Search Documents

By Mike Johnson, Niels Verbaan, David Dreisinger

The Search Minerals Foxtrot project in Labrador represents a significant Canadian resource of rare earth elements rich in the sought after heavy rare earth elements (19.8% HREE/TREE). A preliminary economic assessment of the project indicated that the project is technically feasible and economically attractive. A variety of metallurgical test programs have been undertaken which have led to significant streamlining and simplification of the process flowsheet. The improved flowsheet should allow Search to reach production earlier and will use conventional processing equipment. The results of these test programs are presented and discussed in this paper.

Jan 1, 2014

By P. R. Jones

The Bureau of Mines has written a computer program for the design and cost of a shell and tube type heat exchanger, in which a change in phase occurs on the shell side. The total cost, which was minimized, includes the annual fixed charges and annual operating costs. The program was written to meet the following requirements: (1) Triangular pitch, (2) single or multiple pass, and (3) heating or cooling. Price optimum design was obtained for four standard tube diameters and pitch. Standard heat exchangers whose area equaled or exceeded the required area are also listed. The program was made adaptable to various fluids and to various tube dimensions by including many of the required data such as physical properties of the fluids, tube data, and standard shell data as input data.

Jan 1, 1969

By K. C. Dean

This report is the first of a series concerned with processes for producing magnesium. These reports will evaluate metallothermic, carbothermic , and electrolytic production methods, and will furnish a cost basis for comparing the processes. Areas deemed most promising for future research will be delineated for each procedure. This report presents briefly the history of the metallothermic process, and describes the operations of the Defense Plant Corp. (DPC) plants that employed the process. A hypothetical plant designed to produce 12,000 tons of magnesium per year, using ferrosilicon as a reductant, is described, and raw materials, energy, and major equipment requirements are estimated. Several process modifications are suggested for future research.

Jan 1, 1965

By X. Shi, K. S. Kaspnak

"The generation of free radicals from reactions of nickel (Il)-thiol complexes with molecular oxygen and model lipid hydroperoxides was investigated by electron spin resonance (ESR) utilizing 5,5-dimethyl-1-pyrroline-N-oxide (DMPO) as a spin trap. Incubation of nickel (II) [Ni(II)) with cysteine in an aerobic environment generated hydroxyl (·OH) radical, which then reacted with cysteine to generate a carbon-centered alkyl ( · R) radical. Radical generation was inhibited under a nitrogen atmosphere. Model lipid hydroperoxides, cumene hydroperoxide, and I-butyl hydroperoxide enhanced the yield of these radicals and also generated an alkoxyl (·OR) radical. Radical yield decreased by approximately half under a nitrogen atmosphere. Although histidine did not cause radical formation in the reaction between Ni(II) and cumene hydroperoxide under aerobic conditions, the addition of histidine to a mixture containing Ni(ll), cysteine, and cumene hydroperoxide under the same experimental conditions increased the yield of · R radical but lowered the yield of ·OR and ·OH radical adducts. It thus appears that histidine caused the ·OH attack to be more site-specific. Similar results were obtained utilizing 1-butyl hydroperoxide. Penicillamine or N-acetylcysteine yielded similar results except that under aerobic conditions, reaction between Ni(ll) and N-acetylcysteine without hydroperoxide did not generate a significant concentration of free radicals. Under the same experimental conditions, cystine did not generate any detectable free radicals, suggesting an important role of the -SH group in Ni(II)-mediated free radical generation. The results indicate that free radical generation from the reaction of Ni(Il)-thiol complexes and molecular oxygen, and/or lipid hydroperoxides, may play an important role in the mechanism(s) of Ni(II) toxicity and carcinogenesis. INTRODUCTIONWhile nickel is a well-recognized carcinogen [l, 2]. the underlying biochemical mechanisms remain unclear (3, 4). Recent studies suggest that these mechanisms may involve oxidative DNA damage through free radicals, especially the hydroxyl (•OH) radical [5-13]. The mechanisms of nickel carcinogenicity and toxicity may also involve lipid peroxidation [14-21]. Unlike ferrous ion [Fe(II)], the Ni(II) cation itself does not directly react with 02, H2O2, or lipid hydroperoxides to generate free radicals [12, 21]. However, it has been reported that Ni(II) complexes with certain synthetic oligopeptides, e.g., tetraglycine or glycylglycylhistidine, make Ni(II) reactive with 02. This reaction results in transitory formation of Ni(III) and degradation of the organic ligand via free radical reactions [22]. Such Ni(II)-peptide complexes are also capable of reacting with H2O2 to produce oxygen free radicals [11, 12]. Although the cellular environ¬ment may not contain these particular peptide ligands that are known to render Ni(II) redox active in vitro, it does contain a variety of oligopeptides that are capable of forming Ni(II) complexes at physiological pH, and thus may facilitate Ni(II) redox activity in vivo. These oligopeptides include glutathione (y-L glutamylycysteinylglycine), carnosine (homocarnosine (y aminobutyryl-L-histidine), and anserine ( B-alany1-3-methyl-L-histidine)."

