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By N L. Turner, K Ehrig, V Liebezeit, D J. Robinson, L L. Kuhar, N Francis

Conventional industry tests used to determine leach recoveries are often fully monitored and may be time-consuming and expensive. Such tests may be limiting in geometallurgical applications where large numbers of samples are required to be processed for characterisation of an ore deposit. BHP Billiton currently use a fully instrumented leach test for characterisation of Olympic Dam uranium-rich samples. Researchers at the Commonwealth Scientific Research and Industrial Organisation (CSIRO) were approached to develop an alternative to these full-scale leach tests that could allow for the ranking of samples in terms of their leachability. The novel geometallurgical test was required to use samples of small mass and be affordable and rapid.Three leach test protocols were pursued in developing the small-scale tests. Kinetic leach tests were performed using mild conditions at higher pH, low temperature and low oxidation reduction potential, moderate conditions at intermediate pH, temperature and oxidation reduction potential and aggressive conditions at lower pH, higher temperature and higher reduction potential.This paper presents results from 44 leach tests on 11 samples with varying uranium mineralogy. The developed small-scale tests correlate well with data from the more costly conventional industry laboratory tests, indicating the possibility of using this alternative test as a geometallurgical leach proxy. Simple regression analysis confirmed the importance of pH, reduction potential and temperature on uranium extraction. Experimental data were fitted to published leach models to predict uranium leach extraction for a range of operating conditions.The ultimate aim of the test work is to combine a limited number of large-scale calibration tests, a large number of small-scale geometallurgical tests and leach models for geometallurgical sample characterisation and evaluation of a wide range of scenarios or processing options.CITATION:Turner, N L, Kuhar, L L, Francis, N, Liebezeit, V, Ehrig, K and Robinson, D J, 2013. Development and testing of a small-scale uranium leach for geometallurgical applications, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 345-350 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By K G. van den Boogaart, S Konsulke, R Tolosana Delgado

Adaptive mineral processing has to rely on spatially predicted information on primary geometallurgical parameters, like phase composition, size and shape distributions of grains from various phases, portions of value elements in different grain types. Naively, one would predict these parameters geostatistically and select an optimal processing for the predicted structure. This is suboptimal, due to various kinds of non-linearities in the problem. First, some primary geometallurgical quantities themselves are measured in non-real scales, like compositional or stereologically distorted geometric information. Standard geostatistics has to be replaced by compositional and geometric geostatistics, involving complex transforms and restrictions. Further, only partial and uncertain information is available, introducing a stochastic character to the optimisation problem. Moreover, many response variables leading to costs, outcomes and eventual effects of later processing depend non-linearly on the primary geometallurgical parameters, which implies that the final monetary value is not estimated unbiasedly by kriging. Finally unbiased linear prediction (such as kriging) is not the best method of prediction for decision making. The conditional expectation of the monetary values is needed instead. The impact of these problems is explained in this paper, with simplified examples, and a first approach to a general solution is proposed. CITATION:van den Boogaart, K G, Konsulke, S and Tolosana Delgado, R, 2013. Non-linear geostatistics for geometallurgical optimisation, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 253-258 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By D L. Reid, G Nwaila, J Petersen, J-P Franzidis, Y Ghorbani, M Becker, F C. de Beer, L C. Bam

Traditional methods of gold extraction have involved comminution and processing via cyanide leaching, all of which are associated with energy, cost and environmental implications. Subsequently, numerous opportunities for improvement and optimisation strategies in gold mining and processing have been explored, including heap leaching, which has significantly lowered comminution costs. This paper explores the effect of the more energy efficient high-pressure grinding rolls (HPGR) on the comminution behaviour (especially on the crack density) and cyanide leaching performance of laboratory reactors study on run-of-mine gold ore comprising the Ventersdorp Contact Reef (VCR) and the Elsburg Reefs (ER), sourced from Carletonville in the Witwatersrand Basin in South Africa. The ore was comminuted using HPGR at three different pressure settings (120, 90 and 60 bar). Large (-16/+11.2 mm) and small (-5.6/+4 mm) particles of the HPGR product where then mineralogically characterised using optical microscopy, quantitative evaluation of minerals by scanning electron microscopy (QEMSCAN) and X-ray computer tomography (CT) before cyanidation. The results of the leach experiments indicated a correlation between gold extraction, particle size and crack density. Mineralogical characterisation of the ore indicates that the Fe-sulfides present in the VCR are likely to be more reactive than those in the ER, thus having a more favourable influence on gold cyanidation. Overall, the results show promise for the heap leaching of Witwatersrand gold ores prepared using HPGR and demonstrate the value of a multi-disciplinary geometallurgical approach.CITATION:Nwaila, G, Becker, M, Ghorbani, Y, Petersen, J, Reid, D L, Bam, L C, de Beer, F C and Franzidis, J-P, 2013. Morro do Ouro geological model with a metallurgical view, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 75-84 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By T Muzondo, C Prins, D De Vaux, R Schouwstra

