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By Baozhong Ma, Qian Li, Yonggang Wei, Shiwei Zhou, Bo Li, Chengyan Wang, Hua Wang

The magnesium-rich nickel oxide ore (w (Ni) =1.09 %, w (MgO)=29.08 %) mixed with 6 % and 8 % anthracite were roasted at different temperatures. XRD and SEM/EDS techniques were utilized to characterize the phase and microstructure transformation of the ores. The results show that lizardite and chrysotile of raw ore were converted into forsterite and enstatite during reduction roasting process. Simultaneously, iron and nickel oxide were reduced and migrated from the initial magnesium silicate. Fe3Si were formed when the roasting temperature went up to 1300 ℃ and 1350 ℃, and a small amount of Ni was observed in it. Temperatures got too high were not benefit to the polymerization of ferronickel.

Jan 1, 2015

By Jeferson Preti

Este trabalho apresenta a análise, o projeto e o desenvolvimento de um manipulador robótico industrial de baixo custo para linhas de produção. O aparato proposto possui potencial para contribuir na melhoria das condições de utilização de células robóticas no cenário industrial nacional, auxiliando na superação dos desafios existentes na implantação de células robóticas por pequenas e médias empresas, nomeadamente, custos de implantação, manutenção e reprogramação/reconfiguração. O manipulador robótico industrial foi projetado considerando uma estrutura metálica leve de baixo custo, com elementos mecânicos de precisão média e não dedicados, facilmente encontrados no mercado nacional. Além disso, o manipulador robótico foi projetado para ser capaz de alcançar velocidades médias provendo tempos de ciclo de operação quase equivalentes aos apresentados por robôs polares articulados convencionais, nas mesmas aplicações. O sistema de controle foi concebido para não empregar o dispendioso sistema convencional de hardware centralizado de controle de eixos, sendo esta operação realizada por algoritmo computacional executado no mesmo PC responsável pela gestão e integração dos processos. Assim, a operação emprega dispositivos acionadores descentralizados considerando o envio dos sinais de referência diretamente aos acionadores, possibilitando a compensação das restrições dos esforços da estrutura com recursos de suavização de trajetórias. A integração com o usuário foi projetada para possuir uma interface gráfica de manipulação amigável e que permita facilmente os processos de operação, manutenção e de reconfiguração. Fornecendo ainda, recursos de supervisão, histórico de falhas e assistência remota. Por fim, um protótipo do manipulador robótico industrial proposto é apresentado demonstrando as principais características construtivas e operacionais.

Jul 30, 2018

By Rudolf E. Greuer

Every mine contains inflammable materials, either in form of the minerals mined or in the form of brought-in supplies. Although great efforts are made to make mines as far as possible fireproof and to prevent ignition sources, the possibility of mine fires, like that of other accidents, will always continue to exist. Detailed statistics are available for coal mines. They show (65,112) that the number of major mine fires in the USA over the last 20 years has remained more or less constant with approximately 50 per year. The same number is reported (26) for the British coal mines. Other countries (147) report about 1 major fire for every 10 million tons of coal production. Conflicting data are published on the number of fatalities caused by fires, presumably because frequently deviating opinions on the cause of death exist. On the average (82,99) 4 miners are killed per year in the US and in the British coal mines. Although this number is much smaller than that for several other causes of fatalities, one must keep in mind that almost every small fire can develop into a large disaster.

Jan 1, 1973

By M. Abouhamad

According to the Canadian Urban Transit Association (CUTA), 140 Billion CAD is required to maintain, rehabilitate, and replace subway infrastructure between 2010 and 2014. The current practice adopted by transit authorities for prioritizing subway stations for rehabilitation is based on the station structural needs. While this classification is reflective of station condition, other factors, such as station size, location and passenger capacity, play an important role. The criticality of a station is an index that represents the functional importance of a station depending upon a set of identified factors. The system criticality is based on several attributes, such as station location, size, and nature of use. This paper presents a novel method of clustering subway stations for rehabilitation priority based on their criticality level. The different stations in a subway network are rated according to their relative importance against predefined attributes. The weights and scores of the attributes are computed with the help of experts and current subway network data. The analysis is done using the Fuzzy Analytic Network Process (FANP) to accommodate the subjectivity of human judgment as being expressed in natural language which entails ?fuzziness? in real-life problems and account for the interdependency between the selected attributes. The output of the model is a criticality based clustering of subway stations. The proposed framework helps authorities prioritize stations for rehabilitation and highlight stations with more criticality for a more robust asset analysis.

