoid the boundary effects under combined lateral and uplift loads. Experiments were carried out on single piles at isolated uplift, isolated lateral loading and combined lateral and uplift loading, embedded in sandy soil. Results indicate that load–deflection behavior is nonlinear for isolated uplift and lateral load tests as well as in case of combined loadings. It is also observed that the behavior of piles under isolated loadings is substantially different when compared to combined loading.INTRODUCTIONPile foundations are generally used to support compressive loads from superstructures. Some structures, like transmission towers, mooring systems for ocean surface or submerged platforms, tall chimneys, jetty structures, etc. are constructed on pile foundations, which have to resist large lateral and uplift loads and moments. The various loads (compressive, lateral and uplift) and moments act on the piles simultaneously rather than isolated manner. There are well-established theoretical methods present to evaluate the pile behaviour under different isolated loadings namely, verticalcompressive, vertical-uplift and lateral (Poulos and Davis, 1980), but there are very limited studies focused on pile behaviour under combined loadings. Though there is good number of studies reported on pile behaviour under combined compressive-lateral and compressive-uplift loadings (Ramasamy, 1974; Jain et al. 1987; Zhang and Small, 1999; Dash and Pise, 2003; Karthigeyan et al. 2006 & 2007; , there are only very few studies reported on pile behaviour under combined uplift and lateral loads. Darr et al. (1990) described an approach to a rational solution of the interaction of pile to combined uplift and lateral loads based on analytical and experimental studies. Influence of cyclic loading was also considered. Narasimha Rao and Prasad (1993) investigated the uplift behaviour of pile anchors subjected to lateral cyclic loading. There were many onshore and offshore situations where lateral cyclic loading may affect both the pullout and lateral loading capacity of pile anchors. Jetty and wharf structures are usually subjected to lateral forces from wave and wind action. If these cyclic lateral loads are acting on the supporting piles, the resulting movement of the upper part of the embedded length of pile may reduce the skin friction. This progressive deterioration in pullout resistance may not be reflected by a pullout test made soon after the installation. Hence, Tomlinson and Woodward (2008) pointed out that a generous safety factor on the ultimate pullout load should be adopted for piles in such situations. Mroueh and Shahrour (2007, 2008) presented a threedimensional finite element analysis of the response of battered piles to the combined lateral and vertical pullout loads. Nevertheless, the model is not validated well due to lack of good experimental data based on rigorous experiments. Thus there is a scope for investigating the effect of lateral load on pile behaviour under uplift load and vice versa based on carefully designed experiments, which is main focus of the present investigation."

Jan 1, 2017

By K. Tobór-Osadnik, M. Wyganowska, A. Manowska

"The behaviour of employees is an essential issue in the field of occupational health and safety. Safe behaviour is to a large extent determined by, apart from motivation and preventive actions, an employee’s attitude towards hazard. Thus, attention should be given to defining employees’ attitudes, and following that, to the possibility of correcting and shaping these attitudes in relation to hazard and obeying occupational health and safety regulations. The authors have focused on the analysis of employee attitudes to health and safety regulations in Polish coal mining companies, taking into consideration earlier research on the behaviour of selected employees. The paper presents the methods used to identify Z-type (passive) behaviour. Next, this behaviour is analysed to identify differences between a Z-type employee (enslaved) and other employees. To conclude, the paper presents a list of possible motivational tools that may be used to encourage occupational health and safety in Z-type employees. IntroductionThe technical state of equipment and conditions in the workplace greatly influence occupational safety. However, the deciding factor influencing the rate of accidents in the workplace is the frequency with which employees practise risky behaviour. Factors such as the social conditioning of conduct and motivation for organizing safe work conditions have been included in the notion of creating a positive culture of work safety. This notion has been approved as one of the main goals in management (Studenski, 1996).Safe behaviour is to a large extent, apart from motivation and preventive actions, determined by an employee’s attitude towards hazard. All actions undertaken in the field of occupational health and safety, including training, motivational systems, or imitation of behaviour resulting from a high culture of occupational safety in a given work environment, will not bring about the desire effects if workers have an inappropriate attitude towards occupational health and safety regulations."