The Mogalakwena Platinum Mine in the northern limb of the Bushveld Complex is Anglo American PlatinumÆs only open cast operation exploiting the Platreef. The Platreef, which extends along the basal contact of the Bushveld Complex, is geologically and mineralogically a much more complex orebody than the Merensky and UG-2 reefs. Changes in the footwall and the genesis of the Platreef translate into a number of rock types being present. These rock types vary in hardness and recovery potential and present challenges to metallurgical staff trying to optimise the concentrator. A true understanding of the implications of treating these rock types is required if the maximum value from this orebody is to be obtained.In order to more accurately forecast production and incorporate ore variation in the mine plan and comminution and flotation circuits, a geometallurgical approach to managing the operation has been used and is being further developed.CITATION:Schouwstra, R, De Vaux, D, Muzondo, T and Prins, C, 2013. A geometallurgical approach at Anglo American PlatinumÆs Mogalakwena Operation, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 85-92 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By J Jasper, L Koroznikova, J Begelhole

This paper outlines a comparison of heavy liquid and heavy suspension separation methods for iron ore characterisation.As part of Arrium MiningÆs program to improve its knowledge of ore types being processed in its two hematite ore beneficiation plants (OBP), metallurgical evaluation of hematite feed for the upgrading process has become a major focus.Iron ore deposits almost always contain more than one valuable (and relatively dense) iron mineral. Iron ores are found with a range of iron contents, giving rise to density variations.At present the industry relies on heavy liquid separation techniques for the evaluation of iron ore samples arising from exploration, mining or metallurgical processes. There are only a few high-density liquids available, which are both high-cost and highly toxic.Low-toxicity solutions that can be utilised at relative densities up to 3.0 have been developed. However, highly-toxic organic liquids are required presently to achieve relative densities beyond 3.0.Bromoform which has a specific gravity (SG) of 2.89, and diiodomethane (SG 3.31) are commonly used; both present significant health and safety hazards.æClericiÆs solutionÆ (mixtures of thallium formate and thallium malonate) provide liquids having specific gravities between 4.0 and 5.0. ClericiÆs solution is highly toxic and testing is currently conducted by a limited number of laboratories worldwide.An alternative to ClericiÆs solution and organic liquids is a low-toxicity, high-SG, suspension technique, which has been demonstrated successfully for heavy mineral sands. This heavy suspension method employs mixtures of fine tungsten carbide particles in lithium heteropolytungstate (LST) solutions.Heavy liquid separation is not commonly used as part of routine iron ore feed characterisation due to the expensive, toxic and time consuming nature of the technique. Our results show that the heavy suspensions method can achieve low-cost, low-toxic separation and are outlined and results compared with results using ClericiÆs solution presented.Heavy suspension technique provides a theoretical/absolute separation of a particular sample. By placing an iron ore sample in a suspension of a particular density, it produces two products: a sink fraction and a float fraction. As iron oxides-hydroxyoxides are denser than the gangue minerals associated with the ore, particles that have high iron content will sink and the particles with gangue association will float. This process is repeated over several densities, thus also enabling separation of the constituent iron ore phases. A theoretical grade and a theoretical mass recovery can be calculated. With these calculations, a grade-mass recovery curve can be constructed for any element that is of interest.This type of characterisation can be used to either prepare OBP feed-piles of known processing characteristics, or to benchmark the performance of the process against what can be theoretically achieved on a continuous basis.CITATION:Begelhole, J, Jasper, J and Koroznikova, L, 2013. Application of the heavy suspension technique for ore beneficiation plant feed characterisation from the Southern Middleback Ranges, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 269-278 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By M Dusci, A Trueman, S Poos, R Baumgartner, M Brittan

