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By G. R. Speich

The age-hardening of Fe-18 to 21 pct Ni marten-sites containing small amounts of titanium, aluminum, copper, or molybdenum has been studied by hardness measurements, transmission electron microscopy, extraction replicas, and X-ray and electron diffraction. Electyon-probe microanaly-sis of the extracted precipitates was also performed. The effects of temperature and composition on the aging kinetics have been studied in detail for Fe-20 pctNi-Ti martensites. All the martensites hardened on aging at 400" to 500 "C with a single aging peak. In the Fe-20 pct Ni-Ti martensites hardening was associated with the formation of a fine dispersion of NisTi. No precipitation was observed in an Fe-21 pct Ni-2.6 pct A1 alloy, although the hardness increased from 327 to 545 Dph during aging at 500°C. Copper was precgitated from an Fe-20 pct Ni-10.7pct Cu alloy, at least during the later stages of age-hardening. Hardening in an Fe-18 pctNi-5pct Mo alloy was associated with the precipitation of an intemzetallic compound tentatively identified as NisMo. The formation of austenite and the recovery of the defect structure of the martensite occur simultaneously with the normal precipitation processes &ring aging of these alloys. THE age-hardening of substitutional iron-base martensites is an important subject for study since age-hardening is one of the principal means of strengthening the substitutional iron-base martensites in precipitation-hardening stainless steels1 and maraging steels.a~4 In contrast to Fe-C martensites, these martensites are relatively soft and ductile in the as-quenched condition, due to the low solid-solution hardening effect of the substitutional elements as compared to carbon. Also, these martensites are hardened by aging at low temperatures in contrast to Fe-C martensites which generally soften on tempering. Titanium and aluminum, singly or in combination, as well as copper and molybdenum, have been the principal alloying additions to stainless steels to obtain an age-hardening reaction.' Ti-A1 or Co-Mo-Ti combinations have been used in the case of maraging steels.3"4 The present work has been confined to a study of the age-hardening characteristics of an Fe-18 to 21 pct Ni martensite to which small amounts of titanium, aluminum, copper, and molybdenum were added in order to study the effects of each alloying element separately. The age-hardening characteristics of these alloys were studied by hardness measurements, transmission electron microscopy, extraction replicas, and X-ray and electron diffraction. Electron-probe micro-analysis of the extracted precipitates was also performed. The types and dispersion of precipitates, the formation of austenite, and the recovery of the defect structure of the martensite all were studied. EXPERIMENTAL PROCEDURE Alloys. The compositions of the alloys studied are listed in Table I. The level of 18 to 21 pct Ni was chosen to assure complete transformation to martensite on quenching and is the same nickel level used in maraging steels. The concentrations of titanium, aluminum, copper, and molybdenum were chosen after a study of the and Fe-Ni-MO' ternary diagrams indicated how much of each alloying element could be dissolved in austenite. Alloys with 2 and 4 pct Cu were also studied, but these did not show precipitation hardening at the nickel levels studied and will not be discussed further. The alloys were prepared from electrolytic iron and high-purity* nickel, titanium, aluminum, copper, and molybdenum by vacuum melting of 20-lb heats. These were vacuum-cast into two 8-lb ingots. The ingots were hot-rolled at 1100°C to 1/2-in. plate and subsequently cut into 3/8-in. cubes. The cubes were sealed in evacuated quartz capsules and solution-treated for 16 hr at 1100°C, except for the Fe-20 pct Ni-10.7 pct Cu alloy and Fe-21 pct Ni-2.6 pct A1 alloys which were solution-treated for 16 hr at 1300" and at 1250"C, respectively. Metallographic examina-

