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By E. G. King

Thermodynamic calculations involving the oxides of tungsten and molybdenum have been hampered by lack of accurate entropies and high temperature heat contents. This paper presents work by the Federal Bureau of Mines on new low-temperature heat-capacity data leading to the evaluation of the 298.15° K. entropies of tungsten dioxide and tungsten trioxide, as well as high-temperature heat contents (above 298.15° K.) of molybdenum dioxide, molybdenum tri-oxide, tungsten dioxide, and tungsten trioxide. Included are heats of fusion of the two trioxides. The heats of formation at 298.15° K. of these four oxides are tabulated as measured by Mah4 5/ of this laboratory. Included also are the 298.15° K. entropy of Mo02 measured by Kin 6/ of this laboratory, and that for Mo03 according to Kelley and King.7/ These basic data provide a consistent compilation from which to perform accurate thermodynamic calculations involving these compounds. No previous low-temperature- heat-capacity measurements have been reported for tungsten dioxide. Seltz, Dunkerley, and DeWitt8/ measured the low-temperature heat capacity of tungsten trioxide. The only previously-reported high-temperature heat-content measurements for any of the oxides were conducted by Cosgrove and Snyder,9/ who measured molybdenum trioxide to 1,300° K.

Jan 1, 1960

By T. C. Atchison

This report describes a mobile laboratory designed and constructed by the Bureau of Mines in 1950 to meet the needs of an experimental blasting research program. The laboratory has facilities for making; film recordings of 16 simultaneous transient electrical signals over a broad range of amplitude, frequency, and duration. The signals are recorded with specially designed oscilloscopes and high-speed drum cameras. Each of the 16 channels records on a separate strip of 35-millimeter film by using interchangeable input units, transducers having different sensitivities and output impedances can be accommodated. The laboratory can be used to record both steady-state and transient phenomena originating as electrical voltages or capable of being converted to electrical voltages by appropriate transducers. Thus, the laboratory can, be used in studying various types of vibration problems or high-speed phenomena, such as ground and building vibrations, machinery vibrations, airborne vibrations, electrical-circuit switching phenomena, millisecond timing, and seismic phenomena occurring when rock is broken by explosives.

Jan 1, 1956

By M. H. Kline

The Great Gossan Lead in Carroll County, Va., is one of the largest undeveloped sulfide ore bodies known in the eastern United States. It extends for 16.7 miles along the western slope of the Blue Ridge Mountains (fig. 1). The various known segments of the deposit, extending from the southwest end to the northeast, are: The Great Outburst or Iron Ridge segment, Chestnut Creek, Copperas Hill, Sarah Ellen, Wild Cat, Cranberry, Dalton Hill and offset segment to the south of the Cranberry, Little Reed Island, Little Vine, and the Betty Baker at the northeast end. All of these segments have been explored or mined to various extents in the past for the iron gossan and secondary copper ore. The Great Outburst or Iron Ridge segment is now being mined by the General Chemical Division of the Allied Chemical & Dye Corp. for the sulfur and iron content of the primary ore. These deposits are becoming increasingly of Interest as a. large potential source of iron and sulfur owing to their proximity to Birmingham, where the burned cinder sells at a premium, and to the acid markets of the region.

Jan 1, 1949

By W. H. Carrington, A. C. Richardson

"INTRODUCTION The Powhatan mine of the Franklin Coal Mining Co. is located in the western part of Jefferson County, Ala., on the Louisville and Nashville Railroad, 40 miles west of Birmingham. The Mary Lee bed at this point yields coal with fair coking qualities, but with an ash content as mined so high as to prohibit its use in the production of metallurgical coke. At present the entire output of the mine is washed in single-compartment jigs and marketed as locomotive and domestic fuel.Figure 1 gives a typical seam section of the Mary Lee bed at the Powhatan mine. This section shows that the bed is divided by rock partings into three benches. In many parts of the mine, particularly in the older workings the roof rock is so weak that it can not be held without excessive timbering. This condition has restricted the operation in many parts of the mins to the middle and bottom benches of coal. The 6 inches of draw rock between the top and middle benches is very strong and makes an excellent roof requiring only a normal amount of timbering to support it. In the newer workings of the mine the character of the rock above the top bench is strong and it is believed that in the future it will be possible to work all three benches. This study was undertaken for the purpose of determining the washing characteristics of the Mary Lee bed at Powhatan and the effect on these characteris-tics of including or omitting the coal from the top bench. It was also the purpose of the study to show whether it would be possible to produce a washed product sufficiently low in ash to be used for the manufacture of metallurgical coke. This paper is one of a series of reports on the washability of Alabama coals which is being prepared by the U. S. Bureau of Mines and tin University of Alabama. With the cooperation of the coal producers of Alabama. It contains the results of screen sizing and float-and-sink tests of representative samples of run-of-mine coal, and the results of table tests on the minus 3/16-inch sizes of the raw coal."

