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By K. L. Cashdollar, C. K. Man, J. R. Gibbins

Oxyfuel combustion is currently one of the principal technological options being considered for capturing carbon dioxide from pulverised coal power plants. In oxyfuel combustion, coal is burnt in a mixture of recycled flue gases and added oxygen instead of in air. In principle this yields a flue gas containing only carbon dioxide, water vapour and small amounts other impurities. Oxyfuel combustion is superficially similar to combustion in air, but there are inevitable differences. This paper describes ignition tests on pulverised coal suspensions using a suite of coals of different rank and from different countries of origin and over a range of oxygen and coal concentrations of interest for oxyfuel combustion. The ignition tests were carried out using the National Institute for Occupational Safety and Health (NIOSH) 20-litre explosion chamber. The purpose was to determine how easily the various coals ignite and burn in mixtures of O2 and CO2 compared to their combustion in air. The residual char volatile and ash contents for the ignition residues were measured using a thermogravimetric analyser (TGA), allowing Q factors (i.e., enhancement in apparent volatile yield due to higher heating rates and/or heterogeneous reactions) to be determined and compared. An ignition index has been derived from the explosion and char data. This index has been used to rank low volatile coals for ignition propensity in air. The results show that to obtain ignition and combustion comparable to that in air, the oxyfuel O2-CO2 gas mixture must contain over 30% O2. Keywords: CO2 capture, combustion, pyrolysis, oxyfuel.

By K Ehrig

You are a geologist, geometallurgist, or metallurgist/process engineer and are fortunate enough to work for an organisation who asks you to design/execute a geometallurgy program. What seems like a simple request is actually not a trivial exercise. æRecipeÆ style manuals are not readily available. However, many æexpertsÆ are lurking around willing to deliver solutions which will solve all of your problems. Even though similar ore deposit styles (e.g. porphyry Cu, IOCG, Ni-laterites, calcrete hosted U, etc.) have many similar characteristics, each ore deposit is unique. Hence your geometallurgy program needs to be æfit-for-purposeÆ. This paper offers some insights gained via designing and executing geometallurgy programs from exploration through to production, and working at a mine where you are held accountable for your metallurgical performance predictors.CITATION:Ehrig, K, 2013. Geometallurgy - What do you really need to know from exploration through to production?, in Proceedings MetPlant 2013 , pp 28-33 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Jul 15, 2013

By Hartley JS, Wills KJA

The Thalanga massive sulphide deposit is hosted by Upper Cambrian rhyolites and volcaniclastics of the Mt. Windsor Volcanics near their contact with overlying dacites, rhyolites and sediments of the Trooper Creek Formation. The ores and host rocks have been subjected to a single strong deformation and to lower to middle greenschist facies metamorphism. A main lens with surface gossan dimensions of 55U m x 6 m dips steeply, plunges shallowly to the west and is offset by a series of normal faults. It is flanked by smaller lenses to the east where the mineralized horizon is stopea out by granite. The area to the east and south of the gossan is masked by Tertiary cover. A complex exhalite package is represented by banded sphalerite-pyrite- galena-chalcopyrite, massive pyrite and chalcopyrite and assemblages dominated by dolomite, chlorite-actinolite, tremolite, talc, barite and rare gypsum. Accessory tetrahedrite, arsenopyrite, bismuthinite, magnetite and native gold are associated locally. Pods of quartz-magnetite formed distally. The ores are underlain by strongly to moderately pyrite-silica-sericite altered rhyolites with the strongest alteration closest to an interred synvolcanic fault. This alteration is characterised by an enrichment in MgO, Na2O, FeS2 and base metals with a depletion in CaO and Na2O. There is a general enrichment in Pb and Zn towards the hanging wall with some enrichment of Cu near the base of the main lens due to replacement by ore tiuias near vent discharge sites. Zonation of Cu to 2n-Pb in also evident over narrow intervals

