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By Y L. Ma, M Chen, W Bruckard

With the extensive exploitation and gradual depletion of high-grade copper reserves, the mining industry is paying more and more attention to the hydrometallurgical extraction of copper from lowgrade and arsenic bearing copper ores. Hydrometallurgical processing, such as heap leaching, column leaching and bioleaching, provide a viable alternative to the traditional pyrometallurgy due to its harmony with the environment, moderate capital investment, and low operating costs. However, the slow leaching kinetics of enargite (Cu3AsS4) and chalcopyrite (CuFeS2) remain problematic for commercial leaching practice. The formation mechanism and the nature of the passivating layers during leaching is still a matter of debate in hydrometallurgical research. In this study, the dissolution mechanism of enargite and chalcopyrite in sulfuric acid solution was investigated using a range of electrochemical and spectroscopic analysis methods. Electrochemical oxidation of enargite demonstrated an obvious passivation region from 500 to 750 mV (Ag/AgCl). The formed passivation film was found a n-type semiconductor behaviour, which is different from the original enargite with a p-type behaviour. The results of X-ray photoelectron spectroscopy (XPS) suggested that a nonstoichiometric film Cu(3−x)As(1−y)S4 (x>>y) accumulated on the electrode surface, which accounted for the obvious decrease in current density in the passive potential region. For chalcopyrite, three important potentials of 550, 680 and 730 mV which are related to the formation and dissolution of passivation film were observed based on the cyclic voltammetry (CV) and potentiodynamic polarisation. Raman and X-ray absorption near edge structure (XANES) spectra studies of the chalcopyrite electrodes after being treated under these three potentials indicated a metal-deficient sulfide of Cu1−xFe1−yS2 (y>>x) might be responsible for the passivation phenomenon. Hence, it is concluded that the passivation of enargite and chalcopyrite are similar which are caused by metaldeficient sulfide surfaces although the compositions of the metal-deficient sulfide are different.

Aug 24, 2022

By Y Tang, G Si

The analysis of rock fragment sizes plays a pivotal role in various stages of geotechnical and mining engineering. Traditional case-based methods often falter in addressing the variability in rock fragment images due to fluctuating geological conditions and imaging environments. To counter this challenge, AI-based models necessitate training on expansive and diverse data sets, encompassing a wide range of conditions and fragment types. However, the creation of such data sets is often hampered by financial and environmental constraints. This paper introduces a novel approach for rock fragment recognition, which leverages the power of AI for data augmentation, automated annotation and prediction. The methodology integrates three key components: Style-Based Generator Architecture for Generative Adversarial Networks (StyleGAN) for data augmentation, the Segment Anything Model (SAM) for automated annotation, and the multiscale version of you only look once (YOLO-MS) real-time instance segmentation model. The proposed method begins by training a new StyleGAN model using the original data set. It then delves into exploring the latent vectors of different rock fragment images to generate specific ‘style representations’. These latent vectors form the foundational elements of each image in a high-dimensional space, encapsulating critical features such as size, shape, texture, and colour variations. The next step involves conducting quality checks on the generated images to ensure their realism and suitability as training data. Subsequently, the augmented image set is annotated using modified SAM module, followed by training the YOLO-MS real-time instance segmentation model. The performance of this model, trained on the augmented data set, is compared with a model trained on the original data set, particularly in terms of generalisation abilities in new scenarios. The results exhibit a significant enhancement in accuracy, robustness, and generalisability of the model trained on the augmented data set, underscoring the potential of StyleGAN as a powerful tool for data augmentation in geotechnical engineering image analysis.

