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By M. P. Amsden

"Ecstall Mining Limited, a subsidiary of Texasgulf, Inc., Operates the Kidd Creek Mine, Concentrator and Zinc Plant at Timmins, Ontario. Two different ore types are mined and milled to produce concentrates of copper, zinc, lead and tin. The ores are processed at the Concentrator in three separate individual milling circuits, each with the capacity to treat up to 3500 tons per day. Two circuits treat copper-zinc ore 1t an average combined rate of 6500 tons per day and the third circuit treats 3500 tons per day of silver-lead zinc ore. Conventional crushing, grinding and flotation procedures are followed. The purpose of this paper is to describe Ecstall's experience with rubber mill linings in the grinding circuits.CrushingBoth ores are crushed to minus 6 inches at the Mine and delivered by rail to the Concentrator where they are reduced by secondary and tertiary crushing to minus 5/8 inch.GrindingThe crushed ores are prepared for selective flotation by grinding with rod mills and two stages of ball milling. flotation circuit middling products are reground in regrind mills prior to further treatment. A typical flowsheet of one of the grinding circuits is shown in Figure 1.All the grinding units are Allis-Chalmers Mills. The rod mills are 10 1/2 feet diameter by 16 feet long. Both the primary and secondary ball mills are 12 feet diameter by 18 feet long and all regrind mills are 6 feet diameter by 12 feet long. The primary mills are charged with 1 13/16 inch forged balls. Secondary mills are charged with 1 1/2 inch forged balls and the regrind mills are charged with 1 inch forged balls. All cyclones are Kreb units. The primary cyclones are Dl5B hydrocyclones, the secondary cyclones are D6B hydrocyclones and all regrind cyclones are D6B hydrocyclones."

Jan 1, 1974

By Fred E. Gray

The mill of Bralorne Mines, Limited, is located on the government highway in the Bridge River mining district of British Columbia, approximately fifty miles northeast of Shalalth, the shipping point on the P.G.E. railway. Prior to 1931, the property now owned by Bralorne Mines, Limited, was operated by Lorne Gold Mines, Limited. During the early operation of the mine, the ore had been treated at various times in one of three small amalgamation mills on the property. With the succession to ownership by the Bralorne Mines, Limited, work was started on construction of a new mill of approximately 100 tons capacity per day. The new mill was put into operation in the month of February, 1932, and since that date has been in continuous operation, milling an average of slightly over 3,000 tons of ore a month. The ore treated in the Bralorne mill is a gold-bearing quartz containing a very small amount of silver. About 75 to 80 per cent of the gold is in the form of free gold, the principal remaining portion being intimately associated with pyrite and arsenopyrite. The gangue rock is quartz, together with varying but relatively small amounts of altered diorite or albitite. In some of the ore, usually the higher grade portions, there is also considerable talc, which forms much slime in grinding. The mill is situated near the portal of the main haulage tunnel and the ore is received directly from the mine ore-trains, which dump on to the grizzly over the coarse-ore bin of the crushing plant. Figure 1 shows the flow-sheet of the mill as it is now being operated. Various changes have been made in the flow-sheet and in the reagents since the commencement of operations, and doubtless minor changes will continue to be made in order to increase the efficiency of the mill. Among the more important changes were those from two-stage to single-stage grinding, and from amalgamation plates to blankets. The change in the crushing was made because too much crushing was done when both primary and secondary mills were employed.

Jan 1, 1933

By Sub-Committee of the Committee on Research

"THE FOLLOWING REPORT was compiled by a sub-committee of The Metallurgical Society of CIM, Committee for Research, and represents a viewpoint of the steel industry in Canada. The objective was to define those areas in which the industry considers that external sources of Research and Development are a necessary function in supporting the in-house R & D conducted by the industry.On future occasions, the viewpoints of other metallurgical industries, such as those of nickel, copper and aluminum, will be presented. The report is divided into several sections: 1.-R & D Spending by the Steel Industry (a) Memberships in Recognized Steel Research Centres (b) Memberships in Recognized Industry Associations (c) Sponsored Research at Recognized Centres (d) Sponsored Research at Universities(e) Sporadic Research 2.-Areas for Research and Development(a) Instrumentation (b) Environment Control (c) Refractories (d) Sponsored Research at Universities(e) Electric Furnaces (f) Continuous Casting"

Jan 1, 1970

By C. B. Mapes, E. C. Dowling Jr.