Jan 1, 1987

By D Pienaar, B McFadzean, C T. O’Connor

Collector and frother molecules in sulfide mineral flotation are thought to have separate roles in the flotation process, where the collector selectively hydrophobizes the mineral surface and the frother adsorbs onto the bubble surface, inhibiting bubble coalescence. Molecular interactions have been observed between these molecules which allow them to co-adsorb at each of the respective interfaces, improving pulp phase recovery. This study investigated the molecular interactions between sodium diethyl dithiophosphate (SDEDTP) and hexanol, and the mechanism by which these interactions improve the recovery of galena. In this study each of the respective interfaces were investigated for the adsorption of SDEDTP. The adsorption of SDEDTP on galena was measured by UV-Vis spectrophotometry and isothermal titration calorimetry. At the air-water interface foam stability and pulp bubble coalescence was used to quantitatively discern if there are interactions between SDEDTP and hexanol. Microflotation and induction time experiments were performed to determine the effect of SDEDTP, hexanol and their mixtures on mineral recovery and bubble-particle attachment. The results of all these tests were collated to determine if SDEDTP-hexanol mixtures synergistically improve sulfide mineral recovery. It was found that SDEDTP reduced bubble coalescence in the pulp demonstrating activity at the airwater interface. Together SDEDTP and hexanol synergistically enhanced foam stability. This indicated that there are attractive molecular interactions between these reagents. Even though DTP did not adsorb onto galena, DTP-frother mixtures synergistically improved the recovery and attachment probability of this mineral. Adsorption studies with aeration showed that DTP in the presence of a frother transfers from the air-water interface to the galena mineral-water interface during bubble-particle collision. It was proposed that the transfer of hexanol through the thin film enhanced the kinetics of film thinning between the bubble and the particle by destabilising the thin film thus improving pulp phase mineral recovery.

Aug 24, 2022

By S. O. Bada

Coal samples taken from the No. 2 Seam and No. 4 Seam in a South African colliery were tested in a rotary triboelectrostatic separator. The two-stage triboelectrostatic separation results using the -177 µm size fraction reduced No. 2 Seam coal containing about 30.4 per cent ash to a clean product of 8.9 per cent and 13.1 per cent ash with combustible recoveries of 9.6 per cent and 30.7 per cent respectively. The same separation approach on No. 4 seam feed coal, which contained 36 per cent ash, produced a clean coal product with 10.8 per cent ash at a combustible recovery of 6.0 per cent. Petrographic tests show a significant improvement in the vitrinite content and a reduction in visible minerals encountered when using the triboelectrostatic separator, with about 53 per cent vitrinite reporting to the clean fraction for No. 2 Seam compared to the feed content of 21 per cent, and a 54 per cent vitrinite in the clean No. 4 Seam from a feed content of 21 per cent. Significant sulphur reductions were also observed after separation in both coal samples, with a better separation in the second-stage coal products.

Jan 1, 2012

By Yuanwci Shi

This paper discusses the results of research on the interaction between roof strata and shield supports including the active and passive supporting functions of the shield supports which prevents roof strata separation; pressure distribution on the canopy and under the base plate as measured in the laboratory and underground; comparison between various shield structures regarding their effectiveness on roof and floor control; and determination of optimum support capacity under given geological and mining conditions including hard-tocave roof

Jan 1, 1997

By J. E. Dutrizac

The dissolution of low-iron sphalerite, (Zn,Fe)S containing 0.08% Fe, in ferric sulphate-sulphuric acid media was investigated using closely sized fractions of crushed sphalerite crystals and sintered disks made from the crushed crystals. Linear kinetics are observed, and the predominant reaction products are ZnSO4, FeSO4 and elemental sulphur. The leaching rate increases systematically with increasing temperature, and the calculated apparent activation energy is 56 kJ/mol for the sized sphalerite and 54 kJ/mol for the sintered disks. The relatively high apparent activation energy suggests that the rate is chemically controlled, a conclusion supported by the insensitivity of the rate to the disk rotation speed. The rate increases as the 0.22 power of the Fe(SO4)1.5 concentration, and as the 0.22 power of the H2SO4 concentration. However, in the absence of ferric ions, the rate increases more significantly with increasing H2SO4 concentrations, and relatively rapid rates are observed in solutions containing >0.5 M H2SO4. In 0.1 M Fe(SO4)1.5-0.3 M H2SO4 media, the measured rate decreases with increasing sulphate concentrations, added as Li2SO4. The rate of dissolution of low-iron sphalerite is promoted by dissolved copper concentrations as high as 800 mg/L. In contrast, dissolved silver, even in the 0-2 mg/L concentration range, significantly retards the dissolution of the low-iron sphalerite.