Nov 1, 1995

By R. R. Oder, R. E. Jamison, E. D. Brandner

This paper presents the preliminary test results obtained using a 0.38-kg/s (3,000-lb/hr) beta prototype MagMill. In processing Upper Freeport coal, the beta prototype recovered 82 % of the weight of the feed and 91 % of the heat content while reducing the potential emissions of sulfur by 61%. Pyritic sulfur in the MagMill product was reduced by 78% compared with that in the feed. For all runs, the mill product particle size was controlled to between 70% and 80% -741m (200 mesh). Recoveries of mercury, arsenic and selenium ranged from 35% to 45% of the amounts found in the feed. Power draw was reduced by 26%, and mill throughput was increased by 9% compared to the pulverizer operating with no magnetic separator attached.

Jan 1, 2002

By Leon Lorenzen, Charlene Gokhale

"In excess of 24 x 106 tons (Eskom, 1997) of coal-derived fly ash is produced annually in South Africa for the production of electric power. A large quantity of this ash is disposed of as a solid waste in landfills, thus posing a serious environmental problem. Due to the shortage of landfill sites, new ways of utilising fly ash are needed. Recently several authors have shown that various combustion fly ashes can be converted into zeolites to obtain industrial products with applicability in environmental management. Geopolymerisation has emerged during the last few years as a possible solution to some waste stabilisation and solidification problems. henolic compounds have been shown to be toxic to soil microorganisms at the parts-per-million level. Indeed several of the organic compounds classified by the U.S. Environmental Protection Agency as priority pollutants, are phenols. Immobilisation of phenols by adsorption on zeolites and encapsulation in a geopolymer appears to be a promising solution to this problem.This paper reports a technique for the production of a low-silica sodium zeolitic material from fly ash (zeolite NaP1), and its application for the stabilisation of phenols by adsorption and subsequent encapsulation in a geopolymer matrix. A commercial zeolite, clinoptilolite was also utilised as an adsorbent. Due to their uniform pore sizes and large surface areas, zeolitic materials are suitable for ion exchange and adsorption of certain organic substances. Adsorption data show that the commercial zeolite, clinoptilolite was an effective adsorbent for organics. Adsorption data showed that between 51.2 ppm and 74.3 ppm of chlorophenol or between 15.4 ppm and 32.5 ppm of phenol could be adsorbed. Physical encapsulation of the coated zeolite loaded with organic within a geopolymeric matrix increased the compressive strength of the matrix from 28.80 kN to 40.79 kN. Leaching data for the various geopolymer matrices with encapsulated and loaded zeolites show no organics being leached from the system at a detection level of 2ppm. According to the SABS these would have been acceptable organic concentrations within a waste water stream."

