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RAYMOND M. Howe (author's reply to discussion*).-Dr. Unger states that magnesite will hardly supersede dolomite in fettling after a heat; that it is hard to believe a slag composed of oxide of iron containing about 6 per cent. of phosphorus is the active corroding, agent in a boil in a furnace; and that boiling cannot be said to be the result of the chemical action of a high-phosphorus slag on a basic bottom. These are well-established facts that no one would venture to question. The authors were misinterpreted in the statement that "in the summary, it is claimed that magnesite low in lime, or of greatest purity, ranks first in resistance to slaking," etc. On the contrary, the position has been taken throughout that while a low lime content is advantageous, the presence of several per cent. of iron oxide (an impurity), is necessary in order to confer the proper bonding and sintering properties in dead-burned grain magnesite to be used for furnace hearths. We cannot subscribe to the view that pure magnesia is no better fitted for a refractory than pure lime,' nor that the pure natural varieties of magnesite; such as Grecian or Washington, must necessarily be burned with silica and oxide of iron to produce a satisfactory material. On a small scale, pure magnesia has been satisfactorily used as a refractory in the form of crucibles. In the production of dead-burned grain magnesite from the Grecian or Washington mineral, iron oxide is added but the addition of silica is neither customary nor desirable. It is possible to manufacture brick of good quality from both the Grecian and the Washington material without adding either silica or iron oxide, providing they are burned at a sufficiently high temperature. This is regularly done on a commercial scale both in America and abroad when brick of. exceptionally high refractoriness or special purity are desired. The following analysis is of an English brick of Grecian magnesite which is extremely low in all impurities.1

Jan 6, 1919

By G. G. Gunther, C. L. Boeke

THE zinc deleading processes at the Parral and Santa Barbara mills are described separately to provide a basis for comparison. Although the two procedures are fundamentally alike, there are some differences in application to meet specific conditions. The Asarco mill at Parral in the State of Chihuahua is a flotation plant treating 1450 metric tons- per day of complex sulphide copper-lead-zinc ores. In general, the procedure used for selective separation of the minerals into a copper, a lead, and a zinc concentrate follows the usual practice. First, a bulk copper-lead concentrate is floated and then separated into a final copper and a final lead concentrate by the sulphurous acid process. A small tonnage of high grade gravity lead concentrate is tabled from the bulk copper-lead cleaner tailing before it is reground so as to avoid undesirable over-grinding and sliming of this portion of the lead, mineral. Next, a zinc concentrate is floated from the lead rougher tailing and, as described later, is separated into a final lead product and a final zinc concentrate. Finally, the zinc rougher tailing receives a strong scavenger float to remove all recoverable middling values for regrinding, and return to the flotation circuits. The slime is separated from the scavenger flotation product, and only the sand portion goes to the regrind section. The minerals in the separated slime are extremely resistant to all methods of selective separation and pose one of the major problems awaiting solution. Nevertheless, the slime shows a profit when mixed with either the lead or the zinc concentrate, except when metal prices are very low, so it is accepted as a final product for lack of a more profitable method of handling it. In contrast, the minerals in the reground sands of the

Jan 1, 1952

By Ronald F. Ayers

The basic research for this study was conducted by Battelle's Columbus Laboratories in 1974. The high-sulfur content of coal threatens to erode its competitive position in the future. The impact of sulfur removal on final costs of eastern interior coal lies at the very heart of this market analysis. An extensive market survey was conducted that considered both traditional coal markets as well as anticipated future markets. Competition for coal from this province considers low-sulfur Western coal, nu- clear power, international oil and coal trade, as well as Appalachian coal producers. Based on projections of future energy consumption under several scenarios, a comprehensive market forecast for eastern interior coal was made to 2040. The study upon which this paper is based was completed by Battelle's Columbus Laboratories for the U.S. Army Corps of Engineers in 1974. It is but part of an overall effort by the Corps to evaluate the costs and benefits to the nation of waterway improvements. This study is primarily concerned with future coal markets for production from those counties near the Wabash River in the heart of the Eastern Interior Province. An objective here is to consider a most pessimistic energy (and hence, coal) demand for planning purposes.