The Canahuire epithermal Au-Cu-Ag deposit in southern Peru is a complex and challenging deposit for metallurgical studies. It has issues of gold locking in sulfides and non-sulfides, deleterious elements and acid rock drainage (ARD). From scoping study to feasibility study, there has been considerable improvement in the understanding of the important geometallurgical characteristics that need to be measured and modelled. This paper presents the current understanding and the requirements to continue to provide optimal models for mining studies.Significant effort has been put into understanding the genesis of the deposit. Improved spatial and temporal understanding of lithology, alteration, structure and mineralogy was used to build a geological and alteration model of the deposit.Early metallurgical programs quantified the effect of head grade on process plant recoveries, but the geometallurgical and statistical analyses did not identify other physical characteristics that influence these recoveries. The studies improved the understanding of the nature of locked gold which can occur as minute inclusions (< 5 ¦m) in sulfides (primarily pyrite with lesser arsenopyrite, pyrite being 100 times more abundant than arsenopyrite) and gangue minerals (quartz and carbonates) as well as solid solution in arsenopyrite and pyrite.The presence of pyrite and the limited buffering capacity of waste rocks increases the potential ARD, which will require mitigation costs before, during and after operations. Waste rock ARD potential has been classified and incorporated in the geometallurgical model. The current classification of waste rock at Canahuire, using international classification standards, is limited due to the complexity of the deposit.Complex deposit metallurgy necessitates a complex process flow sheet, including flotation and cyanidation. Economic recovery will be constrained by the relationships between economic variable grade, other elements and mineralogy. These constraints and inter-relationships are difficult to establish throughout the deposit with a single test. A follow-up geometallurgical program is under investigation and will attempt, with the help of additional test work, to map areas of higher and lower recoveries. It is hoped that metallurgical response can be linked to measurable parameters other than head grade. If this is possible, these factors can be incorporated into future geometallurgical models.CITATION:Baumgartner, R, Dusci, M, Trueman, A, Brittan, M and Poos, S, 2013. Building a geometallurgical model for the Canahuire Epithermal Au-Cu-Ag Deposit, Southern Peru - past, present and future, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 51-58 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By M I. Pownceby, S Bhargava, F Charalambous, S McMaster, R Ram, J Tardio

"A key component of any geometallurgical investigation involves being able to predict element or mineral recoveries from simplified input data such as bulk chemistry and/or mineralogy. This relies on the metallurgist having access to accurate information regarding the chemistry of the ore and gangue minerals as well as the likely impact on processing/extraction caused by the impurities (present either as gangue or as substitutional impurities). In this study the chemical properties of two commercially important uranium minerals, brannerite (U4+Ti2O6), and uraninite (U4+O2), were characterised using X-ray diffraction (XRD), scanning electron microscopy (SEM), and electron probe microanalysis (EPMA). Significant levels of impurities were present in both samples with the uranium minerals deviating significantly from their ideal chemical formulae. Differences in chemistry were due to: cationic substitution decay of the uranium isotopes into radiogenic lead and other daughter products mixed uranium oxidation states post-depositional alteration.As well, the brannerite sample showed evidence of significant radiation-induced metamictisation. Leach tests to measure the ease of extraction of uranium from both samples were conducted over a wide range of conditions (temperature, acid concentration and oxidant concentration). For uraninite, the lower U dissolution rates observed in the natural sample compared to a synthetic UO2 sample were directly attributed to the presence of impurities. For brannerite, significant metamictisation of the natural sample led to enhanced U extraction rates compared to a heat treated fully crystalline sample. This study highlights the importance of detailed mineralogical characterisation studies in any uranium process mineralogy investigation as the compositional, textural and microstructural aspects of the main uranium phases present will likely play an important role in any process to extract uranium.CITATION:Ram, R, Charalambous, F, McMaster, S, Pownceby, M I, Tardio, J and Bhargava, S, 2013. Chemical and microstructural characterisation studies on naturally occurring uranium minerals - implications for processing, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013, pp 325-334 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 29, 2013

