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By C M. Wawryk, S L. Garwin, J D. Foden

"An EXTENDED ABSTRACT is available for download. A full-length paper was not prepared for this presentation. The Batu Hijau porphyry Cu-Au deposit in south-western Sumbawa, Indonesia is an ideal natural laboratory to study the fractionation of iron isotopes in magmatic rocks that range in composition from basaltic andesite to tonalite. Intrusive rocks are associated with a porphyry system that contains well-preserved early hypogene copper mineralisation. We analysed pre-, syn- and post-mineralisation igneous intrusive rocks. We also separated magnetite, chalcopyrite and bornite from hypogene porphyry-style quartz veins, and measured the Fe-isotope ratios of samples by solution multi-collector ICP-MS. Iron isotopic composition of samples from the magmatic suite show an increasing d57Fe with increasing SiO2, supporting geochemical and textural evidence that the Batu Hijau Tonalites underwent closed system fractionation. Equilibrium and co-existing mineral textures allow the calculation of the following preliminary empirical mineral-mineral fractionation factors at 500°C for certain mineral pairs.Iron isotopes have the potential to provide geothermometric data to complement fluid inclusion data, especially where heating stages have operational limitations and where fluid boiling results in a wide variety of inclusion types that may make analysis difficult.CITATION:Wawryk, C M, Foden, J D and Garwin, S L, 2015. Iron isotope fractionation in magmatic-hydrothermal minerals – a porphyry copper case study from the Batu Hijau deposit, Sumbawa, Indonesia, in Proceedings PACRIM 2015 Congress, pp 389–396 (The Australasian Institute of Mining and Metallurgy: Melbourne)."

Mar 18, 2015

By R. P. Stahura

Conveyors are the lifeline of mining and processing operations. They continuously supply materials to and carry finished products and waste away from operations. When conveyors are running at less than maximum efficiency, the operation's productivity is in trouble. Inefficient conveyors suffer carryback, leading to the buildup of materials on idlers and other expensive components. They spill and leak material at loading zones and conveyor transfer points. This causes accumulations that can damage the belt, wear moving components and increase both clean-up labor and maintenance expenses. They wander or mistrack, spilling material and endangering personnel and conveyor components. And through these inefficiencies, they multiply the operation's hidden costs. These added expenses occur in lost production, increased downtime for service and maintenance and replacement costs for prematurely worn equip¬ment. In addition, the attitude that inefficiency is "good enough" is recognized elsewhere in the organization. As a result, other departments relax or operate at less than peak performance. Quality goes down along with employee morale. Costs of inefficient conveyors A key to efficiency is handling a product as few times as is necessary. That means conveyors should be loaded, track true to the unloading point and then be unloaded, all without material escape or waste motion. An inefficient conveyor is often signaled by accumulations of DURT - material that has escaped from the system and is now at large in the plant. This DURT adds costs to an operation that are uncounted and, perhaps, uncountable.

Jan 1, 1992

By Muir DM, Ritchie IM, Gibbons SL

Fundamental studies on the transformations of iron oxides have been carried out and related to the solution conditions in the Becher Process. The results show that a number of iron oxide interconversion reactions occur in the aeration reactor with the products depending on the pH, temperature and oxidation potential of the aeration liquor. It is concluded that the lack of process control in the aeration reactor of the Becher Process significantly hinders the ability to predict and produce high quality single phase iron oxides of a consistent colour.

Jan 1, 1989

By William D. Hissem

While much technology has been developed and brought to bear in the area of blasting applications, the foundation work required for success in the muck pile begins with the drilling program.

Jan 1, 1997

The Beginnings of Mineral Processing Research in Canada - A Short Account

Sep 13, 2010

By B. S. Xakalashe

Keywords: Pyrometallurgy, silicon, solar cells Silicon has been the dominant material in the photovoltaic (PV) industry since its application in the space industry in 1958. This review focuses on crystalline silicon solar cells, primarily due to their dominance in the photovoltaic industry, omitting other photovoltaic cell technologies such as second generation (e.g. thin films) and third generation (e.g. nano-structured solar cells). The value chain for the production of crystalline silicon solar cells has been reviewed. The primary processing steps for the production of silicon solar cells from quartz are as follows: bulk production of metallurgical-grade silicon via carbothermic reduction in a submerged furnace, refining of metallurgical-grade silicon via the chemical means to polycrystalline silicon, or through the metallurgical route to solar-grade silicon, wafer manufacturing, and, lastly, silicon solar cell manufacturing. During downstream processing, solar cells are interconnected and encapsulated into solar modules (panels), which can be used individually or incorporated into a photovoltaic system for electricity generation and supply. The cost for crystalline silicon based solar cells is approaching one US dollar per watt peak ($1/Wp), while the most cost-effective solar modules in industry have reported costs below $1/Wp, and are based on CdTe thin films. Solar cell energy conversion efficiencies as high as 22% have been reported in industry for crystalline silicon solar cells.

