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By Timothy W. Ellis, Abbas H. Mirza, R. David Prengaman

Recycled lead, i.e. material produced by the recycling of lead-acid batteries, has become the primary source of lead in much of the world. This has been important to the recycled lead industry as other uses have dwindled, e.g. lead based pigments, chemicals, fuel additives, solders and CRT glasses. Presently, battery manufacturing accounts for greater than 85% of lead consumption worldwide while recycled lead accounts for approximately the same market share of lead supply. Battery manufacturing and production of recycled lead are intimately coupled. In 2007, of all the industrial base metals, lead from lead-acid batteries had the highest recycling rate in North America at greater than 95%. In this paper we will review some of the processes and technologies used in a modern lead acid battery recycling facility, and how recycled lead has become the material of choice for battery construction through the development of a recovery and refining process that exceeds the industry requirements. We will also briefly review an advanced air emissions treatment system in a modern lead recycling plant that demonstrates the feasibility of a new maximum available control technology (MACT) for secondary lead smelters.

Jan 1, 2011

By James A. Robertson

"The Pronto Mine located at the east end of Lake Lauzon, Long Township, some 12 miles east of Blind River is of historic note being the discovery locality and the first producing mine of the Elliot Lake uranium camp. Radioactive bedrock was discovered in 1949, a commercial deposit was verified in 1953 and production commenced in 1955. Production continued to April 1960: total tons milled 2,264,404 from which 4,643,835 pounds U,O, were recovered at a recovered grade of 2.05 pounds U3O8 per short ton.The orebody is in a bed of pyritic quartz pebble conglomerate at the base of the Matinenda Formation of the Elliot Lake Group of the Huronian Supergroup. The rocks strike east and dip 15 degrees to 20 degrees south and unconformably overlie Early Precambrian granite, the upper surface of which is marked by a regolith. Several diabase dykes cut the orebody which is also affected by albite, chlorite, and carbonate-rich alterations. To the south the orebody is cut by a fault. The orebody is 6to 10 feet but locally 10 to 15 feet thick, has a strike length of 3,500 feet and extends down dip for 3,600 feet to a depth of 1,000feet. Some 300,000 tons of ore grade mineralization remain in the deeper portion of the mine.IntroductionThe Pronto Mine, (Photo I) at the east end of Lake Lauzon in Long Township some 12 miles east of Blind River, is of particular interest as being the discovery site and the first producing mine of the Elliot Lake camp.Production at the Pronto Mine commenced in 1955 and continued until 1960 when the mill was converted to treat copper ore from the nearby Pater Mine at Spragge. A description of both mines, based on material provided by the mine staff, was given in the report on ""Geology of the Spragge Area"" (Robertson, 1970).As little study has been done on Pronto geology or petrology since mine closure, the earlier description of exploration and geology is essentially repeated, but shortened, here- the main change being that the stratigraphic terminology has been amended as recommended by the Federal-Provincial Committee on Huronian Stratigraphy (Robertson et al., 1969)."

Jan 1, 1986

By K. Ihara, R. Akiyoshi, Y. Takaki, S. Kang, H. Shishido

"Tensile tests and scanning electron microscopy-electron backscattered diffraction (SEM-EBSD) analysis were performed in an Al-Mg-Si alloy to clarify the effect of annealing and cold-rolling reduction on the texture formation. The hot-rolled specimens were cold-rolled with the reduction of 58-75%(CR1), followed by annealing at 773 K for 5 min(IA). The secondary cold-rolling(CR2)for the IA specimens with the reduction of 33–66%, followed by the solution heat treatment(ST), were performed. Focusing on the CR1 and CR2 specimens, the average r-values increased with higher primary and lower secondary cold-rolling reduction, respectively. This was considered to be due to the increase of r-values measured in the direction of 45 degree with respect to rolling direction, caused by the formation of the ß-fiber components (Brass {011}<211>, Copper {112}<111> and S {123}<634>) with high density. Based on the texture analysis of annealed specimens it was suggested that the high density of the ß-fiber components after IA and the small amount of stored strain energy of CR2 introduced by the lower cold-rolling reduction remained the ?-fiber components even after solution treatment.INTRODUCTION Al-Mg-Si alloys have been applied to automobile body applications, due to their excellent paint-bake hardening (age-hardening) and corrosion resistance compared to other aluminum alloy. On the other hand, the mechanical properties and deep drawability of Al-Mg-Si alloys are inferior to those of steels. Thus, it is important to improve the mechanical properties and deep drawability in order to expand the application components. One of the best methods to improve the deep drawability is to increase the Lankford coefficient (r-value). Previous studies reported that the increase of the average r-value ( ) improves the deep drawability. The relationship between the r-value and texture of the alloy is also well known. Inoue et al. reported that the ß-fiber components, such as Brass ({011}<211>), Copper ({112}<111>) and S ({123}<634>), increase the r-value measured in the direction of 45o with respect to the rolling direction. r"

