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By J. Z. Yuan

The purity of rectorite is only about 70% after preliminary mineral processing, which has limited its application. In this research, different pulp densities, different dispersants, different dispersing methods and purification flow sheets were used to purify rectorite. The results show that it is possible to obtain high pure rectorite clay with the purity above 90% and concentrate yield between 24.9% and 29.4% by the purification process with composite dispersants, stirred mill grinding dispersion and so on. The obtained high pure rectorite can be further used in rectorite nanocomposites.

Jan 1, 2014

By H. D. Yu

In this paper, an evaluation about the process mineralogy of the rich iron mine in Mongolia with comprehensive methods is given; this provides foundation of the comprehensive recovery of iron and cobalt in the ore. The research shows that the iron?s grade is 61.23%, Co?s grade is 0.02%, the ore is rich iron ore and its Co content also reaches border mining grade. For the ore, if want get high grade iron concentrate powder, must identify the mineral composition and the occurrence of iron and take into ac-count the recovery of Co content as associated resources. Chemical phase analysis results show that 86.35% of iron exists in magnetite, which means that the theoretical recovery ratio of iron is close to 86%. Minerals spectrum analysis confirmed that the magnetite containing a small amount of Mg, Al, and other impurities, the actual iron minerals to 70.28%, which means that theoretically iron grade iron concentrate only close to 70.28%. Based on the result of iron chemical phase analysis, by investigating the liberation of sulfide minerals and gangue, the recovery index of iron can be forecasted, when grinding fineness is 35%, 45%, 55% and 65% bellow 0.074mm,theoretical content of Fe in iron concentrate separately is 67.71%,67.88%,68.78%,and 69.43%,accordingly the theoretical recovery of Fe is 87.38%,87.05%,86.92% and 86.63%. From the perspective of process mineralogy, the forecast mineral beneficiation indicators show that the ore is easy sorting ore, iron processing operations have higher recovery rate, but wants sorting of high-grade iron ore concentrate still need appropriate grinding fineness. Furthermore, associated element Co, existing mostly in pyrite and pyrrhotite, is valuable in the ore. Pyrite and pyrrhotite have ideal liberation under grinding, so cobalt can be easily enriched in sulfide concentrate.

Jan 1, 2014

By Sirish L. Shah

It is now common to have archival history of thousands of sensors sampled every second over long time. Yet we frequently have process engineers complain:??.We are drowning in data but starving for information??. How can these rich data sets be put to use? This paper addresses the issue of information and knowledge extraction from data with emphasis on process and performance monitoring including fault detection and isolation. Most of the major plant, factory, process, equipment and tool disruptions are avoidable, and yet preventable fault detection and diagnosis strategies are not the norm in most industries. It is not uncommon to see simple and preventable faults disrupt the operation of an entire integrated manufacturing facility. For example, faults such as malfunctioning sensors or actuators, inoperative alarm systems, poor controller tuning or configuration can render the most sophisticated control systems useless. Such disruptions can cost in the excess of $1 million per day and on the average they rob the plant of 7% of its annual capacity. Over the last decade the fields of multivariate statistics and data visualization and analysis methods have merged to develop powerful sensing and condition-based monitoring systems for predictive fault detection and diagnosis.These methods rely on the notion of sensor fusion whereby data from many sensors or units are combined with process information, such as physical connectivity of process units, to give a holistic picture of health of an integrated plant. Such methods are at a stage where these strategies are being implemented for off-line and on-line deployment. This article attempts to outline the field of sensor fusion - the application of signal processing methods, in the temporal as well as spectral domains, on a multitude and NOT singular sensor signals to detect incipient process abnormality before a catastrophic breakdown is likely to occur Keywords: Process analytics, process and performance monitoring, multivariate statistical analysis, sensor-fusion

