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By R. V. Higgins

A numerical method is presented to calculate the isopressure (isobar) lines and streamlines for an oilfield from the pressure distribution. A knowledge of these lines is useful in the study of the flow of fluids in underground reservoirs, especially for those containing gaseous and/or liquid hydrocarbons. This work was done primarily to enable determination of the shape factors needed in the calculation of petroleum reservoir performance. However, it has application for the flow of water in aquifers, or electricity or heat in odd-shaped geometry. Techniques previously developed were used to calculate the pressure distribution. From this pressure distribution, the isopressure lines were calculated accurately by the method presented in this paper. Then by successively projecting orthogonal lines from one isopressure line to another, the streamlines are determined. From the coordinates of the isopressures and the streamlines, the shape factors can then be determined by a published method. Computer methods are presented to calculate the streamlines and isopressures for any well-spacing pattern existing within a field with multiple wells. The method reproduces the flow net for several well configurations having extensive geometrical variations. Such information provides the petroleum engineer with data from which he can compute oil recoveries for different patterns and thereby maximize the recovery of hydrocarbons from the reservoir.

Jan 1, 1972

By G. Robert Guillet

"Ontario enjoys the advantage of its proximity to the large industrial market of northeastern North America. Together with Quebec and fifteen nearby U.S. states, an industrial base of more than half the total for both countries is provided by a population of 100 million.Mineral fillers such as barite, calcium carbonate, kaolin, mica, silica and talc are of major importance in the manufacture of paper, paint, plastics, rubber, vinyl tile, carpet backing, putty, caulks, sealants and adhesives. Ontario has all of these minerals, but domestic production falls short of demand in some cases, and mica and kaolin are not produced at all.This paper reviews the market and outlines the distribution of the major filler-consuming plants of northeastern North America. It also identifies the principal producers of filler minerals in the United States and Canada.IntroductionOf all the uses for industrial minerals, mineral fillers are probably the least understood. Originally used primarily to add low-cost bulk to a variety of commodities without seriously affecting their properties, filler minerals have become essential components that enhance and extend the properties of their hosts. Hence the term ""extender"" which, for all practical purposes, is synonymous with ""filler"". Today, fillers and extenders are not solely low-cost additives, but ingredients that provide essential characteristics to the products they fill.The major markets for mineral fillers are paint, paper, plastics, rubber, adhesives and floor coverings. But there are many others: putty, pesticides, wire and cable coatings, caulking and asphaltic compounds, oilcloth, wall-paper, joint cements, inks, sealants and many others. Barite, calcium carbonate, kaolin, mica, silica and talc are among the more important filler minerals discussed in this paper, but there are at least a dozen others. And the increasing practice of coating the mineral surfaces with certain coupling agents or metal stearates is constantly expanding the range of characteristics and hence the marketing opportunities.Whiteness, particle shape, fineness of grind and cost are the principal considerations in selecting a filler, but other characteristics such as weight, opacity, hardness and chemical inertness may be dominant considerations in specific applications."

Jan 1, 1987

Bahuerachi Project Characteristics Why it?s nicer at Bahuerachi Mexico is a mining country Low political, regulatory and trade risk Low social/permitting risk Proximity to infrastructure Road Power grid (8 km) Rail line (25 km) High grade zones (skarns), CRD and near surface oxide component are sweet spots to the overall system. Size of low grade system points to potential long mine life?and numerous new targets developing. Timelines-2006? 90 to 100 combined RC and core holes to go! MAIN ZONE Drilling ? Goat ?Finish Mid April ? Main Zone, going North, depth of testing dependent, estimated for May ? North Lobe-May ? Commission independent resource estimate by May 06 for results of first pass drilling to date ?tonnesand grades ?Main Zone Milestone. ? Continue infill or expanded drilling to July (minimum) ? 1stpass RC scheduled until September OTHER Targets ? Begin drill testing North Skarn target Mid-April, minimum 5 drill holes, 1,000 meters. Ongoing expansion of target with surface work (mapping) ? Road to Colome(Skarnin north of Main Zone) as part of porphyry program ? Tule(southern) porphyry and skarn system-soils and mapping OUTSTANDING events Metallurgical report on floating and leaching tests (Sulphide/oxides).