Jan 1, 2011

By Ammar Henchiri, Godfrey McDonald

"Breakwater Tunisia S.A.’s Bougrine mine is located in a semi-arid region of Tunisia characterized with Triassic salt domes. Due to extensive agricultural land-use in the mine area, a zero-discharge tailings facility design and high water recycling rates to the concentrator were chosen to minimize the environmental impact to the surrounding area. The process water supply has an accumulation of naturally occurring salts due to high evaporation rates and the need to recycle 70% of the process water. The elevated salt content of the process water had an adverse effect on the efficiency of the flotation reagents, which led to the production of lower quality zinc concentrate.The impact of the water salinity on the zinc concentrate quality was documented by extensive laboratory testing. A feasibility study was prepared and a decision was made to install a reverse osmosis plant for desalination of the process water. A plant was constructed during 2000 which currently supplies up to 85 m3/hr of de-mineralized water, equal to approximately 45% of the total process water requirement. The salinity of the process water decreased from about ten to twelve grams per litre before installation to less than three grams per litre. Together with minor modifications to the concentrator circuit, Breakwater Tunisia has increased the zinc concentrate grade from 50% zinc to 55% zinc without compromising the zinc recovery rate of approximately 84%.This paper discusses the successful installation of a reverse osmosis desalination plant that allowed Breakwater Tunisia to improve the grade of the Bougrine mine zinc concentrate and thus increase the net smelter return.INTRODUCTIONBreakwater Resources Ltd., through a wholly owned subsidiary, Breakwater Tunisia S.A., acquired the Bougrine underground mine and related assets in September 1997. During the winter of 1997/1998, the company rehabilitated the mining equipment, modified the concentrator circuit, developed a new mine ventilation system and prepared a new mining production program. The mine was reopened on May 2, 1998 and was in commercial production as of June 1, 1998."

Jan 1, 2003

Tougher physical mining and processing conditions as well as economic circumstances are causing many mining companies to re-evaluate the effectiveness of their mine planning. The recent wave of inexpensive computing power provides the engineer an opportunity to go beyond the simple one-off manual mine design and production schedule. The basis of a good mine plan is a good reserves model. Concepts of mine model development are explored. The only advanced computer methods that have found consistent success in optimising mine planning functions are economic pit limits determination and material scheduling. Three pit 'optimisation' methods are examined; the moving cone, the Lerchs-Grossman 3-D graph algorithm, and the new network flow algorithm. A comparison between the methods in terms of total profits generated and computer time involved are made. The results show that both algorithms produced a higher profitability than the simple moving cone, but at much higher execution times. However, the profit increase never exceeded much more than 1 % of the base moving cone case. Finally, a method for the development of long range material production schedules with forward waste planning is presented.

Jan 1, 1989

By Xinyang Wang

It is believed that sulfur and volatile matter con-tents in coals are the main intrinsic properties to cause the self-heating of coal. Their oxidation at lower temperatures than that of fixed carbon to initiate coal's self-heating should be quantified. This study is aimed to improve the previous mathematical model developed by the authors for studying the coal's propensity for spontaneous combustion. It enhances the model's ability to consider the effects of sulfur, volatile matter and moisture contents in the coal three important factors affecting the coal's self-heating process. Sulfur exists in coal primarily in the form of pyrite which will be oxidized rapidly under suitable conditions. Volatile matters, higher in low rank coals, are more easily to be oxidized. Heat of water condensation provides initial energy for low temperature oxidation. Heat release rates for pyrite oxidation and moisture condensation are built in the model. Finally, the simulation results in terms of time versus temperature on pyrite oxidation and moisture condensation are validated with the adiabatic testing data respectively.