By M I. Pownceby, A Torpy, C Johnson, N C. Wilson

To extract uranium from low-grade, calcrete-hosted uranium (CHU) ore is challenging owing to the presence of carbonate and swelling clay gangue minerals that require an alkaline lixiviant to be used. Western Australia possesses ~75 000 U3O8 t in CHU resources. Improvements to alkaline leach extraction practices would improve the economic potential of these deposits.A column leach study of CHU ore was run for 105 days using an alkaline carbonate-bicarbonate lixiviant. The uranium content of the liquor plateaued after 75 days at ~275 mg U/L; the calculated maximum solution capacity was 800 mg U/L. Spiked peaks and troughs were seen in the data set beyond the 60th day, where concentrations ranged from 220 - 290 mg U/L, indicating possible cyclic uptake and loss of uranium from the solution.Pristine and leached ore samples were geochemically analysed and mineralogically characterised at high resolution using a field emission gun-electron probe micro-analyser (FEG-EPMA). Results showed that leached ore samples from the top of the column contained less carnotite than pristine ore. In contrast, leached ore samples from the column base contained regions with more carnotite than pristine ore, indicating precipitation. Three carnotite grain micro-structures were identified in the leached ore; fan-spherulite, granular and core-shell cubes, with evidence for multiple growth phases.Evidence of carnotite precipitation was seen at the edge of and in pore spaces within montmorillonite and dolomite grains. The point of zero charge of both minerals is lower than the pH of the lixiviant (pH 10.8), thus the mineral surfaces are negatively charged and would not attract UO2(CO3)34- ions out of solution. Similarly, the decrease in the uranium content of the lixiviant is not attributed to super-saturation, as this was unlikely to have been achieved. Work is ongoing to understand the reason for carnotite precipitation and the fluctuations in the lixiviant uranium concentration that are seen.CITATION:Johnson, C, Pownceby, M I, Wilson, N C and Torpy, A, 2013. Microscale characterisation of pristine and processed ore - implications for leaching calcrete-hosted uranium ore, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 303-316 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By A F. Cropp, D J. Bradshaw, W R. Goodall

Mineralogy and critically the texture of both the ore and gangue phases are of paramount importance in the flotation recovery of copper from porphyry ores. Mineralogy and texture will define the theoretical grade recovery curve for a feed ore. Actual grade-recovery falling below this may be due to texture and gangue influences, whilst desired grade-recovery above this line will not be possible unless the characteristics of the feed are altered.This review discusses examples of porphyry copper deposits where process mineralogy has been used to characterise these textural and gangue influences on recovery by flotation. More specifically, the influence exerted by grain size, liberation, association and elemental distribution is explored. The implications of these on overall plant philosophy and operation are highlighted, along with the subsequent potential impact on recovery.CITATION:Cropp, A F, Goodall, W R and Bradshaw, D J, 2013. The influence of textural variation and gangue mineralogy on recovery of copper by flotation from porphyry ore - a review, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 279-292 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By G N. Musafer, M H. Thompson, R C. Wolff, E Kozan

