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[A Aall, Christian H., M49 A Dir, Smelt & Ref, Am. Metal Climax, Inc., 1270 Ave. of the Americas, New York 20, N. Y. Aaroe, S. L., A54 A VP, W. S. Tyler Co. of Canada Ltd., P. O. Box 100, St. Catharines, Ont., Canada Abalos, Teodulo Q., J57 A Prod Frmn, Lepanto Cons. Mining Co., Lepanto, Mt. Province, Philippines Abbitt, James M., A54 770 Sole Blvd., Bartow, Fla. Abdullah, M. Y., J53 Dept. of Mines Res. Div., P. O. Box 1016 Tiger Lane,-Ipoh Peram, Malaya Abel, John F., Jr., J53 F Mine Engr, Thompson Creek Coal & Coke, Carbondale, Colo. Abell, Leo M., M31 B Const Supt, Phelps Dodge Corp., Morenci, Ariz. Abendroth, H. E., A57 Mangore Australia Pty. Ltd., 901 Hay St., Perth, W. Aust.,, Australia Abenius, Hakan V., M52 Falun, Sweden]

Jan 1, 1961

[A Aalseth, Earl P. (M 51) Geol, Amerada Petr. Corp., Box 1498, Billings, Mont. Abadie, Henry G. (M 43) Asst to Supvr of Oper, Long Beach Oil Dev. Co., 255 S. Santa Clara, Long Beach 7, Calif. Abbe, T. Waldo (A 56) Ass't Dist Oper Supt, Sun Oil Co., Beaumont, Tex. Abbott, J. L. (M 56) Partner, Pritchard & Abbott, 501, Century Bldg, Fort Worth, Tex. Abbott, Richard H. (J 51) Owner, Abbott & Howard, 422 W. Hermosa, San Antonio, Tex. Abbott, Seth J., Jr. (M 51) Tekoil Corp., .2;A6 Mercantile Nat'l. Bank. Dallas, Tex. Abbott,. William G. (M 50) Div Mgr, Rice Eng. & Op. Inc., Box 1142, Hobbs, N. M. Abderhalden, R. R. (J,59) Box 100, Carmi, Ill. Abel, Malcolm D., Gen Mgr, Bakke Oil Co., Midland, Tex. Abel, Raymond L. (M 28) Prof of Chem Engr, Univ. of Pittsburgh, Pittsburgh 13, Pa. Abel, Wayne K. (M 57) 1513 Patton Drive, Odessa, Tex.]

Jan 1, 1961

[A Aall, Christian H., M49 D Mgr, American Metal Climax, Inc., 61 Broadway, New York 6, N.Y. Aaroe, S. L., A54 B Sales Mgr, The W. S. Tyler Co. of Can. Ltd., St. Catharines, Ont., Canada Abalos, Teodulo Q., J57 A Foreman, Lepanto Cons. Ming. Co., Mt. Province, Philippines Abbass, G., M55 P. O. Box 680, Hong Kong, China . Abbitt, James M., A54 770 Sole Blvd., Bartow, Fla. Abdullah, M. Y., J53 Dept. of Mines Res. Div., P. O. Box 1016, Tiger Lane, Ipoh Perak, Malaya Able, John F., Jr., J53 A Ming Engr, USA SIPRE 1215 Washington Ave., Wilmette, Ill. Abell, Leo M., M31 B Conct Supt, Phelps Dodge Corp., Morenci, Ariz. Abenius, Hakan Wilhelm, M52 A Mng Dir, Stora Kopparbergs Bergslags AB, Falun, Sweden Abenoroth, Harry F., A57 Natl. Carbon India Ltd., 18A Brabourne Rd., Box 217, Calcutta, India Abercrombie, Harry W., J56 1645 Camphor Dr., Lakeland, Fla.]