Jan 1, 2018

Although Canadian bentonite is competitive in quality for most uses, it has not been accepted for the pelletizing of iron ore concentrates. In 1962, Canada consumed about 10,000 tons of imported bentonite for this use. By the end of 1965, the planned domestic consumption for this purpose alone will probably be more than 100,000 tons a year, valued at about $3 million. Consequently, a challenge exists for the establishment of a Canadian source of high-quality bentonite for pelletizing. Such a bentonite would also be suitable for the two other major applications -well drilling and foundry use. Brief mention is made of such topics as the identification, 1noperties, occurrences, exploration, applications, technology and laboratory testing of this clay. In particular, the type of bentonite in demand, the geological horizons warranting exploration, and simple preliminary test methods are discussed.

Jan 1, 1964

By Michael Zurowski

This paper traces the history of International Mogul's assessment program on the Lake Ainslie barite-fluorite deposits of Cape Breton Island. The geology of the area is outlined, and the main vein systems described. The geophysical and geochemical exploration techniques employed are explained, the metallurgy of the ore is covered, and the market prices and economics of operation are described.

Jan 1, 1972

By L. X. Li

Coking coal producers often encounter variations in clean coal quality when mining multiseam deposits containing coals with different washability and coking properties. This paper describes how, for a single coal property, an initial clean coal specification with an ash content of 8.5% on an air-dried basis (ADB) and a free swelling index (FSI) of 5.5 can be improved to a specification with 7.5% ash content ADB and an FSI of 6. This is accomplished by sorting coal seams into two groups for processing and blending. A preliminary economic model demonstrates how this improvement enhances economic returns through a beneficial factor.

Jan 1, 2014

By D. Van Tonder

ABSTRACT The comparative economics of ion exchange and direct precipitation have been analyzed by developing indicative CAPEX/OPEX models for typical alkaline leach uranium circuits. An agitated tank ore leach application is considered, comparing resin-in-pulp and direct precipitation as recovery options. Capital and operating cost estimates are derived from rates and factors used in recent studies and projects. The analysis showed the main economic drivers to be the ore grade and resin loading. The resin loading is impacted by the prevalence of competing ions, especially chloride. At resin-in-pulp solution chloride concentrations below 3 g/L and uranium grade below 640 g/t U3O8, resin-in-pulp is more economical, whereas at chloride concentrations above 3 g/L, direct precipitation is more economical.