Jan 1, 2013

Based on experimental and computer simulation results from our group, we report a systematic, atomic level analysis of carbon dissolution from carbonaceous materials in molten iron. Experimental results on graphite/Fe-C-S system were obtained using carbon dissolution studies, XRD and FESEM investigations and were supplemented with Monte Carlo simulations. Three basic mechanisms, namely carbon atom dissociation rate, interfacial phenomena and mass transfer in the melt were found to be responsible for the overall dissolution process. While mass transfer in the melt is governed by the concentration gradients, melt composition and temperature; impurities present in ash play a significant role in the interfacial phenomena. For less ordered forms of carbonaceous materials, carbon atom dissociation rate depends strongly on the degree of long-range order and is an important rate controlling mechanism in the overall dissolution process. A systematic comparison of dissolution rates for a variety of coal-chars, natural and synthetic graphites has been carried out in an attempt to identify rate-controlling mechanisms. The structure of the carbonaceous material appears to be an important underlying factor in the carbon dissolution process.

Jan 1, 2003

By J. Hines

Traditionally, fuel oil or diesel was the collector of choice in coal flotation, but in recent years these materials have come under increased scrutiny because of concerns about the toxicity of some components. In response to these concerns, Georgia-Pacific Chemicals LLC has commercialized a patent pending coal collector (Talon® 9400 reagent) that is 100% derived from the pulping of trees. This study presents a comparison of yields and recoveries for different coal collectors, including the one derived from the pulping of trees.

Jan 1, 2011

By Belcher C. B

A procedure was required for the rapid determination of silicon in low-alloy irons and a suitable method used the formation and reduction of silicomolybdic acid at 50°C. The procedure gives results for elemental silicon and this enables the correct computation of oxidation requirements in basic oxygen steelmaking. The method could be useful in iron foundries which have not installed direct reading spectrometers.INTRODUCTIONOxygen steelmaking experiments required rapid determinations of 0,5-1,6 per cent silicon in iron (3-4 per cent C) within 10 min of sampling; a reproducibility better than ±0.03 per cent Si was desired. Only elemental silicon (Si°) is of interest as a fuel in basic oxygen steelmaking technology, and the proposed procedure determines exclusively this form of silicon. The method is described as it may prove useful to other workers although the interference study would be incomplete for some applications.The analysis of silicon in iron is frequently obtained using direct reading spectrometers, but for the proposed experiments the spectrometers could not be used because of the prohibitive distance from the furnace. It should be noted that spectrometers determine both the elemental silicon and that present as silicon dioxide in occluded slag and inclusions.The silicon content of iron and steel is determined in this laboratory by spectrophotometric measurement of a "molybdenum blue" colour. The reactions involved have been extensively investigated; Strickland (1952) showed that a...

Jan 1, 1965

By T. van Heerden

A range of supported gold catalysts was prepared by ion exchange, varying many of the preparation variables, including concentration in the precursor solution, washing procedure, as well as drying and calcination procedures. These catalysts have been characterized extensively. TEM images show essentially the same crystallite size distributions, between 2?5 nm, for almost all catalysts, the only exception being catalysts not washed in ammonia, which did not show any small crystallites. Additional characterization with SEM yielded an interesting discovery. Catalysts that appear identical on the TEM also contain some large crystallites in the range of 50?500 nm. Differences in dispersion due to the drying procedure not seen on the TEM can now be observed. Oxygen chemisorption is being investigated as an additional method to characterize gold based catalysts to complement the typically used electron microscope techniques.

Jan 1, 2012

On the Hauraki goldfields, within the limits of Cape Colville Peninsula, the Paheozoic rocks are confined to the district north of a line drawn from Mercury Bay on the east coast to Rocky Point on the shore of the Frith of Thames. South of Kennedy's Bay they are developed on the east coast only at Kuaotunu, at which place gold mining is carried on in sandstones and slates of this age. Between Tapu Creek and Coromandel there is, along and adjacent to the shore of the gulf, a very considerable development of PaJreozoic and in part of Trias rocks, and between the Tiki Stream and the northern end of Tokatea Hill, along the western slope of the main range, lies the special area of the Palreozoic or carboniferous rocks that have more particularly to be dealt with in this paper. The same formation has a large devolpment between Cabbage Bay and the northern slopes of Moehau, and appears to the water marge on both sides of this part of the peninsula.In this part they are of special interest as having, on the west spur of Moehau, a considerable variety of dyke rocks intruded into the sedimentaries, the interest in which is increased by the fact that these dykes theIllselves are of Palreozoic age and correspond to the dykes that are so' abundant in the Tokatea-Tiki area. It is this Tokatea-Tiki area as a goldfield, and its rocks as distinguished from later volcanic' products' on other parts 'of the peninsula...

