Search Documents

By N. Geoffroy, E. Benguerel, G. P. Demopoulos

In the late 1990s, a chemical process to remove mercury and selenium from weak sulphuric acid solutions was patented and implemented in the CEZinc refinery in Valleyfield, Quebec. The CEZinc process comprises two stages. In the first one, sodium sulphide is added to the weak acid solution in order to precipitate the soluble mercury. The solution is then treated with sodium dithionite in order to reduce the selenium to elemental form. Because of recent changes in the composition of the industrial solution, a project to study the background chemical reactions was started. In this paper, a review of the background chemistry is presented on the basis of several eh-pH diagrams on one hand, while on the other experimental results are reported dealing with the reaction of selenium (IV) species with either dithionite, sulphide or a combination of the two. According to this work, elemental selenium enjoys a wide pH-eh range stability with selenium sulphide being metastable. Selenium (IV) in single metal synthetic solutions was found to be reduced - to elemental state - at ambient temperature down to ppb range with dithionite as long as the stoichiometric ratio (dithionite/selenium) was in excess of two and the pH < 1.7. Under these conditions the reaction was very fast reaching completion within one minute. Sodium sulphide proved equally effective in reducing selenium (this time as selenium sulphide) to ppb range from single metal solutions. However, in mixed Se-Hg solutions deviations from this "ideal" behaviour was observed resulting in higher levels of residual soluble selenium left in solution.

Jan 1, 2008

By B. K. Choi, S. H. Kang, G. E. Kim, K. B. Kim, S. Noh, T. K. Kim, H. J. Jin

Oxide dispersion strengthened (ODS) steel is being considered as an in-core structural material of future nuclear reactor systems because of its excellent creep and irradiation resistance on the basis of uniformly distributed nano-oxide particles with a high density, which is extremely stable at high temperature in a ferritic/martensitic matrix. Up to now, ODS steels have been intensively studied and developed to apply these materials to the in-core structural component of future nuclear systems. The primary activity is to develop high strength advanced ODS steel, fabrication technology for the structural components and key joining technology for the component fabrication. As a result, a Fe-10Cr-1Mo alloy with a superior creep resistance at high temperatures has been developed. An optimized fabrication process of this alloy system has been established through various process conditions in mechanical alloying, hot/cold working, and heat treatment processes. Joining technology for the ODS steel components is also being developed using solid-state welding such as magnetic pulse welding, friction stir welding and diffusion boding. These R&D activities will contribute to the realization of ODS materials for future nuclear reactor system applications.

Jan 1, 2015

By E. A. G. Colls

PART I.-GASES IN INDUSTRY INTRODUCTION THE part played by gases in industry can be considered from at least four distinct viewpoints, viz: (1) As air to support combustion and life and do various kinds of work (2) As fuel, or as essential to certain chemical processes (3) As sources of danger from explosion or fire ( 4) As hazards to man&apos;s health The present paper deals with gases only insofar as they are sources of danger, or are hazards to health. It may be noted, however, that, in point of tonnage, air is one of the most important materials handled in any industrial plant. In the operations of the Consolidated Mining and Smelting Company, for example, 138,000 tons of air are handled daily, the only material exceeding this figure being water. The United States Bureau of Mines has listed no fewer than seventy-four gases and vapours that, under certain conditions, may be considered as ex-plosive or dangerous (poisonous). The commonest and most important of these are as follows : Carbon monoxide Methane Acetylene Hydrogen Oxygen Hydrogen sulphide Benzol vapour Ammonia Petroleum vapour Carbon disulphide Hydrochloric acid gas Cyanogen Carbon oxysulphide Chlorine ` Fluorine (and fluorides) Acetone vapour Acetic acid vapour Water gas Natural gas Gasoline vapour Coal gas Producer gas Ether vapour Nitrogen oxides

