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By Caitlin Rogers

The environmental and economic sustainability of froth flotation is dependent on effective management, which in turn improves the performance of a concentrator. In economic terms this means improved recovery of valuable minerals, in environmental terms this means effective management of acid generating tailings. Three indicators were selected to measure the performance of an integrated flotation system. The system consists of two stages of flotation; valuable mineral flotation followed by environmental desulfurisation by froth flotation. The suitable indicators were selected based on their fulfilment of four attributes. An attribute is a desired aspect of an indicator. The four attributes were: comprehensive, relevant, sensitive and quantitative. Two environmental indicators and one economic indicator were selected. They represent revenue generation from valuable minerals and environmental cost of management. The suitability of the selected indicators was shown using illustrative scenarios.

Jan 1, 2014

By Pawel Strzalkowski, Marta Baszczynska, Urszula Kazmierczak

The paper presents issues related to interference of mining activities with the environment. Exploitation of mineral resources causes primarily a modification of the landscape. All of the negative impacts on environment are short-lived and last as much as it takes to exploit the raw material. After the mine closure reclamation is necessary during which all aspects that reduce harmful effects of the mining activities on the environment must be taken into account. Current ways of reclamation allow recreating natural environment, which is different from the original and enriched in diverse new values. This requires propositions of new forms of converted land development through a detailed analysis of technical, natural, planning, economic and social sphere requirements. Before making final decisions regarding selection of direction of reclamation, a thorough analysis of the key factors has to be carried out. All steps related to the implementation of the reclamation project are shown in the paper using Limestone Mine "Górazdze" located in the south-western part of Poland as an example. This paper also presents an analysis of current ways of post-mining reclamation towards agricultural and forestry landscape, along with our own suggestion for their extension in order to preserve biodiversity. For choosing optimal solutions the most relevant criteria were considered: existing natural values and possibility of their protection. Taking into account the economic and social aspects, supported by natural potentials, implementation of tourism and recreation in this area were proposed. It was shown that this proposition would not interfere with the current trends of the natural landscaping. Finally, after completion of reclamation and land development in the considered mine area, creation of a geo-park was proposed along with appearance of geotourism in the area. To illustrate the proposed forms of post-mining land development in the form of maps, an ArcGIS(ESRI) software was used.

Jan 1, 2014

By D. D. Ndenguma

This investigation compares the results from an experimental and numerical study of air flow in a scaled-down underground coal mine model. This was done in order to determine if numerical analysis can be relied upon when searching for ventilation solutions to control high concentration of coal dust and methane gas in underground coal mines. Steady state analyses were used to identify flow patterns and recirculation regions within the mining section while transient state analyses were used to determine the time taken to extract the initial air from the model. The agreement between the experimental and numerical results indicates that numerical modelling is useful in this regard. The study went further to devise a method of determining the optimum position of the jet fan that is responsible for mine-gas dilution at different stages of mining.

Jan 1, 2014

By C. G. Anderson

Alkaline sulfide leaching technology (i.e. ASL) has been studied, presented and published throughout the literature and utilized in some current engineering studies. Yet, the actual industrial applications are very few and the knowledge about these is very limited. Hence, a large gap between the laboratory, publications, engineering studies, and the actual industrial plant exists. Recent studies of ASL applied to copper enargite concentrates definitively bear out this dichotomy. Hence, this paper will seek to dispel the common misperceptions that continue to surround the selective industrial ASL hydrometallurgical technology. For edification of the reader, a listing of ten common misconceptions and myths is listed. As well, ASL history, fundamental aspects and a new flowsheet application for simultaneous gold and high purity antimony oxide production from low grade materials is included. The associated estimated economic considerations are also included to heighten enlightenment about the application of this industrially proven technology.

Jan 1, 2014

By H. Q. Peng

The study of synergistic reagents combination of mineral floatation is more and more important with the decreasing of bonanzas now. In order to determine the chemical reaction mechanism, here we present the synergistic reagents combination: amyl-xanthate, butyl-dithiophosphate and N,N-diethyldithiocarbamate ester, which dissolved by different organic solvents. The reagents were applied by an Anhui mine to float low-grade covellite as a substitute for ethyl-xanthate. One reaction products Na2HPSO3?5H2O (disodium hydrogen-thiophosphate pentahydrate) which was re-crystalized and measured by X-ray diffraction analysis. In its crystal structure, the two crystallo-graphically different Na ions are six-coordinated and are bridged by two covalent bonds with the O atoms of water molecules to give a basket unit. However, we can?t get Na2HPSO3?5 H2O by combining butyl-dithiophosphate and N,N-diethyldithiocarbamate ester under the same condition. This discovery may provides a intuitionistic evidence that in the process of reaction, the three com-pounds would cooperate with each other, but the decisive reaction may be the hydrolyzation of amyl-xanthate.