Apr 1, 1933

By Larry A. Haas

The Bureau of Mines constructed a torsion effusion apparatus to measure the equilibrium vapor pressure of pure metals, alloys, and compounds at temperatures up to 1,500° K. The reliability of the apparatus was established by determining the vapor pressure of silver. The data obtained on solid and liquid silver in the temperature range 1,200° to 1,500° K can be expressed by the following equations:

Jan 1, 1965

By K. A. Fowler, L. W. Higley

The effect of uranium on the transformation kinetics and the hardenability of a low- alloy steel was evaluated . Isothermal transformation curves were developed from metallographic studies , and hardenability was determined by standard Jominy end- quench tests . For the steels investigated , the addition of 0.15 weight- percent uranium was found to produce a significant shift in the isothermal transformation curve and caused a related increase in hardenability . These effects diminished rapidly when the uranium content was increased above 0.2 weight - percent .

Jan 1, 1964

By Winthrop F. Watts

The U.S. Bureau of Mines evaluated the performance of a catalyzed diesel particulate filter (CDPF) and a CDPF combined with a diesel oxidation catalyst (DOC) at two metal mines. This report describes the results from the two field evaluations. The CDPF-DOC was installed on a load-haul-dump (LHD) powered by a 175-kW, prechambered, turbocharged engine. This system reduced diesel particulate matter (DPM) concentrations by 71±28 pet, as determined by size-selective sampling with gravimetric analysis, and by 71±29 pet, as determined by respirable combustible dust (RCD) analysis at the vehicle operator's location. The CDPF was installed on a diesel-hydraulic, roof-bolting jumbo, powered by a 172-kW engine. The CDPF reduced DPM concentrations by 72±21 pet, as determined by size-selective sampling with gravimetric analysis, and by 62±25 pet, as determined by RCD analysis at the vehicle operator's location. Underground evaluation was more difficult because of frequent movement by the roof-bolting jumbo, variation in daily workload, tremendous fluctuation in ventilation airflow rates, and use of a high sulfur diesel fuel, which promotes the formation of sulfate particles, decreases filtration efficiency, and hastens the deterioration of the catalyst.

Jan 1, 2010

By Albert L. Toenges

(1) The Castleman Basin was investigated by diamond drilling, engineering examination, and geologic study. Agreements permitting investigation of about 14,700 acres of land were entered into with 79 landowners. Eleven beds of coal between the horizons of the Harlem and Mercer beds were penetrated in drilling. These beds from top downward are: Harlem, Upper Bakerstown, Lower Bakerstown, Brush Creek, Upper Freeport Rider, Upper Freeport, Upper Kittanning, Middle Kittanning, Lower Kittanning, Mount Savage, and Mercer. The total estimated reserves of coal (measured, indicated, and inferred), 14 inches or more thick, in six beds follow: [Coal bed: Etimated reserves, tons Harlem _______________________ 23,430,000 Lower Bakerstown _______________ 44, 688, 000 Brush Creek ____________________ 23, 694, 000 Upper Freeport __________________57, 731, 000 Upper Kittanning ________________ 40, 450, 000 Middle Kittanning ______________42,276,000 Total________________________ 232,269,000]