Jan 1, 1940

By L. D. van Dyk, G. S. Tshofu

Iron ore fines are by-products of iron ore mining operations. Unlike iron ore lumps, fines cannot directly be used in conventional iron making processes, and consequently large quantities accumulate around the world. Pelletizing and sintering can be used to convert iron ore fines into agglomerates or briquettes for processing with lump ore, but these techniques are energy intensive and produce greenhouse gases. This research investigated the extraction of iron from iron ore fines using acetylacetone (a ß-diketone) as an environmentally friendly alternative process for fines utilization. A 2k factorial experiment design was used to identify the significant extraction variables. It was found that the reaction temperature and solid to liquid ratio had significant effects on the extraction process. The extraction kinetics were studied at different temperatures and the highest iron extraction (97 %) was obtained after 48 hours at 413 K and 0.025:1 (g:mL) solid to liquid ratio for a particle size range of +106 to -150 µm. The extraction products were easily separated from the unreacted acetylacetone by flash distillation and iron(III) acetylacetonate crystals were recovered. An economic evaluation showed that selling the crystals was profitable. Alternatively, the crystals can be reduced with hydrogen to iron particles and acetylacetone (for reuse).

Jan 1, 2015

The Environmental Excellence in Exploration (E3) project is driven by the recognition that the minerals industry can only maintain its long term viability by ensuring its continued access to lands to explore for, and develop, new mines. Widespread implementation of sound environmental management practices by the exploration community and improved education and understanding of that by stakeholders will help substantially in accomplishing this, and E3 is designed to meet these needs. Exploration crews are now viewed as ambassadors for the global mining community. Their performance in managing the environmental aspects of an exploration program can demonstrate a commitment on the part of the international mining sector to environmentally responsible exploration and mining. We have all observed that failure to behave responsibly can alienate local residents, encourage anti-mining NGOs and jeopardize development. As the saying goes, ?you don?t get a second chance to make a first impression?, and we want to make a favourable first impression. The E3 project is focused on creating an electronic manual, the e-manual, which will provide rapid access to the most up-to-date information on environmental management practices for minerals exploration globally. The e-manual will reflect current thinking and practices in environmental management. It will be richly illustrated with actual examples that reflect the realities of exploration. It will strive to identify the key environmental issues and concerns that apply to most exploration projects, and identify other sources of relevant information useful to field practice. It is our belief that E3, or something very like it, is central to ensuring that the industry survives the current challenges to its viability. E3 will be a cornerstone of the mining industry?s drive to sustainability simply stated, if we are not permitted to explore for mines, there will be none of them at some point in the relatively near future.

May 1, 2002

By L. S. Almeida, U. A. Courbassier, C. T. Guimãaraes, M. N. Souza, V. L. Silva, H. P. Dias, G. A. Bicalho, B. S. Rocha, P. N. Rodrigues, A. Carnevale

During primary aluminum production the anode changing is a very important task. So improvements on it will be essential to avoid disturbance and have a better operational control. After anode changing a good current distribution will be guaranteed using a cavity cleaner and precise anode setting. Albras switching a manually anode setting to an automatic one solved the setting problems. In this paper it will be shown some pot line results and the improvements on workers ergonomic and safety conditions. The device was developed in a partnership between Albras and Pesto.

Jan 1, 2006

By Robert B. Parsons

"The last edition of Tax Notes expressed concern about two proposed tax changes in Finance Minister Paul Martin&apos;s 1995 budget that could have detrimental effects on Canada&apos;s mining industry. This month, Tax Notes expands on these concerns. This article is based on a paper that the author presented at ClM &apos;95 in HalifaxIntroductionOn a global basis, there are more investment opportunities in the mining industry today than at any other time in history. Countries in Central and South America, Eastern Europe, the CIS, Central Asia, and Asia are competing aggressively to attract investment to all sectors of their domestic mining industries. Today, the demand for investment dollars exceeds the amount of dollars that are available for investment in mining. It is not surprising, then, that the established mineral producing nations are witnessing a decline in spending on exploration and development on their home turf, and an increase in spending in developing countries. In the context of a developed country such as Canada, there are two manifestations of the problem of declining investment: (I) Foreign investors are allocating more of their capital budgets to new opportunities in developing countries; and (2) Canadian juniors and seniors are spending proportionately more abroad. This shift in global spending patterns is the source of some concern for the future of Canada&apos;s mining industry, particularly because it is widely believed that the current rate of discovery of ore reserves in this country is too low to replenish depleting reserves.""Government bashing"" has always been a popular pastime in Canada. Invariably, this pastime has focussed, at !east in part, on taxation. In view of the intense competition that Canada faces on the global mining scene, it is important that the role of taxation in the decision-making process be kept in perspective. This paper seeks to put the role of taxation into perspective."