"To reduce concentrate dewatering and drying costs, the Concentrator Division at Phelps Dodge Morenci, Inc. investigated available filtration technologies. Numerous methods were explored, including: drum, disk, belt, pressure, hyperbaric, and ceramic media filtration. An economic evaluation of the individual filtration technologies indicated the advantages of ceramic media filtration for Morenci concentrates. This paper discusses the technological development culminating in the first full scale application of ceramic media disk filters in North America. Low moisture contents are obtained at high production rates and greatly reduced operating costs.INTRODUCTIONPhelps Dodge commissioned the Morenci Concentrator Filter Plant in 1942 with four 8'6"" Dorr-Oliver cloth disk filters. That year, the filter plant processed 265,537 tons of concentrate grading 20.5% Cu. The filter cake production averaged 9.3% moisture. In 1944, the Extension Filter Plant commenced operation with three additional 8'6"" Dorr-Oliver cloth disk filters. This coincided with the expansion of the concentrator. Production that year totaled 451,567 tons of concentrate grading 23.8% Cu. Moisture averaged 9.4%.Through the years additional filter units have been added in response to increased concentrate production. An Eimco drum filter was installed on the extension side and an additional Dorr-Oliver disk filter was installed on the original side in the 1950's. In 1961, two 8'6"" Peterson disk filters were installed, one on each side to replace two worn-out DorrOlivers. The installation of four 10xl2 foot Peterson drum filters was completed in 1974, coinciding with the Metcalf Concentrator startup. An Eimco belt filter was installed later.The greatest change to concentrate dewatering at Morenci occurred in 1963 with the addition of a 10x60 foot rotary gas fired dryer. The installation also included a number of conveyors to deliver filter cake from both plants to and from the dryers. Other ancillary systems included dust scrubbers and their slurry pumps. The commencement of drying was undertaken due to the rapid increase in cake moisture as a result of the LPF process and the recycling of acid plant scrubber dust slurry from the smelter. In 1972, a second dryer system was installed to increase capacity."

Jan 1, 1993

By R. Alarcón Sch., R. Abel F.

For many years, copper cathode quality has been a priority for end consumers, since it affects the variety of products that can be obtained from them. From the beginning, physical and chemical quality of the wire bars was controlled, as this product was used to obtain wire rod and other forms of copper by wire drawing. At that time, all the electro refined cathodes were melted and casted as wire bars. Subsequently, in the 80’s, with the introduction of continuous casting furnaces, it was possible to directly produce wire rod from cathodes. From then on, cathodes quality standards were consistently increased, by the introduction of uniform criteria, among which we can identify ASTM and British Standards as well. Also, producers began to use more demanding internal standards than the existing specifications, in order to differentiate their cathodes as high quality products among customers. Today the physical aspect of cathodes, including nodules, cracks, sulfates, or others, is the first element used by end customers to assess their quality. This paper aims to show a brief vision of the evolution of quality specifications for products used to manufacture copper wire. INTRODUCTION From the beginning of refined copper production for industrial purposes, mandatory minimum quality conditions were established. These quality conditions were used as the main element to determine prices and discounts of the respective sales contracts. Reviewing the copper development history, we can appreciate that its quality requirements had been constantly evolved, so that currently refined copper has an extremely high quality standard, that allows its direct use in the production of ultra-thin cables and other products applied in the industry. In each stage, refined copper production has fostered the development of technology used in their treatment. Similarly, cathode processing technology has been evolving to minimize treatment costs in order to generate a wire rod for several uses, ranging from power cables to super conductors. In this sense, to the already known type of fusion processes of the Southwire or Asarco type (capacities over 80 kt / year), wire rod production processes of the Upcast or Rautomead type (capacities between 20-50k t / year) have been added. They immediately deliver oxygen-free wire rods. In both cases, we can conclude that the clients' requirement had evolved from a chemical criteria focus, to considering more subjective aspects, such as visual control as the first stage of inspection.