Jan 1, 1963

In understanding the consequence of existing law, and the likely implications of its reform, it is necessary to comprehend the logic of the situation that the law provides individual decision makers and how that situation would be adjusted by reform. In particular, the way in which natural resources, including minerals, are used and managed is influenced by the definition and structure of property rights that the law provides. Property rights are enforceable claims to use or to benefit from resources. An example is a mining licence that allows its holder to extract minerals in a specified area. Property rights establish the structure of incentives, opportunities and constraints within which resource use decisions are made, ie the logic of the situation, and hence influence the use and management of resources. The extent and type of mining in New Zealand, for example, reflects the rights that miners have to extract minerals, and their rights to benefit from mining as against their duties to compensate landowners and pay royalties. This paper describes the characteristics of minerals that are relevant to the definition of property rights, analyses the implications of alternative property right arrangements and describes the existing situation.

Jan 1, 1988

By Aaron L. Sacks, David R. Good, Srinivas Yennamanda, Joseph K. Carey

Construction of Parcels 6 and 7, the second phase of The Wharf, began in 2019 and geotechnical construction was completed by December 2020. The overall project consisted of horizontal site, parks, and office buildings. The Wharf’s Phase 2 development includes approximately 1.2 million ft2 (110,000 m2) of above-grade construction including five multi-story, mixed-use buildings constructed over up to three levels of underground parking. The site is located between the WMATA Green Line Tunnels to the north and the Washington Channel to the south; it is bisected by a 108-in. (2740-mm) diameter DC Water outfall pipe. This arrangement, along with very difficult ground conditions, created challenges in the geotechnical design and construction. The support of excavation for this complex project required several different methodologies, including sheet piles, soldier piles, displacement piles, tiebacks, deep foundation anchors, jet grouting, and internal bracing with multi-tier rakers. Ground improvement was also required for support of spread footings in soft soils over the garage footprint. Underpinning of the active 108-in. (2740-mm) diameter DC Water outfall pipe running on a north/south alignment through the center of the site between the two garage structures was also performed. Since portions of the support of excavation are below the groundwater table, an extensive pre-excavation dewatering program was necessary and was separate from the foundation package. On the north side of the project, support of excavation (SOE) was required on a curved alignment, offset approximately 10 ft (3 m) from the outbound Green Line tunnel. Due to the proximity of the tunnel, a stiff, near-zero displacement wall was required. A portion of the buildings extend over the tunnels, imparting load to the tunnels to approximately restore original overburden loads excavated for the basement space. The building foundation is a 3 to 4-ft (0.9 to 1.2-m) thick mat slab anchored into the Potomac clay formation. Continuous movement monitoring of the tunnels was performed by an automated system. This paper describes the design and construction of the SOE and foundations for this high-profile project, which required collaboration between the Owner, Engineer, Construction Manager, and Specialty Geotechnical Contractor to solve many challenges.

Oct 1, 2022

Electrical trailing cable used to power coal mining machinery is frequently damaged in usage because of tensile strain or crushing effect of mining machines running over the cable. One of the repair problems is finding the exact location of a short or open in this cable so it may be spliced or otherwise repaired. The U.S. Bureau of Mines and FMC corporation signed Contract No. H0 122011 in August, 1971, to develop instrumentation for finding faults in coal mine trailing cable. This report describes performance of several existing instruments as trailing cable fault locators and also construction details and performance records of several cable fault location instruments that FMC designed, built and tested as part of this project.

Jan 1, 1973

By Roy L. Wilfong

The thermal decomposition of the ammonium sulfate, carbonate, nitrate, oxalate, and sulfate salts of praseodymium, neodymium, and samarium was investigated thermogravimetrically in the temperature range 25° to 1,500° C. Each salt was decomposed at a heating rate of 2.5° C, per minute. The pyrolytic sequences have been identified and the temperatures of formation of inter-mediates, the minimum oxide formation temperatures, and values for loss on ignition have been determined. The nonstoichiometric ranges between Pr6011 and Pr203 and the extent of these ranges have been determined for oxides derived from the carbonate, nitrate, and oxalate salts of praseodymium. The alum and sulfate salts of praseodymium produced the sesquioxide without forming the intermediate non-stoichiometric oxides. The temperature limits of formation and regions of stability for the alums and sulfates were better defined than were those for the carbonates, nitrates, and oxalates. The minimum oxide formation temperature increased in the order of samarium, neodymium, and praseodymium irrespective of the anion.