Sep 1, 2012

By T. S. Reddy

Research and Development Centre for Iron and Steel (RDCIS) a unit of Steel Authority of India Limited (SAIL) is continuously engaged in reduction of energy consumption at SAIL plants by implementing innovative and new concepts. In this regard, continuous efforts are being made to recover waste heat in Sinter Plants. This paper discusses existing waste heat recovery measures taken and proposed measures planned in Sinter Plants. One such effort is on waste heat recovery from sinter coolers. Hot sinter is discharged to the crusher at the end of the sinter machine at a temperature of 500 to 800°C. Temperature of hot sinter is brought down to nearly 100°C in the sinter cooler with air-cooling. The air after cooling the sinter is generally discharged to the atmosphere at about 225 to 300°C. It is planned to recover heat from the hot air that is being released to atmosphere and heat the process water, which is being added at ambient temperature in mixing drum at Bhilai Steel Plant. The temperature of raw sinter mix will be raised by addition of this hot water, which will help in improving the productivity of sinter machine. It is estimated that Waste heat recovery to the tune of 1.5 to 2.0 Gcal/h is possible with reduction in CO2 emissions in the range of 4000 to 5000 ton/year. The novel approach that is being adopted is addition of hot water in mixing drum for higher sinter productivity for the first time in India. Keywords: waste heat recovery, sinter plant, hot water generation, emission reduction, CDM

Sep 1, 2012

By J. Quinteros-Riquelme

Despite increasing demand, the supply of silver is limited by its inadequate recovery from ores. Due to its scarcity in nature, its high ore variability and complex mineralogy of current silver deposits, its recovery by mineral froth flotation presents a real challenge for process engineers. A silver ore often contains significant amounts of five to ten different silver minerals and knowledge of the mineralogy is a necessary precursor to flotation testing. In this work, a complex silver ore was treated by using batch laboratory flotation, in an effort to find the best experimental conditions to obtain the optimal silver recovery. Mineralogical characterization of feed samples was conducted using a combination of tools, namely the mineral liberation analyzer (MLA) and inductively-coupled plasma mass spectrometry (LA-ICP-MS), which indicated that most of the silver occurred as ?invisible? silver in pyrite. The pyrite assay of the ore was approximately 4%. The ore was processed in two flotation stages. The first stage, sulphide flotation, aimed to collect a sulphide mineral rich concentrate; then a non-sulphide flotation stage was performed by adding sodium sulphide and collectors to the remaining material in the cell, with the objective of obtaining a pyrite rich concentrate. To reach the target recovery of silver from this ore, various variables were altered. In the first stage: mixed collectors, activators, dispersants, and mainstream inert grinding were assessed. In the second stage, the conditions for sulphidization and subsequent flotation were both investigated. From the grade recovery curves for silver and sulphur it was possible to observe a similar metallurgical behavior for both elements, supporting the results given by the mineralogical characterization. Keywords: silver oxide, froth flotation, sulphidization, mig

Sep 1, 2012

By B. W. Zhao

Quantitative analysis of minerals composing in ore is primary in process mineralogy, a veracious quantification and analysis is very crucial to optimize or design a beneficiation process, especially for a low grade and complicated ore. This paper will discuss a SEM-EDS based quantitative analysis developed in JKtech Australia through an example from Jinchuan lean ore. For a low grade, com-plex intergrowths and texture lean ore, chemical phase analysis of value minerals and identification by optical microscope are very essential, unite the SEM-EDS based quantitative analysis, we can understand exactly the lean ore, explain and quantify the process performance.

Jan 1, 2014

By M. Ito

Cobalt-rich ferromanganese crust and nodule ores from seamount areas contain volcanic and sedimentary rocks as substrate or nuclei and these ores require mineral processing to remove the substrate/nuclei rock before smelting. This paper reviews the results of jig separation and air table treatment for the coarse fraction and flotation and hybrid jigging for the fine fraction. Using these techniques substrate/nuclei rock was removed from the cobalt-rich ferromanganese oxide components. The mineralogical properties and metallurgical treatment methods including hydrometallurgical treatment of low grade ore is also reviewed.