Jan 1, 1978

By P. Pietrokowsky

RECENTLY a comprehensive investigation of the various sigma binary alloys was published by Duwez and Baen.1 It was shown that the following conditions are necessary for the formation of the sigma phase: (1) the difference in atomic diameters of the two alloying metals must not be more than about 8 pct; (2) of the two elements which form sigma, one must exhibit a body-centered cubic structure while the second metal must be face-centered cubic, at least in one of its allotropic forms. In addition, a tetragonal unit cell was proposed and powder patterns of six sigma phases were indexed for d spacings greater than 1.640 kx. Since the indexing, based on tetragonal symmetry, led to only fair agreement, the possibility of sigma being orthorhombic was investigated. Various methods for indexing orthorhombic powder patterns are de- scribed in the literature.' The method used in this investigation was a graphical examination of the differences in values of sin' 9 for the adjacent lines of the powder diffraction pattern. This method led to a complete indexing of the Cr-Co (60-40) pattern. Because of the strong similarity between the various sigma alloys, it was then possible to assign indexes to the patterns of Fe-Cr (50-50), Fe-Cr-Mo (30-30-40), Fe-V (50-50), Co-V (50-50), and Ni-V (50-50). The values of sin' 9 and indexes of the six sigma alloys, together with visually estimated intensities, are presented in table 1. In general, the similitude between the six patterns is quite good. For spacings greater than 1.75 kx a few differences are noticeable. In the Ni-V pattern, no (320) exists and the two strong lines (030) and (031) are separated by only two lines of lower intensity, unlike any of the other sigma patterns. However, very little is known about the Ni-V phase diagram and it is possible that the equal atomic percentage composition in this system lies in a two-phase region. At lower spacings there is a close analogy between the patterns. The planes

Jan 1, 1951

By Burton H. Boyum

GREATER depth of exploration drill holes and increasing cost of drilling have been principal factors in reviving interest on the Marquette Iron Range in controlled directional drill-hole deflection. This deflection is obtained by the application of the Hall-Row wedging technique. Modifications were made in the technique and equipment in the effort to simplify and strengthen the procedure. The practice is similar in many respects to the oil well type of deflection with a whipstock.

Jan 1, 1947

By R. R. Hartman, W. B. Agocs

In the course of a return flight from Olympia, Wash., to Laramie, Wyo., an airborne magnetometer profile was recorded continuously. The level of flight was controlled at barometric levels along segments of the flight. Barometric altitude was changed from 3000 ft to a maximum of 12,000 ft above mean sea level to take care of topographic variations. Terrain clearance varied from 800 to 7300 ft. Horizontal positions were obtained by recording and tying to cities, towns, airports, river crossings, and other landmarks in the course of the flight. Figs. 1-6 show the course of the flight and the general geologic and tectonic features traversed. The flight line begins south of Olympia, Wash., and proceeds south across the Puget-Willemette depression to the Columbia River. Thence it proceeds eastward along the Washington-Oregon border across the Cascade Mts. and lava flows and the Umatilla basin to Pendleton, Ore. From Pendleton it traverses the Blue Mts. uplift of Oregon in a southeasterly direction, and then to the Boise basin of southwestern Idaho. The flight line swings in an easterly direction as it passes over the Snake River downwarp to the south of the Idaho batholith. It then passes over the northern portion of the Great Basin and the heavily overthrust area at the intersection of the Utah, Idaho, and Wyoming borders. The flight then assumes an easterly course to cross the series of basins and uplifts of southern Wyoming and terminates near the western flank of the Laramie uplift.