Jan 1, 2012

By A. Ghahreman, M. Oliazadeh

"Heap leaching is an attractive process for low grade deposits where the metal content of ore does not justify the high cost of milling and agitated leaching. In general, the heap leaching capital cost is low, construction is rapid, and production costs are low. The primary disadvantage of heap leaching is low recoveries (typically 65% of agitated leach recovery); thus, recovery improvements could convert more lower-grade deposits into minable reserves. This will also allow to process primary sulfide ores and result in a dramatic expansion of the technology, as ~80% of total ore types are sulfidic in nature. The old gold operations tailings are another massive source of low-grade gold material that can be retreated by the heap leach process. The major parameters affecting the recovery rates are ore characteristics (mineralogy, particles size of metal and host minerals, ore permeability), and operational conditions (segregation of ore, compaction, leach cycle time, lift height, and solution application rates). The design of a percolation leach process is based on a limited number of coarse ore bottle roll and/or column tests under ideal conditions. The economics of the projects and engineering design of the process facilities are developed based on the bench scale test work results and the application of the conventional engineering scale up factors. This paper will deal with the parameters affecting the HL efficiencies and focus on the potential improvement of gold heap leach recoveries. This would include design of heap leach operation and evaluation of processes such as fine crushing and bioleaching.INTRODUCTION Gold heap leaching is a hydrometallurgical process designed to treat amenable low-grade gold ores that contain typically 0.5 to 1.5 g/t gold (Marsden and House, 2006; Wong Wai Leong and Mujumdar, 2010). Ore is stacked by various types of equipment on an impermeable barrier, and a sodium cyanide solution is applied to the surface of the stacked ore. Gold, silver, and other metals contained in the ore are dissolved to various degrees by the cyanide application, as it percolates downward through the stack of the ore. The pregnant leach solution (PLS) is then collected at the bottom of the heap. The PLS is then sent to the gold recovery plant where the metals are extracted. The barren leach solution (BLS) is then reapplied to the top of the pad. Ore is placed on a pad or previously leached lift by various means, including ramp conveyor belts, radial-arm and self-leveling stackers, and trucks. Once trucks are used to construct the pads, the pad can be compacted and hence the pad should be graded and ripped or scarified (roughened up) with wheeled or tracked equipment to produce shallow cuts to increase surface area exposure to the leachate."

Jan 1, 2019

"Real-time, on-stream analysis of the metal content of process slurries is an essential prerequisite for process monitoring and advanced control of mineral processing circuits. On-stream X-Ray Fluorescence (XRF) sensors for base metal applications are available commercially and form the basis of many plant monitoring circuits. To date, these commercial technologies have been insufficiently sensitive to measure precious metals such as gold and platinum group elements, typically present at part-per-million (ppm) and sub ppm levels. CSIRO has developed a novel X-ray based technology, called UltraGold, which enables detection of gold in slurries on a real-time basis with a precision below 100 parts-per-billion. This technology is based on the use of advanced X-ray optics, extensive Monte Carlo computer modelling for analyser design, high accuracy X-ray spectrum fitting where the X-ray intensities are matrix corrected. In this paper, we will introduce this technology and discuss the results of a proof of principle study performed in the laboratory with plant slurries (tailings and concentrate) from an Australian beneficiation plant. Finally, we will discuss further planned improvements. As projected grades in (gold) mining around the world fall and several large-scale mines approach the limits of their economic reserves, this method can enable significantly reduced operating costs by rapid analysis to improve circuit efficiency and hence improve recovery significantly.INTRODUCTION This paper describes a study undertaken to explore the feasibility of applying CSIRO?s UltraGold XRF technology to the on-stream measurement of gold in process slurries. The provision of rapid, accurate information of gold grade in feed, tailings and concentrate streams would facilitate significantly improved process control and early detection of plant upsets, resulting in substantial cost-savings. CSIRO have patented X-ray fluorescence (XRF) techniques for the analysis of key elements in slurries present at part-per-million (ppm) and sub-ppm levels. Conventional, commercially available on-stream XRF instruments generally have detection limits in the tens of ppm range, precluding their use for analysis of elements like gold that are mined and processed at much lower concentrations."

Jan 1, 2017

By T. R. Kostecki, J. Hirschi

"Analytical engineering design is based upon a trial-and-error iterative and deterministic process. Within this process, the engineer obtains some estimated values, plugs them into de facto closed-form equations, and receives output, which is expected to be a single number that serves as the basis for the design. This number is typically a factor of safety, or some other equivalent strength-stress ratio. This provides the engineer with a quick and relatively quantitative design methodology. This can create problems however, because in mining applications, the actual in situ system is highly variable, complex and often chaotic, which can lead to potentially incorrect conclusions that result in unsafe designs. A more appropriate and reliable approach is a probabilistic analysis for engineering design. This process is used widely in civil and other engineering disciplines, but is often overlooked for applications in coal mine design. Additionally, it seems the amount of past studies using this approach, especially in coal mine design, are rather limited. Considering how the probabilistic approach can account for uncertainty in parametric values and how unpredictable a mining design can be, the authors believe that this approach has potential in mining. This paper will focus on a summary of past studies related to probabilistic analysis in coal mine pillar design and provide recommendations for future work that could improve design reliability. INTRODUCTIONFeasibility and fundamental design procedures for excavations often start with an assessment of mine openings, pillar design, and the surrounding structure by using a deterministic approach with closedform solutions (ex. Bienawski, Obert-Duvall). These are reliable methods, but designers know that the inputs in these closed-form solutions are estimates at best and do not incorporate any degree of uncertainty. This is therefore not an optimal design procedure.A more appropriate design should incorporate some uncertainty because of the chaotic and variable nature of geology and mining conditions in general. In an attempt to account for uncertainty, a probabilistic approach can be adopted, which accounts for deviations in variables and provides a more optimum design solution. By applying a probabilistic approach, a designer can look at multiple failure scenarios at the same time instead of using the same deterministic design over and over."