Jan 1, 2003

By Harry Siewert

"The commissioning of the 4th concentrator (C4) at Freeport Indonesia in early 1998 increased total mill throughput from 130k to 230k tonnes per day. The C4 flowsheet consists of a single 38 ft diameter SAG mill, four 24 ft diameter ball mills followed by four banks of 4,500 ft3 WEMCO flotation cells.The design of the C4 rougher flotation circuit was based on the expectation that the copper and gold recoveries achieved with the 4500 ft3 flotation cells would be equivalent to or better than that achieved with the 3,000 ft3 flotation cells in the 3rd concentrator (C3) rougher circuit. This assumption was due to the fact that the C4 flotation feed size would be less than 15% +212 microns compared to the C3 rougher flotation feed size of less than 23% +212 microns. By mid 1998 it had become apparent that the C4 rougher flotation copper and gold recoveries were below those predicted.In order to determine the cause of the lower recoveries, stage by stage rougher flotation surveys were performed in all four concentrators. The results of the surveys showed that the C4 rougher flotation circuit had a lower recovery of +200 micron material than that achieved in the C 1, C2 and C3 concentrators. Through mineralogical analysis, it was determined that a majority of the copper contained in the +200 micron fractions was liberated and recoverable. This paper describes the steps taken to increase coarse particle recovery, overall plant recovery and the results achieved."

Jan 1, 2001

By M. M. Gilkey

This report describes the effects of water shortage on Arizona's mineral industries. The information presented was obtained in interviews with company representatives. Operations covered included all State metal mines using substantial quantities of water and all concentrators and smelters. Also included in the survey were 8 operations in the nonmetallic group; 22 in the plating, metal-fabricating, and metal-forming categories; 1 public-utility power company; and 6 water companies. The extent of the water shortage in Arizona is reflected in mineral- industry water-use practices, in the high cost and low quality of water used at many operations, and in the stringency of State control of well drilling and pumping. Many mineral-industry operations are among those users most seriously affected by the uneven water supply.

Jan 1, 1963

By M. M. Gilkey

This report describes the effects of water shortage on Arizona's mineral industries. The information presented was obtained in interviews with company representatives. Operations covered included all State metal mines using substantial quantities of water and all concentrators and smelters. Also included in the survey were 8 operations in the nonmetallic group; 22 in the plating, metal-fabricating, and metal-forming categories; 1 public-utility power company; and 6 water companies. The extent of the water shortage in Arizona is reflected in mineral- industry water-use practices, in the high cost and low quality of water used at many operations, and in the stringency of State control of well drilling and pumping. Many mineral-industry operations are among those users most seriously affected by the uneven water supply.

Jan 1, 1963

By J. Spotts McDowell

Ackowledgments........................... 5 Introduction............................. 5 The Silica Minerals. Stability Relations......................... 6 Optical Properties........................ 9 Density.............................. 10 Melting Points....;..................... 10 Thermal Expansion..................,..... 10 Solubilities............................ 12 Identification of Cristobalite and Tridymite.............. 12. The Silica Refractories. Raw Materia1........................... 13 American Deposits....................... 13 Properties Determining Usability................ 15 Expansion on Heating..................... 16 Texture........................... 17 Silica Brick............................ 17 Manufacture........................... 18 Properties of Silica Brick .................... 19 Analysis ......................... 19 Density......................... 19 Porosity......................... 20 Strength....................... 21 Melting Point....................... 22 Specific Heat....................... 22 Thermal Conductivity................... 23 Expansion........................ 24 Effect of Rapid Temperature Change.........:... 26 Constitution......................... 26

Jan 1, 1918

By Andreas Oberrauner

Content ? What is? an introduction ? Crushing technology ? Conveying in pits ? Pit-exiting strategies ? Mine Planning in IPCC ? Summary/Conclusions EHS slide ? Sandvik?s objective is zero harm to our people, the environment we work in, our customers and our suppliers ? Current EHS-figures will be added in August! Who is this? Andreas Oberrauner ? Born in Austria ? Living in Cologne (Ger) ? Mining Engineer ? Montanuniversitaet Leoben (Austria) 2000-2005 ? PhD on Mineral Processing 2008-2012 ? Sandvik Mine Planning Department ? Main task: Provide practical and efficient solutions for mining-challenges