Jan 1, 2019

By Alexander Levran

The main thrust of this presentation is to illustrate the growing contribution of solar energy to the mining industry by replacing existing mechanical and pneumatic tools and equipment with more effective and efficient electrical tools due to the increased efficiency and lower cost of solar energy generation. LCOE (levelized cost of energy/electricity) for solar energy is becoming highly competitive with other conventional sources of energy. The distributed architecture of solar power plants allows the supply of energy to highly remote and abandoned geographies. We will focus on the trend for this contribution to the mining industry over the next three years. Water desalination and delivery to the mining area will be topic of discussion regarding the contribution of solar systems in Latin America (LATAM) and other geographies. INTRODUCTION Increasing price pressure on the mining industry has generated a strong interest for mining companies to investigate energy costs and consumption. Currently, energy costs in mining economics contribute15% to 25% of the total commodity cost. In the past, most mines were operated by diesel gensets. Very high logistics costs for diesel supply, high and fluctuating diesel prices and theft led to very high energy prices. To overcome this problem, the mining industry has turned to solar energy, employing two main solutions: (i) adding a small scale (single level MWp energy supply) solar to an existing diesel system to create a hybrid solution operating as a microgrid environment; and (ii) replacing the existing diesel system with a large scale grid connected photovoltaic system financed by utilities or private IPP owners that signed a long-term power purchase agreement (“PPA”). In both applications, the near-term trend is to add storage and weather controls to optimize the electrical performance of the system. Use of concentrated solar solution (CSP) in the past was employed in a few remote sites to provide electrical energy to the mines. Currently this technology is not competitive with the photovoltaic (PV) systems. In some installations we have seen usage of a small hybrid system that is designed as relocatable, containerized and delivers scalable electrical power. In addition to the evolution of electrical energy sources, we see the trend of reduction of energy consumption in the mines by optimizing energy efficiency and generating load shifting solutions. Many studies of electrical energy in the mining industry support the growth of this trend in the mining industry.

Jan 1, 2019

By A. Bendada, P. Servais, X. P. Maldague, C. Ibarra-Castanedo, C. Mohr

Infrared (IR) thermography is a nondestructive, non-contact and non-intrusive technique that allows the fast inspection of large and complex structures with limited accessibility. Pulsed thermography is particularly interesting for the inspection of aerospace materials such as composites given that, after submitting the specimen surface to a thermal front, the most common types of subsurface discontinuities (e.g. porosity, de laminations, dis bonds, fiber breakage and inclusions) can be detected with an IR camera as regions showing abnormal temperature patterns. We present first the case of an aircraft door with water ingress and surface repairs on its honey comb structure. We also highlight the advantages and limitations of thermography for the inspection of aircraft composite parts, such as edge flaps, rotor blades and speed breaks. Finally, we expose some results from a Kevlar® non-planar specimen with Teflon® inclusions at different depths and locations.