Jan 1, 1962

By W. A. Calhoun

A method for treating high-iron Arkansas bauxites for recovering both abrasive and metal-grade bauxite has been developed by the Bureau of Mines. Present practice usually produces a reject containing appreciable quantities of metal-grade bauxite; however, the processing renders the alumina in the reject unsuitable for the Bayer extraction treatment. Thus the Arkansas abrasive bauxite industry has, in the past, produced little or no metal-grade bauxite. The present investigation was made to determine the possibilities of batter utilization of those particular bauxites through recovery of the wasted metal-grade portion. The large expansion of aluminum-production facilities planned for 1951-53 makes recovery of metal-grade bauxite from presently treated abrasive and marginal abrasive ores en especially timely objective and a welcome addition to our aluminum potential. The quality of the Arkansas bauxites and the inherently associated titania content have made this material particularly attractive to the abrasives industry. however, the gradual depletion of natural abrasive-grade bauxite reserves in this area, the comparative scarcity of high-grade ore, and the difficulty of maintaining adequate reserves have necessitated blending different grades of bauxite calculated to meet specifications. Production of abrasive-grade bauxite from tile, high-iron reserves 13 becoming, increasingly necessary. In one commercial operation, producing abrasive-grade from ores averaging slightly less than 10 percent Fe2O3, approximately 2.7 tons of ore are required to produce 1 ton of abrasive-grade bauxite. The reserves of ore of this grade, however, have been considered inadequate for a long-range production, and ultimately ores averaging 12 to 15 percent Fe2O3 will have to be treated to moot the continued demands of the abrasive industry.

Jan 1, 1952

By C. Siyasiya

One of the problems that is occasionally encountered during the continuous casting of DIN 1.4003 stainless steel (hereafter referred to as 1.4003) is the side bulging effect, a problem that is generally prevalent in ferritic stainless steels. This occurs because the unconstrained narrow sides of the solidification shell are not able to withstand the ferrostatic pressure once the strand has emerged from the mould. Coupled with side bulging, there is strand width variation at high temperatures, i.e. when the steel is in the ferrite-austenite dual phase region. Both of these dimensional changes to the slab profile create some processing problems in subsequent hot rolling operations when unacceptable width variations are encountered. The strength of the solidification shell and its ability to withstand the ferrostatic pressure during continuous casting is dependent on its thickness and phase composition when exiting from the mould up to a few metres downstream. From the study of the high temperature metallurgical behaviour of this steel, it was observed that a thicker solidification shell when exiting from the mould and a higher austenite volume fraction in the steel would be favourable for the reduction of the side bulging effect during continuous casting. It was also found that as long as the d-ferrite to austenite phase ratio keeps fluctuating due to variations in chemical composition and process control in the dual phase region from cast to cast, the strand width variation problem would probably persist. The remedy to this effect lies in more strict chemical composition and process control during continuous casting of this steel. The hot ductility experiments revealed that 1.4003 exhibits good hot ductility in the strand straightening temperature range with a minimum of 75 per cent reduction in area and this was attributed to the high volume fraction of ferrite (0.2 to 0.4) in the steel. This would provide a remedy to side bulging by increasing the secondary cooling rate of the strand in order to form a thicker solidification shell without necessarily risking transverse cracking and other surface defects during unbending. Keywords: side wall bulging, resistance bending moment, applied bending moment, ferrostatic pressure.

Jan 1, 2005

02, NaCI03, H202, Na0CI and Ce+4 have been examined as oxidants in an alkaline carbonate system for uranium in in situ leaching. The South Texas and New Mexico ores contained up to 2.6 meqJg of reducing compounds which consume oxidants in the leading operation. Leaching rates did not increase linearly with the oxidation potential of the oxidants. A mild oxidant can be used to maximize uranium oxidation selectively and oxidant efficiency. 02 can oxidize most of the uranium mineral with an adequate rate and high oxidant efficiency.