Jan 1, 2015

By Takashi Nakamura, Atsushi Iizuka, Yong Fan, Etsuro Shibata

The level of iron in typical copper slag reaches nearly 40% by mass, in the form of iron silicate. We designed a method to oxidize the nonmagnetic iron silicate to magnetite, permitting the selective recovery of the slag’s iron content by magnetic separation. This would effectively decrease the volume of dumped slag; the reclaimed iron could be used for iron and steel making. The crystallization behaviors of magnetite and hematite were studied as reaction products of the molten oxidation of copper slag. A gas atmosphere of 1% by volume of oxygen was found to effectively precipitate the slag’s iron content as magnetite.

Jan 1, 2015

By C P. Gravenor

In 1953, a deposit of sedimentary oolitic iron ore was discovered in the Clear Hills area of northwestern Alberta. Since that time, detailed drilling has outlined reserves in excess of 200 million tons of ore grading 30 to 35 per cent iron. Attempts to physically beneficiate the ore to meet blast furnace or direct reduction feed specifications have been, in general, unsuccessful. In 1960, Premier Steel Mills Limited and the Research Council of Alberta jointly sponsored a pilot-plant test at the R-N Corporation at Birmingham, Alabama. About 5,000 tons of ore were treated, and briquettes containing 90 per cent Fe were produced, with 83 per cent recovery. At the same time that the R-N tests were being made, the Research Council initiated a program to produce high-purity powders by chemical methods. Several purification techniques were investigated; hydrochloric acid dissolution of reduced ore was finally adopted. Briefly, the steps involved in this acid process are as follow

Jan 1, 1964

By I. A. Tinto

"Labrador City is located in the southwestern portion of Newfoundland-Labrador, approximately 965 kilometers north-east of Montreal. The mine and beneficiation complex of the Iron Ore Company of Canada, known as the Carol Project, is situated 535 metres above sea level in a climatic region characterized by cold winters and short, cool summers.HistoryThe Iron Ore Company of Canada commenced work in the area in 19 4 9' however, it was not until 1958 that the decision was made to proceed with mining operations. The ore body consists of Specular Hematite (Fe203) and Magnetite (Fe304) with small quantities of Limonite and Geothite. The average grade of the ore bodies is 39% iron.The mining facilities, crushing plant, and concentrator were in operation by the early part of 1962. In the summer of 1961, a decision was made to build a pelletizing plant adjacent to the concentrator. This plant was designed, erected and placed in operation during 1962 and the first half of 1963. Since the completion of the pelletizing plant, additional expansions to both the pellet plant and concentrator have taken place in 1967 and 1973. Today, the Carol Project has the capacity to produce 20 million tonnes of concentrate from which 10.5 million tonnes of pellets can be produced.The period 1980-85 spans a period of energy crisis, world-wide recession, and a consequent re-structuring of the North American steel industry as it struggles to survive in an arena of excess world steel making capacity, government subsidized industries, and the increasing competition from overseas and from developing countries.The media headlines over the past few years echo the woes of the industry and the strategy plans for survival of the fittest. Today's buzz words are foreign competition, steel import quotas, joint ventures, employee participation, work rules, quality, productivity, and state of the art technology."