Jan 1, 2008

The banded iron formations "jasper bars," jaspilites, banded hematite quartzites or banded ironstones, etc., as they have. variously been termed in Western Australia, constitute one of the most striking features of the Pre-Cambrian in this State. They occur in at least two distinct divisions of the Pre-Cambrian, viz., in horizons interbedded with quartzites, shales and thin bedded dolomite in the N~llagine (Proterozoic) Series; and amongst the Older Pre-Cambrian rocks, associated with the metamorphosed sediments of the Jimperding-Chittering Series, the Yilgarn Whitestone Series and the Mosquito Creek Series, and interbedded with metamorphosed basic lavas, tuffs and sediments of the Older prenstone or Kalgoorlie Series.In the Hamersley Ranges in the north-west of Western Australia banded ferroginous cherts are well developed amongst the horizontal sediments of Nullagine Age. These iron formations have recently sprung into prominence as they have been found to form the host rocks for important deposits of· blue asbestos. They are closely comparable with the unique crocidolite-bearing banded ironstones of the Cape Province, South Africa, and have been described elsewhere in some detail by the writer. (1) t .The banded iron formations with which it is intended to deal principally in the following pages, form most abundantly in the Central and Eastern Goldfields of Western Australia where they form portions of the Older Greenstone or Kalgoorlie Series of auriferous rocks. In these regions their chemical inertness and physical hardness provide considerable resistance to the agents of erosion and consequently they frequently stand out in strong topographic relief in otherwise monotonously flat or gently rolling country. These banded-iron formations have proved of considerable direct economic importance in the goldfields and in other portions of the State because of thei!! associations with 'gold, iron -and to' a lesser extent, manganese; whilst indirectly because of their peculiar nature, form and topographic prominence, etc, they have been of tremendous assistance to the field geologist both in the practical application of methods of geological mapping and in the' elucidation of geological structures. Finally, they have recently acquired a new importance in the specialised search for ore-bearing lodes or for structural information over areas of soil-covered country, as their form and composition make them ideal subjects for the use of either electrical or m!1-gnetic methods of geophysical prospecting.

Jan 1, 1941

By Rao P. K, Sahoo P. K

The main constituents of ferromanganese slags are silicates of Mn, Ca and AI. Factors affecting the recovery of manganese from a low manganese content ferromanganese slag (about 16 per cent MnO) during acid leaching were studied. These included time, temperature, agitation, sulphuric acid addition, solid:liquid ratio and particle size. Agitation rates greater than 300 rev/min. leaching periods greater than 30 min and temperatures above ambient were found to have no effect on Mn recovery. Dissolution of Mn was found to be highly dependent on the amount of acid added.About 90 per cent of the Mn was recovered when 5·5 times the stoichiometric amount of acid was used. About 28 per cent of the Mn was recovered when the stoichiometric quantity of acid (with respect to Mn alone) was used. However, the recovery increased to about 75 per cent when the total stoichiometric requirement of acid with respect to Ca, Al, Mg and Fe as well as Mn was used for leaching. The extent of Mn dissolution also depended on the particle size of the slag. The percentage of Mn recovery (using 5·5 times the stoichiometric amount of acid) increased from about 60 per cent to about 92 per cent when particle size decreased from -36 +52 to -150 +200 mesh (B.S.S.). When the results of this study were compared with those in a previous study involv,ing the leaching of a high manganese content slag (containing about 40 per cent MnO) results were similar except that there was a gr-eater consumption of acid in the present case (i.e. low manganese content slag).

Jan 1, 1979

By Holmes R. J, Miles J. G

An on-stream shale detector has been developed that is suitable for use on conveyor belts carrying iron ore of up to 200 mm particle size. The shale is distinguished from high-grade iron ore by means of the substantially greater total natural gamma-ray activity (400-3000 keV) of the shale, which is due to the presence of uranium (214Bi), thorium (208TI) and potassium (40K). Other gangue materials, sueh as highly siliceous cherts and jaspilites, escape detection because of their low activity. A dynamic trial of the shale detector at Mt Whaleback, using a large-volume (100 × 100 400 mm long) "Polyscin" Nal(TI) gamma-ray detector, demonstrated that as little as 20 tonne of ore on a conveyor belt (equivalent to partial truckloads of ore) can readily be monitored for shale content.

Jan 1, 1981

By Roy C. Fedotoff, Jon Hurt, Gregg Sherry, Gilbert Tang

The 1,380 m (4,200 ft) long New Crystal Springs Bypass (Polhemus)Tunnel (NCSBT) will replace the existing Crystal Springs Bypass Pipeline. This tunnel project is part of the SFPUC’s $4.3 billion capital improvement program to repair and seismically upgrade their aging pipelines, tunnels, reservoirs and dams that provide drinking water to more than 2.4 million customers in the San Francisco Bay Area. This paper describes the development of the tunnel alignment and design, and the complex ground conditions of the Franciscan Mélange. Of particular interest is the challenge of tunneling with a possible downhill grade of 3%, a rigorous environmental process and incorporating the lessons learned from 1960s construction of the adjoining Crystal Springs Bypass Tunnel.

