Search Documents

By Benedetto Corain

The production and dispersion of metal nanoclusters onto inorganic supports and amorphous carbon rest on well consolidated technologies belonging to the realm of industrial catalysis and of basic catalysis research (1). In spite of the existence of a variety of specific synthetic strategies, their very rationale relies on three main approaches i. e.: A: precursors of both the metal nanoparticles and of the relevant supports (or the support itself) are intimately mixed (even let to react) at ambient conditions and then thermo-reduced according to very controlled protocols (2); B: precursors of metal nanoclusters are let to be adsorbed onto suitable supports from the gas or liquid phase and subsequently thermally decomposed (3); C: metastable size-controlled metal nanoclusters are previously generated in a liquid medium and subsequently transferred onto pre-formed support particles (4). The production and dispersion of metal nanoclusters onto organic soluble supports is also a rather well documented academic praxis (5, 6, 7, 8) able to provide e.g. size-controlled Au0 nanoclusters of 4.4±1.7 nm (5). Our group started in 1997 developing (9) an innovative approach to the synthesis of metal nanoclusters dispersed inside insoluble, albeit accessible (see below) mechanically robust gel-type resins (10), which procedure was tested so far on palladium metal. Metal ions are previously dispersed upon ion-exchange inside of the polymer framework, followed by chemical reduction and by the aggregation of born metal atoms into nanoclusters, the size of which is templated (11, 12) by the three-dimensional intercommunicating meshes that build up the overall polymer framework (Figure 1).

Oct 1, 2003

By Stefan K. Schwank

The paper describes the two foundation techniques - mini piles and postgrouted bored piles. The mini pile system is presented with its design and installation parameters, especially the drilling technique. Two case histories demonstrate the application under extremely limited space and traffic conditions and the required modifications of the equipment. After the description of the postgrouted bored piles and its grouting technique, the paper gives a comparison of postgrouted piles and standard piles on a large basic test in Germany. The Brooklyn Queen's Expressway, N.Y., case history shows the application of this technique after redesign of the original proposal. 1. General Increasing requirements to improve existing foundations to carry additional loads and to increase the bearing capacity of bored piles leads to two new piling techniques: the mini-pile and the post grouted bored pile.

Jan 1, 1991

By J. R. Levin, E. J. Schelter

"We present some of our recent efforts in the development of predictive, directed oxidation chemistry of cerium(III) complexes under non-aqueous conditions. The electrochemistry of cerium(III)- alkali metal heterobimetallic aryloxide complexes is reported and compared with cerium aryloxide complexes that are kinetically stabilized by hydrogen bonding cations that span between the complexed aryloxide ligands. Comparative electrochemical measurements reveal differences between the heterobimetallic complexes and the hydrogen-bonded complexes.INTRODUCTIONThe rare earth elements comprise the lanthanides, La–Lu, and the element yttrium (Aspinall, 2001). Rare earth ores such as monazite, LnPO4, and bastnäsite, LnFCO3, typically bear mixtures of light rare earths: La–Sm while monazite, LnPO4, contains mixtures of heavy rare earths (Eu–Lu) (Cotton, 2006). Pure rare earth elements typically are isolated using a liquid-liquid separations process.(Bautista, 1995) The hydrometallurgy of these elements is a difficult problem because the separation factors between neighboring rare earths, which are predicated on the small differences in the sizes of the trivalent ions, are quite small (Cox, 1992). The element cerium, with its 4f1 electronic configuration in the trivalent state, is unique among the rare earth elements due to a relatively accessible 4f0 electronic configuration. The accessibility of the 4f0 configuration underlies the chemistry of cerium(IV), the only rare earth ion with molecular chemistry in the tetravalent oxidation state (Cotton, 2006). Cerium is trivially separated from mixtures of light rare earths by making use of its unique oxidation chemistry. In an effort to extend separations chemistry by oxidation reactions to other rare earth elements such as terbium and praseodymium, the solution electrochemistry of well-defined cerium complexes is of interest."

Jan 1, 2012

During the period 1979 thru 1982, Multi Mineral Corporation conducted a mining research program at the United States Department of the Interior's Bureau of Mines Oil Shale Mining Environmental Research Facility in the Central Piceance Creek Basin, Rio Blanco County, Colorado. The program consisted of mining, environmental and geotechnical research data and the results are described in this report.