Jan 1, 2006

By D. R. Hatton

To obtain sufficient material on which to perform copper-molybdenum separation testwork a variability set of drill hole reject samples amounting to several tons was put together to include the different ore types proportions expected in the copper circuit. The samples were treated in a copper circuit pilot plant and enough mass of bulk concentrate was recovered to conduct copper moly separation tests in the laboratory. Tests consisted of stage flotation reactor (SFR) rougher pilot plant tests, conventional laboratory rougher, cleaner and 4 stage open circuit cleaner tests. The mineralogical liberation analysis of the feed and concentrate was used to model the effect of liberation on the grade-recovery relationship of the different samples. Mineral kinetic parameters for the various samples were determined by calibration to the test data. The copper concentrate results as simulated from previous studies on the same deposit were used to simulate the variability in head grade and throughput expected for the feed to the copper molybdenum separation circuit for each of the first 10 years of production. This variation in feed was then simulated through the separation circuit to obtain optimised molybdenum grade recovery curves to forecast the circuit production for each of the first 10 years. INTRODUCTION Incorporating Geometallurgy into the design for a copper molybdenum separation is especially challenging due to the low mass of final concentrate typically produced during testwork. This is due to the low molybdenum head grades and high overall molybdenum upgrading expected. With molybdenum head grades of around 300 ppm, 1 tonne of copper circuit feed is expected to produce around 300 g of molybdenum concentrate in the plant. In the laboratory however, this may end up only resulting in a few grams. Obtaining sufficient mass for laboratory testing therefore requires starting with a large initial sample and careful testwork planning to maximise the utilisation of this mass. A testwork program was designed to investigate the effect of ore variability on the copper molybdenum separation circuit (here after referred to as the molybdenum circuit). Composite samples were selected to represent the various ore types, copper content, moly content, pyrite content and clay contents expected in the copper circuit feed. These samples were run through a bulk copper pilot plant to create the feed for the molybdenum testwork. The molybdenum testwork consisted of rougher kinetic flotation tests, rougher cleaner kinetic tests, rougher cleaner kinetic tests with regrind, stage flotation reactor (SFR) pilot plant tests, open circuit cleaner tests. These tests were used to calibrate the ore kinetics in the IGS-FLEET model for simulation of the molybdenum circuit performance.

Jan 1, 2019

By T. Donkin, B. Patterson, M. I. Guthrie, J. T. Ross

"Interest in the use of particle-based ore sorting has increased significantly with recent advances in sorting technologies and higher capacities per unit. Particle-based ore sorting has the potential to provide great value in processing lower grade ores from mines while delivering higher grades to the mill, as well as in upgrading waste rock into ore. Typically the focus is on the amenability of the ore to ore sorting and associated reductions in energy, water, and consumables utilization. However, layout significantly affects the installed cost of a processing plant, and the impacts on layout from fitting an ore sorting circuit into the plant plan need to be carefully considered. This paper examines processing plant layout considerations that play an important role in ore sorting projects, including additional crushing and screening requirements, transport of rejected material back to the waste stockpile (mine fleet requirements), and effects on the processing plant footprint. ¦ KEYWORDS Cold climates, Ore sorting, Plant layout RÉSUMÉ L’intérêt porté à l’utilisation du tri granulométrique du minerai a considérablement augmenté au vu des récents progrès réalisés en matière de technologies de triage et des capacités supérieures par unité. Le tri granulométrique du minerai offre une plus-value intéressante en termes de traitement du minerai à plus faible teneur extrait des mines ; il permet par ailleurs l’acheminement vers le concentrateur de minerai à plus haute teneur et la revalorisation des stériles dans le minerai. On met généralement l’accent sur la susceptibilité du minerai au triage et sur les réductions connexes en termes d’utilisation de l’énergie, de l’eau et de biens consommables. Cependant, l’aménagement physique de l’équipement a une incidence non négligeable sur le coût installé d’une usine de concentration, et les répercussions sur l’aménagement de l’installation d’un circuit de triage du minerai dans l’usine doivent être soigneusement examinées. Cet article étudie les considérations relatives à l’aménagement de l’usine de traitement qui jouent un rôle important dans les projets de triage du minerai, et notamment les exigences supplémentaires en matière de concassage et de criblage, le transport de matériau résiduel jusqu’à la pile de stockage des déchets miniers (nombre de camions requis dans le parc minier) et les effets sur l’empreinte de l’usine de traitement. ¦ MOTS CLÉS aménagement de l’usine, climats froids, triage du mineraiINTRODUCTION Ore sorting has been practised throughout history. An early report by Agricola in 1556 documents how metallic and non-metallic minerals were extracted from rocks by laboriously breaking them with hammers and picks and hand-picking selected material with higher grade (Hoover & Hoover, 1950). The concept has not changed, but sorting technology has evolved significantly over the last 20 years"