Jan 1, 2007

By Tim O’Neil

Nearly 4,800 mining professionals and exhibitors occupying 580 booths attended the 2000 SME Annual Meeting and Exhibit, Feb. 28-March 1, in Salt Lake City, UT. The technical program included80 sessions and four specialty symposia: bulk material handling, control 2000, minor elements 2000 and plant operaters. Meeting highlights included the keynote session. Executive shared their perspectives on pivotal issues and approaches to address the challenges of the new millennium. SME has begun planning for its 2001 Annual Meeting, Feb. 26-28, in Denver, CO. The meeting carries the theme “2001 — A Mining Odyssey.” A call for papers has been issued and exhibit space is 80% reserved. For information, visit SME’s website, www.sme-net.org. Or write Box 625002, Littleton, CO 80162-5002,ph 800 763 3132 or 303 973 9550, fax 303 979 3461, or email meetings@smenet.org.

Jan 1, 2000

The paper is a general review of practice in design of sub-level open stopes in Northern Rhodesian copper mines and gives examples of some interesting developments during the last five or six years. It discusses the effect of hangingwall subsidence and the methods used to combat rock pressure on working areas.INTRODUCTIONAll producing mines on the Northern Rhodesian Copperbelt have large ore reserves and are designed for high rates of production. The three mines (Mufulira, Rhokana Corporation, and Roan Antelope) where sub-level open stoping is used, hoist from 250,000 to over 400,000 short tons of ore a month so that any stoping method used must be adaptable to concentrated' mining. Individqal stopes produce from 5,000 to over 25,000 short tons of ore a month.Structure af the ore bearing sediments is simple; faulting in ore is almost entirely absent and copper mineralisation is found in the same beds over great distances...

Jan 1, 1954

By C. A. Young

Cyanide is a toxic species that is found predominantly in industrial effluents generated by metallurgical operations. Cyanide's strong affinity for metals makes it favorable as an agent for metal finishing and treatment and as a lixivant for metal leaching, particularly gold. These technologies are environmentally sound but require safeguards to prevent accidental spills. Various methods of cyanide remediation by separation and oxidation, including photolytic advanced-oxidation processes, are therefore reviewed. Reaction mechanisms are presented throughout the paper. The methods are compared in regards to their effectiveness in treating various cyanide species: free cyanide, thiocyanate, weak-acid dissociables, and strong-acid dissociables.

Jan 1, 1996

By Chandramohan P. V., Ravi Kishore

"An underground reservoir was to be constructed at Doha in Qatar. Simsima lime stone is present at the bottom. When the reservoir is empty, there will be uplift at the bottom but this will change to downward load when it is full. The rock at the bottom had high bearing capacity to resist downward load. But uplift had to be resisted by piles or anchors. The reservoir has a size of 120mx80m. Shrinkage and creep of concrete coupled with thermal contraction imposed a horizontal movement of 26mm on the extreme piles. So, piles have to accommodate this as well. This unique situation needed a unique solution. The solution was to provide piles with flexible high tensile strands to take tension. An annular space near the head of the pile would facilitate horizontal movement as well. Compression load was directly passed on to the raft bearing on rock.INTRODUCTIONAn underground reservoir for storage of drinking water was to be constructed at Doha, Qatar. The reservoir was proposed to have a plan size of 120m x 80m. Clear height inside the reservoir was proposed as 17.2m, from the bottom of roof to the top of bottom raft. Overall height of the reservoir at the outlet from the top of the roof to the bottom of raft was to be 21.2m. For the sake of inspection and in order to prevent pollution from the surroundings a gallery was planned around the reservoir. This could accommodate pipelines as well. This gallery was 3.0m wide on three sides and 8.4m wide on the outlet side.The gallery had removable gratings as cover in order to facilitate maintenance. Capacity of the reservoirwas proposed to be 40million gallons. The reservoir is divided into four compartments with baffle walls in each one for water circulation. Roof of the reservoir is kept at 300mm above ground level. There are two levels of car park on top of the reservoir. Top of the reservoir roof is at +14.35. Bottom varies from - 6.68 to -7.08. Lowest water table is at +6.00. Concrete structure of the reservoir was designed by a local consultant. The Navayuga Engineering Company was entrusted with the construction. Please see Figs 1 and 2."

Jan 1, 2017

By Persio P. Rosario

Crushing has proven to be of fundamental importance in mine mill integration at Highland Valley Copper (HVC). Highland Valley Copper has achieved large throughput and good quality control through the gyratory crushers by proper blast design and better gap control. The next step, in optimizing the mine mill relationship, is evaluating the crusher liner wear and its shape influence on performance and product size reduction. To do this a laser measurement device has been developed and data is being recorded on the concave and mantle liner wear. This paper will outline the work to date and indicate specific objectives of the work.