Sep 1, 2024

By T Higuchi, K Fukada, K Takehara, Y Iwami, S Fujiwara

Following the Paris Agreement adopted in 2015 and the SDGs, reduction of CO2 emissions has been taken up as an issue worldwide, and the steel industry, which has a particularly large emission, is required to significantly reduce it. Most of the CO2 generated in the steel industry is generated from the ironmaking process, due to the use of coke and its raw material coal in the ironmaking process. JFE Steel Corporation has been considering the use of hydrocarbon-based gaseous fuels and liquid fuels as a partial alternative to coke breeze used in the sintering process since 2006, immediately after the Kyoto Protocol came into effect in 2005. In a laboratory study, a pot test was used to investigate the effect of the type of fuel, its amount and its injection method on the heat pattern in sinter bed. As a result, the authors developed a technology, in which a predetermined amount of gas fuel or liquid fuel was injected from the surface of sintering bed to extend the holding time of 1200°C or higher at which liquid phase sintering occurs in the layer, to improve the sinter strength while reducing the amount of coke breeze. The authors succeeded in putting this technology to practical use using hydrocarbon-based gas fuel in 2009 and achieved a maximum annual reduction of 60 000 tons of CO2 per sintering machine. In this report, the authors introduce the results of laboratory studies on the use of various energy sources, the practical application of the technology for injecting hydrocarbon-based gaseous fuel into the sintering machine, and the operational results.

Nov 8, 2021

By M Simanjuntak, A M. Supomo

PT Freeport IndonesiaÆs copper/gold operation disposes of approximately 222 000 dry metric tonnes of tailings per day via two thickeners. Reduction of the flocculant dosage rates in each of the tailing thickeners has been achieved with the installation of Clarometers«, modifications to the existing operating DCS control strategy and a change in plant flocculant. This has reduced the flocculant consumption rate in the last twelve months by approximately 20 per cent. It has also highlighted the disparity in the settling rates of the two thickeners. Collaborative efforts between Cytec technical site engineers and Freeport operational personnel have made possible the overall gains achieved in the tailings thickener optimisation.

Jan 1, 2003

By R O. James

The usual focus of papers on fatty acid collector action in non-sulfide flotation is on the adsorption of the carboxylate and/or neutral molecule species at the mineral-solution interface. Little attention is paid as to whether or not the solution conditions correspond to true solutions, micellar and other self-assembly objects or precipitates. Our examination of the solution chemistry of the important fatty acid collector, oleic acid, has revealed that many, if not most investigators set their experimental conditions to be in micellar or precipitate domains while arguing, often by implication, that they have only solute species present. We have investigated the equilibrium solution domains usually encountered in studies of oleic acid flotation of such minerals as barite, calcite and fluorite. The alkaline earth-fatty acid and liquid oleic acid precipitate phases exert a strong influence on the solution chemistry, a fact not often appreciated in many studies.

Jan 1, 2005

By P J Savory

Ranger is a uranium mining operation located within one of the most environmentally sensitive regions of Australia. Geology has played an important role in mine planning, operations and rehabilitation since discovery of the deposits 25 years ago. The Ranger orebodies have a reserve total of 166 300 tonnes of U308 including 90 400 tonnes of U308 at North Ranger. At current milling rates these reserves give a mine life greater than 40 years. The uranium is hosted in Lower Proterozoic rocks of the Cahill I ormation and is associated with strong chlorite alteration. In pit grade control involves the use of calibrated probes and a radiometric truck discriminator allowing fast, accurate grade determination of material. Ore is defined at a cut-off grade of 0.2 per cent U308. Mineralised material is defined by the Uranium Mining (Environmental Control) Act 1979 (UMEC Act) at a grade of 0.02 per cent U30s. Natural water levels in the #1 Pit area vary as much as 7.5 metres between wet and dry seasons. Ground water inflow into the pit during the dry season is 600 m3/day. No significant slope failures have occurred in the pit. The environmental impact of mining operations is constantly monitored. Rehabilitation of non-mineralised stockpiles is ongoing. This paper discusses the interaction between geology, hydrogeology, rock mechanics and grade control with the present mining operation.

Jan 1, 1994

Mount Isa Mines Limited has been mining silver-lead-zinc ore at Isa Mine for 60 years. Mining methods have evolved continuously, and current production rates of 4.7 Mt/yr are obtained from a combination of sublevel open stopping, cut and fill, and benching methods. In the near future, orebodies mineable by open stoping will be gradually depleted, and the relatively new benching method will be further refmed to replace cut and fill methods wherever possible.