Sep 1, 2012

By R. D. van der Weijden, W. F. C. van Wageningen

"Copper(II) can be recovered or removed from acidic copper sulfate solutions as cuprite or metallic copper powder by reduction with carbohydrates (van der Weijden et al., 2001, 2002). In order to make this process suitable for a commercial scale pipe reactor, process conditions and reactor configuration need to guarantee proper throughput of the dilute suspension. This is where crystal engineering also comes into view. Copper powder characteristics, such as size and shape of particles, influence the tendency to adhere to reactor walls and to agglomerate, which in turn influence the throughput. Furthermore, separation, drying, packaging and product quality, are dependent on the powder characteristics.In this paper the effect of both chemical and physical parameters on the shape and size of particles were systematically studied in a number of autoclave experiments. These parameters include mixing, Cu(II) concentration, pH, temperature, seeding, use of additives and reactor materials. Additionally, Monte Carlo simulations of copper growth inside a Kenics static mixer were made. Results show that the use of additives, and the use of static mixers influence particle characteristics the most."

Jan 1, 2003

By B. Hosseini

Considering the subtractive trend of the sulfide and high-grade zinc ores in worldwide and also in Iran, Nowadays special attentions have been drawn to the extraction of zinc from its other resources such as low-grade oxide ores and secondary resources. Oxide ore of the eastern part of Mehdi-abad lead and zinc mine is silicate and has an average grade of 7% (with cut off grade of 4%). Main mineral of the Mehdi-abad ore is Hemimorphite and this mineral is associated with Goethite, Hematite, Ferrous Dolomite, and Manganese oxide mineral so that oxides of Iron, manganese and silica include almost 50% of the total ore. In this paper, the results obtained from the leaching kinetic study of the low-grade zinc oxide ore using Sulfuric acid are presented. The effects of particle size, reaction temperature, acid concentration, and solid percent on the dissolution rate have been investigated. The results obtained from the Taghochi approach showed that the zinc recovery is about 78% under the following optimized conditions: particle size: 106µm, leaching time: one hour, temperature: 45°C, acid concentration: 15% and solid percent: 15%. Kinetics study was revealed that zinc minerals leaching controlled by diffusion rate through the product layer during leaching time with the activation energy of 5 KJ/mol and compliance with the 1- (2/3. x) ? (1- x) 2/3 = k. t model. Keywords: leaching kinetics, kinetics models, sulfuric acid leaching, taguchi methods, low grade zinc ore, mehdi-abad mine

Sep 1, 2012

By Shuji Owada, Shinya Suzuki, Chiharu Tokoro, Daisuke Haraguchi, Sayaka Izawa

"Coprecipitation with ferrihydrite has been one of the major treatment method for As(V) removal from wastewater such as acid mine drainage. We already confirmed coprecipitation of As(V) with ferrihydrite consists of two kinds of mechanism; one is two dimensional As(V) uptake to the surface of ferrihydrite by surface complexation and another is three dimensional As(V) uptake into ferrihydrite by surface precipitation. We also already confirmed As(V) adsorption process by ferrihydrite could be quantitatively evaluated by original surface complexation model with parameter values reported by Dzombak and Morel. However, As(V) coprecipitation process couldn’t quantitatively be represented by only the original model. In this study, construction and calculation using surface precipitation model were attempted for As(V) coprecipitation treatment with ferrihydrite. In the surface precipitation model, precipitation was described by the formation of solid compound between ferrihydrite and ferric arsenate. Activity of these precipitates was determined by surface precipitation ratio of FeAsO4(s) obtained experimentally from XANES analyses. Solubility products of surface precipitation of FeAsO4(s) (Ksp_FeAsO4(suf.)) were determined by fitting to sorption densities and surface precipitation ratio in each condition. The values of Ksp_FeAsO4(suf.) were determined 10-7.7 at pH5 and 10-10.2 at pH7, respectively. Based on the obtained Ksp_FeAsO4(suf.) value, As(V) removal and isotherm were calculated for As(V) co-precipitation treatment using surface precipitation model. Good agreement between experimental and calculated values was observed. These results were suggested that the quantitative prediction of As(V) co-precipitation treatment was possible if Ksp_FeAsO4(suf.) value was estimated experimentally."