Jan 1, 2019

By I. M. Marshall

A review of technical literature covering Canadian mining emphasizes the advancement and changes that have been made in mining practice. However, current technical publications rarely outline basic principles or state definite rules that govern profitable mine operation. it may be argued that the broad principles of mining have long a go been outlined in various handbooks, text-books, and periodicals, and that these principles never alter. This is in great part true, but modern machinery, improved meta1-lurgical practice, and other advances, have in part modified these principles or changed the manner of their application. Many engineers hesitate to state specific rules, because it is so easy to quote an exception to a rules that any such statement appears to lose weight upon its very utterance. The exception to rules, and the reluctance to formulate rules, has forced such maxims as "the only rule in mining is the point of a pick," and "gold is where you find it". As an illustration of rules and their exceptions, one might quote the time-honoured maxim that a mill should not be built before a shaft has been sunk on a property in point of fact, Canadian mining history is replete with examples of wasted capital where a mill was built before a shaft had been bottomed. Y et this past year has seen a property enter profitable production whereon the building of the mill was started before the shaft was sunk. Instances such as this should not be accepted as evidence that a rule has been overthrown, but rather as an exception to the rule. The case cited pays tribute to the application of the diamond-drill combined with the correlation of sound geology. Incidentally, both these features emphasize a modern trend in the development of Canadian mining properties-a trend that is perhaps worthy of further comment. It is such trends that affect the principles of mining or modify their application. It is with such that this paper deals, at ]east in part. It is hoped that the statement of principles and the opinions herein outlined will be of sufficient interest to arouse discussion.

Jan 1, 1939

By J. A. Russell

"UNTIL the last few years, the collieries of the Dominion Coal Company, Limited, while highly mechanized as to the cutting and transportation of the coal, still relied on the hand-loading of coal from the seam onto face conveyors. In these circumstances it was possible to assure that no large proportion of extraneous materials would be loaded with the coal, and the product could be quite well cleaned for the market by screening and hand-picking.Within the past few years, however, the Company has introduced an intensive programme of mechanization which will result in the virtual elimination of hand-loading .of coal. It has been the experience of other producers that mechanical loading inevitably leads to a very large increase in the amount of impurities in the product. This is occasioned by the fact that, at least up to the present, all types of loading machines have relied on the coal being broken from the seam by under-cutting and shooting. In this operation, a certain amount of roof and pavement material inevitably becomes mixed with the coal and, since selective loading is impossible with a loading machine, all this foreign material is loaded out with the product."

Jan 1, 1952

By W. V. McKnight

The paper discusses the equipment and methods used to establish some of the characteristics of a braking system. Some typical tests are described and an explanation of the approach used to derive information from the recorder charts is given.

Jan 1, 1966

By Michael Davies

Mined Material Management Meeting or Missing the Mark? o you agree that we have the technology to consistently design robust M3 facilities? ?YES your experience do these M3 facilities perform as expected during operations? ?USUALLY hat can be done to improve performance, e.g. better communications between project and operating teams, discontinuity between design and operational input by designers, others? ?UNDERSTANDINGWHY THINGS GO WRONG an we identify the key characteristics of ?good M3 facilities?, i.e. ones that are performing well? Can we identify ?good M3 facilities?, i.e. ones that perform well and can be held up as examples? ?WITHOUT QUESTION?? your opinion, for what reason do they not perform as expected? ?NO SINGLE REASON??..

May 1, 2010

By Sib N. Mukherjee

Main ventilation fans are used in all the mines and they run continuously 24 hours a day and 365 days in a year. Any improvement in their performance can lead to considerable power saving. The basic principle for selection, operations, and related measures are discussed in brief in the paper. The contributions of different elements of mine fan on its performance are discussed in brief. The means to improve efficiency of a running fan is also discussed and the importance of saving even 1 Kwh is elaborated. It is found that the cost of the energy saved may even permit a replacement fan to be procured in a few years time.