Jan 1, 1993

The main objectives of this paper are to identify the main sources of coal dust and to investigate measures for minimisation of dust generated at these sources at the Bukit Asam open cut mine, on the island of Sumatera, Indonesia which uses a

Jan 1, 1994

By R F. G Phelps

The former Gwynfynydd gold mine is located within the heart of the Snowdonia National Park, North Wales, United Kingdom. The black shale-hosted quartz reefs have intermittently produced more than 50 000 ounces of gold since 1863. Its most recent period of operation by Welsh Gold PLC was between 1992 and 1999 when it extracted 10 000 tonnes annually from a total resource base of 180 000 tonnes. A historical mining grade of 15 grammes/tonne was recovered from the Chidlaw Reef on which all production was based. Erratically distributed gold pockets hosted in the footwall zone of a 3 - 6 m wide quartz reef characterise the mineralisation. The gold exhibits a high-nugget effect and as a consequence the accurate determination of tonnage and grade was difficult. Production was undertaken by overhand shrinkage stoping. Due to its location within a National Park certain environmental constraints were placed on the operators. The principal requirement of planning permission was that processing should take place above ground and not involve chemicals. As a result, an underground mill based on physical separation methods was constructed in response to these environmental constraints. Much of the mine discharge is related to the flow of rainwater through the workings from surface openings on the reefs. Discharge from the underground milling facility was enhanced in various metals, particularly zinc, though was reduced to legally acceptable levels using liming tanks prior to discharge into the River Mawddach. The company was required to monitor and treat all water discharged from the mine before it reached the river. The mine closed in 1999, since which time a tip re-processing has continued as part of an environmental remediation and gold supply program.

Jan 1, 2002

The reasons for selecting two stage pebble milling in preference to conventional methods of grinding are discussed. Commissioning of the first section was completed in October, 1969. Improvements in both the operating and engineering aspects were then incorporated in the section commiss ioned in March, 1971.

Jan 1, 1975

Dewatering tailing slurries by mechanical means is often not possible and gravity and solar driven processes must be used. It has been shown previously that better use of gravity is achieved when the tailing is drained as it settles. Not only are more compact sediments obtained but also the dewatering is faster. From the results of laboratory and field tests reported here, equations were established which describe the evaporation and drainage components of the dewatering. These equations were used to calculate the effects of ponding depth, solids content of the tailing and clim- atic conditions on the time required to dewater the tailing. Since the calculations can be made with and without the drainage component, the advantages to be gained with drainage can be determined. The tailing used in the work was a clay slime from a sand washing operation. However, it is anticipated that this approach will be applicable to other similar tailing.

Jan 1, 1978

The Southwest Pacific is a region of active volcanism and geothermal systems. Only in New Zealand have the geothermal systems been exploited for electricity generation and industrial processing. At present, approximately 280 MWe of geothermal electricity is generated in New Zealand. A considerable amount of further exploration work is required before the total geothermal potential of the region can be assessed and before the significance of these resources can be judged against other local energy sources.

Jan 1, 1990

By Thomas L. J

A series of tests on rock stress measurement devices used with the overcoring method indicated that improvements could be made in their construction. A prototype inclusion cell was developed with strain gauge rosettes bonded to a 0.05 mm thickness stainless steel sheet which was formed into a cylinder around two end pieces. The finished diameter was slightly larger than previous cells so that the thinner plate and the reduced annulus of Araldite cement in the installation borehole gave a better response in the laboratory than the other cells tested, especially in simulated bedded rock. It was less affected by inhomogeneity and temperature changes. Its high sensitivity should make it suitable for both absolute stress measurement and field monitoring. A table of comparative readings is given for the new cell and for four other devices used in simulated in-situ rock conditions.

