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By Leiting Yue, Peng Ren, Yu Shen, Zhihong Liu, Haibao Shao, Longgong Xia, Feng Yu

The Kennecott-Outotec Flash Converting technology has been proven as an advanced and mature process in 5 individual plants during the past 2 decades. High grade copper matte (65–72%) produced in the flash smelting, or other smelting technologies is granulated to 3-5mm granules in a water torrent, and further crushed to fine powder (≈50µm) and dried to contain less than 0.3% H2O. Oxygen enriched air, together with fine copper matte powder and lime flux are injected into the reaction shaft by a matte burner. The copper making and slag making reactions will happen in very short time and distance during the particle falling and settling. However, industrial practice has found negative effects caused by sodium contamination. Na is introduced in the copper matte granulating process, and appears as Na2SO4 on particle surface. When Na content was high, scaling problems in the boiler will be worse, and the processing air will be blocked by the growing accretion around the matte burner, and as-produced blister copper is always high in S and O. In this present study, an industrial matte sample was used in the experimental work. Na was introduced into the matte powder by Na2SO4 solution soaking. The burning behaviour of the doped copper matte powder has been investigated as a function of the impurity concentration and processing temperature. Morphology and composition of these samples explained how Na2SO4 converts and reacts in the oxidizing atmosphere, and how they or their converting species influence the burning behaviour of matte particles. Cross-sections of as-prepared samples were analyzed with SEM-EDS, and the reaction mechanism has been carefully interpreted. Results from the present study can benefit both academic and industrial people. INTRODUCTION "Flash Converting" technology was developed jointly by Kennecott Utah Copper Smelter and Outotec (Finland) OY in 1992. The first industrialization of the technology was in Utah Smelter in 1995. Since 2006, it has been successfully applied in Xiangguang Copper, Tongling Jinguan Copper Branch, Fangchengang Jinchuan Copper, and Ningde Southeast Copper. The technology has also been further developed in those smelters. At present, roughly 2 million tons blister copper is produced annually through the Kennecott-Outotec Flash Converting technology, accounting for more than 10% of global primary copper production. The technology has advantages of high efficiency, high sulfur capture rate, good in environmental issues, mature equipment supporting, high automatic control level, low comprehensive energy consumption and flexible connection with the smelting unit, which make the technology to be one of the best choices in investing a new large-scale copper smelter or updating an old copper project in the world.

Jan 1, 2019

By Nick Vagenas

"Loading and transportation are important activities of the mining process. Automation of these activities in underground hard rock mining has been discussed for a long time. This paper deals with the performance evaluation of a prototype automatic Load-Haul-Dump (LHD) vehicle (a 7-ton GHH LF LHD model) operating in Zinkgruvan mine, Sweden. The purpose of the data analysis is to evaluate the operational and maintenance characteristics of the automatic LHD system in the mine. Graphical and numerical methods have been used for the statistical analysis of the data. IntroductionDuring the past years, the idea of integrated automation and tele-operation on Load-Haul-Dump (LHD) machines (Fig. 1) has attracted considerable interest in the Swedish mining industry. This is mainly due to the demand for improvement in the working environment and due to the rapid development of economic and reliable microprocessors for mining vehicles. Several advantages can be foreseen with the application of a Remote-controlled/Automatic LHD (RAL) system in underground mining. Some of them are (1)':• better utilization of working hours;• less interruption in production at shift changes;• better operational control of a fleet of vehicles;• improved safety; and• one operator may be able to operate more than one vehicle simultaneously."

Jan 1, 1993

By R. P. Taylor

"This paper covers the development of the property to its present production level of20,000 tonnes per day from the Valley Mine. It will also review the analysis of various case studies for the expansion of the project to its full potential, and discuss the impact of the recent structural change in the copper market on the development of a large low-grade deposit such as Valley.IntroductionIn 1964 Cominco participated, along with a number of other companies and individuals, in the formation of Valley Copper Mines Ltd. This company was formed in order to facilitate exploration on a large number of mineral claims held by these parties in British Columbia's Highland Valley, approximately 400 km northeast of Vancouver (Fig. I). Cominco 's ownership of Valley Copper was gradually increased over the years bot h through shares gained for exploration expenditures and through shares purchased on the open market. By the mid- 1970sCominco' s interest in Valley Copper exceeded 80%.ExplorationExploration from 1964 to 1969 led to the discovery of a massive porphyry copper depo sit now known as the Valley orebody. A claim boundary divided the deposit with 80% of it on Valley Copper claims and 20070 on claims held by Bethlehem Copper which was already mining adjacent copper orebodies. During the period when the Valley ore body was discovered, exploration by other companies resulted in the discovery of the large Lornex and Highrnont deposits nearby. The stage was now set for the Highland Valley to become an important copper-producing area (Fig. 2)."