The most important aspect of modelling a geological variable, such as metal grade, is the spatial correlation. Spatial correlation describes the relationship between realisations of a geological variable sampled at different locations. Any method for spatially modelling such a variable should be capable of accurately estimating the true spatial correlation. Conventional kriged models are the most commonly used in mining for estimating grade or other variables at unsampled locations, and these models use the variogram or covariance function to model the spatial correlations in the process of estimation. However, this usage assumes the relationships of the observations of the variable of interest at nearby locations are only influenced by the vector distance between the locations. This means that these models assume linear spatial correlation of grade. In reality, the relationship with an observation of grade at a nearby location may be influenced by both distance between the locations and the value of the observations (ie non-linear spatial correlation, such as may exist for variables of interest in geometallurgy). Hence this may lead to inaccurate estimation of the ore reserve if a kriged model is used for estimating grade of unsampled locations when non-linear spatial correlation is present. Copula-based methods, which are widely used in financial and actuarial modelling to quantify the non-linear dependence structures, may offer a solution. This method was introduced by Bßrdossy and Li (2008) to geostatistical modelling to quantify the non-linear spatial dependence structure in a groundwater quality measurement network. Their copula-based spatial modelling is applied in this research paper to estimate the grade of 3D blocks. Furthermore, real-world mining data is used to validate this model. These copula-based grade estimates are compared with the results of conventional ordinary and lognormal kriging to present the reliability of this method.CITATION:Musafer, G N, Thompson, M H, Kozan, E and Wolff, R C, 2013. Copula-based spatial modelling of geometallurgical variables, in Proceedings The Second AusIMM International Geometallurgy Conference (GeoMet) 2013 , pp 239-246 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 29, 2013

By G F. Brent, S Hawke, M Rothery, P Dare-Bryan

Mine-to-mill studies have previously demonstrated downstream productivity benefits from relatively modest increases in blast energy, or powder factor. These increases have up to now been limited by safety and environmental constraints, since excessive blast energy can result in flyrock, unacceptable vibration, airblast and wall damage.Here, a new blasting method that overcomes these constraints is presented. For the first time it is possible to employ powder factors that are several fold higher than conventional blasting. Independent modelling has shown that such powder factors can potentially increase mill throughput by 20 to 40 per cent. The economic implications are substantial, both in terms of increasing production in existing operations and in consideration of capital and plant requirements for greenfield sites. In addition, mill electricity and grinding media consumption and their associated costs and energy and emissions penalties can be reduced.This method represents a step-change in blasting practices. It involves a novel design utilising dual blast layers within a single blast event, all initiated with state-of-the art electronic blasting systems. The energies in the lower layer can be as high as five times the standard energies, providing for intense fragmentation of the ore. Results from blast models have been confirmed in field trials of the method.Open cut gold mining, in particular, stands to benefit from this method. As gold grades decline, milling costs and throughput increasingly become constraints on production that can be alleviated with this new method. Additionally, it opens possibilities for improved recovery. Blast modelling studies show that dilution of gold ore within the blast can be managed with the new method. Furthermore, it has been shown that vibration from the new method is actually lower than from conventional blasting, allowing the use of the technique in proximity to mine highwalls and other key infrastructure such as underground orepasses.It is concluded that this new method could substantially increase gold mine production and profitability while reducing overall energy consumption and associated emissions.CITATION:Brent, G F, Dare-Bryan, P, Hawke, S and Rothery, M, 2013. Ultra-high-intensity blasting - a new paradigm in mining, in Proceedings World Gold 2013 , pp 395-400 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By W T. C Kendall, H D. Ngo

Garden Well is a shear-hosted Archaean orogenic gold deposit located 100 km north of Laverton, Western Australia. The Garden Well processing plant is designed for a nominal 491 t/h milling rate and annual capacity of 4 Mt. The plant has three key innovations:1. a scrubbing circuit, expected to reduce grinding power consumption by up to 20 per cent2. a secondary cycloning/gravity circuit, providing a second opportunity for gravity gold recovery (additionally, the circuit effectively increases the leach residence time of the coarse gold bearing fraction of the leach feed by approximately 60 per cent, without any additional tankage)3. the use of mid-stream oxygenation to enhance gold recovery.The Garden Well deposit is free-milling with overall laboratory gravity/leach gold recoveries exceeding 95 per cent at a P80 grind size of 150 ¦m. Three mineralogical domains have been identified: oxide, transition and fresh, with the fresh domain having subdomains of fresh ultramafic and fresh shale. There is a high component of gravity recoverable gold in all three domains.This paper will discuss these innovations and the design challenges and the risk mitigation strategies that were adopted to ameliorate the prototyping risk. The performance of the plant since commissioning together with lessons for the future will also be presented.CITATION:Smith, R J, Kendall, W T C and Ngo, H D, 2013. Treatment plant innovation at Garden Well, in Proceedings World Gold 2013 , pp 315-324 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By J Savage, A Crawford, M Doyle, N McNaughton, T G. Blenkinsop