May 1, 2007

By James A. Finch, Yue Hua Tan, Wei Zhang

"The paper is part of our study of the frother structure-property relationship using bubble rise velocity. Single bubble rise velocity profiles were determined in a 350 cm column for surfactants from the polypropylene glycol (PPG) family. Using velocity at 300 cm, the concentration to reach minimum velocity (CMV) is determined. The CMV is shown to decrease as alkyl chain length (n, number of carbons) increases and as the number of propylene oxide groups (m) increases. Linear correlations log CMV vs. n and m were observed. Taking literature data for critical coalescence concentration (CCC), linear log CMV vs. log CCC correlations were also noted. Mechanisms are briefly discussed, and prediction of CCC made for a commercial polypropylene glycol.INTRODUCTIONAs one of the great enabling technologies of the 20th century, froth flotation is a highly versatile method for physically separating minerals by exploiting differences in wettability (hydrophobicity). Over the last century, flotation reagents have undergone significant developments (Khoshdast and Sam, 2011). One important group of reagents is frothers which are used to reduce bubble size, slow bubble rise velocity and help stabilize froth (Klimpel and Isherwood, 1991).Frothers, originally derived from natural sources (e.g., pine oil and cresylic acid), are largely replaced today by synthetic products which provide more consistent properties. Polyglycols, based on PEO (polyethylene oxide), PPO (polypropylene oxide), or PBO (polybutylene oxide) groups, were first described by Leja and Nixon (1957) and have attracted wide use since then (Farrokhpay 2011). The chemical structure of polyglycols can be represented by a general formula: R(X)mOH, where R = H, or CnH2n+1 and X stands for EO (-C2H4O-), PO (-C3H6O-), or BO (-C4H8O-). The polypropylene glycol ethers (CnH2n+1(PO)mOH) are the most common of these reagents (Pugh, 2007) and the focus of this study.In general, the chemical structure of frother molecules comprises two parts, a non-polar hydrophobic hydrocarbon (alkyl: CnH2n+1) chain and a polar hydrophilic head. By introducing the ether -Olinkage, which acts as another polar site, the propoxy group (-OC3H6-) in the structure makes the frother readily soluble in water (Somasundaran and Wang, 2006), facilitating the industrial use of these frothers. Available as by-products, Dow Chemicals introduced as series of polyglycols, e.g., Dowfroth (DF) 200, 250, 263, and 1012, the most familiar being DF250 (CH3(PO)4OH), a polypropylene glycol methyl ether. While no longer available from Dow, these and other polyglycols are still widely used."

Jan 1, 2016

By E. W. Coderre, R. C. Baxter

"This paper describes the townsite of Wabush and the two railways operated by Wabush Mines for the loading and unloading of iron ore concentrate. The town of Wabush is located approximately 200 air miles north of Sept-Iles, Quebec and is in the Province of Newfoundland and Labrador. Construction of the town-site began in 1961 to provide housing accommodation for the construction force and permanent employees in the mining and milling operations located 4 miles away. Wabush Mines operates two short railway lines in loading and unloading concentrate between the concentrator, located at Wabush, and the pellet plant at Pointe Noire, Quebec. Both of these railways connect with the main line of the Quebec North Shore and Labrador Railway and provide a shuttle service between the two phases of the operation."

Jan 1, 1969

By I. A. Menshikh, S. A. Kotov, N. L. Shinkarkin

All the cycle for conversion of natural and reprocessed uranium of ROSATOM’s “TVEL” Fuel Company is concentrated at the Siberian Chemical Plant. Conversion capacities are located on two sites, i.e. the Radiochemical Plant, which refines feedstock, and the Conversion Plant, which produces uranium oxides and uranium hexafluoride. Liquid radioactive waste arising in the process, after pretreatment, is transferred to a dedicated national operator for underground disposal. Environmental strategies pursued by the Fuel Company involve the introduction of process solutions intended to eliminate liquid radioactive waste and convert it into a solid phase. In the 5–7 years coming, work will be performed to refurbish and upgrade conversion facilities of the Siberian Chemical Plant that will principally change its radioactive waste management scheme. This paper describes the current waste management scheme and sets out planned schemes for management of natural and reprocessed uranium waste, which will be implemented in the refurbishment of conversion facilities of the Siberian Chemical Plant. The new technologies for the management of liquid radioactive waste from uranium conversion described in the present paper have an undeniable advantage over the current technology mainly due to significantly less environmental harm.