Jan 1, 1995

By Richard Simon

This paper presents an ongoing study on the use of borehole breakouts to estimate in situ stresses at depth in a Canadian underground mine. Breakouts were identified using an acoustic televiewer (ATV) probe. Rock samples were tested in a laboratory to determine their failure curve. Breakout analyses were performed using a 2D failure criterion and a multiaxial failure criterion. Analyses were carried out using both short-term (peak) and long-term strengths (the latter considered here as being represented by the damage initiation threshold DIT). The analyses have shown that the use of the longterm strength and a multiaxial failure criterion leads to results that are more consistent with stress measurements performed in the field, in the vicinity of the mine.

Jun 1, 2012

By Y. Jiang, B. Li, R. Liu

"In this study, laboratory flow tests were conducted on 2-D artificial rock fracture network models containing a single intersection constituted by two inlet and two outlet branches. Three models with different intersecting angles of 60°, 90° and 120° were tested using both dye solution and distilled water. Constant flow rates were imposed on one inlet, and the flow patterns in the fracture intersections were captured by using a CCD camera. The test results were compared with the predictions made by numerical simulations that solved the Navier-Stokes equations. The results revealed that when Reynolds number (Re) is as low as less than 1, the intersecting angle has negligible influence on the flow rate of each branch and the flow patterns within a fracture intersection. As the interesting angle ? and Re (e.g., from 10 to 200) change, the normalized flow rates of different outlet branches change significantly, due to the inertial effect of fluid flow. These changes could be represented by a series of mathematical expressions involving Re and ?, which could be applied to fracture network models to improve their prediction accuracy on hydraulic properties (e.g., permeability and breakthrough curves of particles) of rock masses. INTRODUCTIONCoupled stress, flow, heat and mass transport are the corner stone subjects for many geoscience and geo-engineering disciplines, such as geological disposal of radioactive waste and geothermal energy exploitation. Many outstanding issues need to be investigated to enhance the knowledge on these subjects, and specifically more in-depth research in testing and modeling of the fluid flow in fractured rock masses is needed. In recent years, discrete fracture network (DFN) models have been extensively used to study the fluid flow and mass transport behaviors of fractured rock masses (e.g., Min et al., 2004; Zhao et al., 2011). In these models, each fracture is usually represented by a parallel-plate model, in which fluid flow exactly follows the cubic law. Therefore, comparative flow rate in each outlet branch of an intersection in these models only depends on its aperture. In reality, due to the surface roughness of fractures, the magnitude of mechanical aperture is usually larger than that of the hydraulic aperture of each fracture (Li et al., 2008; Xiong et al., 2011), and abundant flow patterns could exist in an intersection, influenced by its geometry, varying with changing Reynolds number (Re) (Kosakoswski & Berkowitz, 1999). Recent studies have also revealed that different mixing patterns might exist at a fracture intersection, bounded between streamline routing model and complete mixing model, that determine the final distribution of solutes in fractured rock masses (Johnson and Brown, 2001; Park et al., 2001). Numerical simulation has been the principal method adopted in previous studies, and the studies conducting flow tests on intersected fractures are less reported (Wilson & Witherspoon, 1976; Johnson and Brown, 2001). In this study, laboratory flow tests and numerical simulations by solving the Navier-Stokes equations were conducted on 2-D models containing a single intersection constituted by two inlet and two outlet branches, intersected at different angles. The main objective is to study the influence of intersecting angle on the flow behavior of the intersected fractures and the variations of flow patterns and fluid redistribution in each model along with the changes of the Re and the intersecting angle ?. The influence of surface roughness was not considered."