Area selection criteria for gold exploration have historically highlighted the low prospectivity of high-metamorphic grade terranes relative to regions with lower metamorphic grades. The Tropicana gold project, Western Australia, is a rare example of a major greenfields gold discovery in Archean mid-amphibolite to granulite-facies gneissic rocks that have experienced widespread recrystallisation and partial melting.The project, located on the tectonically reworked eastern margin of the Yilgarn Craton, is part of the Tropicana Joint Venture, which is 70 per cent owned by AngloGold Ashanti Australia (manager) and 30 per cent by Independence Group NL. Construction of the mine commenced in the June quarter of 2011 and first gold pour from open pit mining is anticipated in the December quarter of 2013. The approved project will have a ten-year mine life and in the first three years of operation, gold production will be between 470 000 - 490 000 oz/a at a cash cost of A$590 - A$630/oz.Reserves as at 31 December 2011 total 56.4 Mt grading 2.16 g/t for 3.91 Moz of gold. The mineral resource, as of 30 December 2012, has grown to 7.89 Moz of contained gold, including Inferred Resources of 11.9 Mt at 2.83 g/t for 1.08 Moz.Economic gold mineralisation post-dates peak metamorphism and is interpreted as younger in age (ca. 2500 Ma) than other gold deposits in the Yilgarn Craton on the basis of structural and geochronological constraints. Mineralisation is genetically related to an imbricate thrust stack that records a prolonged history of reactivation during the Proterozoic era. Gold mineralisation formed from higher temperature (>350¦C) silica-undersaturated fluids that preferentially migrated though a favourable intensely potassium metasomatised zone. Permeability created during brittle fragmentation was accompanied by replacement of mafic metamorphic minerals, and synchronous partitioning of strain into pervasively biotite-sericite-pyrite-altered stylolites and shear planes that bound more competent lithons.CITATION:Doyle, M, Savage, J, Blenkinsop, T G, Crawford, A and McNaughton, N, 2013. Tropicana - unravelling the complexity of a +6 million ounce gold deposit hosted in granulite facies metamorphic rocks, in Proceedings World Gold 2013 , pp 87-94 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By Q Zhou, G Barrett, Y Choi, J Jiang

As part of a general review of processing double refractory ores through Barrick GoldÆs autoclaves /carbon-in-leach (CIL) facility at Goldstrike, a study was made to evaluate the use of surfactants for reducing the loss of gold during cyanide leaching of preg-robbing gold ores. Consistent improvement of gold recovery was observed with surfactants at various testing conditions. This paper will discuss the results obtained from laboratory and pilot-scale testing, as well as, review potential mechanisms for the observed improvement in gold recovery.CITATION:Zhou, Q, Barrett, G, Jiang, J and Choi, Y, 2013. Surfactants for gold recovery improvement with preg-robbing gold ores, in Proceedings World Gold 2013 , pp 367-372 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By R J. Beazley, M C. Woods

"The International Cyanide Management Code (the Code) is a voluntary industry program for gold miners and associated cyanide transporters and cyanide producers. By becoming a signatory, a company commits to follow the CodeÆs principles and implement its standards of practice.Signatories are required to undergo an initial certification audit within three years and a recertification audit every subsequent three years. Recertification audits evaluate compliance over the preceding three-year period. This approach presents a number of challenges. Golder Associates has undertaken in excess of 75 initial certification audits and 25 recertification audits; more than any other audit firm. This paper outlines some of the challenges identified and lessons learnt from the recertification audit process. Central to the process is the challenge for organisations to maintain commitment to compliance over the full three-year period and effectively address deficiencies or non-conformances that may have occurred during that period in a prompt manner.The International Cyanide Management Institute (ICMI) provides guidance in evaluating deficiencies or non-conformances, which requires consideration of the æcauseÆ, ædurationÆ and æongoing compliance effortsÆ and an assessment of the concept of ægood faithÆ in response actions. Golder AssociatesÆ experience with the recertification process highlights some common deficiencies with Code compliance programs, such as: system breakdowns (leading to ineffective communication between departments or loss of information) exceedance of discharge limits inadequate inspections, maintenance activities and associated record-keeping.Such deficiencies can be attributed to: personnel changes organisational changes or structures management systems (eg integrated or standalone) awareness and interpretation of Code requirements transparency of management decisions with Code implications.We have identified that ongoing programed assessment is an effective strategy in maintaining Code compliance.CITATION:Beazley, R J and Woods, M C, 2013. Cyanide code recertification - the three-year challenge, in Proceedings World Gold 2013, pp 247-254 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 26, 2013