Aug 1, 2013

By Burt G. Look, David W. Lacey

"Certification of foundation capacity during the construction phase is often assessed by strength or weathering state descriptors based on visual observations. This case study used the Point Load Index (PLI) test as a quantitative tool in the construction certification of a pile’s design capacity. Construction phase tests were completed on irregular sized rock samples whilst comparable design phase testing was completed on intact rock core samples. Statistical comparisons were made to assess the repeatability between the PLI tests, with best-fit Probability Distribution Functions (PDFs) determined for both datasets. Pronounced differences were observed based on the PDF adopted to characterize the PLI dataset, the consequence of which would be a significant change to the pile’s design capacity. The adoption of the lower quartile value is shown to satisfy both design conservatism and construction simplicity requirements. The commonly held belief that rock samples produced during socket excavation may be biased towards the higher strength portion of the rock mass, is shown to be invalid for this site. As the central bridge piers were certified using Plate Load Tests (PLTs), the resultant load-settlement relationships were compared with the PLI strength assessments made for similar materials recovered from the adjacent abutment piles.INTRODUCTIONThe upgrade of the Foxwell Road Overpass across the Pacific Motorway in South East Queensland required the duplication of an existing four span bridge structure. The foundations of the new bridge included the installation of 1.2m diameter cast in place (bored) piles at the bridge abutments and 900mm diameter cast in place (bored) piles below a retaining wall to be constructed adjacent to the existing abutment.The site geology was dominated by the Palaeozoic Neranleigh–Fernvale Beds, predominantly comprised of argillite, sandstone and greywacke. Limited soil materials existed at the site, with Extremely Weathered (EW) rock typically encountered within metres of the existing ground surface. The exception to the existence of shallow rock were locations where existing filling of the site had occurred – i.e. approach embankments to existing bridge structure.Capacity of pile sockets is typically assessed onsite by descriptive rock strength or weathering assessment. Such descriptors encompass a wide range of values and lack precision. Due to the subjectivity of such assessment techniques – a factor of 3 is often observed in terms of strength assessment based on one’s interpretation of rock strength descriptors alone – uncertainty on site often occurs regardless of whether a lower bound, average or other characteristic design parameter applies."

Jan 1, 1900

By G. R. Elliott

Foreword The office of the Supervisory Mining Engineer, a branch of the l. Federal Government, is financially interested in no oil company and has no stock to sell. This office, however, is deeply interested in the proper and efficient development of Canada's natural resources. The people of Canada are interested in the petroleum development in Turner Valley for two principal reasons: As represented by the Department of the Interior, they are the largest owners of petroleum and natural-gas rights in the field; As a nation, they are vitally interested in the development of petroleum and natural gas as a national asset, and therefore, also, in all productive property, no matter who directly controls the leases. As has been stated by Mr. Charles C. Ross, Supervisory Mining Engineer, "The Department, being responsible for the administration of these public resources, necessarily requires regulations to protect them from abuse by lessees. Our portion of this responsibility is to record a complete history of all drilling operations and to see that proper drilling methods are adopted to prevent damage and wanton waste of the valuable natural resources under discussion." Not only does our position necessitate an impartial and a judicial viewpoint, but, being day by day in touch with all operations in the western provinces, we are uniquely situated to comprehend both individual and general problems.

Jan 1, 1930

By B. K. Mishra, Subrat Kumar Padhy, B. C. Tripathy, I. N. Bhattacharya

Manganese is a difficult metal to electrodeposit due to its high electronegativity and continues to possess unique process challenges. Manganese deposits of high quality are electrodeposited on 316 grade stainless steel from sulphate solutions in the presence of organic additives such as tetra ethyl ammonium bromide (TEABr), tetra propyl ammonium bromide (TPABr), and tetra butyl ammonium bromide (TBABr). The concentrations of these additives were examined over a relatively broad range to evaluate their effect on current efficiency, specific energy consumption and deposit morphology of the electrodeposited manganese metal. A maximum current efficiency of 68% was achieved in the presence of TEABr in the bath. X- ray diffraction studies revealed that (330) (411) planes were the most preferred planes of crystal growth during manganese electrowinning at a current density of 500 A/m2 resembling alpha-manganese irrespective of the nature of additive. Scanning electron micrographs showed smooth and uniform deposit morphologies when manganese was electrodeposited in the presence of TEABr.