Jan 1, 1961

Abbey. Robert Graham, District Mgr.. The W. W. Sly Mfg. Co., 50 Church St., New York, N. Y. '21 Abbott, Clarence E., V.P., Charge of Raw Materials, Tenn. Coal, Iron & R. R. Co., 1242 Brown-Marx Bldg., Birmingham, Ala. '04 Abbott, Louis Benjamin, Chief Engr., Consolidation Coal Co., Watson Bldg., Fairmont, W. Va. '15 Abeel, George H., Jr., Cons. Min. Engr 12S1, S. Canon Dr., Beverly Hills, Cal. '18 4 -Abel, Raymond L., Asst. Prof., Dept. of Pet. Refin.. Univ. of Pittsburgh. Pittsburgh, Pa. '28 Abel, Walter D., Cons. Engr 650 S. Grand Ave., Los Angeles, Cal. '82 Abele. Louis T., Min, & Met. Engr., Supt., Texas Hill Mine Coulterville, Cal. '31 Abell, Leo M Sullivan Concentrator, Chapman Camp, B. C., Canada '31 Abernathy, George Elmer, Prof. of Geol. & Min., Kansas State Teachers College. Pittsburg, Kan. '20 Aborn, Robert H., Asst. Met., Research Lab., U. S. Steel Corp., Lincoln Highway, Kearny, N. J. '19 Abraham, W. E. V., Member, Geological Staff of Burmah Oil Co., Ltd., Nyaunghla, Upper Burma, India. '28 Abstein, Henry T., Engr. & Mgr., Profile-Tamarack Mines Co Yellow Pine, Idaho '27 Acker, E. O'C., Met 128 East Washington Lane, Germantown, Philadelphia, Pa. '86 Ackerman, D. E., Met., Research Lab., International Nickel Co., Inc Bayonne, N: J. '24 Ackerman, George F., Engr., Real del Monte y Pachuca Min. Co., Apt. 3, Pachuca, Hgo., Mexico '29 *Acres. T. H.. Geol. Dept., Valuation & Pet. Engrg., Richfield Oil Co., 555 S. Flower St., Los Angeles, Cal. '29 Adachi, Jinzoo Address Wanted '88

Jan 1, 1934

[A AALSETH, Earl P (M 51) Consult Geol Engr 2019 Eldorado Dr, Billings, Monl ABADIE, Henry G (M 43) Asst to Supt of Oper Long Beach Oil Dev Co 925 Harbor Plaza, Long Beach 2, Calif ABBE, T Waldo (A 56) Asst Dist Oper Supt Sun Oil Co PO Box 66, Stowell, Tax ABBOTT, Fred E Jr (M 59) Abqaiq Dist Mgr Arabian American Oil Co Dhahran, Saudi, Arabia ABBOTT, Clifton T (A 60) Apartado 677, Maracaibo, Venezuela ABBOTT, J L (M 56) Partner Pritchard & Abbott 1010 Ft Worth Natl Bk Bldg, Fort Worth 2, Tex ABBOTT, Richard H (J 51) Partner Abbott & Howard 422 W Hermosa San Antonio 12, Tex .ABBOTT, William G (M 50) Div Mgr Rice Engrg & Operating Inc Box 1142, Hobbs, N. M. ABDERHALDEN, Ronald R (J 59) Prod Engr Continental Oil Co Box 100, Carmi, III ABEL, Malcolm D (J 50) Gen Partner Abel & Bancroft PO Box 865, Midland, Tex ABEL, Ramond L (M 28) Prof of Chem Eng Univ of Pittsburgh, Pittsburgh 13, Pa ABEL, Wayne K (M 57) 1513 Patton Drive, Odessa, Tex ABELL, Joseph M (J 55) Petr Engr Tennessee Gas & Oil Co Box 1772, Casper, Wyo ABELS, Thomas A (J 60) Exploit Engr Shell Oil Co Box 193, New Orleans 3, La ABENDROTH, G F (M 46) Dring Prod Supt Lyons & Logan 1500 Beck Bldg, Shreveport, La ABERCROMBIE, Bolling A (M 60) Mgr Product Planning Axelson-Garrett PO Box 2427, Longview, Tex ABERCROMBIE, C T (160) Prod Engr Cities Ser Petr Co Box 472, Brownfield, Tex ABERCROMBIE, H L Jr (J 55) Prod Engr Mobil Oil Co Room 1800 Gr PI Life Bldg, Lubbock, Tex ABERCROMBIE, Robert (J 57) Prod Engr Mobil Oil Co PO Box 1770 Shreveport, La ABERG, Richard S (M 57) Area Prod Geol Shell Oil Co of Canada, Box 100 Calgary, Alta, Canada]