By J Tiihonen, J OÆCallaghan, T Haakana

Outotec is today capable of providing technologies, process equipment and engineering for the construction of pressure oxidation leaching (POX) plants in any location in the world. Outotec works with customers from mine to pure metal, participating in plant design from the process development phase (including test work execution/supervision) to plant commissioning and operations. Either key equipment technology packages with basic engineering or entire POX plants can be supplied.The addition of pressure oxidation equipment to OutotecÆs product portfolio adds to and complements already existing significant experience in general hydrometallurgical process and proprietary equipment design and supply.In addition to providing key pressure vessels, piping and valves to a POX plant, Outotec can offer an enhanced and proven autoclave agitation system that maximises oxygen mass transfer and utilisation. Novel energy and water recovery technology can also be tailored to a customerÆs specific needs. Importantly Outotec owns and operates extensive test work facilities and can provide test work to ensure the optimum POX flow sheet and materials of construction. Outotec ensures that best available technology (BAT) concepts are used in POX design to improve the availability of the process and minimise unpredicted shutdowns.CITATION:Tiihonen, J, Haakana, T and OÆCallaghan, J, 2013. Outotec pressure oxidation - more out of sulfide ore, in Proceedings World Gold 2013 , pp 197-206 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By P Breuer, X Dai, A Bergamin, D Hewitt

"Copper-ammonia-thiosulfate?leaching of gold has been researched for several decades as a potential alternative to cyanidation. However, this technology has not yet been applied commercially due to many challenges such as complex solution chemistry, reagent degradation and losses, system instability with losses of precious metals and difficulties in gold recovery from the leachate. Progress has been made at CSIRO in tackling some of these challenges including:better understanding and control of the leach conditions to minimise reagent losses whilst maximising gold recovery use of strong base ion exchange resins to recover the gold strategies to deal with polythionates that adsorb competitively with gold on ion exchange resins development and evaluation of process flow sheets.As a result there has been increased interest from the gold industry and renewed activities to develop thiosulfate based processes for gold recovery. One application area, which has been developed to the point of piloting, is the treatment of gravity gold concentrates using a copper-ammonia-thiosulfate leach with ion exchange recovery of the gold thiosulfate. This paper describes some of the advancements in the development of a potential process flow sheet for this application.CITATION:Dai, X, Breuer, P, Hewitt, D and Bergamin, A, 2013. Thiosulfate process for treating gold concentrates, in Proceedings World Gold 2013, pp 61-70 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Sep 26, 2013

By Y Peng, B Guo

In gold processing plants, the water from the cyanidation stages is treated to detoxify cyanide species and this recycle water becomes the main part of the process water. Despite the low concentration of free and weak acid dissociable (WAD) cyanides in process water, the recoveries of gold and silver is still affected during flotation, especially when gold and silver are associated with iron sulfide minerals. This is a case at the Hidden Valley (HV) Mine. In this study, the effect of free and WAD cyanides on gold and silver recoveries by flotation from the HV Mine was considered.WAD cyanide (WAD CN) was prepared by mixing sodium cyanide and copper sulfate at a cyanide to copper ratio of 3:1 dosed at different cyanide concentrations. It was found that both free and WAD CN depressed gold and silver and particularly iron sulfides in flotation. The depressed gold and silver recoveries were closely associated with the depressed recovery of iron sulfide minerals, suggesting that free and WAD CN may not depress the flotation of liberated gold and silver minerals significantly. It was also found that 10 ppm free cyanide completely depressed the flotation of iron sulfide minerals and WAD CN depression is probably through the WAD dissociation to free cyanide species (mainly aqueous HCN) during the grinding process, resulting from a decrease in pH. Thermodynamic calculation showed that 5.5 ppm free cyanide was released in the end of grinding at an initial WAD CN concentration of 50 ppm. This research provides a guideline to counteract the negative effect of WAD CN in the flotation of gold and silver minerals.CITATION:Guo, B, Peng, Y and Espinosa-Gomez, R, 2013. The effect of weak acid dissociable cyanide on gold and silver flotation in Hidden Valley Mine, in Proceedings World Gold 2013 , pp 341-346 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By G N. Phillips