May 1, 2006

By Robert L. Rough

This report presents the results of an investigation by Federal Bureau of Mines engineers of water-injection projects in the northwestern Pennsylvania and southwestern New York area, where oil-producing wells have been converted from pumping to flowing. Data from 24 leases converted to flowing were collected and examined. Only 10 leases had information of significant scope for inclusion in the final analysis. The projects were classified in one of two categories. Group I consisted of leases operated to permit an evaluation of operational changes in terms of existing pressure differentials between injection and producing wells. Group II included remaining properties, for which enough information was available to justify an economic analysis but which did not have sufficient production data to support an engineering study because of radical changes in operational techniques. Variations in production and costs resulting from conversion to flowing were examined for production methods, well-spacing and completion techniques, and reservoir characteristics. Where water-injection rates were constant, oil production usually decreased rapidly at the time of conversion; production then increased slightly for 6 to 8 months before resuming a normal decline rate considerably below the estimated pumping rate. The abrupt decrease in production after conversion is indicative of lower pressure differentials between injection and producing wells, caused by the increased hydrostatic head in the producing wells.

Jan 1, 1960

By Garland Likins

High strain PDA testing has become common for verification of capacity of both driven and bored piles. It is equally applicable to Augered-Cast-in-Place (ACIP) Piles. It also evaluates other aspects of the installation such as integrity. The benefit of high strain dynamic test results for the relatively low cost of the tests compared to conventional static testing has resulted in widespread use. The method is described and specific procedures for testing ACIP piles are outlined. Example results demonstrate the application.

Jan 1, 2000

By A. J. Ardell, O. D. Sherby

The elevated-temperature steady-state creep behavior of polycrystalline a Zr was studied in vacuo under constant tensile stress. The experiments were conducted from 660° to 845°C over the stress range 870 to 5400 psi. The steady-state creep rate, is, of a Zr was found to be related to the applied stress, a, and temperature, T, by the equation where C is a constant. Two interpretations of the data are considered, each requiring different values of the parameters ß, Q, and . It is shown that this formula can be derived using Gilman's phenomeno logical equation relating dislocation velocity to the shear stress for the case where dislocation mobility is limited by the nucleation of kink motion. From the fundamental dependence of strain rate on dislocation velocity and the density of mobile dislocations, the factor exp(ßo) can be related to the stress dependence of the dislocation density, and Q to the energy of kink formation. The two interpretations considered are as follows: Case I—the parameters are adjusted so that the equation above describes the data over the entire range of stress and temperature, implying that creep is controlled exclusively by dislocation glide; Case IIthe parameters are adjusted to allow for the possibility that creep is diffusion-controlled at high stresses but glide-controlled at low stresses. For both cases the values of the parameters are within the spread permitted by the data. Factors favorable to the observation of the unusual stress -dependence of i, for a Zr are discussed and it is shown that the anomalously rapid rates of self-diffusion and the low modulus on the principal glide system are primarily responsible for the anomalous creep behavior. Metal-lograflhic observations are presented and discussed with reference to the overall creep behavior. PREVIOUS investigations of the creep behavior of a Zr have been conducted from room temperature to about 500C The results of these investigations are primarily of engineering significance because of the variety of conditions under which they were carried out, and the low testing temperatures employed. Little information is available concerning the fundamental nature of the elevated-temperature creep behavior of a Zr. This investigation of the creep behavior of a Zr above half the melting temperature (the melting temperature, T,, of a Zr is estimated to be about 1860"K was initiated because there are two significant anomalies of the physical properties of a Zr: a) the rate of self-diffusion in polycrystalline a Zr is anomalously rapid: b) both Young's modulus for polycrystalline a Zr and the shear modylus as-sociated with the prismatic slip system { 1010)( 1120) (the principal slip system in a Zr 7) have anomalously large temperature variations The importance of these quantities to the understanding of creep behavior has been demonstrated, and it was hoped that this investigation would provide a critical test of the predictions based upon the analysis of creep data for other pure metals. However, as the investigation progressed it became increasingly clear that the unusual creep behavior of a Zr could not be analyzed in a conventional manner. 1) EXPERIMENTAL EQUIPMENT AND PROCEDURES Two grades of zirconium, designated A and B, were used in this investigation. The analyses, as supplied by the vendors, are presented in Table I. Material A, with a nominal purity of 99.84 pct, was supplied by the Wah Chang Corp. in the form of cold-rolled sheet from which specimens were machined without further fabrication. Material B, with a nominal purity of 99.95 pct, was purchased from the Nuclear Materials and Equipment Corp. in the form of iodide crystal bar.