Jan 1, 2015

By Brian Hart, Zhe Chen, Liuyin Xia, Mana Pourdasht, Stamen Dimov

"Gold losses related to carbonaceous matter (CM) during processing are a significant problem in the gold processing industry. Inherent CM in gold ores can behave similarly to activated carbon in its ability to adsorb gold cyanide. This phenomenon is termed preg-robbing as the surface adsorbed gold cannot, for the most part, be recovered. Research has identified that gold adsorption by inherent CM is linked to the specific surface area, pore structure, degree of C disorder and surface functional groups. One of the strategies to inhibit CM preg-robbing prior to leaching is a chemical oxidation; a process linked to modification of the surface functionality. In this study, the variability in gold cyanide adsorption due to oxidation with different reagents has been investigated. Variability in gold cyanide adsorption by CM is examined in relation to structural and surface modifications using TOF-SIMS, XPS and Raman spectroscopy.INTRODUCTION A major obstacle for effective gold recovery during carbon in leach (CIL) or carbon in pulp (CIP) processes carbonaceous gold ores is the presence of carbonaceous matter (c-matter) which has the ability to adsorb, or preg-rob gold from the cyanide leach solution. It can be responsible for poor recoveries as the carbonaceous materials (CMs) within the ore competes with activated carbon used during the leaching and adsorption phase of processing (Cay, 2014). Preg-robbing capacity can vary significantly with mild preg-robbing ores showing absorption capacities of less than 1 g Au/t ore, while severe preg-robbing ores may have CM with the capacity to preg-rob more than 500 g Au/t ore (Dunne, 2007). Research by a number of groups have shown that the degree of C disorder has some influence on the ability of the carbonaceous material to adsorb Au(CN)2- (Miller et al, 2005, Helm et al, 2009, Hart et al, 2010). It is also apparent the adsorption characteristics of carbonaceous material is affected by changes in surface chemistry (Dimov, 2016). Various treatment including; flotation to remove the carbonaceous material (Wills, 2010), addition of surface blinding agents (for example kerosene) to passivate or blanket the carbon surfaces (Dimov, 2016), addition of strong adsorbents (eg. activated carbon or resin) to compete with the carbonaceous material and passivation or surface coating by oxidation (pressure, roasting, chlorination and biological oxidation), have been employed prior to leaching in an attempt to minimize the gold losses (Dunne, 2013)."

Jan 1, 2017

By K. Scholey, S. Marcuson

As high grade nickel sulphide ores are being depleted and with the continuing challenges experienced in economically processing nickel laterite ores, it is important to investigate technologies that can extract nickel from low grade ultramafic ores which are present in large quantities worldwide. In the Thompson Nickel Belt, there are some hundred million tonnes of mineralization that are potentially amenable to surface mining. Since the original discovery of the Thompson orebody, recovery of nickel from these ultramafic deposits has been an elusive goal. Research and development projects as well as commercial processing have been attempted. In the 2000&apos;s as other resources became scarcer, a major drilling, mine evaluation and research project was initiated at Vale. In 2007, Vale Base Metals Technology Development invited Cytec and potential academic partners to participate in an industry-university research consortium with the goal of developing new technologies and methods of processing the ultramafic deposits. Three university professors, J. Finch of McGill, P. Somasundaran of Columbia and R. Pelton of McMaster accepted, each group attacking the problem with a different approach. This paper describes the management of the research consortium and the significance of the results from Vale&apos;s perspective. The next four papers in this session will summarize the project and results from the partners&apos; point of view. Vale is pleased to share the experience of the collaborative research and development with the mining industry.