Jan 1, 1961

Core samples, which were collected by the author from the Busang prospect, East Kalimantan, reflect a progressive evolution of a large magmatic-related hydrothermal system that is comparable to that encountered in many similar systems elsewhere in the Pacific region. The initial, localized deposition of sheeted porphyry quartz-molybdenite veins took place at high temperatures and fluid salinities, and at relatively deep levels. This was followed by an extensive phase of phyllic (sericite-quartz-pyrite ¦ tourmaline-apatite) wallrock replacement and vein formation. Propylitic (epidote-chlorite-carbonate-quartz) alteration was formed marginal to the phyllic assemblages. These porphyry-related events were centred in the Southeast Zone, and are probably associated with the emplacement of a felsic intrusion at depth. This event contributed only trace gold to the system. The early stages of hydrothermal activity were followed by an episode of quartz (¦ adularia) û carbonate û base metal sulfide veining, which was accompanied by argillic (illitic-kaolin clay) wallrock alteration. This event was sulfide-rich in the Central Zone and carbonate-dominated in the Southeast Zone. Gold mineralisation was observed in Central Zone drillcore to be associated with both sulfide, as well as carbonate, deposition. A final stage of epithermal-style quartz ¦ stibnite û realgar veins are, in the Central Zone, locally gold-bearing. The latter two events are interpreted to be associated with the late-stage exsolution of metal-bearing brines from the felsic intrusion that formed the earlier porphyry quartz-molybdenite veins and widespread phyllic-propylitic alteration.

Jan 1, 2002

By W Herrmann, R R. Large

Volcanic-hosted massive sulfide (VHMS) deposits in ancient, submarine volcanic belts of Australia include mound, lens and sheet-style Zn-rich polymetallic deposits, massive and disseminated pyritic Cu-Au deposits and disseminated, stratabound Au-only deposits. Variation in morphologies, metal ratios, volcanic environments and alteration features indicates there exists a spectrum of deposits from the classic VHMS model, to hybrids between VHMS-porphyry Cu and VHMS-epithermal end members. Zn-rich, polymetallic deposits form eitheron, or just below, the seafloor, whereas the Cu-Au and Au-only deposits form sub-seafloor by replacement of specific volcanic lithologies. Alteration zoned outwards from quartz -> chlorite -> sericite ¦ carbonate is typical of VHMS deposits across the spectrum. Quartz and carbonate alteration is dominant in the Au-only systems,chlorite alteration is commonly developed close to Cu-rich ores, and sericite and carbonate alteration zones are well developed in the stratiform Zn-rich ores. The most useful geochemical vectors for Zn-rich ores are the alteration index [AI=100(MgO + K2O)/(MgO + K2O + CaO + Na2O)], the chlorite-carbonate-pyrite index [CCPI=100(MgO + FeO)/(MgO + FeO + K2O + Na2O)], Mn content of carbonate, Mg/(Mg+Fe) ratio of chlorite,whole-rock Tl, Sb and Ba/Sr ratio, S34S of pyrite, and whole-rock S18O. The most useful vectors for pyritic Cu-Au ores are AI, CCPI, S/Na2O ratio, Na content of white mica, and Fe content of carbonate.

Jan 1, 2002

By Y Öztas, S McKinley, T Baker

The Kisladag Mine, Turkey, is a large porphyry gold deposit which is mined by open pit methods. In operation for over ten years, Kisladag provides an excellent example of how attention to a geologic feature, namely hydrothermal alteration, became a very effective predictive geological tool for planning and operation. The alteration domains were initially used as a geological tool to assist with establishment of resource model domains and to guide delineation drilling, but they were soon recognised to be correlative to geotechnical characteristics (affecting pit slope angles) and metallurgical performance (heap leach recoveries). Recent developments in spectral processing allow the systematic quantification of complex overlapping alteration phases and have greatly improved the ability to rapidly define internally consistent alteration domains for geotechnical and geometallurgical purposes.Alteration at Kisladag comprises a central core potassic (K-feldspar-biotite) zone, a tourmaline-white mica enveloping zone, an advanced argillic lithocap on the deposit’s eastern side and an overprinting pervasive argillic zone. These alteration zones and their distribution were based initially on strictly qualitative, visual mineralogical logging of diamond drill core. With the need for more accurate and consistent identification of the alteration mineral suites, particularly the phyllosilicate phases, logging was augmented by systematic measurement of spectral data using a Terraspec instrument.Recently the Kisladag spectral database (over 85 000 readings) was reprocessed by the newly developed methodology (aiSIRIS™) that allows relative quantification of the spectrally-responsive minerals. Visualising this transformed spectral mineralogy at various mineral concentration thresholds using implicit modelling software (Leapfrog®) led to the creation of consistent mineralogical and alteration domains that are used for the definition of geotechnical and geometallurgical parameters. An implicit modelling workflow enables these domains to be easily updated as new data is collected while maintaining geological integrity of the model.CITATION:McKinley, S, Baker, T and Öztas, Y, 2017. Alteration at Kisladag gold mine, Turkey – a progressive study in geology, geotechnics and geometallurgy, in Proceedings Tenth International Mining Geology Conference 2017, pp 51–62 (The Australasian Institute of Mining and Metallurgy: Melbourne).