Jan 1, 2017

By Claudio Asioli

"The project’s goal was to construct the Al Ghazala Intercontinental, a multi-use development in the bay area of Tripoli overlooking the Mediterranean Sea. The site of the project is located approximately 500 ft (150 m) from the Mediterranean coast, near the Al Ghazala roundabout in the town center of Tripoli, Libya. The investor of the project was Magna Properties Group, Ltd. – Libya, the main contractor was Man Enterprise S.A.L., and the design and construction management was performed by Dar Al-Handasah Engineering. Trevi S.p.A. was contracted to perform the design and construction of the anchored diaphragm walls and dewatering systems for the excavation of a two-level basement car park, which extends across the full footprint of the site.The site was approximately 640 ft by 230 ft (195 m by 70 m) in plan and nearly flat. The groundwater level typically varies from about 11 ft to 23 ft (3.4 m to 7.0 m) above mean sea level. To construct the required raft foundation, it was necessary to excavate the area down to El. -15.7 ft to -26.3 ft (-4.8 m to -8.0 m), which resulted in an excavation depth ranging from about 27 ft to 39 ft (8.3 m to 12.0 m) below the existing ground surface.Subsurface ConditionsThe subsurface site investigation was performed in three phases by Al-Tamier Engineering Consulting Bureau. During Phase 1, a preliminary investigation was undertaken during the early stages of the project to obtain information about the general stratigraphy and groundwater level at the site. Phase 2 was performed to obtain subsurface information and design parameters, and Phase 3 was performed as a supplementary ground investigation to investigate unexpected ground conditions identified during Phase 2. In total, 14 boreholes were drilled to depths ranging from about 80 ft to 180 ft (24 to 55 m). The generalized subsurface profile is quite heterogeneous, and is predominantly composed of sand with silt and gravel that is underlain by limestone, calcarenite and claystone"

Jan 1, 2017

By Fazel G. Jahromi, Ahmad Ghahreman

"Atmospheric leaching of arsenical sulfide concentrates, and especially enargite leaching, is one of the major challenges within the current hydrometallurgy research area. One of the recent processes developed for sulfide ore treatment is atmospheric leaching in the presence of AF 5, a novel carbon based catalyst, in chloride media. The quantification of different ion concentrations during enargite and chalcopyrite leaching in the presence of AF 5 were measured and the copper recovery rates of 97% and 96% were achieved. The objective of this study is to shed light on the leaching mechanism of the sulfide minerals. Based on the speciation of iron and copper by different titration methods, the AF 5 catalyst first reduced ferric and cupric ions and then oxidized ferrous, cuprous and arsenite ions. The oxidation behavior of the catalyst enhanced the leaching results. The AF 5 catalyst also caused in situ precipitation of scorodite in leaching experiment. The speciation of ions in the chloride media were simulated by Phreeqc software and the dominant species in the leaching solution were determined.INTRODUCTION The hydrometallurgy of copper has been used for several decades and is still under development for more complex copper sulfide minerals due to their refractory nature. Most of the world copper reserves are in the form of chalcopyrite; and enargite is known as a major contaminant. Pyrometallurgical processing of enargite is problematic due to arsenic release and tight environmental regulations (Peacey, Gupta, and Ford n.d.). On the other hand, lower recoveries in the hydrometallurgical processes make most of these processes impractical. Several leaching processes have been developed for the leaching of copper sulfide minerals. Some of the common treatment methods for copper sulfide minerals are pressure oxidation leaching (POX), CESL, Activox, Albion process, atmospheric ferric sulfate leaching, Dynatec, Galvanox, and Hydro copper process (Barr, Defreyne, and Mayhew 2005; Conner and Anderson 2013; D.G. Dixon, Mayne, and Baxter 2008; Hyvärinen and Hämäläinen 2005; Palmer and Johnson 2005; Rohner, Bartsch, and Ngoviky 2012). Generally it is not viable to dissolve copper sulfide minerals at ambient pressure in mild acidic media and dissolution of these refractory minerals requires harsh conditions in the presence of oxidant materials (Biswas and Davenport 2002). Ferric ions have been used as an oxidant in different media in copper sulfide leaching processes. U. S. Bureau of Mines’ Reno Metallurgy Research Center in 1969 (Haver and Wong 1971) investigated ferric chloride leaching of chalcopyrite. Dutrizac and Macdonald (1972) studied ferric sulfate leaching of enargite. Based on this study, 50% of the copper was recovered at 80-85 ºC after 7 days of leaching. Cupric ions can also be used as an oxidant. Parker, Paul, and Power (1981) stated that cupric/cuprous couples are more effective than ferric/ferrous couples in chloride media because they are rapid and reversible. The Hydro Copper process leaches copper sulfide minerals in chloride solution catalyzed by cupric ions. In this process, copper dissolves as cuprous ions in presence of cupric ions (about 10 g/L) (Hyvärinen and Hämäläinen 2005)."