Jan 1, 1986

By K. Tsuchihashi, A. Kishimoto, T. Uda, Y. Kado, S. Maruyama

We recently proposed a continuous production process for titanium metal with some experimental results. In the process, titanium tetrachloride is reduced by Mg in the presences of Bi to form a Bi-Ti alloy at 900ºC. At this temperature, the obtained alloy is liquid and allows for the continuous removal of product and heat from the reaction vessel. The obtained Bi-Ti alloy was vacuum-distilled at 1000ºC for 24 hr, and 98 at % (92 wt %) titanium, which was easily crashed to powder, was obtained. Bi solvent was selected because of the highest titanium solubility at 900ºC and the moderate vapor pressure among the candidate metals (Bi, Sn, Pb, Zn, and Sb).

Jan 1, 2014

By R. C. Hartviksen

"The Drumbo Mine is a new gypsum mine located at exit No. 32 of Highway 401 between Woodstock and Kitchener, Ontario. The flat-lying 6-foot (1.8-metre) bed of gypsum is near the base of the Silurian Salina Formation, about 380 feet (116 metres) below surface. The mine is owned and operated by Westroc Industries Limited. A shaft, 12.5 feet (3.81 metres) in diameter, was drilled and then lined with a liner-sinking technique new to this continent. The shaft was completed in the fall of 1977. Gypsum production was started in December 1978, employing a conventional room - and - pillar method of mining.Historical BackgroundA brief mention of gypsum in the Drumbo area is included in a survey of the Ontario gypsum industry by Guillet. This occurrence was discovered in 1958 when National Gypsum conducted some widespread diamond drilling. Western Gypsum Products Limited acquired leases in 1960 and concentrated a drilling program in Blenheim Township near the village of Drumbo; 79 holes were drilled in an area of 1900 acres (770 hectares). Mining rights were then acquired for 170 0acres (690 hectares). A test shaft, 44 inches (1.1 metres) in diameter, was drilled to obtain a 50-ton (45-tonne) bulk sample. This opening will be used as an emergency escape way and for ventilation.Westroc Industries Limited, a wholly owned subsidiary of BPB Industries, has its head office at Mississauga, Ontario and operates gypsum board plants at Mississauga, Vancouver, Calgary, Winnipeg and Montreal. Other gypsum mines are at Windermere, B.C. and Amaranth, Manitoba."

Jan 1, 1983

By Fritz F. Prugger

In August, 1970, during routine shaft grouting, a major water source was intersected. Water and quicksand under very high pressure entered the shaft at a rate of 65 m3 per minute. The mine and both shafts were flooded. The breach was sealed simultaneously from within the shaft and through a relief hole drilled from surface. The mine was dewatered, rehabilitated and the equipment was restored. Production resumed two years after the accident.

Jan 1, 1979

By A. L. Rutledge, R. S. Nichols

"Waste dump development at the Fording River Operation s in British Columbia began in 1971. In 1981, several unique as well as unplanned situations provided an opportunity to study water flows through waste dumps.The key to the drainage is naturally segregated rock sizes .created by end dumping from the crest of a pile. The largest size material accumulates at the toe. Flow rates along the base of the studied dumps varied from 2,800 to 13,500 m3/day or 0.032 to 0. 156 m3/s (1.2-5.5 cfs}. Sediment concentrations in the water ranged from 1 to 1,800 mg/I.This paper describes water flows through dumps of varied lithology and maturity. The results suggest that neither long-term water flow nor contained sediments in small streams are jeopardized when crossed by end-dumped fills.IntroductionThe Fording River Operations are located in southeastern British Columbia approximately 115 km north of the United State s and 10 km west of Alberta, within the medial range of the Rocky Mountains. All production is carried out at elevations ranging between 1,600 and 2,200 m above sea level.The property is within a continental climatic zone, with temperature extremes of - 40°C in January to +35°C in July. The average annual precipitation of 335 mm of rainfall and 390 cm of snowfall feeds the numerous seasonal, small drainage courses along the Fording River valley.Since start-up in 1971, 149 million bank cubic met res of waste from truck-shovel and dragline mining have been placed in numerous dumps or ""spoils"". The dumps were developed to the point that several unique situations could be studied. During the peak run-off period of May-June 1981, water flow studies were performed on dumps of varied lithology and maturity. This paper describes the results of the study."