Jan 1, 1983

By Harry W. Campbell

A mineral survey conducted by the U.S. Bureau of Mines in 1983 identified no mineral resources in the Beaver Meadows, Blind Horse Creek, Chute Mountain, Deep Creek/Battle Creek, and North Fork of Sun River Wilderness Study Areas (WSA's). A prospect east of the Beaver Meadows WSA has low potential for lead resources. Sand, gravel, and limestone occurrences are numerous in the WSA's; however, similar or better quality materials outside the areas are abundant and more accessible to potential markets. Impure coal and titaniferous-magnetite occurrences are near the WSA's, but are not known to occur within these areas. In 1983, there were 7,025 acres leased for oil and gas within the five WSA's; no current mining claims were in or near any of the WSA's. Evidence of mining activity was found at only one prospect in the WSA's. It is inside the Deep Creek/Battle Creek WSA; no resources or resource potential were identified at this prospect.

Jan 1, 1984

By R. L. Mazza

This final report on methods of reducing and controlling methane in coal mine gob areas indicates that vertical degas holes are beneficial to the mines of northern West Virginia working the Pittsburgh Coal. The USBM funded project involved the drilling and testing of eight vertical holes (four over longwall panels and four over room and pillar panels) based on a review of 13 previously in existence. Areas of observation included gas production history, flow entry profile, underground methane reductions, strata separations, and casing loads (accompanying subsidence). Observations led to the drilling of successful holes drilled short of the mine. Eleven gas production response to applied vacuum tests were conducted at nine degas holes under the contract. Significant production responses were recorded over longwall gobs.

Jan 1, 1977

By Ferron A. Olson

Natural bornite (Cu5FeS4) leached in ferric chloride or in sulfuric or hydrochloric acid solutions with oxygen showed several differences. In ferric chloride 80 of the copper was leached in two stages. The first (30 copper removal) requiring one minute was controlled by mixed kinetics (liquid ferric ion diffusion and chemical surface reaction). The second was controlled by formation of a surface sulfur layer and then diffusion through the sulfur. With oxygen in sulfuric acid reaction was slow and only the first stage was studied. Copper removal had an induction period. The bornite structure disappeared at 12% copper removal (also found with ferric chloride) and covellite formed on the surface with a species inside the particles having an x-ray structure similar to CuFeS2 but with composition Cu3FeS4 (also with ferric chloride). Copper removal was controlled by iron dissolution. Surface iron vacancies filled with Cu+ to give CuS while interior copper dissolution produced Cu3FeS4. Preliminary results with oxygen and hydrochloric acid showed 80% copper removal and sulfur as end products (similar to ferric chloride).

Jan 1, 1982

Tailings embankments can develop a high phreatic surface if the original design for the embankment does not include drainage facilities or if existing drainage facilities become ineffective. Subsequent raises can develop a seepage surface due to a high phreatic surface that can lead to stability problems. The U. S. Bureau of Mines amended contract J0100013 to initiate this study of horizontal drains in tailings embankments. This study developed a technique for determining the length of and spacing between parallel drains through the use of the finite element model UNSAT2. The analysis is based on the combined output of a vertical planar mesh and a horizontal planar mesh. The slot opening in the drain pipe and the length of the perforated section are determined from an analogy to water well design. The pipe diameter and gradient can be determined from Manning's equation. To the authors' knowledge, this is the first attempt at horizontal drain design using a finite element model. Additional research is recommended in this area.

Jan 1, 1982

By John R. Rhodes

The objective of this project was to investigate the feasibility of analytical techniques potentially capable of determination of Mg, Al, Si, S, Ca and Fe in 1 to 2 mg samples of respirable coal mine dust, in a total analysis time of not more than 10 minutes per sample, using equipment capable of being truck mounted for field-laboratory operation. It was not essential that the technique be non-destructive, but the chosen technique is, and this enables the analysis to be performed directly on the 37 mm diameter membrane filter on which the respirable dust sample is normally collected. The sensitivity requirements are therefore quoted in terms of the units of measurement, µg/cm2. The detection limit (3o of the background criterion) should be 0.5 µg/cm2 or less. The precision should be 5% or better, at concentrations above which the detection limit is not the determining factor.

Jan 1, 1972

By David Vergara Segura

Una empresa minera, en condiciones normales, maximiza su operación y minimiza sus pérdidas por tener operativos y equipos ligados a la producción. Por lo que es necesario la integración entre las áreas de la empresa, específicamente entre las de Mantenimiento y Logística. En este sentido, el presente texto señala la importancia del trabajo en equipo entre estas dos áreas, cuyo objetivo común es optimizar la gestión del activo que tiene un impacto significativo y directo en la producción. También se plantea bajo del esquema de una empresa minera ficticia, el desarrollo de estrategias conjuntas, y se define un modelo de gestión logístico, generador de ventaja competitiva, el cual está orientado a la optimización del uso del activo.