Jan 1, 1968

By P. Soupios

Seismic geophysical methods have long been used by geologists and geophysicists to delineate subsurface features. These techniques work because different types and strengths of soil and rock transmit energy at different velocities. The Crosshole-Downhole tests (CH-DH) and seismic refraction survey (RS) are among the most used methods in engineering applications to obtain the elastic properties of subsurface layers. As a result, seismic methods have evolved into a cost-effective tool for rapidly determining depth to bedrock in engineering and construction projects. The seismic methods are best suited to sediment thickness analysis, bedrock quality determination and detection of the presence of weaknesses in the bedrock before the erection of any civil engineering structures such as bridges, tunnels, dams and portals. Seismic methods are also useful in estimating the rippability of bedrock ahead of construction. These methods are particularly useful for large-scale projects that require a significant number of drill holes, resulting in a substantial investment of time and costs for drilling. The CH-DH and RS methods are typically comparable in total cost to drilling, but provide significantly more information in 2-D and 3-D and therefore reduce the likelihood of conceptually oversimplifying the subsurface conditions. The above mentioned methodologies were considered to be the most appropriate geophysical methods for investigating the shallow structure and the dynamic soil properties of the area where the Ilarionas Dam is scheduled to be constructed. The main target of this work was to prove the potential of geophysical methods in providing accurate information to the civil engineer and to obtain information on the dynamic soil and rock properties for earthquake design analyses for the dam construction. Specifically, nine refraction seismic profiles and three cross-hole-downhole seismic tests were implemented to determine the subsurface conditions of the study area. The tests determined the shear and compression wave velocity profiles versus depth and other crucial parameters such as Young and Rigidity modules. Furthermore, they allowed the detailed 2-D mapping (along several profiles of the study area) of the subsurface variation of the soil and rock dynamic moduli.

Jan 1, 2006

By Niles E. Grosvenor

One of the most important considerations in the efficient operation of an under¬ground mine is the haulage system. Often the determining factor between profit or loss is the quick removal of ore and waste from the working places to secondary and main-line haulage areas, and so on to the outside. Important, too, is moving supplies from the surface to the working faces so that the loading process can continue with little interruption. Men must he transported in a rapid but safe manner. It has been through the efficient use and generally the combination of mine cars, track, belt conveyors and rubber-tired haulage equipment that underground operations have been able to compete with the more popular strip or surface mining. As near-surface ore bodies are exhausted, underground haulage will play an expanding part in economically furnishing the world's needs for all types of minerals. The choice of underground haulage equipment, wherever possible, should be one that will give the smallest overall cost of ore removal during the life of the mine while meeting necessary safety requirements. The reader is referred to Sec. 12 for equipment such as scrapers and load-dump-¬haul units that perform loading as well as haulage duties. 14.1-MINE CARS AND TRACK NILES E. GROSVENOR Main-Line and Secondary Haulage-Many mines today use a combination of belt and rail haulage. Even if a- belt system is used to carry the product from the face to the surface, track is used to transport workmen and supplies. A track system, when properly installed, will provide interruption-free and safe haulage. Schrecengost 2 lists the following as major advantages of track haulage: 1. Safety in transporting men in and out of the mine in personnel cars. 2. Easy and rapid transportation of supervisory personnel. 3. A temporary shutdown occasioned by a roof fall or power failure along the haulage system will not shut down the production areas. 4. Quick availability of repair parts and supplies. 5. Large pieces of coal or rock can be handled without damage to the haulage equipment. 6. In areas where quality fluctuates noticeably, different cars may be separated out for special preparation. 7. Rock or equipment may be loaded and moved out of the mine without interference with the production or preparation of the coal. 14.1.1-MINE CARS Mine cars with steel bodies are used in all types of present-day mining. Wooden cars usually are more bulky and less resistant to wear and damage, but are more easily repaired. Regardless of the type of mine car selected, it is most practical to standardize on one type or make to simplify repairs and limit the amount of spare parts necessary to stock. Rigid-body flat-bottomed cars are simpler and usually lower than others of equal capacity. Advantages are: ease of loading because of the low sides, simplicity, cheapness and high ratio of capacity to weight. The disadvantages include the