Jan 1, 1903

By Frank Yu, Bob Fukuhara

"The Stillwater mine is a 3,000 tons/day platinum/palladium underground mine and flotation concentrator located in the Beartooth mountain range in south-central Montana. The site elevation is 5,000 feet above sea level providing a climate with pleasant summers and cold winters. The winters are particularly characterized by very strong winds.The mining methods at Stillwater had been variations of overhand cut-and-fill and some blast-hole stoping. Until construction of the paste back-fill plant, mine back-filling was being practiced using classified hydraulic sand-fill methods. Where higher strengths were necessary, cement was added to the hydraulic fill, however, excessive quantities were necessary due to significant losses with the water drainage from the comparatively low-density fill. There was a need for higher strength back-fill with reduced cement content to augment the hydraulic-fill process.In early 1998, Stillwater Mining Co. commissioned AGRA Simons (then H.A. Simons) in a joint venture with The Industrial Company, TIC, to design and construct a treatment facility to re-process the mill flotation tailing, incorporating the following process alternatives:Produce 100 tph of low strength paste with unconfined compressive strength of 25 to 50 psi,Produce 100 tph of high strength paste with unconfined compressive strength of 100 to 125 psi,Direct all of the excess mill tailing to the sand-fill plant,While no paste is being produced, pump all of the mill tailing to the sand-fill plant,While no paste is being produced and the sand-fill silos are full, direct the mill tailing to the tailing pond.The paste backfill plant was therefore to be designed to produce the two different types of backfill paste as well as have the function of being the distribution center for the mill process tailing .Moderate to high slump pastes would be required because of the comparatively long horizontal transport distances, up to 8,000 feet, and the requirement for a low angle of repose to fill the stope evenly without numerous discharge points."

Jan 1, 2000

By Bibby P. A, Leupen R. A

A 24,300 tonnes per year state of the art Silicon smelter is being constructed for Barrack Silicon Pty Ltd at Kemerton, 20 kilometres north of the City of Bunbury in Western Australia. The plant is designed for the reduction of high purity quartzite lump to metallic silicon in two 27MVa Demag submerged arc electric furnaces. The primary reductant, a high purity charcoal, will be manufactured at the plant from locally sourced jarrah wood waste (Eucalyptus Marginata). Commercial silicon production is scheduled to commence in October 1989. Keywords: Silicon, Smelter, Quartzite, Furnace, Charcoal, Jarrah, Wood, Eucalyptus Marginata.

Jan 1, 1989

Since the last occasion on which I spoke to you on this subject there has been a considerable increase in the mechanical ventilation of Western Australian mines.The following table compares the figures for 1939 with those of 1941. The type of fan most commonly used is the limit load fan. On account of its higher mechanical efficiency it has very largely superseded the multivane fan with forward curved blades.Two fans of the propeller type are in use and these have given very satisfactory service. This type of fan also has a high mechanical efficiency particularly at the correct duty for maximum efficiency.The maximum efficiencies obtainable from the various types are, for "multivane" 670/0, for "limit load" 75%, and' for aerovane 7810/0.References to propeller fans with variable pitch have appeared in the technical press, but no detailed d~scription has been issued. The advantages of these fans for mine ventilation are not obvious. An aeroplane is required to operate over a wide range of duties, while the speed of the motor for maximum efficiency is pl'actically constant. In such circumstances the propeller can be adapted to the particular work it has to do by varying the pitch of the blades. In a mine the speed of the fan can be varied to suit.the conditions, and it would appear that variable pitch is not necessary while there is a reasonable range of fans to choose from.The question of the correct position for the fan still comes in for considerable discussion. Exhausting fans at the surface have the support of time and custom, and in many cases this represents the only reasonable arrangement. Such fans should be fitted with an evase, especially in the case of fans with a high outlet velocity such as the aerovane types.It is claimed that there are advantages in having the fan at the surface where it is readily available for inspection and maintenance. Experience has shown that these advantages are more apparent than real. Fans will run for long periods with no attention other than occasional greasing and cleaning, and modern electric motors will run without attention for very long periods.In some instances the expense of a power cable to take current to the fan may be saved by placing it on the surface, but in the majority of cases...