Sep 12, 2005

By P. L. Swanson, F. M. Boler

The U.S. Bureau of Mimes conducts research at the Galena Mine, Wallace, ID, with the aim of mitigating the effects of rock bursting. Destress blasting is commonly used as a stress control technique at the mine. A digital seismic array and an array of borehole pressure cells (BPC's) had been installed near the site of a stope undergoing mining and periodic destressing. The instrumentation was being monitored at the time of a destress blast of the 46-99 stope. No significant seismic events occurred coincident with the destress. However, the destress was followed by a 21/2-week period of increased seismic activity, including two damaging events on February 7, 1990, at 034500 (hour, minute, and second) and 122020 Pacific standard time. BPC measurements indicated coseismic ground pressure changes on the order of 200 to 300 kPa associated with the damaging events. Fault plane solutions and dislocation models established that stress changes induced by the event at 034500 may have been significant in promoting the occurrence of the event at 122020. Theoretical investigations suggest that applying knowledge of the existing stress field, an understanding of rock burst mechanics, and fracture mechanics principles can improve destress effectiveness.

Jan 1, 1993

By Gerald P. Scanlan

Control of the dust produced by continuous mining machines in coal mines is generally obtained by water sprays from fixed nozzles mounted on the frame of the machine in back of the cutting head. Mounting the nozzles on the rotating head of the machine closer to the coal cutting bits may improve the efficiency of dust suppression. To test this concept, respirable dust measurements were made during 39 regular production shifts in an underground mine using a Joy 11CM continuous miner. The equipment used, difficulties encountered, and measurements obtained are described.

Jan 1, 1974

This report summarizes the results of several field tests conducted by Collins for the Bureau of Mines under contract S0122076 and contract H0232056. The field projects represent a part of Collins continuing effort on a broad study of coal mine communications. These experiments analyze the propagation characteristics of radio signals in a working coal mine environment. The intent of the program is to provide basic propagation loss characteristics by which we may evaluate various approaches to an integrated mine communications system. The goal of such a system is to satisfy both operational and emergency communications needs in the mine.

Jan 1, 1974

To provide cooler air to miners working in hot areas of mines, particularly new deep hardrock mines. Approach Air supplied to hot working areas of mines is cooled by passing it through a series of water sprays. How It Works Water nozzles mounted inside a section of ventilation tubing release cooling sprays of water into the air being blown through the tube. The prototype of the water spray cooler consists of six evenly spaced water sprays located inside a 10-ft. long section of 16-inch-diameter fiberglass ventilation tubing. See diagram. This section of rigid tubing is installed into one of the positive pressure ventilation tubing lines that conduct fresh air into working stopes. The intake manifold to the six water sprays is connected to the mine?s cool water line, and the water valve on the manifold is opened. Warm ventilation air being supplied to the stope passes through the water sprays, and is cooled by the lower temperature water.

Jan 1, 1979

By Gerry Houlahan

The east span of the 3.5 km long SF-Oakland Bay Bridge is supported by different types of foundations along its span. Starting from the west, its first 460 m section comprising twin concrete box-girders is supported by sands and rock on Yerba Buena Island. A 620 m long steel suspension span then bridges a 25 m deep channel that is formed in sediments overlying rock. Twin concrete box girder structures, each 2.4 km long, complete the stretch over the remainder of San Francisco Bay to the engineered earth fill landing at its east end. For most of its length, the Skyway bridges water 3 to 10 m deep over soft surficial Young Bay Mud. The foundation types include spread footings with hold-downs, steel and concrete piles that are set in drilled rock sockets up to 3 m in diameter and 2.5 m diameter steel tubular piles driven to penetrations of up to 100 m. The design and construction-related considerations are presented. The different foundation types, influences of the site geology and earthquake demands on the substructures are discussed. The seismic motions of the bridge superstructures and substructures, as well as the depth-varying soil motions, influenced the foundation design. Together with performance-based design criteria, including post-earthquake footing displacement limits, these seismic demands influenced various aspects of the foundation design, including the use of battered and vertical piles.

Jan 1, 2005

Mining has long been an important activity for the people of Australia . The Aboriginals used rocks and minerals in their culture many thousand years before European settlement. It was not until 1840 that silver-lead ore was discovered in the Mount Lofty Ranges , and developed as Australia's first metalliferous mine. The mining industry contributes significantly to all aspects of the Australian economy, generating substantial employment opportunities, investment and income, export earnings and royalties for Governments. While the mining industry in South Australia is small by comparison with Western Australia, Queensland and New South Wales, it is nevertheless a very important industry in the State.   With the discovery of the world's third largest Cu-Au-U-Ag resource at Olympic Dam in 1975, the State saw a period of intense exploration activity through the early to mid-1980s. However, failure to locate additional world class deposits saw a dramatic reduction in exploration activity during the late 1980s. A perceived lack of prospectivity was compounded by the recognition that exploration for such deposits was neither easy nor inexpensive in South Australia because more than 80% of the State is masked by surficial sand and silt.