Jan 1, 1986

By J. C. Ingram

IT SEEMS particularly appropriate that, in celebrating its Diamond Anniversary, the Canadian Institute of Mining and Metalturgy chose our Province of British Columbia as its locale in this, our own Centennial year. I am sure your organization is justifiably proud of its achievements and growth over the period of its sixty years, and we, for our part, are justifiably proud of our growth over our first one hundred years. With your kind indulgence I pro-pose to talk to you today about our industrial growth, or, to put it an-other way, to highlight, historically, our progress in industrial development over the past one hundred years, and to take the liberty of speculating on what we may reasonably look forward to over the next few years. I am sure, Mr. Chairman, that some may have questioned the appropriateness of a talk on the industrial development of British Columbia to the Canadian Institute of Mining and Metallurgy. However, strangely enough, we in British Columbia owe our origin, constitution-ally and industrially, to the mining industry.

Jan 1, 1958

By W. M. Brewer

Introduction This paper describes some of the mineral resources that are tributary to that portion of the Pacific Great Eastern railway included in the Western Mineral Survey District, No. 6, of British Columbia. This district extends 38 miles northerly from Squamish, the ocean terminus of the railway at the head of Howe sound, to Alta lake. Beyond Alta lake the railway continues northerly through two other mineral survey districts: the Central Mineral Survey District No. 3, and the Northeastern District No. 2. District No. 6 includes that section of the Coast Range from which the waters flow southerly towards Howe sound. The division between District No. 6 and District No. 3 is represented by an imaginary line across the summit between the headwaters of the Cheakamus river, flowing south into the Squamish, and the Green river which flows north and empties into the head of Lillooet lake near Pemberton meadows, about 20 miles from Alta lake. History: - The history of the route of the P. G. E. railway dates back to the old Cariboo days when a pack-horse trail traversed the country northerly from Squamish to the Pemberton meadows, and also south-easterly from Squamish to the head of Seymour creek, thence southerly down that creek to the north arm of Burrard inlet.

Jan 1, 1925

By Maria Agostina Cinellu

Some aspects of the reactivity of the two different kinds of gold(III) oxo complexes [Au2(N,N)2(?-O)2][X]2 [N,N = 2,2&apos;-bipyridine (bipy) (1), 6-alkyl-2,2&apos;-bipyridine (bipyR) (2), R = Me a, CH2Me b, CHMe2 c, CMe3 d, CH2CMe3 e] and [Au2(C,N,N)2(?-O)][X]2 [HC,N,N = 6-benzyl-2,2&apos;-bipyridine (bipyR&apos;) (3), R&apos; = CHMeC6H5 a, CMe2C6H5 b] (X = BF4, PF6) have been studied. Treatment with water converts the unsubstituted bipyridine complex [Au2(bipy)2(?-O)2][PF6]2 (1) and the cyclometallated derivatives [Au2(C,N,N)2(?-O)][PF6]2 (3) into the water soluble monomeric hydroxo species [Au(bipy)(OH)2][PF6] (4) and [Au(C,N,N)(OH)][PF6] (5), respectively. These hydroxo species, likely the intermediates in the formation of the oxo complexes, are quantitatively reverted to the latter ones by reflux in anhydrous solvents. Both kinds of oxo complexes react with PPh3 to give OPPh3, the gold(I) complex [Au(PPh3)2][PF6] and the free bipyridine ligands. The reaction of the dioxo complexes [Au2(bipyR)2(?-O)2][PF6]2 (2a, 2b, 2c, 2e) with different alkenes gives the unprecedented alkene complexes [Au(bipyR)(?2-alkene)][PF6]. The styrene adduct [Au(bipyip)(?2- CH2=CHPh)][PF6] (7) (bipyip = 6-iso-propyl-2,2?-bipyridine c) has been characterized, inter alia, by X-ray diffraction analysis. Organic products arising from olefin oxidation are also found in the reaction mixture.