Jan 1, 2014

By B. Aydin, G. Erturk, G. Bulut

Coal is a complex material because of its structure consisting of carbon constituents and mineral matter. Flotation is readily carried out due to hydrophobic characteristic of coal. Therefore coal flotation is the most commonly used technique for fine coal beneficiation in order to acquire clean coal separating ash forming mineral matter from carbonaceous matter. In the coal flotation, floatability of coal both depends on characteristic of coal and used flotation reagent. Frothers as a flotation reagent are used to facilitate air dispersion into fine bubbles by prevention of bubble coalescence in the pulp phase, and stabilization of flotation froths. In this study, the effects of frother types and concentrations at different pH and particle size on the coal flotation were investigated. The representative sample was taken from Zonguldak, Turkey. It contains 9.1% ash and 7313 (kcal/kg) calorific value. Pine oil, Dowfroth 250, MIBC and Isooctanol were tested as frother types. It is determined that 1.92 ppm frother concentration is sufficient to float coal, except pine oil. In mixed frother tests, it is seen that Dowfroth 250 is more effective than others. No significant difference in coal recovery was observed for flotation tests at the different pH values. The best results are obtained in size of coal (-0.1 mm) with all frothers.

Jan 1, 2014

By V. A. Akinbinua

This work is intended to examine the relationship between rock fragments produced during compression tests using a soft testing machine, e.g. hydraulic press (the machine used in this work is Amlser rock testing machine), and the rock fragments size distribution produced by fragmentation of the same rock through application of explosive. The rocks tested are fine grained marble, medium grained tonalite and fine-medium grained granite, medium grained norite and medium grained gabbro. The rocks types are prepared according to ISRM methods to be tested for strength determination. The rocks are loaded at constant load until failure. The fragments resulting from the failure of each of the rocks types are collected for size characterization by sieve analysis. The same rocks tested under soft testing machine are also prepared into blocks of dimension 150 mm length x 100 mm width x 100 mm height for blasting by explosive application. Each block of the different rocks are drilled through with an 8 mm diameter drill to a depth of 80 mm. Each of the holes on the blocks is spaced from each other at 44.7 mm and with a burden of 28 mm. The holes therefore formed a rectangular blasting pattern. Each of the holes was charged with a 720 mg electronic detonator and fired instantaneously inside a cylindrical blasting chamber. After each shot, the fragments are collected for size characterization. The sizes distributions from blasting are compared with sizes distributions resulting from rock testing using the parameter Xc of the Rosin-Rammler distribution function (RR) and 75% cumulative percentage passing. The analysis and finding from this work is presented in this paper.

Jan 1, 2014

By Ghislain Bournival, Cagri Emer, Seher Ata

"It is well known among flotation practitioners that the contact angle can be correlated with the amount of material recovered from feed by flotation. The contact angle of solids can easily be modified by the addition of a collector. However, some collectors also have frothing properties thus altering the solid and bubble surface properties simultaneously. To avoid this problem, a technique has previously been used in which silanol groups are attached to the surfaces of the particles, but this method has its own problems. In this work, silica particles with various surface hydrophobicities were prepared using an esterification process. By using alcohols with different hydrocarbon chain lengths, from 4 to 12 carbon atoms, surfaces with a wide range of contact angles could be prepared. The technique was used in the modification of silica particles that were tested in a fluidized bed flotation column, and a laboratory mechanical flotation cell. In parallel experiments, dodecylamine (DDA) was used as a collector. It was found that irrespective of the type of flotation machine and surface preparation method, there was a close correspondence between flotation recovery and the contact angle of the particles. The silanation process has known drawbacks relating to the presence of moisture during the reaction, and the stability of the silane coating after it is been prepared. Esterification does not suffer from these disadvantages. This work has shown that the esterification technique is a robust alternative method for preparing hydrophobic quartz surfaces."