Jan 1, 2014

By Albert G. Zima

THE conservation of strategic materials during war rime gives rise to many problems not commonly encountered in times of peace. During normal times, when world trade is unrestricted, we are apt to become lavish to a point of extravagance in our use of those materials which, during rime of war, become scarce owing to inadequate transportation and production facilities or because the enemy may be in position to control sources of supply. It becomes necessary, then, to enforce rationing of available sup-plies, and in some cases, where such supplies are wholly inadequate, we find we must resort to the use of substitute materials. We are now confronted with such a problem to an extent never before experienced, with the result that many of the commodities upon which our civilization depended are now either shut off completely or, because of the heavy demand occasioned by war production, are not available in sufficient quantities to meet requirements predicated on peace-time standards and manufacturing methods. It has become necessary, therefore, to make many changes, some of them very drastic indeed, to enable us to carry on our war effort effectively. This? discussion will deal briefly with one phase of this problem, namely, the conservation of alloys required in the making of steels necessary for war production. In line with a request from the War Production Board, the Technical Committee on Alloy Steels of the American Iron and Steel Institute made a study of experimental steels embodying the !east amount of alloying constituents, with the objective in mind of substituting these steels wherever possible for the standard alloy steels used heretofore. This study embraced the following phases: (1) The availability of silicon and manganese; (2) The average quantity of alloying elements recoverable from scrap; (3) The effect of increases in manganese and silicon contents on the general properties of steel; ( 4) The elements and ranges of elements which might be used to duplicate the hardenability of the steels now in use; (5) The effect of combining several elements in small quantities upon the properties of steel at various hardness and strength levels; (6) A determination as to whether or not the steels selected would suffice for general application. Working on this basis, the Committee arranged for the manufacture of several heats of steels containing various combinations of different amounts of such elements as silicon, manganese, chromium, nickel, and molybdenum. The steels thus produced were compared by hardenability tests.

Jan 1, 1943

By Y. Yang, L. Li, X. Liu

Coal mining in China is facing the transition from output to quality. Based on the total mining capacity and average production, the current situation of coal mining at mine, city, and province levels is analysed, and data in support for the layout of sustainable mining development and the optimization of output provided. The results show that 87% of China's coal is mined by underground methods, with an average production capacity of 0.93 Mt/a per mine. Open pit mining accounts for 13%, with an average mine production capacity of 5.73 Mt/a. The average mining capacity of coal mines in China is 1.05 Mt/a, with 1181 coal mines with an average capacity less than 0.3 Mt/a, accounting for 35% of the total coal mines but contributing only 4.51% to output. They are distributed in about 48 cities in six provinces, seriously restricting the transition to green coal mining. The coal industry should speed up the closure of small coal mines in key provinces and cities, eliminate outdated production capacity in the central region, increase the speed and proportion of coal resources moving westward, and promote high-quality development of coal mining.

Jan 26, 2023

By Fred Tarquinio, Giovanni Bonita, Lars Wagner

"A new embassy for the Peoples Republic of China is under construction in Washington, DC. The 475,000 square feet (44,125 m2) structure has five levels below ground and four above, making it the largest embassy in Washington DC. A vertical soil nail wall was used as the primary support of excavation system for the project. The soil nail wall was irregularly shaped, benched in areas, and up to 98 feet (29.9 m) in height. The soil nail and shotcrete system consisted of approximately 1,600 soil nails and 50,000 square feet (4,645 m2) of exposed shotcrete wall surface. Design and construction challenges included soft soil conditions, inside wall corners, underground utilities, seismic impacts from blasting, and logistical and political factors. Overall, wall movements were lower than expected, with maximum horizontal movement less than 0.25% of the total height of the excavation. INTRODUCTIONThe proposed Embassy of the Peoples Republic of China in Washington, DC, will consist of about 475,000 ft2 (44,125 m2) of building space and contain up to four fl oor levels above ground and fi ve levels of basement (Figure 1). When completed, the building will be the largest embassy in Washington, DC. The architect for the project, Pei Partnership Architects, along with the world-renowned architect I.M. Pei, made effi cient use of the site by inserting the building into the existing slope. Consequently, excavations reach heights up to 98 feet (29.9 m) on the southern side of the property and 42 feet (12.8 m) on the northern side.The soil nail and shotcrete system consisted of approximately 1,600 soil nails and 50,000 square feet (4,645 m2) of exposed shotcrete wall surface. The location of the building relative to the property line called for tight excavation requirements, including precise wall positions and shotcrete tolerances. Design and construction challenges included soft soil conditions, inside wall corners, arched walls, underground utilities, seismic impacts from blasting, and logistical and political factors."