Jan 1, 2014

By William Skinner, Jennifer MacCarthy, Jonas Addai-Mensah, Ataollah Nosrati

"Acid leaching in agitated tanks is central to hydrometallurgical processing for valuable metals’ (e.g., copper, gold, nickel and cobalt) recovery from low grade (e.g., < 2 wt.%) ores. In this study, atmospheric leaching behaviour of Australian saprolitic nickel (Ni) laterite ore using sulfuric acid was investigated under isothermal, batch conditions at pH 1. The effect of primary process variables comprising time (4 h) and temperature (70 and 95 oC) on the leaching mechanisms and kinetics was established for -2 mm, low grade (~1 % Ni) saprolitic ore dispersions at 40 wt.% solid loading. Leaching proceeded incongruently, reflecting the proliferation of gangue minerals’ constituent elements (e.g., Mg, Al, Fe) alongside Ni and Co in the pregnant leach solutions (PLS). Subsequent analysis showed that 89% Ni and 78% Co were extracted after 4 h at 95 oC whilst at 70 oC the recoveries of these metals were markedly low (< 25 %). Overall, 177 and 644 kg H2SO4 /t dry ore were consumed at 70 and 95 oC, respectively. Activation energy of 79.0 ±1.0 kJ/mol was estimated for the mechanism of Ni and Co leaching and associated kinetics. Particles size analyses indicated that when the breakage of frail laterite particles due to shear is taken into consideration, differences in feed and leached product particle size distributions were insignificant , despite a remarkable increase in BET specific surface area of the product. Mineralogical analyses of the feed ore and leached solid products revealed a sub-crystalline silica phase enrichment of the latter. The overall results suggest that the mechanism of acid leaching of saprolitic Ni laterite may be described by a chemical reaction-controlled, shrinking core model."

Jan 1, 2014

By F. L. Wang

The purification process of water-mining carnallite and rough potassium chloride concentrate from Qinghai Salt Lake Industry Group Co. Ltd. are investigated by the preprocessing-reverse flotation technology respectively. The results show that the impurities such as calcium sulfate and sodium chloride can be effectively removed from water-mining carnallite ore and rough potassium chloride concentrate by the new technology, the low-sodium carnallite is obtained and the final potassium chloride product greatly upgraded. The content and the recovery of KCl in the low-sodium carnallite are 25.78% and 97.50%, meanwhile the content of NaCl, CaSO4 in the low-sodium carnallite are 0.56% and 0.24%, and the removal of sodium chloride and calcium sulfate in the low-sodium carnallite are 97.48%, 85.10% respectively. The KCl content and recovery of high quality potassium chloride product are 98.25%, 96.70%, and CaSO4 content is 0.40% with 83.24% calcium sulfate removed in the high quality potassium chloride product.

Jan 1, 2014

By Y. G. Sun

This paper mainly reported separation manganese silver oxidized ores process by amylum de-gradation reduction and its influencing factors. When dosage is given according to nMn : nH2SO4 : n(C6H10O5)n : nH2O=1:k21.8: k116.66:30, the amount of up to 95.93% Mn leach rate and less than 2% silver loss can be obtained. Cyanidation process was used to extracted silver from leaching Mn residues. Silver leach rate could reach 94.15% at consumed amount of 1kg/t NaCN for 1h. Silver leach recovery rate was more than 92.27% by leaching Mn and cyanidation two-step processes so manganese and silver were separated effectively.