Dec 1, 1956

By B. S. Tani, R. V. Schablaske, M. G. Chasanov

MEASUREMENTS of the solubility of scandium in liquid cadmium from 349" to 606°C by Chasanov, Hunt, Johnson, and eder' led to the isolation and characterization of the intermetallic compound ScCQ. The solid phase found in equilibrium with a saturated solution of scandium in liquid cadmium above 422°C is ScCQ. The equilibrium solid phase below this temperature has not as yet been characterized. Hexagonal needles of ScCG were isolated from a 5 wt pct Sc alloy which had been ice-quenched from 500°C. Free cadmium was leached away from the intermetallic with saturated ammonium nitrate solution. The concentration of cadmium in successive leaches was followed polarographically and the leaching process was terminated when the rate of cadmium dissolution decreased markedly. Chemical analysis of the intermetallic thus isolated is as follows: 11.5 wt pct Sc and 88.3 wt pct Cd. The composition of ScCQ is 11.8 wt pct Sc and 88.2 wt pct Cd. X-ray diffraction powder photographs of ScCds taken in a 114.6-mm Debye-Scherrer camera with CuKa, radiation can be indexed on the basis of a hexagonal nit cell. Lattice coonstants are a. = 6.330 ± 0.001A to 6.324 i 0.001A and co = 4.853 i 0.001A. The a0 has a slight range with the lower value seemingly associated with the cadmium-rich terminus of the phase. With eight atoms in the unit cell the calculated intermetallic density is 7.54 g per cu cm; the density as determined by a liquid-displacement method is 7.7 g per cu cm. Powder-diffraction data for ScCQ are recorded in Table I. Stoichiometry, symmetry, unit-cell dimensions, and the number of atoms per unit cell indicate the MgsCd (D019) type structure for ScCQ; space group is D,&-P6,/mmc. Atomic coordinates are:

Jan 1, 1964

By P. K. Kaiser, C. Mackay

A circular shaft with a diameter of 6m was excavated by the conventional drilling and blasting method to a depth of 235m through 60m of glacial till, 1 Om of water bearing basal sand, 1 1 Om of clay shale (Bearpaw Formation) and finally a strata of coal, mudstone, siltstone and sandstone (Oldman Formation). The lined shaft was instrumented at three levels by multipoint extensometers to determine the displacement field near the shaft bottom, embedment strain gauges to measure the strains in the liner and IRAD-stress change gauges to observe the radial and tangential stress changes in the rock mass. The data from these gauges were used to determine the in situ stress field. An attempt to measure in situ stresses by overcoring was also made at a higher elevation. The performance of the shaft and its support was then evaluated by use of the "Convergence-Confinement Method". For this purpose the measurements of stress changes and displacements were combined to determine by extrapolation the displacements ahead of the shaft and after the liner installation. The convergence curves calculated in this fashion were then used to evaluate the performance of the cast-in-place concrete liner and of an alternate shotcrete shaft support system.

Jan 1, 1983

By Paul Weir

DURING the past decade, methods of producing bituminous coal in the State of Illinois, which ranks third in production among the states in which bituminous coal is mined, have undergone great changes. From less than one million tons in 1923, the strip-mine production has gradually increased to a high of 11,725,870 tons in 1937. From a negligible amount prior to 1927, the amount of coal mechanically loaded underground had increased to a high of 28,374,362 tons in 1937. The amount manually loaded in 1937 reached a low of 12,332,023 tons. In this same year, this state ranked first in strip-mine production, also in mechanically loaded production. For this reason a study of the influence of mechanization on location of production in Illinois may be helpful in anticipating what may happen in other producing states. The reason for the changes in methods lies in the differences in costs of production. The Bureau of Research and Statistics of the National Bituminous Coal Commission has made public the following costs of pro-duction by various methods in the State of Illinois (district 10) for the last nine months of 1937: all mines, $1.7602 per ton; strip mines, $1.4319; mechanical loading mines, $1.7457; hand loading mines, $2.1793; all underground mines, $1.8703. These are weighted averages for the entire district. Inasmuch as production in 1937 was reported from 58 counties scattered over two-thirds of the area of the state and from five different seams varying in thickness from less than 3 ft. to as much as 12 ft., it is apparent that the location of production must be influenced by the extent of mechanization possible in the various producing counties.