Jan 1, 2007

By Richard D. Miller

This Bureau of Mines publication contains analyses and related source data for 271 natural gas samples from 22 States collected during calendar year 1982. All samples were obtained and analyzed as part of Bureau of Mines investigations of the occurrences of helium in natural gases of countries with free market economies. This survey has been conducted since 1917. The analyses published herein were made by the mass spectrometer and chromatograph. The results of the investigation of the occurrences of helium are published annually to make the information available to the petroleum industry and the general public. Twenty-six publications have presented the results of 13,051 gas analyses vide prior to 1982. The first 3 bulletins (1-3)3 contain analyses and related source data on 5,218 gas samples collected from 1917 through 1960; these bulletins have been supplemented annually by information circulars (4-17, 19-24, 26) containing 7,833 analyses of samples collected since 1960.

Jan 1, 1983

By K. Barani, S. M. S. Ganji

Creatine was used as a lixiviant for gold dissolution from gold ore. The effects of creatine concentration, temperature, leach time, and pH were examined for their influence on extent of gold dissolution. The results show that at a temperature of 75°C and pH 11.5, gold dissolution increased from 51% to 88% on increasing creatine concentration from 25 to 50 g/t. Further increase in creatine concentration showed a negative effect on the gold dissolution. Gold dissolution increased from 47% to 87% by increasing the temperature from 25°C to 55°C, and from 61% to 89% by increasing pH from 10 to 11.5. Under the optimum conditions of solids’ content of 30%, pH 11.5, creatine concentration of 100 g/t, temperature of 75°C, and hydrogen peroxide addition of 2%, about 90% of the gold could be dissolved from the ore after 24 h. A comparison between creatine and cyanide leaching showed that 90% gold dissolution was achieved at a cyanide concentration of 300 g/t, which is three times higher than the creatine concentration under optimal conditions.

Apr 14, 2024

By John C. Hartley

Large areas of the anthracite beds in the Wilkes-Barre, Pa., region have been first-mined in such a manner that over half of the original coal has been left underground as pillars to support the overburden. To recover the maximum amount of this remaining coal, improved devices to support the roof while pillars are being extracted are needed. Also needed are suitable backfilling systems that will stabilize the strata during the mining and effectively limit the inevitable subsidence after pillars are removed. Accordingly, the Federal Bureau of Mines furnished 400 yielding steel props that had been purchased abroad, where this type of prop had been used successfully. The cooperating company arranged for concurrent tests with a mechanical stower designed and built by an American manufacturer. In the area in which the experiments were conducted, pillar removal, using conventional timbering, was most difficult because the roof fractured badly, the installation of timbers consumed a substantial part of the work effort, and some coal nearly always was lost. With the application of the yielding props, the time needed for securing the roof was reduced 33.9 percent; production per man-shift was in¬creased over 33 percent; coal recovery was improved more than 9 percent; and the convergence between roof and floor, during mining and backfilling, amounted to as much as 8.03 inches without any break in the roof. However, in September 1953 some roof rock fell in pillar 10 owing to insufficient props in a small area where the ends of three top holes drilled in the coal face extended up into the roof rock.