Jan 1, 2014

By Sergio Castro, Janusz Laskowski

In the flotation in highly concentrated electrolyte solutions not only ionic strength but also chemical composition, flotation pH and mineral properties play an important role. As a result an improvement or depression may be observed. A strong improvement in the floatability of hydrophobic bituminous coals and other inherently hydrophobic minerals is characteristic for the "salt flotation process", which is carried out in concentrated electrolyte solutions at natural pH and without addition of any flotation reagents. However, pH is a key factor when saline and hipersaline waters with hydrolyzing metallic ions are used as process water. In the case of flotation of Cu-Mo sulfide ores in seawater, molybdenite is strongly depressed by the Mg2+ hydrolysis products when pH is raised to depress pyrite. Process water with a high content of Mg2+ and Ca2+ ions, and this also includes seawater, have deleterious effect on the anionic flotation of industrial minerals with fatty acids. The flotation of potash ores is carried out in NaCl-KCl saturated brine (6-7 mole/L of NaCl and KCl) with the use of long-chain amines. Such a high electrolyte concentration changes dramatically the amine Krafft point making the collector insoluble in brine; its mode of action entirely differs from that in conventional flotation processes.

Jan 1, 2014

By John A. Rumball, Martin R. Houchin

Data from autogenous and semi-autogenous tests in a 1.67m diameter mill have been analysed in terms of a new model for rock abrasion. This model defines specific rate as the rate of production of fines (material less than 13mm) per unit mass of rock, where the term “rock” is applied to all ore pieces of ore coarser than the grate size. In most cases, an allowance for preliminary rounding and cleavage was made. A method has been developed to analyse steady-state data, using piecewise fitting to the cumulative size distributions. The model was compared to the well-established models, which are based on the population balance method. The specific rate increased for all rock sizes as the volume of 100mm balls in the mill was increased. Tests using a coarser feed and smaller balls provided further evidence that once rocks are rounded, abrasion is due to localised surface damage, caused by impacts, rather than rotational shear. An allowance for rapid rounding of jagged rocks, followed by less rapid abrasion of rounded pebbles was also tested, but the analysis was not conclusive. The average specific rate is a useful measure of the capacity of a primary mill. The effect of power intensity (kW/t of ore) was also investigated as a means of extrapolating the pilot-plant data to large production mills.

Sep 29, 2003

By Xiqing Wu, Tao Yue

"Magnetic seeding co-agglomeration, i.e. adding magnetic seeds, organic depressant (such as the starch), and pre-magnetization for co-agglomeration, was applied in the reverse flotation for hematite ore slimes. Samples of the hematite ore slimes and the pure hematite fines were investigated by the co-agglomeration, respectively. Flotation tests suggest that the depressing effect of starch in the flotation was further enhanced with the addition of magnetic seeds and the pre-magnetization. Following the laser size analysis and flotation tests, TOC adsorption analysis, VSM, surface charge measurement, AFM, FTIR study, and SEM imaging have been utilized to understand the depressing mechanism. Based on the results it was demonstrated that with the addition of magnetic seeds and the low field pre-magnetization, the adsorption of starch onto hematite minerals was strengthened through the magnetic seeding co-agglomeration. The co-agglomeration improved the flotation performance by introducing the magnetic interactions and acting the bridging adsorption of starch between fine hematite and magnetic seeds in a suspension, and then resulting in an intensified coverage of the starch onto hematite particles and positive action in the coagglomeration under the pre-magnetization.INTRODUCTIONFlotation is undoubtedly the most important and versatile mineral processing technique, and both its use and application are continually being expanded to treat greater tonnages and to cover new area. However, its influence was limited to a relatively narrow particle size range of 5–300 µm (Wills and Napier-Munn, 2006). The main reason behind this limitation lies in that fine particles have high specific surface area, so need relatively high dosage of reagents (collectors or depressants), and exhibit poor flotation performance while intermediate or properly-sized particles produce high flotation kinetics and need low consumption of reagents. In order to increase the recovery of fine particles, quite a few of flotation techniques have been investigated. Most of them are based on particle aggregation, namely, by enlarging the apparent particle size, such as carrier flotation (Valderrama and Rubio, 1998; Zhu et al., 2009), shear flocculation (Duzyola and Ozkan, 2010; Yin et al., 2011), selective polymer flocculation (Rubio et al., 2007; Song et al., 2012; Ng et al., 2015), oil agglomeration (Laskowski and Lopez- Vladivieso, 2004; Forbes, 2011), temperature responsive polymer flocculation flotation (Forbes et al, 2011), and etc. However, these techniques above-mentioned are mainly studied for the direct flotation of fine minerals, and most of these techniques have not found applications for iron ore slimes especially recovered by the reverse cationic or anionic flotation."