Jan 1, 2011

By A. G. Darnley

"IntroductionTHE PURPOSE of this paper is twofold. Firstly, to drawn attention to recommendations which have been accepted by the International Atomic Energy Agency concerning radiometric reporting methods and calibration in uranium exploration, and secondly to emphasize the benefits that- will stem from adopting them. These recommendations are contained in an IAEA Technical Report, No. 174, which has been prepared with the intention of serving as a general guide to the subject. The existence of this specialized report is likely to be unknown to most of those who can benefit unless it is given some publicity by an organization such as the CIM. The recommendations were prepared by a small international committee consisting of Dr, P. H. Dodd , U.S .A. , Dr. R. L. Grasty. Canada, Dr. L. Levborg, Denmark, Dr. M. Matolin, Czechoslovakia , Dr. S. D. Simov, Bulgaria, and the writer.The fact that there are standard scientific units of mass, distance and time is taken for granted, It is also accepted that the type of instrumentation used to measure one of these parameters is irrelevant to the way the measurement is reported. Geophysical parameters such as magnetic field strength and gravity have generally accepted units, the gamma and milligal, which are defined in SI terms. These units are employed irrespective of the operating principle, or manufacturer or organization involved in the measurement."

Jan 1, 1977

By P. D. Barrette

This paper deals with the flow of granular materials in bins. A hybrid Lagrangian-Eulerian numerical model is introduced. The model is based on Particle-In-Cell (PIC) advection, and continuum equations describing a Mohr-Coulomb criterion. Experiments were conducted to test and verify the performance of the numerical model. Tests were done using three types of particles. Measurements of material properties and flow rates were carried out. Video records were also obtained and used to examine flow patterns. The results indicate that the numerical simulations produce deformation patterns and flow rates which are in good agreement with the experimental observations.

May 1, 2007

By Gordon A. Irons, H. Y. Hwang

An impinging gas jet on a water surface was studied to understand momentum transfer in oxygen steelmaking. Depth, width and oscillation frequency of the jet cavity were measured and the splashes interpreted with Kelvin-Helmholtz instability and combined Rayleigh-Taylor and Kelvin-Helmholtz instability theory. A model to calculate separate gas and liquid velocities, applying the exact momentum boundary condition, is proposed.

Jan 1, 2004

By F. E. Lathe

The method of feeding blast-furnaces to be described below is simply the application of well-known principles, and an attempt to carry that application to its logical conclusion. It does not involve radical changes in equipment, nor does it require unusual skill on the part of the furnaceman. In fact, much of its value lies in its very simplicity. Before giving details of the method it will be well to consider briefly the conditions under which it was used at the Nickelton plant of the British America Nickel Corporation, in the Sudbury district, before that plant closed down. The Sudbury nickel ore consists chiefly of pentlandite, chalcopyrite and pyrrhotite in a gangue of norite or greenstone. The proportions of sulphide and gangue vary widely in different mines, the former constituting about 45 per cent of the total in the British America sorted ore. The gangue is fairly uniform in analysis, carrying about 55 per cent Si02, 18 per cent A120 3, 13 per cent FeO and smaller quantities of CaO, MgO, Na20 and K20. The ore has been frequently described as refractory, a word which seems suitable when one considers the many unsuccessful attempts to smelt it pyritically, as well as the high percentage of coke normally used at all the plants in the district.

Jan 1, 1925

By Alessandro Navarra, Roberto Parra, Boyd Davis, Frank Mucciardi

A smelter scheduling algorithm has been developed, which allocates the oxygen production between the smelting furnace and the converter aisle, so as to maximize copper throughput. The algorithm is intended for daily operation planning, controlling the sequencing of the converter cycles, and the oxygen drawn by these cycles. In some cases, it may be worthwhile to decrease converter oxygen allocation in favour of the smelting furnaces. Thus, a better utilization of the oxygen plant can increase primary copper throughput by several percentage points. This principle is demonstrated through sample computations. The approach presented in this paper can be incorporated into smelter management software.

Jan 1, 2015

By J. Font

The RAF or copper fire refining process at the Caletones smelter of CodelcoChile consists of several pyrorefining stages that successively lowers the levels of S, Fe, Pb, As, Sb, Te, Se and to some extent 0 in the copper melt, allowing the production of high quality fire-refined copper of 99.93 % purity (RAF copper). This chemical feature of the RAF copper is only achieved by quite long processing times, and a considerable consumption of fluxes and fuels in the RAF vessels. The main goal of this study was to improve the RAF process performance by thermodynamic considerations and industrial scale tests, i.e., an in situ approach for the process as featured by intensive sampling, characterization and subsequent modifications. Thus, both theoretical and industrial data were derived, and based on kinetic and thermodynamic evaluations, a higher operational standard was achieved for the RAF process. These new operational practices allowed enhancing the overall economic of the RAF process, by reducing the time and operational costs, and consequently increasing the availability of the vessels.