Sep 20, 2017

By R J. Worland, D Bowyer, J L. Mauk

The TerraSpec is a compact field portable mineral analyser that uses non-destructive reflectance spectroscopy for mineral identification. The instrument uses and measures infrared and visible light that is absorbed by certain covalent and molecular bonds (AlOH, FeOH, MgOH, CO32-, OH, H2O and NH4) within the lattice of a mineral at specific wavelengths producing an absorption spectral profile. A variety of minerals can be detected including clays, micas, carbonates, and hydroxides as well as some sulfates and silicates. However, not all minerals are detectable, such as quartz and feldspar. Alteration minerals replacing volcanic rocks have been studied for several epithermal prospects in the lower Waitekauri Valley (Sovereign, Jubilee, Scotia and Jasper Creek) and a geothermal field in the Taupo Volcanic Zone. At the Sovereign, Jubilee, Scotia and Jasper Creek prospects previous XRD investigations determined well developed clay mineral zonation with illite in the west (Sovereign and Jubilee) grading into interstratified illite-smectite (Scotia) and smectite (Jasper Creek) to the east. Although the percent of illite within interstratified illite-smectite could not be determined and some illite-rich illite-smectite (>90 per cent illite) and some smectite-rich illite-smectite (>90 per cent smectite) could be misidentified as illite or smectite respectively, the TerraSpec survey determined the same zonation of illite to illite-smectite and smectite. Common chlorite, rare calcite and local kaolinite were also detected. At the geothermal field, the TerraSpec was primarily used to determine the occurrence of kaolinite, dickite and alunite, which form in acid conditions. Widely spaced (every 50 to 100 m) XRD results are in excellent agreement with closely spaced (every 5 to 10 m) TerraSpec results that further determined the occurrence of these minerals in previously unrecognised intervals. It also determined the occurrence of zoned smectite, illite-smectite, illite, and chlorite alteration. Overall, the TerraSpec is a rapid mineral identification technique that is very useful in delineating the occurrence and distribution of certain minerals in both epithermal deposits and geothermal fields. Although the TerraSpec cannot detect as many minerals as XRD, the TerraSpec allows data collection at a sampling scale and speed (real time) that is not practical by XRD.

Jan 1, 2006

By Denis Thibodeau

his paper describes a study of an altered mining extraction and the resulting Rockmass response at VALE?s Creighton Mine. Typically, the deep mining zones have strict stope extraction guidelines to ensure safety and productivity; however, these guidelines offer low flexibility or few options for stope sequencing. The 402 O. B. being in a good rock mass, at moderate depth and stress regime at Creighton, offered an opportunity to drive a more flexible mining sequence with stopes and a pillar. A three-phased approach was used to mitigate risk of the mining plan: 1- Numerical modelling to fully anticipate rock mass response to the proposed mining sequences. 2- In situ seismic monitoring to collect stress and seismic activity data. 3- Analysis of the in situ data to correlate to the modelling results. The creation and the extraction of a pillar in the 402 O. B. was successfully completed. The recorded seismic activity agrees well with the numerical modelling since most of the seismic activity is localised in the hangingwall where the deviatoric stress corresponds to an early damage process. The moderate levels of deviatoric stress cause localised failure with low level of seismic activity.

May 1, 2013

By Fernando Pajuelo Rincón

El presente trabajo describe la explotación del cuerpo mineralizado Barnabé en Huarón, donde es interceptado por una veta a través del uso de un equipo LHD neumático y del vehículo LHD -EH. No obstante, es válido mencionar algunas variantes aplicados al método del minado a partir de la estructura de la veta Rey, a fin de alcanzar una explotación selectiva y aumentar el valor de la tonelada del mineral. En ese sentido, las variantes aplicadas al método se dan en base a la flexibilidad del equipo de limpieza, reduciendo los costos de minado en los tajeos Barnabé y Rey.

Aug 26, 1988

By Roberto Maldonado

El presente texto señala el proyecto de profundización en la mina Animón considerando sus características como: geología e hidrogeología, parámetros geomecánicos, niveles de producción, costos de capital y operación, eficiencia del sistema, flexibilidad para cambios en las operaciones, reservas de mineral y consistencia con el sistema de explotación. De forma que a través del conocimiento de estas y de las herramientas gráficas tridimensionales, se pueda analizar las diferentes alternativas, incluyendo condiciones que debe cumplir el proyecto de profundización, el cual abarca también los servicios auxiliares y ventilación.