Jan 1, 1982

By D. M. Cruden

"When two discontinuities form a tetrahedral wedge in a rock slope, a factor of safety for the wedge can be simply calculated (if motion is driven only by gravity and resisted only by friction) from plots of the normals to discontinuities on an overlay of a polar, equal-area spherical projection to which the great circles of a similar equatorial projection have been added.IntroductionThe stability of slopes in rock masses is often controlled by the discontinuities that exist in the masses. In particular, the geometry of the discontinuities constrains the ways in which the mass may fail. Displaying the orientation of the discontinuities on a spherical projection has been found to be a useful way of identifying possible failure modes. The most concise display shows the orientation of the normals (or poles) to the discontinuities that compose the fabric of the rock mass. Computer processing of large samples of discontinuity orientations is necessary if the sampling biases identified by Terzaghi (1965) are to be routinely corrected. Fortunately, displays of the poles to discontinuities (or pi diagrams) are relatively easily produced on the line printer of a computer or by a computer plotter (Cruden , 1978; Ramsden and Cruden, 1979). Unfortunately, further analysis of the stability of a rock mass has tended to use traces of typical discontinuities on a spherical projection rather than pi diagrams; examples may be seen in Hoek and Bray's book (1981)."

Jan 1, 1990

By Robert B. Parsons

"The customary onslaught of government budgets this spring offers lots of interesting reading to the mining industry.While the favourable changes tend to get all the fanfare, there are some ""sleepers"" in the host of proposed changes which will be bitter pills for some mining people to swallow.IntroductionOn a scale of one to ten, the Canadian mining industry will probably give this year's federal and provincial budgets a score that is pretty close to five. Although some budgetary proposals are generally perceived to be favourable to the industry, there are other provisions (and lack of provisions) which are considered to be negative.This month, Tax Notes examines in a summary manner the principal features of the 1985 federal and provincial budgets which are of particular interest to this country's mineral industry."

Jan 1, 1985

By Eric Best

"In the past two to three years, all continuous mining machines at the Potash Corporation of Saskatchewan Mining Limited, Lanigan Division, have been changed over to a new cutting pattern using 1 -inch- and 1-3/l6-inch-diameter self-sharpening pencil bits. The bits are arranged in a cone-type pattern across the face on 2 1/2 -inch and 3-inch spacing. The result is that the ore is removed by chipping and flaking. Previously, rap-lock bits were used, with the pattern being several bits in single rows at wide spacings. The cutting action was grinding and breaking.Besides improved penetration rates and lower bit costs, there are many other advantages. The ore size is much smaller, resulting in less wear and tear on conveyors and other associated equipment. Feeder-breakers are no longer routinely set up at the head end of every extensible belt, as the banana-shaped chunks of ore that used to require breaking are no longer produced. Also, less dust is generated by the cutting heads and fewer stops are required for bit changes. Even the mill operation has been improved, as fewer fines are produced.Further improvements are still sought after, but, all in all, the new cutting pattern is considered to be a giant step forward from the old method."

Jan 1, 1981

By R. E. Lawless

The transportation challenge began with the need to move millions of tons of coal annually from Western Canada to Ontario. The paper will discuss the options which were available, the final mode selected and the economic trade-offs which were involved. It will outline the demands of unit train technology and the effect of transportation requirements on the other elements of the whole system.

Jan 1, 1979

By James E. Rider

"Fractures in mine hoist drumshafts are rare. We know of no previously reported attempts to repair a fractured drumshaft; any feasible method would involve welding and the associated problems of distortion, crack formation and strength.In June 1984, a fracture was discovered in the drumshaft of the production hoist in the Teck Corporation, Lamaque Division Mine at Val d'Or, Quebec. Delivery time on a new shaft would have been at least six months. The shaft was repaired in ten days and the total out -of-service time was four weeks.This paper describes why the shaft failed, how it was repaired, and the special alignment procedures employed during re-installation to minimize stresses in the repaired area.IntroductionThe performance of a mine hoist drumshaft is absolutely critical to mine operation. An inoperable drumshaft means no hoist, which in turn means no production or mine operation.Fractures in mine hoist drumshafts are rare. Previously when they have occurred, no one has seriously considered attempting a repair because of problems involved. Any feasible method would involve welding, which raises several major problems - namely, metallurgical, alignment, and strength.In July 1984 this very situation occurred at the Teck Corporation, Lamaque Division Mine in Val d'Or, Quebec.It was recognized that a new shaft would take at least 6 months' fabrication and delivery time. However, having had some experience at repairing broken shafts in other machines under similarly desperate circumstances, and after due consideration, it was concluded that by applying the correct techniques and engaging the right expertise, it would be possible to perform a repair and have the mine back in operation within a month.Thanks to outstanding efforts by all, the repair was accomplished in ten days and total out-of-service-time was only four weeks. The causes of the failure were determined and the calculated stress levels confirmed by strain gauge measurement during operation.The success of this project was achieved by adhering rigorously to fundamental management and engineering principles."