Jan 1, 2017

By Bilgehan Kekec, Sertac Dündar, Niyazi Bilim

"Knowledge of the abrasion resistance of aggregates is important when using them for asphalt and concrete mixes and highway construction materials. In this study, the usability of natural building stone waste as aggregates for different engineering applications was investigated. To this end, test samples were obtained from a number of natural stone quarries and stone cutting factories. The abrasion tests were carried out on the test samples and results were compared between samples. The abrasion strength values were determined with both the Micro-Deval (MDe) and the Los Angeles (LA) abrasion test methods. A correlation coefficient was also determined between the LA and MDe tests results using an appropriate statistical model.Introduction The rapid consumption of natural resources has led researchers to work on the efficient utilization of such resources. To this end one can convert waste into useful raw materials, or determine alternative uses of the industrial waste materials. This has become increasingly important as storing or dumping waste may result in environmental problems. In addition, the use of industrial waste in a different application of the construction industry prevents rapid consumption of limited natural resources and can mitigate environmental problems related to raw material production, Industrial waste such as blast furnace slag, fly ash, building demolition material, marble waste and dismantled asphalt have been used as highway and concrete materials (Ahmed 1993, Ramaswamy and Aziz 1992, Schroeder 1994, Ceylan and Manca 2013, Holtz and Eighmy 2000, Hebhoub et al 2011). It is very important to analyze whether these aggregates are of the required quality in terms of their application and their economic life. This analysis can be carried out using various tests such as the Micro-Deval and the Los Angeles abrasion tests, sieve analysis, durability chemical resistance, peeling and adhesion, and freezing-thawing tests (Erdem et al 1996). Specifications for aggregates also include terms that define the grain shape, cleanliness and surface textures."

Jan 1, 2017

By L. Gutierrez, S. Gering, C. Calderon-Arteaga

"INTRODUCTION Drill and blast (DnB) represents the most important, and sometimes the most costly processes in a mine.. The cost of drilling and blasting operations greatly contributes to the “high cost trends of the overall mining operations” (Afum B. O. and Temeng V. A. 2015). The use of available information to improve the DnB processes can be the difference between a highly expensive process and an optimized one. Mining operations have access to several types of data sets and key information from a wide variety of different systems. This information is normally used to improve, evaluate and apply processes for drilling and blasting. This may include different types of data from the different stages of the process (before, during, and after the drilling and blasting operations), such as hole locations (planned and actual), penetration rates, drill operators, fragmentation (expected and resulting), explosive (design and usage), geology, vibration, and others. This information can be used on its own or combined for further analysis to reduce costs, improve safety, and evaluate results. Fortunately, due to advances in mining software, drill and blast engineers can exploit this data and create reports to evaluate results and improve the DnB process. However, as users start combining information from multiple datasets and establishing standard operating procedures for reporting this data across multiple sites, it becomes valuable to create auditable, automated, and sustainable processes for handling the information. In many cases the task of aggregating and standardizing the data formats has already been completed and is available to consumers via the Enterprise Data Warehouse (EDW). A data warehouse team extracts data from the source systems and transforms it so that it is meaningful for decision support (Barbara H. Wixom, Hugh J. Watson, 2007). Our initial implementation plan for the DnB solution included using data stored at the sites; however we learned early on in the process that much of the work for aggregating and supplying the required data was already completed. The goal for this case study is two-fold: to show how information can be used to make decisions and improve processes, highlighting the value of using an EDW for managing Drill&Blast information; and to discuss how technical challenges encountered during the implementations were resolved. This paper is targeted at users that want to better manage their DnB data or try to set up standardized workflows for using this information. This case study will discuss the process of implementing a DnB workflow at multiple sites within Freeport McMoRan Inc (FMI) using both data at the sites and information available using the EDW. The paper will begin with an overview of the project. The discussion will then describe how DnB processes were used to set up daily workflows in order to provide information for evaluating process and making decisions. The final section will discuss some of the technical challenges and how they were solved, as well as possible next steps for further improving the workflow."