Sep 12, 2005

By Oswaldo Ortiz Sánchez

El presente trabajo describe la alternativa de uso del mortero de resina en la fijación de pernos de anclaje de las excavaciones mineras, consolidación y disipación de vibraciones en los cimientos de plataformas para la instalación de molinos, winches, tolvas, etc. Esta opción surge en respuesta al problema de reforzamiento con pernos de anclaje en ambientes con aguas corrosivas o en proceso de deformación acelerada en las excavaciones mineras, así como ante obstáculos de subsidencia de cimentación en plataformas, donde se encuentran instalados equipos de gran tonelaje, y que producen fuertes vibraciones durante su funcionamiento.

Jul 31, 2003

By John Reilly

Traditional methods of project procurement of have remained virtually unchanged in the U.S. infrastructure construction industry for more than 50 years. The traditional method, Design-Bid-Build (DBB), uses a two-step process that separates planning and design from construction. Design is generally done by the public agency and their consultants and the subsequent construction contract is procured from the private sector, almost always by a “low-bid” approach. This method has worked well for many projects, delivering quality work for the lowest bid price. This is particularly true for those projects where the work, and the public agency’s management procedures, are well understood by the contracting community and there is relatively low uncertainty in the work or conditions, particularly geotechnical conditions for underground construction. However, concerns exist with the DBB process. It is time consuming because all planning and design work must be completed prior to beginning any construction work and it is of concern for complex or large projects, plus those with significant risk, where the separation of design and construction, in conjunction with pressures resulting from the low-bid environment, often result in substantial cost and schedule increases. Frequently, these increases occur in a non-productive, inefficient, adversarial work environment leading to claims, disputes and costly litigation (Quick 2002).

Jan 1, 2007

By John Reilly

The author?s paper at RETC 2007, ?Alternative Contracting Methods? addressed strengths and weaknesses of DBB+DB and introduced Construction Manager/General Contractor (Portland model) and Alliancing (Australian model). Considerable interest in these was expressed by several public agencies at that Conference and at the presentation. The author is assisting the Washington State Department of Transportation (WSDOT) and the Toronto Waterfront Revitalization Corporation (TWRC) with possible implementation of Alliancing. WSDOT is evaluating ways to do this and is considering a delivery methodology, under existing Legislation, based on the CMGC Portland model with incentives and disincentives, moving towards Alliancing. This paper will build on the 2007 paper and update implementation considerations.

Jan 1, 2008

By Wesley Schmutzler

The Deep Mixing Method (DMM) was employed to raise and support the LPV (Lake Pontchartrain and Vicinity) -111 Levee in New Orleans. Even using innovative technologies, the tight schedule to achieve the 100 year elevation by June 1, 2011 was a daunting endeavor. The size and scope of DMM proposed for LPV-111 was on a scale never attempted outside of Japan. Over 1.65 million cubic yards of DMM was installed. LPV-111 is adjacent to the Bayou Sauvage Wildlife Refuge, which is the largest urban National Wildlife refuge in the United States. By utilizing DMM to control settlement and improve stability of the taller levee, side slopes were steepened from the conventional 1V:4H to 1V:2.85H, thus avoiding encroachment into the Bayou Sauvage and reducing the amount of clay needed for the completed levee. The COE utilized Early Contractor Involvement (ECI) for this contract. The ECI process allowed for input from the DMM contractor, TREVIICOS South, in order to optimize equipment resources and material requirements. This paper gives an overview of the extensive DMM requirements for LPV-111 and explains the benefits of the ECI process.