Jan 1, 1990

By John J. Baz-Dresch, Kenneth L. Bickel, Winthrop F. Watts

Catalyzed diesel particulate filters (CDPF's) reduce the concentration of diesel particulate matter (DPM) and may reduce the emissions of carbon monoxide (CO) and hydrocarbons (HC) in diesel exhaust. Asamera Minerals' Cannon Mine first installed CDPF's in 1987, and currently has 12 diesel- powered vehicles equipped with CDPF's. The Cannon Mine and the U.S. Bureau of Mines collaborated to evaluate the durability and performance of a CDPF. One of the CDPF's used at the mine was periodically evaluated in the USBM's diesel emissions laboratory after 839, 1,584, and 2,881 h of in-mine service. The objectives of this report are to present results from the USBM's evaluation of this CDPF, to describe the Cannon Mine's experience and cost analysis of using CDPF's, and to make recommendations for the future use of CDPF's. CDPF's improve air quality at the Cannon Mine, but they frequently become plugged and are subject to excessive mechanical shocks and stress, shortening their useful life. Mine records indicate that CDPF's account for 0.8 to 4.9 pct of the vehicles' operating cost at the mine. CDPF life to date has ranged from 1,671 h to more than 5,992 h. Laboratory tests of the CDPF determined that DPM removal efficiency decreased and regeneration temperature increased over time.

Jan 1, 1994

By R G. Jeffrey

The Northparkes, Endeavour 26 orebody is a porphyry copperûgold deposit and comprises a moderately to well jointed rock mass characterised by gypsum veining, the intensity of which decreases with depth. The top 480 metres of the orebody is currently being mined by block caving, the undercut dimensions measuring 196 metres in length by 180 metres in width. Continuous caving was never achieved after the completion of the undercut thus cave inducement techniques were sought to maintain caving so as to safely sustain production. The use of hydraulic fracturing as a cave inducement tool was successfully trialled in December 1997 using existing exploration boreholes located midway up the current lift. Subsequent fracturing campaigns have enjoyed various degrees of success and have yielded in excess of seven million tonnes of ore at a significantly lower cost than conventional cave inducement techniques. Monitoring of both the hydraulic fracture system and the rock mass response has provided considerable insight into the geometry, growth and influence of hydraulic fracture networks above the Northparkes block cave, and has initiated additional research into the use of hydraulic fracturing in other mining methods.

Jan 1, 2000

By P. S. Capper

"Generally speaking, the most intensive efforts at dust control in the mining industry have, in the past, been concerned with underground operations and where uranium ore or high silica material is processed. In the past several years, Stoop Rock has made Intensive efforts to reduce dust levels in it's Iron ore pelletizing complex. There have been no great engineering break-throughs with regard to dust control in such plants, and certainly no new engineering techniques have had to be applied at Steep Rock. This paper deals with how significant improvements in dust levels have been achieved through minor modification to dust collectors and ventilation units, improvements in operating practices, and education of supervisors and hourly personnel.PROCESS DESCRIPTIONSteep Rock Iron Mines is located 120 miles west of Thunder Bay near Atikokan. (fig. 1) Run-of-mine ore is pelletized along with some -1"" concentrate that has been processed in the concentrator (a summer operation only), which utilizes gravity separation to upgrade a mechanical mixture of ore and waste."