Jan 1, 1973

By Morris B. J

Soil air samples taken from the top one metre of the soil profile, were measured for C02 and 02 using portable field analysers at a number of sites of known sulphide mineralisation in South Australia. Carbon dioxide anomalies were detected over actively oxidising sulphides during autumn and winter following recent rainfall. Anomalies were not detected where no oxidation was occurring, where seasonal conditions had been very dry, or where the sulphur content of the ore was low (

Jan 1, 1993

By Stewart R, Manson RA, Haig DW, Perembo RCB, Kruman B

Since the advent of plate tectonic modelling, the Ramu-Markham valley has been thought the site of a classical island-arc/conti- nent collision zone. In this interpretation the units south of the Markham Valley are held to be island are / micrcontinental mate- rial accreted to Australia and those north of the valley are thought to represent a separate Finisterre island-arc terrane. Recent remapping by the Geological Survey of Papua New Guinea shows: (1) there is no terrane boundary along the Ramu-Markham valley (2) the Finisterre Volcanics are probably part of either a fore-arc sequence or oceanic plateau obducted onto a microcontinent/ volcanic-arc composite terrane, accreted to the continental Australian plate. A new tectonic model is proposed for northern PNG and involves: (I) Eocene to Late Oligocene subduction below a microcontinent remote from Australia to produce the Sepik are and related intrusives, the Finisterre Volcanics (fore-arc or possible oce- anic plateau), together with the Alife blueschist. (2) obduction of the Sepik arc in Late Oligocene-Early Miocene times over the advancing Australian plate. This resulted in crustal melting, some of the products of which are the Mid- dle to Late Miocene Akuna and Bismarck intrusive complexes of the Maramuni arc. (3) obduction of the Finisterre Volcanics began in Early Pliocene times and continues today. (4) post-Middle Miocene mineralisation is the result of melting after obduction of the Sepik microcontinent.

Jan 1, 1997

"La mina Rublo disminuyó sus costos de explotación mediante la aplicación de pastillas de carburo ""continental"" en la preparación de barrenos en el lugar mismo de la mina. Por tal motivo, el presente texto señala los datos obtenidos con la preparación de barrenos y la economía obtenida con este sistema. La preparación de barrenos consiste en un corte de la cabeza del barreno a través del un previo calentamiento, para luego ser derivado en una nueva cabeza, de manera que la superficie plana tenga una conexión del conducto de agua y que la forma requerida para la cabeza de este barreno sea en forma de Chaflán, a través de la barra de soldadura. Una vez conectado el conducto de agua, se cortan los rebarbados del barreno en los extremos del canal para la pastilla, obteniendo el ángulo exacto del barreno para la perforación. Finalmente, el canal para la pastilla es limado y cubierto con soldadura, colocando la pastilla en la soldadura y revistiéndola nuevamente para ser fijada en el barreno. De otro lado, los factores económicos -en tanto mano de obra y el costo de materiales-, no representan mayor costo en los barrenos, obteniéndose un precio menor de US$ 2. 60, a diferencia de los barrenos anteriores. Así, la reconstrucción de los barrenos resulta fácil y barata a través del uso de pastillas de carburo de tungsteno ""Continental"", evitando problemas de roturas o de soldadura. "