By Timothy C. Siegel, Derrick Dasenbrock, Rich Lamb, Paul J. Axtell

"The axial resistance provided by deep foundations may be divided into two components: side resistance and tip resistance. The direction that the side resistance acts depends on the relative movement between the deep foundation and the adjacent soil. That is, when the foundation moves downward relative to the soil, then the side resistance is positive and acts upward. Conversely, when the soil moves downward relative to the foundation the side resistance is negative and acts downward. Research supports that both positive side resistance and negative skin friction develop in essentially all deep foundations. The side resistance distribution is a function of the soil strength and stiffness, the applied top loads, and whether the top load is sustained, transient, or a combination of sustained and transient loads. Consideration of drag load and downdrag has become more convoluted with implementation of geotechnical aspects into the AASHTO LRFD Bridge Design Specifications and its use of load and resistance factors. This paper examines the current AASHTO Specifications and presents an alternative design approach for drag load and downdrag using the LRFD framework. The alternative design approach is illustrated by two examples involving drag load and downdrag.IntroductionThe axial resistance provided by deep foundations may be divided into two components: side resistance and tip resistance. The direction that the side resistance acts depends on the relative movement between the deep foundation and the adjacent soil. That is, when the foundation moves downward relative to the soil, then the side resistance is positive and acts upward. Conversely, when the soil moves downward relative to the foundation the side resistance is negative and acts downward. Research supports that both positive side resistance and negative skin friction develop in essentially all deep foundations. The side resistance distribution is a function of the soil strength and stiffness, the applied top load, and whether the top load is sustained, transient, or a combination of sustained and transient.Consideration of drag load and downdrag has become more convoluted with implementation of geotechnical aspects into the LRFD Bridge Design Specifications and its use of load and resistance factors. This paper examines current LRFD design specifications and presents an alternative design approach for drag load and alternative design approach is applied to several examples where drag load and/or downdrag may control design."

Jan 1, 2015

Technical disputes, commercial negotiations and workplace/societal conflict are a natural part of doing business and just living itself. Conflict is everywhere û at home (between family and neighbours); in the workplace (between management, co-workers and unions), with contractors and with other companies; and everywhere at the community level, dealing with land access (pastoralists/farmers and indigenous/First Nation people), environmental protestors and NIMBY-ites - Civil Society in general. Exploration and mining companies, operating in more remote, less developed and culturally diverse regions, tend to encounter myriad areas of conflict (typically emotion-charged) and they are outlined. Dispute prevention, management and various binding and non-binding resolution techniques are discussed. The paper gives a general overview of the ADR nomenclature and framework (mediation, conciliation, expert determination, adjudication, arbitration and litigation) encouraging technical professionals to participate. Its thesis is that lawyers should not necessarily be the first port of call when problems arise between the mining workforce, contractors, joint venture partners, purchasers of prospects/mines, traditional land owners, protest groups, etc. If the matter must be litigated, the role of the expert witness is critical in pretrial planning, negotiations, mediation and litigation management, so a few guidelines are provided. Whilst dispute resolution has a legal context, the paper is written from an AusIMM technical professionalÆs perspective, emphasising practical long-lasting pragmatic solutions.

Jan 1, 2006

By S. J. Lötter

Analysis of the major and minor components of raw zircon as well as plasma-dissociated zircon was undertaken using inductively coupled plasma optical emission spectroscopy (ICP-OES). Microwave-assisted acid extraction as well as flux fusion using lithium tetraborate were investigated as digestion methods. Microwave-assisted acid extraction samples were analysed with matrix-matched standards. The most successful microwave-assisted acid extractions yielded 44.3(1), 49.75(7), 78.3(3) and 90.0(7) per cent recovery for Zr, Hf, Al, and Fe respectively using sulphuric acid. In no instance was acid extraction capable of complete digestion of the sample matrix. A standard addition method was applied to the flux-fusion samples due to the high complexity of the sample matrix. Method validation for the flux fusion procedure was performed using the SARM 62 certified reference material (CRM) with acceptable recovery ranges being based on the 95 per cent confidence intervals of the CRM. Successful analyses were achieved for Zr, Hf, and Ti with apparent content of 66(6), 1.7(1) and 0.15(1) per cent respectively.

Jan 1, 2012

By S. Rolseth, J. Thonstad

The traditional electrolyte for aluminium electrolysis is based on molten cryolite (Na3AlF6), acting as solvent for the raw material, alumina (Al2O3). Over the years there has been a trend to increase the content of excess aluminium fluoride (AlF3) to the cryolite-based electrolyte, in order to enhance the current efficiency of the process. In most cases one has ended up at 11?13 wt% excess AlF3because higher contents makes it difficult to control the heat balance of the process. This problem may be overcome if sensors are developed that will allow online control of electrolyte temperature and composition, and we may then see a surge towards still higher AlF3contents. In the development of new anode materials to replace the carbon anode with inert, oxygen-evolving anodes, focus is on anode corrosion, and a low electrolyte temperature is then highly desirable. While the conventional process operates at around 960°C, electrolyte temperatures as low as 750°C are being tested. This is achieved by having large excess contents of AlF3(40 wt%). The consequences of using such electrolyte compositions are discussed.

Jan 1, 2004