Jan 1, 2014

By Julian Dimitrov, Kremena Dedelyanova

"The paper presents research on hydrodynamic processes occurring at the elementary act of flotation. Discussed existing models to determine the effectiveness of conflict of bubbles with particles in vibration column flotation machine. The paper presents a disperser for a column flotation machine, in which the dispersion of the gas phase is carried out using vertical vibration with defined frequency and amplitude. The paper presents research of mechanism for the creation of air bubbles in vibratory column flotation machine. The factors influencing the increase in the duration of the bubble in the area of contact with the mineral particles are discussed. Research was carried out on the effect of frequency and amplitude of vibrations on speed of precipitation of mineral grains of different density. Formulas are derived for the parameter effect of vibrations, applicable to the design of flotation machine. The collision efficiency of the bubbles in vibratory column flotation machine is determined. The vibrations of the hydrated layer allow for cost-effective implementation of the elementary act of flotation by providing larger relative velocities at the contact point between the bubble and the solid phase. It is proposed to complement the model more accurate representation the mechanism of attachment of the particles to the bubble."

Jan 1, 2014

By R. F. Favreau, Patrice Favreau, Dennis Mahan

Cast blasting is becoming more and more popular, not only in coal mines but also in other operations which require excavation of an upper layer of waste rock to uncover temporarily and excavate a layer of ore, which may for example be material for the fertilizer industry.

Jan 1, 2014

In this paper, various methods, such as XPS, XRD, SEM and zeta potential measurement are applied to investigate the action mechanism of sodium sulfide in flotation of lead and zinc oxysalt minerals. The experimental results show that the mechanisms of sodium sulfide in flotation of lead oxysalt minerals and zinc oxysalt minerals are different: on the surface of cerusite, there is lead sulfide phase formed under the reaction of sodium sulfide, resulting that the cerusite surface shows the form of galena, which is advantageous to the adsorption of anion collector and improves the floatability of cerusite as a result. On the surface of zinc oxysalt minerals, there is no zinc sulfide phase formed, but the sodium sulfide increases its surface electronegativity, and enhances the adsorption of cation collector lauryl amine, so the floatability of zinc oxysalt minerals is improved. The difference of action mechanisms of sodium sulfide on lead and zinc oxysalt minerals exactly explains the reason why different collectors are selected in the flotation of cerusite and smithsonite, which are both carbonate minerals although.

Jan 1, 2014

By Barun Gorain, Aparup Chattopadhyay

"Many double refractory gold deposits are characterized by the dominance of ""invisible gold"" (sub-microscopic gold) as solid solution or as colloidal-sized particles in different sulfides and other phases. These deposits are mainly composed of silicates and carbonates with moderate clay and mica content and with minor amount of sulfides and organic carbonaceous matters. The presence of highly preg-robbing and finely disseminated carbonaceous matter adversely affects gold recovery in leach circuits. Characterization of carbonaceous matters, commonly known as TCM and quantification of gold associated within these carbonaceous matters along with different sulfide and oxide phases is highly complex and challenging. Studies were initiated on various complex ore deposits and also on samples representing various process streams. This paper presents the development of a systematic approach to gold deportment studies using state-of-the-art mineralogy characterization techniques for quantification of invisible and visible metal contents in various species. The relevance of this mineralogy characterization to metallurgy will also be discussed in this paper."

Jan 1, 2014

By K. Saberyan

Zirconium and hafnium are two important elements in nuclear industries. Zirconium is used in fuel rod for its low neutron absorption. Hafnium should be separated from zirconium, because it has higher neutron absorption cross section. In this research, separation process of the mentioned elements from (Zr+Hf)Cl4 mixture produced in the Zirconium production plant (ZPP) of Iran (Esfahan) was studied employing solvent extraction method in the nitric acid medium by using tributylphosphate (TBP) as solvent, and kerosene as diluent. The effects of nitric acid, sodium nitrate and amount of extractant, zirconium concentration in aqueous phase, phase ratio, agitation time, and mixer agitation rate were investigated on the separation process. The process was optimized at 5 M nitric acid, 1 M sodium nitrate, 60% (v/v) TBP. The optimum values for phase ratio, agitation time and agitation rate were 1.5 min and 500 rpm respectively. In this condition, the zirconium extraction efficiency, and separation factor were 65.1% and 205.59, respectively. Finally, we accessed to nuclear grade in this research.