Jan 1, 1976

By E. Niehuis, J. Y. Kim, H. G. Cramer, S. L. Chryssoulis, K. G. Stowe, C. Bendel

TOF-SIMS was used to detect, identify from parent molecular ions and determine the relative concentrations of collectors sorbed on the surface of mineral particles in concentrate and tailings samples from three Canadian concentrators. In the Kidd Creek Zn circuit, sphalerite lost to tailings carried on average a quarter of the amount of isobutyl xanthate present on that recovered to Zn concentrate; amyl xanthate, which is not reported as added to the circuit, was also detected on floated sphalerite and pyrite. At Brunswick, sphalerite particles lost to the scavenger tailings had ten times less amyl xanthate and isobutyl xanthate than those recovered to the Zn final concentrate, while both xanthates were detected on sphalerite floated to the Cu-Pb cleaner circuit. At Matagami, significantly more isopropyl xanthate and isopropyl dithiophosphate were detected on sphalerite recovered to the final Zn concentrate than on that lost to the Zn rougher tailings

Dec 1, 1995

By R. Barany

This report contains the results of experimental work conducted by the Bureau of Mines to obtain the heats of formation at 298.15° K. of analcite, dehydrated analcite, lawsonite, anorthite, hexagonal anorthite, and leonhardite. Thermodynamic data for these minerals have applications in ceramics, extractive metallurgy, and particularly in geochemistry. Except for data on anorthite, no previous similar data existed. The present results will be a substantial aid in deriving the temperature-pressure-equilibrium relationships among these minerals. The heats of formation were determined by solution calorimetry, with hydrofluoric acid as the reaction medium. The results were expressed both in terms of the constituent oxides and in terms of the constituent elements. The heat of formation data were combined with related entropy values to obtain the free energies of formation at 298.15° K.

Jan 1, 1962

Jan 1, 1999

By Sidney Speil

In the study of clays and related minerals, the analytical techniques commonly employed in mineral analysis are not always applicable. The X-ray examination of a clay sample usually will show the major constituents, but often minor· clay impurities will not be detected because of line broadening and the similarity of the main lines of clay· mineral diffraction patterns, The petrographic analysis of clay minerals with clay particles as small as a few microns is usually difficult. With still smaller particles, a gross effect often is noted in which a mixture of several constituents gives the appearance of a single constituent with the mean optical-characteristics of the mixture. 3/ The electron microscope has recently been used to study clay particle shapes of various aluminosilicates. 4/ However, this method has not yet been sufficiently explored. The Chemical method in which a mineralogical analysis is calculated from the oxide chemical analysis has been discussed by Wilson 5/ and others, and many of the shortcomings have been pointed out. It should also be recognized that the variable alkali and alkaline earth content of bentonites makes it inaccurate to assign these basic elements arbitrarily to feldspar or mica in any clay that contains appreciable bentonite.

Jul 1, 1944

By David R. Jessey

Water pollution problems associated with surface metal/nonmetal mines throughout the United States were assessed. Three major problems were identified: acid mine drainage (AMD), toxic concentrations of heavy metals and excessive sedimentation. Several factors affect the type and amount of pollutants generated at a mine site. Among these are hydrologic regime, geology, mineralogy, topography, climate, size of the mineralized area and mining method. Nine surface mines situated in distinctly different settings were visited and their pollution problems studied. These mines were located in Morenci, Arizona; Hayden, Arizona; Sauharita, Arizona; Cobalt, Idaho; Spruce Pine, North Carolina; Iron Mountain, California; Butte, Montana; Fernwood, Idaho; and DeLamar, Idaho-Oregon. A detailed evaluation of the pollution problems at the Morenci mine indicated that a diversion system and treatment pint would be the most effective means of abatement for the existing water quality problems. Based on the study of the Morenci mine and three other porphyry copper mines with differing problems a water management plan was conceived for a new source copper mine. A companion Appendix Volume containing detailed reports on the mine site visits is on file at the US Bureau of Mines Spokane Research Center.

Jan 1, 1981

By William R. Wessels

This report describes a field survey and laboratory investigation into the causes of failure of resiliently clad screen decks applied to coal preparation plants. Blinding of screen deck perforations and delamination of the resilient cladding are studied and mechanisms responsible for these failure modes are hypothesized. A laboratory test program to simulate the mechanisms was begun and abandoned when it became apparent that meaningful test results would require a substantially redirected effort. No meaningful test data was obtained from the laboratory simulation.