Jan 1, 2017

By S. Castro

Hydrolysis of metallic ions depends on pH and the products of hydrolysis either activate flotation or can lead to inadvertent activation of gangue particles, but can also depress flotation of valuable components. One of the most recently studied topics is the use of seawater in flotation. Seawater is a concentrated NaCl solution (about 0.6 mol/L) that also contains considerable amount of Mg2+ and Ca2+ ions. The hydrolysis products of Mg2+ strongly depress flotation of molybdenite over the pH ranges over which they form in the process water. This effect can be eliminated by removal of hydrolysing ions from the process water or by carrying out the flotation at the pH over which such a hydrolysis can be avoided. The former can be exemplified by prior precipitation of the harmful hydrolysing ions as, for example, in the University of Concepcion Patent. The latter can be exemplified by the use of metabisulfite to depress pyrite in the flotation of Cu-Mo sulfide ores in seawater, the process that is carried out at much lower pH, which avoids formation of Mg2+ hydrolysis products.

Jan 1, 2017

By Eric S. White, Thomas J. Sabourin, Khuram R. Mohib

"This paper presents the challenges associated with the design and construction of a steel sheet pile cofferdam supported with one level of grouted anchors in clean to silty sand with gravel. The initial assessment of the subsurface conditions indicated loose to medium dense soil with intermittent dense to very dense layers with no occurrence of cobbles and boulders. Sheet piles were proposed to be installed to a depth of 24 m below the ground surface to limit dewatering requirements for the cofferdam. During sheet pile installation, refusal of piles occurred at multiple locations forming passages for increased flow into the cofferdam. Modifications were made in the design of the dewatering system as a result of the increased flow. Finite element modeling was used to select the necessary modifications to the dewatering system within the cofferdam. Wells were installed based on the findings of the numerical model. Model simulations showed good comparison with monitoring of the field installed dewatering system.INTRODUCTIONIt is necessary to consider the impact of the ground water, subsurface stratigraphy, strength, and drainage behavior of the soil for the design and construction of cofferdams. This paper presents a case history of the construction of a cofferdam in Northern Ontario, Canada. The project consists of the construction of a powerhouse, intake, and tailrace which will generate around 28 MW of renewable clean energy by diverting water from New Post Creek through a power house and discharge into the Abitibi River. The focus of this paper is the dewatering and excavation support required to permit construction of the powerhouse. The layout of the cofferdam is shown in Fig. 1. The cofferdam for the powerhouse is rectangular in shape with sheet piles on all four sides intended to be driven to the design toe El. 101 m. The east and west walls have a length of 46.3 m. North and south sides are 47.6 m long; and in addition, two cantilever sheet pile walls bound the tailrace on the west side and two cantilever walls were installed on the east for construction of the penstock inlet. The ground surface in the powerhouse cofferdam area, before commencement of sheet pile driving, was brought to El. 125; the ground then slopes up to the East, toward New Post Creek, and the site is bounded on the West by the Abitibi River. 186 pairs of sheet piles were used to create the cofferdam and cantilever walls. The deepest excavation is to elevation 114.4 m. Within the west half of the cofferdam footprint, the base of excavation slopes upward at 3H: 1V to facilitate the tailrace discharge into Abitibi River.SOIL STRATIGRAPHYThe cofferdam design was based on the geotechnical investigation conducted by AECOM (2014) which included two relevant boreholes near the powerhouse footprint. The ground elevation at the time of investigation varied between 131 to 129 m. The material observed to the full depth of investigation was comprised generally of coarse to fine sand and gravelly sand or a sand matrix with gravelly inclusions. Some intermittent layers of clay and silt intrusions were also observed. Generally the soils grade finer away from the river. SPT N60 values were recorded in two borings during the field investigation with values reported from 3 to 92. The in-situ conditions ranged from compact to dense with some loose and some very dense zones. Figure 2 shows the variation in SPT N60 values with elevation."