No new goldfields have been found in the Witwatersrand Basin for over 60 years, and one consequence of this is a long-term decline in gold production. Exploration throughout this period has been based on the placer model that infers alluvial transport of gold grains and then sedimentary sorting in the basin; however, there is no viable source for so much alluvial gold and no single sedimentary setting that hosts the gold.An alternative genetic model can now provide a quantified explanation for the source of the gold, and it does not rely on alluvial gold processes. The hydrothermal model can easily explain the source of the Witwatersrand gold as being derived from the background gold at parts per billion (ppb) level throughout the Kaapvaal craton of South Africa. This gold is involved in metamorphic processes, available for solution in metamorphic fluids, and hence may be transported whilst dissolved in fluid into the Witwatersrand Basin. The hydrothermal model warrants consideration as it can explain the source of gold, the large alteration halo in the goldfields, the mineralogy, and especially the gold-carbon association.Working on the premise that if one model (placer) is not giving the desired results (discovery of new goldfields), then it may be prudent to consider alternatives. Application of a hydrothermal model to guide exploration would place importance on large and small early structures in and around the Witwatersrand Basin; it would also emphasise the geochemical nature of potential host rocks (especially C and Fe) rather than their sedimentary origin.CITATION:Phillips, G N, 2013. Origin of Witwatersrand Gold - a viable source region and source process for gold, in Proceedings World Gold 2013 , pp 175-180 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013

By B Levasseur, C Olsen, E Ghasemian Langeroudi, F Larachi, F Safizadeh, C Gagnon

Gold recovery by the cyanidation process is often accompanied by the leaching of other species. This leads to the depletion of the level of free cyanide and oxygen available for gold cyanidation. The largest proportion of the consumed cyanide is diverted by the cyanicides (eg S, Cu, Zn, Fe, etc) into non-valuable complexes.COREMÆs Extractive Metallurgy team has been conducting a research program on the improvement of the gold cyanidation process. As a part of this program, the current study aims to investigate the effect of certain operating parameters on the reactions involved during preoxidation and cyanidation. Flotation tailings and single mineral samples such as pyrite, sphalerite and chalcopyrite, along with their different combinations, were analysed to highlight the influence of ore mineralogy on the operating conditions. The effects of different kinds of oxidants (oxygen, hydrogen peroxide, ferricyanide and ozone) and chemical additives (ammonium sulfate) were investigated.Experiments conducted in alkaline solutions reveal that mineralogy is a key parameter since pyrite, chalcopyrite and sphalerite react quite differently during preoxidation and cyanidation. A significant increase in sulfur dissolution, especially on pyrite, was observed by applying preoxidation. H2O2 preoxidation showed a positive effect on increasing sulfate formation, a desirable by-product from the cyanide consumption point of view. Preoxidation of synthetic ores with ferricyanide resulted in boosting thiosulfate formation. Tests conducted on flotation tailings from a polymetallic mine revealed that a short preoxidation increases the dissolution of the ore leading to higher gold recovery and lower cyanide consumption. Regarding the formation of thiocyanate, the most undesirable by-product of the cyanidation, ferricyanide and ozone were found particularly efficient to hinder their formation. Finally, the addition of ammonium sulfate during the cyanidation process showed some promising results in terms of both gold dissolution and cyanide consumption.CITATION:Ghasemian Langeroudi, E, Levasseur, B, Safizadeh, F, Olsen, C, Larachi, F and Gagnon, C, 2013. Optimisation of operating parameters for cyanidation of sulfide-bearing gold flotation tailings in order to prevent the impact of cyanicides, in Proceedings World Gold 2013 , pp 111-120 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 26, 2013