Jan 1, 1982

By M. John Brodie

This report reviews the regulatory environment as it pertains to waste rock management and disposal from mining operations, excluding coal and placer gold operations, in the \irate of Alaska. It is based on the EPA's staff position on an effective program to regulate mining waste as presented in the May, 1990 Strawman II document. The unique conditions which occur in pans of the state, including a fragile environment, high seismicity and permafrost, are identified. The special waste management practices which are necessitated by these conditions are delineated. The report provides a detailed outline of the current technologies that are suitable for designing, constructing, operating and closing a waste rock facility to meet environmental protection objectives. Cost implications to the mining industry of potential regulatory actions, such as the degree of groundwater protection, are examined.

Jan 1, 1992

By N. Iverson, E. Haft, V. T. McLemore, M. Woodard, E. Owen

Present and emerging technologies are renewing interest in domestic rare earth elements (REE) production. REE deposits throughout the North American Cordilleran alkaline-igneous belt are being re-examined for their economic potential. In New Mexico, the mineral deposits found in this belt are associated with Eocene–Oligocene alkaline to calc-alkaline igneous rocks. Four areas in New Mexico have been examined for their REE potential. The chondrite-normalized REE patterns are similar for all four districts, even though different REE minerals are found. Crandallite, xenotime, bastnäsite and brookite are found in fluorite veins and carbonatites at Laughlin Peak. Bastnäsite was extracted during fluorite processing from 1954-1980 from the Gallinas Mountains, where samples as high as 8% total REE are found in fluorite veins. Other REE minerals include agardite, parasite, xenotime, and monazite. Allanite, thorite and as much as 8133 ppm total REE are found in fluorite veins in the Capitan Mountains. In the Cornudas Mountains, exploration along the outer edge of the Wind Mountain nepheline syenite laccolith and within phonolite dikes, plugs, skarns and carbonate-replacement deposits in Chess Draw contain as much as 3110 ppm TREE, hosted in eudialyte, monazite, bastnäsite, and calciocatapleiite.

Feb 1, 2023

By C. J. Newman, R. J. St. Eloi, G. Macfarlane

"The Kidd Creek copper smelter has been expanded from its original design of59000 tonnes of copper per year to over 120 000 tonnes per year. Modifications to the process gas handling system and acid plant have been made to accommodate this higher production rate and, generally, to optimize the operation.The gas handling system associated with the continuous smelting process is discussed in terms of boiler accretions and modifications to minimize their impact on operations; design changes to effect reductions in high pressure drop duct configurations; material changes to overcome corrosion and plant additions to improve gas cleaning capability. The acid plant is reviewed with references to changes made to accommodate the increased S02 gas strength resulting from the higher smelting rates. IntroductionThe Kidd Creek Division of Falconbridge Limited is a base-metal mining and metallurgical complex located in Timmins, Ontario. The discovery of the original copper-zinc-silver orebody was announced in April 1964. Mining operations began in 1966 with a 9000 tonnes per day (t/d) concentrator corning on stream in November of that year. In April 1972, a 108 000 tonnes per year zinc plant was conunissioned. Over the years the facilities have been expanded, such that the concentrator now has the capacity to process 13 000 t/d of ore. To expand zinc production, the world's second installation of the Commco/Sherritt pressure leaching facility was completed in 1983 to bring total zinc production capacity to 136 000 tonnes per year. In 1973, serious planning for a smelter operation began. In early 1975, after studying both continuous smelting and flash smelting processes, a decision was made to proceed with the technology offered by Mitsubishi Metal Corporation of Japan. The Mitsubishi Continuous Smelting Process was to be used for the smelter and the Onahama No. 3 tankhouse technology for the copper refinery."

Jan 1, 1994