Jan 1, 1939

Discussion of the paper of ALBERT SAUVEUR, presented at the Pittsburgh meeting, October, 1914, and printed in Bulletin No. 93, September, 1914, pp. 2439 to 2449 G. K. BURGESS, Washington, D. C.-This very instructive contribution by Professor Sauveur to our knowledge of that puzzling substance, Hadfield's manganese steel, should not only be read in connection with the paper of Messrs. Hopkinson and Hadfield referred to by Professor Sauveur (Bulletin No. 87, pp. 513 to 530, March, 1914); but one should also have in mind, as throwing much additional light upon the questions raised, two papers recently presented before the Iron and Steel Institute, the one by Sir Robert Hadfield (Journal of the Iron and Steel Institute No. II, 1913) on Heating and Cooling Curves of Manganese Steel, the other by Messrs. Hadfield and Hopkinson (ibid., No. I, 1914) treating of the Magnetic and Mechanical Properties of Manganese Steel. We then have brought together for this substance, the thermal, magnetic, and mechanical properties as well as the resulting microstructure, for the definite heat treatments described, and in particular after long annealing between 500° and 700° C. Sir Robert Hadfield and Professor Hopkinson see in the properties found for manganese steel (of C = 1.25 and Mn = 12.5 per cent.) a demonstration of the untenableness of the allotropic theory of iron, whereas Professor Sauveur reaches the contrary conclusion, that some of the facts observed can be explained only in terms of the existence of beta iron in steel of this composition. There is another possible hypothesis: namely, that these several series of experiments shed no light on the subject of the allotropy of iron, or at least as regards the existence of beta iron. However heretical it may sound, I am inclined to this last belief.

Jan 4, 1915

By Charles B. Dudley

In view of various papers and discussion.;, at recent meetings of the Institute, upon testing, methods of testing, inspectors, inspection and specifications, it has occurred to me that my experience of some fifteen years, in the making and enforcement of specifications, in connection with the Motive Power Department of the Pennsylvania Railroad, might give some value to the few suggestions offered in this paper. There is friction, not to say antagonism, between the producers and the consumers of structural materials. On the one hand, the producers complain of the severity of inspection, or the lack of knowledge and want of good judgment on the part of inspectors, and, indeed, have gone so far as to suggest the abolition of the whole scheme of inspecting and testing materials. On the other hand, the consumers are, apparently, more and more relying on specifications

Jan 1, 1893

By Warren Weaver

Some of the advantages of the inductive method of electrical prospecting were emphasized in a paper by Dr. Max Mason. Since this emphasis was misunderstood by some to indicate a too exclusive interest in inductive methods, we are especially happy to help correct this impression by reporting on some of our work on surface potential methods. Earth Currents and Surface Potentials When two electrodes, A and B, are placed on the surface of the ground a distance d apart, and a 100-volt battery is connected across the elec- trodes, current flows from the positive electrode A to the negative electrode B. The current does not pass directly from A to B along the straight line joining these two points. In fact, a negligible amount of the total current chooses this direct path, and the flow actually takes place

Jan 1, 1929

By A. H. Miller

THIS survey is one of the more recent tests of geophysical methods of prospecting by the Dominion Observatory and the Geological Survey of Canada, of which the purpose is to find out what application such methods may have to geological problems in Canada. The Malagash salt deposit lies on the north shore of Nova Scotia about 40 miles east of the New Brunswick boundary, and forms a part of faulted and folded Carboniferous strata. The salt beds are exposed only in the mine workings, which are about 1000 ft. deep and at one place extend for 1000 ft. along the strike. Lack of rock exposures, complicated folds, and faults make it impossible to predict the location of salt away from the mine. A survey of an area in the vicinity of the mine was therefore undertaken to find out whether the salt could be located by the torsion balance and whether its extension from the mine workings could be traced. As the gravitational effects at Malagash may be fairly typical of those at other concealed salt deposits in the Carboniferous rocks of the Maritime Provinces of. Canada, the survey has a direct bearing on prospecting for other deposits. The survey was made in 1934 by A. H. Miller in collaboration with Dr. W. A. Bell, of the Geological Survey of Canada.. Observations began on June 15 and were completed four months later, on Oct. 15. Definite gravitational effects including a lowering of gravity were observed over the deposit. The survey also disclosed one other area of low gravity east of the mine but whether this area is underlain by a large body of salt is not yet established.