Jan 1, 2014

Mining is an inherently risky business; from the technical, environmental, social, and economic uncertainties associated with advancing an exploration prospect to a viable project to the operating, market, and safety risks and uncertainties attached to a developed mine. Since we cannot totally escape the risk and uncertainty related to resource projects, as an industry we should improve our presentation of the upside and downside risks in the context of the project?s development path and maturity. More transparent, consistent, and balanced views of technical confidence will better inform both internal and external stakeholders about the expected risk in the project. International reporting codes set out the minimum standards, recommendations, and guidelines for public reporting of Exploration Results, Mineral Resources, and Mineral Reserves. However, the reporting code principles of transparency and materiality are largely subject to the interpretation of the competent person(s), which may introduce a degree of subjectivity in reporting, particularly the level of disclosure regarding supporting information. It is fundamental that Mineral Resources, Mineral Reserves, and study outcomes are reported so as to unambiguously present the level of inherent technical uncertainty (or confidence) in a project, while conveying a balanced view of the opportunities a project presents. Reporting needs to consider various stakeholders who may rely on this information, and present the data in the context of the changing risk profile associated with project development paths and project maturity. This paper discusses the interdependence of resource-to-reserve conversion, the consideration of various technical-economic study types, and the level of confidence conveyed to stakeholders relying on these technical reports and other company public announcements.

Jan 1, 2014

By Tedd E. Lister, Andre Anderko, Peiming Wang

Mobile electronic devices such as smart phones and tablets are a significant source of valuable metals that should be recycled. Value metals in phones are gold, palladium, silver, copper, cobalt and nickel. Devices now contain increasing amounts of rare earth elements (REE). Effective recycling schemes should include the recovery of these critical materials. Targeted recycling of items containing more of the less available critical materials could address their future criticality. This presentation will describe an electro-hydrometallurgy approach to efficient recycling of metals from scrap mobile electronics. The electrorecycling (ER) process generates oxidizing agents at an anode while reducing dissolved metals at the cathode. Development of the process involved generation of E vs pH diagrams, complemented with metals dissolution experiments used to assess the effectiveness of various solution chemistries. Although several schemes were envisioned, a two stage process has been the focus of work: 1) initial dissolution of Cu, Sn, Ag and magnet materials using Fe+3 generated in acidic sulfate and 2) final dissolution of Pd and Au using Cl2 generated in an HCl solution. Results from laboratory work will be discussed.

Jan 1, 2014

By Axel Pankewitz, Andrew Smith, Mathias Stender, Christian Behrens

"Particle size measurement is one of the most important factors in obtaining peak performance of the mineral processing plant in order to ensure efficient milling and flotation circuit operation. Off-line particle distribution analysis technologies only allow an infrequent check of the ore slurry size and hence do not allow for timely process monitoring or intervention. Most existing on-line particle size analysers suffer from a variety of disabilities such as poor statistics, non-representative sampling or mechanically complex setup. This paper will describe an Ultrasonic Extinction based method which overcomes many limitations of existing online analysers and has proven its performance for mineral applications over many years. Installation examples will be given. Since new technologies usually raise e questions about comparability and agreement to common particle size analytical methods e.g. sieving or laser diffraction analysis, extensive studies were performed comparing these different technologies to quantify the quality of results as well as its mathematical robustness."

Jan 1, 2014

By Masoud Askari, Ahmad Rafizadeh, Shahamat Rostami, Mohammad Qaredaqi

Gole - Gohar Iron ore mines located in Sirjan, Southeast of Iran, have more than 1 billion Iron ore deposit and this area comprises 45 % of Iran Iron reservoirs. The aim of Wet tailing processing line is recovering Hematite ore from wet tailing of Gole - Gohar iron ore processing plant. The Investigations of Hematite recovery plant showed that the recovery of Iron ore to concentrate in Wet Tailing Processing (WTP) line is very lower than that has been predicted, sampling, and designing of the process parameters are not accurate and designed magnetic field intensity is not reasonable for the recovery of Iron in form of Hematite in this line feed. Applying of MIMS in WTP separator and changes in circuit caused in overwhelming increase of Fe recovery, from 11 to 40%. Although recovery of WTP line was improved, but low recovery of this processing line and high content of Hematite ore in WTP tailing, made applying Wet High Intensity Magnetic separators unavoidable. Two kinds of WHIMS have tested for processing of WTP line tailing. Results showed that traditional Jones separator with grooved plate matrix, is more suitable to achieve a better quality of concentrate compared to Slon® separator.