Jan 1, 1952

By John Ward Smith

Detailed oil yield, lithologic, and mineral distribution data are presented for core and drill-cutting samples from the Western Oil Shale Corp. Project Utah EX-1 Corehole (WOSCO EX-I), drilled to sample a deeply buried oil-shale sequence in the Green River Formation of Utah's Uinta Basin. Drilling of this corehole was part of the evaluation of this site for possible oil-shale development by nuclear explosion. Sections sufficiently thick for nuclear development average 15 gallons per ton or less and consist predominantly of low-grade shales. Some properties of low-grade shales may be advantageous to a nuclear experiment by facilitating breakage, fracture development, and in situ retorting. The formation correlates precisely with the well-studied oil shales 25 miles east near the Colorado border. A 235-foot mineralized section containing nahcolite, shortite, and searlesite whose bottom lies 300 feet above the Mahogany zone is described.

Jan 1, 1972

By R. E. Heithecker

Zwolle oil field of Sabine Parish, La., is different from most oil producing areas of the State in that the oil is obtained from marl and chalk-rock formations. The thickness of the reservoir rocks averages 500 feet; but production is not continuous throughout this thickness, as the oil apparently is localized in vertical and nearly vertical solution cavities and channelways or in porous zones of limited horizontal extent. The nature of the oil accumulation has caused two outstanding peculiarities of the field: (1) About 60 percent of the tests drilled were dry holes and (2) there were many instances of well interference. Commercial production was discovered in November 1928, after 17 years of prospecting in and around the present limits of the area now developed which has a length of about 22 miles and a maximum width of 4 miles. The field had produced 10,266,896 barrels of oil to January 1, 1934. The oil ranges in gravity from 400 to 420 A.P.I. Although the field is divided into several districts which are more or less clearly defined and separated by unproved territory the term Zwolle field", as used in this report, includes the entire area from Blue Lake on the west side, through Zwolle proper, and eastward, including the Many or Eastern extension.

Jan 1, 1934

By A. E. Back

[Several processes for recovering manganese from low-grade ores have been proposed3/4/5/ in which an aqueous slurry of the ore is leached with gas containing nitrogen, oxygen, and sulfur dioxide as obtained from burning sulfur or roasting sulfide ores. The manganese dioxide is dissolved, and most of the sulfur dioxide is oxidized to sulfate, but an appreciable quantity of dithionate is usually formed, together with acid from oxidation of the sulfur dioxide. The over-all reactions may be represented as follows: (1) Mn02 + S02 = Mn++ + S04--. (2) Mn02 + 2S02 = Mn++ +S206--. (3) H20 + So2 + 1/2 02 = 2H+ 5S4--. (4) H20 + 2S02 + 1/2 02 = 2H+ + S206---.]

Jan 1, 1952

By J. H. East

"INTRODUCTION .Very little information regarding coal mining in Spain has been published in the American technical press, and few people realize the extent of this industry or the conditions under which coal is mined. The information in this publication was collected in 1945 and consists of personal observations in Spain, statistics, and other data of a, general nature obtained from official sources.Spain produces bituminous coal, lignite and anthracite, but the total tonnage mined is less than the national requirements. Before the war, an appreciable tonnages coal was imported from Great Britain under the Anglo-Spanish treaty, which rebated import duties and effectually prevented competition from any other foreign source. The war stopped the major part of the important of British coal and caused rapid expansion of the domestic sources, but this was not sufficient to supply the industrial demand. Coal that formerly was not acceptable to industry because of quality is now mined and marketed. The Government, allocates the better-grade bituininous coal to the various industries in accordance with the national importance of the work in which they are engaged; for example, the railroads are allotted 100 percent of their requirements, but cement companies can obtain only 25 percent.The Government offered to inducements to increase the production of coal of any class, but the larger part of the increased tonnage obtained was in inferior grades; as a result, the lignite production was taxed, while a bonus was paid for bituminous-coal production in excess of the 1942 tonnage.The anthracite and bituminous-coal areas were severely damaged during the Civil War and many experienced miners migrated to the lignite mines in eastern Spain. This has resulted in an acute shortage, particularly the Province of Oviedo where the most important bituminous-coal deposits are located."