Jan 1, 1936

By John M. Warde, Raymond M. Richardson

What to do with atomic wastes is one of the major problems of the atomic age. Unlike other waste materials, these cannot be burned, evaporated, or filtered, and the transfer of radioactive material from one physical or chemical state to another is not a complete answer, because only time diminishes radioactivity. Rate of decay of radioactive materials varies from a few seconds to several thousand years and cannot be altered by known economic methods. At present the Atomic Energy Commission and its contractors are coping with the situation adequately. Intensification of private development of atomic power could, however, pose problems in the nation's nuclear energy program.

Jan 5, 1955

By R. H. Richards

The spitzlutte, as described by Rittinger, is an instrument by which saud is sorted in a continual upward-flowing stream of water. Its usual firm is that of a pointed box, placed with the point downward, the box receiving. its feed of sand and water on one side and discharging its tailings on the other. The sorted product or concentration is discharged at the bottom, at the apex of the box, through which it falls against an upward current of water, which current serves to effect the sorting and separation. To make this exposure to the quicksand condition still more effective, an inverted dam is placed across the spitzlutte, which forces the sand in its passage from the feed side to the discharge to pass clown into the more active portion of the upward-flowing current of water. In the form adopted for small tests in the mining laboratory of the Massachusetts Institute of Technology (see accompaaying sketch) the feed is'throogh a central funnel instead of being at the side, and the apex of this funnel, extending down nearly to the apex of the cone, talks the place of the inverted dam in the large spitzlutte. To keep the experiment perfectly under control a bulb or bottle is attached by a rubber connecting-tube to receive the concentrations, and between this bottle and the apex of the spitzlutte is placed a glass tube of conical form, with a side tube for' the admission of water. By regulating the admission of water through this tube the concentration may be allowed to go down into the bulb as fast or as slowly as the richness of the ore seem.; to demand. This spitzlutte may be used on products that have been previously sized to take out the heavy mineral. As an example of this a test was made upon a sample of ore where the galena, blende, and quartz were much mixed up, but separated fairly when crushed. The sample of ore was from Newburyport, and assayed 16.61) per cent. lead.. After sizing through a series of sieves the ore yielded conceutrations and tailings to the spitzlutte as follows :

Jan 1, 1881

By E. A. Rychkun

The transition from Larger word type computers to the small byte oriented micro-computers has allowed specialized software to be placed directly under the control of the people requiring solutions. In addition, with the advent of interactive graphics, many complex geological and mining engineering problems can be solved graphically, thereby further forcing obsolescence on larger computers. Although the industry has not yet caught on or taken full advantage of this fact, some companies have begun to move in this direction. One such case is the Coal Evaluation System presently in use at Manalta Coal Ltd. in Calgary, Alberta. This system, designed to allow interactive analysis of simple to complex coal deposits, leads one from geophysical/core log data, to geological modelling, strip or open pit design, equipment selection, cost estimation, and cash flow analysis. The micro-computer system used is portable, stands alone, and costs less than $120,000. It is the purpose of this paper to present the coal evaluation system and its development methodology which maximizes the use of the newest computer technology. Further, in order to illustrate the practical application of the system, an example application based upon a large operating coal mine will be discussed.