Oct 1, 2003

By John A. Teeter

"A SHORT WHILE AGO I enquired about The Mining Society of Nova Scotia. In all honesty I was apprehensive about addressing such a body if it was highly geared to the technical aspects of discovering and obtaining mineral resources. I was told that this would not be the case. Rather, there would likely be in attendance a broad cross section of people from business, industry and government and from across Canada and the U.S.A. Thus there would be an interest in a free-wheeling discussion of the prospects for industrial development in Cape Breton. Accordingly - being one who hates to miss an opportunity - I intend to exploit the invitation of your executive by being, over the next short while, frankly promotional. I would like to talk about what I consider to be some of the most important attributes of Cape Breton for industrial development and identify some of those prospects. Secondly, I will quickly review some of the things the Cape Breton Development Corporation is doing these days to stimulate some of that industrial development."

Jan 1, 1972

By A. Sobering, G. N. Carlson

"This paper describes the conversion of the grinding section of the W a bush Mines pelletizing plant from conventional wet, open-circuit trunnion overflow ball milling, with filtering, and bentonite mixing on a common conveyor belt, to dry, open-circuit, grate discharge grinding, with pug mill mixing of bentonite and water at individual mills.The test work and data on operating economies to justify the cost of conversion are given. It is too early, at the time of writing, to have complete operating confirmation, but data are available. A brief description of the original plant is included."

Jan 1, 1971

By G. A. Gross

"Nearly 90 per cent of the iron ore produced in Canada is derived from iron-formation or bedded iron deposits. About 70 per cent of this consists of concentrates obtained from iron-formation; another 20 per cent was formed by natural enrichment processes.Four principal varieties of iron-formation are recognized -the Algoma, Superior, Clinton and Minette types. Differences in their geology, mineralogy, chemical com-position and environment of deposition are of special significance in their evaluation as ore.The properties of the ores, including grade, beneficiation qualities and minor element content in taconites, metataconites and naturally enriched ores, reflect characteristics of the primary stratigraphie units from which they are derived. A detailed description of the stratigraphie facies is essential for efficient utilization of these source beds."

Jan 1, 1966

By K. Miao, W. Mu, M. Sharma, A. Haas, N. Dogan

"The ever increasing demand for cleaner steels with low inclusion content has highlighted the limits of our current knowledge for controlling and predicting inclusion agglomeration and removal during liquid steel processing. Key knowledge gaps in this area result from the complex nature of the problems associated with measuring and visualizing the phenomena studied. Confocal scanning laser microscope (CSLM) allows for continuous in situ observation of micron-size samples in real time, at high resolution, under conditions relevant to the steelmaking process. This paper summarizes some of recent CSLM applications in our laboratory to illustrate the methods of analyzing transient behavior. The reaction between inclusions and slag is given as an example. The dissolution rate of calcium aluminate inclusions in CaO-SiO2-Al2O3 slags has been studied at elevated temperatures: 1500, 1550 and 1600°C as well as thermodynamic/kinetic analysis. It is found that total dissolution time decreased with increasing temperature. The rate limiting steps are discussed. It is shown that the diffusion through a product layer is responsible for dissolution at 1500°C. At higher temperature, dissolution is most likely controlled by both boundary layer diffusion and chemical reaction at the slag-inclusion interface. In this paper, the evidence for and against the theory will be critically examined and repercussions of the theory to steel refining processes will be discussed.INTRODUCTION Inclusion formation during liquid steel refining is an unavoidable consequence of current ladle steelmaking processes. The nature and quantity of the inclusions formed in steel is critical in steelmaking, as it affects both productivity through clogging, and downstream physical properties of the steel. It is therefore crucial to better understand and control the formation, agglomeration and dissolution behaviour of inclusions in a slag in order to improve the removability of inclusions from liquid steel. Most research (Sandhage & Yurek, 1988; Sandhage & Yurek, 1990a; Sandhuge & Yurek, 1990b; Sandhuge, 1991) relevant to the kinetics of inclusion removal has been obtained by using a technique where simulated inclusion material (ceramic rods) is dipped in slag and the dissolution rate is measured. While much has been learned using this approach, the difference in scale from bulk materials to inclusions is likely to have a significant bearing on the dissolution kinetics of inclusions in a slag and will certainly result in a very different influence of capillary effects. Further, the data obtained using an indirect (dip test) procedure relies on a comparison of the initial and final conditions of a sample rather than in-situ observation which can be achieved in a confocal microscope in real time."

Jan 1, 2017