Jan 1, 1947

By John W. Finch

The present epoch in human history has been variously described as the age of coal, of oil, of iron and steel, and of power. All agree, however, that it is a great industrial period. Power is of course the vital force in the industrial organism; but power is derived chiefly from mineral fuels or from harnessed and controlled water - also a mineral substance although usually not so classified by industry. However, the latent energy of fuels cannot work for men until it is changed to active energy by combustion and until this active energy is converted into motion. This motion is just as indispensible as the energy itself. Likewise, the latent energy of water cannot be utilized until it, too, is converted into motion; out the mechanisms and devices for converting latent energy into motion, as well as the structures in which they are operated, would not be possible without metals and other minerals. Consequently, minerals are fundamental in industrial civilization.

Jan 1, 1938

By J. M. Mutmansky, C. Lee

"This paper outlines some of the work associated with a research study into the relationship between the characteristics of coal mine dust and the incidence of coal workers' pneumoconiosis (CWP). The project involves study of the chemical, mineralogical, and morphological characteristics of the dust. Early stages of the study have dealt primarily with the size analysis and elemental composition of airborne dust in continuous miner sections. This paper outlines the procedures and findings of the elemental analysis portion of the study.Most of the previous elemental analyses of coal were made available in the quest for information on the combustibility of coal dust or on causal agents and prevalence of CWP. However, no extensive studies have been performed to date, primarily due to the limitations of the analytical methods. A review of the analytical methods for elemental characterization of coal and coal dust particles is presented. TI1e comparisons are made based on the sample mass required, the sample preparation required, the destructivity of the test, and the capability of providing an easy multi-element analysis. The reasons for selecting the proton-induced x-ray emission spectroscopy (PIXE) method are outlined.The PIXE method was applied to both the airborne coal mine dust and channel samples collected from seven continuous miner sections in six different mines. Channel samples of the coal, roof and floor were collected and analyzed. Airborne dust sampling was performed using multi-stage cascade impactors and permissible 2.0 I/min pumps. Sampler locations were fixed in the sections with respect to the continuous miner and roof bolter or with respect to the intake and return airways. Sampling times varied from 45 minutes to 6 hours, depending on the dust concentration.The statistical analysis of the resulting elemental data is presented. Of particular importance are the analyses of the variation of elemental composition with size and the variation in elemental composition over the working section. One interesting finding is outlined showing the multivariate statistical analysis of the trace elements and its implications in the identification of the dust sources. The paper concludes with an analysis of the ramifications of the elemental data to related medical studies."

Mar 1, 1989

By J. A. Herdlick

"INTRODUCTION The BeVan quartz crystal prospect in the Indian Creek mining district of Lemhi County, west-central Idaho, was examined by an engineer of the Bureau of Mines 3/ on July 9, 1943. As quartz crystals possessing peizoelectric properties were on the critical list of strategic war minerals, further exploration of the deposit was recommended. The Bureau of Mines exploration began in December 1943 and continued through January 1944. Additional trenching was completed during May and June 1944. This report presents the data obtained by this exploration.ACKNOWLEDGMENTSIn its program of exploration of mineral deposits, the Bureau of Mines has as its primary objective the more effective utilization of our mineral resources to the end that they make the greatest possible contribution to national security and economy. The Mining Division, Lowell B. Moon, chief, conducts preliminary examinations, does the actual exploratoiy work, and prepares the final report. The Metallurgical Division, O. C. Ralston, chief, analyses samples and makes beneficiation tests.The quartz crystals found during the exploration were examined and classified at the Bureau of Mines College Park, Md., laboratory and checked at the National Bureau of Standards, Washington, D. C.Fred BeVan, of North Fork, Idaho, and Edward F. Cenis, of the Montana Coal & Iron Company, Spoane, Wash., provided much information on the history and past production of the property."

Mar 1, 1948

By E. L. Garton

The oil-producing district, "Southern Oklahoma," is generally considered to be that part of the: State lying southwest of the Arbuckle Mountains. It includes six counties: Cater, Cotton, Garvin, Jefferson, Kiowa, and Stephens. At present cost of the oil is produced from formations of Pennsylvanian age. The individual crude oils resemble those produced in other parts of the State, except that the sulfur content is rather high. This report is a continuation of a study of Oklahoma crude oils3/being made, by the Bureau of Mines, Petroleum Experiment Station, Bartlesville, Okla. in cooperation with the State of Oklahoma. Analyses are given of 27 samples obtained from 21 fields in the southern part of the State, end the physical and chemical characteristics of these crude oils are discussed briefly. Analyses of crude oils from other Oklahoma areas and publications in which these analyses may be found are listed in tables 2 and 3.