Jan 1, 1992

By Phillips H. R

The action of free rolling disc cutters is well understood, relationships between disc geometry and performance having been established both in the laboratory and under field conditions. However, under severe operational conditions a malfunction of the disc bearing assembly is likely to produce a definite change of cutting action. Collapsed or siezed bearings can even prevent the disc from rolling and thereby create what is equivalent to a drag pick. This paper describes a programme of laboratory experiments using deliberately stalled discs. Their performance under such conditions is contrasted with that for a free rolling disc and also with a drag pick having a ridged front developing into a negative radiused back clearance angle. In conclusion an assessment is made of the influence stalled discs can have on the torque and thrust requirements for a tunnel boring machine.

Jan 1, 1981

By Mahoney M

For gas content analysis in recent years, it has been standard procedure to report results on a 'dry ash free' (daf) basis, under the assumption that gas only adsorbs onto coaly material. In order to test the relationship between ash and sas content, samples of various rock types were taken from two drillholes in the Newcastle Coalfield. The results of this study confirmed the correlation between gas content and ash, providing an accurate means of relating gas contents for all carbonaceous rock types.

Jan 1, 1995

By Ushakov S

New geological and geophysical in vestigation including our detailed field observation in different regions of the Koryak upland testify that Nor- theastern Eurasia margin eastward of the Ochotsk-Chukotka belt is composed of a collage of allochtonous terranes arcs and sedimentary filling of back- arc basins, which bordered North East Siberia and Chukotka (1)1). Ancient island are assemblages are the most tipical for this region (2-4; shown by heavy line). They are marked by long (500-1000 km) volcanic belts which become younger towards the Pacific up the Latest Jurassic-Neocomi- an (2) to Late Cretaceous (3) and Pale- Gene (4).

Jan 1, 1987

By Dight P. M, Dugan K. J

Design approaches for the artificial support of open pit walls have been reviewed and the main factors affecting support performance have been identified. An example of passive support in a potentially unstable pit wall has been used to demonstrate the importance of slope displacement as part of the support design process.

Jan 1, 1989

The karst water system in Han-Xing District is charaterised by heterogeneity in karstification and permeability of the limestone aquifer, unsteady flowing of the groundwater along karst runoff zone system, periodic recharge related with the periodic precipitation, and concentrative discharge of the groundwater in the form of karstic spring groups. The basic law is that the quantity of the water is very large during waterflood period and rather small in dry period, which has brought about difficulties and contradictions in mining and water supply. The measure to bring the karst water under control must be based on the principle of comprehensive ways and on the systems engineering method. Macroscopiclly, it is the reasonable countermeasure to retain surface water in the upstream section of the karst water system and to strengthen infiltration in the midstream section and to combine exploitation and utilization of the groundwater with water protection and mine dewatering in the area in which mines are distributed.

Jan 1, 1988

Detailed mapping in the Permian-Triassic clastic sediments of the Southern Alps delineates a number of strike-slip faults, both dextral and sinistral, associated with the major Alpine Fault to the west and displacing a tight array of fault blocks. Concurrent steeply plunging folds are deforming early major folds of probable Cretaceous age, and generating schist locally. To the east a major collapse zone has developed along the crest of a Cretaceous anticline, located over an ancient Permian submarine scarp, with a number of small normal faults. Further east, extensive Carboniferous to Triassic rocks of much the same appearance are exposed as horsts and grabens in a large possible extension zone through central and east Canterbury. This may have crept incrementally from Cretaceous from the offshore Bounty Trough to reach the eastern margins of the Southern Alps in the Pleistocene.

Jan 1, 1990

Continuous processes must be shutdown and restarted regularly. Results from the study of operating plants showed potential value for computer simulation of the shutdown and startup of stirred tank leaching reactors. Simulation allows operational variables such as feedrate, and process variables such as the dissolution kinetics to be altered to establish trends in behaviour. Results are presented for the start- up of a cold, empty, single stirred tank reactor, in which three solids are leached at elevated temperature at steady state. Increasing the average temperature in the reactor during startup did not change the fraction of 'valuable' solid dissolved in the first product but it did increase the fraction of slow dissolving (impurity) solid dissolved.

Jan 1, 1984