Aug 1, 2013

By Brock Wallis, Steve Davidow

The following text will present the concept of rock socketed drilled shafts used to support electrical substation structures, and discuss the cost and schedule risks that traditional design responses to unforeseen shallow rock can pose to a project. Design considerations will be detailed, including rock characterization, shear strength of drilled shafts, and modeling lateral resistance of the shaft and surrounding rock. The specific case of drilled shafts installed for heavily loaded structures at the Moxie Freedom Substation will provide an example of how close collaboration between the engineer and contractor to refine designs based on site-specific feedback can provide tangible benefits to the project. In this example, value engineered designs resulted in an approximate 40% reduction in shaft/concrete volume and a 60% reduction in total rock socket depth. PROJECT OVERVIEW The Moxie Freedom Project included the construction of a new 500 kV switchyard in Berwick, Pennsylvania. The foundation contractor was selected to install both small and large diameter drilled shaft foundations to support the structures within the switchyard. The small diameter shafts were utilized to support transformers, switches, bus supports and a static mast, while the large diameter shafts were used to support one 180-foot monopole and six H-Frame structures. CHALLENGES: ROCK SOCKETED DRILLED SHAFTS Available geotechnical data at the time of bid included limited borings and seismic refraction. The borings were not located at every structure, and the contractor and design engineer were left to interpret desktop studies and geophysics to determine the probable site-specific conditions at each foundation. The data suggested substantial variability in the quality and depth to bedrock across the project area, indicating significant risk of deep embedment into bedrock at all seven large diameter shaft locations. Rock socketed drilled shafts pose unique challenges for both designers and contractors, and the topic has become a focus of national foundation organizations. Traditional design models result in deeper and/or larger diameter shafts where rock is encountered. In the case where site-specific geotechnical conditions are not clearly understood and rock is encountered at shallow depths, this can lead to significant additional rock drilling, impacting overall project cost and schedule. Rock drilling can result in more than ten times the cost of soil drilling and can easily take in excess of ten times longer to excavate.

Jan 1, 2018

By K. A. Natarajan, M. R. Sabari Prakasan

"Biodegradation of sodium isopropyl xanthate using two types of bacterial strains, Paenibacillus polymyxa and Pseudomonas putida, is demonstrated. At concentrations higher than 50 mg/L, the presence of xanthate in the growth medium resulted in bacterial toxicity, retarding growth kinetics. Adaptation through serial subculturing in the presence of higher xanthate concentrations resulted in the development of xanthate-tolerant bacterial strains. Stress proteins secreted by bacterial cells grown in the presence of xanthate were isolated. Bacterial cells could utilize xanthate as a growth substrate, degrading xanthate species in the process. Acidic metabolic products generated by bacterial metabolism promoted efficient xanthate decomposition. Probable mechanisms for the biodegradation of isopropyl xanthate are illustrated.IntroductionDifferent types of alkyl xanthates (ethyl, isopropyl, amyl, etc.) have been used as flotation collectors in the concentration of sulfidic ores for several decades. Large quantities of waste water and xanthate-containing effluents are generated by ore flotation processes, posing considerable environmental challenges. Billions of cubic meters of such process waste waters are produced annually across the world, most of which are discharged to the environment, often without any treatment. Leakages and accidental release of xanthate reagents from manufacturing plants and during transportation and storage can also contaminate the environment. Residual concentrations of xanthate reagents are encountered in waste effluent, which are found to be toxic to aquatic life and unfit for human consumption (Harris, 1984; Okibe and Johnson, 2002). Further, direct recycling of such waste waters for plant operations can compromise water quality standards required for process operations. The presence of residual xanthate in recycled waters from flotation plants deleteriously influences flotation processes. Xanthate can be easily decomposed at low pH values; however, CS2, which is more toxic, will be produced by the acidification of neutral and mildly alkaline xanthate-containing solutions. Physico-chemical methods such as flocculation, chemical oxidation and decomposition and physical adsorption used to remove residual collector reagents from mill process waters are often expensive and not environment-friendly (Oliveira and Rubio, 2009; Cheng et al., 2012; Molina et al., 2013,)."