Jan 1, 1988

By S. Wood

"Plastic Filled Valley (PFV) wire rope represents a significant development over the design of conventional wire rope. A sealing thermoplastic is impregnated under controlled conditions of temperature and pressure into a conventional lubricated wire rope to produce a lattice of plastic which surrounds and separates the strands from each other and from the core. Metal-to-metal contact is thereby alleviated and the lubricant is sealed in. The wear resistance, rope breaking load, fatigue resistance and crushing resistance are all increased. The result is a rope which offers exceptional service life.Laboratory tests carried out in Canada and at the University of Stuttgart, in West Germany, confirm the increase in fatigue life. The field trials conducted so far have indicated that the results obtained in the laboratory can be duplicated in the field.IntroductionIn times of double -digit inflation, the consideration given to operating costs throughout industry commands considerable attention. The same can be said of the mining industry. A set of large-diameter wire ropes used on the huge draglines in strip mining can cost in excess of $100,000. Because a machine may use three sets of rope s each year, it is clear that the costs of wire rope can contribute a considerable percentage to any operating budget. As wire rope is a product which is used extensively throughout the mining industry, it would appear timely to turn our attention to any ""Method of Extending Wire Rope Service Life"" in order that wire rope life can be optimized and wire rope costs can be minimized."

Jan 1, 1982

By Denis Landry

"RÉSUMÉAu cours de dix dernières années, la compagnie Maghemite a développé, expérimenté et breveté un nouveau precédé de concentration du minerai de fer à partir de la récupération d'hématite présente au bassin de sédimentation de la Compagnie Minière Québec Cartier.A partir de cette nouvelle technologie de concentration par induction, la compagnie Maghemite produit une poudre d'hématite qui est mélangée avec du strontium carbonate à un ratio de l à 6 en poids. Le mélange homogène est achemine sur un disque d'agglomération, et ensuite incorpore dans la fournaise de la Compagnie Minière Québec Cartier. Le temps de cuisson et la température (l200°C) correspondent exactement aux critères nécessaires pour la fabrication d'aimants de céramique, Grade 5, à partir de la poudre de ferrite.IntroductionMeghemite a débuté sa production de poudre de ferrite au printemps 1986et prévoit une production de 20 000 tonnes par année dans cette nouvelle usine. A très court terrne, une usine sera construite pour la production de cinq à dix millions de Iivres d'aimants permanents par annee et à long terme qu'une usine de fabrication par robotique de moteurs à aimants permanents, utilises dans I'industrie automobile. La poudre de ferrite à base de strontium est une compose ferro-magnétique forme d'une molécule d'oxide de strontium et de six molécules d'hernatite. Ce compose d'hexa fluorite de strontium a une force tres puissante et fournit la source d'énergie magnétique la moins dispendieuse comparée aux autres aimants permanents. L'utilisation des aimants de céramique formes d'hexa fluorite de strontium a connu un croissance phenornenale depuis 1970 pour atteindre un marché de 500 millions de livres par année en 1985.II n'y a aucune autre usine de production commerciale de poudre de ferrite à base de strontium au Canada. Le facteur determinant qui a favorise l'etabilissement a Port Cartier est base sur la réduction de 30% du cout des aimants de cerarnique provenant de notre poudre. Notre debouche majeur se situe aux États-Unis et vise la production des aimants de cerarnique pour les moteurs utilises dans les automobiles, les ordinateurs et les appareils ménagers, L'objectif de cette compagnie est de réduire le prix futur des aimants de cerarnique à environ 30% du prix actuel.L'usine commerciale de production de poudre de ferrite est maintenant opérationnelle. Le financement et la construction de cette usine sont Ie résultat de l'opération d'une usine pilote sur une période de 5 ans afin de récupérer l'hematite d'un haut niveau de pureté provenant de résidus de I'usine de bouletage de la Compagnie Minière Québec Cartier (CMQC) à Port Cartier. La fournaise de CMQC est utilisee pour chauffer les boulettes cornposees d'un mélange de carbonate de strontium et d'hematite d'un haut niveau de pureté en étalant environ 5 tonnes à l'heure de ces boulettes au-dessus du tablier de boulettes de fer dans une des fournaises fonctionnant à environ 450 tonnes à l'heure."