Jan 1, 1941

By J. M. Ortiz

This paper shows the usefulness of geostatistical conditional simulation combined with the quantification of sampling errors obtained from the analyses of fundamental errors ? validated from duplicate data ? to assess the relevance of the quality and quantity of the information, for short-term mine planning purposes. Traditional blast-hole drilling equipment has been designed for efficient drilling, but not for obtaining high-quality samples. Furthermore, blast-hole sampling interferes with production, and thus usually produces poor-quality results. These results are the basis of short-term plans, where the grades of selective mining units are estimated and used for distinguishing between ore and waste. Under these conditions, misclassification (ore blocks sent to the waste dump and waste blocks processed at the plant) is inevitable, leading to significant hidden losses that can amount to millions of dollars per annum. Reverse circulation drilling with the latest automated sampling technology improves significantly the quality of the information used for short-term planning, and thus reduces misclassification, improving the financial returns of the operation. In this paper, we present the general methodology for assessing the effect of poor blast-hole sampling, as compared to advanced reverse circulation drilling grids at several spacings, in order to arrive at the most appropriate grid for short-term planning. This plan can be prepared well in advance using several additional variables that are usually not available when the plan is based on blast-hole samples. Furthermore, blending options can be analysed in order to optimize plant recovery, minimize the use of sulphuric acid, etc. Three case studies are presented, namely a typical porphyry copper deposit, an exotic oxide copper deposit, and a complex gold deposit, where mineralization is controlled by structures and lithology. This paper shows that in all cases, advanced reverse circulation drilling grids provide good-quality information that, coupled with the use of geostatistics for short-term mine planning, significantly improve the financial returns of the operation.

Jan 1, 2014

By Pathies Nawej Muteb, Tom Strombotne, Karl Leetmaa, Irma Gabric, Keith Darby

"Continuous control of the final grinding product size is important to optimize gold liberation for Gold Milling operations. At Meadowbank Mine an on-line Particle Size Monitor has been employed successfully to achieve the targeted final grind which leads to optimizing the gold recovery at maximum grinding circuit throughput. The live monitoring of the final product particle size leads to a maximum grinding circuit throughput every minute during the process. This paper discusses the optimal utilization of the Particle Size Monitor to assist the Mill operator to maximize the grinding circuit throughput as the milling conditions change due to variable ore processed at Meadowbank Mine. Also the paper includes the usage of the Particle Size Monitor to guarantee the final grind target at each instant of the process.IntroductionAgnico-Eagle is a Canadian-based company that Trades on the TSX & NYSE (AEM). It owns eight mines (8) operating in Nunavut, Quebec, Finland and Mexico and has more than 7,500 employees (Figure 1). 1.6 M ounces of gold were produced in 2015 and the annual average annual production from 2016 to 2018 is forecast to be approximately 1.53 million ounces of gold.The Meadowbank Mine is located in Nunavut, Canada (Figure 2). The mine opened in 2010 and from 2010 to 2014 a total of 1.8M oz of gold was produced. The milling rate is 4.2 Mt per year with an average mill throughput of 11,900 tpd or 496 tph. Average annual gold production over life of mine is expected to be 450,000 ounces. Meadowbank has 775 employees, of which 265 are Inuit or 36% of the total workforce. Estimated life of mine is 2010 to 2018. Gold production in 2015 was 381,804 oz. Meadowbank was Agnico-Eagle’s largest Gold producer in 2015."

Jan 1, 2017

By J. D. Miller

Characterization of feed material with respect to expected concentrate grade and recovery is fundamental to the design of improved separation efficiencies and to achieve sustainable development in the utilization of our mineral resources. An important reference point for this characterization is the liberation-limited grade/recovery curve which represents the perfect separation, the best separation which can be achieved for a given feed material limited only by the extent of liberation. Now, liberation-limited grade/recovery curves can be determined based on 3D mineral liberation analysis of feed material. Thus, actual separation efficiencies can be compared to what might be expected for a perfect separation limited only by the extent of liberation. It is shown that 3D mineral liberation analysis based on X-ray micro CT (XMCT) is preferred to 2D section analysis which overestimates the extent of liberation. By way of example, procedures and experimental results are presented and discussed for feed material in the case of phosphate rock flotation.

Jan 1, 2009