Jan 1, 2015

By Guy Archambault, Réal Daigneault

"Un trait marquant du cadre tectorwstratigraphique de la Sous-province de l'Abitibi est la présence de nombreux couloirs de déformation d’extension régionale et sub-concordants au grain stratigraphique. La présence de grandes masses granitoïdes qui perturbent l'allure du grain tectonique est typique de la partie nord de la Sous-province de l'Abitibi. Des rides E-W constituées de complexes plutoniques précoces forment des reliefs structuraux agissant comme des moles résistants qui interfèrent avec la déformation régionale.Deux types de couloirs de déformation sont distingués, les couloirs de bordure et les discontinuités structurales. Les couloirs de bordure représentent des auréoles de déformation élevée qui s’accompagnent généralement d’un métamorphisme au faciès amphibolite. lls suivent /'interface entre les roches granitoïdes et les assemblages supracrustaux. Ces couloirs sont de puissance kilométrique et sont confines, surtout au sein des roches vertes, a l’interface des complexes granitoïdes d’importance. La limite entre la Sous-province de l'Opatica et les roches supra crustales de l'Abitibi est caractérisée par un important couloir de bordure issu possiblement d'un chargement tectonique irrégulier et concentre lors du raccourcissement horizontal.Les discontinuités structurales sont des failles ductiles qui se propagent surtout en direction E-W mais avec des variantes de directions SE et NE. Les discontinuités E-W se caractérisent par la présence d'une linéation d'étirement à fort angle de chute. Les discontinuités SE sont caractérisées par des linéations d'étirement horizontales et directionnelles et les mouvements observes sont system attiquement dextres. Les discontinuités NE sont des failles à comportement beaucoup plus fragile et se distinguent par des composantes de mouvement senestre. Elles sont tar dives par rapport aux discontinuités E-W et SE et ne représentent pas la symétrique du système SE.La combinaison des systèmes E-W et SE décrit un motif anastomose a l' échelle régionale. Les failles ductiles se rejoignent defaçon asymptotique, isolant des blocs peu ou pas affectes par la déformation. L'anastomose est un phénomène qui se produit a toute échelle et est reliée principalement aux Mt érogénéités et aux anisotropies 1) des forces agissantes (champs de contraintes régionale et locale) et 2) de la réponse del' empilement supra crustal (compositions différentes, fabrique initiate, propriétés mécaniques variées, niveaux d'altération).Dans le but de respecter un raccourcissement horizontal N-S, différents modelés sont proposés; ils mettent en cause soit une transpression dextre, soit des failles inverses réactivées en failles décrochèrent dextres soit des failles de chevauchement redressées."

Jan 1, 1990

By Hassan Ghaffari

? HPGR Process/Overview ? HPGR vs. SAG ? The Manufacturers ? Mine Operations using HPGR ? Projects by Wardrop/Tetra Tech ? Economic Benefits ? Questions Main Operating Parameters ? Press Force (N/mm2) ? Roll Speed (m/s) ? Moisture Content (%) ? Feed Particle Size Distribution Specific throughput M* = throughput/D*L*V (ts/hm3) Flake thickness/strength in balance with the compressing force (floating roll situation)

Aug 1, 2013

By R. G. Reddy

Reduction of different chromite ores with carbon was studied as a function of C/FeO ratio and temperature in the range 700 °C to 1100 °C by thermogravimetry (TGA) analysis. Powders of chromite ore(-150 mesh) and carbon(-150 mesh) were thoroughly mixed in a desired proportions and were placed in the reaction crucible. The reduction rates of reactions were determined by continuously monitoring the weight loss as a function of time at constant temperature using TGA set up. The analysis of results suggest that FeO present in the chromite ores is reduced to Fe involving gaseous intermediates CO and CO2. The overall rate of FeO reduction is controlled by the oxidation of carbon. A kinetic equation, that of random nucleation, was proposed. The activation energies for the reduction of FeO, present in Roast Movat and Transvaal ores, with carbon were determined to be 55800 and 23000 J/mole, respectively. The results of the present study are compared with the data available in literature. The low activation energy values as determined in this study suggest that the carbon oxidation reaction is catalyzed. It is concluded from the present investigation that the low grade chromite ores can be significantly upgraded to higher value added chromite that can be used as a feed source for economical smelting.