Jul 20, 1959

By Eric D. Jamieson

"How well is the Canadian coal industry able to expand in the tough competition with other fuels in Canada and with other suppliers in the international, metallurgical and thermal coal trade? Coal production as a whole decreased between 1950and 1960 and, although there has been a tripling of production since then, underground production continued to decrease until 1975. This trend has been reversed to a certain extent as a result of the modernization of mines in Cape Breton, but in 1978 over 85% of coal production came from surface mining.Against this background, the paper reviews current Canadian mining operations as described in papers presented at the 1979 CIM Annual General Meeting. Conclusions are then drawn regarding some of the longer-term mining applications in relation to the latest coal demand forecast, which indicates a potential Canadian production requirement of 160 million tonnes per year by 2000. IntroductionThe Canadian 'coal industry is experiencing a period of expansion and a new record for production is set with each passing year. This growth pattern over the last IS years has been based on two main markets-the generation of electricity in Canada and the export of coking coal to Japan. Supply to those markets has entailed either the development of mining, coal preparation and transportation systems for the delivery of large volumes of products with predetermined specifications or the establishment of minesite plants designed specifically to suit the characteristics of the coal in the adjacent deposits (Fig. I).Coal is a low-value commodity in relation to its bulk, and the economics of coal use become progressively less attractive with increasing distance from the producing mine. The transportation component in the export trade and in the movement of western coal to Ontario is a major cost factor. In the latter case, it approaches the cost of coal produced at the mine. In addition, the .international competition among coking coal producers chasing diminishing markets in a worldwide steel recession as well as the competition from U.S. coals and other fuel s for Canadian thermal coal have introduced a tight set of parameters to govern mining practices in all parts of the country. Some appreciation of the required changes in mining techniques brought about by declining traditional markets and the rigorous demands of the new bulk markets can be gained by comparing production from surface and underground mines over the past 25 years (Fig . 2)."

Jan 1, 1980

By P. R. Cook

Thunder Bay Terminals' plant, now in operation, cost about 70 million dollars and was completed on time and under budget. The paper is the project manager's account of this accomplishment. From site selection through feasibility, engineering and construction to realization, he emphasizes the necessary philosophies for the control of time and money. The computer as a tool is discussed, as well as techniques for procurement.

Jan 1, 1979

By Steven J. Schatzel, Gerrit V. R. Goodman, Robert B. Krog, C. Özgen Karacan, Gabriel S. Esterhuizen

Although longwall mining productivity can far exceed that of room-and-pillar mining, the total methane emissions per extracted volume associated with longwall sections are generally higher than those for continuous miner or pillar removal sections. Increased face advance rates, increased productivities, increased panel sizes, and more extensive gate road developments have challenged existing designs for controlling methane on longwalls. Methane control research by the National Institute for Occupational Safety and Health (NIOSH) recently examined a number of practices designed to maintain concentrations in mine air within statutory limits and consistently below the lower explosive limit. These included a reservoir modeling approach to predict methane inflows in gate road entries. The outputs sug­gested that emission rates in the gate roads decreased with the use of shielding boreholes and increased degasification time. Also, mining perpendicular to the face cleats liberated more gas into the mine workings, emissions were almost a linear function of Langmuir pressure and volume, and emissions were inversely related to sorption time constant. Subsequent simulations predicted changes in methane drainage using in-seam boreholes. The results showed that longer degasification times resulted in lower face emission rates. Premining degasification produced more methane than that produced during panel extraction, a fact attributed to the already decreased methane content of the coalbed. This work concluded that longer premining degasification periods would be more advantageous to the operator. The industry trend toward increasing longwall face width can produce increased methane emissions from the face due to a higher volume of cut coal on the face conveyor. Two methods were used to estimate face methane levels on longer faces. In the first method, segmented methane data were extrapolated for greater face widths. The second method estimated emissions contributions from the shearer, face conveyor, panel belt, longwall face, and ribs, and summed these for wider panels. Permeability changes in the gob behind the longwall shields were estimated using a NIOSH-developed numerical model. The results showed that permeability was highest near the edges and corners of the gob.