Jan 1, 1987

By Robert B. Parsons

"The budget that was tabled by Finance Minister MacEachen on November 12, 1981 will result in a major tax reform of Canada's income and sales tax systems, the likes of which have not been witnessed by taxpayers since 1971. All segments of the economy will be affected one way or another by the far-reaching budget proposals; the mining industry did not escape untouched.Important changes will be introduced which will alter some of the fundamentals of structuring mineral resource ventures in Canada. This month, Tax Notes examines these changes, and also summarizes the other highlights of this key federal budget.IntroductionFinance Minister MacEachen's budget, with its lower personal tax rates, loophole plugging and tax shelter bashing, represents the biggest shakeup in our tax system since tax reform in 1971. In his budget, presented in the House of Commons on November 12, Mr. MacEachen proposed substantially lower tax rates for middle and upper income individuals, with the top federal and provincial tax rate dropping to about 50%, but in return he eliminated most of the opportunities for individuals, and corporations, to reduce or defer taxes through a wide variety of tax shelter and tax planning mechanisms.Although many of those budget proposals that dealt with the resource industries focused on the implementation of the September 1, 1981 agreement reached by the federal and Alberta governments concerning the National Energy Program (see Tax Notes in the December 1981 issue of the Bulletin), the budget also contained some proposed amendments that would have significant implications for investment in the mining industry.This month, Tax Notes examines these latter proposals, and also summarizes very briefly those budget proposals which are not unique to the resource sector."

Jan 1, 1982

By D. Saramak, T. Gawenda, Z. Naziemiec, A. Saramak

"Crushing and grinding operations are burdensome to the environment due to generating large amounts of dust, noise and waste during course of comminution operations. An indirect negative contribution of industrial crushing processes is an increase of carbon dioxide emissions, which is a byproduct in energy production processes. On the other hand comminution processes in ore enrichment technology are essential due to liberation the useful minerals from the gangue, and producing the demanded particle size fractions of products. The article concerns investigation over negative influence of comminution devices on environment in terms of dust and noise emissions. Several various crushing devices were under investigations, both in laboratory and in industrial scale.The obtained results were analyzed in terms throughput and energy consumption achieved in various crushing devices. The test results allow to conclude that an intensity of dust generation for individual types of crushing devices is varied. An additional aim of this article is to link the aspect of mineral processing with its environmental impact and hence an influence of raw materials beneficiation industry on the quality of life of residents in immediate and close vicinity.INTRODUCTIONMineral raw materials beneficiation processes are an integral part of multi-stage processing of coal, iron ore and non-ferrous metals, production of aggregates, cement, or precious metals and stones. One of the common features of all beneficiation operations is their high energy consumption, which is mainly connected with various operations of feed particle size reduction. Comminution processes in ore enrichment technology are essential to expose and liberate the useful minerals from the gangue, while in aggregate production processes – to obtain the demanded particle size fractions of products. Crushing operations are characterized by a high degree of negative impact to the environment and humans, mainly due to:• High electricity consumption, which indirectly contributes to the increased emissions of carbon dioxide into the atmosphere, since CO2 is often one of the byproducts of energy production;• Relatively rapid wear of device working parts, what forces a production of spare parts and involvement of steel industry;• Intense dust pollution generated during crushing and grinding processes. This is one of the factors affecting the air quality and the consequent deterioration of the living conditions of inhabitants near mines and processing plants; and • Excessive noise emissions."