Jan 1, 1956

By N Collins, A Woodley, A N. Danoucaras, C McCombe, N C. Kunz

Over the past decade, the mining industry has come to recognise the importance of water both to itself and to others. Water accounting is a formalisation of this importance that quantifies and communicates how water is used by individual sites and the industry as a whole. While there are a number of different accounting frameworks that could be used within the industry, the Minerals Council of AustraliaÆs (MCA) water accounting framework (WAF) is an industry-led approach that provides a consistent representation of mine site water interactions regardless of their operational, social or environmental context that allows for valid comparisons between sites and companies.The WAF contains definitions of off-site water sources and destinations and on-site water use, a methodology for applying the definitions, and a set of metrics to measure site performance. The WAF is comprised of two models: the input-output model, which represents the interactions between sites and their surrounding community, and the operational model, which represents on-site water interactions.Members of the MCA have recently adopted the WAFÆs input-output model to report on their external water interactions in their Australian operations, with some adopting it on a global basis. To support this adoption, there is a need for companies to better understand how to implement the WAF in their own operations. Developing a water account is non-trivial, particularly for sites unfamiliar with the WAF or for sites with the need to represent unusual features. This work describes how to build a water account for a given site using the input-output model, with an emphasis on how to represent challenging situations.CITATION:Woodley, A, Danoucaras, A N, McCombe, C, Kunz, N C and Collins, N, 2013. A robust methodological approach for mine site water accounting, in Proceedings Water in Mining 2013 , pp 335-342 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Nov 26, 2013

By W. Curlook, L. M. Pidgeon

THE PURPOSE of this investigation was to study part of the ternary system Co-Fe-S. Jensen ( 1) established the solubility limits of sulphur in pyrrhotite. The compound with 61.7 per cent Fe, corresponding to a formula Fe12S13, was found to melt congruently at l,192°C. Hulsmann and Weibke(2) determined the Co-S phase diagram from O to 35.2 per cent S. The solubility limits of sulphur in the com-pound Co(l-x)S were not determined. The initial object of the present in-vestigation was to determine the composition at which the compound Coci-xiS melted congruently. Once this was ascertained, it was decided to investigate the ternary system Co-Fe-S from the region of 100 per cent Co(1-x) S to the region of 100 per cent Fe12S13.

Jan 1, 1953

By W L. Daniels, C Stilson, C Zimmerman

Mineral sands mining for ilmenite, rutile and zircon has disturbed over 1000 ha of prime farmland in Virginia (USA) since 1997 and additional areas are likely to be disturbed in Virginia and North Carolina (USA) over the next 15 years. Full-scale mining operations at the Old Hickory Project in Virginia were initiated in 1997 by Iluka Resources Inc. and restoration protocols have continued to evolve in response to a variety of economic, technical and social issues. Early on, the return of these lands to agricultural row-crop production was complicated by vertical stratification of tails + slimes and lateral variability in soil physical conditions in the reclaimed pits and by limited topsoil return. Virginia Tech and Iluka have worked cooperatively with all stakeholders for over 20 years to review the pre-existing research base, conduct new and innovative site-specific research and thereby provide reasonable expectations of post-mining soil productivity levels. In 2004, Virginia Tech, Iluka Resources and a local leaseholder (Carraway-Winn family) agreed to jointly manage a 45 ha research demonstration farm where the long-term effects of alternative soil reconstruction practices are being rigorously monitored for both row crops (corn and wheat) and forage production. All mined land crop yields are also compared to an adjacent undisturbed exceptional quality prime farmland soil. Row crop yields between 2005 and 2010 were significantly above county average yields (regulatory target level) and approximately 75 - 80 per cent of undisturbed adjacent prime farmlands. The state regulatory authority has recently relaxed its position on the necessity of topsoil return versus use of topsoil substitutes based on appropriate on-site research results and the ability of the reclaimed soils to meet comparative local county crop yield targets. This cooperative effort allows all clientele groups to objectively assess the post-mining productivity of these mined lands while providing an invaluable educational opportunity for the mining industry. CITATION:Daniels, W L, Stilson, C and Zimmerman, C, 2012. Development of effective rehabilitation protocols for mineral sands mining in Virginia, USA, in Proceedings Life-of-Mine 2012 , pp 97-104 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 10, 2012

By Lawrence H. Roth

Past failures of coal refuse embankments have resulted in more intensified efforts in inspections of coal refuse sites. Inspections, however, are mainly qualitative and time consuming. In August 1975 CH2M HILL was awarded a contract to identify, develop, and test a rapid system for monitoring coal refuse embankments to aid in inspections. The rapid monitoring system developed uses convergent and vertical photography from conventional fixed-wing aircraft. The system was tested on an active landslide and on two coal refuse facilities using both black and white and color infrared film. Field tests showed the system was capable of accurate measurement while providing qualitative data through photointerpretation. The accuracy of the system allows it to be used to monitor coal refuse embankments, tailings dams, major earth dams, and natural slopes. Bibliographies of literature reviews in the area of past coal refuse embankment failures, monitoring instruments and methods, and photogrammetry are included.