Jan 3, 2008

By H. H. Kellogg, T. R. Ingraham

Three anhydrous zinc sulfates have been identified. They are: ZnSO,(a), stable below 1007°K; ZnS04(/3), stable above 1007OK; and ZnO.ZZnSO,. The decomposition pressure of each sulfate has been measured and the following relations calculated from the results: The measured data have been combined with the known themzodynamic properties of ZnS, ZnO, Zn, SO,, and SO, to yield univariant and bivariant phase diagrams for the system Zn-S-0. The application of these diagrams to problems of roasting zinc concentrates is discussed. PRESENT knowledge of the equilibrium chemistry of the system Zn-S:O, so essential to scientific control of zinc-blende roasting, is deficient in several respects. A basic sulfate of zinc has been reported by many investigators, but its composition is in doubt and its thermodynamic properties have not been measured. Our scanty knowledge of the properties of the normal sulfate at roasting temperatures is based on old and inexact studies. A crystal transformation in the normal sulfate, involving a sizable heat effect, has been noted by several investigators but has never been quantified. The studies reported herein were designed to fill these gaps in knowledge and to make possible a reasonably complete thermodynamic description of the system Zn-S-0 at roasting temperatures. The results make possible a far more exact understanding of zinc roasting chemistry than was hitherto possible. EXPERIMENTAL The principal experimental technique employed was the measurement of the total gas pressure developed from decomposition of either ZnSO, or ZnO2ZnS0, in a closed system. The apparatus employed was essentially the same as that described by Warner and lngrahaml and Flengas and tngraham.' The unusual feature is a flexible Pyrex bellows used to separate the reaction gas mixture (S03, SOz, and 02) from the mercury in the manometer and thus prevent corrosion of the mercury by SO3. The bellows operates without evidence of hysteresis and, barring accidents, may be used for several months. The response of the bellows varies from manometer to manometer, but is generally of the order of 0.6-cm displacement for a l-cm change in pressure. The response for all manometers has been linear over the range 0 to 1 atm. To prevent condensation and polymerization of sulfur trioxide, the bellows-manometer was maintained at 100.0" * 0.5" by a circulating bath of silicone oil. The connecting tubing between the manometer and the furnace was maintained at 100.0" * 0.2"* also, with a stirred air bath. The open end of the manometer was connected with a chamber which was maintained at a known pressure. The pressure could be varied so that readings of the height of the mercury column, measured with a cathetometer, could be made with both rising and falling mercury column. By using the average of the readings, any error due to sticking of the mercury column was minimized. The sample was placed in a 2-in.-long platinum boat formed into the shape of a half-cylinder. The sample was prepared as a fine powder and pressed against the inner wall of the platinum boat. A silica thermocouple well, covered with a platinum sleeve, was placed lengthwise along the center of the boat. The temperature of the sample was read on a calibrated Pt-10 pct Rh theirnocouple. The temperature profile of the furnace was constant within ± 0.2 C over the length of furnace occupied by the sample. The horizontal furnace used to contain the sample and the quartz reaction tube was electrically heated, with the control thermocouple placed 1/4 in. from the windings. A Brown Pyro-O-Vane temperature controller with a 3-sec response time was used to maintain the furnace temperature. Before beginning a run, the apparatus, including the bellows manometer, was thoroughly washed in sib with acid and distilled water to remove any

Jan 1, 1963

By Homer Turner

THE nature and comparative features of anthracite and bituminous coals have been discussed by the writer in two previous papers.1 Although this paper is offered as a further contribution to the subject, it seems desirable at the outset to repeat some of the descriptive matter of the early works in order to show the actual connection between various constituents of both coals and the new photomicrographs and other physical and chemical properties.

Jan 1, 1929

By Johnson RW, Rogerson R

New perceptions of the nature of volcanic hazards on Bougainville Island have resulted from a recent remapping of the geology of the island. Ignimbrites and calderas have been identified at six Quaternary centres (Emperor Range, Tore, Kunua, Billy Mitchell, Loloru, and Laluai), and large-scale explosive activity now must be identified as a significant volcanic hazard on the island. Billy Mitchell and Loloru volcanoes are identified as the most likely sites of future, major, explosive activity. Billy Mitchell was recognised formerly as an extinct volcano, but is now known to have produced major eruptions 370 and 918 years BP. Five ignimbrite units recognised at Loloru range in age from about 12 700 to 3200 years BP. Bagana is an active volcano in central Bougainville, but its explosive activity is relatively minor and does not significantly affect areas beyond the uninhabited area of the volcano itself. Balbi is the largest volcano on Bougainville and has an extensive geothermal area at its summit. It was thought to have been in eruption last in the early nineteenth century. However, 370 and 940 year BP plinian ashfalls from Billy Mitchell cover the central area of Balbi, so the latest significant activity from Balbi may have been at least 1000 years ago.