Jan 1, 2007

By Masahiro Eguchi, Giuseppe Granata, Chiharu Tokoro, Hiroki Fukuda, Yuichiro Toba, Shungo Hobo

"Currently, large amounts of wastewater containing boron are discharged from industries like coal-fired power plants. Although coagulation-sedimentation is widely employed for their treatment, only a little consideration has been given to its mechanism. An additional problem is that the produced sludge has poor solid-liquid separation. This study is focusing on coagulation-sedimentation using magnesium, examining the mechanism and improving the solid-liquid separation. First, the co-precipitation with magnesium hydroxide was conducted against high-concentration boron wastewater with 500 mg/dm3as B. Second, in order to improve the solid-liquid separation by maintaining high reactivity, low-crystalline magnesium oxide was synthesized from magnesium carbonate by calcination at 400–700°C. It was tested as an adsorbent of boron and compared to co-precipitation with magnesium hydroxide. Co-precipitation showed high removal capacity. X-ray diffraction (XRD) of the sludge revealed the presence of other compounds besides magnesium hydroxide. This result suggests that other processes play a role other than simple adsorption on to magnesium hydroxide, and provides a plausible explanation for the observed high separability. As for the adsorption, the synthesized magnesium oxide immobilized as much or more amount of boron than co-precipitation. Furthermore, the results of fourier transform infrared spectroscopy (FT-IR) suggested the residual magnesium carbonate improved solid-liquid separability due to its poor solubility.INTRODUCTIONBoron is used in various industrial applications. In glass industry, the addition of a little amount of boron into glass products can enhance heat-resistance and chemical-resistance. Semi-conductor industry also employs boron as dopant for silicon. From these industries, large amounts of wastewater containing boron have been discharged. Additionally, coal-fired power plants have been recently discharging highly concentrated boron wastewater because the amount of boron contained in coal has been increasing due to a gradual decrease of the quality of coal. Since boron is partially proved to be toxic for animals, plants, and human beings (WHO, 1998),the guideline of the World Health Organization limit the boron concentration in drinking water to 2.4 mg/dm3(WHO, 2009).Because boron does not precipitate from solutions by simply changing the pH, the removal could be carried by operations such as adsorption or ion exchange. However, since ion exchange is an expensive operation with relatively low capacity, it is not suitable to treat the large amounts of wastewater produced by heavy industries like the coal-fired power plants. Therefore, coagulation-sedimentation method is still widely used as a suitable alternative way."

Jan 1, 2017

By K. B. Young

Possibly the most complex fatigue problem associated with the development of the axial-flow &apos;gas turbine is discussed in its broader aspects from the metallurgical viewpoint. Reference is made to nodal patterns, interference diagrams, etc. The use of such data in analysis of a turbine :blade failure is illustrated. Special attention is given to the influence of some metallurgical variables affecting fatigue strength and, in particular, heat treatment is shown to have a pronounced effect on .the relative fatigue and creep strength properties of a nickel-chromium-cobalt base alloy suitable for turbine blade applications.

Jan 1, 1958

By N. Shi, T. G. Joseph

ABSTRACTA series of algorithms were developed to perform geometric and kinematic analyses of cable shovel dipper-ground interactions for a given set of mining face conditions. The routines examine and analyze (a) the position of the dipper in relation to the shovel; (b) the dipper in relation to the face conditions; (c) the dipper position in relation to possible interference or collision with crawler tracks during digging cycles; and (d) kinematic and geometric considerations with respect to any point on the dip-per as it conducts a duty cycle. In all cases, field measurement verifcation provided good agreement(within 4% variance).

Jan 1, 2011