Jan 1, 1998

By L. G. Stolarczyk, Y. Luo, S. S. Peng

Detection and assessment of severe geological anomalies ahead of a longwall face greatly benefits the mining operation. Electromagnetic-based Radio Imaging Method (RIM) is one of the most promising geophysical methods for this task. Based on two decades of development, the latest RIM instrumentation (RIM-IV) has expanded its operational range up to 1,800ft.A site demonstration of the RIM-IV technology was recently conducted within a longwall panel. An extensive ground truth study was performed to evaluate the accuracy of the RIM survey results. This study compared the generated RIM tomograms of attenuation rate with the mapped geological anomalies. Three different approaches have been employed to examine the accuracy of the RIM results and to correlate the measured signal attenuation rates with physical properties of the coal seam. The study shows that the RIM-IV technology is able to identify and delineate those geological features that would severely affect the longwall mining operation.

Jan 1, 2004

By Paloma Lazaro, Moe Momayez

Heat-related illnesses (HRI) are relatively common in both hot surface and underground mining operations. When workers are exposed to extreme heat or strenuous work in a hot environment, they become prone to heat stress. Heat strain is the result of the body’s response to external and internal heat stress. It is therefore vital for the conditions leading to heat strain be detected and treated in a timely manner. Heat-related illnesses are manifested by exhaustion and heat stroke. The predicted heat strain (PHS) [ISO 7933 (2004)] model has been developed to predict the health condition of the worker in terms of core body temperature and water loss. The PHS model tested in this study is based on eight physical parameters that are measured at different intervals during a work shift. They include air temperature, humidity, radiation, air velocity, metabolic rate, clothing insulation, posture, and acclimatization. The model predictions are then compared with a direct physiological measurement, such as core body temperature. We present the results of an extensive study that monitored and predicted body’s response to heat stress under different environmental and working conditions. The PHS model provided reliable results in most instances in comparison with other prediction methods currently in use in the field.

By Paloma Lazaro, Moe Momayez

Heat-related illnesses (HRI) are relatively common in both hot surface and underground mining operations. When workers are exposed to extreme heat or strenuous work in a hot environment, they become prone to heat stress. Heat strain is the result of the body’s response to external and internal heat stress. It is therefore vital for the conditions leading to heat strain be detected and treated in a timely manner. Heat-related illnesses are manifested by exhaustion and heat stroke. The predicted heat strain (PHS) [ISO 7933 (2004)] model has been developed to predict the health condition of the worker in terms of core body temperature and water loss. The PHS model tested in this study is based on eight physical parameters that are measured at different intervals during a work shift. They include air temperature, humidity, radiation, air velocity, metabolic rate, clothing insulation, posture, and acclimatization. The model predictions are then compared with a direct physiological measurement, such as core body temperature. We present the results of an extensive study that monitored and predicted body’s response to heat stress under different environmental and working conditions. The PHS model provided reliable results in most instances in comparison with other prediction methods currently in use in the field.

By P. Kolodziejczyk

Mining seismicity can be harmful both under and on the surface. ? Tremors are not totally damaging, but destructive to buildings and infrastructure, especially in highly urbanized regions, such as Upper Silesia in Poland ? Destroy the social appreciation, trust and support for mining industry ? To prevent or reduce these effects, engineers and scientists develop methods allowing prediction of ground shaking intensity near buildings and various losses that can result from it Evaluation and prediction of mining tremor?s damaging influence on buildings is usually solved with two steps: ? Estimation of local ground shaking intensity (based on known attenuation relation) and classification into one of several predefined intensity intervals ? Apply supposed relation between the shaking intensity interval and qualitatively defined damaging effects to express predicted effects This makes a mixed quantitative/qualitative procedure, difficult to analyze or optimize

Aug 1, 2013