Jan 1, 2016

By James E. Rider

"Fractures in mine hoist drumshafts are rare. We know of no previously reported attempts to repair a fractured drumshaft; any feasible method would involve welding and the associated problems of distortion, crack formation and strength.In June 1984, a fracture was discovered in the drumshaft of the production hoist in the Teck Corporation, Lamaque Division Mine at Val d'Or, Quebec. Delivery time on a new shaft would have been at least six months. The shaft was repaired in ten days and the total out -of-service time was four weeks.This paper describes why the shaft failed, how it was repaired, and the special alignment procedures employed during re-installation to minimize stresses in the repaired area.IntroductionThe performance of a mine hoist drumshaft is absolutely critical to mine operation. An inoperable drumshaft means no hoist, which in turn means no production or mine operation.Fractures in mine hoist drumshafts are rare. Previously when they have occurred, no one has seriously considered attempting a repair because of problems involved. Any feasible method would involve welding, which raises several major problems - namely, metallurgical, alignment, and strength.In July 1984 this very situation occurred at the Teck Corporation, Lamaque Division Mine in Val d'Or, Quebec.It was recognized that a new shaft would take at least 6 months' fabrication and delivery time. However, having had some experience at repairing broken shafts in other machines under similarly desperate circumstances, and after due consideration, it was concluded that by applying the correct techniques and engaging the right expertise, it would be possible to perform a repair and have the mine back in operation within a month.Thanks to outstanding efforts by all, the repair was accomplished in ten days and total out-of-service-time was only four weeks. The causes of the failure were determined and the calculated stress levels confirmed by strain gauge measurement during operation.The success of this project was achieved by adhering rigorously to fundamental management and engineering principles."

Jan 1, 1988

By V. C. Wittchen, T. R. Yu, J. E. Croxall

"The consolidated rockfill at Kidd Creek Mines is a weakly cemented, minus 15 cm aggregate which posed problems for conventional drill/blast drifting methods. Consequently, lateral access to mineable ore adjacent to backfilled areas was gained by drifting around the fill in shattered rock.In mid-1987, Kidd Creek Mines began to investigate means of mechanically excavating drifts in backfill . The results of this investigation led to a trial program using a Dosco MK-2A Roadheader to excavate the required drifts in backfill.The roadheader was tested at Kidd Creek Mines from July to November 1988, in 28-735 X /C to be used as the top access for drilling and blasting 32-74/ ST. During this period, the roadheader excavated 54 m of a 4.3 m by 3. 7 m arched drift in backfill. Cutting rates over the period averaged 0.8 m/cutting hour as projected with a daily high of 2.0 m/cutting hour.Wood-lagged 2-piece steel arches on 1.2 m centres were chosen as ground support for the trial. Shotcrete will be tested in a roadheader drive for its potential to improve productivity by replacing the steel arches.The trial program included evaluations of point-attack picks, two sizes of cutter motor, 20 MPa (3000 psi) water-assisted cutting, cuttings-removal systems, and environmental control devices."

Jan 1, 1990

By Helmut Lerchs

An open-pit mining operation can be viewed as a process by which the open surface of a mine is continuously deformed. The planning of a mining program involves the design of the final shape of this open surface. The approach developed in this paper is based on the following assumptions: 1. the type of material its mine value and its extraction cost is given for each point; 2. restrictions on the geometry of the pit are specified (surface boundaries and maximum allowable wall slopes); 3. The objective is to maximize total profit-total mine value of material extracted minus total extraction cost. Two numeric methods are proposed: A simple dynamic programming algorithm for the two-dimensional pit (or a single vertical section of a mine), and. a more elaborate graph algorithm for the general three-dimensional pit. ASURFACE mining program is a complex operation that may extend over many years, and Involve huge capital expenditures and risk. Before undertaking such an operation, it must be known what ore there is to be mined

Jan 1, 1965

By M. Fafard, F. Chevarin, D. Ziegler, H. Alamdari, M Kavand

"Carbon anodes, used in the Hall-Heroult process, are consumed by the electrochemical reaction to produce metallic aluminum. It is also consumed by parasitic reactions with air and CO2. The carbon anode is made of petroleum coke with different particle sizes, butts (recycled anodes) and coal tar pitch. The mixture of fine particles (less than 150 µm) of coke together with the pitch material forms a matrix, binding the large coke particles together. It is generally thought that the binder matrix is more reactive than the other anode constituents. This conjecture was not clearly proved in the literature. The present study is focused on the CO2 reactivity of binder matrix and anode constituents at 960°C, both under chemical regime (100% of CO2) and under a concentration gradient (diffusion). The apparent reaction rates of these materials were measured. The role of the binder matrix in anode consumption and its disintegration (dusting phenomenon) was discussed.INTRODUCTIONThe metallic aluminum production is one of the most important industries in Canada. The Al metal is obtained by the Hall-Héroult process. The principle of this process is the electrochemical reduction of alumina in molten cryolite carried out by an electrical current between carbon anodes and cathode at 960°C (Equation 1). The carbon anode is typically composed of calcined petroleum coke (65 wt.%) and recycled anode (called also butt, 20 wt.%) with coal tar pitch (15 wt.%), playing the role of cement to ensure the cohesion of the anode block."

Jan 1, 2016