Jan 1, 2020

By J. A. Russell

MR. M. W. Boom: I would like to congratulate Mr. Russell on his fine paper. One very good point which has always appealed to me is the smooth working of a steam hoist as compared with electrical. He does not mention the steam hoist at Springhill which has been working there for a good many years. MR. S. R. NEWTON: I have read with a great deal of interest the paper presented by Mr. Russell on the development of haulage engines in the mines of the Dominion Steel & Coal Corporation. He is to be congratulated on having produced a comprehensive article showing, step by step, the various improvements that have been made over the years in the design of such engines. I am quite in accord with Mr. Russell's statement that the positive tooth clutch can have too many teeth, and also that the method of driving a sliding clutch hub of any design should be by means of a hexagon or octagon on the shaft. Where the clutch hub does not of necessity slide on the shaft it can be pressed on and keyed to the shaft in the normal manner. With regard to the 'Cramp' internal-expanding jaw-type clutch, while it is true there are more moving parts than with the clutch consisting of a ring with internal cut teeth and a driver having a fewer number of teeth as .described by Mr. Russell; there are compensating advantages to the internal expanding jaw-type of clutch. The V shaped profile of the teeth permits of engagement of the clutch with very much less 'jockeying' of the drum. This is particularly the case in vertical-lift mine hoists, where it may be necessary to engage and disengage the clutching mechanism at frequent intervals.

Jan 1, 1944

A study was made to determine the effect of increasing concentrations of dissolved oxygen on the floatability of galena pyrite and chalcopyrite. Adsorption, flotation and contact-angle tests were done in deoxygenated, in air-saturated and in oxygen-saturated solutions. The results showed that the adsorption of collector increased as the concentration of oxygen increased. Adsorption followed the exponential law r = kC'/"• Discontinuities in the curves were observed after the adsorption of several monolayers of collector. Although adsorption increased with increasing oxygen concentration, the floatability of the pyrite minerals did not increase, because oxidation had adverse effects on the floatability of these minerals. The floatability of galena was maximum in oxygen-saturated solutions, pyrite was depressed and chalcopyrite was also slightly depressed. Contact-angle tests proved that a bubble could not be attached to large flat surfaces in deoxygenated solutions, because sufficient surface free energy was not available for adhesion after the deformation of the bubble. In the presene of air, all the minerals yielded the same maximum angle of 72 degrees, characteristic of isopropyl xanthate.

Jan 1, 1970

By Bergh. L. C.

On line monitoring and diagnosis systems of process operating performance are becoming an important part of industrial programs, leading to improve process operation and therefore product quality over time. In processes, such as the contact section of a sulphuric acid plant, a large number of input variables, highly correlated, are presented. These characteristics usually pose more difficulties in modelling the process for monitoring and diagnosis purposes. Multivariate statistical projection methods, such as Main Component Analysis, have been proposed to effectively deal with these situations. The application of these ideas to a section of a 2350 MTD sulphuric acid plant, located at the Caletones Smelter, including dry tower, gas blowers, catalytic reactor and S03 absorber processes, is discussed here. A PCA model with eight main components is used for monitoring and diagnosis of more than seventy operating variables. Hottelling's T2 and Q residuals test were used for detecting measurement problems in relevant variables, and for identifying which set of variables were responsible for driving the process outside its normal operating region. Furthermore, considerable information for the correction of the tested operating problems was given by the use of these techniques.

Jan 1, 2007