Jan 1, 2018

By Ye Chen, Jianhua Chen, Meng Liu, Yuqiong Li, Xiao Mu, Cuihua Zhao

"Sulfidization-amine is the most effective method for the recovery of smithsonite (ZnCO3), however the interface interaction details remain unclear. The sulfidization-amine flotation mechanism of smithsonite has been studied by Density Functional based Tight Binding (DFTB+) method in this paper. The slab model of ZnCO3 (101) surface was built and the adsorptions of a monolayer of HS- and S2- ions were conducted to model the sulfidization effect on the ZnCO3 (101) surface adsorption. DDA hardly interacts with the hydrated ZnCO3 (101) surface. Under the low concentration of Na2S, HS- ions form a Zn-SH-SH structure on the ZnCO3 (101) surface, which hinders the interaction between DDA and surface Zn atoms. Under the high concentration of Na2S, a layer of ZnS is formed on ZnCO3 (101) surface, which is favorable for the adsorption of DDA on the surface. This is consistent with the flotation practice where smithsonite flotation requires a large amount of sodium sulfide. The results could provide a microscopic investigation into the sulfidization-amine flotation mechanism of smithsonite.INTRODUCTIONSmithsonite (ZnCO3) is an important and typical oxide mineral of zinc. It is a semi-soluble salt mineral with a solubility product constant of 1.46 × 10-10 (Weast, 1973). The most common and effective method to recover oxidized zinc ores is froth flotation (Caproni et al., 1979; Pereia and Peres, 2005; Kashani and Rashchi, 2008). It is well known that the flotation of oxidized zinc minerals is much more difficult than the flotation of zinc sulphide minerals (Hosseini and Forssberg, 2007).The recovery of zinc oxide ores with poor floatability attracts more and more attention due to the depletion of easy-recovered of zinc sulfide ores.Sulfidization-amine flotation, which using Na2S as sufidizing agent and amine as collector (Mckenna et al., 1949; Rey, 1954; Abramov, 1961; Rey, 1979; Hosseini and Forssberg, 2007). This method is the most successful technology used for zinc oxide minerals flotation in large-scale industrial applications since it was invented in the 1950s (Önal et al., 2005; Pereira and Peres, 2005). There have been numerous experimental researches on the sulfidization-amine flotation of smithsonite. Shi et al., (2013) studied solution chemistry of smithsonite flotation system. Feng and Wen (2017) studied the formation of zinc sulfide species on smithsonite surfaces and its response to flotation performance. Wu et al., (2017) investigated the sulfidization behavior of smithsonite with the use of zeta potential, inductively coupled plasma (ICP), scanning electron microscope (SEM), and X-ray photoelectron spectroscopic (XPS). Their measurement results confirms the chemisorption of sulfur ions and the formation of ZnS film on the smithsonite surface after Na2S treatment, however the influence of HS- ions on the surface and the influence of sulfidization on the amine adsorption have not been discussed."