Jan 1, 2017

By A. Juganda, Jr. Bogin, S. A. Lolon, J. F. Brune, J. W. Grubb

"A longwall gob is mainly filled with broken rocks from the collapsed roof and becomes a porous medium where explosive methane-air mixtures can accumulate. In bleeder ventilation systems, this mixture can migrate out of the gob into the longwall face and other active areas in the mine during barometric or ventilation-induced pressure changes. When external pressures change, the gob does not perceive this disturbance instantly but with a delay due to air flow resistance in the porous gob material. The delay of gob response to outside pressure changes increases the pressure differential across the gob and may cause an outflow of explosive air mixtures from the gob into the adjacent bleeder entries. With computational fluid dynamics (CFD) modeling, researchers at the Colorado School of Mines have evaluated the impact of gob pressure fluctuations on the outgassing of the explosive gas zones (EGZs), the magnitudes and rates of pressure changes, the volumes as well as the potentials location of outgassing if it occurs. INTRODUCTION The air pressure field in underground mines is controlled by many factors such as operating fan settings, ventilation controls, surface atmospheric conditions, and other local events that can intermittently disturb mine pressure, including blasting, roof falls, or inundations. Mine fan settings are rarely changed. Mine atmospheric pressure fluctuations due to adjustments in ventilation controls occur more often during the mining process. Atmospheric conditions and barometric pressures can generate fluctuations in mine pressure on a large scale. Atmospheric pressures change regularly every day but can fluctuate abruptly and become increasingly hazardous in adverse weather conditions. Investigations conducted in coal mines in the United States, Australia, Poland, and South Africa observed higher methane emissions from the gob during periods of falling atmospheric pressures, which led to mine explosions (McIntosh, 1957; Boyer, 1964; Kissell et al., 1973; Fauconnier, 1992; Belle, 2014; Wasilewski, 2014; Lolon et al., 2015). Falling external pressures are understood to cause potential outflow of explosive mixtures from the gob, while rising pressures may push fresh air into the gob. This phenomenon is widely known as gob breathing. The actual processes that trigger gob breathing are not fully understood, nor are the parameters that contribute to the process. Other major events such as roof falls or fan failures can also change the pressure conditions in the mine. In contrast to atmospheric pressure changes, these events can change mine pressures much more rapidly or immediately. TIME LAG AND GOB BREATHING CONCEPT In a bleeder ventilation system, the pressure in the gob is designed to be lower than that of the headgate entries and the longwall face. Air from the gob and gate entries flows towards the tailgate-bleeder returns. When the external pressures are disturbed, this designed pressure arrangement may change, potentially resulting in increased outflow from or inflow into the gob."

Jan 1, 2017

By Christina Pomee, John Parianos

"TOML’s ISA Contract comprises six areas (A-F) that span from 118° to 152° W and from 7° to 15° N or over 70% of the CCZ.During a 2015 exploration cruise, TOML scientists found that the a logging system developed by ISA (2010) was able to be adapted and enhanced, to describe in some detail the varied morphology of nodules both within the TOML areas and between them.The shapes and sizes of nodules seen were then found to relate to substrate type and setting, and thus likely thickness and long-term stability of the geochemically active layer. Consideration of the various processes that might influence growth helps constrain nodule formation further. The nodules effectively record the long-term geochemical conditions that lead to their formation.ISA (International Seabed Authority), 2010. A Geological Model of Polymetallic Nodule Deposits in the Clarion-Clipperton Fracture Zone and Prospector’s Guide for Polymetallic Nodule Deposits in the Clarion-Clipperton Fracture Zone. International Seabed Authority Technical Study: No. 6 ISBN: 978-976-95268-2-2"

Jan 1, 2017

By R. Barbaroux, B. Dubreuil, D. Lemieux, K. Nasrallah, G. Garcia Curiel

"As conventional, base or precious metal ores are being depleted worldwide, the mining industry is being faced with an increasing exploitation of arsenical sulfidic ores. Enargite is a common example. The downstream processing of these ores poses several problems ranging from high smelter penalties to finding economical and environmentally acceptable means of disposing of the arsenic. Several hydrometallurgical processes have been proposed for extracting arsenic from enargite concentrates, notably using alkaline sulphide leaching (ASL). However, few alternatives exist for removing the arsenic from solution and stabilizing it in an approach that is both economical and environmentally acceptable.Dundee Sustainable Technologies (“DST”) has developed a technology for the sequestration of arsenic by vitrification. Originally optimized to cost-effectively stabilize arsenic trioxide (As2O3), DST has shown that vitrification could be successfully extended to the stabilization of other arsenical products, such as calcium arsenate (Ca3(AsO4)2) and sodium arsenate (Na3AsO4). In this paper, the vitrification of arsenic in the context of an enargite leaching was newly explored and demonstrated successfully.Two processing routes are being proposed by DST for the removal of arsenic from enargite concentrates and their stabilization by vitrification. In one route, arsenic is extracted by ASL and is then precipitated under atmospheric conditions and with minimal use of reagents and time. The resulting precipitate is an unstable hydrated ferric arsenate (FeAsO4•2H2O) that is then vitrified in a non-dilutive method, significantly increasing the stability of arsenic and meeting the TCLP guideline. Unlike is required for scorodite, stabilization was successfully achieved without concern for the crystallinity of the precipitate."

Jan 1, 2017