Jan 1, 1995

By Joseph L. Buckley

A total of 55 conveyor belt fire tests were conducted in the Bureau of Mines Fire Test Gallery, located at the Factory Mutual (FM) Fire Test Center West Glocester, R.I. The objectives of these tests were to: 1) determine the fire resistance and burning characteristics of various conveyor belt materials under simulated mine conditions; 2) provide essential data for designing a reliable bench-scale conveyor belt fire resistance test; and, 3) determine fire test conditions that will discriminate between low, moderate and high fire resistant materials. Belts, representative of those which mold he found in underground coal mines were examined under n umber of experimental conditions which included; ignition intensity; air flow rate; ratio of belt bright (h2) to overall gallery height (h1); exposure time; and, belt width. It was found that fire propagation could be achieved for some "fire resistant" belts (complying with the present Schedule 2G standard for approval) when exposed to an Ignition source of =6000 Btu/min for a 15-min period at a belt height ratio of 01.66. There appears to be a dependency of flame propagation on air flow rates and belt width, although the tests performed do not provide a quantitative trend. Recommendations are made for additional work to resolve some anomalous date and to fill voids in the rest program.

Jan 1, 1978

By Frank D. McGuirk

Underground coal mining is traditionally hazardous. Although many danger-prone human activities are now performed by mechanized equipment, this mechanization has itself brought new dangers to the underground mining industry, and the loss of life and limb has caused increased concern for mine safety. The 1969 Federal Coal Mine Health and Safety Act has precipitated a great deal of safety-related research on the part of the Government, industry, and private agencies. Much of this safety research has been focused on the new and varied man-machine interfaces caused by increased mechanization. Recent projects in this area have dealt with standardized controls, emergency shutdown capabilities (panic bars, strike plates, self-centering controls, "dead man" controls), and machine operator protective devices (fully enclosed cabs, canopies, side rails). There was a need for integration of the findings of current and past projects to move rapidly toward the smooth, orderly implementation of standardized operator work station designs for underground mining equipment.

Jan 1, 1975

By D. K. Caddel

Several problems exist with the present design of coveralls used by miners in low coal (seam height 48 inches or less). The back portion of the coveralls often tears when roof bolts or rough areas in the roof are hit. Movement in the shoulder area is restricted. Female low coal miners find it difficult to purchase coveralls that fit properly, and must remove both their hard hat and safety belt in order to urinate and defecate. The objective of this research was to design coveralls which would alleviate these problems. The following features were incorporated into the coveralls; padding in the upper back area to avoid tearing, an action pleat in the shoulders to increase mobility, an inseam zipper to more easily allow miners to perform their bodily functions, and reflective tape to increase visibi¬lity of the miner. A heavyweight denim fabric was used to increase warmth and durability of the coveralls. The coveralls were assessed K long four parameters (comfort, safety, worker productivity, and fabric suitability) using both an in-field assessment by low coal miners and simulation studies. The experimental coveralls proved superior to conventional coveralls along all four parameters. Work clothing sizes for female miners were developed.

Jan 1, 1982

By Robert H. Lambeth

There are no identified mineral resources in the Italian Peak RARE II areas, and there are no producing or developing mines within or adjacent to the study area. Several prospects are in RARE II area M-4945, Idaho, but none were found in the area I-1945, Montana. The Viola Mine (fig. 1, no. 15) vicinity and the Heart Mountain vicinity along the west and south borders, respectively, are being prospected. There has been no recorded production from mines within the study area, but between $2.5 million and $5.0 million worth of lead, silver, and zinc were produced in the adjacent Birch Creek district - dominantly from the Viola Mine - from 1882 to 1889 (Anderson and Wagner, 1944, p. 14). The Viola and other mines in that district are possibly, on basin-margin, carbonate-hosted, lead-silver-zinc deposits stratabound within the Devonian Jefferson Formation. Previous studies have considered them to be hydrothermal, replacement orebodies. Mineral occurrences in the Heart Mountain area are possibly black-shale hosted uranium-vanadium deposits in the Mississippian-Devonian McGowan Creek Formation or perhaps the underlying Devonian Three Forks Formation. The Jefferson and McGowan Creek Formations underlie many scattered segments of the study area. The deposits and occurrence; are not sufficiently exposed to determine tonnage and grade, but sampling indicated moderate resource potential at two properties just outside the study area, the Viola Mine and the Elkhorn Group (fig. 1, no. 33). Local residents indicated there are several thousand tons of zinc-bearing resource; at the Viola line. A 23-ft (70-m) drill hole intercept near Heart Mountain et the Elkhorn Group adjacent to the stuny area contained 0.15 percent uranium oxide

Jan 1, 1983