Jan 1, 1941

By William W. Adams

The stone-quarrying industry of the United States, including such related operations as rock crushing, rock dressing, and the manufacture of cement and lime, reported a larger volume of employment in 1934 than in 1933. Reports from the operating companies to the United States Bureau of Mines showed an increase in the number of men employed, number of man-days of employment, and total number of man-hours of labor performed during the year. Moreover, the average worker had a longer period of employment during 1934, the gain amounting to 11 percent over 1933. The increase in employment was accompanied by no increase in accidents for the industry as a whole; in fact, the accident rate for 1934 was a fraction lower than the rate for 1933. In some branches of the industry the frequency of accidents increased, but these increases were more than offset by reductions in rates for other branches. Reports for 1934 were received from 1,403 active plants. The working force averaged 64,331 men for 204 days per man, and the total period of employment for all of the men was 95,258,880 man-hours. Each employee averaged 1,481 hours of work during the year. The total number of hours of labor represented a gain of more than 8 percent, and the average working time per employee showed a gain of 62 hours per man.

Jan 1, 1936

By W. A. Young

Vermiculite deposits on the. Platt ranch, 12 miles southeast of Encampment Carbon County, Wyo., were investigated by the Bureau of Mines early in 1949. Major activity was centered on property held under lease by the Mikolite Mining & Development Co. (figs. 1 and 2). Vermiculite occurs in masses and lenses of varying size and as disseminations in altered hornblende diorite. Alteration of the host rock probably resulted from the proximity of dikes and irregular masses of pegmatite. Investigation of the Mikolite property consisted of surface trenching, diamond drilling, and sampling. Four trenches totaling 5,401 linear feet were excavated with a bulldozer and Diesel power shovel. Three diamond-drill holes totaling 600 feet were drilled from the surface to determine the character of mineralization at depth. Eighty-one bulk samples were obtained from the trenches, and 130 sludge samples were collected from the drill holes. Samples were analyzed, and ore-dressing tests were made in the Bureau of Mines laboratories at Salt Lake City.

Jan 1, 1952

By J. G. Walters

In 1928, the Coal Carbonization Section of the Federal Bureau of Mines, in cooperation with the American Gas Association, began a survey of the carbonizing properties of American coals. A standard test method for evaluating the carbonizing properties of coals that met the following conditions was developed: To yield products similar to those obtained in commercial operations. To produce yields sufficient to permit analyses and tests of quality. To be laboratory size. To be convenient to operate. To permit reproducible control of test conditions and results. This test method has become known as the Bureau of Mines-American Gas Association (BM-AGA) test (53),3/ and more coals of greater variety have been tested in this apparatus than in any other of similar scale.

Jan 1, 1961

By R. Vernon Helm

Four tables listing values for the various physical properties of those sulfur compounds most likely to occur in petroleum and petroleum products are given herein. The data necessary to bring the first compilation2/ in this subject up to date are given in table I -Revised and Additional Data, which includes boiling points, refractive indices, densities, and freezing points. Tables 11-, III, and IV are published for the first time and include refractive indices for the F, C, and G' lines of hydrogen and the helium D:3 line; surface tensions and viscosities, and refractivity intercepts, specific dispersions, specific refractions, and parachors. The need for information concerning the sulfur compounds in petroleum is becoming-more urgent because of the necessity of refining larger quantities of high-sulfur crude oil to meet the rising demand for petroleum products. For a number of years the Bureau of Mines has been engaged in research to make available more information concerning the properties of the sulfur compounds in petroleum. The petroleum industry has recognized the value of such studies, and as a result the American Petroleum Institute has established Research Project 48A to study sulfur compounds. The investigations under this Project are to be done in Bureau of Mines laboratories as a cooperative project in connection with the work already started.

Jan 1, 1949