Jan 1, 2014

By Antonio A. Cristóvão, Alexandre Pinto

"Abstract Deep foundations of buildings using driven ductile iron micropiles TRIM solutions, leads to recognized advantages, from technical, schedule and economic points of view. High production rates together with the possibility of using conventional equipment, duly adapted, confer this solution a high versatility.The aim of this paper is to describe the main design criteria adopted for the foundations of the Church ""Nossa Senhora dos Navegantes"" building in Lisbon - Portugal. In addition, results of a full scale load test carried out at site are presented, confirming the adequacy of the solution to the geological and geotechnical scenario, which is characterized by the proximity of the Tagus River Basin as well as the presence of heterogeneous landfill material and alluvial layers of soft clay (muds).1. INTRODUCTION Located on the right bank of the Tagus River, in Lisbon, the new Church building of ""Nossa Senhora dos Navegantes"", patroness of fisherman and navigators, with three or four upper floors, is surrounded by a school and by new residential buildings.The Tagus River basin is known by its alluvial soft soils, achieving, in certain areas, more than 50m meters depth, challenging the construction of new facilities due to the significant unfavorable geotechnical conditions.With a modern an unusual architecture, allusive to the ships used by the Portuguese navigators, the building has a reinforced concrete structure, with one basement and three upper floors. A bell tower with about 40m high, emerging from the structure, marks the landscape with the presence of this religious building (figure 2).For all the reasons previously described, geotechnical engineers play a crucial role on the design of valid foundation solutions, from both technical and economic point of view. Ideally, the solutions adopted should be supported by full scale load tests, performed at site, so that design assumptions could be verified and adjusted on time."

Jan 1, 2014

By Gábor Mucsi, Barnabás Csoke, Viktor Mádai, Zoltán Molnár, Viktor Török, Ádám Rácz

The application of the stirred media mill in dry mode came to the front only in recent years, but at the same time several questions arise, such as aggregation, agglomeration, sticking on the liners and the grinding media. During high energy milling, not only the particle size reduces, but among others, in numerous cases the crystal structure and the amorphous state of the material also change due to the mechanical activation taking place. The present paper deals with experiments carried out on the ultrafine fly ash grinding in dry mode at various grinding conditions in a stirred media mill to investigate the mechanochemical effect and the energy efficiency of the mill. During the experiments the particle size distribution, particle shape, specific surface area, amorphity and crystal structure of the products were examined. The product related stress model was used for the evaluation of the effect of milling parameters on the mechanical activation. It was found, based on the experimental results, that there is mechanochemical effect on crystal structure of fly ash in the stirred media mill, as it was revealed by X-ray diffraction and FTIR measurements. The experimental results made it possible to determine the effect of the rotor circumferential speed and so the stress intensity on the mechanical activation of fly ash could be revealed.

Jan 1, 2014

By D. Nyungu

Despite observations of spalling and damage of mine excavation wall rock in the Bushveld Complex (BC) over the passage of time, there have been very few time-dependent or creep tests carried out in South Africa on rock, particularly on BC rock types. The research described in this paper deals with the investigation of stress and strain conditions influencing spalling of wall rock in BC mine excavations, and the influence of time on the tensile strength of several BC rock types. Time-dependent laboratory testing of BC rocks was carried out in indirect tension. The results show that the magnitude of the tensile strength of BC rock types is approximately 5% of their uniaxial compressive strength magnitudes. The average long-term uniaxial compressive strength of the BC rocks, interpreted from the axial stress-volumetric strain graphs, is 56% of the UCS value. The long-term tensile strength is shown to be less than 70% of the normal tensile strength. Extension strains at tensile strength failure ranged between 0.16 and 0.21 millistrain. Values corresponding with the long-term tensile strength are less than 70% of this range, namely, 0.11 to 0.15 millistrain. These results represent new knowledge, since such rock testing and analysis does not appear to have been carried out previously on BC rock types. Elastic numerical modelling was carried out to illustrate the extents of tensile stress zones and extension zones around of typical BC mine excavations. The models showed that large zones of extension strain can occur around BC excavations, and that the magnitudes of the extension strain can substantially exceed the critical values determined from the laboratory testing. The implication of this is that there are substantial zones surrounding BC mine excavations that will be prone to time-dependent spalling conditions and perhaps more significant failure.

Jan 1, 2014