Jan 1, 1983

By Hadyn W. J. Wren

The practical experience obtained from designing and commissioning of fully controlled coal preparation plants, using centralised mini computers is discussed. The importance of defining a workable operating philosophy is highlighted with particular reference to the problems associated with trying to achieve a total 'hands off' concept. These experiences with a centralised computer controlled system have led to a deeper understanding of the interaction between the operation and the control system and the role of local control and management information within the overall control philosophy of a highly automated process plant. The utilisation of an extensive fully distributed microprocessor control system with over 6500 digital and analogue signals split into six autonomous areas with a supervisory system to provide operator interface is described. The important aspects of project definition and design needs are outlined with particular regard for achieving maximum efficiency with minimum complexity. Views of future trends are offered, based on the experience of both centralised computer and distributed processor systems.

Jan 1, 1984

By Milton Lissberger

MILTON L. LISSBERGER, ? New York, N. Y.-Solder is a mechanical mixture of tin and lead, a fact which is susceptible of very simple demonstration. A bar of solder of a grade even as low as 30 per cent. tin and 70 per cent. lead, passed through a buffing machine, will show a surface practically identical with that of a bar of second-quality or reclaimed tin. The buffings, on chemical analysis, will prove to be almost pure lead. According to the best practice, solder is made in the following manner. Virgin pig lead is first melted, and when it is thoroughly liquefied, virgin pig tin is added, together with a small amount of flux; the latter is for the purpose of bringing to the surface the so-called "liver," consisting of impurities that may have remained in either the lead or the tin as a result of incomplete refining. The combined material, when completely liquid, is thoroughly stirred for some hours, and is then cast into small pigs. Just before casting, and continuously during this operation, the molten metal yields dross, consisting largely of the oxides of lead and tin; this should be carefully skimmed off. After the pigs have cooled, they are taken to a smaller kettle, remelted, and cast into the desired shape for use; or if wires, ribbons, etc., are to be made, the solder is cast into slugs suitable for extrusion and rolling. During this second operation, the skimming of dross should be even more carefully done than at first. Hand mixing has proved to be the only reliable method for the production of the best quality of solder, irrespective of its percentages of lead and tin. The best quality of solder is not necessarily that which contains the highest percentage of tin, but rather is that composition which performs best on the required piece of work. In order to produce

Jan 12, 1918

Joseph HartshoRnE, Pottstown, Pa.: I have read Professor Akerman's valuable paper with great interest. Few of the present generation of American steel metallurgists are aware of the very important part taken by Swedish engineers in the successful development of the Bessemer proeess, and I am afraid some of the older ones have forgotten it. Certainly, I think, most of us would have said that Terre Noire was the first to introduce the use of metal direct from the blast-furnace. It is very well, therefore, that honor should be given to whom honor is due. I can speak from personal experience upon one part only of Prof. Akerman's paper; namely, the effect of the temperature at which the molten metal is cast upon the quality of the finished steel. In a general way I have, of course, known for a long time that the

Jan 1, 1894

By W. A. Wissler, B. E. Field

COBALT is a silvery white metal with a slight bluish cast. It strongly resembles nickel in its appearance and properties, notably its resistance to corrosion, although its alloys with other metals differ decidedly in their properties from those of nickel. The name "cobalt" was derived from the German Kobold, meaning goblin, and this came to be applied to the cobalt minerals which, although they resembled ores, did not readily yield metal when smelted by the primitive processes available in the Middle Ages. Cobalt minerals were used as pigments by potters and glass- workers before the Christian era. Cobalt blue glass was found in the tombs of the Egyptians and in the ruins of Troy, and many colors used by the ancient Greeks and Romans contained cobalt. The ancients were entirely unaware that the colors they used were caused by cobalt and the metal itself was not isolated until about the middle of the eighteenth century, by Brandt, although the preparation of cobalt compounds had been carried on in a small way ever since the opening of the silver-cobalt deposits at Schneeberg, Germany, in 1470. By the middle of the nineteenth century, several firms in England were engaged in the refining of cobalt products and the consumption of cobalt oxide in the British ceramic industry in the year 1866 had reached 67,000 lb. COBALT METAL AS A NEW RAW MATERIAL IN ALLOY TECHNOLOGY Nickel and cobalt are usually found together and, although the relative amounts of the two have varied greatly in different ores, those

Jan 1, 1953