Jan 1, 2018

By Jochen Petersen, Steven Bradshaw, Guven Akdogan, Ngoie Mpinga, James Mwase, Jacques Eksteen, Cornelius Snyders

"The platinum group metals (PGMs) and associated minerals are particularly refractory to most traditional direct leach processes. However, the remoteness of many new ore deposits, socio-political risks, the scarcity of skilled labor and constraints on the availability of water and electrical power makes it increasingly more difficult to implement the conventional mill-float-smelt-refine process routes to extract and refine PGMs in remote areas. This paper discusses a process to extract PGM’s from low grade ore and concentrate using a sequential stage heap leach process entailing heap bioleaching and high temperature cyanide leaching, and evaluates the feasibility of implementing a carbon-in-pulp process to recover the PGMs from the pregnant leach solution. The heap bioleaching extracts the base metals in an acidic sulfate medium using a mixed culture of thermophiles. After heap bioleaching the heap is reclaimed, rinsed, agglomerated and restacked for high temperature cyanide leaching where the cyanide liquor is directly heated via solar energy in panels. Palladium, gold and platinum are recovered during the cyanide leaching stage. The pregnant leach solution was evaluated for potential carbon-in-pulp adsorption and subsequent elution similar to gold processing. The kinetics of adsorption and elution compared well with gold adsorption and elution."

Jan 1, 2014

By A. Norori-McCormac

"Air recovery, the fraction of air entering a flotation cell that overflows the cell lip, is linked to flotation performance, and it has been shown through industrial testwork that operating flotation cells at air rates that yield the Peak Air Recovery (PAR) results in high mineral recovery. For operating parameters over which flotation plants have little control, such as particle size, investigating the effect on the position of PAR, and the subsequent effect on flotation performance, proves more challenging. To this end, we have developed a bench scale flotation system that runs continuously and exhibits froth behavior similar to that found industrially, allowing the study of such parameters as particle size in addition to air rate. The bench scale system comprises a 4 l baffled cylindrical flotation cell, stirred by a Rushton impeller. The concentrate is recycled back into the pulp, allowing for continuous operation. Glass beads are used as solid particles, allowing a wide range of particle sizes to be tested, with TTAB as collector and MIBC as frother. The system allows operation at air rates typical of industrial flotation systems (1 -2 cms-1 superficial gas velocity), in addition to yielding a froth that coalesces and bursts and exhibits a peak in air recovery as cell air rate in increased. Solids and water recovery is also measured. The results show that air recovery is sensitive to changes in particle size. The intermediate size distribution showed a peak in air recovery (PAR) that corresponded with the maximum solids flowrate, as found industrially. It is shown that finer particles do result in more stable froths and higher recoveries, particularly at low air rates. The effect of particle size on the position of PAR is not yet unequivocally determined from these results."

Jan 1, 2014

By B. Y. M. Bueno

Biosorption of heavy metals can be an effective process for the removal of heavy metals ions from aqueous solutions. In this study, the adsorption properties of Rhodococcus opacus biomass for Pb(II) and Cu(II) ions was investigated. The effects of initial pH, initial metal concentration and biomass concentration on biosorption efficiency were studied in a batch system. Results showed that the initial pH would play an important role in the Pb(II) and Cu(II) ions removal by R. opacus and affected the zeta potential of R. opacus. The equilibrium adsorption was reached with 60 min. The Langmuir and Freundlich models were used for describing of adsorption isotherm data. The maxi-mum adsorption capacities of biomass were determined as 94.3mgg-1 and 32.2 mgg-1 for the Pb(II) and Cu(II) ions, respectively. The experimental data fitted to pseudo second order kinetic model. Adsorption capacity of Pb(II) ions was found to be reduced by the presence of the other competing metal ions in the system. The FT-IR results of R. opacus biomass showed that biomass has different functional groups and these groups are able to react with metal ions in aqueous solution.

Jan 1, 2014