Jan 1, 1990

By Clarence Seyler

THE technical difficulties of cutting thin sections of coal for examination by transmitted light have hitherto restricted the investigation of the important subject of the microstructure of coal to the few possessed of the requisite skill and time. Apart from this, the method fails with anthracites and other coals rich in carbon, owing to the opacity of the material. Occasional use of the method of polishing a surface, with or without etching, has been made, but it was not until Winter1 published an account of his results that attention was seriously directed to the method. In May, 1923, a specimen of dull anthracite came into my hands; I tried Winter's method on it and the presence of megaspores and other vegetable structures became clearly visible. A preliminary notice was published by me;2 but I soon abandoned the use of Schulze's solution having found that a mixture of chromic and sulfuric acids gave far better results. In the meantime Turner and Randall, in America, had independently developed the method of flame etching, as applied to anthracite, with great success. I have spent a year studying the method of chromic etching, which gives excellent results with bituminous coals and cannels, as well as with anthracite. For anthracites, I have used the chromic method and Turner's method of flame etching, whichever was the more convenient or as a check one on the other. The polishing is done, according to metallurgical practice, by the use of a polishing machine and successively finer emery paper, followed by polishing on cloth moistened with a suspension of levigated green oxide of chromium, and a final rubbing on "selvyt" (a cotton velvet polishing cloth) moistened' with alcohol. The polished sample is examined by reflected light with a 2/3 and 1/6 in. objective. Bituminous coals usually show considerable structure, and even anthracites show it faintly in places. The sample is then etched by immersion in a boiling solution made by adding 10 c.c. of concentrated sulfuric acid to 30 c.c of a saturated solution of chromic acid; enough water is then added to dissolve

Jan 3, 1925

By G. Gabra

"A process of leaching niobium oxide from pyrochlore concentrate using hydrofluoric acid is described. Variables such as acid concentration, temperature, reaction time, solid/acid ratio, agitation speed and particle size are correlated to the recovery of niobium oxide.The relatively low activation energy (1,86 Kcal/mole) and the dependence of reaction rate on agitation suggest that the process is diffusion controlled. The optimum conditions for extracting niobium oxide from the leach solution, using either methyl isobutyl ketone or tributyl phosphate have been determined.IntroductionMost of the commercial production of niobium and tantalum has been derived from the treatment of columbite - tantalite minerals.In recent years (1960) , pyrochlore mineral has been found to be an alternate source of niobium . This mineral varies widely in composition and contains in addition to the main elements of calcium , sodium and niobium, some tantalum, fluorine, rare earth elements, titanium, alkali an d alkaline earth elements.It is well known that the province of Quebec possesses several pyrochlore niobium deposits totalling approximately 151 million ton s at an average 0.45% niobium oxide(1). One of the deposits, the St-Honor carbonatite, was brought into production by Niobec Inc. in 1976. Flotation o f this material produces a concentrate of about 60% Nb205(2).In view of an expanding niobium market in recent years and the presence of large niobium deposits in the province, a research and development program was initiated at the Centre de Recherches Miner ales to evaluate known processes for the separation of niobium and tantalum from each other as well as their purification . Some work has also been undertaken at the CRM to develop an improved extraction process. T his work will be the subject of further communication s."

Jan 1, 1985

By Budden J. R, Rhodes M. K

Bacterial oxidation technology was successfully applied in a mine site pilot plant for the treatment of refractory gold concentrates. The bacterial culture was proven capable of selectively breaking down the refractory sulphide minerals to release the gold. Gold extractions greater than 90 per cent were possible when oxidised concentrate was leached with cyanide solution. The pilot plant was designed using data scaled up from laboratory testing and sized for transport by standard vehicles. The bacterial culture used to break down the refractory gold-bearing mineral was a natural mixed culture able to withstand temperatures up to 55¦C, thus making the technology particularly suitable for use in Australian and in some North American gold mining regions. The pilot plant was operated at the mine site over a six month period. Performance of the bacterial oxidation technology under site conditions was as predicted from the laboratory testing. It was demonstrated that the culture was robust under normal site condi- tions and that the culture could withstand wide variations in the feed and the operating conditions, while still achieving satisfactory oxidation levels. The technology was able to be utilised by site operators and supervisors with minimum intervention. Design data for a commercial facility was collected for a number of different concentrate samples and a feasibility study completed. Estimated capital and operating cost have been obtained.

Jan 1, 1991