Jan 1, 1977

By A. C. Rubel

WHAT does management expect of W and from an engineer? First and foremost, it expects that he should become, and therefore should fit himself in every way to be, a part of management so that he may assume as much and as many of the responsibilities of management as his ability and the opportunities of the job permit. Let me make clear at the start that the profession of pure, technical engineering offers but limited opportunities at the top levels because of the inherent organization of engineering work. The line of succession to top jobs may be likened to a cone with a broad base and an extremely sharp point. Consider any oil company, large or small, or any operating function of that company, and you will find few top engineering jobs in the organization. This is true by the nature of the work handled. There will be a few district engineers depending on the spread of operations, a chief petroleum and production engineer, perhaps a few research engineers, possibly some technical executive assistants, and that is usually all. The road to these jobs is a long one and the competition is tough. The larger the organization the greater the opportunity, but always the ratio of engineers to top engineering jobs is only a small one.

Jan 1, 1947

By M. Djivre, T. Eger, A. Godwin, I. Bhattacherya

Load-haul-dump vehicles (LHDs) are extensively used in underground mining, however, equipment design and operating conditions contribute to restricted operator sight lines. The inability to clearly see people, objects, or hazards around the machine has contributed to a number of accidents including fatal injuries. In order to identify vehicle design characteristics resulting in restricted and blocked sightlines, line-of-sight assessments are traditionally completed in the field. However, field methods are unable to evaluate lineof- sight under dynamic operating conditions, and are limited in their ability to provide feedback on the impact of various operator characteristics such as sitting height. Results of this research show computer simulation and virtual reality can be successfully used to evaluate line-of-sight during the operation of LHD vehicles. In order to benefit from virtual reality applications, the work environment, LHD vehicle, and human posture need to be represented as accurately as possible. A computer simulation program with ergonomic analysis features, Classic JACK 3.1, was successfully used. Threedimensional CAD models of LHDs were developed from manufacturer specifications and pictures taken from LHDs currently in use. The LHD models were imported into the JACK environment, a digital human was positioned in the cab of the LHD vehicle, and the vehicle and human were driven over a typical mine route. Real-time feedback in the JACK program was used to identify what the operator could see under different operating conditions. Machine characteristics and operating scenarios resulting in impaired line-of-sight were successfully identified with this method. The JACK program could also provide real-time feedback on the human’s joint forces and torques, strength requirements, postural comfort, and metabolic energy expenditure. As a result, this method could be used to successfully evaluate musculoskeletal injury risk factors along with system design recommendations to improve workplace safety and productivity in any setting. The LHDs evaluated in the JACK software package can also be combined with mine models and imported into other VR software packages (e.g. Blender) in order to enable viewing in Laurentian University’s Virtual Reality Laboratory. The VR models using these packages can be viewed in stereo to provide better appreciation of spatial vision issues.

Jan 1, 2005

By Carroll W. DeKock

Thermodynamic data for selected metal sulfates were critically evaluated and compiled as part of the Bureau of Mines program to provide a scientific base for use in developing new technology and predicting the feasibility of new processes. Values for Cp°, S°, H° - H°298, - (G° - H°298)/T, ?RC, ?Gf°, and log Kf as functions of temperature are given in tabular form. Thermodynamic data were compiled for Ag2SO4, A12(504)3, A12(S04)3?6H20, BaSO4, BeSO4, BeSO4?2H2O, BeSO4?4H20, CaSO4, CaSO4?1/2H20, CaSO4?2H2O, CdSO4, CdSO4?H20, CdS04?8/3H20, 2CdO?CdSO4, Cs2SO4, In2(S04)3, K2504, KA1(S04)2, KA1(S04)2?12H20, Li2SO4, L12SO4?H20, MgSO4, MgSO4?H2O, MgSO4?2H20, MgS04?4H20, MgS04?6H2O, MgS04?7H2O, Na2SO4, Na2S04?7H20, Na2SO4?10H20, (NH4)2SO4, NH4A1(S04)2, NH4A1(S04)2?12H20, PbSO4, Rb2SO4, T12SO4, and Zr(S04)2.

Jan 1, 1986