May 1, 2002

By Francis Kendorski

The Skyline #3 Mine of Canyon Fuel Company in Utah was planning longwall mine development adjacent to and downdip of older mine workings known to be flooded. Barrier pillar geometries and widths were proposed by mining company personnel. Hydraulic conductivity testing suggested that the general characteristics of the local coal seam, dikes, and faults are only weakly conductive and that leakage through the barriers, if any, would be minor. The mechanical performance of the proposed barrier pillar design was evaluated according to (1) published empirical design methods and (2) numerical stress modeling. Comparison of the proposed design, with the range of barrier widths derived from the empirical methods, served as a first-order check on the adequacy of the proposed design. Numerical modeling was used to evaluate conditions site-specific to the Skyline #3 Mine and barrier geometry. Models were developed to quantify the relationship between barrier width and the abutment stresses onto the future workings. The models were also used to estimate the stress distribution within the barrier pillars. The hydraulic performance of the proposed barrier pillar design was evaluated according to (1) published empirical design methods for hydraulic impoundments, (2) empirical method estimates of seepage through coal barrier pillars, (3) numerical hydrogeologic flow modeling, and (4) numerical strain modeling. Using the techniques described above, and based on relevant industry experience, underground observations, knowledge of local geologic conditions, hydrogeologic measurements, and analytical results, the level of geomechanical risk associated with the barrier design as proposed was considered low and the level of hydraulic risk was considered moderate. The largest uncertainty that remained was the possibility that unfavorable geologic structures, such as faults and dikes, would act as conduits for leakage of impounded water into the new workings. Although the study indicated only minor steady-state leakage would occur through a small number of known structures, the presence and full leakage potential of threatening structures in the barrier could not be reliably known until the barrier was mined. One longwall panel has been completed adjacent to the barrier with no evidence of water flow even in fractured zones. Thus, as predicted by the modeling and analysis, it appears that abutment stresses imparted on the barrier during mining did not substantially alter the natural hydrogeologic characteristics, or leakage potential, of the barrier. The longwall coal mine water-barrier pillar design and performance are considered a success.

Jan 1, 2007

By Berny Rivera

The paper point out the Galvanox process developed at the University of British to leach concentrates containing copper sulfide mixtures, mainly chalcopyrite. This patented process is based primarily on the galvanic interaction between chalcopyrite and pyrite, which allows chalcopyrite to be leached preferentially over pyrite. Under the correct process conditions, near-complete extraction of copper can be reached typically within twelve hours. This study will also show that this process is suitable to treat low grade copper concentrates (bulk concentrates) taking advantage of the selectively of chalcopyrite over pyrite, and the use of pyrite as a catalyst.

Sep 9, 2007

By R. Webster

"Daniel Krige’s influence on soil science, and on soil survey in particular, has been profound. From the 1920s onwards soil surveyors made their maps by classifying the soils and drawing boundaries between the classes they recognized. By the 1960s many influential pedologists were convinced that if one knew to which class of soil a site belonged then one would be able to predict the soil’s properties there. At the same time, engineers began to realize that prediction from such maps was essentially a statistical matter and to apply classical sampling theory. Such methods, though sound, proved inefficient because they failed to take account of the spatial dependence within the classes.Matters changed dramatically in the 1970s when soil scientists learned of the work of Daniel Krige and Georges Matheron’s theory of regionalized variables. Statistical pedologists (pedometricians) first linked R.A. Fisher’s analysis of variance to regionalized variables via spatial hierarchical designs to estimate spatial components of variance. They then applied the mainstream geostatistical methods of spatial analysis and kriging to map plant nutrients, trace elements, pollutants, salt, and agricultural pests in soil, which has led to advances in modern precision agriculture. They were among the first Earth scientists to use nonlinear statistical estimation for modelling variograms and to make the programmed algorithms publicly available. More recently, pedometricians have turned to likelihood methods, specifically residual maximum likelihood (REML), to combine fixed effects, such as trend and external variables, with spatially correlated variables in linear mixed models for spatial prediction. They have also explored non stationary variances with wavelets and by spectral tempering, although it is not clear how the results should be used for prediction. This paper illustrates the most significant advances, with results from research projects."

Jan 1, 2015

The Bureau of Mines annually publishes statistical data reflecting technological trends in the minerals industry (metals and nonmetals except fuels). This report outlines recent developments and trends and the technology outlook for mining practices and metallurgical processing based on a review of the minerals industry during the past 2 years. A historical statistical series which indicates trends in the minerals industry has been extended with 1970 data. In addition, data are given from a 5-year Bureau of Mines cyclic canvass of froth flotation plants. Data for 1970 are compared with those of 1960 and 1965.

Jan 1, 1972